KR20170066656A - Oily composition for hair - Google Patents

Abstract

The present invention provides an excellent effect of preservation stability, has good spreadability on the palm or the head, excellent combing ability at the time of regular firing, and can perform regular firing without being tacky, Provides an oily composition for hair that has excellent hairiness feeling. The oil-based composition for hair of the present invention comprises the component (A): hydrocarbon oil which is solid at room temperature and / or lead (Wax) which is solid at room temperature, component (B): tri (trimethylsiloxy) silylpropylcarbamate pullulan, Component (C): volatile hydrocarbon oil, and component (D): 12-hydroxystearic acid, and substantially water-free.

Description

{OILY COMPOSITION FOR HAIR}

The present invention relates to an oily composition for hair. The room temperature in the present invention indicates a temperature range of 1 to 30 占 폚.

Hair cosmetics such as hair waxes prepared by emulsifying oil and water and hair cream are commonly used as cosmetics for spreading on the palms and spreading them on the hair to perform regular hair growth. However, since these emulsions are mixed with emulsifiers, there is a drawback that the hair straightening agent tends to flow down due to moisture or perspiration, so that the force to bind the hair, that is, the so-called hairiness feeling, is deteriorated.

On the other hand, there is a non-aqueous (non-aqueous) wax mainly composed of a solid oil and a nonvolatile oil, which is prepared without mixing water, a so-called clay. Non-aqueous waxes, such as clay, have excellent tacking power. However, if the solid oil is highly dispersed, the feeling of use of the composition itself becomes heavy, and the spread of the composition spreads widely on the fingers and the palm, and the spread of the hair spreads on the fingers is poor, (finger-combability) is bad, and stickiness is generated. In addition, when the nonvolatile oil is highly aggregated, it is defective that it is necessary to recreate the hairstyle several times due to the lack of sensation and the tendency to stickiness specific to the oil agent, while improving the softness. In addition, there is a drawback that detachment occurs in the high-temperature region and storage stability of the preparation deteriorates.

In order to solve the above drawbacks, attempts have been made to increase the spread of the non-aqueous composition. Specifically, it is possible to use, for example, vegetable oils containing triglycerides as a main component, non-aqueous hair cosmetic compositions containing dimethiconol, cyclic silicone, and dicaprylyl ether (see Patent Document 1) Oil-based clay mineral, a specific surfactant, an oil-in-water emulsion at 25 ° C and an oil-in-water emulsion having a melting point of 35 to 120 ° C (see Patent Document 2) . However, although the degree of tortuosity can be increased to some extent by the above attempts, there is a problem in that sufficient uniformity can not be obtained and it is not possible to set it as expected during regular operation. In addition, there is a problem that sticking specific to the emulsion tends to occur in the above trial.

Therefore, an attempt has been made to reduce the stickiness and give the repulsive force. Specifically, for example, a hair wax product containing silicon-free wax, liquid hydrophobic oil, silicone wax, and water-free hair (see Patent Document 3) has been proposed. However, such an attempt tends to improve stickiness peculiar to the emulsion and give a certain amount of repulsive power, but it tends to cause separation in a high-temperature region, resulting in poor storage stability.

Japanese Patent Application Laid-Open No. 2011-207807 Japanese Patent Application Laid-Open No. 2011-229071 Japanese Patent Application Laid-Open No. 2005-213252

SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned prior arts, and an object thereof is to provide an oily composition for hair that exhibits an excellent storage stability. It is another object of the present invention to provide an oil-based composition for hair that has good toughness on the palms of hands and on the hair, excellent combing ability at the time of regular firing, can perform regular hair without stickiness, and has excellent hairiness after hair straightening .

That is, the present invention provides an oil-based composition for hair which comprises the following components (A) to (D) and is substantially water-free.

Component (A): Hydrocarbon oil which is solid at room temperature and / or lead (Wax) which is solid at room temperature.

Component (B): Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan

Component (C): volatile hydrocarbon oil

Component (D): 12-Hydroxystearic acid

The content of the component (A) is preferably 2 to 20% by mass.

The content of the component (B) is preferably 0.2 to 7% by mass.

The component (C) is preferably at least one volatile hydrocarbon oil selected from the group consisting of hydrogenated polyisobutene, hydrogenated (tetradecenyl / methylpentadecene) and isododecane.

It is preferable that the oil-based oil composition contains at least one member selected from the group consisting of component (E): glyceryl behenate, glyceryl diphenylhexanoate and glyceryl tribehenate.

