CN107072897B

CN107072897B - Oily hair composition

Info

Publication number: CN107072897B
Application number: CN201680003594.9A
Authority: CN
Inventors: 松尾真树; 冈本将典
Original assignee: Mandom Corp
Current assignee: Mandom Corp
Priority date: 2015-03-27
Filing date: 2016-02-08
Publication date: 2020-09-25
Anticipated expiration: 2036-02-08
Also published as: WO2016158011A1; WO2016158012A1; CN107072921B; KR101905735B1; KR101905732B1; JPWO2016158011A1; CN107072897A; JPWO2016158012A1; KR20170066653A; KR20170066656A; CN107072921A; JP6351831B2; JP6351832B2

Abstract

The present invention provides an oily hair composition which exhibits an excellent effect of storage stability, is excellent in extensibility on the palm and hair, has excellent hair styling retention, and does not make the hair tacky after styling. The oil composition for hair of the present invention is characterized by containing a component (a): hydrocarbon oil which is solid at room temperature and/or wax which is solid at room temperature, component (B): a (norbornene/tris (trimethylsiloxy) silylnorbornene) copolymer, component (C): a volatile hydrocarbon oil, and component (D): 12-hydroxystearic acid substantially free of water.

Description

Oily hair composition

Technical Field

The present invention relates to an oily hair composition. In the present invention, room temperature means a temperature range of 1 to 30 ℃.

Background

As a cosmetic that spreads sufficiently on the palm of the hand and then applies it to the hair to perform hair styling, a hair wax, a hair cream, or the like prepared by emulsifying oil and water is generally used. However, these emulsions have a disadvantage that the hair styling agent is liable to run down by moisture or sweat due to the incorporation of an emulsifier, and thus the hair styling retention is poor.

On the other hand, there are cosmetics called clays, which are nonaqueous waxes mainly composed of solid oils and nonvolatile oils and prepared without mixing water. The non-aqueous wax such as clay has excellent hair setting retention. However, if the solid oil is highly compounded, there are the following disadvantages: the composition itself had a heavy feeling in use, had poor spreadability on fingers and hands and spreadability on hair, had poor extensibility, and had stickiness after application. In addition, when a nonvolatile oil is highly compounded, although ductility is improved, the following disadvantages are involved: the hair styling method is liable to cause stickiness peculiar to the oil, and is poor in hair styling ability and hair styling retention, and thus requires repeated hair styling. In addition, the separation occurs in a high-temperature region, and the storage stability of the preparation is deteriorated.

In order to solve the above-mentioned disadvantages, attempts have been made to improve the developability in a nonaqueous composition. Specifically, for example, nonaqueous hair cosmetics containing vegetable oil containing triglyceride as a main component, dimethiconol, cyclic silicone, and dioctyl ether have been proposed (see patent document 1); an oily solid hair cosmetic composition containing an oil-swellable clay mineral, a specific surfactant, an oil agent which is pasty at 25 ℃ and an oil agent having a melting point of 35 to 120 ℃ (see patent document 2). However, although the above attempts can improve the extensibility to some extent, there are problems that a sufficient hair styling force cannot be obtained and hair styling cannot be performed as desired in hair styling. Further, the above attempts have a problem that stickiness peculiar to the oil agent tends to occur.

Therefore, attempts have been made to reduce stickiness and impart hair styling power. Specifically, for example, hair wax products have been proposed which contain a silicone-free wax, a liquid hydrophobic oil, and a silicone wax, and which do not contain water (see patent document 3); and so on. However, although such attempts can improve the stickiness peculiar to oil agents and can impart a certain level of hair styling power, there is a problem that separation in a high temperature region is likely to occur and storage stability is poor.

Documents of the prior art

Patent document

Patent document 1: japanese patent laid-open publication No. 2011-207807

Patent document 2: japanese patent laid-open publication No. 2011-229071

Patent document 3: japanese patent laid-open publication No. 2005-213252

Disclosure of Invention

Problems to be solved by the invention

The present invention has been made in view of the above-mentioned conventional techniques, and an object thereof is to provide an oil composition for hair which can exhibit an effect of excellent storage stability. Further, an object of the present invention is to provide an oily hair composition which exhibits excellent extensibility on the palm and hair, exhibits excellent hair styling retention, and does not make the hair sticky after styling.

Means for solving the problems

Namely, the present invention provides an oil composition for hair, which contains the following components (a) to (D) and does not substantially contain water.

