KR20170050390A - Composition for anti-fine dust comprising negative charged material - Google Patents

Composition for anti-fine dust comprising negative charged material Download PDF

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KR20170050390A
KR20170050390A KR1020150151865A KR20150151865A KR20170050390A KR 20170050390 A KR20170050390 A KR 20170050390A KR 1020150151865 A KR1020150151865 A KR 1020150151865A KR 20150151865 A KR20150151865 A KR 20150151865A KR 20170050390 A KR20170050390 A KR 20170050390A
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composition
dust
skin
negative charge
pmaa
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이승환
이현석
최경호
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(주)아모레퍼시픽
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/02Cosmetics or similar toilet preparations characterised by special physical form
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/55Phosphorus compounds
    • A61K8/553Phospholipids, e.g. lecithin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/02Cosmetics or similar toilet preparations characterised by special physical form
    • A61K8/0216Solid or semisolid forms
    • A61K8/022Powders; Compacted Powders
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/19Cosmetics or similar toilet preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/19Cosmetics or similar toilet preparations characterised by the composition containing inorganic ingredients
    • A61K8/29Titanium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/55Phosphorus compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41Particular ingredients further characterized by their size
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5424Polymers characterized by specific structures/properties characterized by the charge anionic

Abstract

Disclosed is a dustproof composition comprising a negatively charged material. A polymer or an inorganic matter included in the dustproof composition as an active ingredient has a similar zeta potential to dust. Accordingly, the dustproof composition can minimize that dust is attached to the skin through electrostatic power and can easily remove dust from the skin even if the dust is temporarily attached to the skin. Especially, skin penetration of fine dust is prevented, and skin irritation and heavy metal accumulation can be minimized so the dustproof composition is helpful for skin health.

Description

음전하 물질을 포함하는 미세먼지 방진용 조성물{Composition for anti-fine dust comprising negative charged material}TECHNICAL FIELD [0001] The present invention relates to a composition for anti-dust protection comprising a negative charge material,
본 명세서에는 신규한 방진용 조성물이 개시된다.Disclosed herein is a novel composition for dustproofing.
먼지가 체내에 쌓이면, 인체 면역력이 떨어지고 심장 질환이나 호흡기 질환과 같은 각종 질환을 유발할 수 있다. 심지어 기관지에 협착을 일으키기도 하고 장시간 흡입하면 천식이나 폐질환 유병률, 조기 사망률을 증가시킨다. If the dust accumulates in the body, the body's immune system will drop, and it can cause various diseases such as heart disease and respiratory disease. Even causing bronchial stenosis and prolonged inhalation increase the prevalence of asthma and lung disease and increase early mortality.
피부는 먼지와 직접적으로 접촉하는 우리 몸의 가장 바깥쪽으로 유기체와 환경사이의 장벽 역할을 하는데, 자주 직접적으로 오염에 노출 될 경우, 이 장벽 기능이 저하된다. 특히, 미세먼지는 모공보다 20배 더 작기 때문에 피부에 쉽게 침투할 수 있다. 실제로 미세먼지와 같은 대기 오염물질은 피부 건강에 심각한 영향을 주는 것으로 알려졌다. 단기적으로는 조기 노화, 수분 부족, 잔주름과 주름을 증가시키고, 장기적으로는 되돌릴 수 없는 피부 손상으로 인해 피부가 환경적 요소들로부터 몸을 보호하는 기능을 상실하면서 피부암과 같은 심각한 병을 초래할 수 있다.The skin acts as a barrier between the organism and the environment at the outermost of our body, which is in direct contact with the dust. This barrier function is often impaired when exposed directly to pollution. In particular, fine dust is 20 times smaller than pores and can easily penetrate the skin. In fact, air pollutants such as fine dusts are known to have a profound effect on skin health. In the short term, it can lead to premature aging, lack of moisture, wrinkles and wrinkles, and serious illnesses such as skin cancer, with skin irreparable in the long run losing its ability to protect the body from environmental factors .
따라서, 피부에 해롭고 때로는 인체에 치명적인 장애를 일으키는 유해 물질인 먼지의 피부에의 부착을 방지시키기 위한 화장료에 관한 연구가 필요하다.Therefore, there is a need for studies on cosmetics to prevent the adherence of dust, which is harmful to the skin and sometimes harmful to the human body, which is harmful substance, to the skin.
일 측면에서, 본 발명의 목적은, 먼지가 피부에 부착되는 것을 방지하는 것이다.In one aspect, an object of the present invention is to prevent dust from adhering to the skin.
다른 측면에서, 본 발명의 목적은, 피부에 부착된 먼지를 용이하게 제거하는 것이다.In another aspect, an object of the present invention is to easily remove dust adhering to the skin.
다른 측면에서, 본 발명의 목적은, 미세먼지의 피부 침투를 최소화하는 것이다.In another aspect, an object of the present invention is to minimize skin penetration of fine dust.
다른 측면에서, 본 발명의 목적은, 미세먼지로 인한 피부의 오염을 방지 또는 최소화하는 것이다. In another aspect, an object of the present invention is to prevent or minimize skin contamination due to fine dust.
일 측면에서, 본 발명은, pH7의 수용액에서의 제타전위 값이 -2mV 이하인 음전하 물질을 유효성분으로 포함하고 상기 음전하 물질은 고분자 또는 무기물인, 방진용 조성물을 제공한다.In one aspect, the present invention provides a dustproofing composition comprising a negative charge material having a zeta potential value of -2 mV or lower in an aqueous solution of pH 7 as an active ingredient, and the negative charge material is a polymer or an inorganic material.
