KR101224296B1 - Dual-layer aromayic and deodorant composition - Google Patents

Abstract

The present invention relates to a bilayer aromatic deodorant composition, and more particularly, to a bilayer aromatic deodorant composition comprising an upper layer containing an oily perfume and a nonpolar solvent, a water-soluble deodorant, an electrolyte containing a salt, and a lower layer containing water. .

In the double layer aromatic deodorant composition according to the present invention, the upper layer containing the perfume and the lower layer containing the water-soluble deodorant are clearly separated by application of an electrolyte containing a salt, and excellent in stability, and there is no residual of a surfactant or the like. At the same time, the initial deodorizing power and lasting effect are excellent without denatured fragrance and deodorant ingredients, and the fragrance does not change throughout the use period.

Aroma Deodorant, Bilayer, Electrolyte, Salt

Description

Double layer aromatic deodorant composition {DUAL-LAYER AROMAYIC AND DEODORANT COMPOSITION}

The present invention relates to a bilayer aromatic deodorant composition, and more particularly, by applying an electrolyte containing a salt, an upper layer containing a perfume and a lower layer containing a water-soluble deodorant are clearly separated and excellent in stability, such as a surfactant. It relates to a double layer fragrance deodorant composition which not only has no residue but also has excellent initial deodorizing power and lasting effect without modification of the fragrance and deodorant components, and the fragrance does not change throughout the service life.

Recently, in order to remove odorous substances causing unpleasant feelings for comfort and cleanliness of indoor environment and indoors and outdoors, products such as air fresheners, air freshening products, and bacteria and mold odor remover have been used for a long time. . In addition, in recent years, research on volatilization methods for highly volatilable substances such as fragrance oils, deodorants and pest repellents has been continuously increasing.

There are many methods of volatilization for these directional materials. For example, a spray type such as an aerosol sprays the contents of a liquid instantaneously, and another method is to put the contents of a liquid in a container and suck the contents by using a wick to volatilize the contents of fragrance, deodorant, and the like. .

In addition, there is a method of vaporizing the contents in a container in a gel or liquid state. The gel method is a method of naturally volatilizing active ingredients such as fragrance over time after absorbing the contents. For example, there are aqueous gel formulations that absorb and use the active ingredients in gels using polysaccharide components such as carrageenan, gelatin, guar gum, and synthetic polymer resins. In addition to the aqueous gels as described above, oil gel formulations are gradually increasing through gelation in oily solvents. Such solid gel formulations are easy to handle and have excellent decorative functions.

In addition, as a general technique of the liquid type, the oil phase uses a fragrance and a deodorant by using a surfactant, but there is a problem in that the fragrance of the oil phase is modified by a water-soluble deodorant having a high level of reactivity and a reactive surfactant. As another liquid type, an organic solvent is used, and since only an oil-based perfume and a deodorant are used, there is a problem in that synergistic effects on the fragrance deodorant due to the use of a water-soluble deodorant are difficult to obtain.

In order to solve the problems of the prior art as described above, the present invention is excellent in stability by the separation of the upper layer containing the fragrance and the lower layer containing the water-soluble deodorant by the application of an electrolyte containing a salt, the residual such as surfactant It is an object to provide a bilayer free deodorant composition.

It is another object of the present invention to provide a double layer fragrance deodorant composition which is excellent in initial deodorizing power and lasting effect without deterioration of the fragrance and deodorant components, and the fragrance does not change throughout the service life.

In order to achieve the above object, the present invention is a double layer aromatic deodorant composition,

a) an upper layer containing an oily perfume and a nonpolar solvent; And

b) a water-soluble deodorant, an electrolyte comprising a salt, and a lower layer containing water

It provides a bilayer fragrance deodorant composition comprising a.

Hereinafter, the present invention will be described in detail.

The present inventors have conducted studies on products having excellent aroma and deodorant. As a result, the present inventors have found a double-layer fragrance deodorant composition comprising an upper layer containing an oily perfume and a nonpolar solvent and a water-soluble deodorant, an electrolyte containing a salt, and a lower layer containing water. As a result of the manufacturing, the upper layer contains a maximum amount of fragrance components to maintain the fragrance of the fragrance for a long time, the lower layer is confirmed that it can provide a synergistic effect of the deodorant function by using a water-soluble deodorant, to complete the present invention based on this It became.

The bilayer aromatic deodorant composition of the present invention is characterized by including an upper layer containing an oily perfume and a nonpolar solvent, an electrolyte containing a water-soluble deodorant, a salt, and a lower layer containing water.

The upper layer of the fragrance deodorant composition of the bilayer of the present invention contains an oily perfume and a nonpolar solvent.

As the oily perfume, a normal water-insoluble oily liquid perfume can be used.

