CN111093605A - Hair styling composition - Google Patents
Hair styling composition Download PDFInfo
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- CN111093605A CN111093605A CN201980004384.5A CN201980004384A CN111093605A CN 111093605 A CN111093605 A CN 111093605A CN 201980004384 A CN201980004384 A CN 201980004384A CN 111093605 A CN111093605 A CN 111093605A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Abstract
A hair styling composition which is excellent in coating properties and hair styling performance and is excellent in hair styling retention for fine hair. The hair styling agent composition of the present invention comprises: a hydrocarbon selected from the group consisting of microcrystalline wax and polyethylene wax (component a); a hydrocarbon selected from the group consisting of paraffin wax, Fischer-Tropsch wax, and ozokerite (component B); and a kinematic viscosity of 0.5mm22.5mm above s2A dimethylpolysiloxane (component C) having a content of component A of 0.5 to 20.0 mass%,the content of the component B is 0.5 to 20.0 mass%, and the mass ratio of the content of the component A to the content of the component B is 0.20 to 10.0.
Description
Technical Field
The present invention relates to a hair styling composition suitable for a hair styling agent for styling hair.
Background
Hair styling properties that can be imparted by hair styling compositions used for styling hair include a variety of hair styling properties. Examples of hair styling properties include: a property of setting hair to each other (for example, a property of setting hair tightly, a property of setting hair to form a hair bundle, and the like), a property of shaping a hairstyle by forming a flow direction of hair (for example, hair setting force), a property of fixing hair, a property of raising hair, a property of holding a hairstyle for a long time, a property of imparting luster to hair, a property of improving smoothness of hair to each other to impart dry feeling, and the like.
The hair styling composition is designed to exhibit one or more of the above-mentioned hair styling properties depending on the intended hair style, the hair quality to be applied, and the like. Further, there are various properties of hair styling compositions such as liquid, gel, and paste, and hair styling compositions of various properties have different usages, feelings of use, and hair styling properties. In addition, different compositions were designed for hair styling compositions having different properties.
Patent document 1 below discloses a hair styling agent which is an oil-in-water droplet emulsion containing (a) an acrylic thickener, (B) a liquid hydrocarbon, (C) a microcrystalline wax, and (D) an alkali. The oil-in-water emulsion described above is thixotropic.
Patent document 2 discloses an emulsion composition for hair, which contains (a) paraffin wax having a melting point of 70 to 77 ℃, (B) an oily substance that is liquid at room temperature, (C) a nonionic surfactant, and (D) water. In addition, microcrystalline wax is used in the examples of patent document 2. In addition, in the examples of patent document 2, only methylpolysiloxane having a kinematic viscosity of 5cs is used.
Documents of the prior art
Patent document
Patent document 1: japanese patent laid-open publication No. 2017 and 218418
Patent document 2: japanese patent laid-open publication No. 2011-126829
Disclosure of Invention
Problems to be solved by the invention
In the case of the hair styling agent compositions of the prior art described in patent documents 1 and 2, friction may occur during application due to the solid oil component to be blended, and the applicability may be lowered. For example, when a conventional hair styling composition is applied to hair, the solid oil component may be caught on the hair. Therefore, in the case of a conventional hair styling composition, the hair styling composition is not uniformly applied to the hair, and the hair styling composition may be unevenly distributed in thickness on the hair, and the hair styling composition may be locally adhered to a large part. In this case, when hair styling is performed, the hair strands may droop due to a large amount of the hair styling composition adhering to the hair strands, and the hair style cannot be maintained. In particular, in the case of fine hair (for example, in the case of hair aged more than forty), the hair itself has low strength, so that the hair bundle is liable to sag, and the hairstyle of the hair set is liable to collapse.
In addition, in the case of a hair styling composition having only improved applicability, the hair styling power and hair styling retention may decrease.
The invention aims to provide a hair styling composition which is excellent in coating property and hair styling power and is excellent in hair styling retention for fine hair.
Means for solving the problems
The present invention provides a hair styling agent composition comprising the following component (A), the following component (B) and the following component (C), wherein the content of the component (A) is 0.5-20.0 mass%, the content of the component (B) is 0.5-20.0 mass%, and the mass ratio of the content of the component (A) to the content of the component (B) is 0.20-10.0.
