KR20210137498A - 루테늄 촉진제 촉매 조성물 - Google Patents

루테늄 촉진제 촉매 조성물 Download PDF

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KR20210137498A
KR20210137498A KR1020217031900A KR20217031900A KR20210137498A KR 20210137498 A KR20210137498 A KR 20210137498A KR 1020217031900 A KR1020217031900 A KR 1020217031900A KR 20217031900 A KR20217031900 A KR 20217031900A KR 20210137498 A KR20210137498 A KR 20210137498A
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species
catalyst
catalyst composition
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ruthenium
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사르브짓 싱 기디
다니엘 프랜시스 케네디
아니루다 프라모드 쿨카르니
데이비드 알렉산더
코아 팜
개리 마크 폴
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커먼웰쓰 사이언티픽 앤 인더스트리알 리서치 오거니제이션
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00Ammonia; Compounds thereof
    • C01C1/02Preparation, purification or separation of ammonia
    • C01C1/04Preparation of ammonia by synthesis
    • C01C1/0405Preparation of ammonia by synthesis from N2 and H2 in presence of a catalyst
    • C01C1/0411Preparation of ammonia by synthesis from N2 and H2 in presence of a catalyst characterised by the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/03Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B01J29/0316Mesoporous materials not having base exchange properties, e.g. Si-MCM-41 containing iron group metals, noble metals or copper
    • B01J29/0325Noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14Dynamic membranes
    • B01D69/141Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/145Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing embedded catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D71/0221Group 4 or 5 metals
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    • B01D71/0223Group 8, 9 or 10 metals
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    • B01D71/0223Group 8, 9 or 10 metals
    • B01D71/02231Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01D71/02Inorganic material
    • B01D71/022Metals
    • B01D71/0223Group 8, 9 or 10 metals
    • B01D71/02232Nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/2475Membrane reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10Magnesium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/462Ruthenium
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    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
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    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • B01D2257/102Nitrogen
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    • B01D2257/108Hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01D2325/00Details relating to properties of membranes
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Catalysts (AREA)
KR1020217031900A 2019-03-05 2020-03-05 루테늄 촉진제 촉매 조성물 Withdrawn KR20210137498A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
AU2019900709 2019-03-05
AU2019900709A AU2019900709A0 (en) 2019-03-05 Ruthenium catalyst compositions and membranes comprising the same
PCT/AU2020/050206 WO2020176944A1 (en) 2019-03-05 2020-03-05 Ruthenium promoter catalyst compositions

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KR20210137498A true KR20210137498A (ko) 2021-11-17

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US (1) US20210395101A1 (https=)
EP (1) EP3934804A4 (https=)
JP (1) JP2022522874A (https=)
KR (1) KR20210137498A (https=)
CN (1) CN113747972A (https=)
AU (1) AU2020230860B2 (https=)
CA (1) CA3132213A1 (https=)
WO (1) WO2020176944A1 (https=)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102475191B1 (ko) * 2020-12-09 2022-12-06 희성촉매 주식회사 루테늄 복합체가 포함되는 NOx 저장 및 환원 촉매 물품 제조방법 및 이를 포함하는 배기처리 시스템
CN114618481A (zh) * 2020-12-10 2022-06-14 中国科学院大连化学物理研究所 一种合成氨催化剂及其制备方法、应用
US11994061B2 (en) 2021-05-14 2024-05-28 Amogy Inc. Methods for reforming ammonia
US11724245B2 (en) 2021-08-13 2023-08-15 Amogy Inc. Integrated heat exchanger reactors for renewable fuel delivery systems
JP2024521417A (ja) 2021-06-11 2024-05-31 アモジー インコーポレイテッド アンモニアを処理するためのシステムおよび方法
US11539063B1 (en) 2021-08-17 2022-12-27 Amogy Inc. Systems and methods for processing hydrogen
CN114789053A (zh) * 2022-05-06 2022-07-26 福州大学 一种钌基温和合成氨催化剂及其制备方法和应用
US11834334B1 (en) 2022-10-06 2023-12-05 Amogy Inc. Systems and methods of processing ammonia
US11866328B1 (en) 2022-10-21 2024-01-09 Amogy Inc. Systems and methods for processing ammonia
US11795055B1 (en) 2022-10-21 2023-10-24 Amogy Inc. Systems and methods for processing ammonia
KR20260021812A (ko) 2023-06-26 2026-02-13 아모지 인크. 다공성 재료를 처리하기 위한 조성물 및 방법
WO2025236043A1 (en) * 2024-05-15 2025-11-20 Commonwealth Scientific And Industrial Research Organisation Method and reaction system for ammonia synthesis

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1019680B (it) * 1974-07-01 1977-11-30 Inst Neftechimicheskogo Sintez Metodo per la produzione di ci cloolefine
US4714692A (en) * 1986-04-03 1987-12-22 Uop Inc. Microemulsion impregnated catalyst composite and use thereof in a synthesis gas conversion process
US6235677B1 (en) * 1998-08-20 2001-05-22 Conoco Inc. Fischer-Tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids
DE10050709A1 (de) * 2000-10-13 2002-04-25 Basf Ag Verfahren zur Hydrierung von unsubstituierten oder alkylsubstituierten Aromaten unter Verwendung eines Katalysators mit einem strukturierten oder monolithischen Träger
CN100448530C (zh) * 2007-05-23 2009-01-07 浙江工业大学 一种复合氧化物负载钌基氨合成催化剂及其制备方法
CN102921413A (zh) * 2011-08-12 2013-02-13 中国石油天然气股份有限公司 一种钌基氨合成催化剂及制备方法
AU2012324802B2 (en) * 2011-10-21 2017-01-12 Igtl Technology Ltd Methods of preparation and forming supported active metal catalysts and precursors
CA2920507C (en) * 2013-08-14 2021-07-13 Commonwealth Scientific And Industrial Research Organisation Processes utilising selectively permeable membranes
CN105692653A (zh) * 2014-11-28 2016-06-22 中国科学院大连化学物理研究所 制备氨的系统及方法
US10159969B2 (en) * 2015-03-31 2018-12-25 Colorado School Of Mines Ammonia synthesis at moderate conditions using hydrogen permeable membrane reactors
EP3351509B1 (en) * 2015-09-15 2021-09-29 Tokyo Institute of Technology Laves phase intermetallic compound, catalyst using intermetallic compound, and method for producing ammonia
WO2017104021A1 (ja) * 2015-12-16 2017-06-22 日揮株式会社 アンモニアの製造方法
WO2018104455A2 (en) * 2016-12-08 2018-06-14 Technische Universiteit Eindhoven Advanced double skin membranes for membrane reactors
CN109126787B (zh) * 2017-06-16 2021-08-03 中国科学院大连化学物理研究所 一种用于氨合成的稀土金属氧化物负载钌催化剂及其应用

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JP2022522874A (ja) 2022-04-20
AU2020230860A1 (en) 2021-09-30
EP3934804A1 (en) 2022-01-12
WO2020176944A1 (en) 2020-09-10
AU2020230860B2 (en) 2025-11-06
EP3934804A4 (en) 2022-12-07
CA3132213A1 (en) 2020-09-10
CN113747972A (zh) 2021-12-03

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