Component (A): hydrocarbon oil solid at room temperature and/or wax solid at room temperature

Component (B): (norbornene/tris (trimethylsiloxy) silylnorbornene) copolymer

Component (C): volatile hydrocarbon oil

Component (D): 12-Hydroxystearic acid

The content of the component (a) is preferably 2 to 20% by mass.

The content of the component (B) is preferably 0.2 to 7% by mass.

The above component (C) is preferably at least one volatile hydrocarbon oil selected from the group consisting of hydrogenated polyisobutene, hydrogenated (tetradecenyl/methylpentadecene), and isododecane.

Further, the above-mentioned oily hair composition preferably contains the component (E): at least one member selected from the group consisting of glyceryl behenate, glyceryl dibehenate and glyceryl tribehenate.

Further, the above-mentioned oily hair composition preferably contains the component (F): a nonionic surfactant having an HLB value of 2 to 8.

The above-mentioned oily hair composition is preferably a hair styling agent.

ADVANTAGEOUS EFFECTS OF INVENTION

The oil composition for hair of the present invention can exert the following effects: the hair dressing composition has good extensibility on palms and hair, and can exert excellent hair dressing force, and the hair after hair dressing is not sticky. The oil-based hair composition of the present invention can exert an effect of exhibiting particularly excellent storage stability.

Detailed Description

The oil composition for hair of the present invention contains the following components (a) to (D), and does not substantially contain water.

Component (B): (norbornene/tris (trimethylsiloxy) silylnorbornene) copolymer

Component (C): volatile hydrocarbon oil

Component (D): 12-Hydroxystearic acid

The component (A) is a hydrocarbon oil which is solid at room temperature and/or a wax which is solid at room temperature. In the present specification, the "hydrocarbon oil which is solid at room temperature" may be referred to as "component (a 1)". The "wax which is solid at room temperature" may be referred to as "component (a 2)". The component (a) selected from the group consisting of the component (a1) and the component (a2) may be used alone in 1 kind, or 2 or more kinds may be used in combination as appropriate.

Specific examples of the hydrocarbon oil which is solid at room temperature as the component (a1) include ceresin, paraffin, microcrystalline wax, high-melting microcrystalline wax, polyethylene powder, polyethylene wax, vaseline, high-melting paraffin, synthetic wax, and the like. The component (A1) may be used alone in 1 kind, or 2 or more kinds may be used in combination as appropriate.

Specific examples of the wax which is solid at room temperature as the component (a2) include carnauba wax, candelilla wax, beeswax, rice bran wax, shellac wax, spermaceti wax, lanolin, and wood wax. The component (A2) may be used alone in 1 kind, or 2 or more kinds may be used in combination as appropriate.

As the suitable component (a), high melting point microcrystalline wax, polyethylene wax, high melting point paraffin wax, synthetic wax, carnauba wax, and candelilla wax are preferably used in view of hair styling ability and storage stability. Among the suitable components (a), high melting point microcrystalline wax, high melting point paraffin wax, carnauba wax, candelilla wax are more preferably used.

The content of the component (a) in the oil-based hair composition of the present invention is not particularly limited as long as the desired effect can be sufficiently exhibited, and is preferably 1% by mass or more, more preferably 2% by mass or more, based on 100% by mass of the oil-based hair composition, from the viewpoint of imparting a hair styling power and further from the viewpoint of imparting storage stability. Further, from the viewpoint of suppressing deterioration of the extensibility on the palm and the hair, and further from the viewpoint of making the feeling of use light, the oil composition for hair is preferably 25% by mass or less, more preferably 20% by mass or less, of 100% by mass. The content of the component (a) is the total content of all the components (a) blended in the oil composition for hair of the present invention.

The component (B) is a (norbornene/tris (trimethylsiloxy) silylnorbornene) copolymer. The (norbornene/tris (trimethylsiloxy) silylnorbornene) copolymer refers to a copolymer having the INCI name (international dictionary and manual for cosmetic raw materials, 15 th edition, volume 2, 2014, p.2181): NORBORNENE/TRIS (TRIMETHYLSILOXY) SILYLNORBORNENE COPOLYMER.

In the present invention, the hair-setting retention ability is remarkably excellent by containing the component (B). Further, since the total content of the component (a) can be reduced as compared with a conventional oil-based hair composition, it is possible to exert an extremely excellent hair-setting retention force with a light feeling of use without stickiness. In addition, by using the component (a) in combination, the instability of the preparation due to the separation of the slurry can be suppressed, and excellent storage stability can be exhibited.

