KR20120112607A - (메트)아크릴로일-아지리딘 가교결합제 및 접착성 중합체 - Google Patents
(메트)아크릴로일-아지리딘 가교결합제 및 접착성 중합체 Download PDFInfo
- Publication number
- KR20120112607A KR20120112607A KR1020127018975A KR20127018975A KR20120112607A KR 20120112607 A KR20120112607 A KR 20120112607A KR 1020127018975 A KR1020127018975 A KR 1020127018975A KR 20127018975 A KR20127018975 A KR 20127018975A KR 20120112607 A KR20120112607 A KR 20120112607A
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- South Korea
- Prior art keywords
- meth
- weight
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- monomer
- acrylate
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- 239000002998 adhesive polymer Substances 0.000 title description 5
- 239000000203 mixture Substances 0.000 claims abstract description 78
- 239000002253 acid Substances 0.000 claims abstract description 56
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- 239000004971 Cross linker Substances 0.000 claims abstract description 41
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- 239000000178 monomer Substances 0.000 claims description 132
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- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 7
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
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- 125000002947 alkylene group Chemical group 0.000 claims description 4
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- 239000000123 paper Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000005561 phenanthryl group Chemical group 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000011417 postcuring Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- 125000001325 propanoyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- YLQLIQIAXYRMDL-UHFFFAOYSA-N propylheptyl alcohol Chemical compound CCCCCC(CO)CCC YLQLIQIAXYRMDL-UHFFFAOYSA-N 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 125000000168 pyrrolyl group Chemical group 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 125000006413 ring segment Chemical group 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000011593 sulfur Chemical group 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 125000000335 thiazolyl group Chemical group 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- 239000011850 water-based material Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D203/00—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom
- C07D203/04—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings
- C07D203/06—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D203/08—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesive Tapes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910261937.3 | 2009-12-23 | ||
| CN200910261937.3A CN102108133B (zh) | 2009-12-23 | 2009-12-23 | (甲基)丙烯酰基-氮丙啶交联剂和粘合剂聚合物 |
| US12/849,878 | 2010-08-04 | ||
| US12/849,878 US8263711B2 (en) | 2009-12-23 | 2010-08-04 | (Meth)acryloyl-aziridine crosslinking agents and adhesive polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20120112607A true KR20120112607A (ko) | 2012-10-11 |
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| KR1020127018975A Withdrawn KR20120112607A (ko) | 2009-12-23 | 2010-12-14 | (메트)아크릴로일-아지리딘 가교결합제 및 접착성 중합체 |
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| US (1) | US8263711B2 (enExample) |
| EP (1) | EP2516391B1 (enExample) |
| JP (1) | JP2013515819A (enExample) |
| KR (1) | KR20120112607A (enExample) |
| CN (1) | CN102108133B (enExample) |
| WO (1) | WO2011087664A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102495336B1 (ko) * | 2021-11-26 | 2023-02-06 | 울산과학기술원 | 아지리딘기를 함유하는 고분자 브러시를 포함하는 가교제, 이의 제조방법 및 이의 용도 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8067504B2 (en) * | 2009-08-25 | 2011-11-29 | 3M Innovative Properties Company | Acrylic pressure-sensitive adhesives with acylaziridine crosslinking agents |
| US10029816B2 (en) | 2010-05-26 | 2018-07-24 | Avery Dennison Retail Information Services, Llc | Pressure sensitive labels for use in a cold transfer method and process for making |
| CN103282429B (zh) | 2010-12-29 | 2015-11-25 | 3M创新有限公司 | 具有三嗪-环氧交联体系的压敏粘合剂 |
| US10563102B2 (en) | 2012-10-31 | 2020-02-18 | Avery Dennison Retail Information Services Llc | Wash durable cold apply adhesive for apparel labeling and embellishment |
| CN104837949A (zh) * | 2012-12-14 | 2015-08-12 | 3M创新有限公司 | 通过使用电离辐射聚合烯键式不饱和材料来制备封装的粘弹性组合物的方法 |
| WO2014116461A1 (en) | 2013-01-24 | 2014-07-31 | 3M Innovative Properties Company | Photoinitiated oligomerization of methacrylate esters |
| US9475967B2 (en) | 2013-04-15 | 2016-10-25 | 3M Innovative Properties Company | Adhesives comprising crosslinker with (meth)acrylate group and olefin group and methods |
