KR20150109778A - Multi-type deposition apparatus and methode thereof - Google Patents
Multi-type deposition apparatus and methode thereof Download PDFInfo
- Publication number
- KR20150109778A KR20150109778A KR1020140033058A KR20140033058A KR20150109778A KR 20150109778 A KR20150109778 A KR 20150109778A KR 1020140033058 A KR1020140033058 A KR 1020140033058A KR 20140033058 A KR20140033058 A KR 20140033058A KR 20150109778 A KR20150109778 A KR 20150109778A
- Authority
- KR
- South Korea
- Prior art keywords
- process chamber
- substrate
- chamber
- gas
- atomic layer
- Prior art date
Links
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32715—Workpiece holder
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/04—Coating on selected surface areas, e.g. using masks
- C23C16/042—Coating on selected surface areas, e.g. using masks using masks
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45544—Atomic layer deposition [ALD] characterized by the apparatus
- C23C16/45546—Atomic layer deposition [ALD] characterized by the apparatus specially adapted for a substrate stack in the ALD reactor
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/458—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for supporting substrates in the reaction chamber
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/54—Apparatus specially adapted for continuous coating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32366—Localised processing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32458—Vessel
- H01J37/32513—Sealing means, e.g. sealing between different parts of the vessel
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32532—Electrodes
- H01J37/32568—Relative arrangement or disposition of electrodes; moving means
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32623—Mechanical discharge control means
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32733—Means for moving the material to be treated
- H01J37/32743—Means for moving the material to be treated for introducing the material into processing chamber
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32733—Means for moving the material to be treated
- H01J37/32788—Means for moving the material to be treated for extracting the material from the process chamber
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32798—Further details of plasma apparatus not provided for in groups H01J37/3244 - H01J37/32788; special provisions for cleaning or maintenance of the apparatus
- H01J37/32899—Multiple chambers, e.g. cluster tools
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Vapour Deposition (AREA)
Abstract
In the present invention, a plurality of process modules each having a vacuum chamber for forming a vacuum and a vacuum chamber for pressure regulation as a basic unit are stacked on the outside of the process chamber and the process chamber, The process chamber and the vacuum chamber are designed to have the minimum space for the optimum process and the atomic layer deposition process can be simultaneously performed in the process chambers in the plurality of process modules. Thus, the amount of the raw material precursor and the reaction precursor is reduced, It minimizes the cost and improves the productivity. It is also easy to confirm the operation of the device since individual process progress or individual maintenance can be performed for each process module. In addition, the substrate or mask to be atomic layer deposition is brought into close contact with the upper process chamber or the lower process chamber in the optimized process chamber, thereby preventing deposition of the rear surface of the substrate and simultaneously forming two substrates.
Description
The present invention relates to a vapor deposition reactor and a thin film forming method using the vapor deposition reactor, and more particularly, to an atomic layer deposition (ALD) And a vacuum chamber for holding a space of the vacuum chamber in a vacuum state.
In general, a method of depositing a thin film having a predetermined thickness on a substrate such as a semiconductor substrate or a glass substrate includes physical vapor deposition (PVD) using physical collision such as sputtering, And chemical vapor deposition (CVD).
However, in recent years, as the design rule of a semiconductor device has become finer, a thin film of a fine pattern is required and a step of a region where a thin film is formed is greatly increased, so that a fine pattern of atomic layer thickness is formed very uniformly But also the use of atomic layer deposition (ALD), which is excellent in step coverage, is increasing.
This atomic layer deposition method is similar to the general chemical vapor deposition method in that it utilizes a chemical reaction between gas molecules. However, unlike conventional CVD in which a plurality of gaseous molecules are injected into a process chamber at the same time and the resulting reaction product is deposited on the substrate, the atomic layer deposition method injects a gas containing one source material into the process chamber, There is a difference in that a product by chemical reaction between the source material at the substrate surface is deposited by chemically adsorbing the substrate and then introducing a gas containing another source material into the process chamber.
The atomic layer deposition method described above can be applied to a thin film encapsulation for replacing a conventional glass envelope in an AMOLED display, a barrier film for a flexible substrate, a buffer layer for a solar cell, a ferroelectric material for a semiconductor -k) capacitor, or aluminum (Al), copper (Cu) wiring diffusion preventing film (TiN, TaN, etc.).