Component (A): a hydrocarbon selected from the group consisting of microcrystalline wax and polyethylene wax;
component (B): a hydrocarbon selected from the group consisting of paraffin wax, Fischer-Tropsch wax, and ozokerite;
component (C): kinematic viscosity of 0.5mm22.5mm above s2Dimethylpolysiloxane having a molar ratio of less than s.
The hair styling agent composition of the present invention preferably contains the following component (D).
Component (D): a wax ester selected from the group consisting of carnauba wax, sunflower seed wax, beeswax, rice bran wax, and shellac wax.
In the hair styling composition of the present invention, the content of the component (D) is preferably 0.5 to 20.0 mass%, and the mass ratio of the content of the component (D) to the content of the component (B) is preferably 0.60 to 4.00.
ADVANTAGEOUS EFFECTS OF INVENTION
The hair styling agent composition of the present invention comprises a specific component (a), a specific component (B), and a specific component (C), wherein the content of the component (a) is 0.5 to 20.0 mass%, the content of the component (B) is 0.5 to 20.0 mass%, and the mass ratio of the content of the component (a) to the content of the component (B) is 0.20 to 10.0, and therefore, the hair styling agent composition is excellent in coating properties and hair styling power, and is excellent in hair styling retention for fine hair.
Detailed Description
The present invention will be described in detail below.
The hair styling agent composition of the present invention comprises: a hydrocarbon selected from the group consisting of microcrystalline wax and polyethylene wax; a hydrocarbon selected from the group consisting of paraffin wax, Fischer-Tropsch wax, and ozokerite; and a kinematic viscosity of 0.5mm22.5mm above s2Dimethylpolysiloxane having a molar ratio of less than s.
In the present specification, the above-mentioned "hydrocarbon selected from the group consisting of microcrystalline wax and polyethylene wax" may be referred to as "component (a)".
In the present specification, the "hydrocarbon selected from the group consisting of paraffin wax, fischer-tropsch wax and ozokerite" may be referred to as "component (B)".
In the present specification, the "kinematic viscosity" may be 0.5mm22.5mm above s2Dimethylpolysiloxane of less than s"referred to as" component (C) ".
The hair styling agent composition of the present invention comprises a component (a), a component (B), and a component (C), wherein the content of the component (a) is 0.5 to 20.0 mass%, the content of the component (B) is 0.5 to 20.0 mass%, and the mass ratio of the content of the component (a) to the content of the component (B) (the content of the component (a)/the content of the component (B)) is 0.20 to 10.0.
The hair styling composition of the present invention has the above-described structure, and therefore, is excellent in applicability and hair styling power and is excellent in hair styling retention for fine hair.
The hair styling composition of the present invention has good spreadability when applied to hair, and can be uniformly applied to hair.
The hair styling agent composition of the present invention also exerts excellent hair styling retention on hair other than fine hair. Therefore, the hair styling agent composition of the present invention exerts excellent hair styling retention regardless of the thickness of the hair. The hair styling agent composition of the present invention can more effectively exert an effect of excellent hair styling retention when hair is styled in fine hair than conventional hair styling agent compositions.
The hair styling agent composition of the present invention may further comprise a wax ester selected from the group consisting of carnauba wax, sunflower seed wax, beeswax, rice bran wax, and shellac wax. In the present specification, the "wax ester selected from the group consisting of carnauba wax, sunflower seed wax, beeswax, rice bran wax, and shellac wax" may be referred to as "component (D)".
As described above, the hair styling composition of the present invention contains at least the component (a), the component (B), and the component (C). The hair styling agent composition of the present invention may further comprise ingredient (D).
The hair styling composition of the present invention may contain other components besides the components (a) to (D).
The above-mentioned components, for example, the component (A), the component (B), the component (C), the component (D) and others may be used alone or in combination of two or more.
Hereinafter, the details of each component used in the hair styling composition of the present invention will be described.
