KR20180036085A - Lip cosmetic compostion - Google Patents
Lip cosmetic compostion Download PDFInfo
- Publication number
- KR20180036085A KR20180036085A KR1020160126215A KR20160126215A KR20180036085A KR 20180036085 A KR20180036085 A KR 20180036085A KR 1020160126215 A KR1020160126215 A KR 1020160126215A KR 20160126215 A KR20160126215 A KR 20160126215A KR 20180036085 A KR20180036085 A KR 20180036085A
- Authority
- KR
- South Korea
- Prior art keywords
- lip
- cosmetic composition
- melting point
- wax
- high melting
- Prior art date
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Images
Classifications
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/0229—Sticks
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
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- A—HUMAN NECESSITIES
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
Abstract
Description
본 발명은 입술 화장료 조성물에 관한 것으로서, 보다 구체적으로 본 발명은 형태 유지력이 우수하면서도 발림성과 도포성이 우수한 입술 화장료 조성물 및 이를 포함하는 입술용 화장품에 관한 것이다.The present invention relates to a lip cosmetic composition, and more particularly, to a lip cosmetic composition excellent in shape retention ability and excellent in spreadability and spreadability, and a lip cosmetic composition containing the same.
립스틱, 립글로스, 립밤, 및 립 펜슬과 같은 입술용 화장품은 입술에 색상을 부여하여 아름답게 보이도록 하는 동시에 입술을 보호하기 위한 목적으로 사용된다.Lip cosmetics, such as lipsticks, lip gloss, lip balm, and lip pencil, are used for the purpose of protecting the lips while at the same time giving the lips a beautiful look.
이 중, 고형 스틱 형태의 입술용 화장품인 립스틱은 부드러운 발림성을 제공하며, 입술 전체에 도포하기 간편한 형태를 갖는다. 그러나, 립스틱만으로는 뚜렷한 입매를 표현하기에 한계가 있으므로, 섬세한 입술 화장을 위해서는 립 라이너를 이용하여 입술 라인을 별도로 그리거나, 붓과 같은 화장 도구를 이용하여야 하는 번거로움이 따른다. Among them, lipstick, which is a lipstick in the form of a solid stick, provides soft wettability and has a form that is easy to apply to the entire lips. However, since lipstick alone is limited in expressing a clear shopping, it is troublesome to use a lip liner to draw lip lines separately or to use a makeup tool such as a brush for delicate lip makeup.
한편, 립 라이너는 입술 윤곽의 섬세한 표현을 위하여 얇은 펜슬 타입으로 제조되는 것이 일반적이다. 따라서 넓은 면적에 사용할 경우 시간이 많이 소요되며, 상대적으로 뻑뻑한 사용감을 나타내므로 입술 전체 면적에 도포하기에는 적합하지 않다.On the other hand, lip liner is generally made of a thin pencil type for delicate representation of lip contour. Therefore, it is time-consuming to use in a large area, and it is not suitable for application to the entire area of the lips since it shows relatively stiff feeling.
이러한 문제점을 극복하고자, 립스틱과 립 라이너의 중간 형태의 립 펜슬과 같은 제품이 판매되고 있다. 그러나 립 펜슬은 경도가 충분히 높지 않아 사용할수록 끝부분이 닳아 뭉툭해지기 때문에 립 라이너로서의 기능을 회복시키기 위해서는 샤프너를 이용하여 끝부분의 모양을 재건시켜야 하는 불편함이 있다. To overcome this problem, products such as a lip pencil in the form of an intermediate lipstick and lip liner are being sold. However, since the lip pencil is not sufficiently high in hardness, the end portion of the lip pencil becomes worn out as it is used. Therefore, in order to restore the function as a lip liner, it is inconvenient to reconstruct the shape of the end portion using a sharpener.
따라서, 발림성 및 도포 편의성이 우수하면서도, 섬세한 화장 표현이 가능하며 사용에 따라 형태의 변형이 적은 새로운 입술 화장료 조성물의 개발이 필요한 실정이다.Therefore, there is a need to develop a new lip cosmetic composition which is excellent in spreadability and ease of application, can express delicate cosmetics, and is less deformed depending on use.
이에 본 발명의 일 목적은 형태 유지력이 우수하면서도 입술에 도포 시 부드러운 사용감 및 우수한 도포성을 나타낼 수 있는 입술 화장료 조성물을 제공하는 것이다. Accordingly, it is an object of the present invention to provide a lip cosmetic composition which is excellent in shape retention ability but can exhibit a soft feeling upon application to lips and excellent applicability.
본 발명의 다른 목적은 세밀하고 정교한 입술 표현이 가능한 동시에 한번에 다량 도포가 가능하며 반복 사용에도 형태의 변형이 적은 입술 화장료 조성물을 제공하는 것이다.Another object of the present invention is to provide a lip cosmetic composition which is capable of expressing fine and precise lips at the same time, can be applied in a large amount at a time, and is less deformed by repeated use.
본 발명의 또 다른 목적은 상기한 바와 같은 입술 화장료를 포함하는 고형 스틱 타입의 입술 도포용 화장품을 제공하는 것이다.It is still another object of the present invention to provide a solid stick type cosmetic for lip application comprising the above-mentioned lip cosmetic composition.
상기 과제를 해결하기 위하여 본 발명은In order to solve the above problems,
고융점 왁스를 포함하는 입술 화장료 조성물로서,1. A lip cosmetic composition comprising a high melting point wax,
상기 고융점 왁스는 분자 내 하나 이상의 히드록시기를 갖는 선형 폴리에틸렌 왁스; 및 분자 내 하나 이상의 C1 내지 C5의 알킬기를 갖는 선형 폴리에틸렌 왁스;로 이루어지는 군에서 선택되는 1종 이상을 포함하고, Wherein the high melting point wax is a linear polyethylene wax having at least one hydroxyl group in the molecule; And linear polyethylene wax having at least one C1 to C5 alkyl group in the molecule,
상기 조성물의 경도는 100 내지 300 gf인 것을 특징으로 하는 입술 화장료 조성물을 제공한다.Wherein the hardness of the composition is 100 to 300 gf.
