KR20210142677A - 촉매 파라핀 탈수소화 및 촉매 회수를 위한 방법 - Google Patents

촉매 파라핀 탈수소화 및 촉매 회수를 위한 방법 Download PDF

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Publication number
KR20210142677A
KR20210142677A KR1020217033232A KR20217033232A KR20210142677A KR 20210142677 A KR20210142677 A KR 20210142677A KR 1020217033232 A KR1020217033232 A KR 1020217033232A KR 20217033232 A KR20217033232 A KR 20217033232A KR 20210142677 A KR20210142677 A KR 20210142677A
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South Korea
Prior art keywords
metal oxide
effluent stream
reactor
oxide catalyst
catalyst
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Korean (ko)
Inventor
마이클 제이 톨맨
마노즈 나그베카르
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켈로그 브라운 앤드 루트 엘엘씨
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/11—Purification; Separation; Use of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G55/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process
    • C10G55/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only
    • C10G55/06—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one catalytic cracking step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/04—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes
    • C10G70/048—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes by liquid-liquid extraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/14—Packed scrubbers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020217033232A 2019-03-21 2020-03-19 촉매 파라핀 탈수소화 및 촉매 회수를 위한 방법 Ceased KR20210142677A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201962821672P 2019-03-21 2019-03-21
US62/821,672 2019-03-21
PCT/US2020/023627 WO2020191192A1 (en) 2019-03-21 2020-03-19 Processes for catalytic paraffin dehydrogenation and catalyst recovery

Publications (1)

Publication Number Publication Date
KR20210142677A true KR20210142677A (ko) 2021-11-25

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KR1020217033232A Ceased KR20210142677A (ko) 2019-03-21 2020-03-19 촉매 파라핀 탈수소화 및 촉매 회수를 위한 방법

Country Status (7)

Country Link
US (1) US20200299212A1 (https=)
EP (1) EP3941893A4 (https=)
JP (1) JP2022526905A (https=)
KR (1) KR20210142677A (https=)
CN (1) CN113710633A (https=)
SG (1) SG11202110419TA (https=)
WO (1) WO2020191192A1 (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220031025A (ko) * 2019-06-28 2022-03-11 다우 글로벌 테크놀로지스 엘엘씨 냉각된 생성물의 재순환 켄치 스트림으로서의 사용을 포함하는 경질 올레핀을 형성하는 방법
US11117108B2 (en) 2019-09-13 2021-09-14 Kellogg Brown & Root Llc Use of a fuel oil wash to remove catalyst from a fluidized-bed propane dehydrogenation reactor effluent
ES3053058T3 (en) * 2021-08-11 2026-01-19 Exxonmobil Chemical Patents Inc Processes for dehydrogenating alkanes and alkyl aromatic hydrocarbons
CN117794887A (zh) * 2021-08-11 2024-03-29 埃克森美孚化学专利公司 烷烃和烷基芳族烃的脱氢方法
WO2023212497A1 (en) * 2022-04-25 2023-11-02 Kellogg Brown & Root Llc Processes for catalytic paraffin dehydrogenation and catalyst recovery
CN117019022B (zh) * 2023-08-09 2026-02-27 上海润和盛建设备科技有限公司 一种移动床低碳烷烃脱氢系统

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB815332A (en) * 1955-04-25 1959-06-24 Exxon Research Engineering Co Dehydrogenation of hydrocarbons
US5254788A (en) * 1991-09-10 1993-10-19 Stone And Webster Engineering Corporation Process for the production of olefins from light paraffins
JP3678335B2 (ja) * 1998-05-18 2005-08-03 株式会社日本触媒 低級アルカン酸化脱水素用触媒およびオレフィンの製造方法
US20030065235A1 (en) * 2001-09-24 2003-04-03 Allison Joe D. Oxidative dehydrogenation of alkanes to olefins using an oxide surface
US7011740B2 (en) * 2002-10-10 2006-03-14 Kellogg Brown & Root, Inc. Catalyst recovery from light olefin FCC effluent
EP2097163A4 (en) * 2006-12-28 2012-05-23 Uop Llc FLUIDIZED BED REACTOR WITH BACK MIXING FOR DEHYDROGENATION OF LIGHT PARAFFINS
US20090325791A1 (en) * 2008-06-27 2009-12-31 Wei Pan Hydrocarbon Dehydrogenation with Zirconia
US8653317B2 (en) * 2009-03-19 2014-02-18 Dow Global Technologies Llc Dehydrogenation process and catalyst
US9150465B2 (en) * 2010-09-21 2015-10-06 Uop Llc Integration of cyclic dehydrogenation process with FCC for dehydrogenation of refinery paraffins
US9963407B2 (en) * 2013-06-18 2018-05-08 Uop Llc Fluidized catalyst circulation reactor for paraffin oxydative dehydrogenation
CA2867731C (en) * 2014-10-15 2022-08-30 Nova Chemicals Corporation High conversion and selectivity odh process
CA3114440A1 (en) * 2018-09-28 2020-04-02 Exelus, Inc. Improved mixed metal oxide catalyst useful for paraffin dehydrogenation

Also Published As

Publication number Publication date
JP2022526905A (ja) 2022-05-27
SG11202110419TA (en) 2021-10-28
CN113710633A (zh) 2021-11-26
US20200299212A1 (en) 2020-09-24
EP3941893A4 (en) 2023-01-11
EP3941893A1 (en) 2022-01-26
WO2020191192A1 (en) 2020-09-24

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