CN111107835B - Emulsified hair styling composition - Google Patents
Emulsified hair styling composition Download PDFInfo
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- CN111107835B CN111107835B CN201980004564.3A CN201980004564A CN111107835B CN 111107835 B CN111107835 B CN 111107835B CN 201980004564 A CN201980004564 A CN 201980004564A CN 111107835 B CN111107835 B CN 111107835B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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Abstract
Provided is an emulsion hair styling agent composition which has excellent force for raising hair (raising force), ease of forming hair bundles, and excellent extensibility on hair. The composition is an emulsion hair care composition containing the following component (A), the following component (B) and the following component (C). Component (A): carnauba wax, ingredient (B): castor oil, ingredient (C): at least one oil agent selected from the group consisting of cyclic siloxane, methyl trimethicone, ethyl trisiloxane, octyl methicone and dimethylpolysiloxane with viscosity of 0.1-2.0 mPa.s at 25 ℃.
Description
Technical Field
The present invention relates to an emulsified hair styling composition.
Background
Conventionally, as a hair cosmetic composition having a characteristic that a hair can be styled without fixing the hair, an emulsion hair styling composition such as a hair wax (styling wax) has been widely used.
Specifically, for example, hair cosmetics containing a wax, a high-polymerization polyethylene glycol, and a nonionic surfactant are known (see patent document 1); hair styling compositions containing a homopolymer of vinylcaprolactam, an oily component which is solid at 25 ℃, an oily component which is liquid at 25 ℃ and water (see patent document 2; hair styling materials containing waxes, specific liquid oils, volatile liquid oils and water (see patent document 3; hair styling materials containing waxes which are solid at 20 ℃ and volatile silicones (see patent document 4) and the like.
Documents of the prior art
Patent literature
Patent document 1: japanese laid-open patent publication No. 2002-
Patent document 2: japanese patent laid-open publication No. 2004-91406
Patent document 3: japanese patent laid-open publication No. 2005-239677
Patent document 4: japanese laid-open patent publication No. 2007-15935
Disclosure of Invention
Problems to be solved by the invention
As an emulsion hair styling composition such as a hair wax, an emulsion hair styling composition having excellent force for raising hair (raising force) and excellent extensibility on hair is required. Further, for example, from the viewpoint of emphasizing the flow direction of hair, an emulsion hair styling agent composition excellent in ease of hair bundle formation is required.
Accordingly, an object of the present invention is to provide an emulsified hair styling agent composition which has excellent force for raising hair (raising force), ease of formation of hair bundles, and excellent extensibility on hair.
Means for solving the problems
As a result of intensive studies to achieve the above object, the inventors of the present invention have found that a composition containing component (a): carnauba wax, component (B): castor oil, component (C): an emulsion hair dressing composition containing at least one oil agent selected from the group consisting of cyclic siloxanes, methyl trimethicones, ethyl trisiloxanes, octyl methicones and dimethylpolysiloxanes having a viscosity of 0.1 to 2.0 mPas at 25 ℃ can provide an emulsion hair dressing composition having excellent lifting force, ease of hair bundle formation and excellent hair extension. The present invention has been completed based on the above findings.
That is, the present invention provides an emulsion hair styling agent composition containing the following component (a), the following component (B), and the following component (C).
Component (A): carnauba wax
Component (B): castor oil
Component (C): one or more oil agents selected from the group consisting of cyclic siloxane, methyltrimethylsiloxane, ethyltrisiloxane, trisiloxane, octylmethicone and dimethylpolysiloxane having a viscosity of 0.1 to 2.0 mPas at 25 ℃
The above-mentioned emulsion hair styling composition preferably contains the following component (D).
Component (D): polyglycerol polyricinoleate
The above-mentioned emulsified hair styling composition is preferably a hair wax.
Effects of the invention
The emulsified hair styling agent composition of the present invention is excellent in hair lifting force, ease of hair bundle formation, and hair extension. In the present specification, the force for raising the hair is referred to as "raising force". Further, a force that tends to concentrate some hairs to form a bundle of hairs is referred to as "ease of forming a bundle of hairs". Further, the feeling of less resistance and easy uniform spreading when the emulsified hair setting composition is applied to hair is referred to as "spreading on hair".
Detailed Description
The emulsified hair styling agent composition of the present invention contains at least carnauba wax, castor oil, and a specific oil agent. The specific oil agent is at least one oil agent selected from the group consisting of cyclic siloxane, methyl trimethicone, ethyl trisiloxane, octyl methicone and dimethylpolysiloxane having a viscosity of 0.1 to 2.0 mPas at 25 ℃. In the present specification, the carnauba wax is sometimes referred to as "component (a)", the castor oil is sometimes referred to as "component (B)", and one or more oil agents selected from the group consisting of cyclic siloxane, methyltrimethylsiloxane, ethyltrisiloxane, trisiloxane, octylmethicone and dimethylpolysiloxane having a viscosity of 0.1 to 2.0mPa · s at 25 ℃ are sometimes referred to as "component (C)".