이때, 상기 고융점 왁스는 녹는점이 95 ℃이상일 수 있다.At this time, the melting point of the high melting point wax may be 95 ° C or higher.
이때, 상기 고융점 왁스는 중량평균분자량이 500 내지 800 g/mol일 수 있다.The high melting point wax may have a weight average molecular weight of 500 to 800 g / mol.
이때, 상기 고융점 왁스는 조성물 내 5 내지 20 중량%로 포함될 수 있다.The high melting point wax may be contained in the composition in an amount of 5 to 20% by weight.
이때, 상기 입술 화장료 조성물은 액체 유지, 고체 유지, 왁스류, 탄화수소계 오일, 고급 지방산, 고급 알코올, 합성 에스테르유, 및 실리콘유로 이루어지는 군에서 선택되는 1종 이상을 더 포함하는 것일 수 있다.The lip cosmetic composition may further comprise at least one member selected from the group consisting of liquid retention, solid retention, waxes, hydrocarbon oils, higher fatty acids, higher alcohols, synthetic ester oils and silicone oils.
이때, 상기 입술 화장료 조성물은 유성 또는 유중수형 화장료 조성물일 수 있다.At this time, the lip cosmetic composition may be an oily or water-in-oil type cosmetic composition.
또한, 본 발명은 상기 입술 화장료 조성물을 포함하는 고형 스틱 타입의 입술 도포용 화장품을 제공한다.Further, the present invention provides a solid stick type cosmetic for lip application comprising the above-described lip cosmetic composition.
바람직하기로, 상기 입술 도포용 화장품은 지름은 예를 들어 2 내지 5mm일 수 있고, 바람직하게는 예를 들어 3 내지 4 mm이고, 커팅 각도가 50도 이하일 수 있다.Preferably, the cosmetic for lip application may have a diameter of, for example, 2 to 5 mm, preferably 3 to 4 mm, and a cutting angle of 50 degrees or less.
본 발명에 따른 입술 화장료 조성물은 우수한 형태 유지력을 나타내고, 입술에 도포 시 부드럽게 발리며 끈적임이 적어 사용감과 도포성이 우수하다. 이에, 본 발명의 입술 화장료 조성물은 스틱 형태의 화장품, 특히 립스틱 및 립 라이너로서의 역할을 동시에 수행할 수 있는 초슬림 스틱형 립스틱으로 구현되기 적합하며, 반복 사용에도 최초의 성형 형태를 유지할 수 있어 사용 편의성을 높일 수 있다.The lip cosmetic composition according to the present invention exhibits excellent shape retaining ability, softly peeled on application to lips, and less tacky, resulting in excellent feeling and application. Accordingly, the lip cosmetic composition of the present invention is suitable to be realized as a stick-shaped cosmetic product, especially a lipstick and a lip liner which can simultaneously perform a role of lipstick and lip liner, .
도 1은 본 발명의 입술 도포용 화장품의 종단면도이다.1 is a longitudinal sectional view of a cosmetic for lip application of the present invention.
이하, 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자가 용이하게 실시할 수 있도록 상세히 설명한다. 그러나 본 발명은 여러 가지 상이한 형태로 구현될 수 있으며, 여기에서 설명하는 실시예에 한정되지 않는다.DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings. The present invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein.
본 발명은 고융점 왁스를 포함하여 경도가 100 내지 300 gf로 높은 동시에 부드러운 발림감을 가지는 입술 화장료 조성물에 관한 것이다.The present invention relates to a lip cosmetic composition containing a high melting point wax and having a hardness of 100 to 300 gf and a soft feeling of softness.
본 발명에서 상기 고융점 왁스는 녹는점이 95 ℃ 이상인 왁스이며, 바람직하기로 녹는점이 95 내지 130 ℃인 왁스이다. In the present invention, the high-melting wax is a wax having a melting point of 95 ° C or higher, preferably a wax having a melting point of 95 to 130 ° C.
상기 고융점 왁스의 중량평균분자량은 500 내지 800 g/mol인 것이 바람직하다.The weight average molecular weight of the high melting point wax is preferably 500 to 800 g / mol.
본 발명에서 상기 고융점 왁스는 분자 내 하나 이상의 히드록시기를 갖는 선형 폴리에틸렌 왁스; 및 분자 내 하나 이상의 C1 내지 C5의 알킬기를 갖는 선형 폴리에틸렌 왁스;로 이루어지는 군에서 선택되는 1종 이상을 포함하는 것이 바람직하다.In the present invention, the high melting point wax is a linear polyethylene wax having at least one hydroxyl group in the molecule; And linear polyethylene wax having at least one C1 to C5 alkyl group in the molecule.
이러한 왁스들은 기능기가 없는 왁스에 비해 끈적임 없는 우수한 밀착감을 제공하며, 이로부터 입술 화장료 조성물의 전체적인 사용감을 증진시킬 수 있다. These waxes provide an excellent tackiness without tackiness as compared to waxes with no functional groups, thereby enhancing the overall feeling of use of the lip cosmetic composition.
상기 분자 내 하나 이상의 히드록시기를 갖는 선형 폴리에틸렌 왁스는 폴리에틸렌 주쇄를 가지며 히드록시기(-OH)가 주쇄의 중간 또는 말단에 불규칙적으로 결합되어 있는 구조의 왁스로서, 이러한 왁스의 구체적인 예로는 C20~C40 알코올, 에틸렌/프로필렌 코폴리머 등을 들 수 있다.The linear polyethylene wax having at least one hydroxyl group in the molecule has a polyethylene main chain and a hydroxyl group (-OH) is irregularly bonded to the middle or end of the main chain. Specific examples of such waxes include C20-C40 alcohol, ethylene / Propylene copolymer and the like.
