KR20160010468A - Liquid treatment composition for textile product - Google Patents

Abstract

The present invention relates to (A) a fragrance composition, (B) a glucan having a branched cyclic structure portion and an outer branch structure portion and having a degree of polymerization of 50 to 10000, wherein the branched branched cyclic structure portion is α- Glucoside bond and an α-1,6-glucoside bond, and the outer branched structure moiety is a non-cyclic structure moiety bonded to the inner branched ring structure moiety, and (C) A liquid treating composition for a textile product, comprising a cationic surfactant.

Description

[0001] LIQUID TREATMENT COMPOSITION FOR TEXTILE PRODUCT [0002]

The present invention relates to a liquid treating composition for textile products, and more particularly to a liquid treating composition for textile products suitable for use in textile products such as clothing. More particularly, the present invention relates to a liquid treating composition for a textile product, which is excellent in an effect of suppressing change in aroma tone and improving the remainder.

In recent years, there has been a growing demand for products with strong fragrance, and techniques for improving the reverberation property of fragrance by treating agents for textile products are still being improved.

For example, as a method for improving the reverberation property of fragrance by leaving a large amount of fragrance in a laundry bath on a treated cloth, there is known a technique in which a large amount of a fragrance having a high ClogP in a fiber treatment agent is compounded in a fragrance prescription (Japanese Patent No. 3102893). However, the use of high fragrance by ClogP only monotonizes the fiber product after drying and does not meet the needs of the living. In addition, the high fragrance of ClogP has few kinds and is often expensive, which is economically disadvantageous.

On the other hand, low ClogP spices are more difficult to be left in the treatment award than high ClogP spices. Therefore, in particular, in the case of using low-perfume of ClogP, there is a strong tendency that the originally designed perfume is changed before and after the treatment. Japanese Patent Laid-Open Publication No. 2009-144306 discloses a technique capable of imparting a low ClogP flavor to a cloth. However, it is necessary to synthesize a specific polymer and use it in combination with a low ClogP flavor, This is complicated. Also, this technique is not a technique that is intended to suppress the change of the tone. In addition, as described above, ClogP is a low-grade fragrance that is highly likely to cause a change in the tone. However, in the treating agent for textile products, the problem of the change in the tone is present in the whole fragrance including high fragrance of ClogP.

Japanese Patent Laid-Open Publication No. 2011-127260 discloses a fiber product treatment composition containing a specific silicate ester compound. However, according to Japanese Patent Laid-Open Publication No. 2011-127260, it is necessary to blend a fragrance silicate ester compound having a log P of 1 or more and less than 15 with a fragrance silicate ester compound having a log P of 15 or more and less than 50. Therefore, it is necessary to carry out a treatment for converting the perfume component into a silicate ester compound, and the process is troublesome. In addition, as described above, there still exists a problem of a change in the flavor of the fragrance.

Accordingly, an object of the present invention is to provide a liquid treating composition for a textile product which is excellent in the effect of suppressing the change in the tilt angle and improving the reverberation property.

The inventors of the present invention have found that, by blending a specific glucan called highly branched branched dextrin with a perfume in a liquid treating composition for a textile product, a perfume can be left much in the treatment award even in the case of a fragrance having a low ClogP , It was found that the reverberation can be improved while suppressing the change in the tone.

The present invention has been accomplished based on such new knowledge.

According to the present invention,

(A) a perfume composition,

(B) a glucan having a cyclic structure portion and an outer branched structure portion and having a polymerization degree in the range of 50 to 10000, wherein the inner branched cyclic structure portion is an α-1,4-glucoside bond And an α-1,6-glucoside bond, and the outer branch structure portion is glucan, which is a non-cyclic structure portion bound to the inner branched ring structure portion, and

(C) A positive ion surfactant

≪ / RTI > to provide a liquid treating composition for a textile product.

In one embodiment of the present invention, the component (A) contains a perfume ingredient having a ClogP value of 5 or less or a perfume ingredient having a cyclic structure in the structure.

In one embodiment of the present invention, the component (C) is selected from an amine compound, a salt thereof, or a quaternary product thereof having 1 to 3 hydrocarbon groups having 10 to 26 carbon atoms, which may be divided into an ester group or an amide group .

In the liquid treating composition for a textile product of the present invention, by combining the fragrance ingredient (A) and the highly branched cyclic dextrin ingredient (B), a fragrance can be left much in the treatment award even if the fragrance has a low ClogP , It is possible to improve the reverberation while suppressing the change in the tone.

[Component (A)] [

The component (A) contained in the liquid treating composition for a textile product of the present invention is a perfume composition.

The perfume composition used in the present invention is a perfume composition comprising at least one perfume ingredient generally used in a treating composition for textile products, for example, a finishing agent composition or a softener composition for textile products.

Specific examples of the perfume ingredients are not particularly limited and may be appropriately selected in response to the purpose. Examples thereof include aldehydes, phenols, alcohols, ethers, esters, hydrocarbons, ketones, lactones, , Perfumes having a terpene skeleton, natural perfumes, animal perfumes, and the like.

Examples of the aldehydes include, but are not limited to, undecylenic aldehyde, laurylaldehyde, aldehyde C-12MNA, amalcinealdehyde,? -Amylcinnamic aldehyde, cyclic aldehyde, , Citronellal, ethyl vanillin, heliotrophin, anisaldehyde,? -Hexylsynnamaldehyde, octal, ligustral, lily, rical, triplal, vanillin, heliolal and the like.

The phenol is not particularly limited and can be appropriately selected in response to the purpose. Examples include phenol, isogenol, isoengenol, and the like.

The alcohols are not particularly limited and may be appropriately selected in response to the purpose. Examples of the alcohols include aliphatic alcohols such as aldehyde, aldehyde, Hydroxynaphthalene, hydroxynaphthalene, hydroxynaphthalene, hydroxynaphthalene, hydroxynaphthalene, hydroxynaphthalene, hydroxynaphthalene, hydroxynaphthalene,

The ethers are not particularly limited and can be appropriately selected in response to the purpose. Examples thereof include shed lambda, grisalba, methyl ogenol, methyl isoceanol and the like.

Examples of the esters include, but are not limited to, cis-3-hexenyl acetate, cis-3-hexenyl propionate, cis-3-hexenyl salicylate, amyl salicylate, benzyl salicylate, benzyl benzoate, benzyl acetate, cedar acetate, citronellyl acetate, decahydronaphthaleneacetate, p-cresyl acetate, pt-butylcyclohexyl acetate, amyl acetate, methyl dihydro zasumonate, Ethyl acetate, erica acetate, geranyl acetate, geranyl formate, hedino, linalyl acetate,? -Phenyl ethyl acetate, hexyl salicylate, hexyl salicylate, Butylate, stearyl acetate, terpinyl acetate, betiberyl acetate, ot-butylcyclohexyl acetate, manzanate, And the like rilhep Gaetano benzoate.

The above-mentioned hydrocarbons are not particularly limited and can be appropriately selected in response to the purpose. Examples thereof include d-limonene,? -Pinene,? -Pinene and myrcene.

The ketone is not particularly limited and can be appropriately selected in response to the purpose. Examples of the ketone include a-ionone,? -Ironone, methyl-? -Naphthyl ketone,? -Damascone,? -Damascone,? But are not limited to, the following compounds: - Damascone, cis-jasmon, methylionone, allylionone, cashemenan, dihydrozamone, iso super, bertopics, isolonji polaranone,

Raspberry ketone, dynascon, and the like.

The lactones are not particularly limited and may be appropriately selected in response to the purpose. Examples thereof include lactones such as? -Decalactone,? -Undecaractone,? -Nonaracetone,? -Dodecalactone, coumarin, And the like.

The above-mentioned mercury is not particularly limited and can be appropriately selected in response to the purpose. Examples thereof include cyclopentadecanolide, ethyleneblycylate, galactosolve, musk ketone, tonalide and nitromer screw have.

The perfume having the terpene skeleton is not particularly limited and can be appropriately selected in response to the purpose. Examples of the perfume include geraniol (geraniol), nerol, linalool, citral, citronellol, menthol, mint , Citronellal, myrcene, pinene, limonene, terpineol, carbone, yonon, camphor, borneol and the like.

The natural flavoring agent is not particularly limited and can be appropriately selected in response to the purpose. Examples of the natural flavoring agent include orange oil, lemon oil, lime oil, petroleum jelly, oil free, neroli oil, bergamot oil, lavender oil, Citronella oil, geranium oil, peppermint oil, peppermint oil, spearmint oil, eucalyptus oil, lemon grass oil, rapeseed oil, jasmine oil, rose oil, cedar oil, Essential oil (essential oils such as oil, vetiver oil, galbanum oil, oakmoss oil, pine juice oil, camphor oil, petroleum oil, bay oil, telemphen oil, clove oil, clove oil, cacao oil, nutmeg oil, ).