That is, the emulsion hair styling agent composition of the present invention contains at least the component (a), the component (B) and the component (C). The emulsion hair styling agent composition of the present invention may contain components other than the components (a) to (C). In addition, each component contained in the emulsion hair styling agent composition of the present invention, for example, only one component may be used, or two or more components other than the components (a), (B), (C), and (a) to (C) may be used.
[ component (A) ]
The carnauba wax as the component (a) is a natural plant wax collected from leaves and the like of a plant called carnauba (copernia cerifera Martius). The carnauba wax is obtained under the INCI name (INCI: International Nomenclature of Cosmetic ingredients): a compound represented by Copernicia Cerifera (Carnauba) Wax. The component (A) may be used alone or in combination of two or more.
Examples of commercially available products of component (A) include the trade name "TOWAX-1F 8" (manufactured by Toyo chemical Co., Ltd.), the trade name "carnauba wax No. 1" (manufactured by Kagaku corporation), and the trade name "carnauba wax purified No. 1" (manufactured by Cerarica NODA, Ltd.).
The content of the component (a) in the emulsion hair styling composition of the present invention is not particularly limited, but is preferably 1.0 to 25.0% by mass, more preferably 2.0 to 20.0% by mass, and still more preferably 3.0 to 15.0% by mass, based on 100% by mass of the emulsion hair styling composition of the present invention. If the content is 1.0 mass% or more, the raising force and the ease of formation of tufts are further improved. On the other hand, if the content is 25.0 mass% or less, the hair extensibility is further improved. The content of the component (a) is the total content of all the components (a) in the emulsion hair styling composition of the present invention.
[ component (B) ]
The castor oil as the component (B) is one of vegetable oils collected from seeds of castor bean of the family euphorbiaceae. The above castor oil is under the INCI name: a compound represented by Ricinus Communis (Castor) Seed Oil. The component (B) may be used alone or in combination of two or more.
Commercially available products of component (B) include, for example, a product name of "castor oil マルトク A" and a product name of "RICOS CO-EX" (all manufactured by Ito oil Co., Ltd.).
The content of the component (B) in the emulsified hair styling agent composition of the present invention is not particularly limited, but is preferably 0.5 to 30.0% by mass, more preferably 1.0 to 25.0% by mass, and still more preferably 1.5 to 20.0% by mass, based on 100% by mass of the emulsified hair styling agent composition of the present invention. If the content is 0.5% by mass or more, the raising force and the easiness of formation of tufts are further improved. On the other hand, when the content is 30.0 mass% or less, the extensibility on the palm is improved, and the feeling of use is further improved. The content of the component (B) is the total content of all the components (B) in the emulsion hair styling composition of the present invention.
The mass ratio of the content of the component (B) to the content of the component (a) [ content of the component (B)/content of the component (a) ] in the emulsified hair styling agent composition of the present invention is preferably 0.05 to 20.0, more preferably 0.1 to 10.0, and further preferably 0.2 to 2.0. When the mass ratio is 0.05 or more, the ease of forming tufts is further improved. If the mass ratio is 20.0 or less, the rising force is further improved.
[ component (C) ]
The component (C) is at least one oil agent selected from the group consisting of cyclic siloxane, methyl trimethicone, ethyl trisiloxane, octyl methicone and dimethylpolysiloxane with viscosity of 0.1-2.0 mPas at 25 ℃. Examples of the cyclic siloxane include decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, and dodecamethylcyclohexasiloxane. Among them, dimethylpolysiloxane having a viscosity of 0.1 to 2.0 mPas at 25 ℃ is preferable from the viewpoint that the hair after hairstyling is not stiff and the hand feeling is particularly excellent. The viscosity of the dimethylpolysiloxane at 25 ℃ is preferably 1.0 to 2.0 mPas. The component (C) may be used alone or in combination of two or more.
Examples of commercially available products of component (C) include a product name "SH 245 Fluid", a product name "2-1184 Fluid", a product name "SH 200 Fluid 1 CS", a product name "SH 200 Fluid 1.5 CS", and a product name "SH 200 Fluid 2 CS" (all manufactured by Tollido Corning Corp.).
The content of the component (C) in the emulsified hair styling agent composition of the present invention is not particularly limited, but is preferably 0.3 to 20.0% by mass, more preferably 1.0 to 20.0% by mass, even more preferably 2.0 to 15.0% by mass, and particularly preferably 3.0 to 10.0% by mass, based on 100% by mass of the emulsified hair styling agent composition of the present invention. When the content is 0.3% by mass or more, the hair extensibility is further improved. On the other hand, when the content is 20.0 mass% or less, the lowering of the setting force is suppressed, and the setting force and the ease of forming the hair bundle are further excellent. The content of the component (C) is the total content of all the components (C) in the emulsion hair styling composition of the present invention.
