KR20220035614A - O/W Stick-Type Clay Mask Cosmetic Composition Containing Water - Google Patents
O/W Stick-Type Clay Mask Cosmetic Composition Containing Water Download PDFInfo
- Publication number
- KR20220035614A KR20220035614A KR1020200117582A KR20200117582A KR20220035614A KR 20220035614 A KR20220035614 A KR 20220035614A KR 1020200117582 A KR1020200117582 A KR 1020200117582A KR 20200117582 A KR20200117582 A KR 20200117582A KR 20220035614 A KR20220035614 A KR 20220035614A
- Authority
- KR
- South Korea
- Prior art keywords
- oil
- stick
- cosmetic composition
- water
- weight
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 239000002537 cosmetic Substances 0.000 title claims abstract description 44
- 239000004927 clay Substances 0.000 claims abstract description 49
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- 239000003381 stabilizer Substances 0.000 claims abstract description 25
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims abstract description 19
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- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
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- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 6
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 6
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Classifications
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- A—HUMAN NECESSITIES
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- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
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- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
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Abstract
Description
본 발명은 수중유형 유화 스틱형 클레이 마스크 화장료 조성물에 관한 것으로, 더욱 상세하게는 제품 안정성이 우수하고, 피부 자극성이 낮은 수중유형 유화 스틱형 클레이 마스크 화장료 조성물에 관한 것이다.The present invention relates to an oil-in-water emulsified stick-type clay mask cosmetic composition, and more specifically, to an oil-in-water emulsified stick-type clay mask cosmetic composition with excellent product stability and low skin irritation.
피부는 신체의 표면을 덮고 있으므로 외계로부터 자극이나 여러 병원체에 직접 접촉될 기회가 많고, 체내로부터 영향을 강하게 받는다. 피부 건강을 쉽게 지키고 개선하기 위해 마사지 또는 마스크 팩을 이용하고 있다. 종래 미용, 마사지 팩으로는 계란 등의 동물성 단백질이 주로 사용되다가, 수용성 고분자 화합물에 피부 영양제를 첨가시킨 겔 타입의 미용제가 개발되어 많이 이용되고 있으며, 천연과일이나 야채를 이용한 천연 팩도 널리 사용되고 있다. 또한 최근에는 원적외선 및 음이온을 발생시키는 황토, 점토, 숯, 맥반석, 일라이트(ilite) 등을 이용한 제품이 개발되어 각종 오염 및 환경요인에 노출된 인간 생활에 접목되어 이용되고 있으며, 피부질환을 예방하고 개선하기 위해 다양한 시도가 되고 있다.Since the skin covers the surface of the body, there are many opportunities for direct contact with external stimuli or various pathogens, and it is strongly influenced by the body. To easily protect and improve skin health, massage or mask packs are used. Conventionally, animal proteins such as eggs were mainly used for beauty and massage packs, but gel-type beauty agents containing skin nutrients added to water-soluble polymer compounds have been developed and are widely used. Natural packs using natural fruits and vegetables are also widely used. . In addition, recently, products using red clay, clay, charcoal, elvan stone, and ilite, which generate far-infrared rays and negative ions, have been developed and are being used in human life exposed to various pollution and environmental factors, and are used to prevent skin diseases. Various attempts are being made to improve it.
특히, 각종 미네랄 및 화장품의 원료로 사용되고 있는 벤토나이트, 게르마늄 등을 함유하고 있는 점토/머드를 주재로 하는 점토팩과, 독소 제거 및 원적외선 방사 등의 효능을 갖는 황토를 주재로 하는 황토팩 등이 연구되었으며, 시중에도 판매되고 있다.In particular, research has been conducted on clay packs based on clay/mud containing bentonite and germanium, which are used as raw materials for various minerals and cosmetics, and red clay packs based on red clay, which has effects such as removing toxins and emitting far-infrared rays. and is also sold in the market.
팩은 제형과 사용 방법에 따라 건조된 필름을 제거하는 필오프 타입 팩, 팩제를 바른 후 물 세안으로 팩을 제거하는 워시오프 타입 팩, 티슈로 닦아내는 티슈오프 타입 팩 및 시트에 유액이 적셔 있는 시트 타입 팩 등으로 구분할 수 있다. 그 중 워시오프 타입 팩은 팩제를 바르고 마른 후 세안으로 내용물을 제거할 수 있어서 자극이 적고, 사용이 편리하며, 모공 노폐물 제거 및 각질 케어 기능이 뛰어나 대표적으로 많이 사용하는 팩 제형의 하나이다. 그러나 이러한 워시오프형 팩은 제형 안정도가 좋지 않아서 효능을 나타내는 성분의 사용량에 한계가 있거나, 고온 또는 냉온에서 물이 생기는 등의 구조적인 불안 등의 문제도 발생한다.Depending on the formulation and method of use, packs include a peel-off type pack that removes the dried film, a wash-off type pack that removes the pack by washing the face with water after applying the pack, a tissue-off type pack that wipes off with a tissue, and a sheet with latex soaked in it. It can be divided into sheet type, pack, etc. Among them, the wash-off type pack is one of the most commonly used pack formulations as it has less irritation, is convenient to use, and has excellent pore waste removal and dead skin care functions since the contents can be removed by washing the face after applying the pack and drying it. However, these wash-off type packs have poor formulation stability, so there is a limit to the amount of effective ingredients used, and problems such as structural instability such as water forming at high or cold temperatures occur.
종래의 점토(클레이)/머드팩은 피부에 바른 후 마르면 씻어내는 워시오프 타입이 대부분이며, 보다 상세하게는 용기로부터 일정량을 취해 손을 이용하여 얼굴 등에 펴서 발랐다. 그러나, 이와 같은 종래의 점토팩은 사용시 손에 묻어나는 불편함과 불규칙한 발림성 등의 문제가 있었다.Most conventional clay/mud packs are wash-off types that are applied to the skin and then washed off when dry. More specifically, a certain amount is taken from the container and spread on the face using hands. However, such conventional clay packs had problems such as inconvenience in sticking to hands and irregular application when used.