The oily fragrance is preferably included in the fragrance deodorant composition 4 to 36% by weight, when the content is less than 4% by weight has a problem that it is difficult to obtain a period of use for more than one month, when it exceeds 36% by weight There is a problem that the fragrance component is not sufficiently volatilized after formulation.

It is preferable to use a hydrocarbon-based or silicone oil, and the nonpolar solvent is used in the present invention isopa series of Exxon Corporation.

The non-polar solvent is preferably contained in 3 to 40% by weight, more preferably 20 to 38% by weight in the fragrance deodorant composition. If the content is less than 3% by weight, there is a problem that the oily flavor and metal salt deodorant components are not sufficiently volatilized, and when the content exceeds 40% by weight, it is difficult to expect the aroma and deodorant effect.

It is preferable that the upper layer containing the above components contains an oily flavor and a nonpolar solvent in a weight ratio of 1: 9 to 9: 1. The fragrance deodorant composition of the double layer of the present invention has a problem that the upper layer and the lower layer should be volatilized at the same time, when the mixing ratio is out of the above range, the oily fragrance of the upper layer is volatilized earlier or later than the lower layer.

As described above, the upper layer including the oily perfume and the nonpolar solvent may further include a preservative, a dye (pigment), an antifoaming agent, a buffer, an antioxidant, a solubilizer, or a sunscreen agent. The preservative may be used any preservatives commonly used in the fragrance deodorant composition in the art, the dye (pigment) may be used a conventional dye (pigment) soluble in an organic solvent.

The lower layer of the bilayer aromatic deodorant composition of the present invention comprises a water-soluble deodorant, an electrolyte containing a salt, and water.

The water-soluble deodorant acts to give a synergistic effect to the deodorizing power.

The water-soluble deodorant may be used as long as the water-soluble deodorant has been tested for stability and performance, specifically, natural extracts such as glyoxal, green tea extract, persimmon leaf extract, citric acid, or chlorine dioxide may be used. have.

The water-soluble deodorant is preferably included in the fragrance deodorant composition 0.01 to 5% by weight, more preferably from 0.03 to 3% by weight. If the content is less than 0.01% by weight, there is a problem in that synergistic effects on the deodorizing power cannot be expected, and when the content exceeds 5% by weight, there is a problem in that phase separation such as a leakage phenomenon may occur.

The electrolyte containing the salt serves to clarify the double layer of the fragrance deodorant composition of the present invention consisting of the upper layer and the lower layer, and to increase the stability.

In general, when water and oily properties exist together in two different layers, there is a high possibility that bubbles or interlayer suspensions may exist between the two layers. In addition, as the fragrance is applied, the interlayer may become more unstable due to various components in the fragrance. This is because of the polariy component of the fragrance (polariy ingredient) -OH group and -CHO group has a property to be directed to the water phase to delay the separation and make the interlayer unstable. However, fragrances usually have these groups, so it is difficult to get rid of them completely. Therefore, in order to solve this problem, in the present invention, by using a salt in the lower layer, which is an aqueous phase, the density of the aqueous phase is increased and separation is performed. This phenomenon can also be explained by the salting-out.

Salts usable in the electrolyte containing the salts include NaCl, KH ₂ PO ₄ , NaHCO ₃ , NH ₄ CO ₃ , (NH ₄ ) ₂ SO ₄ , MgSO ₄ , Na ₂ SO ₄ , Na ₂ HPO ₄ , MgCl ₂ Or CaCl ₂ . The salts are preferably used in the fragrance deodorant composition of the bilayer of the present invention within 3% by weight, when exceeding the content, the crystals are severely generated in the wick, which can prevent the volatilization from the wick. There is a problem.

The electrolyte containing the salt may use a conventional electrolyte used in the perfume deodorant in the art, in consideration of the reactivity of the fragrance and the deodorant in the upper layer can be selected and used through the appropriate experiments as well as to be.

The electrolyte containing the salt as described above is preferably included in the fragrance deodorant composition in an amount of 0.01 to 3% by weight, and if the content is less than 0.01% by weight, there is a problem in the effect of the salt, that is, the clarity of the separation and the stability of the surface. If it exceeds 3% by weight, there is a problem in that the crystal of salt occurs in the wick to prevent volatilization.

The lower layer of the aromatic deodorant composition of the double layer of the present invention comprising a water-soluble deodorant and a salt as described above contains a residual amount of water in addition to the above components, and in addition, a preservative, a dye (pigment), an antifoam, a buffer, an antioxidant, Solubilizers, sunscreens and the like. The preservative may be used all preservatives commonly used in the fragrance deodorant composition in the art, the dye (pigment) may use a conventional aqueous dye (pigment).