일 측면에 있어서, 본 발명의 방진용 조성물은, 먼지, 특히 미세먼지가 피부에 부착되는 것을 최소화할 수 있다. 구체적으로, 방진용 조성물에 유효성분으로 포함된 음전하 물질은, 먼지와 유사한 음전하의 제타전위를 가지므로, 정전기적 힘에 의해 먼지가 피부에 부착되는 것을 최소화할 수 있고, 먼지가 일시적으로 피부에 부착되더라도 먼지를 피부로부터 쉽게 제거할 수 있다. 특히, 미세먼지의 피부 침투를 방지하여, 이로 인한 피부 염증, 중금속 축적을 최소화할 수 있어서, 피부 건강에 유익하다.In one aspect, the dust-proofing composition of the present invention can minimize adhesion of dust, particularly fine dust, to the skin. Specifically, since a negative charge material contained in an antidustence composition as an effective component has a zeta potential of a negative charge similar to that of a dust, it is possible to minimize adherence of dust to the skin by electrostatic force, Even if attached, dust can easily be removed from the skin. In particular, it prevents skin infiltration of fine dust, thereby minimizing skin inflammation and accumulation of heavy metals, which is beneficial for skin health.
도 1은, 음전하 후보물질들을 포함하는 조성물을 처리한 인공피혁에서의 카본블랙 흡착 테스트의 결과를 보이는 도이다(1: 대조군, 2: PMAA-나트륨 염 (MW=75100) 함유, 3: PMAA-나트륨 염 (MW=18500) 함유, 4: PMAA-나트륨 염 (MW=7750) 함유, 5: 포스포리폰 100 함유, 6: MPC-TiO2 함유, 7: PMAA-나트륨 용액 함유, 8: 포스포리폰 90 함유, 9: 티타늄옥사이드(TiO2 (Titanium Oxide)) 함유, 10: PMAA-TiO2 함유, 11: 대조군, 12: 징크옥사이드(ZnO,(Zinc Oxide)) 함유, 13: 산화알루미늄(Al2O3) 함유, 14: 키토산 함유).
도 2는, 음전하 후보물질들을 포함하는 조성물을 처리한 인공모발에서의 카본블랙 흡착 테스트의 결과를 보이는 도이다(blank: 대조군, 샘플1: PMAA-나트륨 염(mw=75100) 함유, 샘플 2: PMAA-나트륨 염(mw=18500) 함유, 샘플 3: 포스포리폰 100 함유, 샘플 4: MPC 표면처리된 이산화티타늄(MPC-TiO2) 함유, 샘플 5: PMAA-나트륨 함유, 샘플 6: PMAA 표면처리된 이산화티타늄(PMAA-TiO2) 함유).
Figure 1 shows the results of a carbon black adsorption test on artificial leather treated with a composition comprising negative charge candidate materials (1: control, 2: PMAA-sodium salt (MW = 75100) Sodium salt (MW = 18500), 4: PMAA-sodium salt (MW = 7750), 5: phospholipone 100, 6: MPC-TiO 2 , 7: PMAA-sodium solution, phone 90 containing, 9: titanium oxide (TiO 2 (titanium oxide)) containing, 10: PMAA-TiO 2 contained, 11: control group, 12: zinc oxide (ZnO, (zinc oxide)) containing, 13: aluminum (Al oxide 2 O 3 ), and 14: chitosan-containing).
FIG. 2 shows the results of a carbon black adsorption test on artificial hair treated with a composition comprising negative charge candidate materials (blank: control, sample 1: PMAA-sodium salt (mw = 75100) Containing MPC-TiO2, Sample 5: containing PMAA-sodium, Sample 6: containing PMAA-sodium salt (mw = 18500), Sample 3: containing phospholipone 100, Sample 4: containing MPC surface treated titanium dioxide Containing titanium dioxide (PMAA-TiO2).
본 명세서에서 방진이란, 먼지가 피부에 부착되는 것 또는 피부에 임시적으로 부착된 먼지가 피부에서 제거되어 피부에 침투하는 것을 예방하거나, 최소화하는 것을 의미한다. 즉, 본 명세서의 방진용 조성물을 피부에 적용할 경우, 피부에 먼지가 부착되는 것을 최소화 할 수 있고, 만약 먼지가 피부에 부착되더라도 바람 등의 물리적 힘에 의하여 쉽게 제거될 수 있다.In the present specification, dustproof means to prevent dust from adhering to the skin or to prevent the dust temporarily adhering to the skin from being removed from the skin and penetrating into the skin. That is, when the dust-proofing composition of the present invention is applied to the skin, it is possible to minimize the adherence of dust to the skin, and even if dust adheres to the skin, it can be easily removed by physical force such as wind.
본 명세서에서 먼지는, 대기 중에 섞여 있는 미립자를 총칭하는 것으로, 보통0.1㎛~10mm의 입경을 가진 부유물질을 의미한다. 특히, 입경이 10㎛이하인 경우 미세먼지, 0.1㎛ 이하인 경우 극미세 먼지라고도 한다. 여기서 입경은, 미세먼지 각 입자 지름의 평균값을 의미할 수 있다. 먼지는, 모래, 흙 및 꽃가루와 같은 자연에서 유래한 물질 또는 탄소, 탄소 연소물, 금속염 및 중금속과 같은 산업공정으로부터 유래한 물질 등을 포함하는 물질이다. 먼지의 존재 형태는 흄(fume), 미스트(mist), 연기, 증기 또는 연무일 수 있다. 일반적으로 먼지, 특히 미세먼지의 제타전위 값은 음수이다.In the present specification, dust is a generic term of fine particles mixed in the air and means a suspended material having a particle diameter of usually 0.1 to 10 mm. Particularly, when the particle diameter is 10 μm or less, it is called fine dust, and when it is 0.1 μm or less, it is also called minute dust. Here, the particle size can mean the average value of the particle diameter of the fine dust particles. Dust is a material that is derived from nature, such as sand, soil, and pollen, or from industrial processes such as carbon, carbon burn, metal salts, and heavy metals. The presence of dust can be fume, mist, smoke, steam or mist. In general, the zeta potential of dust, especially fine dust, is negative.
