KR20160040026A

KR20160040026A - A solution for saponification, manufacturing method thereof and detergent composition by using them

Info

Publication number: KR20160040026A
Application number: KR1020140133492A
Authority: KR
Inventors: 이정훈; 엄경자
Original assignee: 이정훈
Priority date: 2014-10-02
Filing date: 2014-10-02
Publication date: 2016-04-12

Abstract

Provided in the present invention are: a saponified solution, which can manufacture a soap in a safe and easy manner by evenly stirring the same in oil, without directly using a strong alkaline solution in a soap manufacturing process; and a manufacturing method thereof. According to one feature of the present invention, the saponified solution and the manufacturing method thereof are configured to mix an effective microorganism group containing at least one aerobic microorganism including at least one selected from the group consisting of a microorganism derived from soil and a microorganism derived from seawater in water with organic matter, and to dissolve sodium hydroxide in an effective microorganism fermented solution obtained by fermenting and culturing the same.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a saponification solution, a preparation method thereof, and a detergent prepared using the saponification solution,

The present invention provides a saponifying solution containing a useful microorganism in a detergent manufacturing process and capable of preparing a detergent by uniformly stirring a solution prepared by pretreating alkali, and a method for preparing the same, and a detergent prepared using the same.

The chemical structure of the detergent consists of a hydrophobic group which is well mixed with oil and a hydrophilic group which dissolves well in water. Types of surface active agents can be divided into anionic detergents (including soaps and most synthetic detergents), cationic detergents, nonionic detergents, and positive detergents that determine positive and negative ions according to рН of wash water. The term " saponification " means neutralizing fatty acids or saponifying fats and oils to make detergents.

As a raw material for producing the detergent, there are used fats such as fat and oil, and alkali such as sodium hydroxide and potassium hydroxide, and the production methods thereof include a heating method, a hydrolysis method, and a cooling and half-heating method. In recent years, there has been an increasing interest in soaps using natural substances. In particular, the demand for natural detergents is increasing due to environmental pollution through detergents and skin diseases such as atopy. As a method for producing a detergent, a low-temperature method (CP) is a method of dissolving fat and mixing sodium hydroxide with stirring to prepare a strong alkaline sodium hydroxide or potassium hydroxide. However, these substances are odorless, white or colorless, persisting solid, reacts violently with water and splashing or inhaling during the reaction leads to severe irritation of the airways and skin. If it enters the eyes, , Since the number of saponification is different for each oil, it is troublesome to use a metered amount according to maintenance.

On the other hand, interest in the development and use of nature-friendly products is increasing as the environment-friendly issues become social issues. One such example is the increased interest and utilization of useful microorganisms (EMs). EM is a combination of microorganisms which are beneficial to humans or nature among the many microorganisms present in the natural world. EM is named after the first person of Effective Microoganisms. Effective microorganisms are fermented by photosynthetic bacteria, yeast bacteria, lactic acid bacteria, actinomycetes, It is a group of complex microorganisms that anaerobically survived 80 species of 5 genera and 10 genera with synthetic ability. It is known that detergents are prepared by adding EM as a raw material in the course of manufacturing detergents. However, in this case, there arises a problem that useful microorganisms are killed due to strong alkalinity in the course of mixing with sodium hydroxide or potassium hydroxide after the raw materials are mixed and dissolved There is a problem that an anaerobic useful microorganism is killed in the course of prolonged exposure to air in the manufacturing process to remove the toxicity of sodium hydroxide.

On the other hand, sodium chloride is added as an electrolyte in the process of producing soap, and it serves as an electrolyte. In addition, in order to extend the preservation period of the detergent, a separate preservative is contained. In this case, there is a harmful problem to the human body.

Patent Publication No. 10-2012-0021342

Disclosure of the Invention The present invention has been made to solve such a problem, and it is an object of the present invention to provide a soap solution which can contain a large amount of useful microorganisms even when exposed to air, And a method for producing the saponification solution.

The present invention also provides a saponification solution which can be preserved for a long period of time by containing a rhusin extract which functions as a preservative while replacing sodium chloride, and a method for producing the same.

