KR20180055018A - Light-weight polypropylene resin composition and molded product of vehicle interior material using the same - Google Patents
Light-weight polypropylene resin composition and molded product of vehicle interior material using the same Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/016—Additives defined by their aspect ratio
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
Abstract
Description
A low specific gravity polypropylene resin composition and a molded article for an automobile interior material.
Recently, as interest in the environment and energy has increased, automobile industry has been rapidly required to be lightweight and highly functional due to fuel efficiency improvement and air pollution.
In order to increase comfort when riding, resin or fiber with soft image is mainly used for automobile interior parts. Among the above automobile interior parts, a crash pad is an automobile interior part, also called an instrument panel or a dash board, which is attached to the lower end of the front glass of the driver's seat and has a meter such as a speedometer, meters, and an apparatus for accommodating an air conditioner, a radio, a clock, an ashtray, a small article, and the like. These crash pads are of a type that surrounds a separate surface layer, and a paint and non-paint type.
In the case of the core material of the wrapping type, in recent years, the use of PPF (a composite material containing an inorganic filler added to polypropylene) has been greatly increased in terms of cost reduction and weight reduction. However, It is difficult to reduce the content ratio and it is difficult to achieve thinning and lightening because a thickness exceeding a certain level is required for securing the reliability of the product.
In addition, MuCell method or chemical foaming method has been applied in terms of weight reduction, but problems such as appearance defects and molding are difficult and physical properties are deteriorated.
Another example of weight saving is the use of a glass bubble of a three-dimensional hollow structure (Microsphere), but also a technique to prevent breakage of the glass bubble in processing and a compatibility problem between the glass bubble and the polypropylene resin And it is difficult to make the crash pad more complicated in structure or to be thick in thickness in order to secure the performance of the crash pad product and it is not easy to reduce the weight .
In addition, conventional propylene and glass fiber composite materials are designed to prevent breakage of glass fiber in order to preserve the physical properties, and they are designed by using a direct gate or a crash pad structure with no holes, . However, it is obvious that the conventional composite material has many difficulties in the automotive reliability evaluation items such as the head impact test and the air bag deployment test due to the strong brittleness, and furthermore, the shape of the product The change and deterioration of the physical properties are large, resulting in a serious problem in the final molded product quality.
In addition, the mass production materials described above are often unsatisfactory in the evaluation of volatile organic compounds (VOCs) and odors, and no fundamental solution has been found.
One embodiment of the present invention provides a low specific gravity polypropylene resin composition.
Another embodiment of the present invention provides a molded article for an automobile interior material comprising an injection molded article of the low specific gravity polypropylene resin composition.
In one embodiment of the present invention, the first inorganic filler and the second inorganic filler each include a polypropylene resin, a thermoplastic elastomer, a first inorganic filler, and a second inorganic filler, wherein the first inorganic filler and the second inorganic filler each contain magnesium hydroxide, magnesium oxysulfate, titanium oxide , Potassium oxide, and combinations thereof, wherein the first inorganic filler is a plate-like type and the second inorganic filler is an acicular type.
In another embodiment of the present invention, there is provided a molded article for an automobile interior material comprising an injection molded article of the low specific gravity polypropylene resin composition.
The low specific gravity polypropylene resin composition includes a low specific gravity filler to provide light weight, high mechanical strength and impact resistance, and low dimensional shrinkage and dimensional stability control. In addition, it is possible to reduce the incidence of sharp edges which are a big problem when the product is broken, reduce volatile organic compounds (VOCs), and suppress the generation of odor.
Hereinafter, embodiments of the present invention will be described in detail. However, the present invention is not limited thereto, and the present invention is only defined by the scope of the following claims.
In one embodiment of the present invention, the first inorganic filler and the second inorganic filler each include a polypropylene resin, a thermoplastic elastomer, a first inorganic filler, and a second inorganic filler, wherein the first inorganic filler and the second inorganic filler each contain magnesium hydroxide, magnesium oxysulfate, titanium oxide , Potassium oxide, and combinations thereof, wherein the first inorganic filler is a plate-like type and the second inorganic filler is an acicular type.