Commercially available products can be used as the component (B). Examples of commercially available products of component (B) include NBN-30-ID (product name, manufactured by shin-Etsu chemical Co., Ltd.).

The content of the component (B) in the oil-based hair composition of the present invention is not particularly limited as long as the desired effect can be sufficiently exhibited, and is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, of 100% by mass of the oil-based hair composition, from the viewpoint of providing an exceptionally excellent hair-holding power and further from the viewpoint of exhibiting storage stability. From the viewpoint of suppressing stickiness, the amount of the oil composition for hair is preferably 10% by mass or less, and more preferably 7% by mass or less, based on 100% by mass of the oil composition for hair.

The component (C) is a volatile hydrocarbon oil. In the present invention, by containing the component (C), the stickiness peculiar to the oil agent can be suppressed and a light feeling in use can be obtained even in an oily composition.

Specific examples of the component (C) include isoparaffin, light mobile isoparaffin, hydrogenated polyisobutene, hydrogenated (tetradecenyl/methylpentadecene), and isododecane. The component (C) may be used alone in 1 kind, or may be used in combination of 2 or more kinds. As the suitable component (C), hydrogenated polyisobutene, hydrogenated (tetradecenyl/methylpentadecene), isododecane are preferably used in view of ease of extension.

Commercially available products can be used as the component (C). Commercially available hydrogenated polyisobutene products include, for example, Marukasol R (trade name, manufactured by PELLENSHI petrochemical Co., Ltd.), IP SOLVENT 1620 (trade name, manufactured by shingling Co., Ltd.), PARLEAM EX (trade name, manufactured by Nissan oil Co., Ltd.), and the like. Examples of commercially available hydrogenated (tetradecenyl/methylpentadecene) compounds include SMART5 (trade name, manufactured by Nikko chemical Co., Ltd.). Examples of commercially available isododecane include Creasil ID CG (trade name, manufactured by CIT Sarl corporation).

The content of the component (C) in the oil-based hair composition of the present invention is not particularly limited as long as the desired effect can be sufficiently exhibited, and is preferably 40% by mass or more, more preferably 50% by mass or more, of 100% by mass of the oil-based hair composition, from the viewpoint of producing the oil-based hair composition. Further, from the viewpoint of storage stability and further from the viewpoint of improvement of hair styling ability, the hair oil composition is preferably 85% by mass or less, more preferably 75% by mass or less, based on 100% by mass of the hair oil composition. The content of the component (C) is the total content of all the components (C) blended in the oil composition for hair of the present invention.

The component (D) is 12-hydroxystearic acid. 12-hydroxystearic acid refers to saturated fatty acids having an asymmetric hydroxyl group on the carbon at the 12-position of stearic acid. In the present invention, the effect of improving the extensibility of the palm and hair can be exhibited by containing the component (D). In addition, the effect of particularly excellent storage stability in a high temperature region can be exhibited.

Commercially available products can be used as the component (D). Examples of commercially available products of the component (D) include hydroxystearic acid (trade name, manufactured by Kawaken Fine Chemicals co., ltd.), 12-hydroxystearic acid (trade name, manufactured by KF tradingco., ltd.), and the like.

The content of the component (D) in the oil-based hair composition of the present invention is not particularly limited as long as the desired effect can be sufficiently exhibited, and is preferably 0.2% by mass or more, more preferably 0.3% by mass or more, of 100% by mass of the oil-based hair composition, from the viewpoint of imparting storage stability. In addition, from the viewpoint of improving the extensibility, the amount of the oil composition for hair is preferably 7% by mass or less, and more preferably 6% by mass or less, based on 100% by mass of the oil composition for hair.

The oil composition for hair of the present invention contains substantially no water. This can provide an exceptionally excellent hair-setting holding force. In the present invention, "substantially no water" means "no water is separately contained", and does not exclude a small amount of water contained in each compounding ingredient.

In addition, from the viewpoint of further improving the storage stability, the oil composition for hair of the present invention may contain at least one selected from the group consisting of glyceryl behenate, glyceryl dibehenate and glyceryl tribehenate as the component (E). The component (E) may be used alone in 1 kind, or may be used in combination of 2 or more kinds as appropriate. As an appropriate component (E), glyceryl behenate is preferably used in view of exerting particularly excellent storage stability.