It is an object of the present invention to provide a useful microorganism group containing at least one aerobic microorganism containing at least one selected from the group consisting of soil-derived microorganisms and marine water-derived microorganisms, Characterized in that sodium hydroxide is dissolved in the microbial fermentation broth.

Wherein the organic substance is selected from the group consisting of saccharides, amino acids, and soil organic substances.

The present invention also provides a saponification solution prepared by mixing the fermented microorganism fermentation broth obtained by dissolving the above sodium hydroxide and further adding a ruckus extract solution to the fermentation broth.

Derived microorganism comprising at least one aerobic microorganism comprising at least one selected from the group consisting of microorganisms originating from soil and microorganisms originating from marine aquatic organisms in an amount of from 5 to 60% by weight based on 100% by weight of water, from 5 to 60% Sodium hydroxide is mixed with the useful microorganism fermentation broth at a weight ratio of 1: 0.3-0.6 to the saponification solution.

In order to solve the above-mentioned problem, the present invention provides a useful microorganism group containing at least one aerobic microorganism comprising at least one selected from the group consisting of microorganisms derived from soil and marine aquatic organisms, in an amount of 5 to 60 wt% %, Water: 100% by weight, organic matter: 5 to 60% by weight; water; and fermentation and cultivation to produce a useful microorganism fermentation broth; A second step of mixing the useful microbial fermentation broth with sodium hydroxide at a weight ratio of 1: 0.3 to 0.6, relative to the fermentation broth of the useful microbial fermentation broth, to prepare an alkaline fermentation fermentation broth; A third step of aging the alkali-soluble microbial fermentation broth; And a fourth step of mixing and agitating the aged fermentation broth with a rhusin extract solution at a weight ratio of 1: 0.03 to 3 relative to the fermentation broth.

The detergent can be prepared by simply using the saponification solution according to the present invention as a substitute for conventional sodium hydroxide or potassium hydroxide and simply stirring to maintain the saponification solution according to the present invention without using strong alkali sodium hydroxide or potassium hydroxide And the mixture is agitated, a detergent can be easily produced by a simple and safe process.

Also, the soap produced using the saponified oil according to the present invention contains a useful microorganism and is excellent in the effect of removing the active oxygen due to the antioxidative action of the microorganism, and the detergent containing the rhusin extract and having a long preservation period can be produced.

1 is a flowchart schematically showing a method of producing a saponification solution according to an embodiment of the present invention.
2 is a flowchart schematically showing a method of manufacturing a saponification solution according to another embodiment of the present invention.
3 is a flowchart schematically showing a process for producing soap using a saponifying solution according to the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Reference will now be made in detail to the preferred embodiments of the present invention, examples of which are illustrated in the accompanying drawings. While the present invention has been described in connection with certain exemplary embodiments, it is to be understood that the invention is not limited to the disclosed exemplary embodiments. It is to be understood, however, that the invention is not limited to the particular forms disclosed, but includes all modifications, equivalents, and alternatives falling within the spirit and scope of the invention.

The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. Unless otherwise defined, all terms used herein, including technical or scientific terms, are to be construed as having the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs . It should also be understood that terms such as those defined in commonly used dictionaries are to be interpreted as having a meaning consistent with the contextual meaning of the related art and are not to be construed as an ideal or overly formal sense unless expressly defined in the present application Do not.

The saponifying solution according to one embodiment of the present invention is a solution of a useful microorganism group containing at least one aerobic microorganism selected from the group consisting of soil-derived microorganisms and marine aquatic-derived microorganisms, Which is obtained by dissolving sodium hydroxide in a fermentation broth of a useful microorganism obtained by culturing, and is simply used for producing detergent by stirring.

The organic material is at least one selected from the group consisting of saccharides, amino acids, and soil organic materials. The water can be purified water, and it can use various kinds of organic matter such as molasses-containing water, rice flour, fruit juice, and liquid containing an inorganic matter.

