KR20230045339A - Color cosmetic composition comprising polyol-oil emulsions - Google Patents
Color cosmetic composition comprising polyol-oil emulsions Download PDFInfo
- Publication number
- KR20230045339A KR20230045339A KR1020210128057A KR20210128057A KR20230045339A KR 20230045339 A KR20230045339 A KR 20230045339A KR 1020210128057 A KR1020210128057 A KR 1020210128057A KR 20210128057 A KR20210128057 A KR 20210128057A KR 20230045339 A KR20230045339 A KR 20230045339A
- Authority
- KR
- South Korea
- Prior art keywords
- cosmetic composition
- polyol
- powder
- oil
- glycol
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 105
- 239000000839 emulsion Substances 0.000 title claims abstract description 70
- 239000002537 cosmetic Substances 0.000 title claims abstract description 65
- 239000000843 powder Substances 0.000 claims abstract description 87
- 239000000049 pigment Substances 0.000 claims abstract description 37
- 238000009472 formulation Methods 0.000 claims abstract description 25
- 239000000454 talc Substances 0.000 claims abstract description 18
- 229910052623 talc Inorganic materials 0.000 claims abstract description 18
- 239000003921 oil Substances 0.000 claims description 124
- 235000019198 oils Nutrition 0.000 claims description 61
- -1 sericite Substances 0.000 claims description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 27
- 239000010445 mica Substances 0.000 claims description 26
- 229910052618 mica group Inorganic materials 0.000 claims description 26
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 14
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 229920005862 polyol Polymers 0.000 claims description 12
- 150000003077 polyols Chemical class 0.000 claims description 12
- 229920002545 silicone oil Polymers 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 9
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 9
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 8
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000004677 Nylon Substances 0.000 claims description 6
- 229920001778 nylon Polymers 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 150000003904 phospholipids Chemical class 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- YSRSBDQINUMTIF-SNVBAGLBSA-N (2r)-decane-1,2-diol Chemical compound CCCCCCCC[C@@H](O)CO YSRSBDQINUMTIF-SNVBAGLBSA-N 0.000 claims description 4
- 229940043375 1,5-pentanediol Drugs 0.000 claims description 4
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 claims description 4
- 239000011703 D-panthenol Substances 0.000 claims description 4
- 235000004866 D-panthenol Nutrition 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 claims description 4
- 229940106189 ceramide Drugs 0.000 claims description 4
- 235000012000 cholesterol Nutrition 0.000 claims description 4
- 229940097037 decylene glycol Drugs 0.000 claims description 4
- 229960003949 dexpanthenol Drugs 0.000 claims description 4
- 229940105990 diglycerin Drugs 0.000 claims description 4
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 4
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 4
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 claims description 4
- 229940051250 hexylene glycol Drugs 0.000 claims description 4
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 claims description 4
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 claims description 4
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 claims description 4
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- 239000008158 vegetable oil Substances 0.000 claims description 4
- NCZPCONIKBICGS-UHFFFAOYSA-N 3-(2-ethylhexoxy)propane-1,2-diol Chemical compound CCCCC(CC)COCC(O)CO NCZPCONIKBICGS-UHFFFAOYSA-N 0.000 claims description 3
- 241001237961 Amanita rubescens Species 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 3
- 229940100524 ethylhexylglycerin Drugs 0.000 claims description 3
- 229960005150 glycerol Drugs 0.000 claims description 3
- 239000002502 liposome Substances 0.000 claims description 3
- 239000007908 nanoemulsion Substances 0.000 claims description 3
- 229920000193 polymethacrylate Polymers 0.000 claims description 3
- 239000011863 silicon-based powder Substances 0.000 claims description 3
- 150000001783 ceramides Chemical class 0.000 claims description 2
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- 239000011230 binding agent Substances 0.000 abstract description 24
- 230000000694 effects Effects 0.000 abstract description 3
- 229940008099 dimethicone Drugs 0.000 description 30
- 239000004205 dimethyl polysiloxane Substances 0.000 description 30
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 30
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 30
- 239000002994 raw material Substances 0.000 description 27
- 238000011156 evaluation Methods 0.000 description 15
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- 230000000052 comparative effect Effects 0.000 description 12
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 12
- 238000011161 development Methods 0.000 description 11
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical class CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 10
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 229940097941 polyglyceryl-10 laurate Drugs 0.000 description 9
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- 238000002360 preparation method Methods 0.000 description 8
- 238000004220 aggregation Methods 0.000 description 7
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- 239000004615 ingredient Substances 0.000 description 7
- XMFXBMLFOSSELI-UHFFFAOYSA-N 2-octyldodecyl 12-octadecanoyloxyoctadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(CCCCCC)CCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC XMFXBMLFOSSELI-UHFFFAOYSA-N 0.000 description 6
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 6
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
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- Emergency Medicine (AREA)
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Abstract
Description
본 발명은 폴리올-오일 유화물을 포함하는 색조 화장료 조성물에 관한 것이다.The present invention relates to a color cosmetic composition comprising a polyol-oil emulsion.
파우더는 피부 톤(tone) 및 피부 결(texture)을 고르게 하고 모공, 흠집, 잔주름 등을 감추기 위하여 얼굴 및 신체의 기타 부위에 도포될 수 있다. 이러한 파우더 형태의 메이크업 조성물의 구성은 바탕 질감을 부여하고 특정 색상이 발현될 수 있도록 모체를 제공하며 나아가 사용이 용이하도록 만드는 체질 원료(Bulking agent)와 가시광선 영역의 빛의 과학을 바탕으로 하는 다양한 유·무기 색소(Colorant)의 조합을 기본으로 한다. 여기에 성형성과 모든 원료가 조합을 이룰 수 있도록 돕는 인체에 무해한 오일류와 적정량의 방부제가 함유되어 일반적인 압축 성형된 파우더류 화장품이 완성된다. The powder can be applied to the face and other parts of the body to even out skin tone and texture and to hide pores, blemishes, fine lines, and the like. The makeup composition in the form of powder is composed of a bulking agent that gives a background texture, provides a base for a specific color to be expressed, and makes it easy to use, and various materials based on the science of light in the visible light range. It is based on the combination of organic and inorganic colorants. Here, oils harmless to the human body and an appropriate amount of preservatives that help formability and all raw materials are combined, completing general compression-molded powder-type cosmetics.
이렇게 구성된 파우더 화장품은 더 나아가 진주 광택 안료(Pearlescent pigment)를 구성 원료에 포함하여 고유 굴절률을 활용한 광택을 낼 수도 있으며 나아가 바탕색과는 또 다른 색감을 연출해 극대화된 아름다움을 표현해낼 수도 있다. 진주 광택 안료를 함유하는 압축 분말상 화장료 조성물은 진주 광택 안료의 함량에 따라 오일의 함량을 결정하는 형태로 안정도 확보 및 발림성의 적절성 확보를 위해 보통 10%~30% 정도 범위의 오일 바인더를 사용한다.Powder cosmetics composed in this way can further include pearlescent pigment in the constituent raw materials to create a gloss utilizing the unique refractive index, and furthermore, it can express a maximized beauty by creating a color different from the background color. The compressed powder cosmetic composition containing the pearl luster pigment determines the oil content according to the content of the pearl luster pigment, and usually uses an oil binder in the range of 10% to 30% to secure stability and appropriateness of application.
그러나 더 높은 효과를 얻기 위해서 보다 많은 양의 진주 광택 안료가 존재할수록 유리하지만 진주 광택 안료의 비율이 높아짐에 따라 파우더 제형의 성형성 및 낙하 안정도를 유지하기가 어려워진다는 위험도가 존재한다. 이에 따라 파우더 바인더 및 오일 바인더의 함량을 높여 이를 극복하려 하지만 경도 및 사용감이 크게 저해되며 많은 시행착오를 요하게 된다.However, it is advantageous to have a larger amount of pearlescent pigment to obtain a higher effect, but there is a risk that it is difficult to maintain moldability and falling stability of the powder formulation as the proportion of pearlescent pigment increases. Accordingly, an attempt is made to overcome this by increasing the content of the powder binder and the oil binder, but the hardness and the feeling of use are greatly inhibited, and a lot of trial and error is required.
한편, 무기 안료 중의 하나인 탈크(Talc:활석)의 경우 마그네슘을 포함한 규산염 광물로, 피부에 대한 전연성, 부착성, 땀과 피지의 흡수성과 사용감촉, 그리고 광택 등의 마무리를 조정하는 원료로서 거의 모든 파우더 타입 색조 화장품에 함유되어 있다. 이러한 파우더 베이스 메이크업의 주기제인 탈크는 가격이 저렴하며 대량으로 산출되기 때문에 제지, 섬유, 고무, 의약품, 화장품 등의 산업 전 분야에서 광범위하게 사용되고 있다. 활석은 그 특성으로서 무미무취로 화학적/열적으로 불활성이며, 유제의 흡수능력이 크다는 등의 사용시 장점이 있고, 가벼운 커버, 우수한 퍼짐성을 위해 콤팩트에 30~50% 사용된다[F. V. Wells, Cosmetics and the skin, eds, I.I. Lubowe, 216, REINHOLD BOOK Co., New York (1964)]. 하지만, 탈크는 폐질환, 폐암, 피부암, 난소암과의 밀접한 관련성이 있는 석면과 화학적 구성 성분이 매우 유사하며, 모암 속에서 탈크이 발달할 때 바로 인근에 석면, 특히 백석면과 투각섬석(트레몰라이트)이 함께 만들어질 가능성이 있고, 순수한 활석을 채광하기는 쉽지 않고 여러 불순물이 혼재하는데 발암 물질인 석면이 섞여 있을 경우 특히 문제를 일으킨다는 연구 보고가 있다.(미국 국립 독성 연구원)On the other hand, in the case of talc (talc), one of the inorganic pigments, it is a silicate mineral containing magnesium. It is contained in all powder type color cosmetics. Since talc, which is a main agent of such powder-based makeup, is inexpensive and produced in large quantities, it is widely used in all industries such as paper, textile, rubber, pharmaceuticals, and cosmetics. As a characteristic, talc is tasteless and odorless, chemically/thermally inactive, and has advantages such as high absorption capacity of emulsions, and is used in compacts for a light cover and excellent spreadability by 30-50% [F. V. Wells, Cosmetics and the skin, eds, I.I. Lubowe, 216, REINHOLD BOOK Co., New York (1964)]. However, talc is very similar in chemical composition to asbestos, which is closely related to lung diseases, lung cancer, skin cancer, and ovarian cancer. ) is likely to be made together, and it is not easy to mine pure talc, and various impurities are mixed. There is a research report that it causes problems especially when asbestos, a carcinogen, is mixed. (US National Institute of Toxicology)
그래서 파우더 베이스 메이크업 제품에서 매끄러운 사용감의 활석을 배제하고 운모(MICA)와 고령토(KAOLIN) 같은 성분을 사용한 제품도 있지만, 거친 사용감을 나타내는 무기자외선 차단제인 이산화티타늄(TITANIUM DIOXIDE), 산화아연(ZINC OXIDE)를 처방하지 않고 사용감을 향상시킨 비기능성 제품에 국한되어 있는 실정이다. 또한 활석 대신 운모를 다량 사용시 충분한 성형 안정성을 얻을 수 없는 경우가 많다.So, in powder-based makeup products, there are products that use ingredients such as mica (MICA) and kaolin (KAOLIN) by excluding talc for a smooth feeling of use, but titanium dioxide (TITANIUM DIOXIDE) and zinc oxide (ZINC OXIDE), which are inorganic sunscreens that show a rough feeling of use. ), but is limited to non-functional products that improve the feeling of use. In addition, when a large amount of mica is used instead of talc, sufficient molding stability cannot be obtained in many cases.