The oil-based oil-based composition preferably contains a nonionic surfactant having a component (F) HLB value of 2 or more and 8 or less.

The oil-based composition for hair is preferably a stabilizer.

INDUSTRIAL APPLICABILITY The oil-based composition for hair of the present invention exhibits an excellent effect of exhibiting excellent finger combing properties at the time of straightening, with good flexibility on the palm and hair. In addition, the oily composition for hair of the present invention can perform regular hair growth without tackiness, and hair after hair growth has an effect of having excellent hairiness. Further, the oil-based composition for hair of the present invention exhibits remarkably excellent storage stability.

The hair oilable composition of the present invention is characterized by containing the following components (A) to (D), and substantially free from water.

Component (A): hydrocarbon oil which is solid at room temperature and / or lead

Component (B): Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan

Component (C): volatile hydrocarbon oil

Component (D): 12-Hydroxystearic acid

The component (A) is a hydrocarbon oil which is solid at room temperature and / or a solid which is solid at room temperature. In the present specification, the above-mentioned " hydrocarbon oil solid at room temperature " is sometimes referred to as " component (A1) ". The above-mentioned " lead that is solid at room temperature " may be referred to as " component (A2) ". The component (A) selected from the group of the component (A1) and the component (A2) may be used singly or in a combination of two or more.

Specific examples of the hydrocarbon oil which is solid at room temperature which is the component (A1) include ceresin, ozokerite, paraffin, microcrystalline wax, high melting point microcrystalline wax, polyethylene powder (polyethylene powder), polyethylene wax, Vaseline, high melting point paraffin, synthetic wax and the like. One kind of the component (A1) may be used alone, or two or more kinds may be appropriately used in combination.

Specific examples of the solid at room temperature which is the component (A2) include, for example, carnauba wax, candelilla wax, beeswax, rice bran, shellac wax, whale wax, lanolin, . One kind of the component (A2) may be used alone, or two or more kinds may be appropriately used in combination.

As the suitable component (A), use is made of a high melting point microcrystalline wax, a polyethylene wax, a high melting point paraffin, a synthetic wax, a carnauba wax, and a candelilla wax from the viewpoint of exhibiting a sense of style and further from the viewpoint of storage stability desirable. Among the suitable components (A), it is more preferable to use high melting point microcrystalline wax, high melting point paraffin, carnauba wax, and candelilla wax.

The content of the component (A) in the oil-based oily composition of the present invention is not particularly limited as long as the desired effect can be sufficiently exhibited, but from the viewpoint of imparting a sense of speediness and further, Is preferably 1% by mass or more, and more preferably 2% by mass or more, based on 100% by mass. From the viewpoint of suppressing the deterioration of the softness on the palms of hands and hair, and furthermore, from the viewpoint of light feeling, it is preferably 25 mass% or less, more preferably 20 mass% or less, of 100 mass% Do. The content of the component (A) is the sum of the contents of all the components (A) to be compounded in the oil-based hair composition of the present invention.

The component (B) is tri (trimethylsiloxy) silylpropylcarbamate pullulan. Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan is a compound represented by the name INCI (International Cosmetic Ingredient Dictionary and Handbook, 15th Edition, Book 3, 2014, p.3669): TRIMETHYLSILOXYSILYLCARBAMOYL PULLULAN.

In the present invention, by containing the above-mentioned component (B), it is possible to exhibit a remarkably excellent shape without deteriorating the finger combing property after application. Furthermore, since the total content of the component (A) can be reduced as compared with the conventional oil-based composition for hair, it is possible to exhibit a remarkably excellent feeling of feeling with a light feeling without tackiness. In combination with component (A), destabilization of the preparation by syneresis can be suppressed and excellent storage stability can be exhibited.

A commercially available product can be used as the component (B). Commercially available products of the component (B) include, for example, TSPL-30-ID (trade name, manufactured by Shin-Etsu Chemical Co., Ltd.).

The content of the component (B) in the oil-based hair composition of the present invention is not particularly limited as long as the desired effect can be sufficiently exhibited. However, from the viewpoint of imparting a remarkably good shape feeling without compromising finger combing property at the time of regular hair removal, More preferably 0.1% by mass or more, and more preferably 0.2% by mass or more, based on 100% by mass of the oil-based composition for hair from the standpoint of exhibiting storage stability. Further, from the viewpoint of inhibiting tackiness, 10 mass% or less, and more preferably 7 mass% or less, of 100 mass% of the oil-based composition for hair is preferable.