The useful microorganism in the present invention is a group of useful microorganisms containing at least one aerobic microorganism comprising at least one selected from the group consisting of soil-derived microorganisms and marine aquatic-derived microorganisms, wherein the soil-derived microorganisms are selected from the group consisting of carbohydrate- , Glutamic acid, glycine, and vermiculite are mixed and collected in a soil. The marine water-derived microorganisms are cultured and harvested by introducing plant-derived natural materials, water, and organic matter including sugar into marine water.

The saponification solution according to the present invention is a solution prepared by dissolving sodium hydroxide, which is a strong alkali, in a useful microorganism group beforehand, and is used as a substitute for caustic soda when a detergent is produced. Sodium hydroxide is NaOH, which is a representative material of strong bases. It is a dangerous substance that corrodes other substances. It is also called caustic soda because it is highly corrosive. The saponification solution according to the present invention is an environmentally friendly emulsifier which is different from sodium hydroxide and is an environmentally friendly emulsifier used in the production of a detergent, and is useful microorganisms containing at least one aerobic microorganism including at least one selected from the group consisting of microorganisms derived from soil and microorganisms derived from marine water (Isomorphic substitution) of noxious gas of sodium hydroxide and sulfuric acid by using the above-mentioned group.

In addition, the saponified oil according to the present invention is for producing soap by simple stirring with a grease, and is useful microorganisms containing at least one aerobic microorganism selected from the group consisting of soil-derived microorganisms and marine aquatic- By weight of water is mixed with water in an amount of 5 to 60% by weight based on 100% by weight of water and 100% by weight of water and 5 to 60% by weight of organic matter is mixed with water and fermented and cultured, thereby dissolving sodium hydroxide in the fermentation broth. Sodium hydroxide is mixed with the useful microorganism fermentation broth at a weight ratio of 1: 0.3 to 0.6.

Further, the saponification solution according to another embodiment of the present invention is obtained by additionally mixing a rhusi extract with a useful microorganism fermentation broth in which sodium hydroxide is dissolved.

1 is a flowchart schematically showing a method of producing a saponification solution according to an embodiment of the present invention.

Referring to FIG. 1, a process for producing a saponification solution capable of forming a soap by maintaining and simple agitation, is a process for producing a saponification solution which comprises at least one aerobic microorganism including at least one selected from the group consisting of microorganisms derived from soil and microorganisms derived from marine water Or more of a useful microorganism group is mixed with water in an organic material and fermented and cultured to prepare a useful microorganism fermentation broth. The soil-derived microorganisms are cultured and harvested by allowing the organic material containing carbohydrate to be mixed with at least one selected from the group consisting of chitosan, glutamic acid, glycine and vermiculite in a soil, and the marine water- Materials, water and organic matter including sugar are put into marine water for cultivation and harvesting. The soil-derived microorganisms and marine water-derived microorganisms are composed of aerobic yeast and bacteria, and include Saccharomyces cerevisiae, Bacillus pumilus, and Exiguobacterium acetylicum. .

The useful microorganism group is added with water and 5 to 60% by weight based on 100% by weight of water, and mixed with water in an amount of 5 to 60% by weight based on 100% by weight of water. The organic material may be selected from the group consisting of saccharides, amino acids, and soil organic materials, and the organic material provides nutrients necessary for the fermentation of the useful microorganism group. The water can be purified water, and it can use various kinds of organic matter such as molasses-containing water, rice flour, fruit juice, and liquid containing an inorganic matter. It is preferable that the useful microorganism fermentation broth is cultured for about 3 to 20 days so that the microorganism group, water, and organic matter are mixed and fermentation is sufficiently performed.