(component (A))
The component (a) is a hydrocarbon (wax component) selected from the group consisting of microcrystalline wax and polyethylene wax. Microcrystalline and polyethylene waxes are hydrocarbons that are solid at 25 ℃. By using the component (a), appropriate adhesion can be provided between hairs, and the hair styling power and the hair styling holding power for fine hair can be improved. The component (A) may be used alone or in combination of two or more.
The microcrystalline wax is a microcrystalline wax specified in JIS K2235.
Examples of the commercially available microcrystalline wax include a trade name "HI-MIC-2065", a trade name "HI-MIC-1090", a trade name "HI-MIC-2095", a trade name "HI-MIC-1045" (both of which are manufactured by Japan wax Co., Ltd.), a trade name "MULTIWAAX W-835", a trade name "MULTIWAAX X145 AH", and a trade name "MULTIWAAX X123 AH" (both of which are manufactured by Sonneborn Inc.).
The polyethylene wax is a polymer of ethylene. Examples of the method for producing the polyethylene wax include a method of polymerizing ethylene and a method of decomposing a polyethylene for general molding.
The polyethylene wax is preferably a polyethylene wax having a melting point of 120 ℃ or lower, from the viewpoint of effectively exerting the effects of the present invention.
The commercially available POLYETHYLENE wax is, for example, sold under the trade name "PERFOMALENE PL POLYETHYLENE" (melting point 88 ℃ C., manufactured by New Phase Technologies).
The microcrystalline wax and the polyethylene wax may be used alone or in combination.
The content of the component (a) in 100% by mass of the hair styling agent composition of the present invention is 0.5% by mass or more and 20.0% by mass or less. When the content of the component (a) is less than 0.5% by mass, the hair may be difficult to be gathered. When the content of the component (a) exceeds 20.0 mass%, the setting force may be reduced.
The content of the component (a) in 100% by mass of the hair styling composition of the present invention is preferably 2.0% by mass or more, more preferably 4.0% by mass or more, preferably 18.0% by mass or less, more preferably 16.0% by mass or less. When the content of the component (a) is not less than the lower limit and not more than the upper limit, appropriate adhesive force can be provided between hairs, and the hair setting force and the hair setting holding force for fine hairs can be further improved. The content of the component (a) is the total of the contents of all the components (a) in the hair styling composition of the present invention.
The mass ratio of the content of the component (A) to the content of the component (B) (the content of the component (A)/the content of the component (B)) is 0.20 to 10.0. When the mass ratio (content of component (a)/content of component (B)) is less than 0.20 or exceeds 10.0, the hair styling composition may be difficult to be uniformly applied to the hair, and the hair setting holding power for fine hair may be reduced.
The mass ratio of the content of the component (a) to the content of the component (B) (content of the component (a)/content of the component (B)) is preferably 0.30 or more, more preferably 0.40 or more, preferably 8.0 or less, more preferably 7.0 or less. When the mass ratio (the content of the component (a)/the content of the component (B)) is not less than the lower limit and not more than the upper limit, the hair-setting force and the hair-setting holding force for fine hair can be further improved. When the mass ratio (content of component (a)/content of component (B)) is not less than the lower limit, coatability can be improved.
(component (B))
The component (B) is a hydrocarbon (wax component) selected from the group consisting of paraffin wax, fischer-tropsch wax, and ozokerite. Paraffin waxes, fischer-tropsch waxes and ozokerites are hydrocarbons that are solid at 25 ℃. By using the component (B), the hair setting force and the hair setting holding force for fine hair can be improved. The component (B) may be used alone or in combination of two or more.
The paraffin wax is defined in JIS K2235.
As the commercially available product of the paraffin wax, there may be mentioned the trade name "SP-0165" and the trade name "HNP-9" (both manufactured by Japan wax Seikagana Kogyo Co., Ltd.).
The fischer-tropsch wax is a wax produced by the fischer-tropsch process. The above-mentioned Fischer-Tropsch wax is a wax having a name sometimes referred to as "synthetic wax". The fischer-tropsch process described above refers to a process for the synthesis of wax using carbon monoxide, hydrogen and a catalyst. Examples of the catalyst include iron, cobalt, and nickel.