일 측면에서, 본 발명은, pH7의 수용액에서의 제타전위 값이 -2mV 이하인 음전하 물질을 유효성분으로 포함하고, 상기 음전하 물질은 고분자 또는 무기물인, 방진용 조성물이다. 본 명세서에서, 음전하 물질이란, 제타전위(zeta potential)값이 음의 값을 갖는 물질을 의미할 수 있다. 제타전위 값은 통상적으로 알려진 방법에 의하여 측정될 수 있다.In one aspect, the present invention is a composition for vibration damping, which comprises a negative charge material having a zeta potential value of -2 mV or lower in an aqueous solution of pH 7 as an effective component, and the negative charge material is a polymer or an inorganic material. In this specification, a negative charge substance may mean a substance having a negative zeta potential value. The zeta potential value can be measured by a conventionally known method.
상기 음전하 물질의 제타전위 값은, -2mV이하일 수 있고, -3mV이하, -10mV이하, -20mV이하, -30mV이하, -40mV이하, -50mV이하, -60mV이하, -70mV이하일 수 있으나, 이에 제한되는 것은 아니다. The zeta potential value of the negative charge material may be -2 mV or less and may be -3 mV or less, -10 mV or less, -20 mV or less, -30 mV or less, -40 mV or less, -50 mV or less, -60 mV or less or -70 mV or less But is not limited to.
상기와 같은 측면에서, 상기 음전하 물질은, pH7의 수용액에서의 제타전위 값이 -50mV 내지 -10mV일 수 있다. 상기 제타전위 값은, -50mV 내지 -10mV, -45mV 내지 -10mV, -40mV 내지 -10mV, -35mV 내지 -10mV, -30mV 내지 -10mV, -25mV 내지 -10mV, -25mV 내지 -10mV, -50mV 내지 -15mV, -50mV 내지 -20mV, -50mV 내지 -25mV, -50mV 내지 -30mV, -50mV 내지 -35mV 또는 -50mV 내지 -40mV일 수 있으나, 이에 제한되는 것은 아니다. 특히, 상기 고분자 또는 무기물의 제타전위 값이 -45mV 내지 -10mV의 범위에서, 미세먼지 방진 효과가 가장 우수하다. 미세먼지는, 음의 제타전위를 갖기 때문에, 방진용 조성물 내의 음전하 물질과의 정전기적 척력에 의하여 피부 부착이 최소화되는 것일 수 있다.In this aspect, the negative charge material may have a zeta potential value in an aqueous solution of pH 7 of -50 mV to -10 mV. The zeta potential value is in the range of -50 mV to -10 mV, -45 mV to -10 mV, -40 mV to -10 mV, -35 mV to -10 mV, -30 mV to -10 mV, -25 mV to -10 mV, -50 mV to -40 mV, -50 mV to -20 mV, -50 mV to -25 mV, -50 mV to -30 mV, -50 mV to -35 mV, or -50 mV to -40 mV. Particularly, when the zeta potential of the polymer or the inorganic material is in the range of -45 mV to -10 mV, the fine dust-preventing effect is most excellent. Since the fine dust has a negative zeta potential, the skin adhesion may be minimized by the electrostatic repulsion force with the negative charge substance in the dustproof composition.
상기와 같은 측면에서, 상기 고분자는 포스포리피드(phospholipid) 또는 폴리(메스아크릴레이트)(poly(methacrylate))일 수 있으나, 이에 제한되는 것은 아니다. In this regard, the polymer may be, but is not limited to, phospholipid or poly (methacrylate).
또한, 상기 무기물은, 이산화규소(SiO2) 또는 이산화티타늄(TiO2)일 수 있으나, 이에 제한되는 것은 아니다.In addition, the inorganic material may be silicon dioxide (SiO 2 ) or titanium dioxide (TiO 2 ), but is not limited thereto.
또한, 상기 포스포리피드는, 포스파티딜글리세롤(phosphatidylglycerol), 포스파티딜에탄올아민 (phosphatidylethanolamine), 포스파티딜세린(phosphatidylserine), 폴리에틸렌글리콜 포스포리피드(polyethyleneglycol phospholipid), 스핑고미엘린(sphingomyelin) 및 포스파티딜콜린(phosphatidylcholine)으로 구성되는 군으로부터 선택되는 것일 수 있으나, 이에 제한되는 것은 아니다.In addition, the phospholipid may be composed of phosphatidylglycerol, phosphatidylethanolamine, phosphatidylserine, polyethyleneglycol phospholipid, sphingomyelin, and phosphatidylcholine. But is not limited thereto.
또한, 상기 포스파티딜콜린은, 하이드로제네이티드 포스파티딜콜린(hydrogenated phosphatidylcholine)일 수 있다. In addition, the phosphatidylcholine may be hydrogenated phosphatidylcholine.
일 구현예에서, 상기 포스파티딜콜린은, 상표명 포스포리폰 50®(phospholipon50®), 포스포리폰 75®(phospholipon75®) 포스포리폰 80H®(phospholipon80H®) 포스포리폰 85G®(phospholipon85G®) 포스포리폰 90G®(phospholipon90G®) 포스포리폰 90H®(phospholipon90H®) 포스포리폰 50®(phospholipon50®) 포스포리폰 50®(phospholipon50®) 또는 포스포리폰 100®(phospholipon100®) 인 물질일 수 있다. 이들 물질은, 시그마알드리치사(Sigma Aldrich)부터 구할 수 있다.In one embodiment, the phosphatidylcholine is selected from the group consisting of phospholipon 50®, phospholipon 75® phospholipon 80H®, phospholipon 85G® phospholipone, 90G® (phospholipon90G®) phospholipon90H® phospholipon50® This can be a phospholipon50® or a phospholipon100®. These materials can be obtained from Sigma Aldrich.
또한, 상기 폴리(메스아크릴레이트)는, 폴리(메스아크릴 산) 나트륨 염(Poly(methacrylic acid) sodium salt)을 포함할 수 있다.In addition, the poly (methacrylate) may include a poly (methacrylic acid) sodium salt.
