JP5241905B2 - Deodorant formulated with an efficacy enhancer for organic deodorant ingredients - Google Patents

Description

The present invention relates to a deodorant containing an efficacy enhancer of an organic deodorant component comprising green leaf alcohol.

  Conventionally, various types of deodorants are used. For example, as a deodorant, those using inorganic materials such as activated carbon, zeolite, photocatalytic titanium oxide and silver ions, those derived from plants such as polyphenol, phytoncide, catechin, hinokitiol, or an air cleaner using ozone Etc. are known.

By the way, green leaf alcohol and green leaf aldehyde are components of fragrance called “green fragrance” that are diffused from the leaves and have been widely used as a kind of aromatic component. It has been attracting attention because it has been proved that the fragrance ingredients have a mental effect such as stress reduction, recovery from fatigue, and further enhancement of concentration.
As for green leaf alcohol and green leaf aldehyde, for example, the attractive effect enhancer of Doganebuibui attractant (see Japanese Patent No. 3085894), the repellent effect enhancer of dog, cat and avian repellent composition (Japanese Patent Publication No. 57) No. -25521 (see Japanese Patent Publication No. -25521), or a use example of "Wasabi Flavor" as a modifier (see Japanese Patent No. 3553283).
As described above, there are several documents related to the action and effect of green leaf alcohol and green leaf aldehyde, but there is still no document describing the combination of the deodorant component and the enhancement effect of the deodorant effect.

Japanese Patent No. 3085894 Japanese Patent Publication No.57-25521 Japanese Patent No. 3553283

An object of the present invention is to provide a useful deodorant that is a compound that effectively enhances the efficacy of an organic deodorant component and that contains an efficacy enhancer of an organic deodorant component that can be used with peace of mind. And

In order to achieve the above object, the present invention adopts the following configuration.
(1) Containing green leaf alcohol as a compound that enhances the deodorizing effect of an organic deodorant component, and the organic deodorant component further includes a koji extract, a tea extract, and a grapefruit seed extract containing plant polyphenols. An organic deodorizing component characterized in that it is one or two of the selected plant extracts and the blending ratio of green leaf alcohol to the plant extract is 0.01 / 1 to 0.25 / 1 A deodorant containing a potency enhancer.
(2) deodorant containing a combination of enhancer organic deodorant component according to disinfectant component further includes a (1).
(3) Formulating the efficacy enhancer of the organic deodorizing component according to (2), wherein the sterilizing component is at least one selected from the group consisting of chlorhexidyl gluconate, ε-polylysine, chitosan, and tetrahydrolinalool. Deodorant .
(4) The deodorizer which mix | blended the efficacy enhancer of the organic type deodorizing component as described in (2) whose said microbe elimination component is (epsilon) -polylysine .

ADVANTAGE OF THE INVENTION According to this invention, the deodorizer which mix | blended the efficacy enhancer of the organic deodorizing component which is a compound which effectively enhances the efficacy of an organic deodorizing component and can be used safely is provided. This deodorant has not only an excellent deodorizing effect, but also has an effect of giving relaxation and refreshing feeling, promoting stress reduction, fatigue recovery, and improving concentration, and thus its practicality is extremely high.

In the present invention, an organic deodorant component is used. The reason is that an inorganic deodorant component and green leaf alcohol or green leaf aldehyde may be used in combination, but in this case, the effect of enhancing the efficacy by the latter cannot be expected.
As the organic deodorant component used in the present invention, considering safety, etc., those derived from plants containing plant polyphenols, terpenoids, etc., or betaine types such as alkylcarbobetaines, alkylsulfobetaines, alkylamidocarbobetaines, etc. Examples thereof include amphoteric surfactants and graft polymerization type polymer compounds, but are not limited thereto.

  Here, plant polyphenols are widely distributed as secondary metabolites in plants. For example, flavonols, isoflavones, tannins, catechins, quercetins, anthocyanins and derivatives thereof, phenolic acids And a single or mixture thereof. They may be extracts from plants such as persimmon, tea, grapefruit, hydrangea, mugwort, honoki, forsythia, and in particular one or two selected from persimmon extract, tea extract, grapefruit seed extract Suitable for the present invention.

Terpenoids are also widely present in plant essential oils, for example, terpene alcohols such as hinokitiol, terpineol, linalool, α-pinene, β-pinene, limonene, p-menthane, α-terpinene, terpinolene, carene, camphene, elemen, myrcene. A terpene-based cyclic hydrocarbon compound such as carvone can be used as a deodorizing component. These compounds may be isolated or synthesized from plant essential oils, and can also be used in the form of plant essential oils in which they are combined.
The plant polyphenols and terpenoid-containing materials are preferable in light of the spirit of the present invention because the deodorizing effect by green leaf alcohol or green leaf aldehyde is particularly remarkable.

