KR20140135199A - Z-1,1,1,4,4,4-헥사플루오로-2-부텐 및 e-1,1,1,4,4,4-헥사플루오로-2-부텐의 공비-유사 조성물 및 그의 용도 - Google Patents

Z-1,1,1,4,4,4-헥사플루오로-2-부텐 및 e-1,1,1,4,4,4-헥사플루오로-2-부텐의 공비-유사 조성물 및 그의 용도 Download PDF

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KR20140135199A
KR20140135199A KR20147025469A KR20147025469A KR20140135199A KR 20140135199 A KR20140135199 A KR 20140135199A KR 20147025469 A KR20147025469 A KR 20147025469A KR 20147025469 A KR20147025469 A KR 20147025469A KR 20140135199 A KR20140135199 A KR 20140135199A
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South Korea
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composition
azeotrope
1336mzz
hfo
foam
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Korean (ko)
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마크 엘. 로빈
조셉 안토니 크레아쪼
개리 로
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이 아이 듀폰 디 네모아 앤드 캄파니
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Application filed by 이 아이 듀폰 디 네모아 앤드 캄파니 filed Critical 이 아이 듀폰 디 네모아 앤드 캄파니
Publication of KR20140135199A publication Critical patent/KR20140135199A/ko
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143Halogen containing compounds
    • C08J9/144Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0028Liquid extinguishing substances
    • A62D1/0057Polyhaloalkanes
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0071Foams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/14Manufacture of cellular products
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203Polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/34Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348Hydroxycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/71Monoisocyanates or monoisothiocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/007Organic compounds containing halogen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/30Materials not provided for elsewhere for aerosols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/04Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B39/00Evaporators; Condensers
    • F25B39/02Evaporators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/56Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances gases
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/14Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • C08J2375/08Polyurethanes from polyethers
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/12Hydrocarbons
    • C09K2205/126Unsaturated fluorinated hydrocarbons
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    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/22All components of a mixture being fluoro compounds
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    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/32The mixture being azeotropic

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Emergency Management (AREA)
  • Business, Economics & Management (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Dispersion Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fire-Extinguishing Compositions (AREA)
  • Detergent Compositions (AREA)
KR20147025469A 2012-02-17 2013-02-14 Z-1,1,1,4,4,4-헥사플루오로-2-부텐 및 e-1,1,1,4,4,4-헥사플루오로-2-부텐의 공비-유사 조성물 및 그의 용도 Withdrawn KR20140135199A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261599993P 2012-02-17 2012-02-17
US61/599,993 2012-02-17
PCT/US2013/026133 WO2013123184A1 (en) 2012-02-17 2013-02-14 Azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene and e-1,1,1,4,4,4-hexafluoro-2-butene and uses thereof

Publications (1)

Publication Number Publication Date
KR20140135199A true KR20140135199A (ko) 2014-11-25

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ID=47755043

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Application Number Title Priority Date Filing Date
KR20147025469A Withdrawn KR20140135199A (ko) 2012-02-17 2013-02-14 Z-1,1,1,4,4,4-헥사플루오로-2-부텐 및 e-1,1,1,4,4,4-헥사플루오로-2-부텐의 공비-유사 조성물 및 그의 용도

Country Status (17)

Country Link
US (1) US20150014606A1 (enExample)
EP (1) EP2814580A1 (enExample)
JP (1) JP2015514814A (enExample)
KR (1) KR20140135199A (enExample)
CN (1) CN104114243A (enExample)
AU (1) AU2013221529B2 (enExample)
BR (1) BR112014020279A8 (enExample)
CA (1) CA2864802A1 (enExample)
CL (1) CL2014002165A1 (enExample)
CO (1) CO7061091A2 (enExample)
HK (1) HK1199854A1 (enExample)
IN (1) IN2014DN06771A (enExample)
MX (1) MX2014009826A (enExample)
PE (1) PE20142140A1 (enExample)
RU (1) RU2014137471A (enExample)
SG (1) SG11201404893PA (enExample)
WO (1) WO2013123184A1 (enExample)

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WO2014070838A1 (en) 2012-10-30 2014-05-08 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Fluorocarbon molecules for high aspect ratio oxide etch
JP2016087478A (ja) * 2014-10-29 2016-05-23 旭硝子株式会社 固形物の粉砕および/または混練用分散媒体組成物
ES2886899T3 (es) * 2015-02-06 2021-12-21 Chemours Co Fc Llc Composiciones que comprenden E-1,1,1,4,4,4-hexafluoro-2-buteno y usos del mismo
EP3253844B1 (en) * 2015-02-06 2022-06-22 The Chemours Company FC, LLC Compositions comprising z-1,1,1,4,4,4-hexafluoro-2-butene and uses thereof
US9944839B2 (en) 2015-04-27 2018-04-17 Trane International Inc. Refrigerant compositions
CN107810247B (zh) 2015-04-27 2021-03-30 特灵国际有限公司 改善制冷剂混合物和/或共沸混合物中的滑移,r123制冷剂的替代品及其制冷剂组合物、方法和系统
KR102625643B1 (ko) 2017-06-07 2024-01-15 쓰리엠 이노베이티브 프로퍼티즈 컴파니 침지 냉각용 유체
CA3077388C (en) * 2017-10-10 2024-04-09 The Chemours Company Fc, Llc Process for the manufacture of thermoplastic foam containing hfo-1336mzz(z) and hfo-1336mzz(e)
CN113316626B (zh) * 2019-01-17 2023-10-27 科慕埃弗西有限公司 包含(e)-1,1,1,4,4,4-六氟丁-2-烯的共沸物和类共沸物组合物
ES2781127A1 (es) * 2019-02-27 2020-08-28 Ormazabal Corporate Tech A I E Sistema de aislamiento eléctrico de bajo impacto ambiental para aparamenta eléctrica de media y alta tensión
EP4235702A4 (en) * 2020-10-22 2024-07-24 Agc Inc. ELECTRICAL EQUIPMENT

