JP6992972B2 - Oily hair cosmetics - Google Patents
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- JP6992972B2 JP6992972B2 JP2017235123A JP2017235123A JP6992972B2 JP 6992972 B2 JP6992972 B2 JP 6992972B2 JP 2017235123 A JP2017235123 A JP 2017235123A JP 2017235123 A JP2017235123 A JP 2017235123A JP 6992972 B2 JP6992972 B2 JP 6992972B2
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Description
本発明は、油性毛髪化粧料に関するものであり、さらに詳しくは塗布時のツヤ感に優れ、しっとり感があり、べたつき感が少なく、塗布時からのツヤの持続性に優れ、塗布性のよい油性毛髪化粧料に関するものである。 The present invention relates to an oil-based hair cosmetic, and more specifically, it has an excellent glossiness at the time of application, a moist feeling, a little stickiness, an excellent glossiness from the time of application, and an oiliness with good applicationability. It is about hair cosmetics.
ヘアオイルは毛髪に油分を補い、ツヤ感やしっとり感を与えることを目的として使用される頭髪化粧料の一種であり、従来より、オリーブ油等の植物油、流動パラフィン等の鉱物油が主成分として用いられてきた。近年では、特にシリコーンオイル等を配合したヘアオイルがべたつかない使用感のヘアオイルとしてニーズが高まっている。 Hair oil is a type of hair cosmetic used for the purpose of supplementing the oil content of hair and giving it a glossy and moist feeling. Conventionally, vegetable oils such as olive oil and mineral oils such as liquid paraffin have been used as main components. I came. In recent years, there has been an increasing need for hair oils containing silicone oil or the like, which have a non-greasy feel.
特許文献１には、使用中ののびや広がりがなめらかで、さらに、仕上がりのしなやかさ、軽さ、しっとり感やまとまり易さ、ツヤ感を付与する効果にも優れたヘアオイルを目的として、エステル化合物、２５℃における粘度が１，０００ｍＰａ・ｓ以上の高分子シリコーンおよび揮発性油剤を含有したヘアオイルが開示されている。特許文献２には、べたつきを抑えられ、仕上がりの軽さに優れ、使用後のツヤ感およびハリ・コシ感の付与に優れた油性毛髪化粧料を目的として、揮発性炭化水素、植物油および２５℃における粘度が１万ｍＰａ・ｓ以上かつ５００万ｍＰａ・ｓ以下のジメチコノールを含有した油性毛髪化粧料が開示されている。 Patent Document 1 describes an ester compound for the purpose of hair oil having a smooth spread and spread during use and also having an excellent effect of imparting suppleness, lightness, moistness, cohesiveness, and luster to the finish. , A hair oil containing a polymer silicone having a viscosity at 25 ° C. of 1,000 mPa · s or more and a volatile oil agent is disclosed. Patent Document 2 describes volatile hydrocarbons, vegetable oils and 25 ° C. for the purpose of oily hair cosmetics which suppress stickiness, have an excellent lightness of finish, and have excellent glossiness and firmness after use. Disclosed is an oily hair cosmetic containing dimethiconol having a viscosity of 10,000 mPa · s or more and 5 million mPa · s or less.
特許文献１のヘアオイルでは、オリゴマーエステルを用いているため、毛髪にしっとり感は得られるが、オリゴマーエステルのべたつき感が生じ、また、揮発性油剤を使用しているため毛髪のツヤ感を持続させることは困難であった。特許文献２の油性毛髪化粧料では、揮発性炭化水素を用いているため、使用後のツヤ感は得られるが、ツヤ感を持続させることは困難であった。 Since the hair oil of Patent Document 1 uses an oligomer ester, a moist feeling can be obtained for the hair, but a sticky feeling of the oligomer ester occurs, and since a volatile oil agent is used, the glossiness of the hair is maintained. It was difficult. Since the oil-based hair cosmetics of Patent Document 2 use volatile hydrocarbons, a glossy feeling after use can be obtained, but it is difficult to maintain the glossy feeling.
本発明者は、前記課題を解決するために鋭意検討した結果、（Ａ）ジメチルポリシロキサン、（Ｂ）ジメチコノール、（Ｃ）イソノナン酸イソノニルを含有し、前記（Ｂ）成分と前記（Ｃ）成分の含有量の質量比（Ｂ）／（Ｃ）が０．４８～３．２であることを特徴とする油性毛髪化粧料を提供するものである。 As a result of diligent studies to solve the above problems, the present inventor contains (A) dimethylpolysiloxane, (B) dimethiconol, and (C) isononyl isononanoate, and the component (B) and the component (C). Provided is an oily hair cosmetic having a mass ratio (B) / (C) of 0.48 to 3.2.
