KR20240134895A - 디(히드록시메틸)테트라히드로푸란의 합성 방법 및 폴리에스테르 및 폴리우레탄에서의 그의 적용 - Google Patents

디(히드록시메틸)테트라히드로푸란의 합성 방법 및 폴리에스테르 및 폴리우레탄에서의 그의 적용 Download PDF

Info

Publication number
KR20240134895A
KR20240134895A KR1020247023576A KR20247023576A KR20240134895A KR 20240134895 A KR20240134895 A KR 20240134895A KR 1020247023576 A KR1020247023576 A KR 1020247023576A KR 20247023576 A KR20247023576 A KR 20247023576A KR 20240134895 A KR20240134895 A KR 20240134895A
Authority
KR
South Korea
Prior art keywords
trans
dhmthf
cis
mixture
mol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
KR1020247023576A
Other languages
English (en)
Korean (ko)
Inventor
브리안 슈피겔베르크
아드리안 브란트
호르스트 베크
알렉산더 쿡스
제르가이 틴
요하네스 헤라르뒤스 더프리스
Original Assignee
헨켈 아게 운트 코. 카게아아
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 헨켈 아게 운트 코. 카게아아 filed Critical 헨켈 아게 운트 코. 카게아아
Publication of KR20240134895A publication Critical patent/KR20240134895A/ko
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/12—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3218—Polyhydroxy compounds containing cyclic groups having at least one oxygen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/423—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
    • C08G18/425—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids the polyols containing one or two ether groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/123—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1535—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
    • C09J167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00—Compositions for adhesives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Adhesives Or Adhesive Processes (AREA)
KR1020247023576A 2022-01-18 2022-12-16 디(히드록시메틸)테트라히드로푸란의 합성 방법 및 폴리에스테르 및 폴리우레탄에서의 그의 적용 Pending KR20240134895A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP22151959.8 2022-01-18
EP22151959.8A EP4212518A1 (en) 2022-01-18 2022-01-18 Methods for the synthesis of di(hydroxymethyl)tetrahydrofuran and its application in polyesters and polyurethanes
PCT/EP2022/086288 WO2023138854A1 (en) 2022-01-18 2022-12-16 Methods for the synthesis of di(hydroxymethyl)tetrahydrofuran and its application in polyesters and polyurethanes

Publications (1)

Publication Number Publication Date
KR20240134895A true KR20240134895A (ko) 2024-09-10

Family

ID=79730589

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020247023576A Pending KR20240134895A (ko) 2022-01-18 2022-12-16 디(히드록시메틸)테트라히드로푸란의 합성 방법 및 폴리에스테르 및 폴리우레탄에서의 그의 적용

Country Status (7)

Country Link
US (1) US20240368099A1 (https=)
EP (2) EP4212518A1 (https=)
JP (1) JP2025504449A (https=)
KR (1) KR20240134895A (https=)
CN (1) CN118574813A (https=)
TW (1) TW202336082A (https=)
WO (1) WO2023138854A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116903823A (zh) * 2023-08-17 2023-10-20 广州境好新材料有限公司 一种生物基自修复聚氨酯树脂及其制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8324409B2 (en) * 2010-04-23 2012-12-04 The Board Of Trustees Of The University Of Illinois Efficient method for preparing 2,5-dimethylfuran
FR3020811B1 (fr) * 2014-05-09 2016-06-10 Roquette Freres Polyesters aromatiques thermoplastiques comprenant des motifs tetrahydrofuranedimethanol et acide furanedicarboxylique
EP3037453A1 (fr) * 2014-12-22 2016-06-29 Rhodia Operations Polyesters issus de diacide carboxylique aromatique et du 2,5-bis(hydroxymethyl)tetrahydrofurane
WO2017091437A1 (en) 2015-11-24 2017-06-01 Archer Daniels Midland Company Organotin catalysts in esterification processes of furan-2,5-dicarboxylic acid (fdca)
WO2017091412A1 (en) 2015-11-24 2017-06-01 Archer Daniels Midland Company Oligomers of fdca and glycols from a one-pot esterification-transesterification process using water-tolerant metal triflate catalyst
CN116615479A (zh) * 2020-12-18 2023-08-18 巴斯夫欧洲公司 包含2,5-双(羟甲基)四氢呋喃的聚酯多元醇

Also Published As

Publication number Publication date
EP4212518A1 (en) 2023-07-19
US20240368099A1 (en) 2024-11-07
TW202336082A (zh) 2023-09-16
EP4466256A1 (en) 2024-11-27
CN118574813A (zh) 2024-08-30
JP2025504449A (ja) 2025-02-12
WO2023138854A1 (en) 2023-07-27

Similar Documents

Publication Publication Date Title
US20100105831A1 (en) Moisture-curing hot-melt adhesive with good adhesion
US20240368099A1 (en) Methods for the synthesis of di(hydroxymethyl)tetrahydrofuran and its application in polyesters and polyurethanes
EP4132989B1 (en) Thermoplastic polyurethanes derived from lignin monomers
CN115926124B (zh) 一种聚丁二酸/对苯二甲酸丁二醇酯基热塑性聚酯弹性体及其制备方法
US4096129A (en) Glutarate-containing polyesterpolyols, methods of preparation and polyurethane compositions derived therefrom
CN112839976B (zh) 包含生物基聚酯多元醇的热熔粘合剂组合物
EP3127934B1 (en) Polyester polyol having superior durability
EP2752438A2 (en) Production method for a biodegradable polyester copolymer resin
JP2008095109A5 (https=)
US7094357B2 (en) Compatibilizing agent, polyester polyol mixture containing the same, and hot-melt adhesive obtained from the mixture
JPH05263059A (ja) ポリウレタン系接着剤
CN104151547A (zh) 非异氰酸酯法制备酰胺型可生物降解热塑性聚氨酯的方法
US4734462A (en) Preparation of block polyurethane-amides
JP3983321B2 (ja) 熱可塑性ポリウレタン組成物およびその製造方法
EP1693396B1 (en) Crystalline polyester polyol and hot melt adhesive
CN101613455B (zh) 高固含量型聚氨酯树脂组合物及其制备方法
EP3719046B1 (en) Crystalline polyesterpolyol
JPH0790072A (ja) 高分子量ポリエステルの製造方法
CN118406222B (zh) 一种生物基聚酯多元醇及其制备方法、应用
Noordover Polyesters, polycarbonates and polyamides based on renewable resources
JPH039923A (ja) ポリエステルポリオールの製造法及びそれを用いたポリウレタンエラストマー
EP3087116A1 (en) Polyurethane
CN111100275A (zh) 一种全生物降解增粘剂及其制备方法
CN121824930A (zh) 一种聚酯多元醇及其制备方法和应用
JP3048313B2 (ja) 高分子量脂肪族ポリエステルの製造方法

Legal Events

Date Code Title Description
PG1501 Laying open of application