The animal flavor is not particularly limited and can be appropriately selected in response to the purpose. Examples of the animal flavor include, for example, musk, royal jelly, dissociated flavor, miso flavor and the like.

In the liquid treating composition for a textile product of the present invention, it is preferable to use, as the component (A), a perfume composition containing a perfume component having a ClogP value of 5 or less. For example, the flavor component may be contained in an amount of 10% by mass or more, more preferably 30% by mass or more, further preferably 50% by mass or more, particularly preferably 70% by mass or more with respect to the total mass of the perfume composition .

In the liquid treating composition for a textile product of the present invention, it is preferable to use, as the component (A), a perfume composition containing a perfume component having a cyclic structure in its structure. For example, the perfume ingredient may be contained in an amount of 10% by mass or more, more preferably 20% by mass or more, further preferably 35% by mass or more, and particularly preferably 60% by mass or more with respect to the total mass of the perfume composition .

More preferably, in the liquid treating composition for textile products of the present invention, a perfume composition containing a perfume ingredient having a ClogP value of 5 or less and having a cyclic structure is used. More preferably, in the liquid treating composition for a textile product of the present invention, a perfume composition containing 20 mass% or more of a perfume component having a ClogP value of 5 or less and a cyclic structure, particularly preferably a ClogP value of 5 or less A perfume composition containing 40 mass% or more of a perfume ingredient having a cyclic structure is also used.

The cyclic structure referred to herein may be, for example, a hydrocarbon ring structure or a heterocyclic ring structure, and may be monocyclic or polycyclic, and may be a condensed polycyclic structure, a crosslinked ring structure, a spirocyclic structure, Or an unsaturated ring structure may be used. The hetero atom contained in the heterocycle includes, for example, O, S, N and P.

Specific examples of the cyclic structure include monocyclic compounds such as benzene and condensed ring compounds such as naphthalene. As the element forming the cyclic structure, a carbon ring compound or a heterocyclic compound may be used. As the size of the ring, a six-membered ring compound such as cyclopentane, furan or the like, a five-membered ring compound such as cyclohexane or benzene, or the like may be used.

Specific examples of the perfume ingredient in the component (A) to be suitably used in the liquid treating composition for a textile product of the present invention include isoy super (ClogP 4.7, cyclic structure), ethyl vanillin (ClogP 1.8, (ClogP 3.8, with cyclic structure), Ogenerol (ClogP 2.4 with cyclic structure), Damascone (ClogP 4.7, with cyclic structure), Heliolane ClogP 1.4, with cyclic structure), benzyl salicylate (ClogP 4.2, with a cyclic structure), Kashmeran (ClogP 4.0 with a cyclic structure), coumarin (ClogP 1.4 with a cyclic structure), dimethylbenzylcarvinyl acetate (ClogP 1.9 with a cyclic structure), terpineol ClogP 2.6, (ClogP 4.3, with a cyclic structure), triflal ClogP 2.4 (with a cyclic structure), phenylethyl alcohol (ClogP 1.2 with a cyclic structure), hexyl cinnamaldehyde (ClogP 4.9 with a cyclic structure) ), beta-yonone (ClogP 3.8, with cyclic structure), hedione (ClogP 2.4, cyclic structure (ClogP 5, with cyclic structure), methylionone (ClogP 4.2 with cyclic structure), limonene (ClogP 4.4 with cyclic structure), Rilal (ClogP 2.2 with cyclic structure), Lilial 3.9, having a cyclic structure), and the like, but the perfume ingredients used in the present invention are not limited thereto. More preferred are iso-super, ethyl vanillin, gamma undecalactone, ougenol, beta damascone, and helio-benzyl salicylate. More preferably, it is ougenol, beta damascone, and helioide benzyl salicylate.

The ClogP value is calculated by dividing the 1-octanol / water partition coefficient (P), which represents the ratio of the equilibrium concentration in 1-octanol and water (water), to the chemical in logarithm to base 10 . The ClogP value is obtained by decomposing the chemical structure of a compound into its constituent elements by the f value method (hydrophobic fragment constant method) (See, for example, Clog 3 Reference Manual Daylight Software 4.34, Albert Leo, David Weininger, Version 1, March 1994).

Generally, a perfume composition containing a large amount of a fragrance component having a low ClogP value is more hydrophilic than a perfume composition containing a large perfume component having a large ClogP value because the fragrance is hydrophobic with a larger ClogP value I can tell.

In the liquid treating composition for a textile product of the present invention, a perfume ingredient having a ClogP value of 1.0 or more and 8.0 or less in terms of freshness and palatability of the perfume composition is preferably 30 mass% or more, , More preferably not less than 45 mass%, more preferably not less than 50 mass%, particularly preferably not less than 80 mass%, further more preferably not less than 90 mass%.

The perfume composition used in the present invention may contain a treating agent composition for textile products, for example, a solvent commonly used in a finishing agent composition for a textile or a softener composition. Examples of the solvent for the perfume include at least one selected from the group consisting of acetine (triacetin), MMB acetate (3-methoxy-3-methylbutyl acetate), sucrose diacetate hexaisobutylate, ethylene glycol dibutylate, hexylene glycol, dibutyl sebacate (Diethyleneglycol monomethyl ether), carbitol (diethylene glycol monoethyl ether), TEG (triethylene glycol), benzyl benzoate (BB), propylene glycol, phthalic acid (Dipentaerythritol hexafluorophosphate), dipropylene glycol (DPG), parnesene, dioctyl adipate, tributyrin (glyceryl tributanoate), and the like. , Hydrolyzate 5 (1,2-pentanediol), propylene glycol diacetate, cetyl acetate (hexadecyl acetate), ethyl abietate, avarin (methyl abietate), Citroflex A-2 (Tributyl citrate), Citroflex A-4 (tributyl acetyl citrate), Citroflex No. 2 (triethyl citrate), Citroflex No. 4 (tributyl citrate) (Methyldihydroabietate), MITD (isotridecyl myristate), polyimolonen (limonene polymer), and 1,3-butylene glycol.

These solvents are incorporated in the perfume composition in an amount of, for example, 0.1 to 30 mass%, preferably 1 to 20 mass%.

In the liquid treating composition for a textile product of the present invention, the blending amount of the component (A) is not particularly limited, but when it is used as a softener composition, it is preferably 0.01 to 5% by mass, Is from 0.1 to 5% by mass, and more preferably from 0.5 to 3% by mass. Is preferably 0.001 to 1% by mass, more preferably 0.005 to 1% by mass, and still more preferably 0.01 to 0.5% by mass, based on the total mass of the entire composition when it is used as a spray-type fiber treatment composition. When the blending amount of the component (A) is less than 0.001% by mass, the fragrance is weak, and it is difficult to know the effect of improving the effect of suppressing the change in the tone variation and improving the reverberation. If the blending amount of the component (A) is more than 5% by mass, the storage stability at a high temperature may be lowered.

[Component (B)] [

The component (B) contained in the liquid treating composition for a textile product of the present invention is a glucan having a degree of polymerization ranging from 50 to 10000, having an inner ring branched structure portion and an outer branched structure portion, The branched cyclic structure portion is a cyclic structure portion formed by an? -1,4-glucosidic bond and an? -1,6-glucosidic bond, and the outer branched structure portion is a noncyclic structure bonded to the inner branched cyclic structure portion Part, glucan. Such a glucan is also referred to as highly branched cyclic dextrin or cluster dextrin. In the present specification, the component (B) is also referred to as " highly branched cyclic dextrin ".

The highly branched cyclic dextrin contained in the liquid treating composition for a textile product of the present invention has a molecular weight of from about 30,000 to about 1,000,000, has one cyclic structure in the molecule, and has a large number of glucan chains And mainly includes dextrin having a combined weight average polymerization degree of about 2500.

The inner branching cyclic structure portion of the highly branched cyclic dextrin contained in the liquid treatment composition for a textile product of the present invention is composed of about 10 to 100 glucose, and a plurality of non-cyclic branched glucan And the outer branch structure portion composed of the chain is bonded.

For example, the degree of polymerization of the highly branched cyclic dextrin contained in the liquid treating composition for a textile product of the present invention is in the range of 50 to 5,000.

For example, the degree of polymerization of the branched branched cyclic structure portion of the highly branched cyclic dextrin contained in the liquid treating composition for a textile product of the present invention is in the range of 10 to 100.

For example, the degree of polymerization of the branched structure portion of the highly branched cyclic dextrin contained in the liquid treating composition for a textile product of the present invention is 40 or more.

