KR20120064030A - 이산화탄소의 배출이 저감된 가스화 방법 - Google Patents

이산화탄소의 배출이 저감된 가스화 방법 Download PDF

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KR20120064030A
KR20120064030A KR1020110129125A KR20110129125A KR20120064030A KR 20120064030 A KR20120064030 A KR 20120064030A KR 1020110129125 A KR1020110129125 A KR 1020110129125A KR 20110129125 A KR20110129125 A KR 20110129125A KR 20120064030 A KR20120064030 A KR 20120064030A
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South Korea
Prior art keywords
carbon
carbon dioxide
gasification
catalyst
reaction
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KR1020110129125A
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English (en)
Korean (ko)
Inventor
김진홍
양자현
정일용
조대희
김정묵
김옥윤
이종찬
김규태
박주원
박삼룡
최선
오승훈
심현민
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에스케이이노베이션 주식회사
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Priority to PCT/KR2011/009437 priority Critical patent/WO2012077978A2/ko
Priority to AU2011339160A priority patent/AU2011339160A1/en
Priority to JP2013543097A priority patent/JP2013544946A/ja
Priority to EP11846868.5A priority patent/EP2650258A4/en
Priority to CA2820859A priority patent/CA2820859A1/en
Priority to US13/992,859 priority patent/US20130326953A1/en
Priority to CN2011800593887A priority patent/CN103261089A/zh
Publication of KR20120064030A publication Critical patent/KR20120064030A/ko
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/061—Methanol production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0943—Coke
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0969—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0986—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • C10J2300/1815—Recycle loops, e.g. gas, solids, heating medium, water for carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Industrial Gases (AREA)
  • Carbon And Carbon Compounds (AREA)
KR1020110129125A 2010-12-08 2011-12-05 이산화탄소의 배출이 저감된 가스화 방법 Withdrawn KR20120064030A (ko)

Priority Applications (7)

Application Number Priority Date Filing Date Title
PCT/KR2011/009437 WO2012077978A2 (ko) 2010-12-08 2011-12-07 이산화탄소의 배출이 저감된 가스화 방법
AU2011339160A AU2011339160A1 (en) 2010-12-08 2011-12-07 Gasification method for reducing emission of carbon dioxide
JP2013543097A JP2013544946A (ja) 2010-12-08 2011-12-07 二酸化炭素の排出が低減されるガス化方法
EP11846868.5A EP2650258A4 (en) 2010-12-08 2011-12-07 GASIFICATION METHOD FOR REDUCING EMISSIONS OF CARBON DIOXIDE
CA2820859A CA2820859A1 (en) 2010-12-08 2011-12-07 Gasification method for reducing emission of carbon dioxide
US13/992,859 US20130326953A1 (en) 2010-12-08 2011-12-07 Gasification Method for Reducing Emission of Carbon Dioxide
CN2011800593887A CN103261089A (zh) 2010-12-08 2011-12-07 减少二氧化碳排放的气化方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020100124651 2010-12-08
KR20100124651 2010-12-08

Publications (1)

Publication Number Publication Date
KR20120064030A true KR20120064030A (ko) 2012-06-18

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KR1020110129125A Withdrawn KR20120064030A (ko) 2010-12-08 2011-12-05 이산화탄소의 배출이 저감된 가스화 방법

Country Status (8)

Country Link
US (1) US20130326953A1 (enExample)
EP (1) EP2650258A4 (enExample)
JP (1) JP2013544946A (enExample)
KR (1) KR20120064030A (enExample)
CN (1) CN103261089A (enExample)
AU (1) AU2011339160A1 (enExample)
CA (1) CA2820859A1 (enExample)
WO (1) WO2012077978A2 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014104712A1 (ko) * 2012-12-26 2014-07-03 에스케이이노베이션 주식회사 기류 건조기를 포함하는 탄소 연료의 가스화 복합 설비
KR101664833B1 (ko) * 2015-10-02 2016-10-13 주식회사 윈테크에너지 스팀 플라즈마를 이용한 일산화탄소 제조장치 및 제조방법
KR20200015012A (ko) * 2018-08-02 2020-02-12 에스케이이노베이션 주식회사 내열성 탄산무수화효소 변이체 및 이를 포함하는 이산화탄소 포집용 조성물