Sodium hydroxide is mixed at a weight ratio of 1: 0.3-0.6 in preparation of the useful microbial fermentation broth and aged for 3 to 5 days to prepare a saponification solution. Sodium hydroxide is preferably mixed at a weight ratio of 1: 0.3 to 0.6 in comparison with the microbial fermentation broth. When a small amount of sodium hydroxide is used, saponification does not occur. However, when an excessive amount of sodium hydroxide is used, the viscosity of the detergent produced becomes high and becomes hard. During the stirring of the useful microbial fermentation broth with sodium hydroxide, these materials react to generate a high temperature and a considerable amount of gas. After about 3 to 4 hours, the temperature is lowered and the vessel is opened so that the gas due to the reaction can be removed . And aged for 3 to 5 days to prepare an alkali soluble fermented microorganism. The saponification solution prepared using the conventional microorganism useful for EM can not be effectively used because the survival of useful microorganisms is very poor when the detergent is killed in the course of contact with the air. However, the saponification solution prepared using the useful microorganisms according to the present invention Since the aerobic microorganism is alive and useful in the saponification solution, a detergent containing useful microorganisms can be produced.

2 is a flowchart schematically showing a method of manufacturing a saponification solution according to another embodiment of the present invention.

2, a useful microorganism group containing at least one aerobic microorganism selected from the group consisting of soil-derived microorganisms and marine aquatic-derived microorganisms is dissolved in an amount of 5 to 60 wt% based on 100 wt% of water, Sodium hydroxide is mixed with the useful microorganism fermentation broth at a weight ratio of 1: 0.3-0.6 to the beneficial microorganism fermentation broth, and the sodium hydroxide is mixed with the sodium hydroxide at a weight ratio of 5: In addition to the fermented microbial fermentation broth, at a weight ratio of 1: 0.03 to 3, followed by stirring. Rhus javanica Linnaeus is a deciduous arboreous tree belonging to the genus Lacquer, which is dried and then boiled or squeezed to produce an extract. The saponification solution prepared by incorporating rhusi extract prolongs the preservation period of the detergent prepared by using it.

utility Microbial Extraction

Soil-derived microorganisms were collected by the following procedure.

A mixture of chitosan powder, 30 g of glutamic acid, 30 g of glycine, and 50 g of vermiculite was mixed with 1 kg of brown rice and 7% of barley rice at a weight of 7: 3, and the mixture was placed in a wooden box of 20 cm X 15 cm X height 10 cm, To a depth not to cover the upper surface of the wooden box, and to cover the side of the perimeter of the wooden box for about 6 to 8 days. After that, the wooden box was taken out and mixed with 1 kg of brown sugar and stored in a pot.

Microorganisms derived from marine water were collected by the following procedure.

One kilogram of radish, 1.5 liters of water, and one kilogram of brown sugar were boiled for about 10 minutes and put in a fine mesh, soaked in seawater for about 3 to 7 days. After that, the net was taken out and mixed with 500g of brown sugar uniformly and stored in a pottery bowl.

Production of rusk extract

6,000 g of water was added to 1,000 g of Rhus javanica leaf and stem, boiled for 1 to 2 hours, and filtered to obtain a sieve. The extracted solution is about 300-400 g

Preparation of useful microbial fermentation broth

A useful microorganism group, a white sugar, and water containing at least one aerobic microorganism including at least one selected from the group consisting of a plastic container having a size of 25 Kg to cultivate the useful microorganism group and a microorganism derived from the soil-derived microorganism and the marine aquatic organism are prepared. Weigh 15Kg of tap water that has been placed in the 30Kg container for 24 hours or more. Dissolve 6Kg of sugar evenly and pour into a container containing tap water. Pour 6Kg of microorganisms into the above solution and mix evenly. The container was opened and stirred once a day. A fermentation broth containing at least one or more aerobic microorganisms selected from the group consisting of soil-derived microorganisms and marine water-derived microorganisms, which is a basic solution for producing a saponification solution by being aged for about 10 days, .

Preparation of alkali-soluble fermentation broth for microorganism Example 1

The useful microorganism fermentation broth was prepared and used according to the above-described manufacturing process of the useful microorganism fermentation broth. Prepare a stainless steel container and weigh the sodium hydroxide to be added to the pre-made fermentation broth. 11.2 kg of sodium hydroxide required for 28 kg of the useful microorganism fermentation broth was weighed. The fermented broth of fermented microorganism was divided into 3 portions, so 8Kg of fermented liquid prepared separately for 2, 3, and 4 times was separately stored and kept in another container.