The low specific gravity polypropylene resin composition suitably includes a first inorganic filler of a plate-like shape and a second inorganic filler of a needle-like shape having a low specific gravity to give a light weight and excellent mechanical stiffness, impact resistance and dimensional stability, It is possible to reduce the incidence of sharp edges at the time of fracture of the molded article which is an injection product.
Specifically, each of the first inorganic filler and the second inorganic filler contained in the low-specific-gravity polypropylene resin composition is preferably a low-specific-gravity magnesium hydroxide, magnesium oxysulfate, titanium oxide, potassium oxide, A combination thereof, that is, a chemical bond thereof, so that weight reduction and thinning can be imparted.
Further, the low specific gravity polypropylene resin composition includes the first inorganic filler having a plate-like structure and the second inorganic filler having a needle-like structure in combination, thereby providing a lightweight structure, Impact properties can be imparted, and dimensional stability can be imparted through low shrinkage and orientation control.
At this time, the first inorganic filler to the second inorganic filler are mixed at a weight ratio of about 1: 1 to about 1: 2 to give a significantly improved impact resistance with excellent rigidity, and the second inorganic filler, And the dimensional stability can be simultaneously given. Specifically, when the weight ratio of the second inorganic filler to the first inorganic filler is less than the above range, sufficient rigidity can not be imparted. When the weight ratio of the second inorganic filler exceeds the above range, the rigidity is excellent, And dimensional stability problems such as a serious deformation during injection molding may occur.
Specifically, the total content of the first inorganic filler and the second inorganic filler may be about 7 to about 50 parts by weight based on 100 parts by weight of the polypropylene resin. By including the first inorganic filler and the second inorganic filler in the above-mentioned range, excellent stiffness can be imparted to the polypropylene resin, and impact resistance and dimensional stability can be imparted. More specifically, when it is contained in an amount less than the above-mentioned range, the mechanical rigidity is not sufficiently improved, so that the shape of the molded article formed therefrom can be easily deformed during handling, and when it is contained in a content exceeding the above range, And the dispersibility of the first inorganic filler and the second inorganic filler in the composition is deteriorated, and the impact resistance may be lowered.
The first inorganic filler has a thin film shape having a Z-axis length (thickness) smaller than that of a plate-like structure, that is, a cross-sectional area represented by the lengths of the X-axis and the Y-axis. About 0.5 [mu] m to about 2 [mu] m, and an aspect ratio of about 2 to about 4, the major axis diameter / minor axis diameter. The first inorganic filler has a plate-like structure and has an aspect ratio of the above range, so that it has an excellent rigidity effect, improves the flowability of a composition containing the same, facilitates molding, and gives excellent dimensional stability to a molded article during injection molding And it is possible to reduce the incidence of sharp edges at the time of the molding breakage. Specifically, when the aspect ratio of the first inorganic filler is less than the above range, the stiffness and the impact reinforcing effect are significantly reduced. When the aspect ratio is more than the above range, dispersion of the inorganic filler is difficult during injection molding, There may be a problem.
The second inorganic filler may have an acicular shape and may have an aspect ratio of about 5 to about 30 microns in length and an aspect ratio of about 10 to about 30 in average length / average diameter. The second inorganic filler has an acicular shape and has an aspect ratio of the above range. Thus, the second inorganic filler can be reduced in weight by including a substance having a low specific gravity, while at the same time providing a significantly improved rigidity, The index can be prevented from being lowered. Specifically, when the aspect ratio of the second inorganic filler is less than the above range, the stiffness and the impact reinforcing effect are remarkably reduced at the same weight, and when the aspect ratio of the second inorganic filler exceeds the above range, The second inorganic filler may be broken by the pressure at the time of extrusion or injection of the composition, and the physical properties of the second inorganic filler may be lowered.
The low specific gravity polypropylene resin composition is a random copolymer obtained by polymerizing a comonomer selected from the group consisting of homo-polypropylene, propylene, ethylene, butene, pentene, hexene and octene as a base raw material, ethylene- Rubber-blended block copolymers, branched polypropylene, and combinations thereof. ≪ Desc / Clms Page number 7 >
Specifically, the polypropylene resin includes a first ethylene-propylene copolymer resin and a second ethylene propylene copolymer resin, and the first ethylene-propylene copolymer resin includes about 5 wt% to about 10 wt% ethylene, The second ethylene-propylene copolymer resin may comprise greater than about 10 weight percent ethylene and up to about 15 weight percent ethylene. The polypropylene resin is contained in the low specific gravity polypropylene resin composition in an amount of about 40% by weight to about 70% by weight, and is economical and excellent in processability due to cost reduction. The first inorganic filler and the second It can be included in the composition together with an inorganic filler to impart excellent mechanical strength and excellent impact resistance.