일 구현예에서 상기 폴리(메스아크릴 산) 나트륨 염(Poly(methacryl acid) sodium salt)은, 폴리(메스아크릴 산)-나트륨 염(PMAA-Na Salt)(MW=75100), 폴리(메스아크릴 산)-나트륨 염(PMAA-Na Salt)(MW=18500), 폴리(메스아크릴 산)-나트륨 염(PMAA-Na Salt)(MW=7750) 또는 폴리(메스아크릴 산)-나트륨 염(PMAA-Na Salt)(MW=1270)일 수 있다. 이들은, 시그마알드리치사(Sigma Aldrich) 로부터 입수할 수 있다.In one embodiment, the poly (methacrylic acid) sodium salt is selected from the group consisting of poly (methacrylic acid) -sodium salt (PMAA-Na Salt) (MW = 75100), poly Sodium salt (PMAA-Na salt) (MW = 18500), poly (methacrylic acid) -sodium salt (MW = 7750) or poly (methacrylic acid) Salt) (MW = 1270). These are available from Sigma Aldrich.
또한, 상기와 같은 측면에서, 상기 무기물은, 2-메타크릴로일옥시에틸 포스포릴콜린(2-(methacryloyloxy)ethyl phosphorylcholine, MPC)또는 폴리(메스아크릴 산)(Poly(methacrylic acid))으로 표면 처리 된 것일 수 있다. 이러한 표면 처리는, 무기물의 표면에 커플링제를 반응시킨 후, 생체친화성 고분자인 2-메타크릴로일옥시에틸 포스포릴콜린(MPC)또는 폴리(메스아크릴 산)을 예컨대 그라프팅 공법을 통해 무기물의 표면에 고르게 코팅하여 얻을 수 있으나, 표면 처리 방법은 이에 제한되지 않고, 예컨대, 한국특허 제2012-0065929호에 개시된 방법 등 공지의 방법에 의할 수 있다.In addition, in the above-mentioned aspect, the inorganic material may be formed by 2-methacryloyloxy ethyl phosphorylcholine (MPC) or poly (methacrylic acid) It may be processed. This surface treatment can be carried out by reacting the surface of the inorganic material with a coupling agent and then reacting the biocompatible polymer 2-methacryloyloxyethylphosphorylcholine (MPC) or poly (methacrylic acid) But the surface treatment method is not limited thereto. For example, a known method such as the method disclosed in Korean Patent No. 2012-0065929 can be used.
상기와 같은 측면에서, 상기 음전하 물질은, 방진용 조성물 총 중량을 기준으로, 1 내지 50중량%로 포함될 수 있다. 상기 음전하 물질의 함량은, 제한되지 않고 1 내지 40중량%, 1 내지 30중량%, 1 내지 20 중량%, 1 내지 10 중량%, 1 내지 8중량%, 1 내지 6 중량% 또는 1 내지 4 중량%일 수 있다. In this respect, the negative charge material may be contained in an amount of 1 to 50% by weight based on the total weight of the composition. The content of the negative charge material is not limited and may be 1 to 40 wt%, 1 to 30 wt%, 1 to 20 wt%, 1 to 10 wt%, 1 to 8 wt%, 1 to 6 wt% or 1 to 4 wt% %. ≪ / RTI >
상기와 같은 측면에서, 상기 조성물은 입경이 10㎛이하인 미세먼지를 방진하는 것일 수 있다. 입경 크기는, 제한되지 않고, 100㎛ 이하, 90㎛ 이하, 70㎛ 이하, 50㎛ 이하, 30㎛ 이하, 20㎛ 이하, 15㎛ 이하 또는 10㎛ 이하일 수 있다.In the above aspect, the composition may be to dust the fine dust having a particle diameter of 10 mu m or less. The size of the particle size is not limited and may be 100 μm or less, 90 μm or less, 70 μm or less, 50 μm or less, 30 μm or less, 20 μm or less, 15 μm or less or 10 μm or less.
상기와 같은 측면에서, 상기 방진용 조성물은, 화장료 조성물일 수 있고, 화장료 조성물은 메이크업용 화장료 조성물, 특히 파우더 또는 팩트일 수 있다.In the above aspects, the dust-proofing composition may be a cosmetic composition, and the cosmetic composition may be a cosmetic composition for make-up, particularly a powder or a powder.
본 명세서에서 "화장료"는, 미용 기능뿐만 아니라, 미용 기능 외에 추가적으로 의학적 기능을 가질 수 있는 모든 물질을 의미할 수 있다. As used herein, the term " cosmetic "may refer to any substance that, in addition to cosmetic functions, may have additional medical functions in addition to cosmetic functions.
구체적으로, 화장료 조성물로는 예를 들어, 기초 화장료, 메이크업 화장료, 모발용 화장료, 바디용 화장료 등이 있을 수 있고, 그 제형은 특별히 제한되지 않으며, 목적하는 바에 따라 적절히 선택할 수 있다. Specifically, the cosmetic composition may be, for example, a basic cosmetic composition, a makeup cosmetic composition, a hair cosmetic composition, a body cosmetic composition or the like, and the formulation is not particularly limited and may be appropriately selected according to the purpose.