상기 분자 내 하나 이상의 C1 내지 C5의 알킬기를 갖는 선형 폴리에틸렌 왁스는 폴리에틸렌 주쇄를 가지며 C1 내지 C5의 알킬기가 주쇄의 중간 또는 말단에 불규칙적으로 결합되어 있는 구조의 왁스이다. The linear polyethylene wax having at least one C1 to C5 alkyl group in the molecule is a wax having a polyethylene main chain and a C1 to C5 alkyl group irregularly bonded to the middle or end of the main chain.
이때, 상기 C1 내지 C5의 알킬기는 메틸기, 에틸기, 프로필기, 이소프로필기, 부틸기, 또는 펜틸기일 수 있으며, 하나의 폴리에틸렌 주쇄에 상기 알킬기는 1종 이상이 포함될 수 있다. 이러한 왁스의 구체적인 예로는 폴리에틸렌프로필렌코폴리머를 들 수 있다.At this time, the C1 to C5 alkyl group may be a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, or a pentyl group, and one or more of the alkyl groups may be contained in one polyethylene main chain. Specific examples of such waxes include polyethylene propylene copolymers.
상기 분자 내 하나 이상의 히드록시기를 갖는 선형 폴리에틸렌 왁스 및 분자 내 하나 이상의 C1 내지 C5의 알킬기를 갖는 선형 폴리에틸렌 왁스는 단독 또는 혼합하여 사용될 수 있고, 그 혼합 비율은 특별히 제한되지 않으며 필요에 따라 적절히 조절될 수 있다.The linear polyethylene wax having at least one hydroxyl group in the molecule and the linear polyethylene wax having at least one C1 to C5 alkyl group in the molecule may be used alone or in combination and the mixing ratio thereof is not particularly limited and may be suitably adjusted have.
이때, 분자 내 하나 이상의 C1 내지 C5의 알킬기를 갖는 선형 폴리에틸렌 왁스의 중량평균분자량은 600 내지 800 g/mol인 것이 바람직하며, 분자 내 하나 이상의 히드록시기를 갖는 선형 폴리에틸렌 왁스의 중량평균분자량은 500 내지 700 g/mol인 것이 바람직하다.The linear polyethylene wax having at least one C1 to C5 alkyl group in the molecule preferably has a weight average molecular weight of 600 to 800 g / mol, and the linear polyethylene wax having at least one hydroxyl group in the molecule has a weight average molecular weight of 500 to 700 g / mol.
본 발명에서 고융점 왁스는 상술한 효과를 확보하기 위하여, 조성물 내에 5 내지 20 중량%로 포함되는 것이 바람직하다. 만일 고융점 왁스의 함량이 5 중량% 미만이면 경도가 약하여 고형 스틱형 화장품으로 제조하기 적합하지 않으며, 20 중량%를 초과하면 경도가 지나치게 높아져 도포량 및 발림감 특성이 저하되므로 상기 범위 내에서 적절히 조절한다.In the present invention, the high melting point wax is preferably contained in the composition in an amount of 5 to 20% by weight in order to secure the above-mentioned effect. If the content of the high melting point wax is less than 5% by weight, the hardness is weak and it is not suitable to be manufactured into a solid stick type cosmetic product. If it exceeds 20% by weight, the hardness becomes too high, do.
본 발명의 입술 화장료 조성물은 상술한 고융점 왁스 이외에도 일반적으로 입술 화장료 조성물에 사용되는 액체 유지, 고체 유지, 왁스류, 탄화수소계 오일, 고급 지방산, 고급 알코올, 합성 에스테르유, 및 실리콘유로 이루어지는 군에서 선택되는 1종 이상을 더 포함할 수 있다.The lip cosmetic composition of the present invention can be used in a group consisting of liquid, solid, waxes, hydrocarbon oils, higher fatty acids, higher alcohols, synthetic ester oils and silicone oils, which are generally used in lip cosmetic compositions in addition to the above- And may further include at least one kind selected therefrom.
상기 액체 유지로는 올리브유, 동백유, 호호바유, 트리글리세리드, 카프릴릴/카프릭트리글리세리드, 트리옥탄산글리세린, 트리이소팔미트산글리세린 등이 예시된다. Examples of the liquid holding furnace include olive oil, camellia oil, jojoba oil, triglyceride, caprylyl / capric triglyceride, glyoxalic acid trioctanoate, glycerin triisopalmitate and the like.
상기 고체 유지로는 야자유, 경화야자유, 팜유, 경화유, 경화피마자유 등이 예시된다. Examples of the solid fat retaining furnace include coconut oil, hardened palm oil, palm oil, hardened oil, hardened castor oil and the like.
상기 왁스류로는 밀랍, 칸데릴라 왁스, 카나우바 왁스, 라놀린, 호호바 왁스 등이 예시된다. Examples of the waxes include beeswax, candelilla wax, carnauba wax, lanolin, and jojoba wax.
상기 탄화수소계 오일로는 유동 파라핀, 스쿠알렌, 바셀린, 마이크로크리스탈린 왁스, 이소헥사데칸, 이소데칸, 운데칸, 스쿠알란, 알파올레핀올리고머, 하이드로제네이티드 폴리데센, 하이드로제네이티드 폴리이소부텐 등이 예시된다. Examples of the hydrocarbon-based oil include liquid paraffin, squalane, petrolatum, microcrystalline wax, isohexadecane, isodecane, undecane, squalane, alpha olefin oligomer, hydrogenated polydecene, and hydrogenated polyisobutene .
상기 고급 지방산으로는 라우르산, 미리스트산, 팔미트산, 스테아르산, 베헤닌산 등이 예시된다. Examples of the higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid and the like.
상기 고급 알콜로는 세틸알콜, 스테아릴알콜, 베헤닐알콜, 미리스틸알콜, 세토스테아릴알콜, 2-옥틸도데칸올 등이 예시된다. Examples of the higher alcohols include cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, cetostearyl alcohol, and 2-octyldodecanol.
