KR20160097592A - Eco-friendly deodorant composition - Google Patents

Eco-friendly deodorant composition Download PDF

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Publication number
KR20160097592A
KR20160097592A KR1020150019461A KR20150019461A KR20160097592A KR 20160097592 A KR20160097592 A KR 20160097592A KR 1020150019461 A KR1020150019461 A KR 1020150019461A KR 20150019461 A KR20150019461 A KR 20150019461A KR 20160097592 A KR20160097592 A KR 20160097592A
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Prior art keywords
oil
present
ammonia
weight
deodorant composition
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KR1020150019461A
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Korean (ko)
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한상길
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한상길
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Priority to KR1020150019461A priority Critical patent/KR20160097592A/en
Priority to PCT/KR2016/001304 priority patent/WO2016129893A1/en
Publication of KR20160097592A publication Critical patent/KR20160097592A/en

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
    • A61L9/12—Apparatus, e.g. holders, therefor
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Botany (AREA)
  • Zoology (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The present invention relates to an environmentally-friendly deodorant composition mixed with oil having a formaldehyde deodorizing rate and oil having an ammonia deodorizing rate at a weight ratio of 10-45:55-90. The deodorant composition according to the present invention is made of only natural oil usually used in flavoring agents, so the deodorant composition is not harmful to the human body and can effectively remove formaldehyde and ammonia smells. Moreover, the deodorant composition according to the present invention includes only natural refined oil, so not only a deodorizing effect but also a fragrant effect can be obtained and thus a dual effect can be ensured. Accordingly, the deodorant composition according to the present invention can be applied in various types by using spray, dispenser, aerosol, or gel types.

Description

[0001] The present invention relates to an eco-friendly deodorant composition for removing formaldehyde and ammonia,

The present invention relates to an environmentally friendly deodorant composition effective to remove formaldehyde and ammonia.

Sick house syndrome is caused by volatile organic compounds. Among them, formaldehyde is a typical causative substance, and formaldehyde is a colorless gas with irritating odor and has a characteristic of being soluble in water. Preservatives and adhesives used mainly in construction and furniture, spray paints for interior decoration are a major problem, and a new house using formaldehyde-containing building materials has a problem of releasing formaldehyde into the room for many years .

In addition, sulfur odor, ammonia odor, xylene, toluene, benzene, etc. are exposed unprotected. Among them, when dyeing due to the smell of ammonia in the dye, many cases of side effects such as eye strain or itching under the head are increasing.

There are physical, chemical, biological, and sensory methods to remove odors in the room, but the deodorizers that have been commercially available do not show the effect. In addition, since most deodorants contain artificial organic chemicals, they can cause other problems even if they are harmful to the human body and have a deodorizing effect.

Korean Patent Laid-Open Publication No. 2013-0109444 discloses a deodorant composition comprising an essential oil derived from plants as an active ingredient. Specifically, it comprises 0.2 to 20% by weight of essential oil derived from mint or corn oil, based on the total weight of the composition, Ammonia, and methyl mercaptan from the exhaust gas.

However, it is still necessary to develop an environmentally friendly deodorant while effectively removing odors such as formaldehyde and ammonia.

Korean Patent Publication No. 2013-0109444

 The object of the present invention is to solve the various problems of conventional deodorant products in the present invention, and it is an object of the present invention to provide an eco-friendly deodorant capable of effectively removing the two odors by selectively mixing materials having excellent deodorization effect with formaldehyde and ammonia Compositions.

The eco-friendly deodorant composition according to the present invention is characterized in that an oil having a formaldehyde deodorization ratio and an oil having an ammonia deodorization ratio are mixed at a weight ratio of 10 to 45: 55 to 90.

The oil having the formaldehyde deodorization rate may be composed of 50 to 75% by weight of eucalyptus oil and 25 to 50% by weight of hyssop oil.

The oil having the ammonia deodorization ratio may be selected from the group consisting of 5 to 40 wt% of olibanum oil, 5 to 15 wt% of lemongrass oil, 5 to 15 wt% of geranium oil, 1 to 30 wt% of lemon oil, And 5 to 45% by weight of lime oil.

The oil having an ammonia deodorization rate may further contain 1 to 15% by weight of orange oil.

The composition may be used either as a spray, a dispenser, an aerosol or a gel.

The composition may further comprise a natural directional component.