[ Water ]
The emulsified hair styling agent composition of the present invention preferably contains water. The water is not particularly limited, and is preferably purified water. The content of water in the emulsified hair styling agent composition of the present invention is not particularly limited, and is preferably 10.0 to 90.0% by mass, more preferably 20.0 to 80.0% by mass, and still more preferably 30.0 to 60.0% by mass, based on 100% by mass of the emulsified hair styling agent composition of the present invention.
[ component (D) ]
The emulsified hair styling composition of the present invention preferably further contains polyglycerol polyricinoleate. In the present specification, the polyglycerol polyricinoleate may be referred to as "component (D)". When the emulsified hair styling agent composition of the present invention contains the component (D), the ease of forming hair bundles can be further improved while maintaining the lifting force. The component (D) may be used alone or in combination of two or more.
The polyglycerol polyricinoleate is an ester of condensed ricinoleic acid and polyglycerol. Examples of the component (D) include polyglycerol-3 polyricinoleate, polyglycerol-5 polyricinoleate, polyglycerol-6 polyricinoleate and polyglycerol-10 polyricinoleate. Among them, polyglycerol-6 polyricinoleate is preferable.
The component (D) is commercially available under the trade name "POEM PR-300" (manufactured by Rikagaku corporation) or "S-Face CR-1001" (manufactured by Sakazaku Kagaku Kogyo Co., Ltd).
The content of the component (D) in the emulsified hair styling composition of the present invention is not particularly limited, but is preferably 0.1 to 10.0% by mass, more preferably 0.3 to 8.0% by mass, and still more preferably 0.5 to 5.0% by mass, based on 100% by mass of the emulsified hair styling composition of the present invention. When the content is 0.1% by mass or more, the ease of forming tufts is further improved. On the other hand, if the content is 10.0 mass% or less, the raising force and the ease of formation of the tufts are more easily maintained. The content of the component (D) is the total content of all the components (D) in the emulsion hair styling agent composition of the present invention.
[ component (E) ]
The emulsified hair styling composition of the present invention preferably further contains a hydrocarbon having a melting point of 50 ℃ or higher and lower than 65 ℃. In the present specification, the hydrocarbon having a melting point of 50 ℃ or higher and lower than 65 ℃ may be referred to as "component (E)". When the emulsified hair styling agent composition of the present invention contains the component (E), the generation of hair roughness and hair stagnation after application to hair can be further alleviated, and the hair can be made more ductile. The component (E) may be used alone or in combination of two or more.
Examples of the component (E) include hydrocarbon waxes such as ceresin, paraffin, microcrystalline wax, synthetic wax, and polyethylene. Among them, paraffin wax and microcrystalline wax are preferable.
Examples of commercially available products of component (E) include a product name of "Paraffin Wax-125" (melting point: 53 ℃ C.), a product name of "Paraffin Wax-135" (melting point: 59 ℃ C.), a product name of "SP-0145" (melting point: 62 ℃ C.), and a product name of "Paraffin Wax-145" (melting point: 63 ℃ C.) (all manufactured by Japan Seika Seisaku-Sho K.K.).
The content of the component (E) in the emulsion hair styling composition of the present invention is not particularly limited, but is preferably 0.1 to 15.0% by mass, more preferably 0.1 to 10.0% by mass, even more preferably 0.5 to 8.0% by mass, and particularly preferably 1.0 to 6.0% by mass, based on 100% by mass of the emulsion hair styling composition of the present invention. When the content is 0.1% by mass or more, the generation of hair-dryness and hair-stagnation after application to hair can be further alleviated, and the hair can be further excellent in the extensibility. On the other hand, if the content is 15.0 mass% or less, the lowering of the setting force is suppressed, and the setting force and the ease of forming the hair bundle are further improved. The content of the component (E) is the total content of all the components (E) in the emulsion hair styling composition of the present invention.
[ other ingredients ]
The emulsion hair styling agent composition of the present invention may contain components (other components) other than the components (a) to (E) and water within a range not impairing the effects of the present invention. The other components are not particularly limited, and examples thereof include components generally used in cosmetics and quasi drugs. Specific examples thereof include surfactants other than the component (D) (cationic surfactants, anionic surfactants, nonionic surfactants, amphoteric surfactants, and the like other than the component (D)); lower alcohols such as ethanol; oily components other than components (a) to (C) and (E) (polyhydric alcohols other than components (a) to (C) and (E), silicone oils, ester oils, waxes, vegetable oils, hydrocarbons which are solid at 25 ℃ and have a melting point of less than 50 ℃, hydrocarbons having a melting point of 65 ℃ or higher, hydrocarbon oils, fats and oils, higher alcohols, higher fatty acids, and the like); thickeners such as carboxyvinyl polymer, acrylic acid/alkyl methacrylate copolymer, hydroxymethyl cellulose, hydroxypropyl methyl cellulose, xanthan gum, etc.; a fragrance; an ultraviolet absorber; an antioxidant; a metal ion chelating agent; film-forming polymer compounds such as polyvinylpyrrolidone; kaolin, silica, talc, and other powders; a pigment; a pigment; a dye; vitamins; amino acids; an astringent; a whitening agent; an animal or plant extract; an acid; alkali, and the like.