本発明によれば、塗布時のツヤ感に優れ、しっとり感があり、べたつき感が少なく、塗布時からのツヤの持続性に優れ、塗布性のよい油性毛髪化粧料が得られる。 According to the present invention, it is possible to obtain an oily hair cosmetic having excellent glossiness at the time of application, a moist feeling, less stickiness, excellent durability of gloss from the time of application, and good applicationability.
以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.
本発明による油性毛髪化粧料には、塗布時のツヤ感に優れる観点から、（Ａ）ジメチルポリシロキサンを含有する。 The oily hair cosmetic according to the present invention contains (A) dimethylpolysiloxane from the viewpoint of excellent glossiness at the time of application.
本発明に用いる前記（Ａ）成分の２５℃条件下における動粘度は、塗布性の観点から２～１,０００,０００mm2/sのものが好ましく、より好ましくは１０～１００，０００mm2/sである。 The kinematic viscosity of the component (A) used in the present invention under 25 ° C. conditions is preferably 2 to 1,000,000 mm 2 / s, more preferably 10 to 100,000 mm 2 / s from the viewpoint of coatability. Is.
本発明に用いる前記（Ａ）成分は、油性毛髪化粧料中に含有されていればよいが、好ましくは８０～９２質量％がよく、より好ましくは８５～９２質量％がよい。前記（Ａ）成分が８０質量％未満の場合、塗布時のツヤ感がなくなるおそれがある。一方、前記（Ａ）成分が９２質量％を超える場合、べたつき感が生じるおそれがある。 The component (A) used in the present invention may be contained in an oily hair cosmetic, preferably 80 to 92% by mass, and more preferably 85 to 92% by mass. When the component (A) is less than 80% by mass, the glossiness at the time of application may be lost. On the other hand, when the component (A) exceeds 92% by mass, a sticky feeling may occur.
本発明による油性毛髪化粧料には、しっとり感の観点から、（Ｂ）ジメチコノールを含有する。 The oily hair cosmetic according to the present invention contains (B) dimethiconol from the viewpoint of moist feeling.
本発明に用いる前記（Ｂ）成分は、ジメチルポリシロキサンの末端メチル基が水酸基になったものである。ジメチコノールの２５℃における動粘度は、好ましくは５００，０００mm2/s以上、さらに好ましくは１，０００，０００mm2/s以上であり、また、べたつきのなさ、剤の伸ばしやすさの観点から好ましくは６５，０００，０００mm2/s以下、さらに好ましくは３５，０００，０００mm2/s以下である。 The component (B) used in the present invention is obtained by converting the terminal methyl group of dimethylpolysiloxane into a hydroxyl group. The kinematic viscosity of dimethiconol at 25 ° C. is preferably 500,000 mm 2 / s or more, more preferably 1,000,000 mm 2 / s or more, and is preferably from the viewpoint of non-stickiness and ease of spreading of the agent. It is 65,000,000 mm 2 / s or less, more preferably 35,000,000 mm 2 / s or less.
本発明に用いる前記（Ｂ）成分は、油性毛髪化粧料中に含有されていればよいが、好ましくは４．８～９．６質量％がよく、より好ましくは７．２～９．６質量％がよい。前記（Ｂ）成分が４．８質量％未満の場合、しっとり感がなくなるおそれがある。一方、前記（Ｂ）成分が９．６質量％を超える場合、べたつき感が生じるおそれがある。 The component (B) used in the present invention may be contained in the oily hair cosmetic, preferably 4.8 to 9.6% by mass, and more preferably 7.2 to 9.6% by mass. % Is good. When the component (B) is less than 4.8% by mass, the moist feeling may be lost. On the other hand, when the component (B) exceeds 9.6% by mass, a sticky feeling may occur.
本発明による油性毛髪化粧料には、べたつき感の少なさの観点から、（Ｃ）イソノナン酸イソノニルを含有する。 The oily hair cosmetic according to the present invention contains (C) isononyl isononanoate from the viewpoint of less stickiness.
本発明に用いる前記（Ｃ）成分は、油性毛髪化粧料中に含有されていればよいが、好ましくは３～１０質量％がよく、より好ましくは５～１０質量％がよい。前記（Ｃ）成分が３質量％未満の場合、べたつき感を生じるおそれがある。一方、前記（Ｃ）成分が１０質量％を超える場合、塗布性が悪くなるおそれがある。 The component (C) used in the present invention may be contained in an oily hair cosmetic, preferably 3 to 10% by mass, more preferably 5 to 10% by mass. If the component (C) is less than 3% by mass, a sticky feeling may occur. On the other hand, when the component (C) exceeds 10% by mass, the coatability may deteriorate.