Examples of the commercial product of the above fischer-tropsch wax include "cireblele 108" (manufactured by cireblele corporation).
The commercially available products of the ozokerite include a trade name "CERESIN # 810", a trade name "CERESIN # 820", and a trade name "refined ozokerite N" (both manufactured by NIKKO RICA).
The paraffin wax, the Fischer-Tropsch wax, and the ozokerite may be used alone or in combination of two or more.
From the viewpoint of more effectively exerting the effect of the present invention, the component (B) preferably contains a hydrocarbon selected from the group consisting of paraffin wax and fischer-tropsch wax.
The content of the component (B) in 100% by mass of the hair styling agent composition of the present invention is 0.5% by mass or more and 20.0% by mass or less. When the content of the component (B) is less than 0.5% by mass, the hair setting may be poor. When the content of the component (B) exceeds 20.0 mass%, the coating property and the hair-setting retention force for fine hair may be lowered.
The content of the component (B) in 100% by mass of the hair styling composition of the present invention is preferably 1.0% by mass or more, more preferably 2.0% by mass or more, preferably 15.0% by mass or less, more preferably 13.0% by mass or less. When the content of the component (B) is not less than the lower limit and not more than the upper limit, the coating property, the hair setting force and the hair setting holding force for fine hair can be further improved. The content of the component (B) is the total of the contents of all the components (B) in the hair styling composition of the present invention.
(component (C))
Component (C) has a kinematic viscosity of 0.5mm22.5mm above s2Dimethylpolysiloxane having a molar ratio of less than s. The dimethylpolysiloxane is a volatile compound which is liquid at 25 ℃. By using the component (C), the coatability can be improved. The component (C) may be used alone or in combination of two or more.
The kinematic viscosity of the dimethylpolysiloxane was 0.5mm22.5mm above s2The ratio of the water to the water is less than s. The above dimethyl polysiloxaneDynamic viscosity is less than 0.5mm2/s or more than 2.5mm2At the time of s, the volatility of dimethylpolysiloxane is lowered, and the coatability is sometimes deteriorated.
From the viewpoint of further improving coatability, the kinematic viscosity of the dimethylpolysiloxane is preferably 0.8mm2A thickness of 1.0mm or more, more preferably2A length of at least 2.2mm, preferably 2.2mm2Less than s, more preferably 2.0mm2The ratio of the water to the water is less than s.
The kinematic viscosity is 25 ℃. The kinematic viscosity at 25 ℃ was measured by a capillary viscometer method.
The content of the component (C) in 100% by mass of the hair styling composition of the present invention is preferably 0.5% by mass or more, more preferably 1.0% by mass or more, preferably 10.0% by mass or less, more preferably 8.0% by mass or less. When the content of the component (C) is not less than the lower limit and not more than the upper limit, the coatability can be further improved. The content of the component (C) is the total of the contents of all the components (C) in the hair styling composition of the present invention.
(component (D))
Component (D) is a wax ester selected from the group consisting of carnauba wax, sunflower seed wax, beeswax, rice bran wax and shellac wax. Component (D) is a wax ester which is solid at 25 ℃. By using the component (D), the adhesion between hairs can be improved, and the hair styling power and the hair styling holding power for fine hairs can be further improved. The component (D) may be used alone or in combination of two or more.
The carnauba wax is under the INCI name: the compound described in Copernicia Cerifera (Carnauba) Wax.
Examples of the commercially available products of the carnauba wax include a trade name "TOWAX-1F 8" (manufactured by Toyo chemical Co., Ltd.), a trade name "carnauba wax No. 1" (manufactured by Kaga-Marzu Co., Ltd.), and a trade name "carnauba wax refining No. 1" (manufactured by CERARICA NODA Co., Ltd.).
The sunflower seed wax is named as INCI: the compound described by Helianthus Annuus (Sunflower) Seed Wax.
Commercially available sunflower seed wax products include "purified sunflower wax" (manufactured by Wako fat industries, Ltd.) and "VGB 5 ST" (manufactured by ADM Japan).
Commercially available products of the beeswax include a trade name "コウサンダッシュウミツロウ" (manufactured by Sanko chemical industries, Ltd.) and a trade name "purified beeswax CY-100" (manufactured by Wako fat industries, Ltd.).