예를 들면, 상기 화장료 조성물은 용액, 현탁액, 유탁액, 페이스트, 겔, 크림, 로션, 파우더, 비누, 계면활성제-함유 클린싱, 오일, 분말 파운데이션, 유탁액 파운데이션, 왁스 파운데이션 및 스프레이 등으로 제형화될 수 있으나, 이에 한정되는 것은 아니다. 보다 상세하게는, 유연화장수, 영양화장수, 로션, 바디로션, 영양 크림, 마사지 크림, 모이스처 크림, 핸드크림, 에센스, 아이 크림, 클렌징 크림, 클렌징 폼, 클렌징 워터, 팩, 젤, 패치, 수중유(O/W)형, 유중수(O/W)형 등의 기초 화장료, 립스틱, 메이크업베이스 또는 파운데이션 등의 색조 화장료, 샴푸, 린스, 바디클렌저, 치약 또는 구강 청정제 등의 세정료, 헤어토닉, 젤 또는 무스 등의 정발제, 양모제 또는 염모제 등의 모발용 화장료 조성물로 제형화 될 수 있다.For example, the cosmetic composition can be formulated into a solution, suspension, emulsion, paste, gel, cream, lotion, powder, soap, surfactant-containing cleansing, oil, powder foundation, emulsion foundation, wax foundation, But is not limited thereto. More specifically, the present invention relates to a cosmetic composition, which comprises at least one of a softening agent, a nutritional lotion, a lotion, a body lotion, a nutritional cream, a massage cream, a moisturizing cream, a hand cream, an essence, an eye cream, a cleansing cream, a cleansing foam, a cleansing water, Shampoos, rinses, body cleansers, toothpastes or mouthwashes, hair tonics, cosmetics, cosmetics, cosmetics, cosmetics, cosmetics, Gel or mousse, or a hair cosmetic composition such as a hair dye or a hair dye.
이하, 하기의 실시예를 통하여 본 발명을 보다 구체적으로 설명한다. 그러나 하기의 실시에는 본 발명에 대한 이해를 돕기 위해 예시의 목적으로만 제공된 것일 뿐, 본 발명의 범주 및 범위가 이에 한정되지 않는다.Hereinafter, the present invention will be described more specifically with reference to the following examples. However, the following embodiments are provided for illustrative purposes only in order to facilitate understanding of the present invention, and the scope and scope of the present invention are not limited thereto.
[실시예 1] 미세먼지와 황사 표준물질의 제타전위 분석 및 미세먼지 대체물질 선별[Example 1] Analysis of zeta potential of fine dust and yellow sand standards and selection of fine dust substitute
본 발명의 방진 효과 확인에 사용할 먼지 대체물질을 선별하기 위하여, 미세먼지와 황사, 먼지 대체물질 후보군의 제타전위를 분석하였다. 제타전위는 Zetasizer nano instrument(Malvern 사)를 이용하여 측정하였다. Zeta cell에 공기방울이 생기지 않도록 주사기를 이용하여, 콜로이드 상태 또는 에멀젼 상태의 시료를 가득 채우고, 마개로 zeta cell을 막은 후, zeta cell을 상기 Zetasizer nano instrument에 삽입하여, 제타전위를 측정하였다. In order to select the dust substitute material to be used in confirming the dustproof effect of the present invention, the zeta potential of the candidate group of fine dust, yellow dust, and dust substitute was analyzed. The zeta potential was measured using a Zetasizer nano instrument (Malvern). To avoid air bubbles in the Zeta cell, the zeta cell was inserted into the Zetasizer nano instrument, and the zeta potential was measured by filling the colloid or emulsion state with a syringe and closing the zeta cell with a plug.
그 결과는 하기 표 1과 같다. The results are shown in Table 1 below.

구분

division
Sample Sample Zeta Potential (mV)Zeta Potential (mV)
미세먼지fine dust 미세먼지 (한국외대)Fine dust (Hankuk University of Foreign Studies) -16.7-16.7
황사 (양재동)Yellow dust (Yangjae-dong) -21.2-21.2
유럽 표준물질 (Sigma Aldrich)European Standard Substance (Sigma Aldrich) -14.3-14.3
In vitro
test 샘플
In vitro
test sample
카본블랙 (LC902) Carbon black (LC902) -18.3-18.3
산화철 (Mapico)Iron oxide (Mapico) -0.1-0.1
숯가루Charcoal powder -29.0-29.0
*물질 옆 괄호에 기재된 것은 각 물질의 출처이다. * Substances listed in parentheses are sources of each substance.
미세먼지는 일반적으로 유기 탄소화합물 22%, 탄소원소 8%, 질산염 22%, 황산염 15%, 토양지각성분 15%, 기타 18%로 구성되어 있으므로(국립과학원), 본 발명에서는 미세먼지 구성 성분 중 약 30%(유기탄소 화합물 및 탄소원소)를 차지하며, 미세먼지와 유사한 제타전위를 갖는 카본블랙을 미세물질의 대체물질로 선별하였다.The fine dust is generally composed of 22% of organic carbon compounds, 8% of carbon element, 22% of nitrate, 15% of sulfate, 15% of soil perception component and 18% of other (National Academy of Sciences) Carbon black, which occupies about 30% (organic carbon compounds and carbon elements) and has zeta potential similar to that of fine dust, was selected as a substitute for the fine material.
[실시예 2] 방진 효과의 측정[Embodiment 2] Measurement of dustproof effect
[실시예 2-1] 피혁 실험[Example 2-1] Leather experiment
방진용 조성물에 사용될 후보 물질의 제타 전위 값은 하기 표 2에 기재된 바와 같다.The zeta potential values of the candidate materials to be used in the antivibration composition are as shown in Table 2 below.