Pour 50 kg of the useful microorganism fermentation broth into the barrel and dissolve 11.2 Kg of sodium hydroxide. At this time, sodium hydroxide was stirred with a whisk to dissolve it well. After 3 to 4 hours, the temperature of the high temperature was lowered, and when the useful microorganisms reacted with the strong sodium hydroxide, the surface was whitened, and all of them were recovered by using the fine resin. After that, 8Kg was divided into 3 equal portions at intervals of 4 hours and mixed and stirred. When the temperature dropped below about 40 ° C, it was stored in a stainless steel barrel to avoid direct sunlight in an open state. The temperature was maintained at about 20 to 30 ° C.

Preparation of fermentation broth for microbial fermentation with alkali dissolution Example 2

Pour 50 kg of the useful microorganism fermentation broth into the barrel and dissolve 11.2 Kg of sodium hydroxide. At this time, sodium hydroxide was stirred with a whisk to dissolve it well. After 3 to 4 hours, the temperature of the high temperature was lowered, and when the useful microorganisms reacted with the strong sodium hydroxide, the surface was whitened, and all of them were recovered by using the fine resin. After that, 8Kg was divided into 3 equal portions at intervals of 4 hours and mixed and stirred. When the temperature dropped below about 40 ° C, it was stored in a stainless steel barrel to avoid direct sunlight in an open state. After fermentation of the alkali-soluble fermentation broth for 5 days, 1.2 kg of rhusi extract was added and stirred, and the fermentation broth was aged for 3 days while the container was opened. The temperature was maintained at about 20 to 30 ° C.

FIG. 3 is a flowchart illustrating a process for producing soap using the saponification solution according to the present invention. Referring to FIG. 3, the process for producing soap using the saponification solution according to the present invention will be described. First, various kinds of fat are weighed, the saponified solution is weighed, do. The saponified solution is slowly poured into the dissolved fat. Continue stirring until a trace occurs, and if necessary, add incense or functional additives to the soap mold (mold). After thermally neutralizing at a temperature of 70 캜, the mixture was natural-cured at room temperature, and the soap produced in the soap mold was separated after curing. Completed soap can be used immediately after 24 hours.

Production of soap using the saponification solution according to the present invention

A saponification solution was prepared according to Example 2 of the fermentation broth for alkali soluble fermentation using the useful fermentation broth prepared according to the fermentation broth of the present invention.

First, 25 g of palm, 30 g of coconut, 25 g of olive, 10 g of rice bran oil, and 10 g of castor oil were weighed to obtain 100 g of total oil. On the other hand, 42.8 g of the saponified solution according to Example 2 was weighed. The mixture was thoroughly mixed on a hot plate of 40 to 60 to completely dissolve the mixed oil. The metered saponification solution was homogeneously stirred while slowly poured into the oil. The viscosity of the saponified solution mixed with the grease increased. Then, it was stirred slowly for 10 to 30 minutes until a trace occurred. When the traces were completely up, I put aroma oil and spices. The mixture was poured into a soap mold and thermally neutralized at a temperature of 70 ° C for about 3 to 4 hours. After heat aging, the mixture was cured at room temperature, and the soap produced in the soap mold was separated after curing.

Manufacture of water-bath using the saponification solution according to the present invention

First, 25 g of palm, 30 g of coconut, 25 g of olive, 10 g of rice bran oil, and 10 g of castor oil were weighed to obtain 100 g of total oil. On the other hand, 20.0 g of the saponified solution according to Example 2 was weighed. The mixture was thoroughly mixed on a hot plate of 40 to 60 to completely dissolve the mixed oil. The metered saponification solution was homogeneously stirred while slowly poured into the oil. The viscosity of the saponified solution mixed with the grease increased. Glycerin (15 g) was mixed and slowly stirred for 10 to 30 minutes. When the trace completely occurred, aroma oil and fragrance were added. Then, a water bottle was prepared in a container.

After the saponification solution according to the present invention was prepared, the solution was filtered with a filter after 3 days, the dye was added to the solution to stain the bacteria remaining on the filter, and then the micrograph was observed with a slide glass and a cover glass. .