Commercially available products can be used as the component (E). Examples of commercially available products of glyceryl behenate include COMPRITOL 888 CG (trade name,

manufactured by japan corporation), and the like. Examples of commercially available products of glyceryl dibehenate include compositions E ATO (trade name,

manufactured by japan corporation), and the like. Examples of commercially available products of glyceryl tribehenate include compotol 888 ATO (trade name,

manufactured by japan corporation), and the like. In the present invention, a mixed raw material containing the above-mentioned component (E) may be used.

The content of the component (E) in the oil-based hair composition of the present invention is not particularly limited as long as the desired effect can be sufficiently exhibited, and is preferably 0.5% by mass or more, more preferably 1% by mass or more, of 100% by mass of the oil-based hair composition, from the viewpoint of further improving the storage stability. In addition, from the viewpoint of improving the extensibility, the amount of the oil composition for hair is preferably 12% by mass or less, and more preferably 10% by mass or less, based on 100% by mass of the oil composition for hair. The content of the component (E) is the total content of all the components (E) blended in the oil composition for hair of the present invention.

In addition, the oil-based hair composition of the present invention may contain a nonionic surfactant having an HLB value of 2 to 8 as the component (F) in order to improve the washability from the hair during shampooing.

Examples of the component (F) include polyglycerol fatty acid esters, polyethylene glycol fatty acid esters, polyoxyethylene fatty acid esters, and polyoxyethylene fatty acid sorbitan. The fatty acid constituting the component (F) may be a straight chain fatty acid or a branched fatty acid, and is not particularly limited as long as the desired effect can be exerted, and a branched fatty acid is preferable from the viewpoint of washability. In addition, from the viewpoint of further improving the washability, the component (F) is preferably a multi-chain type except for the above conditions. Specific examples thereof include polyglycerol esters of multi-chain branched fatty acids, polyethylene glycol esters of multi-chain branched fatty acids, polyoxyethylene glycerol esters of multi-chain branched fatty acids, and polyoxyethylene sorbitan esters of multi-chain branched fatty acids.

Specific examples of suitable component (F) include PEG-3 glyceryl triisostearate (HLB value: 2), PEG-2 diisostearate (HLB value: 3), PEG-3 diisostearate (HLB value: 3), polyglycerol triisostearate-2 (HLB value: 3), PEG-4 sorbitan triisostearate (HLB value: 3), PEG-5 glyceryl triisostearate (HLB value: 3), polyglycerol diisostearate-2 (HLB value: 4), PEG-4 diisostearate (HLB value: 4), polyglycerol diisostearate-3 (HLB value: 5), PEG-5 diisostearate (HLB value: 5), PEG-10 glyceryl triisostearate (HLB value: 5), PEG-8 diisostearate (HLB value: 6), PEG-10 glyceryl diisostearate (HLB value: 7), Polyglyceryl diisostearate-6 (HLB: 8), polyglyceryl triisostearate-10 (HLB: 8), PEG-12 (HLB: 8), PEG-20 (HLB: 8), and the like. The component (F) may be used alone in 1 kind, or may be used in combination of 2 or more kinds as appropriate.

The content of the component (F) in the oil-based hair composition of the present invention is not particularly limited as long as the desired effect can be sufficiently exhibited, and is preferably 1% by mass or more, more preferably 2% by mass or more, of 100% by mass of the oil-based hair composition in terms of washability on hair during shampooing. In addition, from the viewpoint of hair set retention and storage stability, the hair oil composition is preferably 20% by mass or less, more preferably 15% by mass or less, based on 100% by mass of the hair oil composition. The content of the component (F) is the total content of all the components (F) blended in the oil composition for hair of the present invention.

In addition to the above components, components generally used in cosmetics may be blended in the oil-based hair composition of the present invention as long as the effects of the present invention are not impaired. Examples of the other components include oils other than the above-mentioned oily components such as fatty acid ester oils; surfactants other than the above; polyhydric alcohol, lower alcohol, ultraviolet absorbent, antioxidant, perfume, colorant, chelating agent, antiseptic/bactericide, humectant, algefacient, plant extractive solution, amino acid, etc. The other components may be blended as appropriate depending on the use and purpose thereof.

Further, the hair oil composition of the present invention can be suitably used as a hair styling agent since it exhibits an excellent hair styling retention.

Examples

The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples. Unless otherwise specified, the compounding amount is expressed as "% by mass", and all the compounding ingredients are converted to pure ingredients. The evaluation was carried out under constant temperature and humidity conditions of 23 ℃ and 60% humidity.

The following ingredients were used in the examples and comparative examples.

(component (A))

High melting point microcrystalline wax: trade name "HI-MIC-1090" (manufactured by Japan wax Co., Ltd.)