The emulsified hair styling agent composition of the present invention may contain at least one of a hydrocarbon oil and an ester oil (a hydrocarbon oil and/or an ester oil) as the other component, from the viewpoint of further improving the extensibility in the palm and hair. The hydrocarbon oil and/or ester oil is preferably in a liquid state at 25 ℃. In the present specification, "liquid at 25" means the following properties: when 50g of a sample (oil solution) was put into a glass bottle having a radius of 2cm and a height of 7cm and the glass bottle was inverted at 25 ℃, the sample was dropped from the glass bottle within 5 minutes from immediately after the inversion. The hydrocarbon oil and/or ester oil may be used alone or in combination of two or more.
Examples of the hydrocarbon oil include α -olefin oligomers, mineral oils, hydrogenated polyisobutene, isododecane, light isoparaffins, light liquid isoparaffins, and liquid paraffin.
Examples of the ester oil include ethyl oleate, isopropyl myristate, isopropyl palmitate, myristyl myristate, cetyl palmitate, 2-ethylhexyl palmitate, oleyl oleate, octyldodecyl myristate, octyldodecyl oleate, ethyl isostearate, isopropyl isostearate, propylene glycol isostearate, cetyl 2-ethylhexanoate, glyceryl tri-2-ethylhexanoate, glyceryl tri (octanoate/decanoate), glyceryl tri-isopalmitate, pentaerythritol tetra-2-ethylhexanoate, diisopropyl adipate, isocetyl octanoate, isostearyl octanoate, isocetyl isostearate, octyl dodecyl isostearate, octyldodecyl dimethyl octanoate, isononyl isononanoate, pentaerythritol tetra-octanoate, isopropyl octanoate, octyl dodecyl isostearate, octyl dodecyl dimethyl octanoate, octyl dodecyl isononanoate, pentaerythritol tetra-octanoate, Pentaerythritol tetraisostearate, and the like.
The content of the hydrocarbon oil and/or ester oil in the emulsified hair styling agent composition of the present invention is not particularly limited, but is preferably 0.5 to 30.0% by mass, more preferably 1.0 to 25.0% by mass, and still more preferably 3.0 to 20.0% by mass, based on 100% by mass of the emulsified hair styling agent composition of the present invention. When the content is 0.5% by mass or more, the extensibility on the palm and hair is more excellent. On the other hand, if the content is 30.0 mass% or less, the raising force and the ease of formation of the tufts can be further maintained. The content of the above hydrocarbon oil and/or ester oil is the total of the contents of all the hydrocarbon oils and ester oils in the emulsion hair setting composition of the present invention.
The emulsion hair styling agent composition of the present invention may contain a wax other than the component (a) as the other component from the viewpoint of adjusting the feel of the hair after application. Examples of the wax include candelilla wax, rice bran wax, beeswax, and sunflower seed wax. The content of the wax in the emulsified hair styling agent composition of the present invention is not particularly limited, and is preferably 0.5 to 20.0% by mass, more preferably 1.0 to 15.0% by mass, and even more preferably 1.5 to 10.0% by mass, based on 100% by mass of the emulsified hair styling agent composition of the present invention, from the viewpoint of adjusting the feel of hair.
Examples of the nonionic surfactant include sorbitan fatty acid esters, glycerin fatty acid esters, and alkylene oxide adducts thereof, polyglycerol fatty acid esters, polyoxyalkylene alkyl ethers, polyoxyalkylene fatty acid esters, polyoxyalkylene alkylphenols, polyoxyethylene sorbitol fatty acid esters, polyoxyethylene alkylbenzaldehyde condensates, polyoxyethylene sterols and derivatives thereof, polyoxyethylene lanolin and derivatives thereof, polyoxyethylene beeswax derivatives, sugar esters, polyoxyethylene hydrogenated castor oil, and polyoxyethylene castor oil.
Examples of the sorbitan fatty acid ester include sorbitan monooleate, sorbitan monostearate, sorbitan monoisostearate, sorbitan monopalmitate, sorbitan monolaurate, sorbitan trioleate, sorbitan tristearate, sorbitan sesquistearate, sorbitan sesquioleate, sorbitan sesquiisostearate, and sorbitan coconut oil fatty acid ester. Examples of the alkylene oxide adduct of the sorbitan fatty acid ester include polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monoisostearate, polyoxyethylene sorbitan monoloco fatty acid ester, polyoxyethylene sorbitan tristearate, and polyoxyethylene sorbitan trioleate.