| EP2886620B1 (en) * | 2013-12-18 | 2019-11-27 | 3M Innovative Properties Company | Post-curable pressure-sensitive adhesive |
| JP6369023B2 (ja) * | 2014-01-08 | 2018-08-08 | 東洋インキＳｃホールディングス株式会社 | 反応性モノマーおよびそれを用いてなる樹脂組成物 |
| EP3122833B1 (en) | 2014-03-26 | 2020-01-01 | 3M Innovative Properties Company | Ultraviolet cured (meth)acrylate pressure-sensitive adhesive composition and process for producing thereof |
| CN104449426B (zh) * | 2014-11-20 | 2016-07-06 | 北京天山新材料技术有限公司 | 一种可紫外光固化耐高温压敏胶 |
| CN104559827B (zh) * | 2014-12-29 | 2017-11-21 | 3M创新有限公司 | 可压缩的微米级聚合物颗粒及其用途、可固化组合物及其制备方法、压敏粘合剂、胶带 |
| KR20170136572A (ko) * | 2015-04-13 | 2017-12-11 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 가교결합을 위한 발광 다이오드를 사용하여 가교결합된 감압성 접착제의 제조 방법 |
| WO2016209916A1 (en) * | 2015-06-22 | 2016-12-29 | 3M Innovative Properties Company | Pressure sensitive adhesive comprising (meth)acrylic polymer and amino acid crosslinker |
| KR102126094B1 (ko) * | 2015-11-19 | 2020-06-23 | 주식회사 엘지화학 | 라디칼 경화형 접착제 조성물 및 이를 포함하는 편광판 |
| CN106928865B (zh) | 2015-12-31 | 2021-01-12 | 3M创新有限公司 | 可固化的粘合剂组合物、压敏粘合剂和制备压敏粘合剂的方法 |
| JP7271825B2 (ja) | 2018-07-23 | 2023-05-12 | コベストロ （ネザーランズ） ビー．ブイ． | マルチアジリジン化合物 |
| CN116018362A (zh) * | 2020-09-30 | 2023-04-25 | 富士胶片和光纯药株式会社 | 二次电池用粘合剂组合物、电极用组合物、电极片及二次电池以及这些电极片及二次电池的制造方法 |
| WO2024160696A2 (en) * | 2023-01-31 | 2024-08-08 | Basf Se | Curable composition, 3d-printed object formed therefrom and process of forming the same |
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| US20050070688A1 (en) * | 2003-09-26 | 2005-03-31 | 3M Innovative Properties Company | Reactive hydrophilic oligomers |
| US7074839B2 (en) * | 2004-03-01 | 2006-07-11 | 3M Innovative Properties Company | Crosslinkable hydrophilic materials from reactive oligomers having pendent photoinitiator groups |
| GB2420117A (en) * | 2004-11-10 | 2006-05-17 | Sun Chemical Ltd | Piperazino based multi-functional photoinitiators |
| US7807754B2 (en) * | 2006-03-13 | 2010-10-05 | 3M Innovative Properties Company | Dry apply adhesive graphic films |
| TWI332015B (en) * | 2006-06-21 | 2010-10-21 | Univ Tamkang | Synthesis method for aminoester alternative copolyymer |
| US7385020B2 (en) * | 2006-10-13 | 2008-06-10 | 3M Innovative Properties Company | 2-octyl (meth)acrylate adhesive composition |
| KR100867948B1 (ko) * | 2006-12-13 | 2008-11-11 | 제일모직주식회사 | 유기 절연막 형성용 감광성 수지 조성물 및 이를 포함하는소자 |
| US7393901B1 (en) | 2007-02-16 | 2008-07-01 | 3M Innovative Properties Company | Acrylate adhesives containing silica nanoparticles crosslinked with polyfunctional aziridines |
| US20080200587A1 (en) | 2007-02-16 | 2008-08-21 | 3M Innovative Properties Company | Pressure-sensitive adhesive containing acicular silica particles crosslinked with polyfunctional aziridines |
| US7652095B2 (en) * | 2007-06-20 | 2010-01-26 | 3M Innovative Properties Company | Pressure-sensitive adhesive containing aziridinyl silanes |
| US8329851B2 (en) * | 2007-06-29 | 2012-12-11 | 3M Innovative Properties Company | Functional polymer with a pendant color changing indicator |
| US7652103B2 (en) * | 2008-02-14 | 2010-01-26 | 3M Innovative Properties Company | Acrylic pressure-sensitive adhesives with aziridine crosslinking agents |
| US7714076B2 (en) | 2008-03-27 | 2010-05-11 | 3M Innovative Properties Company | Acrylic pressure-sensitive adhesives with aziridine crosslinking agents |
| US7838110B2 (en) * | 2008-12-02 | 2010-11-23 | 3M Innovative Properties Company | Aziridine-functional photoactive crosslinking compounds |
-
2009
- 2009-12-23 CN CN200910261937.3A patent/CN102108133B/zh not_active Expired - Fee Related
-
2010
- 2010-08-04 US US12/849,878 patent/US8263711B2/en not_active Expired - Fee Related
- 2010-12-14 KR KR1020127018975A patent/KR20120112607A/ko not_active Withdrawn
- 2010-12-14 WO PCT/US2010/060219 patent/WO2011087664A1/en not_active Ceased
- 2010-12-14 JP JP2012546026A patent/JP2013515819A/ja active Pending
- 2010-12-14 EP EP10795179.0A patent/EP2516391B1/en not_active Not-in-force
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102495336B1 (ko) * | 2021-11-26 | 2023-02-06 | 울산과학기술원 | 아지리딘기를 함유하는 고분자 브러시를 포함하는 가교제, 이의 제조방법 및 이의 용도 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2516391A1 (en) | 2012-10-31 |
| CN102108133B (zh) | 2014-12-10 |
| US20110152445A1 (en) | 2011-06-23 |
| EP2516391B1 (en) | 2015-03-11 |
| CN102108133A (zh) | 2011-06-29 |
| US8263711B2 (en) | 2012-09-11 |
| WO2011087664A1 (en) | 2011-07-21 |
| JP2013515819A (ja) | 2013-05-09 |
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| PA0105 | International application |
Patent event date: 20120719 Patent event code: PA01051R01D Comment text: International Patent Application |
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