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US4394491A (en) 1980-10-08 1983-07-19 The Dow Chemical Company Addition polymerizable adduct of a polymeric monoahl and an unsaturated isocyanate
US5164419A (en) 1991-05-20 1992-11-17 E. I. Du Pont De Nemours And Company Blowing agent and process for preparing polyurethane foam
DE4305163A1 (de) 1993-02-19 1994-08-25 Bayer Ag Verfahren zur Herstellung von Hexafluorbuten
US8618339B2 (en) 2007-04-26 2013-12-31 E I Du Pont De Nemours And Company High selectivity process to make dihydrofluoroalkenes
JP5624882B2 (ja) * 2007-04-27 2014-11-12 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company Z−1,1,1,4,4,4−ヘキサフルオロ−2−ブテンの共沸および共沸様組成物
BR122018074416B1 (pt) * 2007-06-12 2019-03-19 E. I. Du Pont De Nemours And Company Composição e processo para produzir refrigeração
US7795482B2 (en) * 2007-07-03 2010-09-14 E. I. Du Pont De Nemours And Company Method of hydrodechlorination to produce dihydrofluorinated olefins
KR20100063027A (ko) * 2007-07-20 2010-06-10 이 아이 듀폰 디 네모아 앤드 캄파니 조성물 및 폴리아이소시아네이트계 폼의 제조에서 트랜스-1,1,1,4,4,4-헥사플루오로-2-부텐 폼-형성 조성물의 용도
KR101527244B1 (ko) * 2007-09-06 2015-06-08 이 아이 듀폰 디 네모아 앤드 캄파니 E-1,1,1,4,4,5,5,5-옥타플루오로-2-펜텐의 공비 및 공비-유사 조성물
EP2164917B1 (en) * 2008-03-07 2019-04-24 Arkema Inc. Halogenated alkene heat transfer compositions with improved oil return
AU2009259965B2 (en) * 2008-06-20 2015-08-27 E. I. Du Pont De Nemours And Company Azeotropic and azeotrope-like compositions of Z-1,1,1,4,4,4-hexafluoro-2-butene
BRPI1010133A2 (pt) * 2009-06-03 2016-03-15 Du Pont "aparelho resfriador, método para a produção de resfriamento no aparelho resfriador e utilização do cis-hfo-1336mzz"
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CA2774202C (en) * 2009-09-16 2017-11-28 E. I. Du Pont De Nemours And Company Composition comprising cis-1,1,1,4,4,4-hexafluoro-2-butene and trans-1,2-dichloroethylene, apparatus containing same and methods of producing cooling therein
US20110144216A1 (en) * 2009-12-16 2011-06-16 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
US8426655B2 (en) * 2010-03-26 2013-04-23 Honeywell International Inc. Process for the manufacture of hexafluoro-2-butene
JP5598910B2 (ja) * 2010-06-14 2014-10-01 独立行政法人産業技術総合研究所 フッ素化合物の製造方法
US9003797B2 (en) * 2011-11-02 2015-04-14 E L Du Pont De Nemours And Company Use of compositions comprising 1,1,1,2,3-pentafluoropropane and optionally Z-1,1,1,4,4,4-hexafluoro-2-butene in power cycles

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Publication number Publication date
HK1199854A1 (en) 2015-07-24
PE20142140A1 (es) 2015-01-04
IN2014DN06771A (enExample) 2015-05-22
US20150014606A1 (en) 2015-01-15
WO2013123184A1 (en) 2013-08-22
JP2015514814A (ja) 2015-05-21
CN104114243A (zh) 2014-10-22
RU2014137471A (ru) 2016-04-10
EP2814580A1 (en) 2014-12-24
CO7061091A2 (es) 2014-09-19
BR112014020279A2 (enExample) 2017-06-20
CL2014002165A1 (es) 2015-01-09
SG11201404893PA (en) 2014-09-26
AU2013221529A1 (en) 2014-08-28
CA2864802A1 (en) 2013-08-22
AU2013221529B2 (en) 2016-07-07
BR112014020279A8 (pt) 2017-07-11
MX2014009826A (es) 2014-09-11

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