The glycerin fatty acid ester includes both a monoglyceride and a polyglycerin fatty acid ester. Examples of the monoglyceride fatty acid ester include glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, glyceryl monooleate, glyceryl monocerucate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, and glyceryl dianhydronate. Examples of the polyglycerin fatty acid ester include polyglycerin fatty acid esters having a polymerization degree of 2 to 10 such as a monoglyceride of a fatty acid ester of a monoglyceride of a fatty acid having a polymerization degree of 2 to 10, such as diglycerol monocaprylate, decaglycerol monocaprylate, hexaglycerol monolaurate, decaglycerol monolaurate, poly (4 to 10) glycerol monolaurate, decaglycerol monomyristate, decaglycerol monostearate, decaglycerol monoisostearate, poly (2 to 10) glycerol monostearate, diglycerol monooleate, hexaglycerol monooleate, diglycerol sesquioleate, poly (2 to 10) glycerol diisostearate, poly (6 to 10) glycerol distearate, diglycerol triisostearate, and poly (10) glycerol tristearate. Examples of the alkylene oxide adduct of a glycerin fatty acid ester include polyoxyethylene glyceryl monostearate and polyoxyethylene glyceryl monooleate.
Examples of the polyoxyalkylene fatty acid ester include polyethylene glycol fatty acid esters such as polyethylene glycol monooleate, polyethylene glycol monostearate, and polyethylene glycol monolaurate; propylene glycol fatty acid esters such as propylene glycol monostearate, propylene glycol monolaurate and propylene glycol monooleate.
Examples of the polyoxyalkylene alkyl ether include polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxypropylene cetyl ether, polyoxypropylene isocetyl ether, polyoxypropylene stearyl ether, and polyoxypropylene oleyl ether.
Examples of the anionic surfactant include higher fatty acid soaps, alkyl sulfate ester salts, alkyl phosphates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkylphenyl ether sulfates, alkyl ether phosphate esters, alkyl ether carboxylates, acyl methyl taurates, N-acyl-N-methyl- β -alanates, N-acyl glycinates, N-acyl glutamates, polyoxyethylene alkyl carboxylates, alkylphenyl ether sulfonates, alkylsulfosuccinic acid and its salts, N-acyl sarcosines and its salts, and polyoxyethylene coconut fatty acid monoethanolamide sulfates.
Examples of the cationic surfactant include amine salts such as alkylamine salts, fatty acid amide salts, and ester-containing tertiary amine salts, alkyl quaternary ammonium salts such as monoalkyl quaternary ammonium salts, dialkyl quaternary ammonium salts, trialkyl quaternary ammonium salts, and benzalkonium chloride quaternary ammonium salts, cyclic quaternary ammonium salts such as alkylpyridinium salts, and benzethonium chloride.
Examples of the amphoteric surfactant include glycine-type amphoteric surfactants such as alkyl glycinate, carboxymethyl glycinate and N-acylaminoethyl-N-2-hydroxyethyl glycinate, aminopropionic acid-type amphoteric surfactants such as alkyl aminopropionate and alkyl iminodipropionate, aminoacetic acid betaine-type amphoteric surfactants such as alkyl dimethylaminoacetic acid betaine and fatty acid amide propyl dimethylaminoacetic acid betaine, and sulfobetaine-type amphoteric surfactants such as alkyl hydroxysulfobetaine.
The content of the surfactant other than the component (D) in the emulsion hair styling agent composition of the present invention is not particularly limited, and is preferably 0.5 to 15.0% by mass, more preferably 1.0 to 10.0% by mass, based on 100% by mass of the emulsion hair styling agent composition of the present invention. When the content is 0.5% by mass or more, the emulsion stability is further excellent. On the other hand, if the content is 15.0% by mass or less, the feeling of use is further excellent.
Examples of the thickener include water-soluble natural polymers, semi-synthetic polymers, and synthetic polymers. Examples of the water-soluble natural polymer include gum arabic, tragacanth gum, guar gum, locust bean gum, karaya gum, irish moss, quince seed gum, gelatin, shellac, rosin, casein, and the like. Examples of the semi-synthetic polymer having water solubility include sodium carboxymethylcellulose, hydroxyethylcellulose, methylcellulose, ethylcellulose, sodium alginate, ester gum, nitrocellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, crystalline cellulose and the like. Examples of the water-soluble synthetic polymer include polyvinyl alcohol, sodium polyacrylate, carboxyvinyl polymer, acrylic acid/methacrylic acid ester copolymer, polyvinyl methyl cellulose, polyamide resin, and polyethylene glycol. Among these, water-soluble synthetic polymers are preferable, and carboxyvinyl polymers and acrylic acid/methacrylic acid ester copolymers are more preferable.