따라서, 우수한 파우더 메이크업 제형을 제공하기 위하여 비교적 높은 진주 광택 안료의 함량이지만 탈크를 사용하지 않고도 낙하 안전성이 확보할 수 있고, 탈크를 포함하지 않아 소비자를 만족시킬 수 있는 화장료 조성물에 대한 개발이 요망된다.Therefore, in order to provide an excellent powder makeup formulation, it is desired to develop a cosmetic composition that has a relatively high pearl luster pigment content but can secure fall safety without using talc and does not contain talc to satisfy consumers. .
본 발명은 비교적 높은 진주 광택 안료의 함량이지만 탈크를 사용하지 않고도 낙하 안전성이 확보되면서 기존에 일반적인 압축 분말상 제형에 적용되지 않았던 폴리올-오일 유화물 형태의 복합체를 함유하는 고성능의 오일 바인더를 과량으로 적용하여 사용자에게 보다 탁월하고 차별화된 사용감을 줄 수 있는 고광택, 고발색의 높은 화장 효과를 줄 수 있는 고성능의 화장료 조성물을 제공하고자 한다.The present invention has a relatively high pearlescent pigment content, but secures fall safety without using talc, and applies an excessive amount of high-performance oil binder containing a polyol-oil emulsion complex that has not been applied to conventional compressed powder formulations. It is an object of the present invention to provide a high-performance cosmetic composition that can give a high gloss and high coloration cosmetic effect that can give users a more excellent and differentiated feeling of use.
상기 상술한 목적을 달성하기 위하여 본 발명은 폴리올-오일 유화물을 포함하는 유상부, 및 분체를 포함하는 색조 화장료 조성물을 제공한다.In order to achieve the above object, the present invention provides a color cosmetic composition comprising an oil phase part containing a polyol-oil emulsion and a powder.
본 발명의 일 구현예에 따르면, 상기 분체는 탈크를 포함하지 않는 것을 특징으로 한다. According to one embodiment of the present invention, the powder is characterized in that it does not contain talc.
본 발명의 일 구현예에 따르면, 상기 분체는 마이카, 합성운모, 세리사이트, 실리카, 이산화티탄, 실리콘계 파우더, 보론 파우더, 징크옥사이드, 나일론 파우더, 폴리메타크릴레이트 파우더, 우레탄 파우더, 아크릴레이트 (코)폴리머, 폴리에틸렌 (코)폴리머, 유기계 색소안료 및 무기계 색소 안료로 이루어진 군에서 선택된 어느 하나 이상을 포함한다.According to one embodiment of the present invention, the powder is mica, synthetic mica, sericite, silica, titanium dioxide, silicon-based powder, boron powder, zinc oxide, nylon powder, polymethacrylate powder, urethane powder, acrylate (co ) includes at least one selected from the group consisting of polymers, polyethylene (co)polymers, organic color pigments and inorganic color pigments.
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물은 나노에멀젼 또는 리포좀이다.According to one embodiment of the present invention, the polyol-oil emulsion is a nanoemulsion or a liposome.
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물에서의 폴리올은 글리세린, 다이글리세린, 에틸헥실글리세린, 폴리글리세린, 에틸렌글라이콜, 다이에틸렌글라이콜, 폴리에틸렌글라이콜, 프로필렌글라이콜, 다이프로필렌글라이콜, 폴리프로필렌글라이콜, 부틸렌글라이콜, 펜틸렌글라이콜, 헥실렌글라이콜, 카프릴릴글라이콜, 데실렌글라이콜, 프로판다이올, 펜탄다이올, 헥산다이올, D-판테놀 및 옥탄다이올로 이루어진 군에서 선택된 어느 하나 이상이다.According to one embodiment of the present invention, the polyol in the polyol-oil emulsion is glycerin, diglycerin, ethylhexyl glycerin, polyglycerin, ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol , dipropylene glycol, polypropylene glycol, butylene glycol, pentylene glycol, hexylene glycol, caprylyl glycol, decylene glycol, propanediol, pentanediol, hexane diol, at least one selected from the group consisting of D-panthenol and octanediol.
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물에서의 오일은 에스테르계 오일, 실리콘 오일 및 식물성 오일로 이루어진 군에서 선택된 어느 하나 이상이다.According to one embodiment of the present invention, the oil in the polyol-oil emulsion is any one or more selected from the group consisting of ester-based oils, silicone oils and vegetable oils.
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물은 물, 인지질, 계면활성제, 세라마이드 및 콜레스테롤로 이루어진 군으로부터 선택된 어느 하나 이상을 더 포함한다.According to one embodiment of the present invention, the polyol-oil emulsion further includes any one or more selected from the group consisting of water, phospholipids, surfactants, ceramides and cholesterol.
본 발명의 일 구현예에 따르면, 상기 유상부는 화장료 조성물 총 중량 대비 30 중량% 초과하여 포함된다.According to one embodiment of the present invention, the oil phase portion is included in more than 30% by weight based on the total weight of the cosmetic composition.
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물은 유상부 총 중량 대비 5 내지 70 중량% 포함된다.According to one embodiment of the present invention, the polyol-oil emulsion is included in an amount of 5 to 70% by weight based on the total weight of the oil phase.
본 발명의 일 구현예에 따르면, 상기 유상부 내에서의 폴리올-오일 유화물과 그 외의 성분의 비율(중량)은 1 : 0.1 내지 10 이다. According to one embodiment of the present invention, the ratio (weight) of the polyol-oil emulsion and other components in the oil phase is 1:0.1 to 10.
본 발명의 일 구현예에 따르면, 상기 유상부 내에서의 폴리올-오일 유화물 : 실리콘 오일 : 그 외 성분의 비율(중량)은 1 : 0.01 내지 10 : 0.1 내지 10이다.According to one embodiment of the present invention, the ratio (weight) of the polyol-oil emulsion: silicone oil: other components in the oil phase is 1: 0.01 to 10: 0.1 to 10.
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물은 화장료 조성물 총 중량 대비 0.1 내지 40 중량% 포함된다.According to one embodiment of the present invention, the polyol-oil emulsion is included in 0.1 to 40% by weight based on the total weight of the cosmetic composition.
본 발명의 일 구현예에 따르면, 상기 화장료 조성물은 투웨이케익, 팩트, 파우더 파운데이션, 아이섀도, 블러셔 및 하이라이터로 이루어진 군으로부터 선택되는 제형이다.According to one embodiment of the present invention, the cosmetic composition is a formulation selected from the group consisting of two-way cake, pact, powder foundation, eye shadow, blusher, and highlighter.
본 발명은 폴리올-오일 유화물을 통해 색조 화장료에 있어서 높은 함량의 오일 바인더를 포함하는 색조 화장료 조성물을 제공할 수 있고, 이를 통해 특히 탈크를 포함하지 않음에도 불구하고 낙하 안정도가 비교적 안정적으로 확보되어 낙하 시 파손의 우려가 적고 피부에 적용되어 보다 탁월한 발색과 광택, 차별화된 사용감, 끊김이 덜한 피부 도포성을 발휘하는 색조 화장료 조성물을 제공한다.The present invention can provide a color cosmetic composition containing a high content of an oil binder in a color cosmetic through a polyol-oil emulsion, and through this, despite not including talc, the drop stability is relatively stably secured and the drop Provided is a color cosmetic composition that is less likely to be damaged when applied to the skin and exhibits more excellent color development and gloss, a differentiated feeling of use, and less breakage on the skin.
또한, 본 발명은 겔상과 액상 오일 두 가지를 특정 비율로 혼합 적용하였으며 과량으로 적용하여도 압축 분말상을 유지할 수 있다. 고함량의 오일 적용에도 리본 믹서 공정 없이 헨셀 믹서 공정(기존 공정)으로 생산 가능하다. In addition, in the present invention, both gel and liquid oils are mixed and applied in a specific ratio, and the compressed powder form can be maintained even when applied in excess. Even when high oil content is applied, it can be produced by the Henschel mixer process (existing process) without the ribbon mixer process.
도 1은 본 발명의 실시예에 따른 색조 화장료의 외관 모습이다. 실시예 1 (와인) 및 실시예 2 (갈색) (용기에 부착 후 자연광 촬영)
도 2는 본 발명의 실시예 조성물들의 외관 모습이다.
도 3은 본 발명의 실시예 조성물에 대한 피부 광택 표현 사진이다. (와인색은 실시예 1, 갈색은 실시예 2, 하박 내측 도포)
도 4는 본 발명의 실시예 조성물에 대한 피부 발색 표현 사진이다. (눈꺼풀 도포)
도 5는 본 발명의 실시예 조성물과 비교예 조성물의 외관을 비교한 사진이다.1 is an external appearance of a color cosmetic according to an embodiment of the present invention. Example 1 (wine) and Example 2 (brown) (photographed in natural light after attaching to the container)
Figure 2 is an external appearance of the composition of the embodiment of the present invention.
3 is a photograph of skin gloss expression for the composition of an example of the present invention. (Wine color is Example 1, brown is Example 2, inner coating of hawthorn)
4 is a photograph of skin color expression for the composition of an example of the present invention. (Eyelid application)
Figure 5 is a photograph comparing the appearance of the composition of the embodiment of the present invention and the comparative example composition.
상기 상술한 목적을 달성하기 위한 본 발명은 폴리올-오일 유화물을 포함하는 유상부 및 분체를 포함하는 색조 화장료 조성물을 제공하는 것을 특징으로 한다. 이하 도면을 참조하여 본 발명을 구체적으로 설명한다.The present invention for achieving the above object is characterized by providing a color cosmetic composition comprising an oil phase and a powder containing a polyol-oil emulsion. The present invention will be described in detail with reference to the drawings below.