이에 한국등록특허 제2096009호는 스틱 타입의 클레이팩을 개시하였다. 하지만 이는 사용시 손에 묻어나지 않고 피지 흡착 효과가 우수하였으나, 오일이 포함되어있지 않아 보습력이 부족하고, 클레이와 같은 파우더 성분들이 고루 분산되지 않으며, 소듐스테아레이트로 인해 발수현상이 발생될 우려가 있었다. Accordingly, Korean Patent No. 2096009 disclosed a stick-type clay pack. However, although this did not stick to hands when used and had an excellent sebum absorption effect, it lacked moisturizing power because it did not contain oil, powder ingredients such as clay were not evenly dispersed, and there was a risk of water repellency occurring due to sodium stearate. .
이에, 본 발명자들은 상기 문제점을 해결하기 위하여 노력한 결과, 소듐스테아레이트(sodium stearate) 고형화제가 함유된 조성물에 벌킹제, 특정 성분의 유상경도 형성제 및 유화안정제를 특정 비율로 첨가시킬 경우, 조성물을 수중유형으로 안정화시킴으로서, 보습력, 보존 경도 안정도, 발림성 및 건조속도가 우수한 수중유형 유화 스틱형 클레이 마스크 화장료 조성물을 제조할 수 있다는 것을 확인하고, 본 발명을 완성하게 되었다.Accordingly, the present inventors have made efforts to solve the above problem, and as a result, when a bulking agent, a specific oil phase hardness former, and an emulsion stabilizer are added at a specific ratio to a composition containing a sodium stearate solidifying agent, the composition By stabilizing it in an oil-in-water form, it was confirmed that an oil-in-water emulsified stick-type clay mask cosmetic composition with excellent moisturizing power, storage hardness stability, spreadability, and drying speed could be manufactured, and the present invention was completed.
본 발명의 목적은 보존 경도 안정도, 보습력, 발림성 및 건조속도가 우수한 수중유형 유화 스틱형 클레이 마스크 화장료 조성물 및 이로 제조된 클레이 마스크용 수중유형 유화 스틱을 제공하는데 있다.The purpose of the present invention is to provide an oil-in-water emulsion stick type clay mask cosmetic composition with excellent storage hardness stability, moisturizing power, spreadability and drying speed, and an oil-in-water emulsion stick for clay masks made therefrom.
상기 목적을 달성하기 위하여, 본 발명은 소듐스테아레이트, 유상 경도 형성제, 수상 경도 형성제, 유화안정제, 벌킹제, 유상부, pH 조절제 및 수상부를 포함하는 수중유형 유화 스틱형 클레이 마스크 화장료 조성물에 있어서, 상기 유상 경도 형성제는 폴리에틸렌 왁스, 파라핀 및 마이크로 크리스탈린 왁스이고, 유화안정제는 마이크로 크리스탈린 셀룰로오스 및 셀룰로오스검인 것을 특징으로 하는 수중유형 유화 스틱형 클레이 마스크 화장료 조성물을 제공한다.In order to achieve the above object, the present invention is an oil-in-water emulsion stick type clay mask cosmetic composition comprising sodium stearate, an oil phase hardness former, an aqueous phase hardness former, an emulsion stabilizer, a bulking agent, an oil phase, a pH adjuster, and an aqueous phase. It provides an oil-in-water emulsified stick-type clay mask cosmetic composition, wherein the oil phase hardness formers are polyethylene wax, paraffin, and micro-crystalline wax, and the emulsion stabilizers are micro-crystalline cellulose and cellulose gum.
본 발명에 있어서, 상기 수중유형 유화 스틱형 클레이 마스크 화장료 조성물은 소듐스테아레이트 1~10중량%, 유상 경도 형성제 1~5중량%, 수상 경도 형성제 0.1~10중량%, 유화안정제 0.3~5중량%, 벌킹제 0.1~30중량%, 유상부 1~30중량%, pH 조절제 1~10중량% 및 수상부 잔량을 포함하는 것을 특징으로 한다.In the present invention, the oil-in-water emulsified stick-type clay mask cosmetic composition contains 1 to 10% by weight of sodium stearate, 1 to 5% by weight of an oil phase hardness former, 0.1 to 10% by weight of an aqueous phase hardness former, and 0.3 to 5% by weight of an emulsion stabilizer. It is characterized in that it includes % by weight, 0.1 to 30% by weight of bulking agent, 1 to 30% by weight of oil phase, 1 to 10% by weight of pH adjuster, and the remaining amount of water phase.
본 발명에 있어서, 상기 유상 경도 형성제를 구성하는 폴리에틸렌 왁스, 파라핀 및 마이크로 크리스탈린 왁스의 혼합비(중량%)는 40~60:35~55:2~8인 것을 특징으로 한다. In the present invention, the mixing ratio (% by weight) of polyethylene wax, paraffin and micro crystalline wax constituting the oil phase hardness former is 40 to 60:35 to 55:2 to 8.
본 발명에 있어서, 상기 수상 경도 형성제는 디스테아레스-100 IPDI (disteareth-100 IPDI)인 것을 특징으로 한다.In the present invention, the water hardness forming agent is characterized as disteareth-100 IPDI (disteareth-100 IPDI).
본 발명에 있어서, 상기 유화안정제를 구성하는 마이크로 크리스탈린 셀룰로오스 및 셀룰로오스검의 혼합비(중량%)는 10~20: 80~90인 것을 특징으로 한다.In the present invention, the mixing ratio (% by weight) of microcrystalline cellulose and cellulose gum constituting the emulsion stabilizer is 10 to 20: 80 to 90.
본 발명에 있어서, 상기 벌킹제는 카올린, 티타늄디옥사이드, 징크, 피브이피 및 실리카로 구성된 군에서 선택되는 1종 이상인 것을 특징으로 한다.In the present invention, the bulking agent is characterized in that it is one or more selected from the group consisting of kaolin, titanium dioxide, zinc, PVP, and silica.