The component (C) is a volatile hydrocarbon oil. By containing the component (C) in the present invention, it is possible to suppress the tackiness peculiar to the emulsion and to provide a feeling of light feeling despite the oil-based composition.

Specific examples of the component (C) include, for example, isoparaffin, light isoparaffin, light flowing isoparaffin, hydrogenated polyisobutene, hydrogenated (tetradecenyl / methylpentadecene) . The component (C) may be used alone or in combination of two or more. As a suitable component (C), hydrogenated polyisobutene, hydrogenated (tetradecenyl / methylpentadecene) and isododecane are preferably used from the viewpoint of ease of spreading.

Commercially available products of the component (C) may be used. Examples of commercial products of hydrogenated polyisobutene include Marca Sol R (trade name, manufactured by Maruzen Sekiyu Kagaku), IP Solvent 1620 (trade name, manufactured by Idemitsu Kosan), Parleam EX (trade name, And the like. Commercially available products of hydrogenation (tetradecenyl / methylpentadecene) include, for example, SMART5 (trade name, manufactured by Nikko Chemicals Co., Ltd.). Commercially available products of isododecane include, for example, Creasil ID CG (trade name, manufactured by CIT Sarl).

The content of the component (C) in the oil-based oil-based composition of the present invention is not particularly limited as long as the desired effect is sufficiently exhibited, but from the viewpoint of the oil-based composition, it is preferable that the content is 40 mass% or more in 100 mass% By mass, and more preferably 50% by mass or more. Further, from the viewpoint of storage stability and further from the viewpoint of improving the repulsive power, it is preferably 85% by mass or less, more preferably 75% by mass or less, of 100% by mass of the oil-based composition for hair. The content of the component (C) is the total amount of the content of all the components (C) to be blended in the hair oil-based composition of the present invention.

The component (D) is 12-hydroxystearic acid. 12-Hydroxystearic acid is a saturated fatty acid having an unsatisfactory hydroxyl group at carbon at the 12-position of stearic acid. In the present invention, by containing the above-mentioned component (D), the effect of improving the softness on the palm and the hair is exhibited. In addition, the storage stability in the high temperature region is remarkably excellent.

Commercially available products can be used for the component (D). Examples of commercially available products of the component (D) include hydroxystearin (trade name, manufactured by Kawaken Fine Chemical Co., Ltd.) and 12-hydroxystearic acid (trade name, manufactured by KF Trading Co., Ltd.).

The content of the component (D) in the oil-based oil-based composition of the present invention is not particularly limited as long as the desired effect can be sufficiently exhibited. However, from the viewpoint of imparting storage stability, the content of 0.2% And more preferably 0.3 mass% or more. From the viewpoint of enhancing the toughness, it is preferably 7 mass% or less, more preferably 6 mass% or less, of 100 mass% of the oil-based composition for hair.

The oil-based composition for hair of the present invention is substantially water-free. As a result, it is possible to give a remarkably excellent model feeling. In the present invention, " substantially water-free " means " water is not added separately ", and a small amount of water contained in each of the ingredients is not excluded.

The oil-based composition for hair of the present invention may further contain at least one member selected from the group consisting of glyceryl behenic acid, glyceryl sebacate and glyceryl tribehenate as the component (E) from the viewpoint of further enhancing storage stability have. The component (E) may be used alone or in combination of two or more. As a suitable component (E), it is preferable to use glyceryl behenate from the viewpoint of exhibiting remarkably excellent storage stability.

Commercially available products of the component (E) may be used. Commercially available products of glyceryl behenate include, for example, Compritol 888 CG (trade name, manufactured by Gattefosse). Commercially available products of glyceryl dibenic acid include, for example, Compritol E ATO (trade name, manufactured by Gattefosse). Commercially available products of glyceryl tribehenate include, for example, Compritol 888 ATO (trade name, manufactured by Gattefosse). In the present invention, a mixed raw material containing the component (E) may be used.

The content of the component (E) in the oil-based oil-based composition of the present invention is not particularly limited as long as the desired effect can be sufficiently exhibited, but from the viewpoint of further enhancing the storage stability, And more preferably 1% by mass or more. From the viewpoint of enhancing the toughness, it is preferably 12 mass% or less, more preferably 10 mass% or less, of 100 mass% of the oil-based composition for hair. The content of the component (E) is the total amount of all the components (E) contained in the oil-based hair composition of the present invention.