When a carboxyvinyl polymer or an acrylic acid/methacrylic acid ester copolymer is used as a thickener, it is usually neutralized with an alkaline substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine; inorganic bases such as ammonia, sodium hydroxide, and potassium hydroxide; basic amino acids such as arginine, and the like. The amount of the basic substance added is an amount sufficient to neutralize the carboxyvinyl polymer and the acrylic acid/methacrylic acid ester copolymer, and may be appropriately blended depending on the kind and the amount of these components used.
When the emulsified hair styling agent composition of the present invention contains a thickener, the content of the thickener in the emulsified hair styling agent composition of the present invention is not particularly limited, and is preferably 0.01 to 1.5% by mass, more preferably 0.1 to 0.5% by mass, based on 100% by mass of the emulsified hair styling agent composition of the present invention, from the viewpoints of emulsion stability and formulation stability. The content of the thickener is the total content of all thickeners in the emulsion hair styling composition of the present invention.
The emulsion hair styling composition of the present invention is not particularly limited, and can be produced by a known or customary method. For example, the emulsion can be produced by mixing the above components and emulsifying the mixture by a phase inversion emulsification method using a homomixer or the like. The mixing and emulsification may be performed separately or simultaneously.
The emulsified hair styling agent composition of the present invention is particularly preferably a wax-like emulsified hair styling agent composition (hair wax) from the viewpoint of excellent lifting force and easiness of hair bundle formation.
The emulsified hair styling agent composition of the present invention is excellent in lifting force and easiness of hair bundle formation by using carnauba wax [ component (a) ] and castor oil [ component (B) ] in combination. Since the component (a) has a certain degree of hardness, it is excellent in lifting force, while there is a problem that the property of forming tufts is insufficient. In the present invention, particularly, by using the component (B) in addition to the component (a), flexibility and adhesiveness can be imparted to the component (a) while maintaining the hardness of the component (a). This can further improve the ease of formation of hair bundles, and can further reduce the hair hardness of the hair after the hair is styled.
Furthermore, by using one or more oil agents [ component (C) ] selected from the group consisting of cyclic siloxane, methyl trimethicone, ethyl trisiloxane, octyl methicone and dimethylpolysiloxane having a viscosity of 0.1 to 2.0mPa · s at 25 ℃, the hair-dressing agent is excellent in the extensibility on the hair, and is volatilized after being applied to the hair, so that the sticking force and the ease of formation of hair bundles by using the components (a) and (B) can be exerted.
In addition, when the component (a) and the component (B) are used as the main hair setting components, the same or more hair setting power and the same or more hair extension property can be exhibited with respect to a conventional emulsified hair setting composition containing candelilla wax as the main hair setting component, which is excellent in hair setting power (setting power and easiness of formation of hair bundles) and hair extension property on hair. As described above, according to the emulsified hair setting composition of the present invention, an emulsified hair setting composition having a hair setting effect equivalent to or more than that of a conventional emulsified hair setting composition containing candelilla wax as a main hair setting component can be produced from a different raw material composition from that of the conventional emulsified hair setting composition.
Examples
The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples. The blending amounts shown in the tables are the blending amounts of the respective components (i.e., the blending amounts of the effective components in the respective raw materials), and are expressed as "% by mass" unless otherwise specified. In addition, "-" in the amounts blended in the tables means that the component was not blended.
Examples 1 to 21 and comparative examples 1 to 5
The respective samples of examples and comparative examples were prepared in the form of hair wax by a conventional method using the components (a) to (E) and other components) described in the table to obtain an emulsion hair care composition, and the following evaluations were performed.
(evaluation)
Each of the emulsion hair styling compositions obtained in examples and comparative examples was evaluated as follows. Evaluation was performed by 3 professional judges. The evaluation results are shown in the table.
[ test example 1: evaluation of lifting force (force for lifting Hair) ]
0.75g of the emulsified hair styling composition obtained in each example and each comparative example was taken out from the palm of the hand and applied to a wig (training manikin: manufactured by YUKARI JAPAN). Coating is carried out on any left half and any right half of the wig. Then, the hair at the top of the wig is straightened so as to rise upward from the root and be concentrated. Then, the "lifting force" was evaluated according to the following evaluation criteria.
< evaluation criteria for lifting force >
O (good): the hair can be styled in such a way that the hair sticks up.
X (bad): the hairs cannot be raised.
[ test example 2: evaluation of easiness of formation of Hair bundle ]
Immediately after the evaluation of the above test example 1, the hair of the wig after hairstyling was observed, and the "ease of hair bundle formation" was evaluated according to the following evaluation criteria.
< evaluation criteria for ease of formation of Hair bundles >
Excellent (good): a well-defined tuft is formed.