본 발명에 있어서, 상기 유상부는 에스테르계 오일, 탄화수소계 오일 및 식물성 오일로 구성된 군으로부터 선택되는 1종 이상인 것을 특징으로 한다.In the present invention, the oil phase is characterized in that it is at least one selected from the group consisting of ester oil, hydrocarbon oil, and vegetable oil.
본 발명에 있어서, 상기 자극완화제는 모란뿌리 추출물, 마치현 추출물 및 병풀 추출물로 구성된 군에서 선택되는 1종 이상인 것을 특징으로 한다.In the present invention, the irritant reliever is characterized in that it is at least one selected from the group consisting of peony root extract, portulaca portulaca extract, and centella asiatica extract.
본 발명에 있어서, 상기 pH 조절제는 살리실릭애씨드, 소듐시트레이트 및 소듐클로라이드인 것을 특징으로 한다.In the present invention, the pH adjusting agent is characterized in that salicylic acid, sodium citrate, and sodium chloride.
본 발명에 있어서, 상기 수상부는 정제수 및 보습제로 구성된 군으로부터 선택되는 1종 이상인 것을 특징으로 한다.In the present invention, the aqueous phase is characterized in that it is at least one selected from the group consisting of purified water and moisturizer.
본 발명에 있어서, 상기 수중유형 유화 스틱형 클레이 마스크 화장료 조성물은 자극 완화제, 알코올류, 스킨 컨디셔닝제, 보존제, 착색제, 착향제, 분말제, 금속이온봉쇄제 및 미용영양제로 구성된 군으로부터 선택되는 1종 이상을 추가로 포함하는 것을 특징으로 한다.In the present invention, the oil-in-water emulsified stick-type clay mask cosmetic composition is one selected from the group consisting of irritation relievers, alcohols, skin conditioning agents, preservatives, colorants, flavoring agents, powders, metal ion sequestrants, and cosmetic nutrients. It is characterized by additionally including more than one species.
본 발명은 또한, 상기 수중유형 유화 스틱형 클레이 마스크 화장료 조성물로 제조된 클레이 마스크용 수중유형 유화 스틱을 제공한다.The present invention also provides an oil-in-water emulsion stick for a clay mask made from the oil-in-water emulsion stick type clay mask cosmetic composition.
본 발명에 따른 수중유형 유화 스틱형 클레이 마스크 화장료 조성물은 소듐스테아레이트(sodium stearate) 고형화제가 함유된 조성물에 벌킹제, 특정 성분의 유상경도 형성제 및 유화안정제를 특정 비율로 첨가시켜, 조성물을 수중유형으로 안정화시킴으로써, pH 및 수분감량에 대한 안정도가 우수하고, 발림성 및 건조속도 또한 우수하다.The oil-in-water emulsified stick-type clay mask cosmetic composition according to the present invention is made by adding a bulking agent, a specific oil phase hardness former, and an emulsion stabilizer in a specific ratio to a composition containing a sodium stearate solidifying agent, so that the composition can be submerged in water. By stabilizing the product, it has excellent stability against pH and moisture loss, as well as excellent spreadability and drying speed.
본 발명에서는 (a) 소듐스테아레이트(sodium stearate); (b) 폴리에틸렌 왁스, 파라핀 및 마이크로 크리스탈린 왁스로 구성된 유상 경도 형성제; (c) 수상 경도 형성제; (d) 마이크로 크리스탈린 셀룰로오스 및 셀룰로오스검으로 구성된 유화안정제; (e) 벌킹제; (f) 유상부; (g) pH 조절제 및 (h) 수상부가 수중유형 유화 스틱형 클레이 마스크 화장료 조성물에 포함될 경우, 제형의 pH가 안정화되고, 제형의 내구성(경도, 발한성)도 향상된다는 것을 확인하고자 하였다.In the present invention, (a) sodium stearate (sodium stearate); (b) an oily hardness former consisting of polyethylene wax, paraffin and microcrystalline wax; (c) water hardness former; (d) emulsion stabilizer composed of microcrystalline cellulose and cellulose gum; (e) bulking agent; (f) paid part; The purpose was to confirm that when (g) a pH regulator and (h) an aqueous phase are included in an oil-in-water emulsified stick-type clay mask cosmetic composition, the pH of the formulation is stabilized and the durability (hardness, perspiration) of the formulation is also improved.
본 발명에서는, 고형화제로 소듐스테아레이트(sodium stearate); 유상 경도 형성제로 폴리에틸렌 왁스, 파라핀 및 마이크로 크리스탈린 왁스; 유화안정제로 마이크로 크리스탈린 셀룰로오스 및 셀룰로오스검을 포함하는 수중유형 유화 스틱형 클레이 마스크 화장료 조성물을 제조하고, 제품의 안정성(발한성), 피부 자극성 및 제형 사용감을 평가하였다. 그 결과 제품의 안정성(발한성), 피부 자극성 및 제형 사용감이 우수하다는 것을 확인하였다. In the present invention, sodium stearate as a solidifying agent; Polyethylene wax, paraffin and microcrystalline wax as oil hardness formers; An oil-in-water emulsion stick-type clay mask cosmetic composition containing microcrystalline cellulose and cellulose gum as an emulsion stabilizer was prepared, and product stability (perspiration), skin irritation, and feeling of use of the formulation were evaluated. As a result, it was confirmed that the product's stability (perspiration), skin irritation, and formulation feel were excellent.