상기 합성 에스테르유로는 이소프로필미리스테이트, 세틸옥타노에이트, 옥틸도데실미리스테이트, 이소프로필팔미테이트, 헥실라우레이트, 미리스틸미리스테이트, 세틸락테이트, 이소세틸이소스테아레이트, 네오펜틸글리콜디카프레이트, 네오펜틸글리콜디헵타노에이트 에틸헥실글리세린, 세틸에틸헥사노에이트, 에틸헥실팔미테이트, 세토스테아릴알콜, 피토스테릴이소스테아릴다이머리디리놀리에이트, 폴리글리세릴-2트리이소스테아레이트 등이 예시된다. Wherein the synthetic ester channel is selected from the group consisting of isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, hexyl laurate, myristyl myristate, cetyl lactate, isocetylisostearate, neopentyl glycol dicarboxylate Polyglyceryl-2-triisostearate, polyglyceryl-2-triisostearate, polyglyceryl-2-triisostearate, polyglyceryl-2-triisostearate, and the like .
상기 실리콘유로는 디메틸폴리실록산, 메틸페닐폴리실록산, 메틸하이드로젠폴리실록산 등의 사슬형 실리콘유; 도데카메틸사이클로헥사실록산, 옥타메틸사이클로테트라실록산, 데카메틸사이클로펜타실록산 등의 환상형 실리콘유; 등이 예시된다.The silicone oil may be selected from the group consisting of chain silicone oils such as dimethylpolysiloxane, methylphenylpolysiloxane and methylhydrogenpolysiloxane; Cyclic silicone oils such as dodecamethylcyclohexasiloxane, octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane; And the like.
이때, 상기 성분의 조성물 내 함량은 본 발명에서 특별히 한정되지 않고 필요에 따라 적절히 조절될 수 있으나, 구체적으로 합성 에스테르유는 40~60 중량%, 탄화수소계 오일은 5~25 중량%, 고급 알코올은 5~25 중량%로 포함되는 것이 바람직하다.In this case, the content of the component in the composition is not particularly limited in the present invention and can be appropriately adjusted as needed. Specifically, the content of the synthetic ester oil is from 40 to 60 wt%, the hydrocarbon oil is from 5 to 25 wt% 5 to 25% by weight.
본 발명의 입술 화장료 조성물은 유성 또는 유중수형(water in oil, W/O) 화장료 조성물로 제조될 수 있다. 여기서 유성 화장료 조성물은 수상 성분 없이 유상으로만 구성된 화장료 조성물을 의미하며, 유중수형 화장료 조성물은 유상을 외상으로 하고, 여기에 수상이 분산된 형태의 화장료 조성물을 의미한다.The lip cosmetic composition of the present invention can be produced with a water-in-oil (W / O) cosmetic composition. Herein, the oily cosmetic composition means a cosmetic composition composed only of oily phase without an aqueous phase component, and the water-in-oil type cosmetic composition means a cosmetic composition in which the oily phase is an external phase and the water phase is dispersed therein.
상기 유상에는 고융점 왁스가 포함되며, 상술한 바의 액체 유지, 고체 유지, 왁스류, 탄화수소계 오일, 고급 지방산, 고급 알코올, 합성 에스테르유, 및 실리콘유로 이루어지는 군에서 선택되는 1종 이상이 포함된다.The oil phase includes a high melting point wax and includes at least one selected from the group consisting of liquid oils, solid oils, waxes, hydrocarbon oils, higher fatty acids, higher alcohols, synthetic ester oils and silicone oils do.
상기 수상은 용제로서 물을 포함하며, 수용성 고분자 및 특정 효능을 가진 유효성분을 포함할 수 있다.The water phase contains water as a solvent, and may contain a water-soluble polymer and an active ingredient having a specific effect.
이때 상기 수용성 고분자는 물에 용해되어 증점제 역할을 하는 것으로, 그 종류가 크게 제한되지 않으며, 예를 들어 천연의 수용성 고분자, 반합성된 수용성 고분자 또는 합성된 수용성 고분자 등이 있다. The water-soluble polymer is dissolved in water to serve as a thickening agent. The type of the water-soluble polymer is not particularly limited, and examples thereof include a natural water-soluble polymer, a semi-synthetic water-soluble polymer, or a synthesized water-soluble polymer.
상기 천연의 수용성 고분자로는 예컨대 식물계 고분자(예컨대 아라비아 검, 트래거캔스 검, 갈락탄, 구아검, 카로브검, 카라야 검, 카라기난, 펙틴, 한천, 퀸스시드(마멜로), 알게콜로이드(갈조 진액), 전분(쌀, 옥수수, 감자, 밀), 글리실리진산); 미생물계 고분자(예컨대 크산탄 검, 덱스트란, 석시노글루칸, 풀룰란(pullulan) 등); 동물계 고분자(예컨대, 콜라겐, 카제인, 알부민, 젤라틴 등) 등을 들 수 있다. Examples of the natural water-soluble polymer include vegetable polymers such as gum arabic, tragacanth gum, galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, queen seed (marmalade, Starch (rice, corn, potato, wheat), glycylic acid); Microbial polymers (e.g., xanthan gum, dextran, succinoglucan, pullulan, etc.); And animal-based polymers (for example, collagen, casein, albumin, gelatin, etc.).
상기 반합성된 수용성 고분자로는 예컨대 전분계 고분자(예컨대, 카르복시메틸 전분, 메틸히드록시프로필 전분 등); 셀룰로오스계고분자(메틸셀룰로오스, 에틸셀룰로오스, 메틸히드록시프로필셀룰로오스, 히드록시에틸셀룰로오스, 셀룰로오스황산 나트륨, 히드록시프로필셀룰로오스, 카르복시메틸셀룰로오스, 카르복시메틸셀룰로오스나트륨, 결정 셀룰로오스, 셀룰로오스 분말 등); 알긴산계 고분자(예컨대 알긴산 나트륨, 알긴산 프로필렌글리콜에스테르 등) 등을 들 수 있다. Examples of the semi-synthetic water-soluble polymer include starch polymers (e.g., carboxymethyl starch, methylhydroxypropyl starch, etc.); Cellulose polymers such as methyl cellulose, ethyl cellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxymethylcellulose, carboxymethylcellulose sodium, crystalline cellulose, cellulose powder and the like); And alginic acid-based polymers (for example, sodium alginate, propylene glycol alginate and the like).