At this time, the first ethylene-propylene copolymer resin and the second ethylene-propylene copolymer resin are contained in a weight ratio of 1: 1 to 1: 4, and excellent impact resistance can be imparted with excellent mechanical strength. Specifically, when the weight ratio of the second ethylene-propylene copolymer resin to the first ethylene-propylene copolymer resin is less than the above range, there is a problem that the impact resistance is low and the shrinkage is seriously generated, , The impact resistance may be good but the mechanical stiffness and scratch resistance may be deteriorated and the heat resistance characteristic may be insufficient.
The first ethylene-propylene copolymer resin comprises about 5 wt.% To about 10 wt.% Of ethylene and has an isotactic index of about 97 to about 50, as measured by 13C NMR, As the highly crystalline ethylene-propylene copolymer resin having a value of 99, excellent stiffness and heat resistance can be imparted.
The first ethylene-propylene copolymer resin has a melt index of about 5 g / 10 min to about 20 g / 10 min measured at a temperature of 230 DEG C and a load of 2.16 kg with the above-mentioned isotactic index. , Excellent mechanical rigidity and impact resistance as well as excellent molding processability can be imparted.
Also, the first ethylene-propylene copolymer resin has a molecular weight distribution diagram (weight average molecular weight / number average molecular weight, polydispersity index) of about 2 to about 5, and more specifically, a molecular weight distribution diagram of about 3 to about 5, It is possible to provide a good machining effect with good moldability. Accordingly, the low specific gravity polypropylene resin composition containing the polypropylene resin composition is very useful for manufacturing a molded article for automobile interior materials, particularly a complex molded article having a three-dimensional structure combined with an area, thickness, etc., such as a crash pad.
The second ethylene-propylene copolymer resin may have a shrinkage percentage of about 1.1% to about 1.3%. Specifically, when a flat plate specimen of 3 mm x 200 mm x 100 mm manufactured at an internal pressure of the injection molding machine of about 30 MPa to about 35 MPa was measured with an optical 3-dimensometer (ESTLE-M 3020)), The shrinkage may be between about 1.1% and about 1.3% before and after aging for 48 hours at% humidity. The second ethylene-propylene copolymer resin is mixed with the first ethylene-propylene copolymer resin at a predetermined ratio to exhibit a low degree of deformation with respect to the change of temperature at a low shrinkage rate, and can provide excellent dimensional stability.
The second ethylene-propylene copolymer resin may be a polypropylene having a reactive rubber-like structure directly produced in a reactor, that is, a reactant made thermoplastic polyolefin (RTPO) polypropylene. The first ethylene- To thereby improve the impact resistance as well as the excellent stiffness and provide the dimensional stability.
The low specific gravity polypropylene resin composition includes a thermoplastic elastomer, and examples thereof include an ethylene-propylene rubber (EPR), an ethylene-propylene-diene rubber (EPDM), an ethylene-butene rubber (EBR), an ethylene- ), Styrene-butadiene rubber (SBR), and combinations thereof, to improve impact resistance.
In one embodiment, the thermoplastic elastomer may be a mixture of ethylene-octene rubber (EOR) and ethylene-butene rubber (EBR). Specifically, the thermoplastic elastomer is prepared by mixing ethylene-octene rubber (EOR) and ethylene-butene rubber (EBR) at a weight ratio of about 2: 1 to about 3: 1, , Scratch resistance can be improved with excellent rigidity.
Specifically, when the weight ratio of ethylene-octene rubber (EOR) to ethylene-butene rubber (EBR) is in excess of the above range, the impact properties at the stiffness and the room temperature may be excellent, Which may be unsuitable for application to the < / RTI > Conversely, when the weight ratio of ethylene-octene rubber (EOR) is less than the above range, the stiffness may be lowered and the scratch resistance may be deteriorated.