Examples of commercially available products of the rice bran wax include "TOWAX-3P 3" (manufactured by TOYA CHEMICAL CORPORATION) and "refined rice bran wax S-100" (manufactured by TOYOBO OIL AND FABRIC INC.).
Examples of commercially available products of THE shellac wax include "dried transparent white ラック" (manufactured by LTD., manufactured by THE JAPAN SHELLLACINDUSTRIES).
The carnauba wax, sunflower seed wax, beeswax, rice bran wax, and shellac wax may be used alone or in combination.
From the aspect of more effectively exerting the effect of the present invention, the component (D) preferably contains a wax ester selected from the group consisting of carnauba wax and sunflower seed wax.
The content of the component (D) in 100% by mass of the hair styling composition of the present invention is preferably 0.5% by mass or more, more preferably 2.0% by mass or more, preferably 20.0% by mass or less, more preferably 10.0% by mass or less. When the content of the component (D) is not less than the lower limit and not more than the upper limit, the hair setting force and the hair setting holding force for fine hair can be further improved. When the content of the component (D) exceeds 20.0% by mass, the hair-setting holding power for fine hair tends to be lower than that in the case where the content of the component (D) is 20.0% by mass or less. The content of the component (D) is the total of the contents of all the components (D) in the hair styling composition of the present invention.
The mass ratio of the content of the component (D) to the content of the component (B) (content of the component (D)/content of the component (B)) is preferably 0.60 or more, more preferably 0.65 or more, preferably 4.00 or less, more preferably 3.85 or less. When the mass ratio (the content of the component (D)/the content of the component (B)) is not less than the lower limit and not more than the upper limit, the hair setting force and the hair setting holding force for fine hair can be further improved.
(other Components)
The hair styling composition of the present invention may contain components other than the above components (a) to (D). The components other than the components (a) to (D) are not particularly limited, and examples thereof include fats and oils which are liquid at 25 ℃, hydrocarbons which are paste-like at 25 ℃, dimethylpolysiloxanes other than the component (C), emulsifiers, emulsification aids, thickeners, polyols, lower alcohols, film-forming polymers, and preservatives.
Examples of the fat or oil that is liquid at 25 ℃ include: hydrocarbons such as mineral oil, squalene, and squalane; ester oils such as isopropyl palmitate, glyceryl tri-2-ethylhexanoate, isopropyl myristate, propylene glycol monostearate, propylene glycol monolaurate, and polyglyceryl isostearate.
Examples of the hydrocarbons which are paste-like at 25 ℃ include vaseline.
Examples of the emulsifier and the emulsification aid include: a nonionic surfactant; polyglyceryl fatty acid esters such as polyglyceryl laurate, polyglyceryl myristate, polyglyceryl isostearate, and polyglyceryl dicaffenate; polyoxyethylene cetyl ethers such as CETETH-20 and CETETH-40; higher alcohols such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetearyl alcohol, and oleyl alcohol.
Examples of the thickener include carboxyvinyl polymers, acrylic acid/alkyl methacrylate copolymers, hydroxymethylcellulose, and hydroxypropylmethylcellulose.
Examples of the polyhydric alcohol include glycerin, diglycerin, 1, 3-butanediol, propylene glycol, dipropylene glycol, 1, 2-butanediol, 1, 2-pentanediol, 1, 2-hexanediol, 1, 2-octanediol, 1, 2-decanediol, and polyoxypropylene methyl glucoside.
Examples of the lower alcohol include ethanol.
Examples of the film-forming polymer include polyvinylpyrrolidone, a vinyl acetate-vinylpyrrolidone copolymer, and an N-methacryloyloxyethyl N, N-dimethylammonium- α -N-methylcarboxylbetaine-alkyl methacrylate copolymer.
Examples of the preservative include methyl paraben, ethyl paraben, propyl paraben, isopropyl paraben, butyl paraben, isobutyl paraben, and phenoxyethanol.
The hair styling composition of the present invention may contain, in addition to the components (a) to (D), chelating agents, antioxidants, plant extracts, dyes, pigments, pH adjusters, perfumes, and the like, within a range not to impair the effects of the present invention.