For example, the degree of polymerization of each unit chain of the branched structure portion of the highly branched cyclic dextrin contained in the liquid treating composition for a textile product of the present invention is 10 to 20 on average.

The highly branched cyclic dextrin contained in the liquid treating composition for a textile product of the present invention is produced, for example, by using an enzyme called a branching enzyme with starch as a raw material. The starting starch is composed of amylose in which glucose is linearly bonded by? -1,4-glucoside bond and amylopectin having a structure in which the complex is branched by? -1,6-glucosidic bond, and amylopectin , And a large number of cluster structures connected together. The branching enzyme, which is a used enzyme, is a glucan chain transfer enzyme widely distributed in plants, animals and microorganisms, and acts on a joint part (an eye part) of the cluster structure of amylopectin and catalyzes a reaction of annularizing it.

More specifically, the highly branched cyclic dextrin contained in the liquid treating composition for a textile product of the present invention has a branched branching structure portion and an outer branched structure portion as described in Japanese Patent Application Laid-Open No. 8-134104, and has a polymerization degree of 50 to 10000 Lt; / RTI > In the present specification, the highly branched cyclic dextrin can be understood in consideration of the description of Japanese Patent Laid-Open No. 8-134104.

The highly branched cyclic dextrin contained in the liquid treating composition for a textile product of the present invention has a specific structure as described above and also has a high degree of polymerization (molecular weight), and α-cyclodextrin (n = 6), β-cyclodextrin (n = 7), gamma -cyclodextrin (n = 8), and the like.

As a specific example of the highly branched cyclic dextrin contained in the liquid treating composition for a textile product of the present invention, "cluster dextrin" (registered trademark) of Glyco Nutrition Food Co., Ltd. can be mentioned.

In place of the highly branched cyclic dextrin, it is also possible to use a general cyclic compound having 6 to 8 of glucose such as? -Cyclodextrin (n = 6),? -Cyclodextrin (n = 7) and? -Cyclodextrin Even when the dextrin is compounded in the liquid treating composition for textile products, the effect of improving the effect of suppressing the change in the degree of color change and improving the reverberation is not obtained, which is equivalent to that of the liquid treating composition for textile products of the present invention.

In the liquid treating composition for a textile product of the present invention, the blending amount of the component (B) is not particularly limited, but when it is used as a softener composition, it is preferably 0.01 to 10% by mass, Is 0.03 to 5% by mass, and more preferably 0.05 to 3% by mass. When the blending amount of the component (B) is more than 0.01% by mass, it is possible to exhibit an excellent effect of suppressing the change in the tone change and improving the reverberation. When the blending amount of the component (B) is more than 10% by mass, the effect of improving the fading change suppression / reverberation property is not particularly improved, the stability at high temperature preservation is deteriorated, the liquid viscosity of the composition is increased, . In the case of a spray type fiber treatment agent, the blending amount of the component (B) is preferably 0.01 to 5% by mass, more preferably 0.03 to 3% by mass, and still more preferably 0.05 to 1% by mass with respect to the total mass of the entire composition %to be. When the blending amount of the component (B) is more than 0.01% by mass, it is possible to exhibit an excellent effect of suppressing the change in the tone change and improving the reverberation. If the blending amount of the component (B) is more than 10% by mass, the stability at high temperature preservation may be deteriorated, and the liquid viscosity of the composition may be increased and the handling property may be lowered.

In the liquid treating composition for a textile product of the present invention, the mass ratio of the component (A) / component (B) is not particularly limited, but when it is used as a softener composition, 1/100 to 20, more preferably 1/10 to 5, and further preferably 1/5 to 1.

The reason why the flavor of the fragrance, particularly the fragrance with low ClogP value, is felt when the odor of the liquid treatment composition for textile products is compared with the odor of the treated cloth is not necessarily clear, but the following reasons are considered.

In the case of the softener composition, when the composition is prepared, the fragrance component (hydrophilic flavor component) having a low ClogP value is hardly received in the vesicle formed by the positive ionic surfactant, It seems to be easy to exist. Therefore, when the softening treatment is performed in the washing process, the fragrance ingredient having a low ClogP value flows out into the rinsing liquid, and is hardly adsorbed on the cloth. Therefore, since the fragrance component having a low ClogP value is present in the treatment promoter in a proportion lower than that in the softener composition, the fragrance is changed and felt.

In the case of the spray-type fiber treatment composition, it is considered that fragrance components having a low ClogP value are difficult to be incorporated into the micelles formed by the cationic surfactant when the composition is prepared, so that they are likely to be present in the bulk. Therefore, the fragrance having a low ClogP value when sprayed on a cloth is liable to volatilize because it is deposited on the fabric in a state in which it is not received in the micelle. Therefore, the perfume component having a lower ClogP value is present in the treated fabric, because the perfume component having a lower ClogP value is present in a proportion lower than that in the spray-type fiber treating composition.

As described above, even in the case of the softener composition and the spray type fiber treatment composition, the fragrance ingredient having a low ClogP value is difficult to be incorporated into the cationic surfactant, and is likely to be present in the bulk.

In the liquid treatment composition for a textile product of the present invention, the highly branched cyclic dextrin is compounded and the highly branched cyclic dextrin dissolved in the bulk has a spiral structure, so that the spice can be enclosed in the spiral structure , It is considered that the capsule body is adsorbed on the capsule. Since the highly branched cyclic dextrin does not maintain the spiral structure on the fiber, the fragrance component is gradually released from the encapsulated body adsorbed on the fiber. Therefore, it is considered that the fragrance of the fragrance component having a low ClogP value can be sufficiently felt, and the change in the flavor tone is suppressed.

Further, when the perfume component has a cyclic structure, it is considered that the fragrance component is more likely to interact with the highly branched cyclic dextrin, and therefore, the effect is considered to be higher.

[Component (C)] [

The component (C) contained in the liquid treatment composition for a textile product of the present invention is a cationic surfactant. For example, in the present invention, the cationic surfactant to be used as the component (C) may include a hydrocarbon group having 10 to 26 carbon atoms (hereinafter sometimes referred to as a "long-chain hydrocarbon group") which may be divided by an ester group or an amide group At least one compound selected from the group consisting of an amine compound having 1 to 3 carbon atoms, a salt thereof and a quaternary product thereof. Among them, acid salts of tertiary amines having at least one hydrocarbon group having 10 to 26 carbon atoms, which may be divided into ester groups or amide groups, or quaternary amines thereof are preferable.

When the liquid treating composition for textile products of the present invention is used as a softener composition, the component (C) may be an amine compound having 1 to 3 hydrocarbon groups of 10 to 26 carbon atoms, which may be divided into an ester group or an amide group, At least one kind of compound selected from the group consisting of salts thereof and quaternary compounds thereof. In particular, the carbon number of the long-chain hydrocarbon group is 10 to 26, preferably 17 to 26, and more preferably 19 to 24. If the carbon number of the long chain hydrocarbon group is 10 or more, flexibility is good, and if it is 26 or less, the handling property is good.

When the liquid treating composition for a textile product of the present invention is used as a spray type fiber treatment composition, the component (C) is an amine compound having two hydrocarbon groups having 10 to 14 carbon atoms, which may be divided into an ester group or an amide group, A salt thereof, a quaternary cargo thereof, and at least one member selected from the group consisting of an amine compound having one hydrocarbon group having 10 to 18 carbon atoms, which may be separated into an ester group or an amide group, Compounds are preferred. Among them, an amine compound having two hydrocarbon groups having 10 to 14 carbon atoms, which may be divided into an ester group or an amide group, a salt thereof and a quaternary compound thereof are particularly preferable.

The long-chain hydrocarbon group may be saturated or unsaturated. When the long-chain hydrocarbon group is unsaturated, the position of the double bond may be at any position, but when the double bond is one, the position of the double bond is distributed around the center of the long chain hydrocarbon group or the central value .

The long-chain hydrocarbon group may be either a chain hydrocarbon group or a hydrocarbon group containing a ring in the structure, and is preferably a chain hydrocarbon group. The chain hydrocarbon group may be either straight chain or branched chain. As the chain hydrocarbon group, an alkyl group or an alkenyl group is preferable, and an alkyl group is more preferable.

The long-chain hydrocarbon group may be divided into an ester group (-COO-) or an amide group (-NHCO-). That is, the long-chain hydrocarbon group may have at least one branching group selected from the group consisting of an ester group and an amide group in the carbon chain, and the carbon chain may be divided by the branching group. When such a branching group is present, the biodegradability is preferably improved.

In the case of having such a branching group, the number of branching groups of one long-chain hydrocarbon group may be one or two or more. That is, the long-chain hydrocarbon group may be branched at one site by a branching group or may be branched at two or more positions. In the case of having two or more branching groups, the respective branching groups may be the same or different.