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CN102186955B (zh) 2008-09-26 2015-09-02 俄亥俄州立大学 将含碳燃料转化为无碳能量载体
EP2483371B1 (en) 2009-09-08 2017-11-08 The Ohio State University Research Foundation Synthetic fuels and chemicals production with in-situ co2 capture
EP2475613B1 (en) 2009-09-08 2017-05-03 The Ohio State University Research Foundation Integration of reforming/water splitting and electrochemical systems for power generation with integrated carbon capture
EP2637777A1 (en) 2010-11-08 2013-09-18 The Ohio State University Circulating fluidized bed with moving bed downcomers and gas sealing between reactors
CN103635673B (zh) 2011-05-11 2016-05-04 俄亥俄州国家创新基金会 载氧材料
US9903584B2 (en) 2011-05-11 2018-02-27 Ohio State Innovation Foundation Systems for converting fuel
AU2014214982B2 (en) 2013-02-05 2017-11-16 Ohio State Innovation Foundation Methods for fuel conversion
CN103232857B (zh) * 2013-04-24 2015-10-28 华东理工大学 一种co2零排放的煤基电力与化工品联产工艺
WO2015131117A1 (en) 2014-02-27 2015-09-03 Ohio State Innovation Foundation Systems and methods for partial or complete oxidation of fuels
KR102287827B1 (ko) * 2014-06-26 2021-08-10 에스케이이노베이션 주식회사 천연 광물을 기반으로 하는 촉매 및 이를 이용한 가스화 방법
AU2017250214B2 (en) 2016-04-12 2021-08-12 Ohio State Innovation Foundation Chemical looping syngas production from carbonaceous fuels
CN105801354B (zh) * 2016-04-29 2018-08-10 昆明理工大学 一种将电解铝高温烟气中的二氧化碳转化为甲醇的装置及方法
US10787362B2 (en) 2016-05-16 2020-09-29 Christopher L. de Graffenried, SR. Hydrogen co-firing with carbon pre-capture for higher carbon ratio fossil fuels
EP3526313B1 (en) 2016-10-17 2021-02-24 Haldor Topsøe A/S Gasification process employing acid gas recycle
CN111065459B (zh) 2017-07-31 2023-09-22 俄亥俄州立创新基金会 具有不相等反应器组件运行压力的反应器系统
US10549236B2 (en) 2018-01-29 2020-02-04 Ohio State Innovation Foundation Systems, methods and materials for NOx decomposition with metal oxide materials
US11413574B2 (en) 2018-08-09 2022-08-16 Ohio State Innovation Foundation Systems, methods and materials for hydrogen sulfide conversion
CA3125491A1 (en) 2019-01-17 2020-07-23 Ohio State Innovation Foundation Systems, methods and materials for stable phase syngas generation
WO2020210396A1 (en) 2019-04-09 2020-10-15 Ohio State Innovation Foundation Alkene generation using metal sulfide particles
EP4010115A4 (en) 2019-08-19 2023-07-19 Ohio State Innovation Foundation MESOPOROUS SUPPORT-IMMOBILIZED NANOPARTICLES BASED ON METAL OXIDE
CA3149858C (en) 2019-09-03 2023-10-10 Liang-Shih Fan Redox reaction facilitated carbon dioxide capture from flue gas and conversion to carbon monoxide
JP7580951B2 (ja) * 2020-06-24 2024-11-12 積水化学工業株式会社 有機物質の製造方法、及び有機物質製造装置
CN112029544A (zh) * 2020-08-17 2020-12-04 新奥科技发展有限公司 催化气化方法及装置
CN113736522A (zh) * 2021-09-22 2021-12-03 东华工程科技股份有限公司 一种减少co2排放的生产合成气的工艺方法及系统
WO2024030014A1 (en) * 2022-08-04 2024-02-08 Petroliam Nasional Berhad (Petronas) Process for converting carbon dioxide to carbon monoxide
CN118754473B (zh) * 2024-06-28 2025-06-24 成都金长岷环保科技有限公司 一种搭建在水泥窑系统上的高浓度二氧化碳捕集系统及低碳排放型水泥熟料生产线

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AU2011339160A1 (en) 2013-07-11
EP2650258A2 (en) 2013-10-16
EP2650258A4 (en) 2015-03-25
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