High melting point paraffin wax: trade name "SP-0165" (manufactured by Japan wax cleaner)

Candelilla wax: trade name "refined candelilla wax" (manufactured by Mitsuba writing Co., Ltd.)

Carnauba wax: trade name "TOWAX-1F 8" (manufactured by Toyao Kaisha)

(component (B))

(norbornene/tris (trimethylsiloxy) silylnorbornene) copolymer: trade name "NBN-30-ID" (manufactured by shin-Etsu chemical Co., Ltd.)

(component (C))

Hydrogenated polyisobutene: trade name "Marukasol R" (produced by Marukasol petrochemical Co., Ltd.)

Hydrogenated (tetradecenyl/methylpentadecene): trade name "SMART 5" (manufactured by Nikkiso Co., Ltd.)

Isododecane: trade name "Creasil ID CG" (manufactured by CIT Sarl Co., Ltd.)

(component (D))

12-hydroxystearic acid: trade name "12-hydroxystearic acid" (KF TRADING CO., LTD., manufactured)

(component (E))

Glyceryl behenate: under the trade name "COMPRITOL 888 CG" ((R))

Society manufacturing)

Glycerol dibehenate: under the trade name "COMPRITOL E ATO" ((R))

Society manufacturing)

Glyceryl tribehenate: under the trade name "COMPRITOL 888 ATO" ((R))

Society manufacturing)

(component (F))

Triisostearic acid PEG-20 glyceryl ester: the trade name is "NIKKOL TGI-20" (manufactured by Nihon surfactant kogyo Co., Ltd.)

Triisostearic acid PEG-3 glyceride: the trade name "EMALEX GWIS-303" (manufactured by Nihon Emulsion Co., Ltd.)

Di-isostearic acid PEG-10 glyceride: the trade name "EMALEX GWIS-210 EX" (Nihon Emulsion Co., Ltd.)

(other Components)

Ethylhexyl palmitate: trade name "Koyo POC" (manufactured by KOYO fine chemical corporation)

Isononyl isononanoate: trade name "SALACOS 99" (manufactured by Riqing Oligomo Co., Ltd.)

Trimethylsiloxy silicic acid: trade name "X-21-5595" (manufactured by shin-Etsu chemical Co., Ltd.)

(alkyl acrylate/dimethicone) copolymer: trade name "KP-550" (manufactured by shin-Yue chemical industry Co., Ltd.)

Cyclopentasiloxane: trade name "KF-995" (manufactured by Shin-Etsu Chemical Co., Ltd.)

Decamethylcyclohexasiloxane: "DOW CORNING TORAY DC 246" (manufactured by Dow Corning Toray Co. Ltd.)

Stearoyl inulin: trade name "Rheopearl ISL 2" (manufactured by Qianye Mill)

And (3) palmitic acid dextrin: trade name "Rheopearl KS 2" (manufactured by Qianye Mill)

(production of Each sample)

Based on the compositions shown in tables 1 to 2, the oil compositions for hair of examples 1 to 10 and comparative examples 1 to 10 were prepared and subjected to the following evaluation tests. The results are shown in tables 1 to 2.

(test example 1: evaluation of extensibility on palm)

The sample 1g obtained in each example and each comparative example was placed on the palm of a hand, and rubbed with each other with both hands, and the extensibility in the rubbing with each other was evaluated organoleptically according to the following evaluation criteria.

The evaluation was performed by 10 sensory evaluation panelists, and the evaluation result with the largest number of persons obtained was regarded as the result of each sample.

< evaluation criteria for extensibility on palm >

O (good): not agglomerated but uniformly spread.

Δ (insufficient): slightly clustered, but expandable.

X (bad): clumped and not uniformly spread.

(test example 2 evaluation of Hair extension)

Using a wig (training manikin: manufactured by YuKARI Japan), the sample obtained in each example and each comparative example was subjected to hair styling, the sample was fused to hair, and the extensibility of the hair during hair styling was evaluated sensorially according to the following evaluation criteria.

The evaluation was performed by the same 10 panelists as described above, and the result of the evaluation with the largest number of persons obtained was regarded as the result of each sample.

< evaluation criteria for extensibility on Hair >

O (good): the film was not unevenly adhered (ムラ and き) and was evenly spread.

Δ (insufficient): slightly non-uniformly attached, but spread apart.

X (bad): non-uniform adhesion and non-uniform spreading.

(test example 3 evaluation of Hair-Conditioning Retention)

After the evaluation of test example 2, the operation of holding and curling the hair tip from the hair was performed 10 times, and the shape of the hairstyle after 60 minutes was visually evaluated according to the following evaluation criteria.

