KR20180057628A - 황화수소의 선택적 제거를 위한 흡수제 - Google Patents

황화수소의 선택적 제거를 위한 흡수제 Download PDF

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Publication number
KR20180057628A
KR20180057628A KR1020187008418A KR20187008418A KR20180057628A KR 20180057628 A KR20180057628 A KR 20180057628A KR 1020187008418 A KR1020187008418 A KR 1020187008418A KR 20187008418 A KR20187008418 A KR 20187008418A KR 20180057628 A KR20180057628 A KR 20180057628A
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KR
South Korea
Prior art keywords
acid
alkyl
absorbent
formula
hydroxyalkyl
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KR1020187008418A
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English (en)
Korean (ko)
Inventor
게랄트 포르베르크
랄프 노츠
토마스 인그람
게오르크 시데르
토르스텐 카츠
크리스티안 그뤼난게르
페테르 데글만
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바스프 에스이
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493Selection of liquid materials for use as absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425Regeneration of liquid absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1468Removing hydrogen sulfide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/103Sulfur containing contaminants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20405Monoamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/2041Diamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20415Tri- or polyamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20426Secondary amines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20431Tertiary amines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20478Alkanolamines
    • B01D2252/20484Alkanolamines with one hydroxyl group
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • B01D2252/20478Alkanolamines
    • B01D2252/20489Alkanolamines with two or more hydroxyl groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50Combinations of absorbents
    • B01D2252/504Mixtures of two or more absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60Additives
    • B01D2252/602Activators, promoting agents, catalytic agents or enzymes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/541Absorption of impurities during preparation or upgrading of a fuel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
KR1020187008418A 2015-09-29 2016-09-28 황화수소의 선택적 제거를 위한 흡수제 Withdrawn KR20180057628A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15187389 2015-09-29
EP15187389.0 2015-09-29
PCT/EP2016/073025 WO2017055304A2 (de) 2015-09-29 2016-09-28 Absorptionsmittel zur selektiven entfernung von schwefelwasserstoff

Publications (1)

Publication Number Publication Date
KR20180057628A true KR20180057628A (ko) 2018-05-30

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020187008418A Withdrawn KR20180057628A (ko) 2015-09-29 2016-09-28 황화수소의 선택적 제거를 위한 흡수제

Country Status (15)

Country Link
US (1) US10617993B2 (enExample)
EP (1) EP3356013B1 (enExample)
JP (1) JP2018531145A (enExample)
KR (1) KR20180057628A (enExample)
CN (1) CN108136316B (enExample)
AU (1) AU2016330797A1 (enExample)
BR (1) BR112018003733A2 (enExample)
CA (1) CA3000037C (enExample)
CO (1) CO2018003666A2 (enExample)
IL (1) IL257668A (enExample)
MX (1) MX2018004010A (enExample)
RU (1) RU2746838C1 (enExample)
SG (1) SG11201801360PA (enExample)
WO (1) WO2017055304A2 (enExample)
ZA (1) ZA201802683B (enExample)

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WO2017182289A1 (de) * 2016-04-18 2017-10-26 Basf Se Vormischung zur herstellung eines absorptionsmittels zur entfernung von sauergasen aus einem fluidstrom
EA036128B1 (ru) 2016-04-25 2020-10-01 Басф Се Способ удаления кислотных газов из потока текучей среды путем применения соединений затрудненных аминов на основе морфолина
MY190751A (en) 2016-08-01 2022-05-12 Basf Se Two-stage method for removing co2 from synthesis gas
ES2877641T3 (es) 2017-02-10 2021-11-17 Basf Se Proceso para la remoción de gases ácidos de una corriente de fluido y los correspondientes usos
EP3619190B1 (en) 2017-05-03 2021-08-04 Basf Se Process for the conversion of ethylene oxide to monoethanolamine and ethylenediamine employing a zeolite
WO2018210738A1 (en) 2017-05-15 2018-11-22 Basf Se Absorbent and process for selectively removing hydrogen sulfide
US11471821B2 (en) * 2020-04-18 2022-10-18 Indian Oil Corporation Limited Process for biogas upgradation
WO2023243592A1 (ja) * 2022-06-13 2023-12-21 旭化成株式会社 ポリカーボネートの製造方法、ジヒドロキシ化合物の回収方法、及びポリカーボネートの製造装置
WO2024180358A1 (en) 2023-02-27 2024-09-06 Totalenergies Onetech Method for selective separation of hydrogen sulfide from a gas mixture
CN116550100A (zh) * 2023-05-30 2023-08-08 江苏太湖新材料控股有限公司 脱硫剂及其制备方法
CN118577100B (zh) * 2024-06-26 2025-01-21 宜兴汉光高新石化有限公司 一种高效复配脱硫脱碳溶剂及其制备方法