Claims

Derived microorganism containing at least one aerobic microorganism comprising at least one aerobic microorganism selected from the group consisting of soil-derived microorganisms and marine aquatic-derived microorganisms is mixed with water in an organic substance and fermented to obtain a fermentation broth of a useful microorganism obtained by dissolving sodium hydroxide &Lt; / RTI >

Derived microorganism comprising at least one aerobic microorganism comprising at least one selected from the group consisting of microorganisms originating from soil and microorganisms originating from marine aquatic organisms in an amount of from 5 to 60% by weight based on 100% by weight of water, from 5 to 60% By weight of water, and then mixing the solution with water to ferment and cultivate the solution. The saponification solution is obtained by dissolving sodium hydroxide in a fermentation broth of a useful microorganism.

The method according to claim 1 or 2,
Wherein the organic substance is at least one member selected from the group consisting of saccharides, amino acids, and soil organic substances.

The method according to claim 1,
Characterized in that the fermentation broth of the fermentation microorganism obtained by dissolving the sodium hydroxide is further mixed and agitated.

The method according to claim 1 or 2,
Wherein the soil-derived microorganism is cultured and harvested by allowing the organic material containing carbohydrate to be mixed with at least one selected from the group consisting of chitosan, glutamic acid, glycine and vermiculite in soil.

The method according to claim 1 or 2,
Wherein the marine water-derived microorganisms are cultured and harvested by introducing plant-derived natural materials, water, and organic matter including sugar into marine water.

Derived microorganism comprising at least one aerobic microorganism comprising at least one selected from the group consisting of microorganisms originating from soil and microorganisms originating from marine aquatic organisms in an amount of from 5 to 60% by weight based on 100% by weight of water, from 5 to 60% Sodium hydroxide is mixed with the beneficial microbial fermentation broth at a weight ratio of 1: 0.3 to 0.6 in the fermentation broth of the useful microbial fermentation broth.

Derived microorganism comprising at least one aerobic microorganism comprising at least one selected from the group consisting of microorganisms originating from soil and microorganisms originating from marine aquatic organisms in an amount of from 5 to 60% by weight based on 100% by weight of water, from 5 to 60% Sodium hydroxide is mixed with the useful microorganism fermentation broth at a weight ratio of 1: 0.3-0.6 to the fermentation broth of the useful microorganism obtained by mixing the fermentation broth with the water, 0.03 to 3, and further stirring the mixture to obtain a saponification solution.

Derived microorganism comprising at least one aerobic microorganism comprising at least one selected from the group consisting of microorganisms originating from soil and microorganisms originating from marine aquatic organisms in an amount of from 5 to 60% by weight based on 100% by weight of water, from 5 to 60% A first step of preparing a useful fermentation broth by mixing fermentation broth with water;
A second step of mixing the useful microbial fermentation broth with sodium hydroxide at a weight ratio of 1: 0.3 to 0.6, relative to the fermentation broth of the useful microbial fermentation broth, to prepare an alkaline fermentation fermentation broth; And
And a third step of aging the alkali-soluble microbial fermentation broth.

Derived microorganism comprising at least one aerobic microorganism comprising at least one selected from the group consisting of microorganisms originating from soil and microorganisms originating from marine aquatic organisms in an amount of from 5 to 60% by weight based on 100% by weight of water, from 5 to 60% A first step of preparing a useful fermentation broth by mixing fermentation broth with water;
A second step of mixing the useful microbial fermentation broth with sodium hydroxide at a weight ratio of 1: 0.3 to 0.6, relative to the fermentation broth of the useful microbial fermentation broth, to prepare an alkaline fermentation fermentation broth;
A third step of aging the alkali-soluble microbial fermentation broth; And
And a fourth step of mixing and agitating the aged fermentation broth with a rhusin extract solution at a weight ratio of 1: 0.03 to 3 relative to the fermentation broth.

A detergent prepared by adding the saponifying solution according to any one of claims 1 to 8 at a weight ratio of 1: 0.3 to 0.5 relative to the weight of the saponified product and stirring at room temperature.