The volume ratio of the upper layer and the lower layer as described above is preferably included in the fragrance deodorant composition of the bilayer in a ratio of 1: 9 to 9: 1, more preferably 3: 7, 5: 5, or 4: It is more preferable that the two phases of the upper layer and the lower layer are volatilized at the same time, thereby increasing the apparent effect.

In addition, the fragrance deodorant composition of the present invention consisting of a double layer of the upper layer and the lower layer as described above will be volatilized due to the wick. That is, the wick sucks up the upper oil layer and the lower aqueous layer at the same time. Specifically, the pulp component may be a wick composed of a pulp-based or pulp-based and synthetic resin-based composite.

In addition, the bilayer aromatic deodorant composition of the present invention may be prepared by mixing an oily flavoring agent and a nonpolar solvent at room temperature and filling the container, followed by separately stirring an electrolyte containing water, a water soluble deodorant, and a salt to fill the container. Can be.

In the double layer aromatic deodorant composition according to the present invention, the upper layer containing the perfume and the lower layer containing the water-soluble deodorant are clearly separated by application of an electrolyte containing a salt, and excellent in stability, and there is no residual of a surfactant or the like. At the same time, there is an advantage that the initial deodorizing power and continuous effect is excellent, without deterioration of the fragrance and deodorant ingredients, and the fragrance does not change throughout the use period.

Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the scope of the present invention is not limited to the following examples.

[Example]

Example 1

20% by weight of ylang-ylang oil with liquid apomate therapy function (purchased from Charabo, France) and 25% by weight of isopa (Exon) with a nonpolar solvent were mixed together and stirred at room temperature for about 2 hours. In another mixer, 1% by weight of the green tea extract, a water-soluble deodorant, 0.2% by weight of KH ₂ PO ₄ (potassium phosphate), an electrolyte salt, 0.05% by weight of a preservative, and the remaining amount of purified water were mixed and stirred for 1 hour to prepare a lower mixture. It was. Then, the upper mixture was filled into the container, and the lower mixture was filled to prepare an aromatic deodorant composition.

Examples 2-3 and Comparative Example 1

Except for using the composition and components shown in Table 1 in Example 1 was carried out in the same manner as in Example 1.

The unit in Table 1 below is weight percent.

division Example 1 Example 2 Example 3 Comparative Example 1 Ylang-Ylang Oil 20 20 20 20 Isopa 20 20 20 20 Sunscreen - - 05 - Green tea extract One One One One KH ₂ PO ₄ One - - - NaHCO ₃ - One - - antiseptic 0.05 0.05 0.05 0.05 water 57.95 57.95 58.45 58.95

The fragrance deodorant composition prepared in Examples 1 to 3 and Comparative Example 1 was used to evaluate the clarity, fragrance, deodorizing power, stability, and residues between the two layers in the following manner.

end. Clarity between two layers-After shaking the bottle containing the fragrance deodorant composition prepared in Examples 1 to 3 and Comparative Example 1 up and down, the visual evaluation of the vividness between the two layers and the presence of suspended solids such as bubbles over time It observed according to, and the results are shown in Table 1 below.

division Example 1 Example 2 Example 3 Comparative Example 1 Interlayer 10 minutes later 4 5 4 4 30 minutes later 5 5 4 3 After 1 hour 5 5 3 3 After 24 hours 4 4 2 2.5

As shown in Table 2, the bilayer interlayer sharpness of the fragrance deodorant composition prepared in Examples 1 to 3 and Comparative Example 1 was observed, the composition of Examples 1 to 3 according to the present invention compared with Comparative Example 1 It was confirmed that the interlayer sharpness was excellent, especially the interlayer sharpness of Example 1 using KH ₂ PO ₄ was the most excellent.

I. Aromatic-The panel deodorant composition prepared in Examples 1 to 3 and Comparative Example 1 is installed in a well-ventilated and well-ventilated room at 25 to 30 ° C., respectively, and has a well developed sense of smell for 5 to 35 days. People were randomly selected and subjected to the sensory test using the 5-point scale method, and measured according to the following evaluation criteria, and the results are shown in Table 3 below.

division Example 1 Example 2 Example 3 Comparative Example 1 directional 7 days after 5 5 5 5 14 days after 4.5 4 4 4 21 days after 4 4 4 4 After 28 days 3 3.5 3 4 35 days after 2 2 2 2

As shown in Table 3, as a result of measuring the aromaticity of the aromatic deodorant composition prepared in Examples 1 to 3 and Comparative Example 1, the compositions of Examples 1 to 3 according to the present invention is usually sufficient to feel the sense of smell. It was found that the scent lasted more than 30 days.