From the viewpoint of further improving the hold of the hairstyling for fine hair, the hairstyling composition of the present invention preferably contains no candelilla wax, or contains candelilla wax at less than 3.0 mass%. When the hair styling composition of the present invention contains candelilla wax, the content of candelilla wax in 100% by mass of the hair styling composition of the present invention is preferably less than 3.0% by mass, more preferably less than 2.5% by mass.
The hair styling composition of the present invention preferably comprises water. The water is preferably purified water.
The content of water in the hair styling composition of the present invention can be adjusted as appropriate by the content of other ingredients. The content of water in 100% by mass of the hair styling composition of the present invention is preferably 20.0% by mass or more, more preferably 25.0% by mass or more, further preferably 30.0% by mass or more, preferably 80.0% by mass or less, more preferably 70.0% by mass or less, further preferably 60.0% by mass or less.
(other details of the Hair styling composition)
The properties of the hair styling composition of the present invention are not particularly limited. The hair styling composition of the present invention may be in the form of liquid, gel, cream, paste, or wax. From the viewpoint of more effectively exerting the effects of the present invention, the hair styling composition of the present invention is preferably creamy or waxy in shape, and more preferably waxy in shape. The hair styling composition of the present invention is preferably a cream-like hair styling composition or a wax-like hair styling composition, and more preferably a wax-like hair styling composition.
As a method for producing the hair styling composition of the present invention, a known method for producing a hair styling composition can be used. Examples of the method for producing the hair styling agent composition of the present invention include: a method (phase inversion emulsification method) in which the respective components are mixed and then phase inversion emulsification is performed using a homomixer or the like. The mixing of the above components and the phase inversion emulsification may be performed simultaneously.
The hair styling composition of the present invention is not particularly limited, and may be used in a form of being filled in a container, for example. When the hair styling composition of the present invention is waxy in shape, the container is preferably a can container. When the hair styling composition of the present invention is in the form of a cream, the container is preferably a bottle container, a tube container, or a can container.
From the viewpoint of further improving the handling properties, the hair styling agent composition of the present invention has a consistency of preferably 5gf or more, more preferably 10gf or more, preferably 150gf or less, more preferably 100gf or less at 25 ℃. The consistency can be obtained by usingThe consistence meter of the ball-shaped connector was measured under the conditions of 25 ℃ at a speed of 60 mm/min and a stroke of 20 mm. Examples of the consistency METER include "RHEO METER" manufactured by Sun Scientific, Inc.
The following describes the relationship between the configuration of the present invention and the effects of the present invention in more detail.
The component (a) has a large number of branched structures and has low crystallinity. The component (B) has a linear structure or a branched structure with a small number of branches, and is a component with high crystallinity. Therefore, in the case of a hair styling composition containing only the component (a) as a hair styling component, although friction is less likely to occur during application and the applicability can be improved, it is difficult to impart hardness to hair and improve the hair styling ability, and the hair styling retention ability for fine hair is reduced. In addition, in the case of a hair styling composition containing only the component (B) as a hair styling component, although hardness is easily imparted to hair, friction is easily generated during application, and applicability is easily lowered. Therefore, in the case of a hair setting composition containing only the component (B) as a hair setting component, the hair setting composition is not uniformly applied to the hair, and the hair setting holding power (particularly, hair setting holding power for fine hair) is reduced. In contrast, since the hair styling composition of the present invention contains the component (a) and the component (B) in a specific mass ratio, it is possible to improve all of the coating properties, the hair styling power, and the hair styling retention power for fine hair.
Further, since the hair styling composition of the present invention contains the component (C), the applicability can be considerably improved. Since the component (C) is a highly volatile component, it can be applied favorably at the time of application, and it volatilizes after application, thereby increasing the concentrations of the components (a) and (B) on the hair. The hair styling composition of the present invention is excellent in coating property and can improve hair styling power and hair styling retention for fine hair by blending the component (C) in addition to the components (a) and (B).
In addition, the hair styling composition of the present invention can improve the hair styling retention regardless of the thickness of the hair.