본 발명은 폴리올-오일 유화물을 포함하는 유상부 및 분체를 포함하는 색조 화장료 조성물이다. The present invention is a color cosmetic composition comprising an oil phase containing a polyol-oil emulsion and a powder.
본 발명의 일 구현예에 따르면, 상기 분체는 탈크를 포함하지 않는다. According to one embodiment of the present invention, the powder does not contain talc.
상기 "포함하지 않는"이란, "실질적으로 포함하지 않는"의 의미이며, 여기에서 "실질적으로"란, 전체 화장료 조성물의 총 중량의 10 중량% 이하까지는 포함할 수 있다는 것을 의미한다. 또한, 이는 상기 탈크가 일정 정도 이상의 광택을 나타내지 않는 정도의 함량으로 수준으로 포함되는 것을 의미할 수 있다. 예를 들면, 상기 "포함하지 않는" 또는 "실질적으로 포함하지 않는" 함량은 10 중량%, 8 중량%, 6 중량%, 4중량%, 2중량%, 1 중량%, 0.9 중량%, 0.8 중량%, 0.7 중량%, 0.6 중량%, 0.5 중량%, 0.1 중량%, 0.09 중량%, 0.08 중량%, 0.07 중량%, 0.06 중량%, 0.05 중량%, 0.01 중량% 이하일 수 있다. The "not including" means "not substantially including", and "substantially" here means that up to 10% by weight or less of the total weight of the total cosmetic composition may be included. In addition, this may mean that the talc is included at a level of an amount that does not exhibit a certain level or more of gloss. For example, the "free" or "substantially free" amount is 10%, 8%, 6%, 4%, 2%, 1%, 0.9%, 0.8% by weight. %, 0.7 wt%, 0.6 wt%, 0.5 wt%, 0.1 wt%, 0.09 wt%, 0.08 wt%, 0.07 wt%, 0.06 wt%, 0.05 wt%, 0.01 wt% or less.
본 명세서에서 다르게 언급되지 않는 한, 특정 물질의 농도를 나타내기 위하여 사용되는 “%”는, 고체/고체는 (중량/중량) %, 고체/액체는 (중량/부피) %, 그리고 액체/액체는 (부피/부피) %이다.Unless otherwise stated herein, "%" used to indicate the concentration of a particular substance is (weight/weight) % for solids/solids, (weight/volume) % for solids/liquids, and (weight/volume) % for liquids/liquids. is (volume/volume) %.
본 발명에 있어서의 "분체"는 화장료의 성분으로서 일반적으로 사용되는 것이며, 백색 및 착색 안료, 자외선 산란제 등의 미립자(소위 나노 입자를 포함함) 및 체질 안료를 포함한다. 백색 및 착색 안료는 화장료의 착색 등에 사용되는 반면에, 체질 안료는 화장료의 감촉 개량 등에 사용된다. 본 발명에 있어서의 "분체"로는 화장료에 통상 사용되는 백색 및 착색 안료, 및 체질 안료를 특별히 제한 없이 사용할 수 있다. 또한, 1 종류 또는 2 종류 이상의 분체를 배합하는 것일 수 있다.The "powder" in the present invention is generally used as a component of cosmetics, and includes fine particles (including so-called nanoparticles) and extender pigments such as white and colored pigments and ultraviolet scattering agents. White and colored pigments are used for coloring cosmetics, etc., whereas extender pigments are used for improving the feel of cosmetics. As the "powder" in the present invention, white and colored pigments commonly used in cosmetics and extender pigments can be used without particular limitation. Alternatively, one type or two or more types of powder may be blended.
분체로는 예를 들면, 무기 분체, 유기 분체, 메탈 소프, 유색 안료, 펄 안료, 금속 분말 안료 등을 들 수 있고, 게다가, 이것들을 복합화한 것도 사용할 수 있다. Examples of the powder include inorganic powder, organic powder, metal soap, colored pigment, pearl pigment, metal powder pigment, and the like, and a combination of these can also be used.
구체적으로는, 무기 분체로는 산화티탄, 산화지르코늄, 산화아연, 산화세륨, 산화마그네슘, 황산바륨, 황화칼슘, 황산마그네슘, 탄산칼슘, 탄산마그네슘, 마이카, 카올린, 세리사이트, 백운모, 합성 운모, 금운모, 홍운모, 흑운모, 리티아 운모, 규산, 무수 규산, 규산알루미늄, 규산나트륨, 규산나트륨마그네슘, 규산마그네슘, 규산알루미늄마그네슘, 규산칼슘, 규산바륨, 규산스트론튬, 텅스텐산 금속염, 하이드록시아파타이트, 버미큘라이트, 하이질라이트(HIGILITE), 벤토나이트, 몬모릴로나이트, 헥토라이트, 제올라이트, 세라믹스 파우더, 제2인산칼슘, 알루미나, 수산화알루미늄, 질화붕소, 질화보론 등이 있다. Specifically, inorganic powders include titanium oxide, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfide, magnesium sulfate, calcium carbonate, magnesium carbonate, mica, kaolin, sericite, muscovite mica, synthetic mica, Phlogopite, lite mite, biotite, lithian mica, silicic acid, anhydrous silicic acid, aluminum silicate, sodium silicate, magnesium sodium silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate, barium silicate, strontium silicate, metal tungstate, hydroxyapatite, Vermiculite, HIGILITE, bentonite, montmorillonite, hectorite, zeolite, ceramic powder, dibasic calcium phosphate, alumina, aluminum hydroxide, boron nitride, boron nitride, and the like.
유기분체로는 폴리아미드 파우더, 폴리에스테르 파우더, 폴리에틸렌 파우더, 폴리프로필렌 파우더, 폴리스티렌 파우더, 폴리우레탄 파우더, 벤조구아나민 파우더, 폴리메틸벤조구아나민 파우더, 폴리테트라플루오로에틸렌 파우더, 폴리메틸메타크릴레이트 파우더, 셀룰로오스, 실크 파우더, 나일론 파우더, 12 나일론, 6 나일론, 실리콘 파우더, 폴리메틸실세스퀴옥산 구상 분체, 스티렌·아크릴산 공중합체, 다이비닐벤젠·스티렌 공중합체, 비닐 수지, 요소 수지, 페놀 수지, 불소 수지, 규소 수지, 아크릴 수지, 멜라민 수지, 에폭시 수지, 폴리카보네이트 수지, 미결정 섬유 분체, 전분 분말, 라우로일라이신 등이 있다. Organic powders include polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane powder, benzoguanamine powder, polymethylbenzoguanamine powder, polytetrafluoroethylene powder, and polymethyl methacrylate. Powder, cellulose, silk powder, nylon powder, 12 nylon, 6 nylon, silicone powder, polymethylsilsesquioxane spherical powder, styrene/acrylic acid copolymer, divinylbenzene/styrene copolymer, vinyl resin, urea resin, phenol resin , fluorine resin, silicon resin, acrylic resin, melamine resin, epoxy resin, polycarbonate resin, microcrystalline fiber powder, starch powder, lauroyl lysine, and the like.
메탈 소프로는 스테아르산아연, 스테아르산알루미늄, 스테아르산칼슘, 스테아르산마그네슘, 미리스트산아연, 미리스트산마그네슘, 팔미트산아연, 라우르산아연, 세틸인산아연, 세틸인산칼슘, 세틸인산아연나트륨 등이 있다. Zinc Stearate, Aluminum Stearate, Calcium Stearate, Magnesium Stearate, Zinc Myristate, Magnesium Myristate, Zinc Palmitate, Zinc Laurate, Cetyl Phosphate, Cetyl Phosphate, Cetyl Phosphate zinc sodium, etc.
유색 안료로는 벵갈라, 산화철, 수산화철, 티탄산철의 무기 적색 안료, γ-산화철 등의 무기 갈색계 안료, 황산화철, 황토 등의 무기 황색계 안료, 흑산화철, 카본 블랙 등의 무기 흑색 안료, 망간 바이올렛, 코발트 바이올렛 등의 무기 자색 안료, 수산화크롬, 산화크롬, 산화코발트, 티탄산코발트 등의 무기 녹색 안료, 감청, 군청 등의 무기 청색계 안료, 적색 3호, 적색 104호, 적색 106호, 적색 201호, 적색 202호, 적색 204호, 적색 205호, 적색 220호, 적색 226호, 적색 227호, 적색 228호, 적색 230호, 적색 401호, 적색 505호, 황색 4호, 황색 5호, 황색 202호, 황색 203호, 황색 204호, 황색 401호, 청색 1호, 청색 2호, 청색 201호, 청색 404호, 녹색 3호, 녹색 201호, 녹색 204호, 녹색 205호, 오렌지색 201호, 오렌지색 203호, 오렌지색 204호, 오렌지색 206호, 오렌지색 207호 등의 타르계 색소를 레이크화한 것, 카민산, 락카산, 카르타민, 브라질린, 크로신 등의 천연 색소를 레이크화한 것 등이 있다.Colored pigments include inorganic red pigments such as bengala, iron oxide, iron hydroxide, and iron titanate, inorganic brown pigments such as γ-iron oxide, inorganic yellow pigments such as iron sulfate and ocher, inorganic black pigments such as black iron oxide and carbon black, manganese Inorganic purple pigments such as violet and cobalt violet, inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide, and cobalt titanate, inorganic blue pigments such as Prussian blue and ultramarine blue, Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227, Red No. 228, Red No. 230, Red No. 401, Red No. 505, Yellow No. 4, Yellow No. 5 , Yellow No. 202, Yellow No. 203, Yellow No. 204, Yellow No. 401, Blue No. 1, Blue No. 2, Blue No. 201, Blue No. 404, Green No. 3, Green No. 201, Green No. 204, Green No. 205, Orange Tar-based pigments such as No. 201, Orange No. 203, Orange No. 204, Orange No. 206, Orange No. 207, etc., and natural pigments such as carminic acid, lacric acid, cartamine, brasilin, crocin, etc. did and so on.
펄 안료로는 산화티탄 피복 운모, 운모 티탄, 산화철 처리 운모 티탄, 산화티탄 피복 운모, 옥시염화비스무트, 산화티탄 피복 옥시염화비스무트, 산화티탄 피복 탈크, 아르젠틴, 산화티탄 피복 착색 운모 등이 있다. Pearl pigments include titanium oxide-coated mica, mica titanium, iron oxide-treated titanium mica, titanium oxide-coated mica, bismuth oxychloride, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, argentine, and titanium oxide-coated colored mica.
금속 분말 안료로는 알루미늄, 금, 은, 구리, 백금, 스테인리스 등이 있다.Metal powder pigments include aluminum, gold, silver, copper, platinum, stainless steel and the like.