In the case of having a branching group in the carbon chain, the carbon atom of the branching group is assumed to be counted to the carbon number of the long chain hydrocarbon group.

The long-chain hydrocarbon group is usually derived from an industrially used un-hydrogenated fatty acid derived from tallow, a fatty acid obtained by hydrogenating or partially hydrogenating an unsaturated part, a plant derived from a plant such as palm, An unsaturated fatty acid or a fatty acid ester, or a fatty acid or a fatty acid ester obtained by hydrogenating or partially hydrogenating an unsaturated moiety.

As the amine compound in the component (C) contained in the liquid treating composition for a textile product of the present invention, a secondary amine compound or a tertiary amine compound is preferable, and a tertiary amine compound is more preferable.

More specifically, as the amine compound in the component (C), a compound represented by the following general formula (C1) may be mentioned.

[Chemical Formula 1]

Wherein R ¹ to R ³ each independently represent a hydrocarbon group having 10 to 26 carbon atoms, -CH ₂ CH (Y) OCOR ⁴ (Y is a hydrogen atom or CH ₃ , and R ⁴ is a hydrocarbon group having 7 to 21 carbon atoms - (CH ₂ ) _n NHCOR ⁵ (n is 2 or 3 and R ⁵ is a hydrocarbon group having 7 to 21 carbon atoms), a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, -CH ₂ CH ( (CH ₂ ) _n NH ₂ , and at least one of R ¹ to R ³ is a hydrocarbon group having 10 to 26 carbon atoms, -CH ₂ CH (Y) OCOR ⁴ , or - (CH ₂ ) _n NHCOR ^5. ]

In the formula, the number of carbon atoms of the hydrocarbon group having 10 to 26 carbon atoms in R ¹ to R ³ is preferably 17 to 26, and more preferably 19 to 24. The hydrocarbon group may be saturated or unsaturated. As the hydrocarbon group, an alkyl group or an alkenyl group is preferable.

Of the -CH ₂ CH (Y) OCOR ⁴ , Y is a hydrogen atom or CH ₃ , and a hydrogen atom is particularly preferable.

R ⁴ is a hydrocarbon group having 7 to 21 carbon atoms, preferably 15 to 19 carbon atoms. In the presence of R ⁴ in the formula plurality, may be the that the plurality of R ⁴ are the same as each other, it does not matter, each different.

Groups of the R ⁴ hydrocarbon, a fatty acid having a carbon number of 8~22 (R ⁴ COOH), fatty acid (R ⁴ COOH) formed by the moieties (fatty acid residue) and, R ⁴ is other than a carboxyl group from, good and even saturated fatty acids even if the unsaturated fatty acid, and , And may be a straight chain fatty acid or a branched fatty acid. Of these, saturated or unsaturated straight chain fatty acids are preferred. The saturation / unsaturation ratio (mass ratio) of the fatty acid composed of R ⁴ is preferably 90/10 to 0/100, and more preferably 80/20 to 0/100 because it imparts good absorbency to the softened clothes .

When R ⁴ is an unsaturated fatty acid residue, there is a cis sieve and a trans-sieve, and the mass ratio of the cis / trans is preferably from 40/60 to 100/0, more preferably from 70/30 to 90/10.

Specific examples of the fatty acid comprising R ⁴ include stearic acid, palmitic acid, myristic acid, lauric acid, oleic acid, elaidic acid, linolic acid, partially hydrogenated palm oil fatty acid (iodine is 10 to 60), partially hydrogenated fatty acid 10 to 60). Among them, a fatty acid composition adjusted to satisfy the following conditions (a) to (c) by combining predetermined amounts of two or more selected from stearic acid, palmitic acid, myristic acid, oleic acid, Is preferably used.

(mass ratio) of (a) saturated fatty acid / unsaturated fatty acid is 90/10 to 0/100, and more preferably 80/20 to 0/100.

(mass ratio) of (b) cis / trans is from 40/60 to 100/0, more preferably from 70/30 to 90/10.

(c) the fatty acid having 18 carbon atoms is 60 mass% or more, preferably 80 mass% or more, the fatty acid having 20 carbon atoms is less than 2 mass%, and the fatty acid having 21 to 22 carbon atoms is less than 1 mass%.

- (CH ₂ ) _n NHCOR ⁵ , n is 2 or 3, and 3 is particularly preferred.

R ⁵ is a hydrocarbon group having 7 to 21 carbon atoms, preferably 15 to 19 carbon atoms. In the presence of R ⁵ in the formula plurality, may be the that the plurality of R ⁵ are equal to each other, it does not matter, each different.

R ⁵ may be the same as R ⁴ .

At least one of R ¹ to R ³ is a long chain hydrocarbon group (that is, a hydrocarbon group having 10 to 26 carbon atoms, -CH ₂ CH (Y) OCOR ⁴ , or - (CH ₂ ) _n NHCOR ⁵ ), two long chain hydrocarbons Lt; / RTI >

When one or two of R ¹ to R ³ are long-chain hydrocarbon groups, the remaining two or one of R ¹ to R ³ is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, -CH ₂ CH (Y) OH, or - (CH ₂ ) _n NH ₂ , an alkyl group having 1 to 4 carbon atoms, -CH ₂ CH (Y) OH, or - (CH ₂ ) _n NH ₂ . Of these, as the alkyl group having 1 to 4 carbon atoms, a methyl group or an ethyl group is preferable, and a methyl group is particularly preferable. Y in -CH ₂ CH (Y) OH is the same as Y in -CH ₂ CH (Y) OCOR ⁴ . _{N in} - (CH ₂ ) _n NH ₂ is the same as n in - (CH ₂ ) _n NHCOR ⁵ .

As preferred examples of the compound represented by the above general formula (C1), there can be mentioned the compounds represented by the following general formulas (C1-1) to (C1-8).

(2)

[Wherein R ⁷ and R ⁸ are each independently a hydrocarbon group of 10 to 26 carbon atoms. R ⁹ and R ¹⁰ are each independently a hydrocarbon group having 7 to 21 carbon atoms.

Examples of the hydrocarbon group for R ⁷ and R ⁸ include the same hydrocarbon groups as the hydrocarbon groups having 10 to 26 carbon atoms for R ¹ to R ³ .

Examples of the hydrocarbon group having 7 to 21 carbon atoms for R ⁹ and R ¹⁰ include the hydrocarbon groups having 7 to 21 carbon atoms for R ⁴ . In the presence of R ⁹ in the formula plurality, may be the that the plurality of R ⁹ is the same as each other, it does not matter, each different.

A salt of an amine compound is obtained by neutralizing an amine compound with an acid. The acid used for neutralization of the amine compound may be an organic acid or an inorganic acid, and examples thereof include hydrochloric acid, sulfuric acid, methylsulfuric acid and the like. The neutralization of the amine compound can be carried out by a known method.

The quaternary compound of the amine compound is obtained by reacting the quaternizing agent with the amine compound. Examples of the quaternizing agent used for the quaternization of the amine compound include halogenated alkyl such as methyl chloride and dialkyl sulfuric acid such as dimethylsulfuric acid. When these quaternizing agents are reacted as amine compounds, the quaternary alkyl group is introduced into the nitrogen atom of the amine compound and a salt of the quaternary ammonium ion and the halogen ion or monoalkyl sulfate ion is formed. The alkyl group introduced by the quaternizing agent is preferably an alkyl group having 1 to 4 carbon atoms, more preferably a methyl group or an ethyl group, and particularly preferably a methyl group. The quaternization of the amine compound can be carried out by a known method.

As the component (C) contained in the liquid treating composition for a textile product of the present invention, at least one member selected from the group consisting of the compound represented by the general formula (C1), a salt thereof and a quaternary product thereof is preferable, (C1-1) to (C1-6), a salt thereof and a quaternary compound thereof, and more preferably at least one compound selected from the group consisting of (C1-1) to (C1-8) More preferably at least one kind selected from the group consisting of quick-setting materials.

The compound represented by the formula (C1), the salt thereof and the quaternary compound thereof may be commercially available ones or may be those prepared by known methods.

For example, a compound represented by formula (C1-2) (hereinafter referred to as "compound (C1-2)") and a compound represented by formula (C1-3) , The fatty acid composition, or a fatty acid methyl ester composition in which a fatty acid in the fatty acid composition is substituted with a methyl ester of the fatty acid, and methyldiethanolamine. At that time, from the viewpoint of improving the flexibility, it is preferable to synthesize such that the abundance ratio represented by "compound (C1-2) / compound (C1-3)" is 99/1 to 50/50 by mass ratio.