따라서, 본 발명은 일 관점에서, 소듐스테아레이트, 유상 경도 형성제, 수상 경도 형성제, 유화안정제, 벌킹제, 유상부, pH 조절제 및 수상부를 포함하는 수중유형 유화 스틱형 클레이 마스크 화장료 조성물에 있어서, 상기 유상 경도 형성제는 폴리에틸렌 왁스, 파라핀 및 마이크로 크리스탈린 왁스이고, 유화안정제는 마이크로 크리스탈린 셀룰로오스 및 셀룰로오스검인 것을 특징으로 하는 수중유형 유화 스틱형 클레이 마스크 화장료 조성물에 관한 것이다.Therefore, in one aspect, the present invention relates to an oil-in-water emulsion stick type clay mask cosmetic composition comprising sodium stearate, an oil phase hardness former, an aqueous phase hardness former, an emulsion stabilizer, a bulking agent, an oil phase, a pH adjuster, and an aqueous phase, It relates to an oil-in-water emulsified stick-type clay mask cosmetic composition, wherein the oil phase hardness formers are polyethylene wax, paraffin, and microcrystalline wax, and the emulsion stabilizers are microcrystalline cellulose and cellulose gum.
본 발명에 있어서, 상기 소듐스테아레이트(sodium stearate)는 제형의 고형화를 위한 것으로서, 전체 조성물중 1~10중량%, 바람직하게는 2~5중량% 사용할 수 있다. 상기 소듐스테아레이트의 함량이 1중량% 미만인 경우에는 고형화 효과가 미미하고, 10중량%를 초과할 경우에는 경도가 지나치게 딱딱하여 사용감이 나쁘거나 PH가 높아서 제품의 안정성이 낮고, 피부 자극도가 높아 제품의 안전성도 낮다.In the present invention, sodium stearate is used for solidifying the formulation and can be used in an amount of 1 to 10% by weight, preferably 2 to 5% by weight, of the total composition. If the content of sodium stearate is less than 1% by weight, the solidification effect is minimal, and if it exceeds 10% by weight, the hardness is too hard, resulting in a poor feeling of use, or the pH is high, resulting in low product stability and high skin irritation. Safety is also low.
본 발명에 있어서, 경도 형성제는 제형의 경도를 유지시키고, 스웨팅을 방지하기 위한 것으로서, 상기 수상 경도 형성제는 디스테아레스-100 IPDI (disteareth-100 IPDI)인 것을 특징으로 하고, 유상 경도 형성제로는 폴리에틸렌 왁스, 파라핀 및 마이크로 크리스탈린 왁스인 것을 특징으로 한다.In the present invention, the hardness former is used to maintain the hardness of the formulation and prevent sweating, and the water phase hardness former is disteareth-100 IPDI. The forming agent is polyethylene wax, paraffin, and micro crystalline wax.
전체 조성물 중 수상 경도 형성제는 0.1~10중량%, 바람직하게는 0.5~3중량% 사용할 수 있으며, 이를 벗어날 경우에는 발림성이 현저하게 떨어지거나, 스틱형태의 제형자체가 형성되지 않을 수 있다.Of the total composition, the water hardness former can be used in an amount of 0.1 to 10% by weight, preferably 0.5 to 3% by weight. If it exceeds this amount, the spreadability may be significantly reduced or the stick-shaped formulation itself may not be formed.
상기 유상 경도 형성제를 구성하는 폴리에틸렌 왁스, 파라핀 및 마이크로 크리스탈린 왁스의 혼합비(중량%)는 40~60:35~55:2~8인 것이 바람직하다. 상기 혼합비의 범위를 벗어날 경우에는 경도가 높아져 발림성이 현저하게 떨어지며 스웨팅현상이 두드러질 수 있는 문제가 있다. The mixing ratio (% by weight) of polyethylene wax, paraffin, and microcrystalline wax constituting the oil phase hardness former is preferably 40 to 60:35 to 55:2 to 8. If the mixing ratio is outside the range, the hardness increases, the spreadability is significantly reduced, and the sweating phenomenon may become noticeable.
전체 조성물 중 유상 경도 형성제는 1~5중량%, 바람직하게는 1~4중량% 사용할 수 있으며, 이를 벗어날 경우에는 발림성이 현저하게 떨어지거나, 스틱형태의 제형자체가 형성되지 않을 수 있다.Of the total composition, the oil hardness former can be used in an amount of 1 to 5% by weight, preferably 1 to 4% by weight. If it exceeds this amount, the spreadability may be significantly reduced or the stick-shaped formulation itself may not be formed.
전체 조성물중 유화안정제는 0.3~5중량%, 바람직하게는 0.5~3중량% 사용할 수 있다. 상기 유화안정제가 0.3중량% 미만인 경우에는 분산안정도가 좋지 않으며 스웨팅 현상이 심화될 우려가 있고, 5중량%를 초과할 경우에는 사용감 및 발림성이 현저하게 저하되며 오히려 파우더 뭉침 현상 및 고온에서 점도가 상승하여 충전시 어려운 문제가 있다. 상기 유화안정제를 구성하는 마이크로 크리스탈린 셀룰로오스 및 셀룰로오스검의 혼합비(중량%)는 10~20: 80~90인 것이 바람직하다.The emulsion stabilizer can be used in an amount of 0.3 to 5% by weight, preferably 0.5 to 3% by weight, in the total composition. If the emulsion stabilizer is less than 0.3% by weight, the dispersion stability is poor and there is a risk that the sweating phenomenon may worsen, and if it exceeds 5% by weight, the feeling of use and spreadability are significantly reduced, and powder agglomeration occurs and viscosity increases at high temperatures. There is a problem when charging as it rises. The mixing ratio (% by weight) of microcrystalline cellulose and cellulose gum constituting the emulsion stabilizer is preferably 10 to 20:80 to 90.
본 발명에 있어서, 벌킹제는 피부를 보호하고, 피부 진정 및 피지 관리효과를 위한 것으로서, 카올린, 티타늄디옥사이드, 징크, 피브이피, 실리카 등을 예시할 수 있으나 이에 한정되는 것은 아니다.In the present invention, the bulking agent is for protecting the skin, soothing the skin, and controlling sebum, and examples include kaolin, titanium dioxide, zinc, PV, silica, etc., but is not limited thereto.
