KR20110092429A - Composition for rodenticide and method for fabricating the same - Google Patents

Composition for rodenticide and method for fabricating the same Download PDF

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KR20110092429A
KR20110092429A KR1020100011843A KR20100011843A KR20110092429A KR 20110092429 A KR20110092429 A KR 20110092429A KR 1020100011843 A KR1020100011843 A KR 1020100011843A KR 20100011843 A KR20100011843 A KR 20100011843A KR 20110092429 A KR20110092429 A KR 20110092429A
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alpha
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paraffin
phenylphenol
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KR101104357B1 (en
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조찬경
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주식회사락희제약
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
    • A01N25/004—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits rodenticidal
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Food Science & Technology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE: A rodenticide composition of a block form and a method for manufacturing the same are provided to enhance insolubility in the water and to ensure convenience. CONSTITUTION: A rodentice composition contains 0.003-0.007 weight5 of Flocoumafen as a main ingredient; 0.0001-0.0003 weight% of alpha cypermethrin, 0.0005-0.0015 weight% of denatonium benzoate, and 0.004-0-.005 weight% of 2-phenylphenol as a preservative; 0.045-0.055 weight% of anhydrous citric acid as a stabilizing agent; 5-49 weight% of paraffin, 0.1-0.9 weight% of sodium chloride, 0.1-0.9 weight% of silica gel as a thickening agent; and 0.1-0.9 weight5 of edible blue coloring agent and 0.1-0.9 weight% of alpha-copper phthalocyanine as a coring agent.

Description

살서제 조성물 및 그의 제조 방법{Composition for rodenticide and method for fabricating the same}Agrochemical composition and its manufacturing method {Composition for rodenticide and method for fabricating the same}

본 발명은 블록타입의 살서제 조성물에 관한 것이다.The present invention relates to a block type insecticide composition.

일반적으로, 살서제는 여러 종류가 개발되어 현재 시판중에 있다. 예를들면, 왈파린, 쿠마테트라릴, 브로디파쿰, 브로마디오론, 다이페나쿰, 훌로쿠마펜, 다이페치알론, 브로메탈린, 다이파시논, 클로르파시논, 쿠마클로 등이 개발되어 있다. In general, several types of fructose have been developed and are currently commercially available. For example, walparin, coumateraryl, brodipacum, bromadione, difenacum, hulocumaphene, difeccialone, bromethalin, difacinone, chlorpacinone, coumaclo, and the like have been developed.

이들 기존의 살서제들은 액체형태, 분말형태 또는 펠렛형태로 개발되어 사용되고 있다. 그러나 이러한 형태의 살서제를 함유하는 기존의 조성물들은 살서제 성분을 프로필렌글리콜, 에틸렌글리콜 등의 용제에 약 성분을 용해시킨 다음 곡물 부스러기에 용액을 섞어 입제 형태로 제조하거나, 탈크, 화이트카본, 밀가루, 설탕, 전분, 방부제, 오식방지제 등에 약 성분을 그대로 혼합하여 분제 형태의 조성물을 제조하거나, 탈크, 화이트카본, 밀가루, 설탕, 전분, 방부제, 오식방지제 등을 식물성기름, 글리세린, 프로필렌글리콜 등과 섞어 펠릿형태로 제조하였다. These conventional insecticides have been developed and used in liquid form, powder form or pellet form. However, conventional compositions containing this type of killing agent are prepared by dissolving the drug ingredient in a solvent such as propylene glycol and ethylene glycol, and then mixing the solution with grains to form granules, or talc, white carbon, flour, sugar. , Powder, starch, preservative, anticorrosive agent, etc. by mixing the ingredients in the form of powder, or talc, white carbon, flour, sugar, starch, preservative, anticorrosive, etc. mixed with vegetable oil, glycerin, propylene glycol and pellet form Was prepared.

그러나, 이들 입제, 분제, 펠릿 형태의 살서제 조성물들은 하수구, 맨홀, 농장, 산림지역 등에서는 사용하기가 곤란하였다.However, these granules, powders, and pelleticides in the form of pesticides were difficult to use in sewers, manholes, farms, forest areas and the like.