Green leaf alcohol and green leaf aldehyde are components of a fragrance called “green fragrance” released from leaves, and their chemical structures are (3Z) -hexenol and (2E) -hexenal, respectively. These compounds are recognized as food additives, and their safety is high.
Aoba alcohol and Aoba aldehyde itself show only a slight deodorant effect even in a considerable amount, and the reason for the remarkable effect of enhancing the effect when combined with an organic deodorant component has not been clearly clarified. It is presumed that an unsaturated chemical structure is involved.

  When a plant extract is used as the organic deodorant component, for example, polyphenols in the plant extract can vary, but green leaf alcohol is 0.01 / 1 to 0.25 / 1 relative to the plant extract. What is necessary is just to mix | blend in the ratio of a grade. Within this range, an effective efficacy enhancing action can be expected, which is advantageous in terms of cost. On the other hand, if the blending amount is large, the smell of green leaf alcohol itself may become too strong.

  In the present invention, a sterilizing component may be blended in addition to the organic deodorizing component and green leaf alcohol as long as the safety and deodorizing effect are not hindered. Examples of such disinfecting components include ethanol, chlorhexidine gluconate, polylysine, chitosan, and tetrahydrolinalol.

Other perfume ingredients such as menthol, citronellal, geraniol, eugenol, caran-3,4-diol, or eucalyptus, citronella, neem, lavender, lemongrass, clover, bergamot-derived essential oils, extracts, and salicylic acid Esters, jasmonic acid esters and the like may be added, and by adding these fragrances, a repellent effect of pests and mites can be imparted.
Moreover, it can also be set as a multipurpose composition by mix | blending suitably other types of active ingredients, such as an insecticide, a disinfectant, and a fungicide.

The present invention also provides a deodorant containing a mixture of a compound that enhances the deodorizing effect of green leaf alcohol and an organic deodorizing component.
The dosage form may be arbitrarily designed according to the purpose and place of use, and examples thereof include a trigger spray for clothes and furniture, an indoor space aerosol agent, and a stationary fragrance.

  Examples of the liquid carrier used in preparing the dosage form include water, alcohols (ethanol, isopropanol, etc.), polyhydric alcohols (diethylene glycol, propylene glycol, 1,3-butylene glycol, glycerin, etc.), ketones, and the like. (Acetone, methyl ethyl ketone, cyclohexanone, etc.), ethers (ethyl ether, dioxane, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, etc.), aliphatic hydrocarbons (kerosene, mineral oil, kerosene, etc.), aromatic hydrocarbons ( Xylene, methylnaphthalene, etc.), esters, acid amides, nitriles and the like are suitable, and one or a mixture of two or more of these is used.

In addition, as necessary, propellant gas (liquefied petroleum gas, dimethyl ether, nitrogen gas, carbon dioxide gas, compressed air, etc.), surfactant (polyoxyethylene alkyl ethers, polyoxyethylene sorbitan fatty acid esters, glycerin fatty acid esters) Etc.), additives such as a gelling agent, a dispersing agent, a spreading agent, a penetrating agent, a stabilizer, a pH adjusting agent, a preservative, and a coloring agent may be appropriately used.
Further, in the present invention, an allergen reducing agent such as formaldehyde scavenger and sesquiterpene alcohol, a fiber protecting agent such as cyclic silicone, and the like can be added to provide other efficacy effects and increase added value.

The trigger spray can be manufactured by mixing green leaf alcohol, organic deodorant ingredients, and desired adjuvants with a liquid carrier such as ethanol, and filling the resulting chemical solution into an appropriate bottle. Can be manufactured by filling such a chemical solution in a pressure vessel and then filling it with an injection gas in accordance with an ordinary method.
In addition, there are types of table-type fragrances, in which the chemical solution is guided to the evaporating member using a liquid absorption core, and the volatile component is diffused, or the gel former is prepared instead of the chemical solution and the volatile component is diffused from this. However, the deodorant of the present invention can be applied to any dosage form.

  The deodorant of the present invention thus obtained can be safely applied to environmental spaces, clothing, bedding, furniture, etc. in living rooms, living rooms, bedrooms, entrances, cars, closets, closets and the like. And it helps to create a clean environment by deodorizing the air in the environment and the objects to be applied, and also provides a relaxed and refreshing feeling to the inhabited people, reducing stress, recovering from fatigue, and improving concentration. Therefore, its practicality is extremely high.

Next, based on a specific Example, the deodorizer which mix | blended the efficacy enhancer of the organic type deodorizing component of this invention is demonstrated in detail.