Such an atomic layer deposition method is a process in which single-wafer, batch-type, and substrate used in PECVD (plasma enhanced chemical vapor deposition) transport the bottom of a small reactor or a method in which a scan type reactor transports the top of a substrate have.
First, in the sheet processing system, a process is performed after one sheet of substrate is loaded. The sheet processing system is composed of a moving susceptor for input / output and heating of a substrate, a diffuser (main body of a showerhead type) have. However, in the single-wafer type, the chambers are very thick to prevent deformation of the process chambers and peripheral portions due to external atmospheric pressure during vacuum formation, and gate valves for carrying in / There is a problem that the productivity is remarkably reduced due to a rapid increase in consumption of raw precursor and reaction precursor, a rapid increase in maintenance cost, and an increase in process time due to an increase in adsorption-purge-reaction-purge time.
In order to solve the problem of increased maintenance cost and low productivity due to the large amount of raw material precursor and reaction precursor due to the large volume of atomic layer deposition equipment, And the process is performed simultaneously. This arrangement type is partially applied to a solar cell process. However, there is a problem that simultaneous film formation is performed not only on the front side but also on the back side of the substrate, a problem of uniformity and reproducibility of thin films on a large number of substrates, There is a problem that the entire ultra-large chamber must be cleaned even in the event of contamination.
Next, in the scan type reactor system, a plurality of small reactors corresponding to the length of one side of the substrate in the vacuum chamber are arranged and a substrate or a small reactor is reciprocated to form a film. However, It is known that there is a problem of low productivity due to particle issue and long deposition time due to difficulty of gas flow control of the reactor.
Accordingly, in the present invention, a plurality of process modules each having a vacuum chamber for forming a vacuum and a vacuum chamber for pressure regulation as a basic unit are stacked on the outside of the process chamber and the process chamber, The process chamber and the vacuum chamber of the module are designed to have the minimum space for the optimal process and the atomic layer deposition process can be simultaneously performed in the process chambers in the plurality of process modules, thereby reducing the amount of the raw material precursor and the reaction precursor, By minimizing the process time, it is possible to improve the productivity while reducing the cost, and it is easy to confirm the operation of the device since individual process progress or individual maintenance can be performed for each process module. The present invention also provides a multi-atomic atomic layer deposition apparatus and method for preventing deposition of a rear surface of a substrate and simultaneously depositing two substrates by bringing a substrate or a mask to be atomic layer deposition into close contact with an upper process chamber or a lower process chamber in an optimized process chamber .
The present invention is a multi-atomic atomic layer deposition apparatus, wherein a process module having a minimum process chamber and a vacuum chamber includes an upper process chamber and a lower process chamber, and is characterized in that when loading or unloading a substrate to be atomic layer deposition process A process chamber in which the upper process chamber and the lower process chamber are separated and the upper process chamber and the lower process chamber are combined to form a closed reaction space when the deposition process is performed on the substrate, And a vacuum chamber in which the chamber is vertically stacked, and the space of the process chamber is maintained in a vacuum state or a pressure can be controlled.
The upper process chamber is fixed to the vacuum chamber, and the lower process chamber moves up and down in the vacuum chamber to be coupled to or separated from the upper process chamber.
The upper process chamber may further include a gas supply unit for supplying a process gas or a purge gas to the closed reaction space on one side of the upper process chamber and a gas exhaust unit for exhausting gas supplied to the closed reaction space, Is provided on the other side of the upper process chamber.
Further, the gas supply unit is formed at an outer or central portion on a side surface or an upper surface of the upper process chamber.
An electrode for generating plasma is formed on the lower surface of the upper process chamber.
In addition, the electrode can be coupled to and separated from the insulator of the upper process chamber and the power input contact portion by the attaching / detaching device of the upper process chamber.
An electrode for generating a plasma is formed at an inlet of the gas supply unit in which the process gas or the purge gas is introduced into the closed reaction space.
The electrode is surrounded by an insulator so as to be insulated from the upper process chamber.
The gas supply unit may be formed of a diffusion space or a showerhead type diffuser for uniform gas flow on a side or a center of the upper process chamber to generate the process gas or gas in a vertical or horizontal direction on the substrate in the closed reaction space. And the purge gas is injected.
Further, the vacuum chamber may include a guide portion for stacking the process chamber in the inner space of the vacuum chamber, and for supporting or transferring the process chamber.