전체 조성물중 벌킹제는 0.1~30중량%, 바람직하게는 10~18중량% 사용할 수 있다. 상기 벌킹제가 0.1중량% 미만인 경우에는 수분증발이 심화되고 사용시 건조되는 속도가 현저하게 저하되는 문제가 있고, 30중량%를 초과할 경우에는 분산이 어렵고 사용감 및 발림성이 좋지 않으며 충전시 점도가 높아 제형 형성에 문제가 있다.The bulking agent may be used in an amount of 0.1 to 30% by weight, preferably 10 to 18% by weight, in the total composition. If the bulking agent is less than 0.1% by weight, moisture evaporation intensifies and the drying speed is significantly reduced when used. If it exceeds 30% by weight, dispersion is difficult, the feeling of use and spreadability are poor, and the viscosity is high when filling the formulation. There is a problem with formation.
본 발명에 있어서, 유상부는 에스테르계 오일, 탄화수소계 오일, 식물성 오일 등을 예시할 수 있다. In the present invention, the oil phase may include ester oil, hydrocarbon oil, vegetable oil, etc.
상기 에스테르계 오일로는 세틸 에틸헥사노에이트(Cetyl Ethylhexanoate), 이소세틸 에틸헥사노에이트(Isocetyl Ethylhexanoate), 이소세틸 미리스테이트(Isocetyl myristate), 이소프로필 미리스테이트(Isopropyl myristate), 네오펜틸 글리콜 디카프레이트(Neopentyl glycol dicaprate), 헥실 라우레이트(Hexyl laurate), 트리에틸헥사노인(Triethylhexanoin), 펜타에리트리틸 테트라옥타노에이트(Pentaerythrityl tetraoctanonate), 에틸헥실 팔미테이트(Ethylhexyl palmitate), 이소노닐 이소노나노에이트(Isononyl isononanoate) 등을 예시할 수 있고, 상기 탄화수소계 오일로는 유동파라핀, 바세린, 이소파라핀류 등의 석유계 오일, 하이드로제네이티드폴리데센, 합성 스쿠알란, 폴리부텐 등의 합성계 오일, 식물성 스쿠알렌 등의 식물계 오일을 예시할 수 있다. 상기 식물성 오일로는 올리브유(Oliver oil), 메도폼유(Medowfoam oil), 로즈힙오일(Rosehip oil), 아보카도유(Avocado oil), 동백유(Camellia oil), 마카데미아너트오일 (Macademia nut oil), 피마자유(Caster oil), 호호바유(Jojoba oil), 코코넛유(coconut oil), 팜오일(palm oil) 및 이들로부터 분리된 화합물 예를들면 카프릴릭/카프릭트라이글리세라이드 등을 예시할 수 있으나 이에 한정되는 것은 아니다. The ester oils include cetyl ethylhexanoate, isocetyl ethylhexanoate, isocetyl myristate, isopropyl myristate, and neopentyl glycol dicaprate. (Neopentyl glycol dicaprate), Hexyl laurate, Triethylhexanoin, Pentaerythrityl tetraoctanoate, Ethylhexyl palmitate, Isononyl Isononanoate (Isononyl isononanoate), etc. can be exemplified, and the hydrocarbon oils include petroleum oils such as liquid paraffin, vaseline, and isoparaffins, synthetic oils such as hydrogenated polydecene, synthetic squalane, and polybutene, and vegetable squalene, etc. Examples include vegetable oils. The vegetable oils include olive oil, meadowfoam oil, rosehip oil, avocado oil, camellia oil, macademia nut oil, and pima. Examples include caster oil, jojoba oil, coconut oil, palm oil, and compounds isolated from these, such as caprylic/capric triglyceride. It is not limited to this.
상기 유상부는 전체 조성물중 1~30중량%, 바람직하게는 1~10중량% 사용할 수 있다. 상기 유상부의 함량이 1중량% 미만인 경우에는 용매로서의 역할이 어려우며, 제품 사용시 수분 보유 효과가 떨어지는 문제가 있으며, 30중량%를 초과할 경우에는 정제수의 함량이 상대적으로 부족하여 유화가 되지 않고 분리가 되며 필요이상의 오일 함량으로 인해 피부 트러블이 생길 수 있는 문제가 있다. The oil phase part can be used in an amount of 1 to 30% by weight, preferably 1 to 10% by weight, of the total composition. If the content of the oil phase is less than 1% by weight, it is difficult to act as a solvent, and there is a problem of poor water retention effect when using the product. If it exceeds 30% by weight, the content of purified water is relatively insufficient, so emulsification does not occur and separation is difficult. There is a problem that skin problems may occur due to excessive oil content.
본 발명에 사용되는 고형화제인 소듐스테아레이트는 pH가 높기 때문에 제형을 안정화시키기 위해서는 pH 조절제를 이용하여, 조성물의 pH를 7.0~9.0으로 조절하는 것이 필요하다. 따라서 본 발명에서는 살리실릭애씨드, 소듐시트레이트 및 소듐클로라이드 혼합물을 pH 조절제로 사용하는 것을 특징으로 한다. 상기 pH 조절제는 전체 조성물중 1~10중량%, 바람직하게는 3~6중량% 사용할 수 있다. 상기 pH 조절제의 함량이 1중량% 미만이거나 10중량%를 초과할 경우에는 고형의 제형이 무너져 제품의 안정성의 문제가 생기거나 피부 자극도가 높아져 제품의 안전성의 문제가 생길 뿐만 아니라 경도가 너무 높아져 발림성이 현저하게 나빠질 수 있다.. Since sodium stearate, a solidifying agent used in the present invention, has a high pH, it is necessary to adjust the pH of the composition to 7.0 to 9.0 using a pH adjuster to stabilize the formulation. Therefore, the present invention is characterized by using a mixture of salicylic acid, sodium citrate and sodium chloride as a pH adjuster. The pH adjuster can be used in an amount of 1 to 10% by weight, preferably 3 to 6% by weight, of the total composition. If the content of the pH regulator is less than 1% by weight or more than 10% by weight, the solid formulation will break down, causing a problem with the stability of the product, or increasing skin irritation, which will not only cause a problem with the safety of the product, but also cause the hardness to increase too much. Spreadability may deteriorate significantly.