[Deodorization test]
Deodorants shown in Table 1 were prepared and evaluated for deodorizing effects on tobacco odor and yakiniku odor. As an organic deodorant component, a koji extract (product name: Pancil FG50) was used. Cut a cotton cloth (5 x 10 cm) with tobacco odor or grilled meat odor in half, spray the deodorizer twice from a distance of 20 cm with trigger spray (attachment amount: about 0.04 g), 1000 mL Erlenmeyer flask Then, immediately and 60 minutes later, the evaluation was performed by 8 panelists according to the following evaluation criteria.
(Evaluation criteria)
Odor intensity 0: Does not feel tobacco odor or grilled meat odor.
Odor intensity 1: Cannot be determined as tobacco odor or grilled meat odor.
Odor intensity 2: Although it is known as a tobacco odor or a grilled meat odor, it is weak.
Odor intensity 3: Clearly known as tobacco odor or grilled meat odor.
Odor intensity 4: A strong smell of tobacco or yakiniku.
Odor intensity 5: A strong smell of tobacco or yakiniku is felt.

As a result of the test, it was confirmed that the deodorizing effect was remarkably enhanced by adding green leaf alcohol to the koji extract as an organic deodorizing component.
In addition, the addition amount was preferably 0.01 / 1 or more with respect to the koji extract in terms of the enhancing effect, but if it exceeds 0.5 / 1, the smell of green leaf alcohol itself becomes too strong. There was a disagreement.

Straw extract (product name: Pancil FG50) 0.5% by weight as organic deodorant component, 0.08% by weight of mixture of green leaf alcohol and green leaf aldehyde, 6.0% by weight of ethanol, 0.4% by weight of sodium lactate Then, 0.3 wt% of alkyl acetate betaine amphoteric surfactant and ion-exchanged water were mixed to prepare a chemical solution used in the present invention. 300 mL of this chemical solution was filled into a plastic bottle to obtain a trigger spray type deodorant of the present invention.
This deodorant was sprayed three times at a distance of 20 to 30 cm on indoor clothes and fabric products with a smell such as cigarettes and pets. As a result, green leaf alcohol and green leaf aldehyde can enhance the deodorizing effect of the koji extract, and residents can feel relaxed due to the effect of green leaf alcohol and green leaf aldehyde diffused in the indoor space. It was.

0.6 g of grapefruit seed extract as organic deodorant component (0.2 w / v% based on the total amount of aerosol content), 0.15 g of green leaf alcohol (0.05 w / v based on the total amount of aerosol content) %), 0.6 g of ε-polylysine as a sterilizing component (0.2 w / v% based on the total amount of the aerosol content), 42 mL of ethanol (14% by volume based on the total amount of the aerosol content), and purified water 120 mL of aerosol stock solution containing 76 mL (25.3 vol% with respect to the total amount of aerosol contents) is placed in an aerosol container, a valve part is attached to the container, and 180 mL of dimethyl ether as a propellant is pressurized and filled through the valve part. Thus, an aerosol type deodorant of the present invention was obtained. The container internal pressure was 0.4 MPa.
When this deodorant was sprayed into the indoor space, the effect of green leaf alcohol significantly increased the deodorizing effect of the grapefruit seed extract, and in combination with the effect of the sterilizing component, it helped to clean the indoor air. In addition, Aoba Alcohol eased the feeling and created a relaxing space.

A transparent polyester containing 120 g of an aqueous solution containing 0.3 g of limonene as an organic deodorant component, 0.5 g of green tea essential oil, 0.1 g of a mixture of green leaf alcohol and green leaf aldehyde, 1.6 g of a nonionic surfactant and 117.5 g of water The container was filled. A felt-shaped felt absorbent core with an outer diameter of 7 mm is mounted through an inner plug attached to the opening of the upper part of the container, and a disk-shaped felt-made evaporation member is brought into contact with the top surface of the absorbent core. Was attached together with the support. Furthermore, a decorative member (artificial flower) was loaded above the evaporating member to obtain a standing type deodorant of the present invention.
This deodorant was used on the side board in the living room. As a result, unpleasant odors were eliminated over a two-month period, and a “green scent” was created to promote a feeling of recovery from fatigue. Artificial flowers that matched the interior also eased the mood and helped create a comfortable space.

Claims (4)

Green leaf alcohol is contained as a compound that enhances the deodorizing effect of the organic deodorant component, and the organic deodorant component is selected from a koji extract, a tea extract, and a grapefruit seed extract containing plant polyphenols One or two kinds of plant extracts, and the compounding ratio of green leaf alcohol to the plant extracts is 0.01 / 1 to 0.25 / 1, and the efficacy enhancer for organic deodorizing ingredients Deodorant formulated with The deodorizer which mix | blended the efficacy enhancer of the organic type deodorizing component of Claim 1 characterized by further including a disinfection component. 3. The efficacy enhancer of an organic deodorant component according to claim 2, wherein the sterilizing component is at least one selected from the group consisting of chlorhexidyl gluconate, ε-polylysine, chitosan, and tetrahydrolinalool. Deodorant formulated with The deodorizing agent blended with an efficacy enhancer of an organic deodorizing component according to claim 2, wherein the sterilizing component is ε-polylysine.