구분division Sample Sample Zeta Potential (mV) Zeta Potential (mV)
(-) charge
후보물질
(-) charge
Candidate material
PMAA-나트륨 염(PMAA-Na Salt) (MW=75100) PMAA-sodium salt (PMAA-Na Salt) (MW = 75100) -34.9-34.9
PMAA-나트륨 염(PMAA-Na Salt) (MW=18500) PMAA-sodium salt (PMAA-Na Salt) (MW = 18500) -30.6-30.6
PMAA-나트륨 염(PMAA-Na Salt) (MW=7750) PMAA-sodium salt (PMAA-Na Salt) (MW = 7750) -24.6-24.6
PMAA-나트륨 염(PMAA-Na Salt) (MW=1270) PMAA-sodium salt (PMAA-Na Salt) (MW = 1270) -8.79-8.79
포스포리폰100®(Phospholipon 100 ®, Sigma Aldrich)Phospholipon 100 (R) (Sigma Aldrich) -17.9-17.9
MPC 표면처리된 이산화티타늄(MPC-TiO2 ) MPC Surface treated Titanium Dioxide (MPC-TiO 2 ) -10.7-10.7
PMAA-나트륨용액(PMAA-Na solution) PMAA-Na solution (PMAA-Na solution) -6.7-6.7
포스포리폰90(Phospholipon 90®, Sigma Aldrich) Phospholipon 90 (Sigma Aldrich) -6.46-6.46
포스포리폰75(Phospholipon 75®, Sigma Aldrich)Phospholipon 75 (Sigma Aldrich) -6.21-6.21
PMAA 표면처리된 이산화티타늄(PMAA-TiO2) PMAA surface treated titanium dioxide (PMAA-TiO 2 ) -2.65-2.65
(+) charge
후보물질
(+) charge
Candidate material
산화아연 (ZnO)Zinc oxide (ZnO) 2121
산화알루미늄(Aluminium oxide)Aluminum oxide 2929
키토산(Chitosan)Chitosan 4.94.9
상기 표 2에 기재된 후보 물질들을 표3에 기재된 제형예에 기재된 함량으로 각각 첨가하여, 방진용 화장료 조성물들을 제조하였다(1: 대조군, 2: PMAA-나트륨 염 (MW=75100) 함유, 3: PMAA-나트륨 염 (MW=18500) 함유, 4: PMAA-나트륨 염 (MW=7750) 함유, 5: 포스포리폰 100 함유, 6: MPC-TiO2 함유, 7: PMAA-나트륨 용액 함유, 8: 포스포리폰 90 함유, 9: 티타늄옥사이드(TiO2 (Titanium Oxide)) 함유, 10: PMAA-TiO2 함유, 11: 대조군, 12: ZnO 함유, 13: 산화알루미늄 함유, 14: 키토산 함유). 실험에 사용된 물질들 중 PMAA-나트륨 염(PMAA-Na Salt) (MW=75100), PMAA-나트륨 염(PMAA-Na Salt) (MW=18500), PMAA-나트륨 염(PMAA-Na Salt) (MW=7750), PMAA-나트륨 염(PMAA-Na Salt) (MW=1270), PMAA-나트륨용액(PMAA-Na solution, 434507 ALDRICH), 포스포리폰100®(Phospholipon 100 ®), 포스포리폰90(Phospholipon 90®) 및 포스포리폰75(Phospholipon 75®)은 Sigma Aldrich로부터 입수하였다. 또한, MPC-TiO2와PMAA-TiO2는, -OH 작용기를 갖는 TiO2 표면에 커플링제를 반응시킨 후, MPC 고분자와 PMAA 고분자 각각을 0.1~10wt% 로 코팅(더욱 상세하게는 3wt%)한 후, 여과 및 분쇄하여 제조하였다. (1: control, 2: PMAA-sodium salt (MW = 75100) containing 3: PMAA 5: containing phospholipone 100, 6: containing MPC-TiO 2 , 7: containing PMAA-sodium solution, 8: containing sodium salt (MW = 18500), 4: containing PMAA-sodium salt Poly phone 90 containing, 9: titanium oxide (TiO 2 (titanium oxide)) containing, 10: PMAA-containing TiO 2, 11: control group, 12: chitosan-containing): ZnO-containing, 13: an aluminum-containing, oxide 14. PMAA-Na salt (MW = 75100), PMAA-Na salt (MW = 18500) and PMAA-Na salt (PMAA-Na salt) MW = 7750), PMAA-Na salt (MW = 1270), PMAA-Na solution (434507 ALDRICH), Phospholipon 100®, Phospholipone 90 (Phospholipon 90®) and Phospholipon 75® were obtained from Sigma Aldrich. In MPC-TiO 2 and PMAA-TiO 2 , a coupling agent is reacted with a surface of TiO 2 having an -OH functional group, and 0.1 to 10 wt% of each of MPC polymer and PMAA polymer is coated (more specifically, 3 wt% , Followed by filtration and pulverization.
이들 각각의 조성물을 각각의 인공 피혁들에 고르게 도포하고, 10분간 건조 시킨 후, 카본블랙 3.125g(이는, 한국 기상철의 미세먼지 경보 수준의 500000배 수준이다)이 들어 있는 대류박스에 넣고, 대류박스 내의 공기를 대류순환장치로 충분히 대류 시켜준 후, 인공 피혁 상에 남아 있는 카본블랙을 육안으로 확인하였다. 그 결과, 제타전위의 음전하 절대값이 가장 큰 PMAA-나트륨 염(mw=75100)을 포함하는 화장료 조성물을 도포한 피혁에서 카본블랙이 가장 적게 검출되었고, PMAA-나트륨 염(mw=75100), PMAA-나트륨 염(mw=18500), PMAA-나트륨 염(mw=7750), PMAA-나트륨 염 용액 및 포스포리폰 100(Phospholipon 100®)가 방진 효과가 있음을 알 수 있었다(도 1). Each of these compositions was evenly applied to each of the artificial leathers and was dried for 10 minutes and then placed in a convection box containing 3.125 g of carbon black (which is 500,000 times the level of the fine dust alarm of Korean vapor iron) After sufficiently convecting the air in the convection box with the convection circulation device, the carbon black remaining on the artificial leather was visually confirmed. As a result, it was found that the carbon black was least detected in the leather to which the cosmetic composition containing the PMAA-sodium salt (mw = 75100) having the largest absolute negative charge of zeta potential was applied, and PMAA-sodium salt (mw = 75100), PMAA Sodium salt (mw = 18500), PMAA-sodium salt (mw = 7750), PMAA-sodium salt solution and Phospholipon 100® were found to have a dust-proofing effect.