All. Deodorizing power-Ammonia, trimethylamine, and methyl mercaptan, which can be tested by the detection tube method, were selected among the representative odorous substances. The detector tube is a simple measuring instrument that is harmful to the human body in the working environment, and cannot be used for GC analysis in terms of accuracy and accuracy. It is impossible to measure trace concentrations below ppm. However, since the concentration of the odor to be regulated is a high ppm level, and experiments to remove the odor in a small space, such as the actual refrigerator, experiments in the ppm range of tens to hundreds of times more concentrated than the cognitive concentration can be applied.

Deodorizing power for the fragrance deodorant composition prepared in Examples 1 to 3 and Comparative Example 1 ammonia (NH ₃ ) is gastec (GASTEC) detection tube no. 3La, trimethylamine (N (CH ₃ ) ₃ ) is a gas Tek detector tube no.180 was used, methylmercaptan (CH ₃ SH) was obtained by using the no.71, respectively, and the results are shown in Table 4 below.

division Example 1 Example 2 Example 3 Comparative Example 1 Deodorization (%) ammonia 93.4 96.5 95.5 94.5 Trimethylamine 97.4 97.0 96.8 97.2 Methyl mercaptan 97.3 97.0 98.0 97.3

As shown in Table 4, the fragrance deodorant composition of Examples 1 to 3 prepared according to the present invention contained green tea extract and showed an excellent deodorant effect against three major odorants of ammonia, trimethylamine, and methylmercaptan. And it was found.

la. Stability and Residues-The fragrance deodorant composition prepared in Examples 1 to 3 and Comparative Example 1 was subjected to stability evaluation for 7 days at the remaining amount, high temperature (50 ° C) and low temperature (-10 ° C) after use, and the result It is shown in Table 5 below.

division Example 1 Example 2 Example 3 Comparative Example 1 Remaining amount Initial (g) 100 100 100 100 Terminal (g) 0.4 0.4 0.3 0.3 stability High temperature (50 ℃) stability stability stability stability Low temperature (-10 ℃) stability stability stability stability

As shown in Table 5, the fragrance deodorant composition of Examples 1 to 3 prepared according to the present invention was confirmed that the contents are stable while using, and the residual amount also hardly appears, so it is efficient and excellent in stability.

In the double layer aromatic deodorant composition according to the present invention, the upper layer containing the perfume and the lower layer containing the water-soluble deodorant are clearly separated by application of an electrolyte containing a salt, and excellent in stability, and there is no residual of a surfactant or the like. At the same time, it has excellent initial deodorizing power and lasting effect without denaturation of fragrances and deodorant ingredients, and the fragrance does not change throughout the use period.

Although only described in detail with respect to the described embodiments of the present invention, it will be apparent to those skilled in the art that various modifications and variations are possible within the technical spirit of the present invention, it is natural that such variations and modifications belong to the appended claims. .

Claims (9)

In the bilayer aromatic deodorant composition, a) an upper layer containing an oily perfume and a nonpolar solvent, wherein the nonpolar solvent is selected from the group consisting of hydrocarbon-based or silicone oils; b) a lower layer containing a water soluble deodorant, an electrolyte comprising a salt, and water, Here, the water-soluble deodorant is selected from the group consisting of glyoxal (glyoxal), green tea extract, persimmon leaf extract, citric acid, and chlorine dioxide, the salt in the electrolyte containing the salt is NaCl, KH _At least one selected from the group consisting of ₂ PO ₄ , NaHCO ₃ , NH ₄ CO ₃ , (NH ₄ ) ₂ SO ₄ , MgSO ₄ , Na ₂ SO ₄ , Na ₂ HPO ₄ , MgCl ₂ , and CaCl ₂ ; A fragrance deodorant composition of a double layer comprising a. The method of claim 1, The fragrance deodorant composition of the double layer, characterized in that the fragrance of the oil phase is included 4 to 36% by weight in the fragrance deodorant composition. The method of claim 1, Bipolar fragrance deodorant composition, characterized in that the non-polar solvent is contained in 3 to 40% by weight in the fragrance deodorant composition. The method of claim 1, The upper layer is an aromatic deodorant composition of a double layer comprising an oily flavor and a nonpolar solvent in a weight ratio of 1: 9 to 9: 1. The method of claim 1, The fragrance deodorant composition of the double layer, characterized in that the water-soluble deodorant is contained in 0.01 to 5% by weight in the fragrance deodorant composition. The method of claim 1, The bilayer aromatic deodorant composition, characterized in that the electrolyte containing the salt is contained in the fragrance deodorant composition in 0.01 to 3% by weight. delete The method of claim 1, Wherein the upper and lower layers further comprise at least one additive selected from the group consisting of preservatives, dyes (pigments), antifoams, buffers, antioxidants, solubilizers, and sunscreens. Aroma Deodorant Composition. The method of claim 1, The volume of the upper layer and the lower layer is contained in the ratio of 1: 9 to 9: 1 in the fragrance deodorant composition of the bilayer, the fragrance deodorant composition of the double layer.