또한, 상기 pH 조절제를 구성하는 살리실릭애씨드, 소듐시트레이트 및 소듐클로라이드의 혼합비(중량%)는 6.0~7.2 : 4.5~5.4 : 89.5~87.4인 것을 특징으로 한다. 상기 pH 조절제를 구성하는 3개의 성분중 1개라도 누락되거나 혼합비를 벗어날 경우에는 고온에서 제형이 무너지거나 스웨팅 현상, 피부자극이 발생되는 문제점이 있다.In addition, the mixing ratio (% by weight) of salicylic acid, sodium citrate, and sodium chloride that constitutes the pH adjuster is 6.0 to 7.2: 4.5 to 5.4: 89.5 to 87.4. If even one of the three ingredients constituting the pH adjuster is missing or out of the mixing ratio, there is a problem in that the formulation collapses at high temperatures, sweating phenomenon, or skin irritation occurs.
본 발명에 있어서, 수상부는 정제수 및 보습제를 포함 할 수 있다. 보습제는 전체 조성물중 0.1중량%~30%중량% 사용할 수 있으며, 정제수는 소듐스테아레이트, 유상 경도 형성제, 수상 경도 형성제, 유화안정제, 벌킹제, 유상부, pH 조절제의 함량에 따라 전체 조성물이 100중량%가 되는 범위내에서 자유롭게 사용할 수 있다.In the present invention, the water phase may include purified water and a moisturizer. Moisturizers can be used from 0.1% to 30% by weight of the total composition, and purified water varies depending on the content of sodium stearate, oil phase hardness former, water phase hardness former, emulsion stabilizer, bulking agent, oil phase, and pH adjuster. It can be freely used within the range of 100% by weight.
상기 보습제로는 메틸프로판다이올, 부틸렌글라이콜, 글리세린, 프로필렌글라이콜, 에틸헥실글리세린, 1,2-헥산다이올, 솔비톨, 디프로필렌글라이콜, 히알루론산 등을 예시할 수 있으나 이에 한정되는 것은 아니다.Examples of the moisturizing agent include methylpropanediol, butylene glycol, glycerin, propylene glycol, ethylhexylglycerin, 1,2-hexanediol, sorbitol, dipropylene glycol, hyaluronic acid, etc. It is not limited.
또한, 본 발명에 따른 수중유형 유화 스틱형 클레이 마스크 화장료 조성물은 자극 완화제, 알코올류, 스킨 컨디셔닝제, 보존제, 착색제, 착향제, 분말제, 금속이온봉쇄제 및 미용영양제 등의 첨가제를 필요에 따라 추가로 포함할 수 있다. In addition, the oil-in-water emulsified stick-type clay mask cosmetic composition according to the present invention may contain additives such as irritation relievers, alcohols, skin conditioning agents, preservatives, colorants, flavoring agents, powders, metal ion sequestrants, and cosmetic nutrients as needed. Additional information may be included.
상기 스킨 컨디셔닝제로는 나이아신아마이드, 금속이온봉쇄제로는 다이소듐이디티에이, 자극완화제로는 모란뿌리 추출물, 마치현 추출물, 병풀 추출물 등을 예시할 수 있고, 미용영양제로는 아데노신, 비타민 C 유도체 등을 예시할 수 있으나 이에 한정되는 것은 아니다.Examples of the skin conditioning agent include niacinamide, metal ion sequestrants include disodium EDTA, irritant relievers include peony root extract, portulaca quince extract, and centella asiatica extract, and cosmetic nutrients include adenosine and vitamin C derivatives. Examples can be given, but are not limited to these.
본 발명은 다른 관점에서, 수중유형 유화 스틱형 클레이 마스크 화장료 조성물로 제조된 클레이 마스크용 수중유형 유화 스틱에 관한 것이다.From another perspective, the present invention relates to an oil-in-water emulsion stick for a clay mask made from an oil-in-water emulsion stick type clay mask cosmetic composition.
본 발명의 클레이 마스크용 수중유형 유화 스틱은 보존 경도 안정도가 높고, 발림성과 보습력 및 피부 안정성이 우수한 장점이 있다.The oil-in-water emulsion stick for clay masks of the present invention has the advantages of high storage hardness and stability, and excellent spreadability, moisturizing power, and skin stability.
[실시예][Example]
이하, 실시예를 통하여 본 발명을 더욱 상세히 설명하고자 한다. 이들 실시예는 오로지 본 발명을 예시하기 위한 것으로, 본 발명의 범위가 이들 실시예에 의해 제한되는 것으로 해석되지 않는 것은 당업계에서 통상의 지식을 가진 자에게 있어서 자명할 것이다. Hereinafter, the present invention will be described in more detail through examples. These examples are only for illustrating the present invention, and it will be obvious to those skilled in the art that the scope of the present invention should not be construed as limited by these examples.