본 발명은 상기와 같은 문제점을 해결하기 위한 것으로, 파라핀을 첨가하여 물에 난용성을 증가시켜서 기존의 살서제 형태로는 사용이 어려운 하수구, 맨홀, 농장, 산림지역 뿐만아니라, 골프장, 야외 수련장, 삼림욕장, 자연휴양시설, 서바이벌 시설 등과 같은 사람들이 많이 이용하는 곳에서 시설 이용객들에게 혐오감을 주지 않고, 사람이나 애완동물들에게는 비교적 안전하며, 눈, 빗물과 같은 수분에도 강하여 야외에서 사용하기 편리한 살서제 조성물 및 그의 제조 방법을 제공하는데 그 목적이 있다.The present invention is to solve the above problems, by adding paraffin to increase the poor solubility in water sewers, manholes, farms, forest areas difficult to use in the conventional form of the algae, as well as golf courses, outdoor training grounds, forest bathing , A natural recreational facility, a survival facility, etc., do not dislike the use of facilities in places where people use a lot, relatively safe for people or pets, and strong against moisture, such as snow, rainwater, etc. Its purpose is to provide a process for its preparation.

상기와 같은 목적을 달성하기 위한 본 발명에 따른 살서제 조성물은, 주성분으로 플로쿠마펜 0.003 ∼ 0.007중량%, 보존제로 알파사이퍼메트린 0.0001 ∼ 0.0003중량%, 데나토니움 벤조에이트 0.0005 ∼ 0.0015중량%, 2-페닐페놀 0.004 ∼ 0.005중량%을 포함하고, 안정제로 무수구연산 0.045 ∼ 0.055중량%, 증량제로 파라핀 5 ∼ 49중량%, 염화나트륨 0.1 ∼ 0.9중량%, 실리카겔 0.1 ∼ 0.9중량%를 포함하며, 착색제로 식용색소 청색 제1호 0.1 ∼ 0.9중량%, 알파구리프탈로시아닌 0.1 ∼ 0.9중량%을 포함하고, 유인제로 싸레기 5 ∼ 49중량%,옥수수가루 5 ∼ 49중량% 및 전분 또는 밀가루 5 ∼ 49중량%을 포함하고, 그 밖에 설탕 0.5 ∼ 2중량%를 포함하여 구성됨에 그 특징이 있다.The salsaicide composition according to the present invention for achieving the above object is 0.003-0.007% by weight of fluorocumene as a main component, 0.0001-0.0003% by weight of alpha cypermethrin as a preservative, 0.0005-0.0015% by weight of denatonium benzoate, 2 It contains 0.004-0.005% by weight of phenylphenol, 0.045-0.05% by weight of citric anhydride as a stabilizer, 5-49% by weight of paraffin as an extender, 0.1-0.9% by weight of sodium chloride, and 0.1-0.9% by weight of silica gel. 0.1-0.9% by weight of food coloring blue No. 1, 0.1-0.9% by weight of alpha copper phthalocyanine, 5 to 49% by weight of waste, 5 to 49% by weight corn and 5 to 49% by weight of starch or flour It includes, and in addition, it is characterized by including 0.5 to 2% by weight of sugar.