본 발명의 일 구현예에 따르면, 상기 분체는 마이카, 합성운모, 세리사이트, 실리카, 이산화티탄, 실리콘계 파우더, 보론 파우더, 징크옥사이드, 나일론 파우더, 폴리메타크릴레이트 파우더, 우레탄 파우더, 아크릴레이트 (코)폴리머, 폴리에틸렌 (코)폴리머, 유기계 색소안료 및 무기계 색소 안료로 이루어진 군에서 선택된 어느 하나 이상을 포함한다. According to one embodiment of the present invention, the powder is mica, synthetic mica, sericite, silica, titanium dioxide, silicon-based powder, boron powder, zinc oxide, nylon powder, polymethacrylate powder, urethane powder, acrylate (co ) includes at least one selected from the group consisting of polymers, polyethylene (co)polymers, organic color pigments and inorganic color pigments.
본 발명의 일 구현예에 따르면, 상기 실리카는 천연 오일 및 실리콘 오일 중 어느 하나 이상과 복합체를 형성한다. According to one embodiment of the present invention, the silica forms a complex with at least one of natural oil and silicone oil.
구체적으로, 상기 식물성 오일은 올리브유, 마카다미아씨 오일, 썬플라워 오일, 야자유 및 팜유로 선택된 어느 하나 이상을 포함한다. 실리콘 오일은 다이메티콘(dimethicone), 페닐트리메티콘(phenyl trimethicone), 다이메티콘/트 리메칠실록시실리케이트(dimethicone/trimethylsiloxysilicate), 다이페닐다이메티콘(diphenyl dimethicone) 및 트리페닐 메티콘(triphenyl methicone)로 이루어진 군에서 선택된 어느 하나 이상을 포함한다.Specifically, the vegetable oil includes at least one selected from olive oil, macadamia seed oil, sunflower oil, palm oil, and palm oil. Silicone oils include dimethicone, phenyl trimethicone, dimethicone/trimethylsiloxysilicate, diphenyl dimethicone and triphenyl methicone ( triphenyl methicone) and at least one selected from the group consisting of
본 발명은 미세결정 셀룰로오스(Microcrystalline cellulose)가 일부 포함된 특정 마이카(Mica)류를 5% 이상 함유하는 것을 주된 특징으로 하며 이 밖에 금속염(Metal soap)류, 실리카(Silica)류 이렇게 3가지 종류의 원료만으로 체질 원료(Bulking agent)를 구성할 수 있다.The main feature of the present invention is that it contains 5% or more of specific mica, which partially includes microcrystalline cellulose, and in addition, three types of metal soap and silica It is possible to constitute a bulking agent only with raw materials.
본 발명의 일 구현예에 따르면, 본 발명의 분체 중 메탈소프를 제외한 마이카(Mica)류, 실리카(Silica)류 등의 모든 기재는 코팅된 기재로 적용할 수 있으며, 그 중 마이카(Mica)류는 비교적 큰 입경(평균 사이즈 30 내지 40㎛ 정도)을 가진 코팅된 마이카(Mica)류를 사용할 수 있다.According to one embodiment of the present invention, all substrates such as mica, silica, etc., excluding metal soap, among the powders of the present invention can be applied as coated substrates, and among them, mica may use coated mica having a relatively large particle diameter (average size of about 30 to 40 μm).
본 발명의 일 구현예에 따르면, 상기 마이카류 및 실리카류는 1: 0.1 내지 10의 비율로 구성을 하여 체질 원료(Bulking agent)를 구성할 수 있다. 구체적으로 상기 마이카류 및 실리카류는 1 : 0.5 내지 5, 더 구체적으로 1 : 0.8 내지 1.2의 비율로 포함한다.According to one embodiment of the present invention, the mica and silica may be constituted in a ratio of 1: 0.1 to 10 to constitute a bulking agent. Specifically, the mica and silica are included in a ratio of 1: 0.5 to 5, more specifically 1: 0.8 to 1.2.
본 발명에 있어서, 종래의 진주 광택 안료(Pearlescent pigment)를 함유하는 압축 분말상 형태의 화장료 조성물은 진주 광택 안료(Pearlescent pigment)의 함량이 다소 높아 미세 플라스틱(Microplastics)류를 사용하여 성형성 저하 및 낙하 안정성 저하 현상을 보완하고자 하였으나, 본 발명은 미세 결정 셀룰로오스(Microcrystalline cellulose)가 포함된 특정 마이카(Mica)류와 메탈 솝(Metal soap) 형태의 파우더 바인더(Magnesium stearate, Magnesium myristate)만을 사용하여 이를 보완하였다.In the present invention, the cosmetic composition in the form of a compacted powder containing a conventional pearlescent pigment has a rather high content of pearlescent pigment, so that the formability is reduced and the drop is reduced by using microplastics. It was intended to compensate for the deterioration in stability, but the present invention uses only specific mica containing microcrystalline cellulose and a metal soap-type powder binder (Magnesium stearate, Magnesium myristate) to compensate for this did
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물은 나노에멀젼 또는 리포좀이다.According to one embodiment of the present invention, the polyol-oil emulsion is a nanoemulsion or a liposome.
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물에서의 폴리올은 글리세린(glycerin), 다이글리세린(diglycerin), 에틸헥실글리세린(ethylhexylgeycerin), 폴리글리세린(polyglycerin), 에틸렌글라이콜(ethyleneglycol), 다이에틸렌글라이콜(diethyleneglycol), 폴리에틸렌글라이콜(polyethyleneglycol), 프로필렌글라이콜(propyleneglycol), 다이프로필렌글라이콜(dipropyleneglycol), 폴리프로필렌글라이콜(polypropyleneglycol), 부틸렌글라이콜(butyleneglycol), 펜틸렌글라이콜(prntyleneglycol), 헥실렌글라이콜(hexyleneglycol), 카프릴릴글라이콜(caprylylglycol), 데실렌글라이콜(Decylene glycol), 프로판다이올(propandiol), 펜탄다이올(pentanediol), 헥산다이올(hexanediol), D-판테놀(D-pantenol) 및 옥탄다이올(octandiol)로 이루어진 군에서 선택된 어느 하나 이상이다.According to one embodiment of the present invention, the polyol in the polyol-oil emulsion is glycerin, diglycerin, ethylhexylglycerin, polyglycerin, ethylene glycol, Diethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, butylene glycol , pentylene glycol, hexylene glycol, caprylyl glycol, decylene glycol, propandiol, pentanediol , At least one selected from the group consisting of hexanediol, D-panthenol, and octanediol.
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물에서의 오일은 에스테르계 오일, 실리콘 오일 및 식물성 오일로 이루어진 군에서 선택된 어느 하나 이상이다.According to one embodiment of the present invention, the oil in the polyol-oil emulsion is any one or more selected from the group consisting of ester-based oils, silicone oils and vegetable oils.
상기 에스테르계 오일은 일례로 C12∼C15 알킬 옥타노에이트(octanoate), 미리스틸 락테이트(myristyl lactate), 세틸 옥타노에이트(cetyl octanoate), 이소프로필 미리스테이트(isopropyl myristate), 옥틸도데실 미리스테이트(octyldodecyl myristate), 헥실 라우레이트(hexyl laurate), 다이(C12-C13) 알킬 말레이트(di(C12-C13) alkyl malate), 미리스틸 락테이트(myristyl lactate), 옥틸도데실 스테아로일 스테아레이트(octyldodecyl stearoyl stearate), 다이이소테아릴 말레이트(diisostearyl malate), 펜타에리스틸 테트라에틸헥사노에이트(pentaerythrityl tetraisostearate) 및 다이글리세릴 트리이소테아레이트(diglyceryl triisostearate)로 이루어진 군에서 선택될 수 있다. 더욱 구체적으로 다이(C12-C13) 알킬 말레이트(di(C12-C13) alkyl malate), 미리스틸 락테이트(myristyl lactate), 옥틸도데실 스테아로일 스테아레이트(octyldodecyl stearoyl stearate), 다이이소테아릴 말레이트(diisosteayl malate), 펜타에리스틸 테트라에틸헥사노에이트(pentaerythrityl tetraisostearate) 및 다이글리세릴 트리이소테아레이트(diglyceryl triisostearate)로 이루어진 군에서 선택될 수 있다.The ester oil is, for example, C 12 ~ C 15 alkyl octanoate (octanoate), myristyl lactate (myristyl lactate), cetyl octanoate (cetyl octanoate), isopropyl myristate (isopropyl myristate), octyldodecyl Myristate (octyldodecyl myristate), hexyl laurate (hexyl laurate), di (C 12 -C 13 ) alkyl malate (di (C 12 -C 13 ) alkyl malate), myristyl lactate (myristyl lactate), octyldodecyl The group consisting of octyldodecyl stearoyl stearate, diisostearyl malate, pentaerythrityl tetraisostearate and diglyceryl triisostearate can be selected from More specifically, di (C 12 -C 13 ) alkyl malate (di (C 12 -C 13 ) alkyl malate), myristyl lactate (myristyl lactate), octyldodecyl stearoyl stearate (octyldodecyl stearoyl stearate), It may be selected from the group consisting of diisosteayl malate, pentaerythrityl tetraisostearate and diglyceryl triisostearate.
상기 실리콘 오일은 일례로 다이메티콘(dimethicone), 페닐트리메티콘(phenyl trimethicone), 다이메티콘/트 리메칠실록시실리케이트(dimethicone/trimethylsiloxysilicate), 다이페닐다이메티콘(diphenyl dimethicone) 및 트리페닐 메티콘(triphenyl methicone)으로 이루어진 군에서 선택될 수 있다.The silicone oil is, for example, dimethicone, phenyl trimethicone, dimethicone / trimethylsiloxysilicate, diphenyl dimethicone and triphenyl It may be selected from the group consisting of methicone (triphenyl methicone).
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물은 물, 계면활성제, 인지질, 세라마이드 및 콜레스테롤로 이루어진 군으로부터 선택된 어느 하나 이상을 더 포함할 수 있다.According to one embodiment of the present invention, the polyol-oil emulsion may further include any one or more selected from the group consisting of water, surfactant, phospholipid, ceramide and cholesterol.
상기 계면활성제는 비이온성, 음이온성, 양이온성 및 양쪽성 계면활성제, 및 이들 중 어느 하나 이상의 혼합물로부터 선택될 수 있다. 계면활성제의 유화 특성 및 기능의 정의에 대하여 [Kirk-Othmer's EncyclopediaofChemicalTechnology, Volume 22, pp. 333-432, 3rd Edition, 1979, Wiley]를 참조할 수 있고, 특히 음이온성, 양쪽성 및 비이온성 계면활성제에 대하여 상기 문헌의 pp. 347-377 를 참조할 수 있다.The surfactant may be selected from nonionic, anionic, cationic and amphoteric surfactants, and mixtures of any one or more of them. On the definition of emulsifying properties and functions of surfactants [Kirk-Othmer's Encyclopedia of Chemical Technology, Volume 22, pp. 333-432, 3rd Edition, 1979, Wiley, especially for anionic, amphoteric and nonionic surfactants, see pp. 347-377.