About 7 to about 38 parts by weight of the thermoplastic elastomer may be included relative to 100 parts by weight of the polypropylene resin. By including the thermoplastic elastomer in the above-described range, the impact strength can be reinforced, and particularly the surface impact strength can be enhanced. Specifically, if it is less than the above range, the impact strength may be lowered, and if it exceeds the above range, the fluidity and compatibility may be limited.
The low specific gravity polypropylene resin composition may further include high density polyethylene. The high-density polyethylene has a specific gravity of about 0.950 to about 0.965, and a melt index of 5 g / 10 min to 20 g / 10 min measured at a temperature of 190 캜 and a load of 2.16 kg. The scratch resistance can be improved and the impact reinforcing effect can be given.
The low specific gravity polypropylene resin composition can improve stiffness while realizing an economically excellent impact strength without containing expensive rubber including the high-density polyethylene together with the above-mentioned polypropylene resin.
The high-density polyethylene is contained in an amount of about 14 parts by weight to about 50 parts by weight based on 100 parts by weight of the polypropylene resin, so that excellent stiffness and excellent impact strength can be imparted.
The low specific gravity polypropylene resin composition may further comprise one additive selected from the group consisting of a compatibilizer, a coupling agent, a slip agent, an antioxidant, a neutralizer, a light stabilizer, and a combination thereof.
The compatibilizing agent is a polyolefin-based compatibilizer and can increase the compatibility between the resins contained in the low specific gravity polypropylene resin composition such as the polypropylene resin.
Wherein the compatibilizer is contained in an amount of about 7 parts by weight to about 25 parts by weight based on 100 parts by weight of the polypropylene resin to improve interfacial adhesion and dispersing efficiency between the resins contained in the low specific gravity polypropylene resin composition, It is possible to improve the mechanical properties, dimensional stability and surface quality of the molded article which is an injection product.
Specifically, the polyolefin-based compatibilizer may be a saturated block copolymer including a styrene-based copolymer.
The coupling agent improves the compatibility of the first inorganic filler and the second inorganic filler with the resin contained in the low specific gravity polypropylene resin composition. It improves the compatibility and improves the dispersion degree, Impact strength can be imparted, and dimensional stability can be simultaneously given.
Specifically, the coupling agent is a modified polypropylene resin including a reactor having reactivity with an inorganic filler in a main chain or a terminal of a polypropylene. Examples of the reactor include maleic acid, maleic anhydride, carboxylic acid, Vinyl acetate, glycidyl methacrylate, vinyl oxazoline, acrylic acid, and the like.
Specifically, the modified polypropylene resin may contain about 2 wt% to 5 wt% of a reactor having reactivity with an inorganic filler in its side chain. More specifically, when the reactor content of the side chains is less than the above range, the compatibility may be lowered and the physical properties may be decreased. In addition, since the substitution amount of the reactor is so small that the interfacial adhesion with the inorganic filler contained in the low specific gravity polypropylene resin composition And the dispersion efficiency may be significantly lowered. On the other hand, when the amount exceeds the above range, the modified polypropylene itself contained in the resin composition of polypropylene tends to be broken down, the effect of increasing the physical properties is small, and the practicality is greatly reduced due to the high production cost compared to the expected effect.
The coupling agent is contained in an amount of about 14 parts by weight to about 50 parts by weight based on 100 parts by weight of the polypropylene resin so as to improve the compatibility between the inorganic filler and the resin to improve the degree of dispersion and impart excellent mechanical stiffness and impact resistance , And dimensional stability at the same time.
The slip agent imparts slipperiness to the surface of the molded article which is an injection product of the low specific gravity polypropylene resin composition to improve the scratch resistance. The slip agent is selected from the group consisting of a siloxane slip agent, an amide slip agent, Lt; / RTI >
The antioxidant may be selected from the group consisting of phenolic antioxidants, phosphite antioxidants, thiodipropionate, and combinations thereof.
The low specific gravity polypropylene resin composition may use calcium stearate or zinc oxide as a neutralizing agent, and a hindered amine type or the like may be used as a light stabilizer.