O (practical): although somewhat random, tufts are formed.
X (bad): little or no tufts are formed.
[ test example 3: evaluation of extensibility in Hair
The feel of resistance when the emulsion hair setting composition was applied to hair in test example 1 was evaluated, and "extensibility on hair" was evaluated according to the following evaluation criteria.
< evaluation criteria for extensibility in Hair >
Excellent (good): the resistance feeling is not felt and the stretch can be easily made.
O (practical): slightly resistant but extensible.
X (bad): the resistance feeling is strong and difficult to extend.
The emulsified hair styling agent composition (example) of the present invention is excellent in lifting force, easiness of hair bundle formation, and extensibility on hair. On the other hand, when the component (a) was not blended and rice bran wax was used instead (comparative example 1), the standing force and ease of formation of the hair bundle were poor. In addition, when the component (B) is not blended (comparative examples 2 to 4), the ease of forming the tufts and the lifting force may be poor. In addition, when the component (C) was not blended (comparative example 5), the extensibility on hair was poor.
Further, immediately after the test example 1, when the hair after the hair dressing was contacted, the hair was noticeably hard and was unpleasant to the touch in comparative example 2. Example 15 was slightly stiff, although not unpleasant to the touch. The other examples and comparative examples were not hard and had excellent touch.
Further, after 30 minutes in the above test example 1, the hair after the haircut was visually observed. In examples and comparative examples 1 and 5, adhesion of white powder was not observed, and peeling inhibition was good. On the other hand, in comparative examples 2 to 4, adhesion of white powder was observed, and the peeling-off inhibiting property was poor.
The details of the main components shown in the table are as follows.
< ingredient (A) >
Carnauba wax: the trade name "TOWAX-1F 8" (manufactured by TOYACHE CHEMICAL CO., LTD.)
< component (B) >
Castor oil: trade name "RICOS CO-EX" (manufactured by Ivy oil Co., Ltd.)
< component (C) >
Decamethylpentasiloxane: trade name "TSF 405" (manufactured by Momentive Performance Materials Japan Co., Ltd.)
Dimethylpolysiloxane (viscosity 2mPa · s): trade name "SH 200C Fluid 2 CS" (manufactured by Torredo Corning Co., Ltd.)
Dimethylpolysiloxane (viscosity 1.5mPa · s): trade name "SH 200C Fluid 1.5 CS" (manufactured by Torredo Corning Co., Ltd.)
< component (D) >
Polyglycerol-6 polyricinoleate: trade name "POEM PR-300" (manufactured by Liyan vitamin Co., Ltd.)
< ingredient (E) >
Paraffin (melting point 53 ℃): trade name "Paraffin WAX-125" (manufactured by Japan Seiko WAX Co., Ltd.)
Paraffin (melting point 59 ℃): trade name "Paraffin WAX-135" (manufactured by Japan WAX Seiko Co., Ltd.)
Paraffin (melting point 63 ℃): trade name "Paraffin WAX-145" (manufactured by Japan WAX Seiko Co., Ltd.)
Paraffin (melting point 62 ℃): trade name "SP-0145" (manufactured by Japan wax Seiko Co., Ltd.)
< other ingredients >
Candelilla wax: trade name "purified candelilla wax R-2 CG" (manufactured by Mitsui Kabushiki Kaisha)
Rice bran wax a: trade name "TOWAX-3F 11" (manufactured by TOYACHE CHEMICAL CO., LTD.)
Rice bran wax B: trade name "TOWAX-3F 17" (manufactured by TOYACHE CHEMICAL CO., LTD.)
Beeswax: trade name "コウサンダッシュウミツロウ" (manufactured by Sanmu chemical Co., Ltd.)
Sunflower seed wax: trade name "purified sunflower wax" (manufactured by Guangguan oil & fat industries Co., Ltd.)
Paraffin (melting point 68 ℃): trade name "HNP-11" (manufactured by Japan wax Kogyo Co., Ltd.)
Paraffin (melting point 74 ℃): trade name "SP-0165" (manufactured by Japan wax Seiko Co., Ltd.), high melting point Paraffin
Microcrystalline wax (melting point 88 ℃): trade name "HI-MIC-1090" (manufactured by Japan wax Co., Ltd.)
Mineral oil: trade name "cartatinon" (manufactured by Sonneborn inc.), liquid paraffin
Dimethylpolysiloxane (viscosity 20mPa · s): trade name "SH 200C Fluid 20 CS" (manufactured by Torredo Corning Co., Ltd.)
Ceteth-20: trade name "BLAUNON CH-320L" (manufactured by Rauwolfia oil & fat industries Co., Ltd.), polyoxyethylene cetyl ether
Sorbitan stearate: trade name "NIKKOL SS-10V" (manufactured by Sun chemical Co., Ltd.)