The vacuum chamber may include fixing means for fixing the upper process chamber and transfer means for moving the lower process chamber up and down.
The present invention also provides a method of depositing a layered atomic layer, the method comprising: loading a substrate and a mask in the process chamber; and, when the substrate and the mask are loaded, the upper process chamber and the lower process chamber of the process chamber are combined, Forming a space, and performing an atomic layer deposition process on the substrate in an enclosed reaction space.
The atomic layer deposition method may further include separating the upper process chamber and the lower process chamber from each other after the atomic layer deposition process is completed, thereby unloading the substrate.
Further, the atomic layer deposition process is performed simultaneously in the process chambers in the two or more process modules.
The atomic layer deposition process is performed separately in the process chambers of the vacuum chamber units in the two or more process modules.
The upper process chamber is fixed to the vacuum chamber, and the lower process chamber moves up and down by a transfer means provided in the vacuum chamber to be coupled to or separated from the upper process chamber.
The step of performing the atomic layer deposition step may include the steps of supplying a raw material precursor to the substrate in the reaction space through a gas supply unit formed on one side of the process chamber, Supplying a purge gas to the substrate through the gas supply unit to exhaust a raw precursor that has not been adsorbed on the substrate, and supplying the reaction precursor to the substrate through the gas supply unit after the exhaust, Forming an atomic layer thin film through a chemical reaction with the precursor and supplying a purge gas to the substrate through the gas supply unit after the formation of the atomic layer thin film to exhaust a reaction precursor that can not bind to the precursor .
Also, at least one of the raw material precursor, the reaction precursor, and the purge gas is supplied or exhausted through the shared gas pipe.
Also, at least one of the raw material precursor, the reaction precursor, and the purge gas may be supplied through a gas supply unit formed as a diffusion space or a showerhead diffuser for uniform gas flow to the side or the center of the upper process chamber, And is injected perpendicularly or horizontally to the substrate.
Generating a plasma at a lower surface of the upper process chamber corresponding to the substrate or at an inlet connected to the reaction space when the reaction precursor is supplied to the substrate; And forming an atomic layer thin film through the reaction.
According to the present invention, in atomic layer deposition, a process module having one or more process chambers housed inside of at least two stacked vacuum chambers is characterized in that in the process chamber housed in each vacuum chamber, By allowing the deposition process to be performed, it is possible to combine various processes for each process module, thereby improving equipment efficiency and individual maintenance by optimizing the process, thereby reducing cost and productivity by minimizing manpower and time for maintenance Can be improved.
In addition, the combination of optimized process modules enables simultaneous process progression in each process chamber, thereby greatly improving productivity.
Also, by minimizing the space for the process in each process chamber, it is possible to improve the productivity by reducing the adsorption time of the raw precursor, the reaction time and the purge time of the reaction precursor by optimizing the volume in the process chamber, and improving the productivity of the raw material precursor, There is an advantage that the consumption of the gas can be reduced and the cost required for the atomic layer deposition process can be reduced.
In addition, a separate external vacuum chamber configuration can simplify the process chamber and reduce weight, which can reduce the maintenance cost of the atomic layer deposition equipment and increase maintenance convenience.
In addition, in the optimized process chamber, the substrate to be atomic layer deposition is suitably brought into close contact with the upper process chamber or the lower process chamber, thereby preventing deposition on the back surface of the substrate.
In addition, the present invention can be implemented as a fixed type in which a plurality of process chambers in a vacuum chamber are fixed, thereby solving the problem of particles generated due to the difficulty of gas control due to the relative motion between the substrate and the process chamber, It is advantageous in that it can be easily applied to various process characteristics and the configuration of the substrate in the future.
1 is a configuration diagram of an atomic layer deposition apparatus according to an embodiment of the present invention;
FIG. 2 is a three-dimensional perspective view of an atomic layer deposition apparatus according to an embodiment of the present invention,
FIG. 3 is a cross-sectional view of an atomic layer deposition apparatus according to an embodiment of the present invention, showing an individual transferring and aligning apparatus or a configuration of a simultaneous transferring and aligning apparatus
4 is a perspective view of a process chamber according to an embodiment of the present invention,
5 is a detailed cross-sectional structural view of a process chamber according to an embodiment of the present invention,
FIG. 6 is a schematic cross-sectional view of a process chamber according to an embodiment of the present invention, in which the process gas is capable of cross flow or moving wave method and plasma process on a substrate,
FIG. 7 is a schematic cross-sectional view of a process chamber according to an embodiment of the present invention, which is a schematic view showing a process gas, a purge gas, a configuration of an exhaust unit, and a multi-divisional deposition process using plasma.