상기 합성된 수용성 고분자로는, 예컨대 비닐계 고분자(예컨대 폴리비닐알코올, 폴리비닐메틸에테르, 폴리비닐피롤리돈, 카르복시비닐폴리머 등); 폴리옥시에틸렌계 고분자(예컨대 폴리에틸렌글리콜 20,000, 40,000,60,000의 폴리옥시에틸렌폴리옥시프로필렌 공중합체 등); 아크릴계 고분자(예컨대 폴리아크릴산 나트륨, 폴리에틸아크릴레이트, 폴리아크릴아미드 등); 폴리에틸렌이민; 양이온 폴리머 등을 들 수 있다. As the synthesized water-soluble polymer, for example, a vinyl polymer (for example, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer, etc.); Polyoxyethylene-based polymers (e.g., polyoxyethylene polyoxypropylene copolymer of polyethylene glycol 20,000, 40,000, and 60,000); Acrylic polymers (for example, sodium polyacrylate, polyethylacrylate, polyacrylamide and the like); Polyethylene imine; Cationic polymers, and the like.
본 발명에 따른 입술 화장료 조성물에서 수상을 구성하는 수용성 고분자로서 다른 성분과의 조화 및 수상의 안정화를 위하여 바람직하기로 암모늄아크릴로일디메틸타우레이트와 비닐피롤리돈의 공중합체(Ammonium Acryloyldimethyltaurate/VP copolymer)를 포함할 수 있다. In the lip cosmetic composition according to the present invention, as a water-soluble polymer constituting the water phase, it is preferable to use a copolymer of ammonium acryloyldimethyltaurate and vinylpyrrolidone (Ammonium Acryloyldimethyltaurate / VP copolymer ).
또한, 수상 내에서 수용성 고분자의 함량은 수용성 고분자의 증점 효과 및 수상의 안정화 효과 등을 고려할 때 물 100 중량부 당 0.05~1 중량부인 것이 바람직하고, 0.1~0.5 중량부인 것이 보다 바람직하다. The content of the water-soluble polymer in the aqueous phase is preferably 0.05 to 1 part by weight, more preferably 0.1 to 0.5 part by weight per 100 parts by weight of water in view of the effect of thickening the water-soluble polymer and stabilizing the water phase.
본 발명에 따른 입술 화장료 조성물에서 수상은 바람직하게는 특정 효능을 가진 유효성분을 포함하는데, 이때, 상기 유효성분은 산화 방지, 보습, 미백 또는 주름 개선 등과 같은 특정 효능을 가지면서 물에 용해될 수 있는 것이라면 그 종류가 크게 제한되지 않으며, 예를 들어 산화 방지 성분으로는 인산, 시트르산, 아스코르브산 등을 들 수 있고, 보습 성분으로는 폴리에틸렌글리콜, 프로필렌글리콜, 글리세린, 1,3-부틸렌글리콜, 자일리톨, 소르비톨, 말티톨, 판테놀, 콘드로이틴 황산, 히알루론산, 무코이틴 황산, 카론산, 아테로콜라겐, 콜레스테릴-12-히드록시스테아레이트, 락트산 나트륨, 담즙산염, dl-피롤리돈카르복실산염, 단쇄 가용성 콜라겐, 디글리세린(EO)PO 부가물, 자리(Rosa roxburghii) 추출물, 서양톱풀 추출물, 메리로드 추출물 등을 들 수 있다. In the lip cosmetic composition according to the present invention, the water phase preferably contains an active ingredient having a specific effect, wherein the active ingredient may be dissolved in water with specific effects such as prevention of oxidation, moisturizing, whitening, Examples of the antioxidant include phosphoric acid, citric acid, and ascorbic acid. Examples of the moisturizing component include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, But are not limited to, xylitol, sorbitol, maltitol, panthenol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, chalonic acid, atelocollagen, cholesteryl-12-hydroxystearate, sodium lactate, , Short-chain soluble collagen, diglycerin (EO) PO adduct, Rosa roxburghii extract, wormwood extract, and Meryl road extract.
본 발명에 따른 화장료에서 수상을 구성하는 보습 성분은 다른 성분과의 조화 측면을 고려할 때 프로필렌글리콜(Propylene glycol), 글리세린(Glycerin), 및 판테놀(Panthenol)로 이루어진 군에서 선택되는 1종 이상으로 구성될 수 있다. 또한, 수상 내에서 특정 효능을 가진 유효성분, 특히 보습 성분의 함량은 다른 성분과의 조화 및 소정의 효능 발휘 등을 고려할 때 물 100 중량부 당 10~30 중량부인 것이 바람직하고, 15~25 중량부일 수 있다.The moisturizing component constituting the water phase in the cosmetic according to the present invention is composed of at least one member selected from the group consisting of propylene glycol, glycerin, and panthenol in consideration of harmony with other components . The content of the active ingredient having a specific effect in the aqueous phase, particularly the moisturizing ingredient, is preferably 10 to 30 parts by weight, more preferably 15 to 25 parts by weight per 100 parts by weight of water, Can be.
이 밖에도 본 발명의 입술 화장료 조성물은 필요에 따라 본 발명의 기술분야에서 통상 사용되는 검, 음이온성, 양이온성, 양쪽성 또는 비이온성 계면 활성제, 실리콘 계면 활성제, 레진, 증점제, 분산제, 산화방지제, 정유, 보존제, 향료, 중화제, 방부제, 자외선 차단체, 미용 활성제, 예컨대, 비타민, 보습제, 유연제 또는 콜라겐 보호제, 착색제, 및 그의 혼합물 중에서 선택되는 첨가제를 더 포함할 수 있다.In addition, the lip cosmetic composition of the present invention may contain, if necessary, a gum, anionic, cationic, amphoteric or nonionic surfactant, silicone surfactant, resin, thickener, dispersant, antioxidant, A preservative, a preservative, a flavoring, a neutralizing agent, an antiseptic, an ultraviolet ray group, a cosmetic active agent such as a vitamin, a moisturizer, a softener or a collagen protecting agent, a colorant, and a mixture thereof.