Carboxyvinyl polymer a: trade name "CARBOPOL 940" (manufactured by NOUBOMU CORPORATION)
Carboxyvinyl polymer B: trade name "CARBOPOL 980 POLYMER" (manufactured by LUOBORU CORPORATION, Japan)
Further, formulation examples of the emulsified hair styling composition of the present invention are shown below.
(formulation example 1) Hair wax
(formulation example 2) Hair cream
Claims (3)
1. An emulsion hair styling agent composition comprising the following component (A), the following component (B), the following component (C) and water,
component (A): the amount of the carnauba wax to be added,
component (B): the reaction mixture of castor oil and water is,
component (C): at least one oil agent selected from the group consisting of cyclic siloxane, methyltrimethylsiloxane, ethyltrisiloxane, trisiloxane, octylmethicone and dimethylpolysiloxane having a viscosity of 0.1 to 2.0 mPas at 25 ℃,
the content of the component (A) is 1.0-25.0 mass%,
the content of the component (B) is 0.5 to 20.0 mass%,
the content of the component (C) is 0.3 to 20.0 mass%,
the water content is 20.0 to 90.0 mass%.
2. The emulsified hair styling agent composition according to claim 1, wherein the emulsified hair styling agent composition comprises the following component (D),
component (D): polyglycerol polyricinoleate.
3. The emulsified hair styling agent composition according to claim 1 or 2, wherein the emulsified hair styling agent composition is a hair wax.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| JP2018-060135 | 2018-03-27 | ||
| JP2018060135 | 2018-03-27 | ||
| PCT/JP2019/010616 WO2019188356A1 (en) | 2018-03-27 | 2019-03-14 | Emulsified hairdressing composition |
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| CN111107835A CN111107835A (en) | 2020-05-05 |
| CN111107835B true CN111107835B (en) | 2022-07-12 |
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| JP (1) | JP6967139B2 (en) |
| KR (1) | KR102361538B1 (en) |
| CN (1) | CN111107835B (en) |
| WO (1) | WO2019188356A1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003026549A (en) * | 2001-07-12 | 2003-01-29 | Kanebo Ltd | Hair cosmetic |
| JP2009013125A (en) * | 2007-07-06 | 2009-01-22 | Mandom Corp | Emulsified cosmetic for hairdressing use |
| CN101951878A (en) * | 2008-01-25 | 2011-01-19 | 株式会社资生堂 | Emulsion-type hair-dressing preparation |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5653608A (en) * | 1979-10-09 | 1981-05-13 | Kobayashi Kooc:Kk | Emulsified stick cosmetic |
| JP4574873B2 (en) | 2001-02-16 | 2010-11-04 | ポーラ化成工業株式会社 | Cosmetics for hair |
| JP3811437B2 (en) | 2002-08-30 | 2006-08-23 | ホーユー株式会社 | Hairdressing composition |
| JP2005239677A (en) | 2004-02-27 | 2005-09-08 | Takara Belmont Co Ltd | Hairdressing agent |
| KR100814196B1 (en) * | 2004-03-25 | 2008-03-17 | 쇼와 덴코 가부시키가이샤 | A skin care and cosmetic preparation containing an inositol derivative |
| JP2007015935A (en) | 2005-07-05 | 2007-01-25 | Kanebo Home Products Kk | Hair dressing agent |
| JP2008222673A (en) * | 2007-03-15 | 2008-09-25 | Serarika Noda:Kk | Oily cosmetic |
| JP2010270081A (en) * | 2009-05-25 | 2010-12-02 | Kao Corp | Hair cosmetic |
| JP2011057624A (en) * | 2009-09-11 | 2011-03-24 | Hoyu Co Ltd | Hair cosmetic composition |
| CN108024943B (en) * | 2016-03-30 | 2021-08-03 | 株式会社漫丹 | Hair styling composition |
-
2019
- 2019-03-14 JP JP2020509906A patent/JP6967139B2/en active Active
- 2019-03-14 KR KR1020207006484A patent/KR102361538B1/en active IP Right Grant
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- 2019-03-14 CN CN201980004564.3A patent/CN111107835B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003026549A (en) * | 2001-07-12 | 2003-01-29 | Kanebo Ltd | Hair cosmetic |
| JP2009013125A (en) * | 2007-07-06 | 2009-01-22 | Mandom Corp | Emulsified cosmetic for hairdressing use |
| CN101951878A (en) * | 2008-01-25 | 2011-01-19 | 株式会社资生堂 | Emulsion-type hair-dressing preparation |
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| Publication number | Publication date |
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| JP6967139B2 (en) | 2021-11-17 |
| KR20200037357A (en) | 2020-04-08 |
| CN111107835A (en) | 2020-05-05 |
| KR102361538B1 (en) | 2022-02-14 |
| WO2019188356A1 (en) | 2019-10-03 |
| JPWO2019188356A1 (en) | 2020-07-02 |
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