8 is a cross-sectional view of a process chamber according to an embodiment of the present invention.
Hereinafter, the operation principle of the present invention will be described in detail with reference to the accompanying drawings. In the following description of the present invention, detailed description of known functions and configurations incorporated herein will be omitted when it may make the subject matter of the present invention rather unclear. The following terms are defined in consideration of the functions of the present invention, and these may be changed according to the intention of the user, the operator, or the like. Therefore, the definition should be based on the contents throughout this specification.
FIG. 1 illustrates various configurations of an atomic layer deposition apparatus according to an embodiment of the present invention. The
The
Hereinafter, the structure of the atomic layer deposition apparatus 1000 of the present invention will be described in detail with reference to FIGS. 1 and 2. FIG.
First, the
Such a
The
Next, the
That is, the
1, a plurality of
FIG. 2 is a three-dimensional perspective view showing the configuration of the atomic layer deposition apparatus 1000 and the
A
FIG. 3 is a cross-sectional view of an atomic layer deposition apparatus 1000 according to an embodiment of the present invention. As shown in FIG. 3, the
4 illustrates a detailed cross-sectional structure of a process chamber according to an embodiment of the present invention.
The
4, when the
When the
At this time, the loading of the
After the
When an independent space is formed in which the
When the atomic layer deposition process for the
Referring to FIG. 4, a
A
Before the
A
FIG. 5 is a perspective view of a process chamber according to another embodiment of the present invention, showing a stereoscopic perspective view of a process chamber in which a gas supply unit is formed by a showerhead method.
Referring to FIG. 5, a
A
FIG. 6 is a schematic cross-sectional view of a process chamber according to an embodiment of the present invention, in which a process gas is jetted on a substrate in a cross flow or a traveling wave fashion.
Referring to FIG. 6, a raw material precursor, a reaction precursor, and a purge gas are introduced into a
Hereinafter, the operation of the
After the adsorption is completed, purge gas (Ar, O 2 , N 2 , N 2 O, etc.) is supplied to the
After the thin film is formed on the
At this time, in order to smoothly react the reaction precursor and improve the thin film characteristics, a heater function is applied to the
Hereinafter, the atomic layer deposition process in the
First, when the
At this time, when the precursor material is injected onto the
Next, in a third step of the atomic layer deposition process, the reaction precursor is supplied through the
By repeating the above-described four-step atomic layer deposition process in one cycle, the atomic layer thin film is formed on the
At this time, in the above-described atomic layer deposition process, the
An
First, the precursor of the raw material is supplied to the
After the adsorption of the raw precursor is completed, a purge gas is supplied to the
Subsequently, the reaction precursor is supplied to the
In order to minimize the influence of the
The precursor of the raw material precursor, the precursor precursor and the purge gas are sequentially supplied to the
Also, in order to minimize contamination of the
The raw precursor, the reaction precursor and the purge gas are supplied to the
Further, the exhaust region close to the
In addition, in order to prevent damage to the lower film due to damage to the lower film due to a material difficult to be directly applied to the plasma or ions or electrons, a gap insulator 1312 is provided between the
7 is a cross-sectional view of a
Sectional area of the large-area substrate without applying a mask to the large-area substrate.
Referring to FIG. 7, the
The reaction precursor and the purge gas are sequentially injected onto the
At this time, each atomic layer deposition unit 1340 has a gas supply unit 1312 for supplying a process gas onto the
In addition, it is possible to make the gas flow as uniform as possible through the showerhead type diffuser, the center hole diffuser, the slit type diffuser, etc., and the process using direct plasma or indirect plasma generated by supplying power to each diffuser becomes possible.
7, in the basic structure for multi-division film formation,
A purge
In FIG. 7, the shower head type diffuser and the center hole diffuser are shown as an example, but various combinations of the shower head type diffuser and the center hole diffuser are possible.