Further, when the quaternary cargo is used, it is more preferable to use dimethylsulfuric acid as the quaternizing agent. At this time, from the viewpoint of flexibility, the compound is synthesized such that the ratio of the quaternary compound of the compound (C1-2) / quaternary compound of the compound (C1-3) is 99/1 to 50/50 in terms of mass ratio .

(Hereinafter referred to as " compound (C1-5) ") represented by general formula (C1-4) -6) (hereinafter referred to as " compound (C1-6) ") can be synthesized by condensation reaction of the fatty acid composition or the fatty acid methyl ester composition with triethanolamine. At that time, from the viewpoint of flexibility, the content ratio of the individual components to the total mass of the compounds (C1-4), (C1-5) and (C1-6) is preferably 1 to 60 mass , The compound (C1-5) is preferably from 5 to 98 mass%, the compound (C1-6) is from 0.1 to 40 mass%, the compound (C1-4) is from 30 to 60 mass% ) Is 10 to 55 mass%, and the compound (C1-6) is 5 to 35 mass%.

In addition, when the quaternary cargo is used, it is more preferable to use dimethylsulfuric acid as the quaternizing agent in order to sufficiently proceed the quarternization reaction. From the viewpoint of flexibility, the ratio of the quaternary compounds of the compounds (C1-4), (C1-5) and (C1-6) is 1 to 60 mass % Of the compound (C1-4), 5 to 98 mass% of the quaternary compound of the compound (C1-5) and 0.1 to 40 mass% of the quaternary compound of the compound (C1-6) More preferably 30 to 60 mass%, the quaternary compound of the compound (C1-5) is 10 to 55 mass%, and the quaternary compound of the compound (C1-6) is 5 to 35 mass%. When the compounds (C1-4), (C1-5) and (C1-6) are quaternized, esteramines which do not quaternarize generally remain after the quaternization reaction. At this time, it is preferable that the ratio of the "quaternary cargo / quaternary esteramine" is within the range of the mass ratio of 70/30 to 99/1.

The compound represented by the general formula (C1-7) (hereinafter referred to as the "compound (C1-7)") and the compound represented by the general formula (C1-8) And an adduct of N-methylethanolamine and acrylonitrile, JOrg. (2-hydroxyethyl) -N-methyl-1,3-propylenediamine synthesized by a known method described in Chem., 26, 3409 (1960). At that time, it is preferable to synthesize the compound so that the ratio of the compound (C1-7) / compound (C1-8) is 99/1 to 50/50 in mass ratio. When the quaternary cargo is used, it is preferable to use methyl chloride as the quaternizing agent, and the presence of the quaternary cargo / compound (C1-8) Is preferably in the range of 99/1 to 50/50 by mass ratio.

In the liquid treating composition for a textile product of the present invention, the component (C) has a function of increasing the adsorption of the component (A) and the component (B), and is blended so as to impart flexibility to the treated cloth.

In the liquid treating composition for a textile product of the present invention, the blending amount of the component (C) is not particularly limited, but it is preferably 0.01 to 30% by mass relative to the total mass of the entire composition.

When the liquid treating composition for a textile product of the present invention is used as a softener composition, the amount of the component (C) to be blended is not particularly limited, but is preferably 5 to 30% by mass, 5 to 25% by mass, and more preferably 8 to 22% by mass. When it is 5% by mass or more, sufficient flexibility imparting effect can be obtained. When it is 30 mass% or less, storage stability is good.

When the liquid treating composition for a textile product of the present invention is used as a spray type fiber treating composition, the amount of the component (C) to be incorporated is not particularly limited, but is preferably 0.01 to 10% by mass relative to the total mass of the entire composition Preferably 0.03 to 8% by mass, more preferably 0.05 to 5% by mass.

In the liquid treating composition for a textile product of the present invention, the mass ratio of the component (B) / component (C) is not particularly limited, but when it is used as a softener composition, it is preferably 1/300 to 2/3, Is 1/25 to 2/3, more preferably 1/15 to 2/3, and when used as a spray type fiber treatment composition, it is preferably 1/1000 to 1000, more preferably 1/80 to 200 , And more preferably from 1/10 to 100.

[Optional ingredients]

The liquid treating composition for a textile product of the present invention may contain components other than the above components (A) to (C) in accordance with necessity, provided that the effect of the present invention is not impaired.

As other components thereof, known components in the liquid treating composition for textile products can be appropriately compounded. For example, water (water), a water-soluble solvent, a nonionic surfactant, silicone, a dye and / or a pigment, a preservative, an ultraviolet absorber, an antibacterial agent and the like may be contained.

The liquid treating composition for textile articles of the present invention is preferably an aqueous composition and preferably comprises water.

As the water, tap water, ion-exchanged water, pure water, and distilled water can all be used. Among them, ion exchange water is suitable.

The non-ionic surfactant can be preferably used for the purpose of improving the emulsion dispersion stability of an oil-soluble component mainly in emulsions when the treating composition for textile products of the present invention is an emulsified product. In particular, when a nonionic surfactant is blended, a sufficient level of freeze restoration stability tends to be secured in terms of commercial value.

As the nonionic surfactant, for example, those derived from higher alcohols, higher amines or higher fatty acids can be used. More specifically, a polyoxyethylene alkyl ether having an alkyl or alkenyl group having 10 to 22 carbon atoms and having an average addition mole number of ethylene oxide of 10 to 100 moles, a polyoxyethylene fatty acid alkyl (having 1 to 3 carbon atoms of the alkyl) ester ; A polyoxyethylene alkylamine having an average addition mole number of ethylene oxide of 10 to 100 mols, an alkyl polyglucoside having an alkyl group or an alkenyl group of 8 to 18 carbon atoms, a hardened castor oil having an average addition mole number of ethylene oxide of 10 to 100 mols . Of these, polyoxyethylene alkyl ethers having an alkyl group of 10 to 18 carbon atoms and having an average addition mole number of ethylene oxide of 20 to 80 moles are preferable.

The content of the nonionic surfactant in the treating composition for a textile product of the present invention can be determined according to a desired function and is, for example, preferably 0.01 to 10 mass%, more preferably 0.1 to 8 mass% Preferably 0.5 to 5% by mass. If the content of the nonionic surfactant is at least the lower limit value, the emulsion dispersion stability of the oil-soluble component in the emulsion and the stability of freezing restoration of the emulsion are further improved. When the content is less than the upper limit, increase in the viscosity of the treating composition for liquid fiber products can be suppressed, and good usability can be obtained.

The kind of the silicone compound is not particularly limited and can be suitably selected in response to the purpose. The molecular structure of the silicone compound may be linear, branched, or may be crosslinked. The silicone compound may be a modified silicone compound, and the modified silicone compound may be modified by one kind of organic functional group or may be modified by two or more kinds of organic functional groups.

The silicone compound can be used in the form of an oil or in the form of a crude emulsion dispersed by an arbitrary emulsifier.

As specific examples of the silicone compound, there may be mentioned, for example, dimethyl silicone, polyether modified silicone, methylphenyl silicone, alkyl modified silicone, higher fatty acid modified silicone, methylhydrogen silicone, fluorine modified silicone, epoxy modified silicone, Modified silicone, and amino-modified silicone.

Of these, polyether-modified silicones, amino-modified silicones, dimethylsilicones, and the like are preferable from the viewpoints of versatility and deodorizing and deodorizing effect, and polyether- desirable.

Specific examples of the polyether-modified silicone include a copolymer of an alkylsiloxane and a polyoxyalkylene. The number of carbon atoms of the alkyl group of the alkylsiloxane is preferably from 1 to 3, and the number of carbon atoms of the alkylene group of the polyoxyalkylene is preferably from 2 to 5. Among these, as the polyether-modified silicone, a copolymer of dimethylsiloxane and polyoxyalkylene (polyoxyethylene, polyoxypropylene, random or block copolymer of ethylene oxide and propylene oxide) is preferable. Specific examples of such polyether-modified silicones include compounds represented by the following general formula (I) and compounds represented by the following general formula (II).

(3)

In the general formula (I), M, N, a, and b represent an average degree of polymerization, and R represents hydrogen or an alkyl group. Here, M is preferably 10 to 10,000, more preferably 100 to 300. N is preferably 1 to 1,000, more preferably 1 to 100. It is also preferable that M > N. a is preferably from 2 to 100, more preferably from 2 to 50. b is preferably 0 to 50, more preferably 0 to 10. R is preferably hydrogen or an alkyl group having 1 to 4 carbon atoms.

The polyether-modified silicone represented by the general formula (I) generally has a structure in which a carbon-carbon double bond such as an organohydrogenpolysiloxane having an Si-H group and a polyoxyalkylene allyl ether, Can be produced by subjecting a polyoxyalkylene alkyl ether having a hydroxyl group to an addition reaction under a platinum catalyst. Therefore, unreacted polyoxyalkylene alkyl ether or organohydrogenpolysiloxane having Si-H group may be contained in the polyether-modified silicone. Since the organohydrogenpolysiloxane having a Si-H group has high reactivity, the amount of the organohydrogenpolysiloxane having a Si-H group in the polyether-modified silicone is preferably 30 ppm or less (as the amount of Si-H).