[실시예 2-2] 인공모발 실험[Example 2-2] Artificial hair test
상기 표 2에 기재된 후보 물질들을 표6에 기재된 제형예에 기재된 함량으로 각각 첨가하여 헤어 미스트를 제조하였다(blank: 대조군, 샘플1: PMAA-나트륨 염(mw=75100) 함유, 샘플 2: PMAA-나트륨 염(mw=18500) 함유, 샘플 3: 포스포리폰 100 함유, 샘플 4: MPC 표면처리된 이산화티타늄(MPC-TiO2) 함유, 샘플 5: PMAA-나트륨 함유, 샘플 6: PMAA 표면처리된 이산화티타늄(PMAA-TiO2)). 헤어 미스트를 동일한 모발 샘플들에 각각 분무하고, 실시예 2-1과 동일한 조건으로, 대류 박스에서 카본블랙 처리한 후, 모발의 질량을 측정하였다. 제타전위 음전하의 절대값이 클수록 모발의 질량 증가폭이 작았고, 제타전위 음전하의 절대값 크기가 클수록 방진효과가 우수함을 알 수 있었다.(Blank: control group, sample 1: PMAA-sodium salt (mw = 75100), sample 2: PMAA- (MPC-TiO2), Sample 5 contains PMAA-sodium, Sample 6 contains PMAA-treated sodium dioxide (mw = 18500), Sample 3 contains phospholipone 100, Sample 4 contains MPC- Titanium (PMAA-TiO2). The hair mists were sprayed on each of the same hair samples, treated with carbon black in a convection box under the same conditions as in Example 2-1, and the mass of the hair was measured. The larger the absolute value of the zeta potential negative charge, the smaller the increase in the mass of hair, and the larger the magnitude of the zeta potential negative charge, the better the dust protection effect.
이하, 본 발명에 따른 조성물의 제형 예를 설명하나, 약학 조성물 및 화장료 조성물은 여러 가지 제형으로 응용 가능하며, 이는 본 발명을 한정하고자 함이 아닌 단지 구체적으로 설명하고자 함이다.Hereinafter, a formulation example of the composition according to the present invention will be described. However, the pharmaceutical composition and the cosmetic composition can be applied to various formulations, which are not intended to limit the present invention but merely to illustrate the present invention.
유연화장수(스킨로션)Flexible longevity (skin lotion)
배합성분Compounding ingredient 중량%weight%
정제수Purified water 잔량Balance
음전하 물질Negative charge substance 10.010.0
에틸렌다이마민테트라아세틱산Ethyleniminametetraacetic acid 0.020.02
글리세린glycerin 5.05.0
부틸렌 글리콜Butylene glycol 3.03.0
피이지/피피지-17/6코폴리머(공중합체)Pigment / PPGI-17/6 Copolymer (Copolymer) 3.03.0
에탄올ethanol 5.05.0
폴리옥시에틸렌하이드로제네이티드
캐스터오일
Polyoxyethylene hydrogencarbonate
Castor oil
0.40.4
메틸파라벤Methyl paraben 0.10.1
방향제(fragrance)Fragrance 0.10.1
방부제, 색소, 향료Preservative, coloring, fragrance 적량Suitable amount
유연화장수(밀크로션)Flexible longevity (milk lotion)
배합성분Compounding ingredient 함량content
정제수Purified water 잔량Balance
음전하물질Negative charge substance 10.010.0
밀납Wax 4.04.0
폴리솔베이트60Polysorbate 60 1.51.5
솔비탄세스퀴올레이트Sorbitan sesquioleate 1.51.5
유동파라핀Liquid paraffin 0.50.5
카프릴릭/카프릭트리글리세라이드Caprylic / capric triglyceride 5.05.0
글리세린glycerin 3.03.0
부틸렌글리콜Butylene glycol 3.03.0
프로필렌글리콜Propylene glycol 3.03.0
카르복시비닐폴리머Carboxyvinyl polymer 0.10.1
트리에탄올아민Triethanolamine 0.20.2
방부제, 색소, 향료Preservative, coloring, fragrance 적량Suitable amount
파우더 또는 팩트 화장료Powder or fact cosmetic
배합성분Compounding ingredient 중량%weight%
음전하물질Negative charge substance 10.010.0
나일론 파우더Nylon Powder 5.05.0
모디파이드 전분Modified starch 3.03.0
이산화티탄Titanium dioxide 3.03.0
마이카Mica 25.025.0
스쿠알렌Squalene 0.50.5
디메치콘Dimethicone 0.80.8
방부제, 색소, 향료Preservative, coloring, fragrance 적량Suitable amount
실리콘처리 탈크Silicone-treated talc to 100to 100
헤어미스트Hair Mist
배합성분Compounding ingredient 함량content
정제수Purified water TO 100TO 100
음전하물질Negative charge substance 1010
글리세린glycerin 5.05.0
부틸렌글라이콜Butylene glycol 5.05.0
페녹시에탄올Phenoxyethanol 0.50.5
PEG/PPG 블록 코폴리머PEG / PPG block copolymer 1.51.5
염화나트륨Sodium chloride 0.30.3
에탄올ethanol 3.03.0
디메치콘Dimethicone 10.010.0
* 상기 헤어 미스트는 유화 공정 없이 균질기를 이용하여 제조하였다.The hair mists were prepared using homogenizer without emulsification process.
영양크림Nourishing cream
배합성분Compounding ingredient 함량content
정제수Purified water 잔량Balance
음전하물질Negative charge substance 5.05.0
밀납Wax 10.010.0
폴리솔베이트60Polysorbate 60 1.51.5
PEG60 경화피마자유PEG60 hardened castor oil 2.02.0
솔비탄세스퀴올레이트Sorbitan sesquioleate 0.50.5
유동파라핀Liquid paraffin 10.010.0
스쿠알란Squalane 5.05.0
카프릴릭/카프릭트리글리세라이드Caprylic / capric triglyceride 5.05.0
글리세린glycerin 5.05.0
푸틸렌글리콜Butylene glycol 3.03.0
프로필렌글리콜Propylene glycol 3.03.0
트리에탄올아민Triethanolamine 0.20.2
방부제, 색소, 향료Preservative, coloring, fragrance 적량Suitable amount

Claims (14)

  1. pH7의 수용액에서의 제타전위 값이 -2mV 이하인 음전하 물질을 유효성분으로 포함하고,
    상기 음전하 물질은, 고분자 또는 무기물인 방진용 조성물.
    a negative charge substance having a zeta potential value of -2 mV or lower in an aqueous solution of pH 7 as an active ingredient,
    Wherein the negative charge material is a polymer or an inorganic material.