The directional component may be 0.01 to 100% by weight based on the total weight of the deodorant composition.

The deodorant composition according to the present invention is harmless to the human body and can effectively remove the formaldehyde and ammonia odor because the deodorant composition according to the present invention is composed only of natural oils commonly used in fragrance.

In addition, since the deodorant composition according to the present invention contains only natural essential oil, it has an advantage of being able to achieve a deodorizing effect as well as a directional effect, thereby achieving the effect of a pudding.

Accordingly, the deodorant composition according to the present invention can be applied in various forms using a spray, a dispenser, an aerosol, a gel or the like.

Hereinafter, the present invention will be described in more detail.

The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms "a," "an," and "the" include singular forms unless the context clearly dictates otherwise. Also, " comprise "and / or" comprising "when used herein should be interpreted as specifying the presence of stated shapes, numbers, steps, operations, elements, elements, and / And does not preclude the presence or addition of one or more other features, integers, operations, elements, elements, and / or groups.

The present invention relates to an environmentally friendly deodorant composition capable of effectively removing noxious gases such as formaldehyde and ammonia by using essential oil.

The eco-friendly deodorant composition according to the present invention is characterized in that an oil having a formaldehyde deodorization ratio and an oil having an ammonia deodorization ratio are mixed at a weight ratio of 10 to 45: 55 to 90.

In the present invention, a long study has been conducted on eco-friendly materials capable of effectively removing formaldehyde and ammonia, which are the most problematic volatile organic compounds in modern life.

As a result, an environmentally friendly deodorant composition capable of effectively removing both formaldehyde and ammonia was obtained as a result of using natural oils having excellent deodorization rate with respect to formaldehyde and natural oils having excellent deodorization rates with respect to ammonia at an optimum ratio .

In the present invention, the oil having a formaldehyde deodorization ratio is characterized by comprising 50 to 75% by weight of eucalyptus oil and 25 to 50% by weight of hyssop oil.

The Eucalyptus oil is a volatile aromatic oil that can be obtained from many species, especially in the leaf glands of Eucalyptus salicifolia and E. globulus . In the present invention, the oil extracted using the steam distillation extraction method may be used for the eucalyptus oil, or a commercially available oil (specific gravity 0.915 0.01, refractive index 1.464 0.01) may be used.

The eucalyptus oil was measured to have an excellent deodorizing effect on formaldehyde showing a deodorization rate of 100% up to 60 minutes.

Hyssop oil having a formaldehyde deodorization rate of the present invention is a sweet, spicy, bitter taste material. Also, the oil contained in the hyssop leaves is used as the deodorant composition of the present invention. In the present invention, the oil extracted using the steam distillation extraction method may be used in the present invention, or a commercially available oil (specific gravity 0.934 0.01, refractive index 1.480 0.01) may be used.

The hysos oil was also measured to have an excellent deodorizing effect on formaldehyde showing a deodorization rate of 100% up to 60 minutes.

In the deodorant composition of the present invention, the oil having a deodorization rate of formaldehyde is preferably composed of 50 to 70% by weight of eucalyptus oil and 25 to 50% by weight of hyssop oil in order to exhibit the highest formaldehyde deodorization rate.

In addition, the oil having the ammonia deodorization ratio contained in the deodorant composition of the present invention may contain 5 to 40% by weight of olibanum oil, 5 to 15% by weight of lemongrass oil, 5 to 15% by weight of geranium oil %, Lemon oil 1 to 30 wt%, and lime oil 5 to 45 wt%.

The oil (Olibanum oil) contained in the oil having the ammonia deodorization ratio of the present invention is obtained by extracting from oriental wood. Fruity flavor is a cool, long-lasting aroma that calms your emotions and helps to stabilize your breathing. In the present invention, the oil extracted with the steam distillation extraction method may be used as the oil or the commercially available oil (specific gravity 0.867 0.01, refractive index 1.471 0.01) may be used.

The oil having an ammonia deodorization ratio of 5 to 40% by weight is preferred from the viewpoint of constitution of a perfume which enhances durability.

Lemongrass oil contained in the oil having an ammonia deodorization ratio of the present invention is a kind of tea which has a digestion promoting function and suits well after a meal. In the present invention, the lemon grass oil may be extracted using steam distillation extraction method, or a commercially available oil (specific gravity 0.885 0.01, refractive index 1.486 0.01) may be used in the present invention.