[Chemical Formula 4]

In the general formula (II), A, B, h, and i are average degree of polymerization, R represents an alkyl group, and R 'represents hydrogen or an alkyl group. Here, A is preferably 5 to 10,000, and B is preferably 2 to 10,000. h is preferably from 2 to 100, and i is preferably from 0 to 50. R is preferably an alkyl group having 1 to 5 carbon atoms. R 'is preferably hydrogen or an alkyl group having 1 to 4 carbon atoms.

The linear polysiloxane-polyoxyalkylene block copolymer represented by the general formula (II) is obtained by reacting a polyoxyalkylene compound having a reactive terminal group with a terminal group reacting with a reactive terminal group of the compound Dihydrocarbylsiloxane. ≪ / RTI > Since such a polyether-modified silicone has a longer polyoxyalkylene chain in the side chain and a higher degree of polymerization of the polysiloxane chain, the viscosity of the polyether-modified silicone is increased as the polymerization degree of the polysiloxane chain is increased. Therefore, in order to improve workability during production and to facilitate incorporation into an aqueous composition, It is preferable to provide it to the combination in the form of a premix. The water-soluble organic solvent includes, for example, ethanol, dipropylene glycol, and butyl carbitol.

Examples of the polyether-modified silicone include SH3772M, SH3775M, FZ-2166, FZ-2120, L-720, SH8700, L-7002, L- KF-6012 and KF-6004 manufactured by Shin-Etsu Chemical Co., Ltd., KF352A, KF615A, X-22-6191, X-22-4515, KF-6012 and FZ- TSF4440, TSF4441, TSF4445, TSF4450, TSF4446, TSF4452, and TSF4460 of Momento Chibu, Performance, Material Japan, and Japan Joint Association.

As the amino-modified silicone, a silicone oil into which an amino group is introduced at the terminal or side chain of a dimethyl silicone skeleton may be substituted with a substituent such as a hydroxyl group, an alkyl group or a phenyl group in addition to the amino group. In the case of an oil, it may be in the form of an amino-modified silicone emulsion obtained by emulsifying a nonionic surfactant or a cationic surfactant with an emulsifier. Preferred oil of amino-modified silicone or base oil in case of emulsion is represented by the following general formula (III).

[Chemical Formula 5]

In the formula (III), R ₁ and R ₆ may be the same or different and represent any one of a methyl group, a hydroxyl group and a hydrogen. R ₂ represents any one of - (CH ₂ ) _n -A ₁ , and - (CH ₂ ) _n -NHCO- (CH ₂ ) _m -A ₁ . A ₁ represents any _one of -N (R ₃ ) (R ₄ ) and -N ⁺ (R ₃ ) (R ₄ ) (R ₅ ) X-. R ₃ to R ₅ may be the same or different and represent any one of a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, a phenyl group, and - (CH ₂ ) _n -NH ₂ . X ^- represents any one of a fluorine ion, a chlorine ion, a bromine ion, an iodine ion, a methyl sulfate ion, and an ethyl sulfate ion. The values of m and n may be the same or different and represent an integer of 0 to 12. The values of p and q represent the degree of polymerization of the polysiloxane and may be the same or different, and p represents 0 to 20,000, preferably 10 to 10000, and q represents 1 to 500, preferably 1 to 100.

In the case of an amino-modified silicone oil used as the treating composition for textile articles of the present invention, the kinematic viscosity at 25 캜 is preferably 50 to 20000 mm 2 / s, more preferably 100 to 10000 mm 2 / s. When the kinematic viscosity is within this range, a high tactile-imparting effect is exhibited, and the composition is favorable and handling of the composition becomes easy, which is preferable.

Examples of the amino-modified silicone oil include those commercially available from Dow Corning Toray Co., Ltd. as SF-8417, BY16-892, BY16-890, KF-864, KF-860, KF-8004, KF-8002, KF-865, KF-867, KF-861, KF-880 and KF-867S are commercially available from Etsu Chemical Co.,

Examples of the amino-modified silicone emulsion type include those sold by Dow Corning Co., Ltd. as SM8904, BY22-079, FZ-4671 and FZ-4672, those sold by Shin-Etsu Chemical Co., Ltd., PolonMF- 14, PolonMF-29, PolonMF-14D, PolonMF-44, PolonMF-14EC and PolonMF-52, and those sold by Asahi Chemical Industry Co., Ltd. as WACKERFC201 and WACKERFC218.

The kinematic viscosity of dimethylsilicone is not particularly limited and is preferably 1 to 100,000,000 mm 2 / s, more preferably 10 to 10,000,000 mm 2 / s, and still more preferably 100 to 1,000,000 mm 2 / s. Further, it may be an oil or an emulsion.

The liquid treatment composition for textile products of the present invention preferably contains a water-soluble solvent in addition to water.

As the water-soluble solvent, one or two or more selected from the group consisting of low-grade (C 1 -4) alcohols, glycol ether solvents and polyhydric alcohols are preferable. Concretely, it is preferable to use at least one selected from the group consisting of ethanol, isopropanol, glycerin, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, hexylene glycol polyoxyethylene phenyl ether, dipropylene glycol monomethyl ether, It is preferable to blend a solvent component selected from water-soluble solvents.

R ^{11 is} -O- (C ₂ H ₄ O) _y- (C ₃ H ₆ O) _z -H (X)

In the formula, R ¹¹ is an alkyl or alkenyl group having 1 to 6 carbon atoms, preferably 2 to 4 carbon atoms. y and z are an average addition mole number, y represents 1 to 10, preferably 2 to 5, and z represents 0 to 5, preferably 0 to 2.

As the water-soluble solvent, ethanol, ethylene glycol, butyl carbitol, propylene glycol, diethylene glycol monobutyl ether and dipropylene glycol monomethyl ether are preferable among the above.

The water-soluble solvent is preferably incorporated in an amount of from 0 to 30 mass%, more preferably from 0.01 to 25 mass%, and even more preferably from 0.1 to 20 mass%, in the liquid treating composition for a textile product of the present invention.

The dyes and / or pigments may be blended for the purpose of improving the appearance of the liquid treating composition for textile products of the present invention. Preferably, it is at least one of water-soluble dyes of red, blue, yellow or azo system selected from acid dyes, direct dyes, alkaline dyes, reactive dyes and mordant-acid mordant dyes.

Specific examples of dyes that can be added are described in the Dye Handbook (published by Organic Synthetic Chemistry Association, July 20, 1970, Maruzen Co., Ltd.).

From the viewpoint of the storage stability of the treating composition for textile products of the present invention and the dyeability to fibers, an acid dye, a direct dye, a reactive dye having at least one functional group selected from a hydroxyl group, a sulfonic acid group, The blending amount thereof is preferably 1 to 50 ppm, more preferably 1 to 30 ppm, based on the entire composition.

Examples of the dyes used in the liquid treating composition for textile products of the present invention include those disclosed in JP-A-6-123081, JP-A-6-123082, JP-A-7-18573, and JP-A-8-27669 , Dyes described in Japanese Patent Application Laid-Open Nos. 9-250085, 10-77576, 11-43865, 2001-181972 or 2001-348784 can be used It is possible.

Preservatives can be used in the treating composition for textile articles of the present invention, mainly to enhance buoyancy, sterilizing power and to maintain antiseptic properties during long-term storage.

Examples of the preservative include isothiazolone-based organic sulfur compounds, benzisothiazolone-based organic sulfur compounds, benzoic acids, and 2-bromo-2-nitro-1,3-propanediol.

Examples of the isothiazoline based oil-based sulfur compounds include 5-chloro-2-methyl-4-isothiazolin-3-one, 2-n-butyl-3-isothiazolone, 3-isothiazolone, 2-methyl-4-isothiazolone-3, 3-isothiazolone, 2-methyl- -One, or a mixture thereof. Among them, 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin- A mixture of 2-methyl-4-isothiazolin-3-one is more preferable, and a mixture of about 77 mass% of electrons and about 23 mass% of the latter is particularly preferable.

Examples of the benzisothiazolone-based organic sulfur compounds include 1,2-benzisothiazolin-3-one, 2-methyl-4,5-trimethylene-4-isothiazolin- As the compound, dithio-2,2-bis (benzmethylamide), a mixture thereof and the like can be given. Among them, 1,2-benzisothiazolin-3-one is particularly preferable.