상기 비이온성 계면활성제는, 일례로, 당류 에스테르 및 에테르, 예컨대 수크로오스 스테아레이트, 수크로오스 코코에이트, 소르비탄 스테아레이트, 소르비탄 모노이소스테아레이트, 소르비탄 트리스테아레이트, 소르비탄 올레에이트, 소르비탄 세스퀴올레에이트, 메틸글루코오스 이소스테아레이트, 수크로오스 (폴리)팔미토스테아레이트, 수크로오스 라우레이트, 수크로오스 팔미테이트, 수크로오스 트리베헤네이트, 수크로오스 올레에이트, 수크로오스 다이스테아레이트, 수크로오스 폴리라우레이트, 수크로오스 라우레이트 및 수크로오스 헥사에루케이트, 및 이의 혼합물; 특히 C8-C24 및 바람직하게는 C16-C22 의 지방산 및 특히 글리세롤 또는 소르비톨의 폴리올의 에스테르, 예컨대 글리세릴 스테아레이트의 에스테르, 폴리글리세릴 다이이소스테아레이트, 폴리글리세릴 이소스테아레이트, 폴리글리세릴 모노스테아레이트, 다이글리세릴 테트라이소스테아레이트, 폴리에틸렌 글라이콜 다이이소스테아레이트, 폴리글리세릴-10 펜타스테아레이트, 글리세릴 모노올레에이트, 글리세릴 라우레이트, 다이에틸렌 글라이콜 (다이)라우레이트, 데카글리세릴 펜타올레에이트, 데카글리세릴 펜타다이이소스테아레이트, 글리세릴 카프레이트/카프릴레이트, 폴리글리세릴-2 (이소)스테아레이트 및 (폴리)리시놀레에이트; 옥시알킬렌화 알코올, 특히 1 내지 15 개의 옥시에틸렌 및/또는 옥시프로필렌 단위를 포함할 수 있는 옥시에틸렌화 및/또는 옥시프로필렌화 알코올, 특히 에톡실화 C8-C24 및 바람직하게는 C12-C18 지방 알코올, 예컨대 2 개의 옥시에틸렌 단위로 에톡실화된 스테아릴 알코올, 또는 옥시에틸렌화 올레일 알코올; 지방 알코올, 예컨대 세틸스테아릴 알코올, 예를 들어 3 내지 20 개의 옥시알킬렌 단위 및 특히 옥시에틸렌화 및/또는 옥시프로필렌화 다이메티콘을 함유하는 옥시에틸렌화 및/또는 옥시프로필렌화 실리콘 화합물; 시클로메티콘/다이메티콘 코폴리올의 혼합물이 있다.The nonionic surfactant is, for example, sugar esters and ethers such as sucrose stearate, sucrose cocoate, sorbitan stearate, sorbitan monoisostearate, sorbitan tristearate, sorbitan oleate, sorbitan cess quioleate, methylglucose isostearate, sucrose (poly) palmitostearate, sucrose laurate, sucrose palmitate, sucrose tribehenate, sucrose oleate, sucrose distearate, sucrose polylaurate, sucrose laurate and sucrose hexaerucate, and mixtures thereof; especially esters of C 8 -C 24 and preferably C 16 -C 22 fatty acids and in particular polyols of glycerol or sorbitol, such as esters of glyceryl stearates, polyglyceryl disostearates, polyglyceryl isostearates, Polyglyceryl Monostearate, Diglyceryl Tetraisostearate, Polyethylene Glycol Diisostearate, Polyglyceryl-10 Pentastearate, Glyceryl Monooleate, Glyceryl Laurate, Diethylene Glycol ( di)laurate, decaglyceryl pentaoleate, decaglyceryl pentadiisostearate, glyceryl caprate/caprylate, polyglyceryl-2 (iso)stearate and (poly)ricinoleate; oxyalkylenated alcohols, in particular oxyethylenated and/or oxypropylenated alcohols which may contain 1 to 15 oxyethylene and/or oxypropylene units, in particular ethoxylated C 8 -C 24 and preferably C 12 -C 18 fatty alcohols such as stearyl alcohol ethoxylated with two oxyethylene units, or oxyethylenated oleyl alcohol; fatty alcohols such as cetylstearyl alcohol, for example oxyethylenated and/or oxypropylenated silicone compounds containing 3 to 20 oxyalkylene units and in particular oxyethylenated and/or oxypropylenated dimethicone; There are mixtures of cyclomethicone/dimethicone copolyols.
음이온성 계면활성제로는, 일례로, C16-C30 지방산의 염, 특히 아민 염, 예컨대 트리에탄올아민 스테아레이트 또는 2-아미노-2-메틸프로판-1,3-다이올 스테아레이트; 폴리옥시에틸렌화 지방산 염, 특히 아민화 염 또는 알칼리 금속의 염, 및 이의 혼합물; 인산 에스테르 및 이의 염; 술포숙시네이트, 예컨대 2나트륨 PEG-5 시트레이트 라우릴 술포숙시네이트 및 2나트륨 리시놀레아미도 MEA 술포숙시네이트; 알킬 에테르 술페이트, 예컨대 나트륨 라우릴 에테르 술페이트; 이세티오네이트; 아실글루타메이트, 예컨대 2나트륨 수소화 탈로우 글루타메이트, 및 이의 혼합물이 있다. Anionic surfactants include, for example, salts of C 16 -C 30 fatty acids, especially amine salts such as triethanolamine stearate or 2-amino-2-methylpropane-1,3-diol stearate; polyoxyethylenated fatty acid salts, especially aminated salts or salts of alkali metals, and mixtures thereof; phosphoric acid esters and salts thereof; sulfosuccinates such as disodium PEG-5 citrate lauryl sulfosuccinate and disodium ricinoleamido MEA sulfosuccinate; alkyl ether sulfates such as sodium lauryl ether sulfate; isethionate; acylglutamates, such as disodium hydrogenated tallow glutamate, and mixtures thereof.
양이온성 계면활성제로는, 알킬이미다졸리디늄, 예컨대 이소스테아릴에틸이미도늄 에토술페이트, 암모늄 염, 예컨대 (C12-30 알킬)트리(C1-4 알킬)암모늄 할라이드, 예를 들어 N,N,N-트리메틸-1-도코사나미늄 클로라이드 (또는 베헨트리모늄 클로라이드)가 있다.Cationic surfactants include alkylimidazolidiniums such as isostearylethylimidonium ethosulfate, ammonium salts such as (C 12-30 alkyl )tri(C 1-4 alkyl)ammonium halides such as N ,N,N-trimethyl-1-docosanaminium chloride (or behentrimonium chloride).
양쪽성 계면활성제로는 예를 들어 N-아실아미노산, 예컨대 N-알킬 아미노아세테이트 및 2나트륨 코코암포다이아세테이트, 및 아민 옥시드, 예컨대 스테아르아민 옥시드, 또는 대안적으로 실리콘 계면활성제, 예를 들어 다이메티콘 코폴리올 포스페이트가 있다. Amphoteric surfactants include, for example, N-acylamino acids such as N-alkyl aminoacetates and disodium cocoamphodiacetate, and amine oxides such as stearamine oxide, or alternatively silicone surfactants, such as Dimethicone copolyol phosphate.
더 구체적으로는 폴리글리세릴 계면활성제이고, 보다 더 구체적으로는 폴리글리세릴 계면활성제는 폴리글리세릴-10 올리에이트, 폴리글리세릴-2 라우레이트, 폴리글리세릴-10 스테아레이트, 폴리글리세릴-10 다이스테아레이트, 폴리글리세릴-4 카프레이트, 폴리글리세릴-6 라우레이트, 폴리글리세릴-10 라우레이트, 폴리글리세릴-2 올리에이트, 폴리글리세릴-10 카프레이트 및 폴리글리세릴-10 카프릴레이트/카프레이트로 이루어진 군에서 선택된 어느 하나 이상일 수 있다. More specifically, it is a polyglyceryl surfactant, and more specifically, the polyglyceryl surfactant is polyglyceryl-10 oleate, polyglyceryl-2 laurate, polyglyceryl-10 stearate, polyglyceryl- 10 Distearate, Polyglyceryl-4 Caprate, Polyglyceryl-6 Laurate, Polyglyceryl-10 Laurate, Polyglyceryl-2 Oleate, Polyglyceryl-10 Caprate and Polyglyceryl-10 It may be at least one selected from the group consisting of caprylate/caprate.
본 발명에서 사용되는 인지질은 당업계에 알려진 통상적인 성분을 제한 없이 사용할 수 있으며, 일례로 하이드로제네이티드 레시틴, 하이드로제네이티드 포스파티딜콜린, 포스포리피드, 하이드로제네이티드 라이소포스파티딜콜린, 하이드로제네이티드 라이소레시틴, 하이드로옥실레이티드 레시틴, 불포화레시틴 또는 이들의 1종 이상 혼합물 등이 있다.As the phospholipid used in the present invention, conventional ingredients known in the art may be used without limitation, and examples thereof include hydrogenated lecithin, hydrogenated phosphatidylcholine, phospholipid, hydrogenated lysophosphatidylcholine, and hydrogenated lysolecithin. , hydroxylated lecithin, unsaturated lecithin, or a mixture of one or more thereof.
본 발명에서 사용되는 세라마이드, 콜레스테롤은 당업계에 알려진 통상적인 물질들을 제한 없이 사용할 수 있다.As the ceramide and cholesterol used in the present invention, conventional materials known in the art may be used without limitation.
본 발명의 폴리올-오일 유화물은 폴리올 복합체라는 용어로도 표현될 수 있다. The polyol-oil emulsion of the present invention can also be expressed in terms of a polyol complex.