또한, 상기와 같은 목적을 달성하기 위한 본 발명에 따른 살서제 제조 방법은, 플로쿠마펜 0.003 ∼ 0.007중량%, 알파사이퍼메트린 0.0001 ∼ 0.0003중량%, 데나토니움 벤조에이트 0.0005 ∼ 0.0015중량%, 2-페닐페놀 0.004 ∼ 0.005중량%, 무수구연산 0.045 ∼ 0.055중량%, 염화나트륨 0.1 ∼ 0.9중량%, 실리카겔 0.1 ∼ 0.9중량% 및 식용색소 청색 제1호 0.1 ∼ 0.9중량%를 1차 혼합하는 단계; 파라핀 5 ∼ 49중량%, 알파구리프탈로시아닌 0.1 ∼ 0.9중량%, 싸레기 5 ∼ 49중량%,옥수수가루 5 ∼ 49중량%, 설탕 0.5 ∼ 2중량% 및 전분 또는 밀가루 5 ∼ 49중량%을 2차 혼합하는 단계; 그리고 상기 1차 및 2차에서 혼합된 조성물을 혼합하고 압축 성형기를 사용하여 일정한 크기의 고형제의 살서제를 가공하는 단계를 포함하여 이루어짐에 그 특징이 있다.In addition, the method for producing a salsaicide according to the present invention for achieving the above object is 0.003-0.007% by weight of fluorocumene, 0.0001-0.0003% by weight of alpha cypermethrin, 0.0005-0.0015% by weight of denatonium benzoate, 2- Firstly mixing 0.004-0.005% by weight of phenylphenol, 0.045-0.05% by weight of citric anhydride, 0.1-0.9% by weight of sodium chloride, 0.1-0.9% by weight of silica gel and 0.1-0.9% by weight of food coloring Blue No. 1; Paraffin 5 to 49% by weight, alpha-guriphthalocyanine 0.1 to 0.9% by weight, 5 to 49% by weight of waste, corn 5 to 49% by weight, sugar 0.5 to 2% by weight and starch or flour 5 to 49% by weight secondary Mixing; And it is characterized in that it comprises a step of mixing the composition mixed in the primary and secondary and processing the salicide of a solid of a certain size using a compression molding machine.

본 발명에 따른 살서제 조성물 및 그의 제조 방법에 있어서는 다음과 같은 효과가 있다.In the killing agent composition and the manufacturing method according to the present invention has the following effects.

즉, 주성분으로 플로쿠마펜을 사용하고 증량제로 파라핀을 사용하여 고형제로 형성하므로 물에 난용성을 증가시켜서 기존의 살서제 형태로는 사용이 어려운 하수구, 맨홀, 농장, 산림지역 뿐만아니라, 골프장, 야외 수련장, 삼림욕장, 자연휴양시설, 서바이벌 시설 등 눈, 빗물과 같은 수분이 많은 지역에서도 쥐를 효과적으로 구제하고, 사람들이 많이 이용하는 곳에서 시설 이용객들에게 혐오감을 주지 않고, 사람이나 애완동물들에게는 비교적 안전한 살서제(쥐약)를 제공한다.In other words, it uses flocouma pen as the main ingredient and paraffin as the extender to form a solid agent, increasing the poor solubility in water, making it difficult to use in conventional form of salicide, sewer, manhole, farm, forest area, golf course, outdoor It can effectively control rats in polluted areas such as snow and rainwater, such as training centers, forest baths, natural recreational facilities, and survival facilities, and it is relatively safe for people and pets without giving them disgust at the places where people use them. Provides an insecticide (rat).

상기와 같은 특징을 갖는 본 발명에 따른 살서제의 조성물 및 그의 제조 방법에 관해 보다 상세히 설명하면 다음과 같다.The composition of the salicide according to the present invention having the characteristics as described above and a manufacturing method thereof will be described in more detail as follows.