실시예 1∼3 및 비교예 1~6: 수분 스틱형 자외선 차단용 화장료의 제조Examples 1 to 3 and Comparative Examples 1 to 6: Preparation of moisture stick-type UV blocking cosmetic
하기 표 1에 나타낸 성분과 조성에 따라, 수상비이커에 마이크로크리스탈린셀룰로오스, 셀룰로오스검 및 피브이피를 70℃로 가열한 정제수에 투입하여 10분간 호모믹싱(homomixing)하여 균일하게 분산시킨 후 다시 수상 비이커를 90℃까지 가열하여 소듐스테아레이트, 살리실릭애씨드, 소듐시트레이트, 소듐클로라이드를 투입하여 100rpm으로 서서히 패들믹서를 이용해 용해 및 혼합하였다. 완전히 용해 시킨 후 메틸프로판다이올, 부틸렌글라이콜, 1,2-헥산다이올, 다이소듐이디티에이, 모란뿌리추출물(제조사 : radiant), 다이스테아레스-100 IPDI 및 정제수를 투입하면서 믹서를 100rpm으로 하여 교반하였다. 유상비이커에 카프릴릭/카프릭트라이글리세라이드, 폴리에틸렌, 파란핀 및 마이크로크리스탈린왁스를 투입하고 90℃로 가열하여 완전히 용해 시켰다. 다음으로 수상 비이커의 내용물에 유상비이커의 내용물을 서서히 투입하면서 100rpm 이상, 5분간 호모믹싱(homomixing)하여 균일하게 혼합하였다. 이후 카올린, 다이아이소스테아릴말레이트, 티아이오투, 실리카를 투입하여 100rpm 이상 5분간 호모믹싱(homomixing) 하였다. 그리고 완전히 용해 분산된 것을 확인한 후 실온까지 냉각시켜 고형화된 클레이 마스크 화장료를 제조하였다. According to the ingredients and composition shown in Table 1 below, microcrystalline cellulose, cellulose gum, and PVP were added to purified water heated to 70°C in an aqueous beaker, homomixed for 10 minutes to uniformly disperse, and then placed back in the aqueous beaker. was heated to 90°C, sodium stearate, salicylic acid, sodium citrate, and sodium chloride were added and slowly dissolved and mixed using a paddle mixer at 100 rpm. After completely dissolving, add methyl propanediol, butylene glycol, 1,2-hexanediol, disodium EDTA, peony root extract (manufacturer: radiant), Disteareth-100 IPDI and purified water while using a mixer. It was stirred at 100 rpm. Caprylic/capric triglyceride, polyethylene, blue pin, and microcrystalline wax were added to an oil beaker and heated to 90°C to completely dissolve. Next, the contents of the oil phase beaker were slowly added to the contents of the water phase beaker and mixed uniformly by homomixing at 100 rpm or more for 5 minutes. Afterwards, kaolin, diisostearyl maleate, thio2, and silica were added and homomixed at 100 rpm or more for 5 minutes. After confirming that it was completely dissolved and dispersed, it was cooled to room temperature to prepare a solidified clay mask cosmetic.
안정제oil paint
stabilizator
시험예 1 : 경도 테스트Test Example 1: Hardness test
상기 실시예 1~3 및 비교예 1~3 및 6의 화장료 조성물의 표면 경도를 Rheometer 기기를 통해 측정한 결과를 하기 표 2에 나타내었다. 경도 측정은 제조후 25℃에서 하루동안 보관한 후에 실시하였으며, 15mm 직경의 어댑터를 사용하여 5cm/min의 속도로 1cm 깊이로 측정하였다. The results of measuring the surface hardness of the cosmetic compositions of Examples 1 to 3 and Comparative Examples 1 to 3 and 6 using a Rheometer device are shown in Table 2 below. Hardness was measured after manufacturing and stored at 25°C for one day, and was measured at a depth of 1 cm at a speed of 5 cm/min using a 15 mm diameter adapter.
시험예 2 : 안정성 평가Test Example 2: Stability evaluation
안정성 평가는 실온, 35℃, 45℃에서 단기간으로 2일, 5일, 10일, 20일과 장기간으로 3개월까지 보관한 후 제품의 상태를 관찰하여 제품의 안정성을 평가하였다. 아래 평가기준으로 스틱 제형 시료 표면의 발한 현상을 육안 관찰하여 안정성을 평가하고, 그 결과를 표 3에 나타내었다. 상태가 매우 양호하면 ◎, 양호하면 ○, 보통이면 △, 불량하면 X로 표시하였다. The stability of the product was evaluated by observing the condition of the product after storing it at room temperature, 35°C, 45°C for a short period of 2 days, 5 days, 10 days, 20 days, and for a long period of up to 3 months. Stability was evaluated by visually observing the sweating phenomenon on the surface of the stick formulation sample using the evaluation criteria below, and the results are shown in Table 3. If the condition is very good, it is marked as ◎, if it is good, it is marked as ○, if it is in average condition, it is marked as △, and if it is poor, it is marked as X.
상기 표 3에서 나타낸 바와 같이, 적정함량의 유화안정제를 혼합하여 사용 처방한 화장료가 안정성에 있어서 매우 양호한 결과를 나타냈다.As shown in Table 3, cosmetics formulated by mixing an appropriate amount of emulsion stabilizer showed very good results in terms of stability.
시험예 3 : 제형 사용감 평가Test Example 3: Evaluation of formulation usability
상기 실시예 및 비교예에서 제조된 화장료를 사용하여 제품을 제조한 후, 20-50세 여성 100명의 패널이 관능 평가로 O/W 수분 머드 스틱 제형의 수분감, 사용감 및 클렌징력 정도를 판정하였다. 이때, 사용감 평가 점수는 매우 우수하면 5점, 우수하면 3점, 보통이면 0점, 나쁜 경우에는 -3점, 매우 나쁜 경우에는 -5점으로 표시하였다. 각 개인별의 평가 점수에 대해 아래의 식과 같은 수식에 의해 평점을 산출하여 하기 표 4에 최종 결과를 나타내었다.After manufacturing the product using the cosmetics prepared in the above Examples and Comparative Examples, a panel of 100 women aged 20-50 years evaluated the moisture, feeling of use, and cleansing power of the O/W moisture mud stick formulation through sensory evaluation. At this time, the usability evaluation score was expressed as 5 points for very good, 3 points for excellent, 0 points for average, -3 points for bad, and -5 points for very bad. For each individual's evaluation score, the score was calculated using the formula below, and the final results are shown in Table 4 below.