In another embodiment of the present invention, there is provided a molded article for an automobile interior material comprising an injection molded article of the low specific gravity polypropylene resin composition. Specifically, the low specific gravity polypropylene resin composition comprises a polypropylene resin, a thermoplastic elastomer, a first inorganic filler and a second inorganic filler, wherein the first inorganic filler and the second inorganic filler each contain magnesium hydroxide, magnesium oxysulfate , Titanium oxide, potassium oxide, and combinations thereof, wherein the first inorganic filler is a plate-like type and the second inorganic filler is acicular, and the injection product of the low specific gravity polypropylene resin composition is an automobile It is included in the molded product for interior use. As a result, it is possible to impart light weight, excellent mechanical stiffness and impact resistance, and provide dimensional stability through low shrinkage and orientation control. In addition, it is possible to reduce the incidence of sharp edges which are a big problem when the product is broken, reduce volatile organic compounds (VOCs), and suppress the generation of odor.
Specifically, the specific gravity of the molded article for automobile interior material containing the injection molded article of the low specific gravity polypropylene resin composition is 0.94 to 1.0, and the fuel economy can be improved by making it extremely lightweight.
In the case of articles of polypropylene resin composition, improvement in impact strength generally causes deterioration of heat resistance. On the other hand, the injection molded article of the low specific gravity polypropylene resin composition can satisfy a high level of heat distortion temperature while having excellent impact strength.
Specifically, the injection molded article of the low specific gravity polypropylene resin composition can have an excellent impact strength not only at room temperature but also at a low temperature. Concretely, it is possible to prevent the phenomenon of cracking in the winter season due to the impact strength of about 5.0 Kgfcm / cm or more at a low temperature (about -10 DEG C). The injection molded article of the low specific gravity polypropylene resin composition has excellent impact strength and a heat distortion temperature of about 135 DEG or more and can be used as an automotive interior material.
In addition, the low-density poly propylene Extrusions of the resin composition can have an approximately 230Kgf / cm 2 or more and excellent tensile strength, about 25,000Kgf / cm 2 or more at the same time, the flexural modulus may be suitable as a molded article for automobile interior. Particularly, it is very useful for manufacturing a complex molded article having a three-dimensional structure that is complex in area, thickness, etc., such as a crash pad.
The low specific gravity polypropylene resin composition can impart high fluidity, excellent mechanical stiffness, impact resistance and excellent dimensional stability at the same time, and molded articles for automobile interior materials including injection molded articles thereof are lightweight and thin, Can be secured at the same time. Specific examples of the automobile interior material include interior pillar trim, interior door trim, glove box, console and crash pad.
Specifically, the molded article for an automobile interior material is very useful for automobile parts requiring a high level of rigidity, impact resistance, heat resistance, dimensional stability and light weight because of complicated three-dimensional structure such as width and thickness, Do. For example, when the molded product is applied to the crash pad for an automobile, the development performance of a viscous air bag (PAB (Passenger Airbag) or DAB (Driver Airbag)) is excellent, and a head impact test It is possible to lower the incidence of sharp edges in the vehicle, and to improve the fuel efficiency by reducing the weight.
Hereinafter, specific embodiments of the present invention will be described. However, the embodiments described below are only intended to illustrate or explain the present invention, and the present invention should not be limited thereto.
Example One
A melt index of about 15 g / 10 min measured at a temperature of 230 DEG C and a load of 2.16 kg, an ethylene content of about 7 wt%, an isotactic index of about 98 measured by 13C NMR , A first ethylene-propylene copolymer resin having a molecular weight distribution (weight average molecular weight / number average molecular weight) of about 3, and a second ethylene-propylene copolymer resin having an ethylene content of about 12% by weight and RTPO having a mold shrinkage ratio of about 1.2% Density polyethylene having a specific gravity of about 0.95 and a melt index of about 15 g / 10 min, measured at a temperature of 190 캜 and a load of 2.16 kg, was about 60% by weight, based on the polypropylene About 16 parts by weight relative to 100 parts by weight of the resin, about 12 parts by weight of a styrene-ethylene-butylene-styrene copolymer as a compatibilizing agent relative to 100 parts by weight of the polypropylene resin, Ropil alkylene weight of polypropylene modified with about 2% by weight were contained the polypropylene resin 100 weight parts of about 14 parts by weight compared to contrast. Further, the inorganic filler contains about 17 parts by weight of the inorganic filler relative to 100 parts by weight of the polypropylene resin, wherein the inorganic filler is a first inorganic filler of a plate-shaped magnesium hydroxide having a major axis diameter of about 1.5 mu m and an aspect ratio of about 2, A needle-shaped magnesium oxy sulfate having a length of about 20 μm and an aspect ratio of about 20 was contained as a second inorganic filler at a weight ratio of 1: 0.5. Then, about 16 parts by weight of a thermoplastic elastomer is contained in an amount of about 16 parts by weight based on 100 parts by weight of the polypropylene resin, and the thermoplastic elastomer is mixed with ethylene-octene rubber (EOR) and ethylene-butene rubber (EBR) A specific gravity polypropylene resin composition was prepared.