本発明による油性毛髪化粧料には、前記（Ｂ）成分および前記（Ｃ）成分を含有するが、塗布時からのツヤの持続性に優れる観点から、油性毛髪化粧料の含有量の質量比（Ｂ）／（Ｃ）が好ましくは、０．４８～３．２がよく、より好ましくは０．９６～２．４がよい。油性毛髪化粧料の含有量の質量比（Ｂ）／（Ｃ）が０．４８未満および３．２を超える場合、塗布時からのツヤの持続性が得られない。 The oily hair cosmetic according to the present invention contains the component (B) and the component (C), but from the viewpoint of excellent durability of gloss from the time of application, the mass ratio of the content of the oily hair cosmetic is ( B) / (C) is preferable, 0.48 to 3.2 is preferable, and 0.96 to 2.4 is more preferable. When the mass ratio (B) / (C) of the content of the oily hair cosmetic is less than 0.48 and more than 3.2, the gloss persistence from the time of application cannot be obtained.
本発明による油性毛髪化粧料の粘度は、塗布性の観点から２５℃条件下で５００～２，５００ｍＰａ・ｓが好ましく、より好ましくは９００～２，５００ｍＰａ・ｓがよい。油性毛髪化粧料の粘度が５００ｍＰａ・ｓ未満の場合、毛髪から垂れ落ちる恐れがある。一方、油性毛髪化粧料の粘度が２，５００ｍＰａ・ｓを超える場合、のびが悪くなるおそれがある。 The viscosity of the oily hair cosmetic according to the present invention is preferably 500 to 2,500 mPa · s, more preferably 900 to 2,500 mPa · s under the condition of 25 ° C. from the viewpoint of coatability. If the viscosity of the oil-based hair cosmetic is less than 500 mPa · s, it may drip from the hair. On the other hand, if the viscosity of the oil-based hair cosmetic exceeds 2,500 mPa · s, the spread may be deteriorated.
本発明による２５℃条件下における粘度は、常法にて調製して得られた油性毛髪化粧料をサンプル瓶（食品１４０：第一硝子株式会社製）に１２０ｇ充填し、２５℃で１日間静置した後に、ヘリカルスタンド付Ｂ型粘度計（モデル：デジタル粘度計ＴＶＢ－１０Ｍ、東機産業株式会社製）により、Ｍ３号ローターを用いて２５℃、１２ｒｐｍで１分間回転させた後に測定したものである。 For the viscosity under 25 ° C. conditions according to the present invention, 120 g of an oily hair cosmetic prepared by a conventional method was filled in a sample bottle (Food 140: manufactured by Daiichi Glass Co., Ltd.) and allowed to stand at 25 ° C. for 1 day. After placing, it was measured by a B-type viscometer with a helical stand (model: digital viscometer TVB-10M, manufactured by Toki Sangyo Co., Ltd.) after rotating at 25 ° C. and 12 rpm for 1 minute using an M3 rotor. Is.
本発明の油性毛髪化粧料には、上記必須成分の他に、本発明の効果を損なわない範囲で、化粧料一般に使用される成分を配合することができる。例えば、油性成分、界面活性剤、紫外線吸収剤、糖類、酸化防止剤、防腐剤、美容成分、香料等を用いることができ、これらは１種または２種以上含有してもよい。 In addition to the above essential ingredients, the oily hair cosmetics of the present invention may contain ingredients generally used in cosmetics as long as the effects of the present invention are not impaired. For example, oily components, surfactants, ultraviolet absorbers, sugars, antioxidants, preservatives, cosmetological components, fragrances and the like can be used, and these may be contained alone or in combination of two or more.
本発明による油性毛髪化粧料は、水を含有せず、透明液状の油性化粧料としてヘアトリートメント等に用いることができる。 The oily hair cosmetic according to the present invention does not contain water and can be used for hair treatments and the like as a transparent liquid oily cosmetic.
以下に実施例を挙げて本発明をより詳細に説明する。なお、これらは本発明を何ら限定するものではない。 Hereinafter, the present invention will be described in more detail with reference to examples. It should be noted that these do not limit the present invention in any way.
本明細書に示す評価試験において、油性毛髪化粧料に含まれる成分およびその含有量を種々変更しながら実施した。各成分の含有量を示す単位はすべて質量％であり、これを常法にて調製した。 In the evaluation test shown in the present specification, the components contained in the oily hair cosmetics and their contents were variously changed. The unit indicating the content of each component is all mass%, which was prepared by a conventional method.
（評価方法）
下記の評価項目について各々下記評価方法により評価を行った。各試料について専門パネラー１０名より、各評価項目について、下記５段階絶対評価基準にて評価し、評点を付け、各パネラー全員の評点合計から、その平均値の小数点第二位を四捨五入して算出し、下記４段階評価結果とした。塗布時からのツヤの持続性に関する（ｄ）の項目については試料塗布後、通常の生活をしてもらい３時間後に測定した。
(Evaluation methods)
The following evaluation items were evaluated by the following evaluation methods. Each sample is evaluated by 10 specialized panelists for each evaluation item according to the following 5-step absolute evaluation criteria, and a score is given. From the total score of all panelists, the second decimal place of the average value is rounded off. Then, the following four-stage evaluation results were used. Regarding the item (d) regarding the sustainability of gloss from the time of application, after the sample was applied, the sample was taken to live a normal life and measured 3 hours later.