The lemon grass oil in the oil having an ammonia deodorization rate is preferably contained in an amount of 5 to 15% by weight from the viewpoint of increasing the strength of the perfume.

The geranium oil contained in the oil having the ammonia deodorization ratio of the present invention is a plant having fragrance such as peppermint, fruit fragrance, floral fragrance, spice fragrance when the leaves are rubbed or crushed. In some African species belonging to the genus Pelargonium, geranium oil is extracted and used. Geranium oil, also known as Pelagonium Oil or Rose Geranium Oil, is colorless to light yellow or greenish, with a rose-like appearance. In the present invention, the oil extracted from the geranium oil by the steam distillation method or a commercially available oil (specific gravity 0.887 0.01, refractive index 1.465 0.01) may be used. The geranium oil in the oil having an ammonia deodorization rate is preferably contained in an amount of 5 to 15% by weight in terms of reinforcing the fragrance middle note.

Also, the lemon oil contained in the oil having the ammonia deodorization ratio of the present invention is a volatile oil obtained from the fruit of lemon ( Citrus limon ). Lemon is a fruit containing a large amount of vitamins A, B and vitamin C. The lemon oil is effective for emotional stability, and it is said that it helps the vitality of the skin to maintain, mood, and vitality of life. In particular, lemon oil has the effect of exterminating bacteria and bacteria and can be applied as an air clean spray. It also has the effect of lowering the heat of people and improving concentration and memory.

In the present invention, the oil extracted from the lemon oil by the pressing method or a commercially available oil (specific gravity 0.855 0.01, refractive index 1,475 0.01) may be used. The lemon oil in the oil having an ammonia deodorization rate is preferably contained in an amount of 1 to 30% by weight in view of enhancing a top note of a fragrance giving a fresh feeling.

The Lime oil contained in the oil having the ammonia deodorization ratio of the present invention is an oil component obtained from the fruit of the lime tree. Lime oil has a sweet and fresh citrus scent. Vitamin C, which is rich in lime, acts as a bright and luminous skin tone. The lime oil is included in the deodorant composition of the present invention and plays an important role not only in the ammonia deodorant but also in the restoration of exhausted mind and body and relieves fatigue, apathy and anxiety, thereby providing psychological vitality and enhancing appetite .

In the present invention, the lime oil may be extracted using a compression method, or a commercially available oil (specific gravity 0.869 ± 0.01, refractive index 1.480 ± 0.01) may be used. The lime oil in the oil having an ammonia deodorization rate is preferably contained in an amount of 5 to 45% by weight in terms of softening the fragrance.

In addition, the oil having an ammonia deodorization ratio according to the present invention may further include 1 to 15% by weight of orange oil.

The deodorant composition according to the present invention preferably mixes an oil having a deodorization ratio with formaldehyde and an oil having an ammonia deodorization ratio at a weight ratio of 10: 45: 55 to 90, The deodorization rate for ammonia is excellent.

The deodorant composition according to the present invention may be used either as a spray, dispenser, aerosol or gel.

The application of the deodorant composition may be performed by spraying, spraying, rubbing, or dipping a solid, gel or liquid material of the deodorant composition of the present invention in a specific site or place where formaldehyde and ammonia odor are present, Or location.

In addition, the deodorant composition according to the present invention can be used as a household cleaning product, a shoe box, a sprayer, a sheet in a shoe, a garbage spray, an air purifier and an air conditioner filter, a deodorant, an air blower and an air blower, a deodorant for a refrigerator, And deodorant for carpets, deodorant for room or car, deodorant for bathroom, deodorant for textile, clothing (underwear and socks), deodorant for car seat, deodorant fiber, waste deodorant and various other deodorants.

Further, the composition according to the present invention may further include a natural direction component to add a desired fragrance. The directional component is not particularly limited and may be a directional component extracted from a natural herb, fruit, flower or the like in a range that does not impair the deodorizing effect contained in the deodorant composition of the present invention. %. ≪ / RTI >

Hereinafter, preferred embodiments of the present invention will be described in detail. The following examples are intended to illustrate the present invention, but the scope of the present invention should not be construed as being limited by these examples. In the following examples, specific compounds are exemplified. However, it is apparent to those skilled in the art that equivalents of these compounds can be used in similar amounts.