따라서, 폴리올 복합체에 사용된 폴리올의 구체적인 종류에 따라 글리세린(glycerin) 복합체, 다이글리세린(diglycerin) 복합체, 에틸헥실글리세린(ethylhexylgeycerin) 복합체, 폴리글리세린(polyglycerin) 복합체, 에틸렌글라이콜(ethyleneglycol) 복합체, 다이에틸렌글라이콜(diethyleneglycol) 복합체, 폴리에틸렌글라이콜(polyethyleneglycol) 복합체, 프로필렌글라이콜(propyleneglycol) 복합체, 다이프로필렌글라이콜(dipropyleneglycol), 폴리프로필렌글라이콜(polypropyleneglycol) 복합체, 부틸렌글라이콜(butyleneglycol) 복합체, 펜틸렌글라이콜(prntyleneglycol) 복합체, 헥실렌글라이콜(hexyleneglycol) 복합체, 카프릴릴글라이콜(caprylylglycol) 복합체, 데실렌글라이콜(Decylene glycol) 복합체, 프로판다이올(propandiol) 복합체, 펜탄다이올(pentanediol) 복합체, 헥산다이올(hexanediol) 복합체, D-판테놀(D-pantenol) 복합체, 옥탄다이올(octandiol) 복합체 등으로 명칭될 수 있다.Therefore, depending on the specific type of polyol used in the polyol complex, a glycerin complex, a diglycerin complex, an ethylhexylgeycerin complex, a polyglycerin complex, an ethylene glycol complex, Diethylene glycol complex, polyethylene glycol complex, propylene glycol complex, dipropylene glycol, polypropylene glycol complex, butylene glycol butylene glycol complex, pentylene glycol complex, hexylene glycol complex, caprylyl glycol complex, decylene glycol complex, propanediol ( propandiol complex, pentanediol complex, hexanediol complex, D-panthenol complex, octanediol complex, and the like.
본 발명의 일 구현예에 따르면, 상기 유상부는 화장료 조성물 총 중량 대비 30 중량% 초과하여 포함된다. 구체적으로 35 중량% 초과, 더 구체적으로 37 중량% 초과할 수 있다. 이는 종래의 진주 광택 안료를 함유하는 압축 분말상 화장료 조성물이 보통 10%~30% 정도 범위의 오일 바인더를 사용한 것과 비교하여 높은 유상부의 함량에도 불구하고 차별화된 사용감 및 안정적이고 적절한 제형을 제공한다는 점에서 기술적 차별성을 갖는다.According to one embodiment of the present invention, the oil phase portion is included in more than 30% by weight based on the total weight of the cosmetic composition. specifically greater than 35% by weight, more specifically greater than 37% by weight. This is in that it provides a differentiated feeling of use and a stable and appropriate formulation despite the high oil content compared to conventional compressed powder cosmetic compositions containing pearlescent pigments using oil binders in the range of 10% to 30%. It has a technical difference.
따라서, 본 발명은 종래의 오일 바인더의 구성과는 상이하게 에스터(Ester)계 오일, 실리콘(Silicone)계 오일만을 오일 바인더로 국한하지 않고 폴리올-오일 유화물도 오일 바인더로 확장 구성함에 따라 다양한 종류와 성상을 가진 원료들을 특정 함량 및 비율로 혼합 구성하여 오일 바인더를 구성하였다는 특징을 가진다.Therefore, unlike the configuration of conventional oil binders, the present invention is not limited to only ester-based oils and silicone-based oils as oil binders, and polyol-oil emulsions are also expanded into oil binders, so that various types and It is characterized in that the oil binder is formed by mixing raw materials with properties in a specific content and ratio.
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물은 겔(gel) 또는 페이스트(paste) 형태를 갖는다.According to one embodiment of the present invention, the polyol-oil emulsion has a gel or paste form.
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물은 상기 폴리올을 유화물 총 중량 대비 30 내지 80 중량% 포함할 수 있고, 구체적으로 40 내지 70 중량%, 더 구체적으로 50 내지 65 중량% 포함할 수 있다. 또한, 상기 오일을 상기 유화물 총 중량 대비 20 내지 70 중량% 포함할 수 있고, 구체적으로 30 내지 60 중량%, 더 구체적으로 35 내지 50 중량% 포함할 수 있다. 상기 함량으로 포함하는 경우 본원 발명이 목적하는 우수한 사용감 및 성형성과 안정도를 제공하는 데 바람직하다.According to one embodiment of the present invention, the polyol-oil emulsion may contain 30 to 80% by weight of the polyol based on the total weight of the emulsion, specifically 40 to 70% by weight, and more specifically 50 to 65% by weight. can In addition, the oil may include 20 to 70% by weight based on the total weight of the emulsion, specifically 30 to 60% by weight, and more specifically 35 to 50% by weight. When included in the above content, it is preferable to provide excellent usability, moldability and stability for which the present invention is intended.
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물은 유상부 총 중량 대비 5 내지 70 중량%, 구체적으로 20 내지 60 중량%, 더 구체적으로 20 내지 50 중량%, 더 구체적으로 30 내지 50 중량% 포함된다. 상기 함량으로 포함하는 경우 본원발명에서 목적하는 고함량의 오일 바인더를 포함하면서 우수한 사용감 및 성형성과 안정도를 갖는 화장료 조성물을 제공할 수 있다.According to one embodiment of the present invention, the polyol-oil emulsion is 5 to 70% by weight, specifically 20 to 60% by weight, more specifically 20 to 50% by weight, more specifically 30 to 50% by weight based on the total weight of the oil phase included When included in the above content, it is possible to provide a cosmetic composition having excellent usability, moldability and stability while including the high content of the oil binder desired in the present invention.
본 발명의 일 구현예에 따르면, 상기 유상부 내에서의 폴리올-오일 유화물과 그 외의 성분의 중량 비율은 1 : 0.1 내지 10, 구체적으로 1 : 0.5 내지 3, 더 구체적으로 1 : 0.5 내지 2, 더 구체적으로 1 : 0.9 내지 1.5이다. 상기 범위 보다 폴리올-오일 유화물의 비율이 지나치게 높으면 본원발명이 목적하는 우수한 사용감을 제공하기 어렵고 딱딱한 느낌을 줄 수 있고, 상기 범위 보다 폴리올-오일 유화물의 비율이 지나치게 낮으면 자칫 성형성 및 안정도가 떨어질 수 있다. According to one embodiment of the present invention, the weight ratio of the polyol-oil emulsion and other components in the oil phase is 1: 0.1 to 10, specifically 1: 0.5 to 3, more specifically 1: 0.5 to 2, and more Specifically, it is 1:0.9 to 1.5. If the ratio of the polyol-oil emulsion is too high than the above range, it is difficult to provide the excellent feeling of use desired by the present invention and may give a hard feeling, and if the ratio of the polyol-oil emulsion is too low than the above range, moldability and stability may be deteriorated. can
본 발명의 상기 유상부는 일례로 조금 더 구체적으로, 폴리올-오일 유화물 : 실리콘 오일(다이메티콘) : 그 외의 성분으로 나눌 수 있으며, 이 경우 상기 세 성분의 구성비(중량비)는 일례로 1 : 0.01 내지 10 : 0.1 내지 10일 수 있고, 구체적으로 1: 0.1 내지 5 : 0.5 내지 5, 더 구체적으로 1: 0.1 내지 3 : 0.5 내지 3, 더 구체적으로 1 : 0.1 내지 1.5 : 0.5 내지 1.5 이다. 상기 범위 내로 존재하는 경우, 폴리올-오일 유화물이 제공하는 우수한 사용감 및 성형성을 최대화하면서 실리콘 오일이 제공하는 매끄러운 사용감을 제공하는 데 바람직하다. The oil phase part of the present invention can be divided into, for example, a little more specifically, polyol-oil emulsion: silicone oil (dimethicone): other components, in this case, the composition ratio (weight ratio) of the three components is, for example, 1: 0.01 to 10: 0.1 to 10, specifically 1: 0.1 to 5: 0.5 to 5, more specifically 1: 0.1 to 3: 0.5 to 3, more specifically 1: 0.1 to 1.5: 0.5 to 1.5. When present within the above range, it is preferable to provide a smooth feeling of use provided by the silicone oil while maximizing the excellent feeling of use and moldability provided by the polyol-oil emulsion.
본 발명의 일 구현예에 따르면, 상기 폴리올-오일 유화물은 화장료 조성물 총 중량 대비 0.1 내지 40 중량%, 구체적으로 5 내지 30 중량%, 더 구체적으로 7 내지 20 중량%, 더 구체적으로 10 내지 20 중량%, 더 구체적으로 12 내지 18 중량% 포함된다. 상기 범위 보다 폴리올-오일 유화물의 함량이 높으면 본원발명이 목적하는 우수한 사용감을 제공하기 어려울 수 있고, 상기 범위 보다 폴리올-오일 유화물의 함량이 낮으면 자칫 성형성 및 안정도가 떨어질 수 있다.According to one embodiment of the present invention, the polyol-oil emulsion is 0.1 to 40% by weight, specifically 5 to 30% by weight, more specifically 7 to 20% by weight, more specifically 10 to 20% by weight based on the total weight of the cosmetic composition %, more specifically 12 to 18% by weight. If the content of the polyol-oil emulsion is higher than the above range, it may be difficult to provide the excellent feeling of use desired by the present invention, and if the content of the polyol-oil emulsion is lower than the above range, moldability and stability may deteriorate.
본 발명에서 사용되는 오일 바인더는 세부적으로, i) 가열이 불필요한 겔(gel) 또는 페이스트(paste) 형태의 폴리올-오일 유화물과 ii) 가열이 필요한 액상 형태의 혼합 구성 오일 바인더로 구분할 수 있고, 더 구체적으로는 i) 폴리올-오일 유화물, ii) 다이메티콘 및 iii) 그 외의 오일 바인더로 구분할 수 있으며 공정에 투입되는 순서는 가열을 포함하지 않는 오일 바인더를 선 투입한 후에 가열이 필요한 오일 바인더를 분산 투입하는 순서로 진행된다.The oil binder used in the present invention can be divided into i) a polyol-oil emulsion in the form of a gel or paste that does not require heating and ii) a mixed oil binder in the form of a liquid that requires heating, and further Specifically, it can be divided into i) polyol-oil emulsion, ii) dimethicone, and iii) other oil binders. It proceeds in the order of distributed input.
본 발명은 폴리올-오일 유화물을 포함하는 혼합 오일 원료 구성의 고함량의 오일 바인더 적용을 통해 종래의 진주 광택 안료를 함유하는 압축 분말상 형태의 화장료 조성물보다 비교적 높은 발색과 광택, 매끄러운 도포 가능성을 도출하고자 하였고 높은 낙하 안전성까지 확보한 화장료 조성물을 제공한다. The present invention is to derive relatively higher color development, gloss, and smooth application than conventional cosmetic compositions in the form of compressed powder containing pearl luster pigments through the application of a high content oil binder of a mixed oil raw material composition containing a polyol-oil emulsion. and provides a cosmetic composition that secures high fall safety.
본 발명은 특정 형태 및 사용감, 제형의 안정도를 유지할 수 있는 범위 내에서 임의의 추가 원료 성분 및 이의 양을 선택할 수 있다.In the present invention, any additional raw material component and its amount may be selected within a range capable of maintaining a specific shape, feeling of use, and stability of the formulation.
본 발명의 일 구현예에 따르면, 상기 화장료 조성물은 투웨이케익, 팩트, 파우더 파운데이션, 아이섀도, 블러셔 및 하이라이터로 이루어진 군으로부터 선택되는 제형이다.According to one embodiment of the present invention, the cosmetic composition is a formulation selected from the group consisting of two-way cake, pact, powder foundation, eye shadow, blusher, and highlighter.