상기 성분들은 수용성 성분은 수상에, 유용성 성분은 유상에 배합하는 것이 바람직하다.It is preferable that the above-mentioned components are blended with water-soluble components and water-soluble components with oil-soluble components.
본 발명에 따른 입술 화장료 조성물의 제조방법은 특별히 한정되지 않으며, 해당 기술분야에서 공지된 방법에 의하여 제조될 수 있다. 구체적으로, 유성 화장료 조성물로 제조할 경우 90~120℃에서 각 성분을 호모 믹서로 혼합하는 방법을 사용할 수 있다. 유중수형 화장료 조성물로 제조할 경우 유상부 및 수상부를 각각 제조한 다음 교반 하에 유상부에 수상부를 첨가하고 호모 믹서를 이용하여 교반하는 방법을 사용할 수 있다.The method of manufacturing the lip cosmetic composition according to the present invention is not particularly limited and may be manufactured by a method known in the art. Specifically, when the oily cosmetic composition is prepared, a method of mixing the components at 90 to 120 ° C with a homomixer can be used. When preparing a water-in-oil type cosmetic composition, it is possible to use a method in which an oil phase part and a water phase part are prepared respectively, and then a water phase part is added to the oil phase part with stirring and the mixture is stirred using a homomixer.
본 발명에 따른 입술 화장료 조성물의 제형은 특별히 한정되지 않으나 고형 스틱 타입인 것이 바람직하다. 구체적으로, 립스틱, 립 라이너, 립밤, 립 크레용, 립 펜슬, 립 글로스 등일 수 있고, 바람직하기로 립스틱이다.The formulation of the lip cosmetic composition according to the present invention is not particularly limited, but is preferably a solid stick type. Specifically, it can be a lipstick, a lip liner, a lip balm, a lip crayon, a lip pencil, a lip gloss, and the like, and is preferably lipstick.
본 발명의 입술 화장료 조성물을 포함하는 고형 스틱 타입 입술 도포용 화장품의 형상은 특별히 제한되지 않고, 다양한 지름을 갖도록 구성될 수 있다. 특히, 립스틱과 립 라이너로서의 역할을 동시에 수행할 수 있도록 하기 위하여 도 1과 같이 지름이 예를 들어 2 내지 5mm, 바람직하게는 예를 들어 3 내지 4 mm인 것이 바람직하고, 커팅 각도는 50도 이하, 바람직하기로 15~50도가 되도록 제조하는 것이 바람직하다.The shape of the solid stick type liposome coating composition containing the lip cosmetic composition of the present invention is not particularly limited and may be configured to have various diameters. Particularly, in order to simultaneously perform the role as lipstick and lip liner, it is preferable that the diameter is, for example, 2 to 5 mm, preferably 3 to 4 mm, for example, as shown in Fig. 1, , Preferably from 15 to 50 degrees.
이와 같이 작은 지름 및 가파른 커팅 각도를 만족할 때, 날카로운 끝부분으로는 입술 라인의 섬세한 표현이 가능하고, 넓은 빗면으로는 한 번에 넓은 부분에 도포가 가능하게 된다. 이에 립 라이너가 별도로 필요하지 않으며 빠르고 쉽게 입술 화장이 가능하여 화장 시간을 단축할 수 있는 장점이 있다.When such a small diameter and a steep cutting angle are satisfied, a sharp lip edge can be expressed in a delicate manner, and a wide bevel can be applied to a wide area at one time. There is no need for a lip liner, and quick and easy lips makeup is possible, which can shorten the makeup time.
특히, 본 발명의 입술 화장료 조성물은 100 내지 300 gf의 높은 경도를 가지므로, 지속적인 사용에도 상기와 같은 단면 형상을 일정하게 유지할 수 있다. 따라서 립 펜슬과 같이 사용 중 끝부분을 재건시켜야 하는 번거로움이 따르지 않아 사용 편의성이 증대된다.Particularly, since the lip cosmetic composition of the present invention has a high hardness of 100 to 300 gf, the cross-sectional shape as described above can be kept constant even after continuous use. Therefore, the ease of use is increased because the end portion of the lip pencil is not required to be rebuilt like a pencil.
이하 본 발명의 이해를 돕기 위하여 바람직한 실시예를 제시하나, 하기 실시예는 본 발명을 예시하는 것일 뿐 본 발명의 범주 및 기술사상 범위 내에서 다양한 변경 및 수정이 가능함은 당업자에게 있어서 명백한 것이며, 이러한 변경 및 수정이 첨부된 특허청구범위에 속하는 것도 당연한 것이다.It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the scope and spirit of the invention as disclosed in the accompanying claims. Changes and modifications may fall within the scope of the appended claims.
[실시예][Example]
제조예 1: 유성 화장료 조성물의 제조Production Example 1: Preparation of oily cosmetic composition
하기 표 1의 각 성분을 115 ℃에서 호모 믹서로 혼합하여 유성 화장료 조성물을 제조하였다(단위: 중량%). Each component of the following Table 1 was mixed at 115 캜 with a homomixer to prepare a oily cosmetic composition (unit: wt%).
표 1에서, 순번 5의 고융점 왁스는 녹는점 100℃, 중량평균분자량 500~700 g/mol의 분자 내 하나 이상의 히드록시기를 갖는 선형 폴리에틸렌 왁스 및 녹는점 95℃ 중량평균분자량 600~800 g/mol의 분자 내 하나 이상의 C1 내지 C5의 알킬기를 갖는 선형 폴리에틸렌 왁스가 1:1 비율로 혼합된 것이다. 순번 6의 비치환된 선형 폴리에틸렌 왁스의 녹는점은 100℃, 중량평균분자량은 500 g/mol이다.In Table 1, the high melting point wax having a melting point of 100 DEG C, a linear polyethylene wax having at least one hydroxyl group in a molecule having a weight average molecular weight of 500 to 700 g / mol and a melting point of 95 DEG C and a weight average molecular weight of 600 to 800 g / mol Of a linear polyethylene wax having at least one C1 to C5 alkyl group in the molecule thereof in a ratio of 1: 1. The melting point of the unsubstituted linear polyethylene wax of No. 6 is 100 占 폚 and the weight average molecular weight is 500 g / mol.