Accordingly, exposure, diffusion, and residual gas can be prevented from being generated outside the film forming region when the raw material precursor, the reaction precursor, and the purge gas are supplied. Accordingly, even when a mask for separating the film forming region of the large- The film formation can be performed.
FIG. 8 is a detailed cross-sectional view of a
8, a gas supply unit 1312 for supplying a process gas onto the
It is possible to constitute a
At this time, if the
8, the
8, the attachment /
At this time. The attachment /
As described above, in the present invention, in the atomic layer deposition, a plurality of unit process chambers for the atomic layer deposition process capable of separating and bonding upper and lower parts are arranged in a stacked manner, and a plurality of process chambers It is possible to simultaneously carry out the atomic layer deposition process in a plurality of process chambers which are realized to have a vacuum chamber for vacuum formation and pressure regulation outside and a minimum space for the optimal process so that the raw material precursor and the reaction precursor Reduce usage and minimize process time to reduce costs and improve productivity. In addition, according to the present invention, the substrate to be atomic layer deposition is completely brought into close contact with the upper process chamber or the lower process chamber in the optimized process chamber, thereby preventing deposition on the back surface of the substrate.
While the invention has been shown and described with reference to certain preferred embodiments thereof, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention. For example, although the operation of the atomic layer deposition apparatus is described by way of example in the embodiment of the present invention, the present invention is equally applicable to PECVD.
Accordingly, the scope of the invention should not be limited by the described embodiments but should be defined by the appended claims.
1100: Vacuum chamber 1200: Process chamber
1010: substrate 1015: substrate support
1017: mask supporting portion 1020: mask
1030: plasma 1101: buffer part
1110: Lower process chamber transfer part 1111: Alignment device part
1112: alignment device auxiliary part 1120: susceptor support part
1202: multi-stage supporting portion 1204:
1210: upper process chamber 1220: lower process chamber
1211: gas exhaust part 1212: gas supply part
1221: base sealing part 1222: additional sealing part
1300: Process module 1312: Diffuser
1313: Electrode 1314: Insulator
1315: Electrode fastening part 1412: Purge gas supply part
1414: Gap insulator 1415: Pressure regulating gas supply part
1416: Displacement attachment unit
Claims (24)
And a process chamber including a vacuum chamber for holding a space of the process chamber in a vacuum state is stacked in a vertical direction.
Wherein at least two process modules including an individual vacuum chamber for holding a space of the process chamber in a vacuum state are laminated in a vertical direction.
Further comprising an alignment device for securing and positioning the substrate and the mask precisely before the upper process chamber and the lower process chamber are coupled to each other.
The alignment apparatus may further comprise:
An atomic layer deposition apparatus including a mask unit or a control unit capable of controlling the rotation of the mask unit or the substrate unit in the left, right, front, and rear directions using an image information processing (vision)
Wherein an electrode for plasma generation is formed on a lower surface of the upper process chamber by an insulator, a contact power supply unit, and a detachable device.
Wherein an apparatus section capable of adjusting a displacement according to a pressure is provided in a gas exhausting portion of the upper process chamber to sequentially increase a deposition region by controlling a surface area of the process gas to completely seal the deposition material layer, Deposition apparatus
The vacuum chamber includes:
Wherein a vacuum is formed in an outer space of the process chamber or is converted into an atmospheric air, and a maintenance opening / closing unit for each process module is constituted.
The vacuum chamber includes:
And a guide part for supporting, loading / unloading or transporting the process chamber to / from the internal space of the vacuum chamber.
The vacuum chamber includes:
A fixing means for fixing the upper process chamber, and a transfer means for moving the lower process chamber up and down.
Wherein the upper process chamber is fixed to the vacuum chamber and the lower process chamber moves up and down in the vacuum chamber to be coupled to or separated from the upper process chamber.
Further comprising a device having a tension control function capable of maintaining an equal bonding force of the entire area when the upper process chamber and the lower process chamber are moved up and down and capable of buffering an excessive bonding force of a specific region. Layer deposition apparatus.
The device having a tension adjusting function is formed by a combination of an O-ring, a spring, a C-shaped block having self-elasticity, or a combination of components capable of varying a certain range of external force such as a membrane or a tube having an expanding and contracting function by external pressure Lt; / RTI >
And a measuring device such as a load cell or a pressure gauge for measuring an excessive bonding force of a specific portion and maintaining an equal bonding force of the entire area when the upper process chamber and the lower process chamber are coupled by moving them up and down. Wherein the atomic layer deposition apparatus further comprises a function of controlling the tension.