이하, 실시예를 통해서 본 발명을 보다 상세히 설명하기로 한다. 하지만, 이들은 본 발명을 보다 상세하게 설명하기 위한 것일 뿐 본 발명의 권리 범위가 이에 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail through examples. However, these are only for explaining the present invention in more detail and the scope of the present invention is not limited thereto.
[제조예 1] 화장료 조성물의 제조[Preparation Example 1] Preparation of cosmetic composition
하기 표 1에 나타낸 성분 원료 1 및 원료 2를 이용하여 압축 분말상의 아이섀도우를 제조하였다. 원료 1의 파우더 조성물은 마이카류, 실리카류, 금속염류, 색소류, 진주 광택 안료로 이루어져 있으며, 상기 파우더의 오일 바인더 및 방부제인 원료 2에서 오일 바인더는 다양한 오일류의 혼합 조성물로 구성되어 있다.An eye shadow in the form of a compressed powder was prepared using the ingredients raw material 1 and raw material 2 shown in Table 1 below. The powder composition of raw material 1 is composed of mica, silica, metal salts, pigments, and pearlescent pigments, and the oil binder of raw material 2, which is the oil binder and preservative of the powder, is composed of a mixed composition of various oils.
본원발명의 원료 2에 포함되는 폴리올-오일 유화물의 구체적인 조성은 다음과 같다. The specific composition of the polyol-oil emulsion included in the raw material 2 of the present invention is as follows.
상기 폴리올-오일 유화물은 폴리올로 부틸렌글라이콜 또는 글리세린을 사용하고, 다이메티콘을 30 중량% 사용하여 구성하였고, 정제수를 포함하는 경우 그의 함량을 10 중량%로 하고 유화제 등의 성분은 적절히 구성하였다. 상기 유화물은 다이메티콘을 고함량으로 포함하고 있어 사용감 및 보습 효과가 우수하다. 상기 유화물을 포함하여 화장료 조성물을 제조하였다. 구체적인 조성물의 성분은 다음 표와 같다.The polyol-oil emulsion was composed of using butylene glycol or glycerin as a polyol and using 30% by weight of dimethicone. did The emulsion contains a high content of dimethicone, so it has excellent feeling of use and moisturizing effect. A cosmetic composition was prepared including the emulsion. Components of the specific composition are shown in the following table.
호th
like
(와인)Example 1
(wine)
(갈색)Example 2
(brown)
(갈색)Example 3
(brown)
(갈색)Example 4
(brown)
(갈색)Example 5
(brown)
료
1one
fee
One
상기 성분들의 함량 조성에 따라, 파우더상인 원료 1의 성분 1-17를 헨셀 믹서에 투입한 후 저속(400~700 rpm) 및 고속(700~1500 rpm)으로 혼합하였다. 그 다음, 원료 2의 성분 18과 19-22, 28을 고르게 먼저 투입한 후에 원료 2의 성분 23-27를 65℃ 이상으로 가온하여 균일 혼합물을 형성하고 이를 상기 혼합물에 미세 분사 후 1200rpm으로 1분 동안 2회 혼합하고 분쇄 처리하였다. 본 처리 후에는 내용물을 알루미늄 팬에 충진하여 약 10 kgf/cm2의 압력으로 2.00 sec 동안 압축 성형하였다.Depending on the composition of the contents of the components, the powdery ingredients 1-17 of Raw Material 1 were put into a Henschel mixer and mixed at low speed (400-700 rpm) and high speed (700-1500 rpm). Then, components 18, 19-22, and 28 of raw material 2 are evenly introduced first, and then components 23-27 of raw material 2 are heated to 65 ° C or higher to form a homogeneous mixture, which is finely sprayed on the mixture and then sprayed at 1200 rpm for 1 minute During the mixing and grinding process twice. After this treatment, the contents were filled in an aluminum pan and compression molded at a pressure of about 10 kg f /cm 2 for 2.00 sec.
[실험예 1] [Experimental Example 1]
상기 표에 나타낸 성분 및 성분비로 제조한 화장료 조성물의 실제적인 외관 및 사용감을 확인하기 위해 관능평가를 수행하였다. Sensory evaluation was performed to confirm the actual appearance and feeling of use of the cosmetic composition prepared with the components and component ratios shown in the above table.
상기 관능평가는 파우더 관련 연구 및 연구 지원을 담당하는 20~30대 남녀 20명을 대상으로 수행하였고, 관능평가를 위한 측정은 시료를 피부에 도포하는 등의 사용을 행한 후에 5점을 만점으로 기준하여 그 수치를 나타내었다. (평가 척도: 1점- 매우 나쁨, 2점- 나쁨, 3점- 보통, 4점- 좋음, 5점- 매우 좋음)The sensory evaluation was performed on 20 men and women in their 20s and 30s who are in charge of powder-related research and research support, and the measurement for sensory evaluation was based on a perfect score of 5 after use such as applying the sample to the skin. and showed the number. (Rating scale: 1 point - very bad, 2 points - bad, 3 points - average, 4 points - good, 5 points - very good)
평가 목록은 외관, 발림성, 발색력, 밀착력, 펄감 표현력, 가루 뭉침, 제형 안정도, 공정 난이도로 결정하였고, 측정 결과를 하기 표에 나타내었다.The evaluation list was determined by appearance, spreadability, color development, adhesion, pearl expression, powder aggregation, formulation stability, and process difficulty, and the measurement results are shown in the table below.
실험 결과, 폴리올-오일 유화물을 형성에 사용한 폴리올의 종류가 3가 알코올인 경우가 2가 알코올인 경우보다 외관의 표현과 제형 안정성이 상대적으로 좋은 편이고 2가 알코올을 사용한 경우는 도포 후의 펄감 표현과 발림이 상대적으로 좋은 편이었다. As a result of the experiment, when the type of polyol used to form the polyol-oil emulsion was trihydric alcohol, the appearance expression and formulation stability were relatively better than the case of dihydric alcohol. Balim was relatively good.
또한, 수분을 함유한 경우가 발색력이 더 높아지는 경향을 보였지만 제형 안정도에서는 장기적으로 좋은 방향은 아니라고 알려져 있다. 따라서, 폴리올-오일 유화물을 구성할 때에 중요하게 생각하는 부분에 맞춰 구성을 하고 사용하면 되는 것이라 판단할 수 있다.In addition, although the color development tended to be higher in the case of containing water, it is known that the long-term stability of the formulation is not good. Therefore, it can be determined that when configuring the polyol-oil emulsion, it can be configured and used according to the important part.
[제조예 2] 폴리올-오일 유화물 함량에 따른 화장료 조성물의 비교[Preparation Example 2] Comparison of cosmetic compositions according to polyol-oil emulsion content
본 발명에 따른 폴리올-오일 유화물의 함량을 달리하여 화장료 조성물을 제조하고 이를 비교하였다. 구체적으로 유화물의 함량은 하기 표와 같다. 제조방법은 하기 함량을 사용한 것을 제외하고는 상기 제조예에서 사용한 방법과 동일하다.Cosmetic compositions were prepared by varying the content of the polyol-oil emulsion according to the present invention and compared. Specifically, the content of the emulsion is shown in the table below. The manufacturing method is the same as the method used in the above Preparation Example except for using the following content.
[실험예 2][Experimental Example 2]
상기에서 제조한 화장료 조성물의 실제적인 외관 및 사용감을 확인하기 위해 관능평가를 수행하였다. 상기 관능평가는 상기와 동일하게 파우더 관련 연구 및 연구 지원을 담당하는 20~30대 남녀 20명을 대상으로 수행하였고, 관능평가를 위한 측정은 시료를 피부에 도포하는 등의 사용을 행한 후에 5점을 만점으로 기준하여 그 수치를 나타내었다. (평가 척도: 1점- 매우 나쁨, 2점- 나쁨, 3점- 보통, 4점- 좋음, 5점- 매우 좋음) Sensory evaluation was performed to confirm the actual appearance and feeling of use of the cosmetic composition prepared above. The sensory evaluation was performed on 20 men and women in their 20s and 30s who are in charge of powder-related research and research support in the same way as above. The values were expressed on the basis of a full score. (Rating scale: 1 point - very bad, 2 points - bad, 3 points - average, 4 points - good, 5 points - very good)
평가 목록은 외관, 발림성, 발색력, 밀착력, 펄감 표현력, 가루 뭉침, 제형 안정도, 공정 난이도로 결정하였고, 측정 결과를 하기 표에 나타내었다.The evaluation list was determined by appearance, spreadability, color development, adhesion, pearl expression, powder aggregation, formulation stability, and process difficulty, and the measurement results are shown in the table below.
실험 결과, 폴리올-오일 유화물의 비율이 높아질수록 가루 뭉침이 적고 제형의 안정도가 높아지며, 폴리올-오일 유화물의 비율이 낮아질수록 제형의 외관과 펄감 및 광택 표현이 좋아지는 경향을 보였다. 따라서, 폴리올-오일 유화물의 함량은 전체 원료 구성 중 10~20%정도가 적정 함량이라 할 수 있다.As a result of the experiment, the higher the ratio of the polyol-oil emulsion, the less powder aggregation and the higher the stability of the formulation, and the lower the ratio of the polyol-oil emulsion, the better the appearance, pearl and gloss expression of the formulation. Therefore, the content of the polyol-oil emulsion can be said to be about 10 to 20% of the total raw material composition.
[제조예 3] 폴리올-오일 유화물을 포함하지 않는 화장료 조성물과의 비교[Preparation Example 3] Comparison with a cosmetic composition not containing a polyol-oil emulsion
본 발명의 폴리올-오일 유화물을 포함하지 않는 비교예 화장료 조성물을 제조하고 본 발명의 실시예 2와 비교하였다. 구체적으로, 본원발명은 폴리올-오일 유화물을 혼합하는 반면, 비교예 조성은 그에 상응하는 양의 부틸렌글라이콜 및 다이메치콘을 개별적으로 혼합한 것이다. 제조방법은 하기 함량을 사용한 것을 제외하고는 상기 제조예에서 사용한 방법과 동일하다.A comparative cosmetic composition not containing the polyol-oil emulsion of the present invention was prepared and compared with Example 2 of the present invention. Specifically, the present invention mixes the polyol-oil emulsion, whereas the comparative example composition separately mixes corresponding amounts of butylene glycol and dimethicone. The manufacturing method is the same as the method used in the above Preparation Example except for using the following content.