상기 표 4에 나타낸 바와 같이 실시예 1~3이 모든 항목에서 우수한 것으로 평가 되었으며, 구체적으로 카올린 및 기타 파우더 원료의 분산이 더 잘된 경우 피지 흡착 효과가 우수하고 세정력도 좋아지는 것을 알 수 있었다. 이러한 경향은 유화안정제와 유상성분 및 유상 경도 형성제의 함유량이나 함유 여부에 따라 큰 차이를 보였다. 비교예 1의 경우에는 유화안정제가 포함되지 않으므로 인해 분산 안정도가 떨어져 발림성이나 피지 흡착능이 떨어진 것으로 평가되었고, 비교예 2의 경우에는 과량의 유화안정제가 포함되어 오히려 분산능이 떨어지며 수분감, 발림성 및 클렌징력에도 나쁜 평가를 받았다. 비교예 3은 과량의 유상 경도 형성제로 인해 경도가 너무 딱딱하여 발림성이 현저히 떨어졌고, 비교예 4의 경우에는 유상경도형성제가 포함되지 않아 경도를 형성하지 못하여 스틱제형으로 만들지 못하여 평가하지 못하였고, 비교예 5의 경우에도 유상경도형성제의 함량이 부족하여 스틱제형으로 구현이 불가능하였다. 비교예 6은 유상경도형성제에서 파라핀의 함량이 높고 폴리에틸렌의 함량이 낮을 경우 끈적이는 사용감과 높은 경도로 인해 각 항목인 수분감, 발림성, 피지흡착능 모두 현저하게 낮은 점수를 받았다.As shown in Table 4, Examples 1 to 3 were evaluated as excellent in all items. Specifically, it was found that when kaolin and other powder raw materials were better dispersed, the sebum adsorption effect was excellent and the cleaning power was also improved. This trend showed significant differences depending on the content or presence of emulsion stabilizers, oil phase components, and oil phase hardness formers. In the case of Comparative Example 1, since the emulsion stabilizer was not included, the dispersion stability was poor and the spreadability and sebum adsorption ability were evaluated to be poor. In the case of Comparative Example 2, the dispersion ability was poor because an excessive amount of the emulsion stabilizer was included, and the moisture, spreadability, and cleansing power were evaluated to be poor. It also received bad reviews. In Comparative Example 3, the hardness was too hard due to the excessive amount of oily hardness former, and the spreadability was significantly poor. In Comparative Example 4, the oily hardness former was not included and hardness could not be formed, so it was not evaluated because it could not be made into a stick formulation. Even in the case of Comparative Example 5, the content of the oil phase hardness former was insufficient, making it impossible to implement it in a stick formulation. In Comparative Example 6, when the oil hardness former had a high paraffin content and a low polyethylene content, it received significantly low scores in each item of moisture, spreadability, and sebum adsorption due to a sticky feeling and high hardness.
이상으로 본 발명 내용의 특정한 부분을 상세히 기술하였는 바, 당업계의 통상의 지식을 가진 자에게 있어서 이러한 구체적 기술은 단지 바람직한 실시 양태일 뿐이며, 이에 의해 본 발명의 범위가 제한되는 것이 아닌 점은 명백할 것이다. 따라서, 본 발명의 실질적인 범위는 첨부된 청구항들과 그것들의 등가물에 의하여 정의된다고 할 것이다.As the specific parts of the present invention have been described in detail above, it is clear to those skilled in the art that these specific techniques are merely preferred embodiments and do not limit the scope of the present invention. will be. Accordingly, the substantial scope of the present invention will be defined by the appended claims and their equivalents.
Claims (11)
In the oil-in-water emulsion stick type clay mask cosmetic composition comprising sodium stearate, an oil phase hardness former, an aqueous phase hardness former, an emulsion stabilizer, a bulking agent, an oil phase, a pH adjuster, and an aqueous phase, the oil phase hardness former is polyethylene wax, An oil-in-water emulsified stick-type clay mask cosmetic composition characterized in that it is paraffin and micro-crystalline wax, and the emulsion stabilizer is micro-crystalline cellulose and cellulose gum.
The method of claim 1, comprising 1 to 10% by weight of sodium stearate, 1 to 5% by weight of oil phase hardness former, 0.1 to 10% by weight of water phase hardness former, 0.3 to 5% by weight of emulsion stabilizer, and 0.1 to 30% by weight of bulking agent. , an oil-in-water emulsified stick-type clay mask cosmetic composition comprising 1 to 30% by weight of the oil phase, 1 to 10% by weight of the pH adjuster, and the remaining amount of the aqueous phase.
The oil-in-water emulsification stick according to claim 1, wherein the mixing ratio (% by weight) of polyethylene wax, paraffin, and microcrystalline wax constituting the oil phase hardness former is 40~60:35~55:2~8. Type clay mask cosmetic composition.
The oil-in-water emulsified stick-type clay mask cosmetic composition according to claim 1, wherein the water hardness former is disteareth-100 IPDI.
The oil-in-water emulsion stick type clay mask cosmetic composition according to claim 1, wherein the mixing ratio (% by weight) of microcrystalline cellulose and cellulose gum constituting the emulsion stabilizer is 10-20:80-90.
The oil-in-water emulsified stick-type clay mask cosmetic composition according to claim 1, wherein the bulking agent is one or more selected from the group consisting of kaolin, titanium dioxide, zinc, PVP, and silica.
The oil-in-water emulsified stick-type clay mask cosmetic composition according to claim 1, wherein the oil phase is at least one selected from the group consisting of ester oils, hydrocarbon oils, and vegetable oils.
The oil-in-water emulsified stick-type clay mask cosmetic composition according to claim 1, wherein the pH adjuster is salicylic acid, sodium citrate, and sodium chloride.
The oil-in-water emulsified stick-type clay mask cosmetic composition according to claim 1, wherein the aqueous phase is at least one selected from the group consisting of purified water and moisturizer.
The method of claim 1, wherein the oil-in-water emulsified stick type clay mask cosmetic composition is selected from the group consisting of irritation relievers, alcohols, skin conditioning agents, preservatives, colorants, flavoring agents, powders, metal ion sequestrants, and cosmetic nutrients. An oil-in-water emulsified stick-type clay mask cosmetic composition, characterized in that it additionally comprises one or more types.
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