Examples
The present invention will be specifically described below with reference to examples and comparative examples. The present invention is not limited to the following examples.
The following components were used in examples and comparative examples.
(component (A))
Microcrystalline wax: trade name "HI-MIC-1090", manufactured by Japan wax Kogyo Co., Ltd
(component (B))
Solid paraffin: trade name "SP-0165", manufactured by Japan wax Seiko Ltd
Fischer-Tropsch wax: trade name "CIREELLE 108", manufactured by CIREELLE corporation
(component (C))
Dimethyl polysiloxane: under the trade name "XIAMETER PMX-200SILICONE FLUID 1.5 CS", manufactured by Dow Corning Toray corporation, and having a kinematic viscosity of 1.5mm at 25 ℃2/s
(component not in accordance with component (C))
Dimethyl polysiloxane: under the trade name "DOW CORNING TORAY SH 200C FLUID 10 CS", manufactured by Dow Corning Toray corporation, and having a kinematic viscosity of 10mm at 25 ℃2/s
(component (D))
Sunflower seed wax: trade name "refined sunflower wax", manufactured by Zhaoguan oil & fat industries Ltd
Carnauba wax: trade name "TOWAX-1F 8", manufactured by Toyazai Kagaku K.K
(others)
Vaseline (hydrocarbon paste at room temperature)
Dimethyl polysiloxane: trade name "Element 14 PDMS 350-JC", manufactured by Momentive Performance materials Japan, having a kinematic viscosity at 25 ℃ of 350mm2/s
Mineral oil (liquid hydrocarbon at 25 deg.C)
Ethylhexyl palmitate (ester oil which is liquid at 25 ℃ C.)
Stearyl alcohol (emulsifying auxiliary)
CETETH-20 (average number of moles of polyoxyethylene groups added 20, polyoxyethylene cetyl ether): trade name "BLAUNON CH-320L", manufactured by Qing Wood oil industries Ltd. (emulsifier)
Stearic acid sorbitan (emulsifier)
Stearic acid (emulsifier)
Carboxyvinyl polymer (thickener)
Triethanolamine (alkali)
1, 3-butanediol (polyol)
Purified water
(examples 1 to 9 and comparative examples 1 to 4)
The hair styling compositions were prepared by compounding the components shown in tables 1 and 2 (the unit of compounding was% by mass). The blending amounts (blending amounts in 100% by mass of the hair styling composition) in the table are expressed as blending amounts (unit: mass%) of the pure components.
All of the hair styling compositions obtained in examples 1 to 9 had a wax-like texture.
(evaluation)
The hair styling composition obtained was evaluated as follows. The evaluation results are shown in tables 1 and 2.
(test example 1: coatability)
1.5g of the obtained hair styling composition was applied to a wig (dummy for training: manufactured by YuKaRIJapan) to complete the hair, and the hair was styled so that the hair was vertically raised from the root. The ease of application at this time was evaluated according to the following criteria.
< evaluation criteria for coatability >
○ (good) the hair styling composition has good spreadability and can be applied uniformly to the hair.
△ (preferred) the hair styling composition is slightly malleable and can be applied substantially uniformly to the hair.
X (bad): the hair styling composition has poor extensibility and is difficult to apply uniformly to the hair.
(test example 2 force)
The hairpiece dressed in test example 1 was left to stand for 1 minute, and then the hair was visually observed. The total efficacy was evaluated according to the following criteria.
< evaluation criteria for Hair force >
○ (good) that the hairstyle just after the hair is well maintained
△ (slightly better) that the hairstyle is maintained to some extent right after the hair is styled
X (bad): substantially all of the hair does not remain in the hairstyle immediately after the hair is styled
(test example 3 holding power for hairstyling of thin hair)
A hair set prepared by selecting only about 300 fine hairs (average hair diameter of about 80 μm) was prepared. 0.02g of the obtained hair styling composition was applied to a hand and the hair of the hair set was styled so that the hair was vertically raised. The hairset after hairstyling was rotated by 90 ° so that the standing hair was horizontal. In this state, the hair set was left standing at 25 ℃ and 60% RH for 3 hours, and then the hair was visually observed. The hair-setting retention force for thin hair was evaluated according to the following criteria.