The oil-based composition for hair of the present invention may contain a nonionic surfactant having an HLB value of 2 or more and 8 or less as the component (F), from the viewpoint of heightening wash-off from the hair during shaving.

Examples of the component (F) include fatty acid polyglycerides, fatty acid polyethylene glycols, fatty acid polyoxyethylene glycerides, fatty acid polyoxyethylene sorbitan and the like. The fatty acid constituting the component (F) is not particularly limited as long as it is a linear fatty acid or a branched fatty acid as long as a desired effect can be exhibited. However, it is preferably a branched fatty acid from the viewpoint of washing down. It is preferable that the component (F) is a multi-chain type in addition to the above requirements from the viewpoint of further increasing the wash-off. Specific examples thereof include polyglyceryl branched chain diols, polyethyleneglycol branched chain branched fatty acids, polyoxyethylene glyceryl branched chain branched fatty acids, and branched polyoxyethylene sorbitan branched chain fatty acids.

Specific examples of the suitable component (F) include triisostearic acid PEG-3 glyceryl (HLB value: 2), diisostearic acid PEG-2 (HLB value: 3), diisostearic acid PEG- ), Triisostearic acid polyglyceryl-2 (HLB value: 3), triisostearic acid PEG-4 sorbitan (HLB value: 3), triisostearic acid PEG-5 glyceryl (HLB value: 3), diisostearic acid (HLB value: 4), diisostearic acid PEG-4 (HLB value: 4), diisostearic acid polyglyceryl-3 (HLB value: 5), diisostearic acid PEG- 5), triisostearic acid PEG-10 glyceryl (HLB value: 5), diisostearic acid PEG-8 (HLB value: 6), diisostearic acid PEG-10 glyceryl (HLB value: 7), diisostearic acid poly (HLB value: 8), triisostearic acid polyglyceryl-10 (HLB value: 8), diisostearic acid PEG-12 (HLB value: 8), triisostearic acid PEG-20 glyceryl : 8). The component (F) may be used singly or in a combination of two or more.

The content of the component (F) in the oil-based oil-based composition of the present invention is not particularly limited as long as the desired effect can be sufficiently exhibited, but from the viewpoint of washing off from the hair at the time of curing, By mass or more, more preferably 2% by mass or more. Further, from the viewpoint of wet feeling and storage stability, it is preferably 20 mass% or less, more preferably 15 mass% or less, of 100 mass% of the oil-based oil-based composition. The content of the component (F) is the total amount of all the components (F) contained in the oil-based hair composition of the present invention.

In addition to the above-described components, components commonly used in cosmetics may be blended into the oily composition for hair of the present invention provided that the effect of the present invention is not impaired. Other components include, for example, emulsions other than the aforementioned oily components such as fatty acid ester oils; Surfactants other than the above; Additives such as polyhydric alcohols, lower alcohols, ultraviolet absorbers, antioxidants, perfumes, coloring agents, chelating agents, preservatives and sterilizing agents, moisturizing agents, refreshing agents, plant extracts and amino acids. The other components may be appropriately compounded depending on the application and purpose.

In addition, the use form of the oily composition for hair of the present invention can exhibit excellent finger combing property at the time of regular hair growth, can perform regular hair growth without tackiness, and has excellent hairiness after hair growth, Can be used to make.

Example

Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. In addition, the blending amount represents " mass% " unless otherwise stated, and the blended components are all converted to pure fractions. The evaluation was carried out under constant conditions of constant temperature and humidity of 23 ° C and a humidity of 60%.

In the Examples and Comparative Examples, the following components were used.

(Component (A))

High melting point microcrystalline wax: trade name " HI-MIC-1090 " (manufactured by Nippon Seiro Co., Ltd.)

High melting point paraffin: Product name "SP-0165" (manufactured by Nippon Seiro Co., Ltd.)

Candelilla lead: "Refined candelilla wax" (manufactured by Mitsubishi Chemical)

Carnauba bait: Product name "TOWAX-1F8" (manufactured by Doagase Co., Ltd.)

(Component (B))

(Trimethylsiloxy) silylpropylcarbamate Pullulan: Trade name "TSPL-30-ID" (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Component (C))

Hydrogenated polyisobutene: trade name " MARCAZOL R " (manufactured by Maruzen Sekiyu Kagaku)

Hydrogenated (tetradecenyl / methylpentadecene): trade name "SMART5" (manufactured by Nikko Chemicals Co., Ltd.)