The low specific gravity polypropylene resin composition was extruded using a twin-screw extruder under the processing conditions of 200 ° C to 240 ° C.
Example 2
A low specific gravity polypropylene resin composition was prepared in the same manner as in Example 1, except that a first inorganic filler which was a plate-like magnesium hydroxide and a second inorganic filler which was an acicular magnesium oxide sulfite were mixed at a weight ratio of 1: 1 .
Example 3
A low specific gravity polypropylene resin composition was prepared in the same manner as in Example 1, except that a first inorganic filler which was a plate-like magnesium hydroxide and a second inorganic filler which was an acicular magnesium oxide sulfite were mixed at a weight ratio of 1: 1.5 .
Example 4
A low specific gravity polypropylene resin composition was prepared in the same manner as in Example 1, except that a first inorganic filler which was a plate-like magnesium hydroxide and a second inorganic filler which was an acicular magnesium oxide sulfite were mixed at a weight ratio of 1: 2 .
Example 5
A low specific gravity polypropylene resin composition was prepared in the same manner as in Example 1, except that a first inorganic filler, which was a plate-like magnesium hydroxide, and a second inorganic filler, which was an acicular magnesium oxide sulfate, were mixed at a weight ratio of 1: 2.5 .
Comparative Example One
A low specific gravity polypropylene resin composition was prepared in the same manner as in Example 1, except that a plate-shaped talc having a diameter of 5 to 10 μm and an aspect ratio of 1: 1 was used instead of the first batch filler and the second inorganic filler.
Comparative Example 2
A low specific gravity polypropylene resin composition was prepared in the same manner as in Example 1, except that tabular talc was used as the first inorganic filler and acicular magnesium oxide was used as the second inorganic filler in a weight ratio of 1: 1 Respectively.
evaluation
The extrudates of the resin compositions prepared in the above Examples and Comparative Examples were injection molded to prepare specimens conforming to the respective ASTM standards, and the following properties were measured using the results. The results are shown in Table 1.
Experimental Example 1. Specific gravity (g / ㎤)
The specific gravity of the specimens prepared in Examples and Comparative Examples was measured according to ASTM D 792, and the results are shown in Table 1.
Experimental Example 2. Tensile strength ( Kgf / cm2 )
The tensile strengths of the specimens prepared in Examples and Comparative Examples were measured at 23 캜 using ASTM D 638. In the measurement, the load application speed was 50 mm / min, and the specimen type was TYPE-I of ASTM 638, and the results are shown in Table 1.
Experimental Example 3. Flexural modulus ( Kgf / cm2 )
Flexural moduli of the specimens prepared in Examples and Comparative Examples were measured using ASTM D 790 at a speed of 10 mm / min. In the measurement, the specimen thickness was 6.4 mm, and the support span distance was 50 mm, and the results are shown in Table 1.
Experimental Example 4 Izod impact strength ( Kgfcm / cm)
The specimens prepared in Examples and Comparative Examples were measured at room temperature (23 캜) and -10 캜 according to ASTM D 256 in Notch, respectively. In addition, the breakage of the specimen during the measurement was also checked, and the results are shown in Table 1.
Experimental Example 5. Heat distortion temperature (℃)
The specimens of 6.4 mm thickness prepared in Examples and Comparative Examples were measured at a load of 4.6 kgf / cm 2 using ASTM D 648, and the results are shown in Table 1.
Experimental Example 6. Transformation
The specimens of the Examples and Comparative Examples (300 mm x 100 mm x 2 m) were injection-molded and after 48 hours, the distortion of the specimen was evaluated. Specifically, in a specimen having a cross-sectional area and a Z-axis length (thickness) indicated by the lengths of the X-axis and the Y-axis, the lengths of the highest point and the lowest point in the Z- Are shown in Table 1.