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US4101633A (en) 1977-02-14 1978-07-18 Exxon Research & Engineering Co. Process and composition for removing carbon dioxide containing acidic gases from gaseous mixtures
JPS53138403A (en) * 1977-05-10 1978-12-02 Ube Ind Ltd Desulfurization of industrial gases
US4471138A (en) 1982-01-18 1984-09-11 Exxon Research And Engineering Co. Severely sterically hindered secondary aminoether alcohols
DE84943T1 (de) 1982-01-18 1983-11-10 Exxon Research and Engineering Co., 07932 Florham Park, N.J. Sekundaere und tertiaere aminoalkohole.
DE3236600A1 (de) 1982-10-02 1984-04-05 Basf Ag, 6700 Ludwigshafen Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und gegebenenfalls h(pfeil abwaerts)2(pfeil abwaerts)s aus erdgasen
DE3308088A1 (de) 1983-03-08 1984-09-27 Basf Ag, 6700 Ludwigshafen Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und/oder h(pfeil abwaerts)2(pfeil abwaerts)s aus gasen
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JP5659084B2 (ja) * 2011-05-30 2015-01-28 株式会社東芝 酸性ガス吸収剤、酸性ガス除去方法および酸性ガス除去装置
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FR3001157B1 (fr) * 2013-01-24 2018-07-27 Ifp Energies Now Solution absorbante a base d'une amine tertiaire ou encombree et d'un activeur particulier et procede d'elimination de composes acides d'un effluent gazeux
JP2015029987A (ja) * 2013-08-07 2015-02-16 株式会社東芝 酸性ガス吸収剤、酸性ガス除去方法及び酸性ガス除去装置
CN104560252B (zh) * 2013-10-28 2017-02-01 中国石油化工股份有限公司 天然气脱硫脱碳剂
EP2990090A1 (de) * 2014-08-25 2016-03-02 Basf Se Absorptionsmittel zur selektiven Entfernung von Schwefelwasserstoff aus einem Fluidstrom

Also Published As

Publication number Publication date
BR112018003733A2 (pt) 2018-09-25
MX2018004010A (es) 2018-05-23
WO2017055304A2 (de) 2017-04-06
EP3356013B1 (de) 2021-08-04
CN108136316B (zh) 2021-07-23
AU2016330797A1 (en) 2018-03-29
RU2746838C1 (ru) 2021-04-21
EP3356013A2 (de) 2018-08-08
JP2018531145A (ja) 2018-10-25
US20180311611A1 (en) 2018-11-01
US10617993B2 (en) 2020-04-14
CA3000037C (en) 2023-08-01
WO2017055304A3 (de) 2017-05-26
CN108136316A (zh) 2018-06-08
SG11201801360PA (en) 2018-04-27
CO2018003666A2 (es) 2018-08-21
CA3000037A1 (en) 2017-04-06
IL257668A (en) 2018-04-30
ZA201802683B (en) 2019-07-31

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Patent event date: 20180326

Patent event code: PA01051R01D

Comment text: International Patent Application

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PC1203 Withdrawal of no request for examination