Isododecane: a trade name " Creasil ID CG " (manufactured by CIT Sarl)

(Component (D))

12-Hydroxystearic acid: trade name "12-Hydroxystearic acid" (manufactured by KF Trading Co.)

(Component (E))

Glyceryl behenate: trade name: " Compritol 888 CG " (manufactured by Gattefosse)

Dibenzoic acid glyceryl: "COMPLEITOL E ATO" (trade name, manufactured by Gattefosse)

Glyceryl tribehenate: trade name " Compritol 888 ATO " (manufactured by Gattefosse)

(Component (F))

Triisostearic acid PEG-20 glyceryl: trade name " NIKKOL TGI-20 " (manufactured by Nippon Specialty Chemicals)

Triisostearic acid PEG-3 glyceryl: trade name "EMALEX GWIS-303" (manufactured by Nippon Emulsion Co., Ltd.)

Diisostearic acid PEG-10 glyceryl: trade name "EMALEX GWIS-210EX" (manufactured by Nippon Emulsion Co., Ltd.)

(Other components)

Ethylhexyl palmitate: trade name "Koiyo POC" (manufactured by Koyo Fine Chemicals Co., Ltd.)

Isononanoic acid isononyl: trade name " Saracose 99 " (manufactured by Nissin OILISO)

Trimethylsiloxy silicate: trade name " X-21-5595 " (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Alkyl acrylate / dimethicone) copolymer: trade name "KP-550" (manufactured by Shin-Etsu Chemical Co., Ltd.)

Cyclopentasiloxane: trade name " KF-995 " (manufactured by Shin-Etsu Silicone Co., Ltd.)

Dodecamethylcyclohexasiloxane: "DOW CORNING TORAY DC 246" (manufactured by Dow Corning Toray Co., Ltd.)

Stearic acid inulin: Trade name "Leopearl ISL2" (manufactured by Chiba Seifun Co., Ltd.)

Dextrin palmitate: "Leopearl KS2" (manufactured by Chiba Seifun Co., Ltd.)

(Preparation of each sample)

According to the compositions shown in Tables 1 to 2, oily compositions for hair for Examples 1 to 10 and Comparative Examples 1 to 10 were prepared and provided in the following evaluation test. The results are shown in Tables 1 to 2, respectively.

(Test Example 1: Evaluation of tensile strength on the palm of a hand)

1 g of the sample obtained in each of the Examples and Comparative Examples was placed on the palm of a hand, rubbed with both hands, and spreading at the time of bending was evaluated according to the following evaluation criteria.

The evaluation was conducted by ten sensory evaluation panels, and the evaluation results obtained the greatest number of people were taken as the results of each sample.

≪ Evaluation Criteria of Yeast Elasticity on the Palm &

○ (Good): Spread uniformly and broadly without lumping

△ (insufficient): A little lumps but spread widely

× (poor): Lumps are generated and do not spread uniformly wide

(Test Example 2: Evaluation of tensile strength on hair)

Using a wig (lesson mannequin: manufactured by YUKARI JAPAN Co., Ltd.), the samples obtained in the respective Examples and Comparative Examples were subjected to regular hair fusing to be well fused to hair, and the spread on the hair at the time of regular hair was evaluated according to the following evaluation criteria .

The evaluation was carried out with the above-mentioned 10 panels of the same evaluation panel, and the evaluation results obtained the greatest number of people were taken as the results of each sample.

≪ Evaluation criteria of softness on hair >

○ (Good): Spread uniformly and widely without clumping

△ (insufficient): Spread slightly, but spread widely

× (poor): Not uniformly spreading by spreading

(Test Example 3: evaluation of finger combing property and stickiness)

After the evaluation in Test Example 2, the hair was flattened as if hair was tied from the root of the hair, and finger combing property and stickiness at the time of regular hair removal were evaluated according to the following evaluation criteria.

The evaluation was carried out with the above-mentioned 10 panels of the same evaluation panel, and the evaluation results obtained the greatest number of people were taken as the results of each sample.

≪ Evaluation Criteria of Finger Combability >

○ (Good): Finger comb is good without stiffness

△ (insufficient): slightly stiff and finger combing is dropped

× (bad): Stiff and poor combing

<Evaluation criteria of stickiness>

○ (Good): No stickiness

△ (insufficient): slightly sticky

× (poor): sticky

(Test Example 4: Evaluation of Sensitivity)

After 10 minutes from the evaluation of Test Example 3, the hairstyle profile of the hair was evaluated visually according to the following evaluation criteria.