(g / cm3)
(Kgf / cm2)
(Room temperature /
Kgf / cm2)
(-10 ° C /
Kgf / cm2)
From the results shown in Table 1, it can be seen that the low specific gravity polypropylene resin composition of the embodiment gives lighter weight, imparts excellent mechanical rigidity and impact resistance which can be used as automobile interior materials, and provides dimensional stability.
Specifically, the comparative example including talc has a specific weight of about 1, so that the fuel consumption is poor and air pollution may still be a problem. In addition, since the comparative example has a low impact strength of 5.0 or less at a low temperature, breakage tends to occur in the winter season, and when the impact strength is measured at room temperature, some or all of the breakage occurs, have.
On the other hand, the example has a low specific gravity, exhibits an excellent tensile strength of about 230 Kgf / cm 2 or more, and exhibits a strain of 2.5 or less, and can be suitably used for an automobile interior material. Particularly, it can be confirmed that it is very useful for manufacturing a complicated molded product having a three-dimensional structure in which the area, thickness and the like are the same as a crash pad.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments, And falls within the scope of the invention.
Claims (18)
Wherein the first inorganic filler and the second inorganic filler each contain one selected from the group consisting of magnesium hydroxide, magnesium oxysulfate, titanium oxide, potassium oxide, and combinations thereof,
Wherein the first inorganic filler is of a plate-like type and the second inorganic filler is of an acicular type
Low specific gravity polypropylene resin composition.
Wherein the polypropylene resin comprises a first ethylene-propylene copolymer resin and a second ethylene propylene copolymer resin,
Wherein the first ethylene-propylene copolymer resin comprises 5 wt% to 10 wt% ethylene,
Wherein the second ethylene-propylene copolymer resin comprises greater than 10 wt% and up to 15 wt% ethylene
Low specific gravity polypropylene resin composition.
Wherein the weight ratio of the first ethylene-propylene copolymer resin to the second ethylene-propylene copolymer resin is from 1: 1 to 1: 4
Low specific gravity polypropylene resin composition.
The first ethylene-propylene copolymer resin has a melt index of 5 g / 10 min to 20 g / 10 min measured at a temperature of 230 ° C and a load of 2.16 kg
Low specific gravity polypropylene resin composition.
Wherein the first ethylene-propylene copolymer resin has a weight-average molecular weight / number-average molecular weight of 2 to 5
Low specific gravity polypropylene resin composition.
The second ethylene propylene copolymer resin has a shrinkage ratio of 1.1% to 1.3% before and after aging for 48 hours at 23 ° C and 50% humidity.
Low specific gravity polypropylene resin composition.
And 7 to 38 parts by weight of the thermoplastic elastomer relative to 100 parts by weight of the polypropylene resin.
Low specific gravity polypropylene resin composition.
The thermoplastic elastomer may be an ethylene-propylene rubber (EPR), an ethylene-propylene-diene rubber (EPDM), an ethylene-butene rubber (EBR), an ethylene-octene rubber (EOR), a styrene- Comprising one selected from the group consisting of
Low specific gravity polypropylene resin composition.
The thermoplastic elastomer is obtained by mixing ethylene-octene rubber (EOR) and ethylene-butene rubber (EBR) at a weight ratio of 2: 1 to 3: 1
Low specific gravity polypropylene resin composition.
Wherein the total content of the first inorganic filler and the second inorganic filler is 7 to 50 parts by weight based on 100 parts by weight of the polypropylene resin
Low specific gravity polypropylene resin composition.
Wherein the weight ratio of the first inorganic filler to the second inorganic filler is 1: 1 to 1: 2
Low specific gravity polypropylene resin composition.
Wherein the first inorganic filler has a major axis diameter of 0.5 탆 to 2 탆,
Long axis diameter / minor axis diameter of 2 to 4
Low specific gravity polypropylene resin composition.
Wherein the second inorganic filler has a length of 5 탆 to 30 탆,
Having an aspect ratio of 10 to 30
Low specific gravity polypropylene resin composition.
Further comprising high density polyethylene
Low specific gravity polypropylene resin composition.