Experimental Example  1: Of the major natural oils Deodorizing force  Test

In this experiment, two reagents, formaldehyde (40%, duksan korea) and ammonia (25%, wake japan) were diluted with distilled water and used at each concentration. Formaldehyde detection tubes (NO91, gastec, japan) and ammonia detection tubes (NO3La, gastec, japan) were used.

The deodorization test of each natural oil was carried out in the following steps by applying a gas detection tube method using the standard test method of ASTM (American Society for Testing Materials) D1988-06 for odor of formaldehyde and ammonia.

1) Test method

① Prepare a 5-pyrex flask with a sealable capacity of 1 L by drilling a hole in the lid so that the detector tube can be inserted and removed.

② The odor solution diluted to an appropriate concentration is injected into the hole of the flask by using a pipette to generate an odor artificially at room temperature.

(3) Use a stirring bar so that odorous substances can be sufficiently volatilized in the flask. 30 minutes after the generation of the odor, the initial concentration (blank) is measured by inserting a detector tube for detecting the odor into the gas detector, and setting each flask to a constant concentration.

④ Spray 1 ml of essential oil prepared in 5 flasks with a constant initial concentration using a syringe. Measure the residual gas concentration of the odor in five flasks using a gas detector at intervals of 30 minutes to 150 minutes.

⑤ All experiments were repeated three times and the measured values were compared and the deodorization rate was calculated.

2) Deodorization  Calculation

Deodorization rate (%) = {(blank concentration - sample gas concentration) / blank concentration} x 100

The natural oils used in the deodorization test are shown in Table 1 below.

Oil type VOC Deodorization rate (%) 30 minutes 60 minutes 90 minutes 120 minutes 150 minutes Orange HCHO 30.6 31.9 38.8 37.5 38.3 NH 3 79.7 83.8 85.9 88.2 89.7 Lemon HCHO 54.2 60.0 64.2 65.4 65.6 NH 3 56.8 88.9 89.4 90.2 90.3 Lemon grass HCHO 45.1 45.1 47.1 51.9 45.1 NH 3 100 100 100 100 100 Geranium HCHO 76.5 76.5 75.0 75.0 75.0 NH 3 100 100 100 100 100 Hyssop HCHO 100 100 100 NH 3 100 100 Eucalyptus HCHO 100 100 NH 3 (+) 0 Olibanum HCHO (+) NH 3 100 100 Lime HCHO (+) NH 3 58,3 100

In the present invention, a natural oil having a deodorization ratio of 80% or more at 60 minutes with respect to formaldehyde and ammonia was used as the deodorant composition of the present invention, based on the deodorization test results of Table 1 above.

Example  1 to 3, Comparative Example  One

The composition shown in Table 2 below was mixed to prepare a deodorant composition.

Content: wt% Example 1 Example 2 Example 3 Comparative Example 1 Oil with formaldehyde deodorization rate (A) Eucalyptus oil (1) 10 20 7.5 4 Hyssop oil (2) 10 15 7.5 One

The oil (B) having an ammonia deodorization ratio Olive oil (3) 24 15 5 37 Lemongrass oil (4) 8 8 5 10 Lemon oil (5) 20 5 25 4 Lime oil (6) 20 19 25 36 Geranium oil (7) 8 8 5 4  Orange oil - 10 20 4 A / B weight ratio 20:80 35:65 15:85 5:95 (1) Specific gravity: 0.915 ± 0.01; refractive index: 1.464 ± 0.01.
(2) The specific gravity is 0.934 ± 0.01, and the refractive index is 1.480 ± 0.01.
(3) The specific gravity is 0.867 ± 0.01, and the refractive index is 1.471 ± 0.01.
(4) Specific gravity 0.885 0.01, refractive index 1.486 0.01.
(5) Specific gravity 0.887 ± 0.01, refractive index 1.465 ± 0.01.
(6) The specific gravity is 0.855 ± 0.01, and the refractive index is 1,475 ± 0.01.
(7) Specific gravity: 0.869 ± 0.01, refractive index: 1.480 ± 0.01.