The evaluation was carried out with the above-mentioned 10 panels of the same evaluation panel, and the evaluation results obtained the greatest number of people were taken as the results of each sample.

<Assessment Criteria of Modesty>

○ (Good): It is kept in a bundle shape.

△ (insufficient): The bundle shape is beginning to collapse

× (bad): The bundle shape is not collapsed and maintained

(Test Example 5: Evaluation of washing down)

After the evaluation of Test Example 4, the hair of the wig that had undergone regular hair removal was washed with shampoo (trade name: Lucido shampoo, manufactured by Mandamusa) with lukewarm water at 40 占 폚 for 1 minute, The sensory evaluation was performed on the following hair follicles according to the following evaluation criteria.

The evaluation was carried out with the above-mentioned 10 panels of the same evaluation panel, and the evaluation results obtained the greatest number of people were taken as the results of each sample.

<Evaluation Criteria for Washing Down>

○ (Good): The hair is washed away without stickiness.

△ (insufficient): The hair is slightly sticky but washed down

× (poor): The hair is sticky, not washed away

(Test Example 6: evaluation of storage stability)

The samples obtained in the respective Examples and Comparative Examples were each charged into a transparent glass container having a capacity of 30 g and the state of the system after storage for one week in a constant temperature bath at 40 캜 was visually observed according to the following evaluation criteria .

The evaluation was carried out with the above-mentioned 10 panels of the same evaluation panel, and the evaluation results obtained the greatest number of people were taken as the results of each sample.

<Evaluation Criteria of Storage Stability>

○ (Good): Immediately after manufacture and no change at all

△ (insufficient): slight separation is recognized

× (poor): Clear separation is recognized

[Table 1]

[Table 2]

From the results of Tables 1 to 2, it was found that the oily-type composition for hair for each of the Examples had a good finger-combability on palm and hair, It can be seen that the hair can be performed regularly and the hair after the hair removal has an effect of having excellent hairiness. In addition, it can be seen that the oily composition for hair for each of the examples exhibits an excellent effect of washing off from the hair. Further, it can be seen that the oil-based compositions for hair of the respective Examples show remarkably excellent storage stability.

On the other hand, it can be understood that the effects of the present invention can not be sufficiently achieved in Comparative Examples 1 to 2, Comparative Example 5 and Comparative Example 8, which do not satisfy the essential constituents of the present invention. Particularly, in Comparative Example 1, Comparative Example 5 and Comparative Example 8, it was found that the effect of the present invention could not be exhibited because the emulsion became so cinerate that the storage stability was poor and the uniformity of the composition was lost have.

Comparative Example 3 and Comparative Example 4 in which component (B), which is an essential component of the present invention, was replaced with another film-forming component, Comparative Example 6 in which component (C) as an essential component of the present invention was substituted with another volatile emulsifier, Also in Comparative Example 7 and Comparative Example 9 and Comparative Example 10 in which the component (D), which is an essential component of the present invention, was replaced by another oil gelling agent, the emulsion grew to become a cinerate state and poor storage stability, The effect of the present invention can not be exerted.

Claims (7)

The oily composition for hair for hair containing the following components (A) to (D) and substantially free from water:
Component (A): Hydrocarbon oil which is solid at room temperature and / or lead (Wax) which is solid at room temperature.
Component (B): Tri (trimethylsiloxy) silylpropylcarbamic acid pullulan
Component (C): volatile hydrocarbon oil
Component (D): 12-Hydroxystearic acid. The method according to claim 1,
Wherein the content of the component (A) is 2 to 20% by mass. 3. The method according to claim 1 or 2,
Wherein the content of the component (B) is 0.2 to 7% by mass. 4. The method according to any one of claims 1 to 3,
Wherein the component (C) is at least one member selected from the group consisting of hydrogenated polyisobutene, hydrogenated (tetradecenyl / methylpentadecene) and isododecane. 5. The method according to any one of claims 1 to 4,
The oily composition for hair is further characterized by containing the following component (E):
Component (E): at least one member selected from the group of glyceryl behenate, glyceryl diphenylhexanoate and glyceryl tribehenate. 6. The method according to any one of claims 1 to 5,
The oil-based composition for hair for hair, further comprising the following component (F):
Component (F): Nonionic surfactant having an HLB value of 2 or more and 8 or less. 7. The method according to any one of claims 1 to 6,
Wherein the composition is a regular tablet.