[官能評価項目]
（ａ）塗布時のツヤ感
（ｂ）しっとり感
（ｃ）べたつき感の少なさ
（ｄ）塗布時からのツヤの持続性
（ｅ）塗布性
[Sensory evaluation items]
(A) Glossy feeling at the time of application (b) Moist feeling (c) Less sticky feeling (d) Persistence of gloss from the time of application (e) Applyability
[５段階絶対評価基準]
５点：非常に良好
４点：良好
３点：普通
２点：やや不良
１点：不良
[5-step absolute evaluation criteria]
5 points: very good 4 points: good 3 points: normal 2 points: slightly defective 1 point: defective
[４段階評価結果]
◎：４点以上
○：３点以上４点未満
△：２点以上３点未満
×：２点未満
[Four-step evaluation result]
⊚: 4 points or more ○: 3 points or more and less than 4 points △: 2 points or more and less than 3 points ×: less than 2 points
実施例１～９より、「塗布時のツヤ感」、「しっとり感」、「べたつき感の少なさ」、「塗布時からのツヤの持続性」および「塗布性」に関して良好な結果が得られた。 From Examples 1 to 9, good results were obtained regarding "glossy feeling at the time of application", "moist feeling", "less sticky feeling", "sustainability of gloss from the time of application" and "applicability". rice field.
本発明により、塗布時のツヤ感に優れ、しっとり感があり、べたつき感が少なく、塗布時からのツヤの持続性に優れ、塗布性のよい油性毛髪化粧料を提供することができる。 INDUSTRIAL APPLICABILITY According to the present invention, it is possible to provide an oil-based hair cosmetic having excellent glossiness at the time of application, moist feeling, less stickiness, excellent durability of gloss from the time of application, and good applicationability.
Claims (2)
（Ｂ）ジメチコノール ４．８～９．６質量％、
（Ｃ）イソノナン酸イソノニル ３～１０質量％、
を含有し、前記（Ｂ）成分と前記（Ｃ）成分の含有量の質量比（Ｂ）／（Ｃ）が０．４８～３．２であることを特徴とする油性毛髪化粧料。 (A) Didimethylpolysiloxane having a kinematic viscosity of 10 to 100,000 mm 2 / s under 25 ° C. conditions, 80 to 92% by mass,
(B) Dimethiconol 4.8-9.6 % by mass ,
(C) Isononyl isononanoate 3 to 10% by mass,
The oily hair cosmetic containing the above component (B) and the content of the component (C) having a mass ratio (B) / (C) of 0.48 to 3.2.
The oily hair cosmetic according to claim 1, wherein the viscosity is 500 to 2,500 mPa · s under the condition of 25 ° C.
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| JP7281915B2 (en) * | 2019-02-14 | 2023-05-26 | 株式会社ミルボン | Non-aqueous hair cosmetic and hair treatment method |
| WO2020241089A1 (en) | 2019-05-28 | 2020-12-03 | 株式会社神戸製鋼所 | Gas treatment method, and gas treatment device |
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|---|---|---|---|---|
| JP2007269726A (en) | 2006-03-31 | 2007-10-18 | Kose Corp | Hair oil |
| JP2008273902A (en) | 2007-05-02 | 2008-11-13 | Kose Corp | Oily hair cosmetic |
| JP2010100543A (en) | 2008-10-22 | 2010-05-06 | Kao Corp | Hair cosmetic |
| JP2010265195A (en) | 2009-05-13 | 2010-11-25 | Kao Corp | Hair treatment composition |
| JP2015227302A (en) | 2014-05-30 | 2015-12-17 | 花王株式会社 | Liquid oil composition |
| JP2017193498A (en) | 2016-04-19 | 2017-10-26 | クラシエホームプロダクツ株式会社 | Hair cosmetic |
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2017
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007269726A (en) | 2006-03-31 | 2007-10-18 | Kose Corp | Hair oil |
| JP2008273902A (en) | 2007-05-02 | 2008-11-13 | Kose Corp | Oily hair cosmetic |
| JP2010100543A (en) | 2008-10-22 | 2010-05-06 | Kao Corp | Hair cosmetic |
| JP2010265195A (en) | 2009-05-13 | 2010-11-25 | Kao Corp | Hair treatment composition |
| JP2015227302A (en) | 2014-05-30 | 2015-12-17 | 花王株式会社 | Liquid oil composition |
| JP2017193498A (en) | 2016-04-19 | 2017-10-26 | クラシエホームプロダクツ株式会社 | Hair cosmetic |
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