Wherein the high-density polyethylene is contained in an amount of 14 to 50 parts by weight relative to 100 parts by weight of the polypropylene resin
Low specific gravity polypropylene resin composition.
The polypropylene resin composition further comprises one additive selected from the group consisting of a compatibilizer, a coupling agent, a slip agent, an antioxidant, a neutralizer, a light stabilizer, and a combination thereof
Low specific gravity polypropylene resin composition.
Having a specific gravity of 0.94 to 1.00
Molded articles for automobile interior materials.
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| KR1020160152140A KR101874918B1 (en) | 2016-11-15 | 2016-11-15 | Light-weight polypropylene resin composition and molded product of vehicle interior material using the same |
| PCT/KR2017/012917 WO2018093130A1 (en) | 2016-11-15 | 2017-11-15 | Polypropylene resin composition having low specific gravity and molded product, for vehicle interior material, using same |
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| KR1020160152140A KR101874918B1 (en) | 2016-11-15 | 2016-11-15 | Light-weight polypropylene resin composition and molded product of vehicle interior material using the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20200083832A (en) * | 2018-12-31 | 2020-07-09 | 현대자동차주식회사 | Polypropylene resin composition having high impact and lightweight and molded product for automobile interior material using the same |
| KR20230035879A (en) * | 2021-09-06 | 2023-03-14 | 주식회사 네오엔프라 | Eco-friendly buoy composition containing highly crystalline polypropylene and graphene oxide |
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| CN109852076B (en) * | 2017-11-30 | 2021-04-16 | 联泓(江苏)新材料研究院有限公司 | Low-odor low-VOC modified thermoplastic elastomer material and preparation method thereof |
| CA3131673C (en) | 2018-12-17 | 2024-02-20 | Nippon Steel Corporation | Laminated core, method of manufacturing same, and electric motor |
| CA3131540A1 (en) | 2018-12-17 | 2020-06-25 | Nippon Steel Corporation | Laminated core and electric motor |
| US11742129B2 (en) * | 2018-12-17 | 2023-08-29 | Nippon Steel Corporation | Adhesively-laminated core, manufacturing method thereof, and electric motor |
| WO2020129940A1 (en) | 2018-12-17 | 2020-06-25 | 日本製鉄株式会社 | Laminated core and rotating electric machine |
| CN113169592A (en) | 2018-12-17 | 2021-07-23 | 日本制铁株式会社 | Laminated iron core and rotating electrical machine |
| CA3131669A1 (en) | 2018-12-17 | 2020-06-25 | Nippon Steel Corporation | Laminated core and electric motor |
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| JP5092216B2 (en) * | 2004-08-19 | 2012-12-05 | 住友化学株式会社 | Propylene-based resin composition production method, propylene-based resin composition, and injection-molded body comprising the same |
| KR100657359B1 (en) * | 2005-02-28 | 2006-12-19 | 삼성토탈 주식회사 | Excellent anti-scratch characteristic polypropylene resin composition |
| KR20100058227A (en) * | 2008-11-24 | 2010-06-03 | 현대자동차주식회사 | High melt flow polypropylene resin composition for bumper of automobile |
| KR101580957B1 (en) * | 2014-05-12 | 2015-12-30 | 현대이피 주식회사 | Polypropylene composition with excellent impact resistance and scratch resistance |
| KR20160064389A (en) * | 2014-11-28 | 2016-06-08 | 주식회사 엘지화학 | Polypropylene resin composition and injecion-molded article prepared therefrom |
| KR101783084B1 (en) * | 2014-12-03 | 2017-09-28 | 주식회사 엘지화학 | Polypropylene composition having low density and low linear thermal expansion, and molded product |
-
2016
- 2016-11-15 KR KR1020160152140A patent/KR101874918B1/en active IP Right Grant
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20200083832A (en) * | 2018-12-31 | 2020-07-09 | 현대자동차주식회사 | Polypropylene resin composition having high impact and lightweight and molded product for automobile interior material using the same |
| KR20230035879A (en) * | 2021-09-06 | 2023-03-14 | 주식회사 네오엔프라 | Eco-friendly buoy composition containing highly crystalline polypropylene and graphene oxide |
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| WO2018093130A1 (en) | 2018-05-24 |
| KR101874918B1 (en) | 2018-07-06 |
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