Examples of the benzoic acid include benzoic acid or a salt thereof, parahydroxybenzoic acid or a salt thereof, methyl p-hydroxybenzoate, ethyl p-oxybenzoate, propyl p-hydroxybenzoate, butyl p-hydroxybenzoate and benzyl p-hydroxybenzoate.

In the liquid treating composition for textile articles of the present invention, the blending amount of the preservative is preferably 0.0001 to 1% by mass based on the total amount of the treating composition for textile products. If the blending amount of the preservative is less than the lower limit, the effect of adding the preservative is hardly obtained, and if it exceeds the upper limit value, the storage stability may be lowered.

The ultraviolet absorber is a medicament having an effect of protecting ultraviolet rays, and absorbs ultraviolet rays, converts them into infrared rays or visible rays, and emits them.

Examples of the ultraviolet absorber include amino benzoic acid derivatives such as p-aminobenzoic acid, ethyl p-aminobenzoate, glyceryl p-aminobenzoate and amyl p-dimethylaminobenzoate; Salicylic acid derivatives such as ethylene glycol salicylate, dipropylene glycol salicylate, octyl salicylate, and myristyl salicylate; Cinnamic acid derivatives such as methyl diisopropylterephosphate, ethyl p-methoxy cinnamate, isopropyl p-methoxy cinnamate, 2-ethylhexyl p-methoxy cinnamate, and butyl p-methoxy cinnamate; Benzophenone derivatives such as 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and 2,2'-dihydroxy-4-methoxybenzophenone; Azole compounds such as urocanic acid and ethyl urocanoate; 4-t-butyl-4'-methoxybenzoylmethane and the like.

The antimicrobial agent is a component that inhibits the growth of bacteria on the fiber and further suppresses the generation of unpleasant odors derived from the degradation products of microorganisms.

Examples of the antibacterial agent include cationic bactericides such as quaternary ammonium salts (benzalkonium chloride)

Diclonic acid, triclosan acid, bis- (2-pyridylthio-1-oxide) zinc, polyhexamethylenebiguanine hydrochloride, 8-oxyquinoline, polylysine and the like.

In addition to the above-mentioned compounds, as the function improving agent, there can be used various additives such as a shrinkage preventing agent, a laundry wrinkle preventing agent, a shape retaining agent, a drape-like preservative, an ironiness improver, an oxygen bleaching inhibitor, a brightener, a whitening agent, (2-sulfostyryl) biphenyl disodium (Chiba Specialty Chemical Co., Ltd., Chinopal BS (trade name, manufactured by Chiba Specialty Chemical Co., Ltd.) A dye fixing agent, an anti-fading agent such as 1,4-bis (3-aminopropyl) piperazine, a stain removing agent, a cellulase, amylase, protease, lipase, Silkprodene powder, a surface modification thereof, and an emulsified dispersion. Examples of the emulsifier include K-50, K-30, and the like. , K-10, A-705, S-702, L-710, FP series Nonionic polymeric compound composed of an alkylene terephthalate unit and / or an alkylene isophthalate unit and a polyoxyalkylene unit, and a silane coupling agent, , Antifouling agents such as FR627 manufactured by KAO KOGYO KABUSHIKI KAISHA, and SRC-1 manufactured by Kurari Tozan Plastics.

[PH of composition]

The pH of the liquid treating composition for a textile product of the present invention is not particularly limited. However, in the case of a liquid softening composition, from the viewpoints of suppressing the hydrolysis of the component (C) Deg.] C is preferably in the range of 1 to 6, more preferably in the range of 2 to 4.

When the liquid treating composition for a textile product of the present invention is used as a spray type fiber treating composition, the pH at 25 캜 is preferably 5 to 11, more preferably 7 to 10, from the viewpoint of enhancing the stability of the perfume .

When pH adjustment is carried out, pH adjustment may be carried out in the presence of an acid such as hydrochloric acid, sulfuric acid, phosphoric acid, alkylsulfuric acid, benzoic acid, para toluenesulfonic acid, citric acid, malic acid, lactic acid, lactic acid, glycolic acid, hydroxyethanediphosphone, phytic acid, ethylenediaminetetraacetic acid, Amine, and the like, alkali metal hydroxides such as sodium hydroxide, alkali metal carbonates, and alkali metal silicates.

[Viscosity of composition]

The viscosity of the liquid treatment composition for a textile product of the present invention is preferably less than 1000 mPa · s (B-type viscometer manufactured by TOKIMEC, 25 ° C., the same applies hereinafter) in the case of a liquid softener composition. Considering the increase in viscosity due to the storage elapsed days, the viscosity immediately after preparation is more preferably less than 800 mPa · s, further preferably less than 500 mPa · s. Within this range, usability such as handling property when put into a washing machine is good.

When the liquid treating composition for textile articles of the present invention is used as a spray type fiber treating composition, the viscosity at 25 캜 is preferably 10 mPa s or less, more preferably 5 mPa s or less, from the viewpoint of handling properties . The viscosity can be controlled by the amount of the component (B) or the amount of water.

[Manufacturing method]

The method of preparing the liquid treating composition for a textile product of the present invention is not particularly limited.

In the case of a liquid softener composition, it can be produced by a known method, for example, the same method as the conventional method for producing a liquid softener composition using a cationic surfactant as a main agent.

For example, the aqueous phase containing the component (A), the component (C), the nonionic surfactant and the component (B) is mixed under the temperature condition of the component (C) To prepare an emulsion, and then, if necessary, adding and mixing other components to the obtained emulsion. The oil phase can be prepared by mixing the components (A) and (C) with the nonionic surfactant at a temperature not lower than the melting point of the component (C) and optionally mixing the components. The water phase can be prepared by mixing optional components in accordance with the necessity of water and the component (B).

In the case of a spray-type fiber treatment composition, the composition is not particularly limited and may be prepared by a usual method. For example, by mixing each of the above components together with water in accordance with necessity.

[Application / Usage]

The use of the liquid treating composition for textile products of the present invention is not particularly limited, but it can be applied to a detergent composition, a bleaching composition, a liquid softening composition, a spray type fiber treating agent and the like. Among them, it is preferable to be applied as a liquid softener composition or a spray-type fiber treatment agent.

The method of treating a textile product such as clothes by the liquid treating composition for a textile product of the present invention is not particularly limited and can be applied to a conventional method such as a cleaning agent, a finishing agent (softener, glue agent, etc.) Can be processed.

The liquid treating composition for a textile product of the present invention is not particularly limited when it is a liquid softening composition. For example, the liquid treating composition for a textile product may be prepared by dissolving the composition of the present invention in a rinsing solution at the rinsing stage of washing, , A method of dissolving the composition of the present invention in water and a method of immersing the composition in a medical treatment. In this case, the composition is diluted to an appropriate concentration. In this case, the bath ratio (weight ratio of the treating solution to the fiber product) is preferably 3 to 100 times, particularly preferably 5 to 50 times. Concretely, when the softening treatment is carried out, it is preferably used in an amount such that the concentration of the component (C) is 0.01 ppm to 1000 ppm, more preferably 0.1 ppm to 300 ppm, do.

When the liquid treating composition for a fiber product of the present invention is used as a spray type fiber treating composition, the method of use is not particularly limited. For example, the treating composition may be contained in a trigger spraying container or a pump spraying container of a dispenser type And directly spraying on the textile product. After spraying, a drying treatment may be carried out in accordance with necessity. The fiber product is not particularly limited, and examples thereof include clothes, curtains, sofas, carpets, towels, handkerchiefs, sheets, pillow covers, and the like. The application amount of the treating agent composition to the fiber product is preferably 0.5 to 10 g, more preferably 1 to 5 g per 100 g of the fiber product.

The spray type fiber treatment agent is desirably accommodated in a trigger type spray container (hereinafter referred to as a trigger). As the trigger container, there is no particular limitation, and a trigger container used in a fiber treatment agent product generally used for giving a fragrance, a deodorizing effect, etc. to a textile product such as clothes can be used. As the trigger container used in the present invention, a trigger container of an accumulative-pressure type is preferable from the viewpoint of spraying properties, good spray pattern, and no after-draw. It is also preferable that the spraying amount is 0.2 to 0.6 g from the viewpoint of preventing the occurrence of unevenness in the fiber product sprayed with the treating composition and from the viewpoint of giving a desired effect to the hands without giving excessive fatigue.

Example

Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited thereto. In the examples, the amount of the components is expressed in% by mass (converted to pure fractions, except when specified).

[Component (A)] [

Table 1: Composition of perfume composition

[Table 1]

[Component (B)] [

B-1: Cluster dextrin (registered trademark, manufactured by Glyco Nutrition Food Co., Ltd.)