제조예 2: 립스틱의 제조Production Example 2: Production of lipstick
상기 제조예 1에서 제조된 유성 화장료 조성물을 95 ℃ 이상 가온하여 녹인 다음, 지름이 4 mm인 립스틱 모양의 성형 틀에 부어서 굳힌 뒤 냉각(-20℃, 10분)하여 용기에 내용물을 결합시켰다. 용기에 결합된 내용물은 30 ℃의 항온조에서 12시간 이상 보관하였다.The oil-based cosmetic composition prepared in Preparation Example 1 was dissolved by heating at 95 ° C or higher, poured into a lipstick-shaped mold having a diameter of 4 mm and hardened, followed by cooling (at -20 ° C for 10 minutes) to bind the contents to the container. The contents bound to the container were stored in a thermostat at 30 DEG C for at least 12 hours.
실험예 1: 립스틱 경도 측정Experimental Example 1: Measurement of lipstick hardness
상기 지름이 11mm인 립스틱 모양의 성형 틀을 사용한 것을 제외하고는 제조예 2와 동일한 방법으로 제조된 립스틱에 대하여 다음과 같은 방법으로 경도를 측정하였다. The hardness of the lipstick prepared in the same manner as in Production Example 2 was measured in the following manner, except that the lipstick-shaped forming die having a diameter of 11 mm was used.
30 ℃의 항온조에 보관되어 있던 립스틱을 꺼내어 즉시 용기를 세운 뒤 내용물을 꺼내고 내용물 중앙에 피아노 줄(두께0.2 mm)을 위치하게 하였다. 상기 피아노 줄을 20 mm/min의 속도로 이동시키며 내용물을 20 mm 정도 절단하면서, 이동거리 중 10~19.5 ㎜ 지점에서 받는 힘을 측정(Rheometer CR-300, SUN Scientific Co.,LTD)하고 그 평균값을 구하여 립스틱의 경도를 도출하였다.The lipstick stored in a thermostatic chamber at 30 ° C was taken out immediately and the container was immediately set up, the contents were taken out, and a piano string (thickness 0.2 mm) was placed in the center of the contents. The piano cord was moved at a speed of 20 mm / min and the contents were cut about 20 mm. The force was measured at 10 to 19.5 mm of the moving distance (Rheometer CR-300, SUN Scientific Co., LTD) And the hardness of the lipstick was determined.
그 결과, 실시예 1 및 비교예 2는 190 gf, 비교예 1은 150 gf로 측정되어, 모두 100 gf 이상의 높은 경도를 나타내는 것을 확인할 수 있었다.As a result, it was confirmed that 190 gf of Example 1 and Comparative Example 2 were measured and 150 gf of Comparative Example 1, indicating that all of them had a high hardness of 100 gf or more.
실험예 2: 관능평가Experimental Example 2: Sensory evaluation
전문 패널 평가단 10명에게 제조예 2에서 제조된 립스틱의 발색 정도, 부드러운 발림 정도 및 도포 후 입술 끈적임 정도를 평가하도록 하였다. 평가는 각 항목에 대하여 5점 만점으로, 해당 속성이 강할수록 높은 숫자로 나타내도록 하였다. 하기 표 2에 그 결과(평균값)를 나타내었다.10 panelists of professional panel evaluators evaluated the degree of color development, the degree of softening of the lipstick prepared in Preparation Example 2, and the degree of lip sticking after application. For each item, the evaluation was out of 5 points, and the higher the number of items, the higher the number. The results (average value) are shown in Table 2 below.
상기 표 2를 참조하면, 실시예 1은 경도가 높음에도 발림성이 매우 부드럽게 나타나는 것을 확인할 수 있다. 그러나, 비교예 1은 실시예 1 보다 낮은 경도를 나타냄에도 발림성 항목에서 실시예 1에 비하여 낮은 점수를 획득하였으며, 실시예 1과 경도가 동일한 비교예 2의 경우는 발림성이 매우 떨어지는 것으로 평가되었다. 또한, 실시예 1은 비교예 1 및 2에 비하여 도포 후의 입술 끈적임이 적고, 발색력 또한 우수한 것으로 나타났다.Referring to Table 2, it can be seen that Example 1 shows very smooth even when hardness is high. However, Comparative Example 1 showed lower hardness than Example 1 in terms of hardness even though it showed lower hardness than Example 1, and Comparative Example 2, which has the same hardness as Example 1, was evaluated to have poor wettability. In addition, Example 1 showed less lips tackiness after application than Comparative Examples 1 and 2, and showed excellent coloring power.
상기 결과로부터, 입술 화장료 조성물에 고융점 왁스를 사용할 경우 기존의 왁스를 사용할 경우와 비교하여 동등한 경도에서 발림성이 현저히 개선되며, 끈적임이 적고 발색력 특성을 향상시킬 수 있음을 확인할 수 있다.From the above results, it can be seen that when the high-melting-point wax is used in the lip cosmetic composition, the spreadability is remarkably improved at the same hardness as compared with the case of using the conventional wax, the stickiness is small and the coloring power property is improved.
본 발명의 입술 화장료 조성물은 내구성이 우수하여 6 mm 이하의 초슬림 형태의 립스틱 제조에 적합하며, 사용에 따른 모양의 변형이 쉽게 일어나지 않는다. 이에, 본 발명의 입술 화장료 조성물로 제조된 립스틱은 단면 일부분을 좁게 성형함으로써 립스틱과 립 라이너로서의 역할을 동시에 수행할 수 있다.The lip cosmetic composition of the present invention is excellent in durability and is suitable for manufacturing lipsticks of an ultra slim shape of 6 mm or less and does not easily deform the shape according to use. Accordingly, the lipstick made of the lip cosmetic composition of the present invention can simultaneously perform a role as lipstick and lip liner by narrowly forming a part of a cross section.