[실험예 3][Experimental Example 3]
상기에서 제조한 화장료 조성물의 실제적인 외관 및 사용감을 확인하기 위해 관능평가를 수행하였다. 상기 관능평가는 상기와 동일하게 파우더 관련 연구 및 연구 지원을 담당하는 20~30대 남녀 20명을 대상으로 수행하였고, 관능평가를 위한 측정은 시료를 피부에 도포하는 등의 사용을 행한 후에 5점을 만점으로 기준하여 그 수치를 나타내었다. (* 평가 척도: 1점- 매우 나쁨, 2점- 나쁨, 3점- 보통, 4점- 좋음, 5점- 매우 좋음)Sensory evaluation was performed to confirm the actual appearance and feeling of use of the cosmetic composition prepared above. The sensory evaluation was performed on 20 men and women in their 20s and 30s who are in charge of powder-related research and research support in the same way as above. The values were expressed on the basis of a full score. (* Evaluation scale: 1 point - very bad, 2 points - bad, 3 points - average, 4 points - good, 5 points - very good)
평가 목록은 외관, 발림성, 발색력, 밀착력, 펄감 표현력, 가루 뭉침, 제형 안정도, 공정 난이도로 결정하였고, 측정 결과를 하기 표에 나타내었다.The evaluation list was determined by appearance, spreadability, color development, adhesion, pearl expression, powder aggregation, formulation stability, and process difficulty, and the measurement results are shown in the table below.
실험 결과, 폴리올-오일 유화물을 형성한 원료를 투입하지 않고 폴리올과 오일을 개별로 투입한 경우에 제형 안정도가 상대적으로 높은 느낌을 주었으나 외관과 펄감 및 광택 표현이 상대적으로 약한 편이며 가루 뭉침도 조금 더 관찰되는 편이었다. 따라서, 폴리올과 오일을 각각 사용하는 것보다는 폴리올-오일 유화물의 형태로 투입하는 것이 제형의 표현력이 더 높아진다고 판단할 수 있다.As a result of the experiment, when polyol and oil were separately added without adding raw materials that formed a polyol-oil emulsion, the formulation stability was relatively high, but the appearance, pearl feeling, and gloss expression were relatively weak, and the powder aggregation was also relatively low. It was a bit more observable. Therefore, it can be determined that the expressive power of the formulation is higher when the polyol and oil are added in the form of a polyol-oil emulsion than when each is used.
[제조예 4] 폴리올-오일 유화물을 포함하지 않는 화장료 조성물과의 비교 2[Preparation Example 4] Comparison 2 with a cosmetic composition not containing a polyol-oil emulsion
본 발명에 따른 폴리올-오일 유화물을 포함하지 않는 비교예 화장료 조성물을 제조하고 본 발명의 실시예 2와 비교하였다. A comparative cosmetic composition not containing a polyol-oil emulsion according to the present invention was prepared and compared with Example 2 of the present invention.
조성예 모두 펄 함량은 동일하지만, 비교예 3은 폴리올-오일 복합체를 포함하지 않고 오일 바인더의 함량을 2배로 증량한 것이고, 비교예 2는 폴리올-오일 복합체를 포함하지 않고 기존에 통상적으로 많이 사용되는 오일 바인더를 포함한 조성예이다. 구체적인 제조방법은 하기 함량을 사용한 것을 제외하고는 상기 제조예에서 사용한 방법과 동일하다.All of the composition examples have the same pearl content, but Comparative Example 3 does not include a polyol-oil complex and the content of the oil binder is doubled, and Comparative Example 2 does not include a polyol-oil complex and is commonly used in the past. It is a composition example including an oil binder to be. The specific manufacturing method is the same as the method used in the above Preparation Example except for using the following content.
(갈색)Comparative Example 2
(brown)
(갈색)Comparative Example 3
(brown)
(갈색)Example 2
(brown)
[실험예 4][Experimental Example 4]
상기 표에 나타낸 성분 및 성분비로 제조한 화장료 조성물의 실제적인 외관 및 사용감을 확인하기 위해 관능평가를 수행하였다. 상기 관능평가는 상기와 동일하게 파우더 관련 연구 및 연구 지원을 담당하는 20~30대 남녀 20명을 대상으로 수행하였고, 관능평가를 위한 측정은 시료를 피부에 도포하는 등의 사용을 행한 후에 5점을 만점으로 기준하여 그 수치를 나타내었다. (* 평가 척도: 1점- 매우 나쁨, 2점- 나쁨, 3점- 보통, 4점- 좋음, 5점- 매우 좋음)Sensory evaluation was performed to confirm the actual appearance and feeling of use of the cosmetic composition prepared with the components and component ratios shown in the above table. The sensory evaluation was performed on 20 men and women in their 20s and 30s who are in charge of powder-related research and research support in the same way as above. The values were expressed on the basis of a full score. (* Evaluation scale: 1 point - very bad, 2 points - bad, 3 points - average, 4 points - good, 5 points - very good)
평가 목록은 외관, 발림성, 발색력, 밀착력, 펄감 표현력, 가루 뭉침, 제형 안정도, 공정 난이도로 결정하였고, 측정 결과를 하기 표에 나타내었다.The evaluation list was determined by appearance, spreadability, color development, adhesion, pearl expression, powder aggregation, formulation stability, and process difficulty, and the measurement results are shown in the table below.
오일 바인더의 함량이 동일할 때, 폴리올-오일 유화물을 적용하지 않고 일반적인 오일 바인더만을 사용한 경우에 외관과 펄감 및 광택 표현이 더 좋았지만 가루 뭉침, 공정 난이도, 제형 안정도가 매우 좋지 않았다. 따라서, 폴리올-오일 유화물을 오일 바인더에 구성하는 것이 제형적으로 더 우수하다는 것을 확인할 수 있다.When the content of the oil binder was the same, when only a general oil binder was used without applying the polyol-oil emulsion, the appearance, pearl feeling, and gloss expression were better, but powder aggregation, process difficulty, and formulation stability were very poor. Therefore, it can be confirmed that the composition of the polyol-oil emulsion in the oil binder is superior in terms of formulation.
이상에서, 출원인은 본 발명의 바람직한 실시예들을 설명하였지만, 이와 같은 실시예들은 본 발명의 기술적 사상을 구현하는 일 실시예일 뿐이며 본 발명의 기술적 사상을 구현하는 한 어떠한 변경예 또는 수정예도 본 발명의 범위에 속하는 것으로 해석되어야 한다.In the above, the applicant has described the preferred embodiments of the present invention, but these embodiments are only one embodiment for implementing the technical idea of the present invention, and any changes or modifications are the same as those of the present invention as long as they implement the technical idea of the present invention. should be construed as falling within the scope.
Claims (13)
A color cosmetic composition comprising an oil phase containing a polyol-oil emulsion, and powder.
The color cosmetic composition according to claim 1, wherein the powder does not contain talc.
The method of claim 1, wherein the powder is mica, synthetic mica, sericite, silica, titanium dioxide, silicon-based powder, boron powder, zinc oxide, nylon powder, polymethacrylate powder, urethane powder, acrylate (co)polymer, A color cosmetic composition comprising at least one selected from the group consisting of polyethylene (co)polymers, organic color pigments and inorganic color pigments.
The color cosmetic composition according to claim 1, wherein the polyol-oil emulsion is a nanoemulsion or a liposome.
The method of claim 1, wherein the polyol in the polyol-oil emulsion is glycerin, diglycerin, ethylhexylglycerin, polyglycerin, ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, dipropylene Glycol, polypropylene glycol, butylene glycol, pentylene glycol, hexylene glycol, caprylyl glycol, decylene glycol, propanediol, pentanediol, hexanediol, A color cosmetic composition comprising at least one selected from the group consisting of D-panthenol and octanediol.
The color cosmetic composition according to claim 1, wherein the oil in the polyol-oil emulsion is at least one selected from the group consisting of ester-based oils, silicone oils, and vegetable oils.
The color cosmetic composition according to claim 1, wherein the polyol-oil emulsion further comprises at least one selected from the group consisting of water, phospholipids, surfactants, ceramides, and cholesterol.
The color cosmetic composition according to claim 1, wherein the oil phase is included in an amount greater than 30% by weight based on the total weight of the cosmetic composition.
The color cosmetic composition according to claim 1, wherein the polyol-oil emulsion is contained in an amount of 5 to 70% by weight based on the total weight of the oil phase part.
The color cosmetic composition according to claim 1, wherein the ratio (weight) of the polyol-oil emulsion to the other components in the oil phase is 1:0.1 to 10.
The color cosmetic composition according to claim 1, wherein the ratio (by weight) of the polyol-oil emulsion:silicone oil:other components in the oil phase is 1:0.01 to 10:0.1 to 10.
The color cosmetic composition according to claim 1, wherein the polyol-oil emulsion is contained in an amount of 0.1 to 40% by weight based on the total weight of the cosmetic composition.
The color cosmetic composition according to claim 1, wherein the cosmetic composition is a formulation selected from the group consisting of two-way cake, pact, powder foundation, eye shadow, blusher, and highlighter.
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| KR20120005773A (en) | 2010-07-09 | 2012-01-17 | 나드리화장품주식회사 | Color cosmetics of talc free containing illite |
| KR102065930B1 (en) | 2017-12-06 | 2020-01-14 | 주식회사 잇츠한불 | Based-powder for make-up having Talc-free, outstanding dispersibility and molding stability |
| KR20200077169A (en) | 2018-12-20 | 2020-06-30 | 코스맥스 주식회사 | Talc-free matte type pressed powder cosmetic composition |
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| KR100874877B1 (en) * | 2007-03-22 | 2008-12-19 | 한국콜마 주식회사 | Oil-in-water-in-oil reversed-phase multi-emulsion phase using polyol-in-oil high density nano-concentrated emulsion, and preparation method thereof |
| KR101396277B1 (en) * | 2012-02-10 | 2014-05-19 | 한국콜마주식회사 | Color Cosmetic Composition Comprising Polyol in Oil as Binder and Manufacturing Method Thereof |
| KR102013619B1 (en) * | 2012-11-08 | 2019-08-23 | (주)아모레퍼시픽 | Emulsion binder composition, cosmetic composition comprising emulsion bider composition and method of manufacturing thereof |
| KR20150044104A (en) * | 2013-10-16 | 2015-04-24 | 코웨이 주식회사 | Makeup kit composition having double layer of makeup layer and moisture and shimmering layer after applying on skin |
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| KR20120005773A (en) | 2010-07-09 | 2012-01-17 | 나드리화장품주식회사 | Color cosmetics of talc free containing illite |
| KR102065930B1 (en) | 2017-12-06 | 2020-01-14 | 주식회사 잇츠한불 | Based-powder for make-up having Talc-free, outstanding dispersibility and molding stability |
| KR20200077169A (en) | 2018-12-20 | 2020-06-30 | 코스맥스 주식회사 | Talc-free matte type pressed powder cosmetic composition |
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