  2. 제1항에 있어서,
    상기 음전하 물질은,
    pH 7의 수용액에서의 제타전위 값이 -10mV 이하인, 방진용 조성물.
    The method according to claim 1,
    The negative charge material,
    wherein the zeta potential value in an aqueous solution of pH 7 is not more than -10 mV.
  3. 제2항에 있어서,
    상기 음전하 물질은,
    pH7의 수용액에서의 제타전위 값이 -50mV 내지 -10mV인, 방진용 조성물.
    3. The method of claim 2,
    The negative charge material,
    wherein the zeta potential value in an aqueous solution of pH 7 is from -50 mV to -10 mV.
  4. 제1항에 있어서,
    상기 고분자는,
    포스포리피드(phospholipid) 또는 폴리(메스아크릴레이트)(poly(methacrylate))인, 방진용 조성물.
    The method according to claim 1,
    The polymer may be,
    Wherein the composition is a phospholipid or poly (methacrylate).
  5. 제1항에 있어서,
    상기 무기물은,
    이산화규소(SiO2) 또는 이산화티타늄(TiO2)인, 방진용 조성물.
    The method according to claim 1,
    The above-
    Silicon dioxide (SiO 2) or titanium dioxide (TiO 2) in the composition for anti-vibration.
  6. 제4항에 있어서,
    상기 포스포리피드는,
    포스파티딜글리세롤(phosphatidylglycerol), 포스파티딜에탄올아민 (phosphatidylethanolamine), 포스파티딜세린(phosphatidylserine), 폴리에틸렌글리콜 포스포리피드(polyethyleneglycol phospholipid), 스핑고미엘린(sphingomyelin) 및 포스파티딜콜린(phosphatidylcholine)으로 구성되는 군으로부터 선택되는, 방진용 조성물.
    5. The method of claim 4,
    The phospholipid,
    Wherein the composition is selected from the group consisting of phosphatidylglycerol, phosphatidylethanolamine, phosphatidylserine, polyethyleneglycol phospholipid, sphingomyelin and phosphatidylcholine. Composition.
  7. 제6항에 있어서,
    상기 포스파티딜콜린은,
    하이드로제네이티드 포스파티딜콜린(hydrogenated phophatidylcholine)을 포함하는, 방진용 조성물.
    The method according to claim 6,
    The phosphatidylcholine,
    A composition for preventing dust, comprising hydrogenated phophatidylcholine.
  8. 제4항에 있어서,
    폴리(메스아크릴레이트)는, 폴리(메스아크릴 산) 나트륨 염(Poly(methacrylic acid) sodium salt)을 포함하는, 방진용 조성물.
    5. The method of claim 4,
    Wherein the poly (methacrylate) comprises a poly (methacrylic acid) sodium salt.
  9. 제1항에 있어서,
    상기 무기물은,
    2-메타크릴로일옥시에틸 포스포릴콜린(2-(methacryloyloxy)ethyl phosphorylcholine, MPC) 또는 폴리(메스아크릴 산)(Poly(methacrylic acid))으로 표면처리된, 방진용 조성물.
    The method according to claim 1,
    The above-
    Wherein the composition is surface-treated with 2-methacryloyloxy ethyl phosphorylcholine (MPC) or poly (methacrylic acid).
  10. 제1항에 있어서,
    음전하 물질은,
    조성물 총 중량을 기준으로, 1 내지 50 중량%로 포함되는, 방진용 조성물.
    The method according to claim 1,
    Negative charge substances,
    1 to 50% by weight, based on the total weight of the composition.
  11. 제1항에 있어서,
    상기 조성물은,
    입경이 10㎛이하인 미세먼지를 방진하는 것인, 방진용 조성물.
    The method according to claim 1,
    The composition may comprise,
    Wherein the fine dust having a particle diameter of 10 mu m or less is dustproofed.
  12. 제1항 내지 제11항 중 어느 한 항에 있어서,
    상기 방진용 조성물은, 화장료 조성물인, 조성물.
    12. The method according to any one of claims 1 to 11,
    Wherein the composition for vibration damping is a cosmetic composition.
  13. 제12항에 있어서,
    화장료 조성물은, 메이크업용 조성물인, 화장료 조성물.
    13. The method of claim 12,
    The cosmetic composition is a makeup composition.
  14. 제13항에 있어서,
    메이크업용 조성물은, 파우더 또는 팩트인, 화장료 조성물.
    14. The method of claim 13,
    The makeup composition is a powder or a cosmetic composition.
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KR20170106579A (en) * 2016-03-11 2017-09-21 코스맥스 주식회사 Anti-dust cosmetic composition
KR20190045684A (en) * 2017-10-24 2019-05-03 (주)아모레퍼시픽 Composition for anti-fine dust
WO2019083181A3 (en) * 2017-10-24 2019-06-20 (주)아모레퍼시픽 Composition for protection against fine dust
KR20200019561A (en) * 2018-08-14 2020-02-24 주식회사 코스메카코리아 cosmetic composition for preventing adhesion of particulated matter
KR20200074444A (en) 2018-12-17 2020-06-25 한국세라믹기술원 Preparation method for cosmetic composition comprising surface modified TiO2 and ZnO for cleaning particulate matter
KR102127053B1 (en) 2018-12-17 2020-06-25 한국세라믹기술원 Preparation method for cosmetic composition comprising surface modified TiO2 and ZnO for blocking particulate matter

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