A gap block replacement device having a predetermined thickness for adjusting the gap required when the process chamber and the lower process chamber are coupled to each other by moving the process chamber up and down or a membrane capable of expanding and contracting by an external pressure difference between two gaps And the gap can be adjusted according to the pressure control applied to the membrane.
The process chamber includes:
A gas supply part for supplying a process gas or a purge gas to the sealed reaction space is provided on one side of the process chamber,
And a gas exhaust part for exhausting the gas supplied to the closed reaction space is provided on the other side of the process chamber.
Wherein an electrode for plasma generation is formed at an introduction portion of a gas supply portion into which the process gas is introduced into a sealed reaction space.
The gas-
A diffusion space of a V, W, VVV, U shape or a showerhead type diffuser for uniform gas flow inside the upper process chamber to form a process gas in the vertical or horizontal direction on the substrate in the closed reaction space, Or the purge gas is injected.
Wherein the process chamber further comprises a heating and temperature control device in the process chamber to prevent condensation or by-products of the process gas or purge gas or exhaust gas.
Wherein a supply pipe or an exhaust pipe is used in which the process gas supply unit or the purge gas supply unit or the gas exhaust unit of the process chamber is shared with at least one or more other process chambers.
A stepped stepped portion is formed outside the coupling portion of the upper process chamber and the lower process chamber for minimizing the deposition area except for the substrate when the process chamber and the lower process chamber are moved up and down, And supplying a predetermined amount of purge gas to the outside of the substrate to minimize deposition on one side including the sealing portion excluding the substrate.
A vacuum chamber is an atomic layer deposition method performed in a multi-atomic atomic layer deposition apparatus having at least one or more process chambers,
A substrate and a mask are loaded in the process chamber; and when the substrate and the mask are aligned and precisely aligned by an alignment device including an image information processing device and the like,
Forming an enclosed reaction space by combining an upper process chamber and a lower process chamber; and performing an atomic layer deposition process for the substrate in the closed reaction space.
The upper process chamber and the lower process chamber each mounting the substrate,
And a controller for controlling the temperature of the reaction chamber,
The deposition process being performed simultaneously on the substrate and the substrate mounted on the lower process chamber
And an atomic layer deposition apparatus.
The upper process chamber is divided into at least two regions with respect to the substrate
Wherein the atomic layer deposition process unit includes at least two atomic layer deposition processes capable of performing atomic layer deposition processes for each of the plurality of atomic regions, wherein the atomic layer deposition process unit includes a gas supply unit and a gas exhaust unit.
The selection of the deposition material or the deposition method or the maintenance of the process chamber may be performed simultaneously or separately for each unit process module including the vacuum chamber. In order to minimize the external influence of each process module, And a buffer space for pressure control and rigidity reinforcement.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020140033058A KR101634694B1 (en) | 2014-03-21 | 2014-03-21 | Multi-type deposition apparatus and methode thereof |
PCT/KR2015/002783 WO2015142131A1 (en) | 2014-03-21 | 2015-03-21 | Multi-type deposition apparatus and thin-film forming method using same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020140033058A KR101634694B1 (en) | 2014-03-21 | 2014-03-21 | Multi-type deposition apparatus and methode thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20150109778A true KR20150109778A (en) | 2015-10-02 |
KR101634694B1 KR101634694B1 (en) | 2016-06-29 |
Family
ID=54144990
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020140033058A KR101634694B1 (en) | 2014-03-21 | 2014-03-21 | Multi-type deposition apparatus and methode thereof |