Experimental Example  2: Deodorization rate  Test

The deodorization rates of the deodorant compositions according to Examples 1 to 3 and Comparative Example 1 were measured in the same manner as in Experimental Example 1. The results are shown in Table 3 below.

sample VOC Deodorization rate by time (%) 5 minutes 10 minutes 30 minutes 60 minutes Example 1 HCHO 88.0 100 100 100 NH 3 94.3 100 100 100 Example 2 HCHO 93.6 100 100 100 NH 3 89.8 100 100 100 Example 3 HCHO 89.2 100 100 100 NH 3 90.5 100 100 100 Comparative Example 1 HCHO 48.6 71.0 72.5 75.3 NH 3 50.5 75.0 78 79

Referring to the results of Table 3 above, it can be seen that an oil having a formaldehyde deodorization ratio of 50 to 75% by weight of eucalyptus oil and 25 to 50% by weight of hyssop oil and 5 to 40% by weight of olibanum oil, An oil having an ammonia deodorization ratio of 5 to 15% by weight of Lemongrass oil, 5 to 15% by weight of geranium oil, 1 to 30% by weight of lemon oil and 5 to 45% by weight of lime oil is mixed with 10 ~ 45: 55 ~ 90 weight ratio showed a superior deodorizing effect compared to the deodorant of Comparative Example which exceeded this content range.

The present deodorizers have excellent deodorizing effect of 80 ~ 90% in the 30 minute deodorization test. However, the deodorants of the present invention exhibit excellent deodorizing effect which is 100% deodorant in 10 minutes in both formaldehyde and ammonia.

In addition, when the content of lemon oil, lime oil, orange oil, etc. is increased as in Example 3, the odor effect as well as the fragrance preference can be improved.

Claims (7)

Wherein an oil having a formaldehyde deodorization ratio and an oil having an ammonia deodorization ratio are mixed at a weight ratio of 10:45:55 to 90:10.
The method according to claim 1,
Wherein the oil having a deodorization ratio of formaldehyde is composed of 50 to 75% by weight of eucalyptus oil and 25 to 50% by weight of hyssop oil.
The method according to claim 1,
The oil having the ammonia deodorant oil may be selected from the group consisting of 5 to 40 wt% of olibanum oil, 5 to 15 wt% of lemongrass oil, 5 to 15 wt% of geranium oil, 1 to 30 wt% of lemon oil, And 5 to 45% by weight of lime oil.
The method according to claim 1,
Wherein the oil having an ammonia deodorization rate further comprises 1 to 15% by weight of an orange oil.
The method according to claim 1,
Wherein the composition is used in any one of the following spray, dispenser, aerosol or gel processes.
The method according to claim 1,
Wherein the composition further comprises a natural direction component.
The method according to claim 6,
Wherein the natural direction component is contained in an amount of 0.01 to 100% by weight based on the total weight of the deodorant composition.

KR1020150019461A 2015-02-09 2015-02-09 Eco-friendly deodorant composition KR20160097592A (en)

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PCT/KR2016/001304 WO2016129893A1 (en) 2015-02-09 2016-02-05 Environmentally friendly deodorant composition for removing formaldehyde and ammonia

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180078841A (en) * 2016-12-30 2018-07-10 (주) 크리니트 Method of making formaldehyde remover using natural material

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US20130109444A1 (en) 2010-07-30 2013-05-02 Huizhou Tcl Mobile Communication Co., Ltd. Mobile Terminal

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JPH09103473A (en) * 1995-10-11 1997-04-22 Sanei Kagaku Kk Deodorant composition
JP2003190264A (en) * 2001-12-25 2003-07-08 Kiyomitsu Kawasaki Aromatic deodorizing composition for environment and aromatic deodorizer for environment containing the aromatic deodorizing composition for environment
KR20030093612A (en) * 2002-06-03 2003-12-11 김대승 Liquid type compositions for antimicrobial and deodorization
JP4336272B2 (en) * 2004-08-19 2009-09-30 株式会社ロッテ Tobacco odor deodorant, food and drink containing the same, deodorant composition, production method and use thereof
KR20110107513A (en) * 2010-03-25 2011-10-04 김오겸 An antobiotic deodorant using refined oil and manufacturing process of an antobiotic deodorant using this

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
US20130109444A1 (en) 2010-07-30 2013-05-02 Huizhou Tcl Mobile Communication Co., Ltd. Mobile Terminal

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180078841A (en) * 2016-12-30 2018-07-10 (주) 크리니트 Method of making formaldehyde remover using natural material

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