< evaluation criteria for hairset holding force for hairline >
○ (good) the hair was well held in a horizontal orientation.
△ (slightly better) the hairs slightly drooping, but the hairs were kept in a horizontal orientation.
X (bad): substantially all of the hair is not held in a horizontal orientation and droops.
The compositions and the results are shown in tables 1 and 2 below.
[ Table 1]
[ Table 2]
Claims (3)
1. A hair styling agent composition comprising the following component A, the following component B and the following component C,
the content of the component A is 0.5-20.0 mass%,
the content of the component B is 0.5-20.0 mass%,
the mass ratio of the content of the component A to the content of the component B is 0.20 to 10.0,
component A: a hydrocarbon selected from the group consisting of microcrystalline wax and polyethylene wax;
component B: a hydrocarbon selected from the group consisting of paraffin wax, Fischer-Tropsch wax, and ozokerite;
component C: kinematic viscosity of 0.5mm22.5mm above s2Dimethylpolysiloxane having a molar ratio of less than s.
2. The hair styling agent composition according to claim 1, comprising the following ingredient D,
component D: a wax ester selected from the group consisting of carnauba wax, sunflower seed wax, beeswax, rice bran wax, and shellac wax.
3. The hair styling agent composition according to claim 2, wherein the content of the component D is 0.5 to 20.0% by mass,
the mass ratio of the content of the component D to the content of the component B is 0.60 to 4.00.
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JP2018-098882 | 2018-05-23 | ||
JP2018098882 | 2018-05-23 | ||
PCT/JP2019/003073 WO2019225061A1 (en) | 2018-05-23 | 2019-01-30 | Hair-styling agent composition |
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CN111093605A true CN111093605A (en) | 2020-05-01 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005239677A (en) * | 2004-02-27 | 2005-09-08 | Takara Belmont Co Ltd | Hairdressing agent |
JP2010270066A (en) * | 2009-05-21 | 2010-12-02 | Mandom Corp | Hairdressing cosmetic |
CN106170319A (en) * | 2014-04-11 | 2016-11-30 | 欧莱雅 | Compositions and dispersion including the granule containing polymer |
CN107072897A (en) * | 2015-03-27 | 2017-08-18 | 株式会社漫丹 | Hair grooming Unctuous compositions |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
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US4954335A (en) * | 1989-05-31 | 1990-09-04 | Helene Curtis, Inc. | Clear conditioning composition and method to impart improved properties to the hair |
JP3128309B2 (en) | 1991-12-27 | 2001-01-29 | 旭硝子株式会社 | Image display device and driving method thereof |
JP4832030B2 (en) * | 2005-09-02 | 2011-12-07 | 花王株式会社 | Hairdressing fee |
JP2011126829A (en) | 2009-12-18 | 2011-06-30 | Mandom Corp | Emulsified composition for hair |
JP6663734B2 (en) | 2016-02-02 | 2020-03-13 | 株式会社アリミノ | Hairdressing composition |
JP6902830B2 (en) | 2016-06-08 | 2021-07-14 | 株式会社ミルボン | Hair styling product |
-
2019
- 2019-01-30 CN CN201980004384.5A patent/CN111093605A/en active Pending
- 2019-01-30 JP JP2020521013A patent/JP7337052B2/en active Active
- 2019-01-30 KR KR1020207006761A patent/KR20200038285A/en not_active Application Discontinuation
- 2019-01-30 WO PCT/JP2019/003073 patent/WO2019225061A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005239677A (en) * | 2004-02-27 | 2005-09-08 | Takara Belmont Co Ltd | Hairdressing agent |
JP2010270066A (en) * | 2009-05-21 | 2010-12-02 | Mandom Corp | Hairdressing cosmetic |
CN106170319A (en) * | 2014-04-11 | 2016-11-30 | 欧莱雅 | Compositions and dispersion including the granule containing polymer |
CN107072897A (en) * | 2015-03-27 | 2017-08-18 | 株式会社漫丹 | Hair grooming Unctuous compositions |
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JP7337052B2 (en) | 2023-09-01 |
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