Country Status (2)
Country | Link |
---|---|
KR (1) | KR101634694B1 (en) |
WO (1) | WO2015142131A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112609170B (en) * | 2020-11-24 | 2022-12-09 | 鑫天虹(厦门)科技有限公司 | Atomic layer deposition apparatus and process |
CN114807906B (en) * | 2022-06-27 | 2022-09-16 | 江苏邑文微电子科技有限公司 | Atomic layer deposition equipment |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010106297A (en) * | 2008-10-29 | 2010-05-13 | Dainippon Printing Co Ltd | Mask alignment device |
KR101044913B1 (en) | 2009-07-14 | 2011-06-28 | 신웅철 | Batch type ald |
KR20110092825A (en) * | 2010-02-10 | 2011-08-18 | 세메스 주식회사 | Plasma processing apparatus and method |
KR20120110823A (en) * | 2011-03-30 | 2012-10-10 | (주)세미머티리얼즈 | Multi layer type thin film deposition apparatus with a function of improved film uniformity |
KR20120140627A (en) * | 2011-06-21 | 2012-12-31 | 도쿄엘렉트론가부시키가이샤 | Batch type processing apparatus |
KR20130062374A (en) | 2010-10-18 | 2013-06-12 | 시너스 테크놀리지, 인코포레이티드 | Deposition of layer using depositing apparatus with reciprocating susceptor |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100568456B1 (en) * | 2003-12-15 | 2006-04-07 | 주식회사 테라세미콘 | Semiconductor manufacturing System and Wafer-Film manufacturing Method |
KR101046611B1 (en) * | 2008-12-29 | 2011-07-06 | 주식회사 케이씨텍 | Batch Type Atomic Layer Deposition System |
-
2014
- 2014-03-21 KR KR1020140033058A patent/KR101634694B1/en active IP Right Grant
-
2015
- 2015-03-21 WO PCT/KR2015/002783 patent/WO2015142131A1/en active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010106297A (en) * | 2008-10-29 | 2010-05-13 | Dainippon Printing Co Ltd | Mask alignment device |
KR101044913B1 (en) | 2009-07-14 | 2011-06-28 | 신웅철 | Batch type ald |
KR20110092825A (en) * | 2010-02-10 | 2011-08-18 | 세메스 주식회사 | Plasma processing apparatus and method |
KR20130062374A (en) | 2010-10-18 | 2013-06-12 | 시너스 테크놀리지, 인코포레이티드 | Deposition of layer using depositing apparatus with reciprocating susceptor |
KR20120110823A (en) * | 2011-03-30 | 2012-10-10 | (주)세미머티리얼즈 | Multi layer type thin film deposition apparatus with a function of improved film uniformity |
KR20120140627A (en) * | 2011-06-21 | 2012-12-31 | 도쿄엘렉트론가부시키가이샤 | Batch type processing apparatus |
Also Published As
Publication number | Publication date |
---|---|
WO2015142131A1 (en) | 2015-09-24 |
KR101634694B1 (en) | 2016-06-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5243525B2 (en) | Flat substrate processing equipment | |
US20080241384A1 (en) | Lateral flow deposition apparatus and method of depositing film by using the apparatus | |
US6902624B2 (en) | Massively parallel atomic layer deposition/chemical vapor deposition system | |
US20160013086A1 (en) | Substrate processing device | |
US20150144060A1 (en) | Cluster-batch type system for processing substrate | |
WO2010035773A1 (en) | Film formation device and substrate processing apparatus | |
US11776828B2 (en) | Vacuum processing device | |
JP2010526446A5 (en) | ||
KR101486937B1 (en) | Atomic layer deposition apparatus and method thereof | |
EP2465972B1 (en) | Method and system for thin film deposition | |
WO1999010558A1 (en) | Vertically-stacked process reactor and cluster tool system for atomic layer deposition | |
KR101787825B1 (en) | Film forming apparatus and film forming method | |
CN109750277B (en) | Apparatus and method for isolating a reaction chamber from a loading chamber with reduced contamination | |
US11404299B2 (en) | Substrate transfer mechanism, substrate processing apparatus, and substrate processing method | |
KR20100106614A (en) | Atomic deposition apparatus and atomic layer deposition method | |
KR101525210B1 (en) | Apparatus for processing substrate | |
US20110100296A1 (en) | Film formation apparatus | |
KR101634694B1 (en) | Multi-type deposition apparatus and methode thereof | |
KR101579527B1 (en) | Atomic layer deposition apparatus with scan-type reactor and method thereof | |
KR101321331B1 (en) | The system for depositing the thin layer | |
KR20150028574A (en) | Stack-type atomic layer deposition apparatus and method thereof | |
KR101512140B1 (en) | Atomic layer deposition apparatus and method thereof | |
KR20140140462A (en) | Atomic Layer Deposition Apparatus | |
JP2004006665A (en) | Vacuum processing device | |
KR101569768B1 (en) | Atomic layer deposition apparatus and method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20190623 Year of fee payment: 4 |