The main component of the cluster dextrin (registered trademark) is a dextrin having a molecular weight of about 30,000 to about 1,000,000, one cyclic structure in the molecule, and a plurality of glucan chains bonded to the cyclic moiety, and having a weight average polymerization degree of about 2,500. The cyclic structure portion is composed of about 16 to 100 glucose, and the cyclic structure has a plurality of non-cyclic branched glucan chains.

B-2 (comparative example):? Cyclodextrin

B-3 (comparative example):? Cyclodextrin

[Component (C)] [

C-1: Cationic surfactant (cationic surfactant described in Example 4 of Japanese Patent Application Laid-Open No. 2003-12471)

C-2: Cationic surfactant (cationic surfactant described in Example 1 of JP-A-2002-167366)

C-3: Didecyldimethyl anonium salt (trade name: Akkado 210, Lion arc irradiation)

[Other optional components]

D-1:

First-order isotridecyl alcohol Ethylene oxide 60 moles Adduct: 2%

Calcium chloride (trade name: granular calcium chloride, Tokuyama Co., Ltd.): 0.5%

· Isothiazolone solution (trade name: Kayong CG-ICP, Dow Chemical Co., Ltd.): 100 ppm *

D-2:

-Polyoxyethylene lauryl ether ethylene oxide 8 mol adduct (trade name: Newcol 1100, Nippon emulsifier): 0.2%

· Isothiazolone solution (trade name: Kayong CG-ICP, Dow Chemical Co., Ltd.) 100 ppm *

* The amount of isothiazolone solution is as it is.

[Preparation method of softener composition]

The blending amounts of the respective components were adjusted as described in Tables 2 and 3 below to prepare liquid softener compositions according to the following procedure.

The liquid softener composition was prepared by using a glass container having an inner diameter of 100 mm and a height of 150 mm and an agitator (Ajita SJ type, manufactured by Shimadzu Corporation) according to the following procedure. First, a component (A), a component (C), and a 60-moles adduct of primary isotridecyl alcohol ethylene oxide, which is an optional component, were mixed and stirred to obtain an oil-in-water mixture. On the other hand, the component (B) and the isothiazolone solution as an optional ingredient were dissolved in purified water for balance to obtain an aqueous mixture. Here, the mass of the ion exchange water for balance corresponds to the remainder obtained by subtracting the total mass of the oil-based mixture and (B) at 980 g. Next, the aqueous mixture heated to the melting point of the component (C) or higher was charged into a glass container and stirred while being heated to the melting point of the component (C), and the aqueous mixture was divided into two portions and stirred. Here, the division ratio of the water-based mixture was 30:70 (mass ratio), and the stirring was performed at a rotation speed of 1,000 rpm for 3 minutes after the first addition of the water-based mixture and for 2 minutes after the second addition of the water-based mixture. Then, calcium chloride as an optional ingredient is added and, if necessary, the pH is adjusted to 2.5 by adding hydrochloric acid (1 mol / l of reagent, Kanto Chemical) or sodium hydroxide (1 mol / l of reagent, And ion-exchanged water was added thereto so as to have a mass of 1,000 g to obtain a desired liquid softener composition.

[Method for preparing spray-type fiber treatment composition]

The amount of each component was adjusted as shown in Tables 4 and 5 below to prepare a liquid softener composition according to the following procedure.

A 500 ml beaker was used to mix an aqueous solution of the component (B) with a solution of the component (A) dissolved in an optional component of ethanol, and ion-exchanged water (total amount of 400 g ) Was added under stirring conditions to obtain a desired spray-type fiber treating composition.

[Evaluation of fidelity and reverberation]

1. Pretreatment method for cotton (cotton) meriyasu cloth (cloth)

(VH-30S manufactured by Toshiba) using a commercially available detergent " Top Platinum Clear " (manufactured by Lion Corporation) for 2 minutes to 10 cm x 10 cm. (The standard amount of detergent used, the bath ratio of 30 times, the tap water at 50 DEG C, the washing time of 10 minutes, the water injection (rinsing) and the rinsing for 10 minutes twice).

2. Softener treatment in rinsing process during washing

The odor of the cotton knitted fabric and the odor of the softener composition after washing using the prepared fabric softener composition as described above was evaluated by sensory evaluation on the following criteria by the panelists. Value of commodity (above commodity value), △ or more.

In addition, the aroma of the cotton knitted fabric after drying was evaluated by a six-step odor strength method using the following criteria. Commodity value, △ or more.

The treatment was carried out by using a two-piece washing machine (VH-30S manufactured by Toshiba) and washing with a commercially available cleaner "Top Platinum Clear" (manufactured by Lion Corporation) for 10 minutes (standard use amount, standard course, After rinsing for 3 minutes, the composition was subjected to a softening treatment (using 10 ml of the composition, 10 ml of the composition, 20 times of the bath ratio, and tap water at 25 캜) for 1.5 minutes in the composition for 3 minutes in the second rinse. And dehydration was performed for one minute between each step of washing and rinsing. After the treatment, it was dried for 20 hours under constant temperature and humidity conditions of 20 ° C and 45% RH.

3. Spray spraying

The spray-type fiber treatment composition prepared as described above was filled in a trigger container and sprayed. After the drying, the smell of the cotton-knitted fabric and the smell of the spray-type textile treatment composition were sensed by the panelists 15 on the basis of the following criteria. Commodity value, △ or more.

In addition, the aroma of the cotton knitted fabric after drying was evaluated by the panelists 15 in the six-step odor strength method according to the following criteria. Commodity value, △ or more.

As the trigger container, a container of a commercially available clothes care agent (product name: "style guard wrinkle cleaner spray", manufactured by Lion Corporation) was taken out, washed well, and dried sufficiently Prepared. The spray type fiber treatment composition was filled in a trigger container and sprayed to the evaluation bottle so that the amount (amount) of 2% owf (= weight (g) of the treatment composition / weight (g) Respectively. After the treatment, it was dried for 20 hours under constant temperature and humidity conditions of 20 占 폚 and 45 占 폚 RH.

<Evaluation Criteria>

(1) The odor of the cotton knitted fabric and the softener composition

◎ ◎ ◎: 14 or more of 15 persons who evaluated that the smell of cotton fabric softener composition was the same

◎ ◎: 11 to 13 out of 15 people evaluated that the smell of cotton fabric softener composition was the same

&Amp; cir &amp;: The ratio of the smell of the cotton fabric to the softener composition was 8 to 15

○: 5 to 7 out of 15 people evaluated as having the same smell as cotton fabric softener composition

?: 2 to 4 out of 15 people evaluated that the smell of cotton fabric softener composition was the same as that of softener composition

X: 1 or less of 15 persons evaluated as having the same smell as cotton fabric softener composition

(2) Fragrance (effect of improving reverberation)

When evaluated by the six-stage odor intensity method (0: odorless, 1: very weak, 2: weak, 3: easily detectable, 4: strong,

&Amp; cir &amp;: The score (score when the component (B) is included) - (score when the component (B)

: &Quot; (score when the component (B) is included) - (score when the component (B) is not included) is 0.3 or more and less than 0.4

?: Score (score when the component (B) is included) - score (score when the component (B) is not included) is 0.2 or more and less than 0.3

?: Score (score when the component (B) is included) - score of 0.1 when the component (B) is not included) to less than 0.2

?: Score of (when the component (B) is included) - (score of when the component (B) is not included) is 0 or more and less than 0.1

X: (score when the component (B) is included) - (score when the component (B) is not included) is less than 0

Table 2: Composition of the softener composition (% by mass)

[Table 2]

* Describe the blending amount as it is.

Table 3: Composition of the softener composition (% by mass)

[Table 3]

* Describe the blending amount as it is.

Table 4: Composition of spray-type fiber treatment composition (% by mass)

[Table 4]

* Describe the blending amount as it is.

Table 5: Composition of spray-type fiber treatment composition (numerical value of composition is% by mass)

[Table 5]

* Describe the blending amount as it is.

Claims (3)

(A) a perfume composition,
(B) having a branching cyclic structure portion and an outer branching structure portion, wherein the branched branched cyclic structure portion is a glucan having a degree of polymerization of 50 to 10000, wherein the branched branched cyclic structure portion is an α-1,4- , 6-glucoside bond, and the outer branch structure portion is glucan, which is an acyclic structure portion bound to the inner branched ring structure portion, and
(C) a cationic surface active agent. The method according to claim 1,
Wherein the component (A) contains a perfume component having a ClogP value of 5 or less or a perfume component having a cyclic structure in the structure. 3. The method according to claim 1 or 2,
(C) is selected from an amine compound having from 1 to 3 hydrocarbon groups having 10 to 26 carbon atoms, which may be divided into an ester group or an amide group, a salt thereof or a quaternary product thereof &Lt; / RTI &gt;