Claims (8)
상기 고융점 왁스는 분자 내 하나 이상의 히드록시기를 갖는 선형 폴리에틸렌 왁스; 및 분자 내 하나 이상의 C1 내지 C5의 알킬기를 갖는 선형 폴리에틸렌 왁스;로 이루어지는 군에서 선택되는 1종 이상을 포함하고,
상기 조성물의 경도는 100 내지 300 gf인 것을 특징으로 하는 입술 화장료 조성물.1. A lip cosmetic composition comprising a high melting point wax,
Wherein the high melting point wax is a linear polyethylene wax having at least one hydroxyl group in the molecule; And linear polyethylene wax having at least one C1 to C5 alkyl group in the molecule,
Wherein the composition has a hardness of 100 to 300 gf.
상기 고융점 왁스의 녹는점은 95℃ 이상인 것을 특징으로 하는 입술 화장료 조성물.The method according to claim 1,
Wherein the high melting point wax has a melting point of 95 ° C or higher.
상기 고융점 왁스는 중량평균분자량이 500 내지 800 g/mol인 것을 특징으로 하는 입술 화장료 조성물.The method according to claim 1,
Wherein the high melting point wax has a weight average molecular weight of 500 to 800 g / mol.
상기 고융점 왁스는 조성물 내 5 내지 20 중량%로 포함되는 것을 특징으로 하는 입술 화장료 조성물.4. The method according to any one of claims 1 to 3,
Wherein the high melting point wax is contained in an amount of 5 to 20% by weight in the composition.
상기 입술 화장료 조성물은 액체 유지, 고체 유지, 왁스류, 탄화수소계 오일, 고급 지방산, 고급 알코올, 합성 에스테르유, 및 실리콘유로 이루어지는 군에서 선택되는 1종 이상을 더 포함하는 것을 특징으로 하는 입술 화장료 조성물.The method according to claim 1,
Wherein the lip cosmetic composition further comprises at least one member selected from the group consisting of liquid retention, solid retention, waxes, hydrocarbon oils, higher fatty acids, higher alcohols, synthetic ester oils and silicone oils. .
상기 입술 화장료 조성물은 유성 또는 유중수형 화장료 조성물인 것을 특징으로 하는 입술 화장료 조성물.The method according to claim 1,
Wherein the lip cosmetic composition is an oily or water-in-oil type cosmetic composition.
상기 입술 도포용 화장품은 지름이 2 내지 5 mm이고, 커팅 각도가 50도 이하인 것을 특징으로 하는 입술 도포용 화장품. 8. The method of claim 7,
Wherein the cosmetic for lip application has a diameter of 2 to 5 mm and a cutting angle of 50 degrees or less.
Priority Applications (3)
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KR1020160126215A KR102610442B1 (en) | 2016-09-30 | 2016-09-30 | Lip cosmetic compostion |
PCT/KR2017/010587 WO2018062802A1 (en) | 2016-09-30 | 2017-09-26 | Lip cosmetic composition |
TW106133566A TW201815437A (en) | 2016-09-30 | 2017-09-29 | Lip cosmetic composition and solid stick type lip sticking cosmetic |
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KR1020160126215A KR102610442B1 (en) | 2016-09-30 | 2016-09-30 | Lip cosmetic compostion |
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KR20200067572A (en) | 2018-12-04 | 2020-06-12 | (주)아모레퍼시픽 | Oil in water type composition having high gloss |
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JP2002284645A (en) * | 2001-03-28 | 2002-10-03 | Kose Corp | Cosmetics for lips |
KR20070083336A (en) | 2006-02-21 | 2007-08-24 | 주식회사 엘지생활건강 | Lipstick composition |
KR101097832B1 (en) * | 2003-10-15 | 2011-12-23 | 가부시키가이샤 코세 | Oily Solid Cosmetic |
JP2014034522A (en) * | 2012-08-07 | 2014-02-24 | Kao Corp | Lip cosmetic composition |
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AU2005271921B2 (en) * | 2004-07-12 | 2008-11-27 | E-L Management Corp. | High gloss non-feathering lip product |
KR101060881B1 (en) * | 2008-11-13 | 2011-08-31 | (주)아모레퍼시픽 | Matte cosmetic composition for lip makeup or lip care |
FR2964566B1 (en) * | 2010-09-13 | 2013-07-19 | Chanel Parfums Beaute | COSMETIC COMPOSITION FOR LIP MAKE-UP |
KR101918798B1 (en) * | 2011-12-21 | 2019-02-08 | 가부시키가이샤 코세 | Stick-type cosmetic holder |
BR112015017568B1 (en) * | 2013-03-25 | 2019-12-24 | Oreal | solid anhydrous composition comprising a high melting wax and silica airgel |
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2016
- 2016-09-30 KR KR1020160126215A patent/KR102610442B1/en active IP Right Grant
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2017
- 2017-09-26 WO PCT/KR2017/010587 patent/WO2018062802A1/en active Application Filing
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JP2519469B2 (en) * | 1987-08-28 | 1996-07-31 | 株式会社コーセー | Stick cosmetics |
JP2002284645A (en) * | 2001-03-28 | 2002-10-03 | Kose Corp | Cosmetics for lips |
KR101097832B1 (en) * | 2003-10-15 | 2011-12-23 | 가부시키가이샤 코세 | Oily Solid Cosmetic |
KR20070083336A (en) | 2006-02-21 | 2007-08-24 | 주식회사 엘지생활건강 | Lipstick composition |
JP2014034522A (en) * | 2012-08-07 | 2014-02-24 | Kao Corp | Lip cosmetic composition |
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KR20200067572A (en) | 2018-12-04 | 2020-06-12 | (주)아모레퍼시픽 | Oil in water type composition having high gloss |
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WO2018062802A1 (en) | 2018-04-05 |
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KR102610442B1 (en) | 2023-12-06 |
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