본 발명에 따른 살서제는, 주성분으로 플로쿠마펜 0.003 ∼ 0.007중량%, 보존제로 알파사이퍼메트린 0.0001 ∼ 0.0003중량%, 데나토니움 벤조에이트 0.0005 ∼ 0.0015중량%, 2-페닐페놀 0.004 ∼ 0.005중량%을 포함하고, 안정제로 무수구연산 0.045 ∼ 0.055중량%, 증량제로 파라핀 5 ∼ 49중량%, 염화나트륨 0.1 ∼ 0.9중량%, 실리카겔 0.1 ∼ 0.9중량%를 포함하며, 착색제로 식용색소 청색 제1호 0.1 ∼ 0.9중량%, 알파구리프탈로시아닌 0.1 ∼ 0.9중량%을 포함하고, 유인제로 싸레기 5 ∼ 49중량%,옥수수가루 5 ∼ 49중량% 및 전분 또는 밀가루 5 ∼ 49중량%을 포함하고, 그 밖에 설탕 0.5 ∼ 2중량%를 포함하여 구성된다.The fungicide according to the present invention contains 0.003-0.007% by weight of flocoumaphen as a main component, 0.0001-0.0003% by weight of alpha cypermethrin as preservative, 0.0005-0.0015% by weight of denatonium benzoate, and 0.004-0.005% by weight of 2-phenylphenol. 0.045 to 0.055% by weight of citric anhydride as a stabilizer, paraffin 5 to 49% by weight, 0.1 to 0.9% by weight of sodium chloride, 0.1 to 0.9% by weight of silica gel as a stabilizer, and food coloring blue No. 0.1 to 0.9 as a colorant. % By weight, 0.1-0.9% by weight of alpha copper phthalocyanine, 5 to 49% by weight of waste, 5 to 49% by weight corn, and 5 to 49% by weight of starch or wheat flour, and 0.5 to 0.5% by weight of sugar. It comprises 2% by weight.

상기와 같은 조성비를 갖는 본 발명에 따른 살서제 제조 방법을 설명하면 다음과 같다.Referring to the method of manufacturing a salsaicide according to the present invention having a composition ratio as described above are as follows.

먼저, 플로쿠마펜 0.003 ∼ 0.007중량%, 알파사이퍼메트린 0.0001 ∼ 0.0003중량%, 데나토니움 벤조에이트 0.0005 ∼ 0.0015중량%, 2-페닐페놀 0.004 ∼ 0.005중량%, 무수구연산 0.045 ∼ 0.055중량%, 염화나트륨 0.1 ∼ 0.9중량%, 실리카겔 0.1 ∼ 0.9중량% 및 식용색소 청색 제1호 0.1 ∼ 0.9중량%를 1차 혼합한다. Firstly, 0.003-0.007% by weight of fluorocumene, 0.0001-0.0003% by weight of alpha cypermethrin, 0.0005-0.0015% by weight of denatonium benzoate, 0.004-0.005% by weight of 2-phenylphenol, 0.045-0.055% by weight of citric anhydride, sodium chloride 0.1-0.9 weight%, silica gel 0.1-0.9 weight%, and 0.1-0.9 weight% of food coloring blue No. 1 are mixed first.

그리고 별도로 파라핀 5 ∼ 49중량%, 알파구리프탈로시아닌 0.1 ∼ 0.9중량%, 싸레기 5 ∼ 49중량%,옥수수가루 5 ∼ 49중량%, 설탕 0.5 ∼ 2중량% 및 전분 또는 밀가루 5 ∼ 49중량%을 2차 혼합한다.And 5 to 49% by weight of paraffin, 0.1 to 0.9% by weight of alpha copper phthalocyanine, 5 to 49% by weight of trash, 5 to 49% by weight of cornmeal, 0.5 to 2% by weight of sugar and 5 to 49% by weight of starch or flour. Secondly mix.

상기 1차 및 2차에서 혼합된 조성물을 혼합하고 압축 성형기를 사용하여 일정한 크기의 고형제의 살서제를 가공한다.The composition mixed in the primary and secondary is mixed and processed with a compression molding machine to process the salicide of a certain size solid.

Claims (2)