< evaluation criteria for Hair styling Retention >

O (good): apparently in the shape it is held in.

Δ (insufficient): the shape of the grip begins to lose its shape.

X (bad): the shape of the grip is deformed and cannot be maintained.

(test example 4: evaluation of tackiness)

After the evaluation in test example 3, the hair stickiness of the wig was evaluated organoleptically according to the following evaluation criteria.

< evaluation criteria for tackiness >

O (good): no stickiness

Δ (insufficient): slightly sticky

X (bad): has stickiness

(test example 5: evaluation of detergency)

After the evaluation in test example 4, the hairpiece subjected to the hair setting was washed with shampoo (trade name: LUCIDO shampooo, manufactured by rambutan corporation), rinsed with warm water at 40 ℃ for 1 minute, dried with a towel, and subjected to sensory evaluation of the dried hair according to the following evaluation criteria.

< evaluation criteria for detergency >

O (good): the hair was not sticky and was washed off thoroughly.

Δ (insufficient): the hair is slightly tacky but can be washed off.

X (bad): the hair was sticky and not washed off.

(test example 6: evaluation of storage stability)

The samples obtained in each example and each comparative example were each filled in a transparent glass container having a capacity of 30g, and the state of the system after being stored for 1 week in a thermostatic bath at 40 ℃ was visually observed and visually evaluated according to the following evaluation criteria.

< evaluation criteria for storage stability >

O (good): and no change was observed immediately after the production.

Δ (insufficient): slight separation was confirmed.

X (bad): a clear separation was confirmed.

[ Table 1]

As is clear from the results in tables 1 to 2, the oily hair compositions of the examples exhibited better spreadability on the palm and on the hair, exhibited excellent hair-setting retention, and exhibited the effect of preventing the hair from becoming sticky after hair setting, as compared with the oily hair compositions of the comparative examples. It is also found that the oil-based hair composition of each example exerts an effect of excellent washability from hair. Further, it was found that the oil-based hair compositions of the examples exhibited particularly excellent storage stability.

On the other hand, the effects of the present invention cannot be sufficiently obtained in comparative examples 1 to 2, comparative example 5, and comparative example 8, which do not satisfy the essential components of the present invention. In particular, in comparative examples 1, 5 and 8, the oil agent bleeds out and becomes a separated state, the storage stability is poor, and the uniformity of the composition is lost, so that the effects of the present invention cannot be exerted.

It is also found that in comparative examples 3 and 4 in which component (B) which is an essential component of the present invention is replaced with another coating forming component, comparative examples 6 and 7 in which component (C) which is an essential component of the present invention is replaced with another volatile oil agent, and comparative examples 9 and 10 in which component (D) which is an essential component of the present invention is replaced with another oil gelling agent, the oil agent also bleeds out to form a separated state, the storage stability is poor, and the uniformity of the composition is lost, and therefore the effects of the present invention cannot be exerted.

Claims

1. An oily hair composition which comprises the following components (A) to (D),

the content of the component (A) is 1 to 25% by mass,

the content of the component (B) is 0.1 to 10 mass%,

the content of the component (C) is 40 to 85 mass%,

the content of the component (D) is 0.2 to 7% by mass,

the water-free glass fiber contains substantially no water,

component (A): a hydrocarbon oil which is solid at room temperature and/or a wax which is solid at room temperature;

component (B): (norbornene/tris (trimethylsiloxy) silylnorbornene) copolymer;

component (C): a volatile hydrocarbon oil;

component (D): 12-hydroxystearic acid.

2. The oily hair composition according to claim 1, wherein the content of the component (A) is from 2 to 20% by mass.

3. The oily hair composition according to claim 1 or 2, wherein the content of the component (B) is from 0.2 to 7% by mass.

4. The oily hair composition according to claim 1 or 2, wherein the component (C) is at least one selected from the group consisting of hydrogenated polyisobutene, hydrogenated (tetradecenyl/methylpentadecene), and isododecane.

5. The oily hair composition according to claim 1 or 2, which further comprises the following component (E),

component (E): at least one member selected from the group consisting of glyceryl behenate, glyceryl dibehenate and glyceryl tribehenate.

6. The oily hair composition according to claim 1 or 2, which further comprises the following component (F),

component (F): a nonionic surfactant having an HLB value of 2 to 8.

7. The oily hair composition according to claim 1 or 2, which is a hair styling agent.