주성분으로 플로쿠마펜 0.003 ∼ 0.007중량%, 보존제로 알파사이퍼메트린 0.0001 ∼ 0.0003중량%, 데나토니움 벤조에이트 0.0005 ∼ 0.0015중량%, 2-페닐페놀 0.004 ∼ 0.005중량%을 포함하고, 안정제로 무수구연산 0.045 ∼ 0.055중량%, 증량제로 파라핀 5 ∼ 49중량%, 염화나트륨 0.1 ∼ 0.9중량%, 실리카겔 0.1 ∼ 0.9중량%를 포함하며, 착색제로 식용색소 청색 제1호 0.1 ∼ 0.9중량%, 알파구리프탈로시아닌 0.1 ∼ 0.9중량%을 포함하고, 유인제로 싸레기 5 ∼ 49중량%,옥수수가루 5 ∼ 49중량% 및 전분 또는 밀가루 5 ∼ 49중량%을 포함하고, 그 밖에 설탕 0.5 ∼ 2중량%를 포함하여 구성됨을 특징으로 하는 살서제의 조성물.It contains 0.003 to 0.007% by weight of fluorocumene as a main component, 0.0001 to 0.0003% by weight of alpha cypermethrin as a preservative, 0.0005 to 0.0015% by weight of denatonium benzoate, and 0.004 to 0.005% by weight of 2-phenylphenol. 0.045 to 0.055% by weight, 5 to 49% by weight of paraffin as an extender, 0.1 to 0.9% by weight of sodium chloride, 0.1 to 0.9% by weight of silica gel, and 0.1 to 0.9% by weight of food coloring blue No. 1 as a colorant, and 0.1 alpha uriphthalocyanine. To 0.9% by weight, 5 to 49% by weight of waste, 5 to 49% by weight corn, and 5 to 49% by weight of starch or wheat flour, and 0.5 to 2% by weight of sugar. A composition of the insecticide, characterized in that. 플로쿠마펜 0.003 ∼ 0.007중량%, 알파사이퍼메트린 0.0001 ∼ 0.0003중량%, 데나토니움 벤조에이트 0.0005 ∼ 0.0015중량%, 2-페닐페놀 0.004 ∼ 0.005중량%, 무수구연산 0.045 ∼ 0.055중량%, 염화나트륨 0.1 ∼ 0.9중량%, 실리카겔 0.1 ∼ 0.9중량% 및 식용색소 청색 제1호 0.1 ∼ 0.9중량%를 1차 혼합하는 단계;
파라핀 5 ∼ 49중량%, 알파구리프탈로시아닌 0.1 ∼ 0.9중량%, 싸레기 5 ∼ 49중량%,옥수수가루 5 ∼ 49중량%, 설탕 0.5 ∼ 2중량% 및 전분 또는 밀가루 5 ∼ 49중량%을 2차 혼합하는 단계; 그리고
상기 1차 및 2차에서 혼합된 조성물을 혼합하고 압축 성형기를 사용하여 일정한 크기의 고형제의 살서제를 가공하는 단계를 포함하여 이루어짐을 특징으로 하는 살서제 제조 방법.0.003% to 0.007% by weight of fluorocumene, 0.0001% to 0.0003% by weight of alpha cypermethrin, 0.0005% to 0.0015% by weight of denatonium benzoate, 0.004% to 0.005% by weight of 2-phenylphenol, 0.045 to 0.055% by weight of citric anhydride, and 0.1 to 0.1% of sodium chloride. First mixing 0.9 wt%, silica gel 0.1-0.9 wt% and food coloring blue No. 1 No. 0.1-0.9 wt%;
Paraffin 5 to 49% by weight, alpha-guriphthalocyanine 0.1 to 0.9% by weight, 5 to 49% by weight of waste, corn 5 to 49% by weight, sugar 0.5 to 2% by weight and starch or flour 5 to 49% by weight secondary Mixing; And
Mixing the composition mixed in the primary and secondary and using a compression molding machine comprising the step of processing the salsaicide of a solid of a certain size.
KR1020100011843A 2010-02-09 2010-02-09 Composition for rodenticide and method for fabricating the same KR101104357B1 (en)

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KR100354194B1 (en) * 1999-01-11 2002-09-26 윤태순 Composition of rodenticide
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MY143382A (en) * 2005-11-18 2011-05-13 Basf Se Aqueous rodenticide formulations

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CN105660628A (en) * 2016-01-04 2016-06-15 安徽康宇生物科技工程有限公司 Soft gelatin rodenticide and preparation method thereof
KR101661439B1 (en) * 2016-02-12 2016-10-10 김대진 Anticoagulant Rodenticide of Granular or Block Type Comprising Coumatetralyl as Effective Component and Manufacturing Method Thereof

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