CN104365676A - Poison bait for killing solenopsis invicta, and preparation method of poison bait - Google Patents
Poison bait for killing solenopsis invicta, and preparation method of poison bait Download PDFInfo
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- CN104365676A CN104365676A CN201410596056.8A CN201410596056A CN104365676A CN 104365676 A CN104365676 A CN 104365676A CN 201410596056 A CN201410596056 A CN 201410596056A CN 104365676 A CN104365676 A CN 104365676A
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- silkworm chrysalis
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The invention discloses poison bait for killing solenopsis invicta, and a preparation method of the poison bait. The poison bait is prepared from the following raw materials by weight percent: 0.15-1.0% of a preservative, 0.005-0.8% of pesticide crude drug and 98.20-99.845% of an attractant, wherein the attractant is silkworm chrysalis meal. The preparation method comprises the steps of A. reeling off raw silk from cocoons, cleaning silkworm chrysalis by water, and then draining off; putting the silkworm chrysalis into a hot pot, drying, frying, grinding the silkworm chrysalis when the silkworm chrysalis is hot, and sieving to obtain the silkworm chrysalis meal; B. evenly mixing the silkworm chrysalis meal and the preservative; C. dissolving the pesticide crude drug by taking ethyl alcohol or acetone as a solvent, and preparing a 0.1-5% pesticide solution; D. spraying the solution obtained in the step C onto the product obtained in the step B, stirring while spraying, drying the whole material after evenly mixing, and respectively packaging. The poison bait is remarkable in solenopsis invicta killing effect, and has the effective killing rate of more than 98%; the silkworm chrysalis raw material is enough and convenient and easy to obtain, so that the poison bait is low in production cost; the poison bait belongs to a biological insecticide which is low in toxicity, efficient and less in residue.
Description
Technical field
The present invention relates to a kind of chemical insecticide, especially a kind of poison bait for killing red ants and preparation method thereof.
Background technology
Red fire ant (Solenopsis invicta) belongs to Hymenoptera (Hymenoptera) Formicidae (Formicidae) Myrmicinae (Myrmicinae) Solenopsis (Solenopsis), originate in Parana (Parana) basin of South America, comprise the states such as Brazil, Paraguay, Argentina.2003, China's Taiwan reported first found that there is red fire ant invasion, and in September, 2004, after the Late Cambrian red fire ant epidemic situation of Wuchuan City, Guangdong Province, the ground such as Guangxi, Hunan, Fujian, Hong Kong, Macao also find S.invicta Buren in succession.The invasion of red fire ant often brings serious ecocatastrophe to locality; the formidable enemy that bio-diversity conservation and agriculture and forestry are produced; red fire ant is except dwelling property of the soil animal eaten in soil; also directly eat plant roots, tender shoots, fruit and seed; cause damage to agricultural production, produce harm to urban green space.Red fire ant is also destroyed the electric switch, ammeter, communications service, traffic lamp box etc. of communal facility, causes damaging communal facility and electronic equipment.In addition, red fire ant is aggressive strong, after people is bitten by red fire ant, is bitten position and has lasting searing pain, and local skin forms erythema, bubble, firmly swollen, has gargalesthesia, often can cause bacillary superinfection again after bubble breaks.May be there is serious anaphylactic shock in the people of minority physique sensitivity, even dead, drastically influence social public security.Red fire ant, except attacks, except even life brings threat to human health, also can attack other animal, destroys the ecological balance.Because red fire ant has so large harm, the states such as the U.S., New Zealand, Australia are all actively developing the control to red fire ant, and China is also actively taking measures.
The most effective method of current control red fire ant is period poison bait method, and poison bait is generally made up of toxic agent, attractant, bait and preservative etc.The principle of period poison bait red fire ant is: the food utilizing red fire ant to like as carrier, and adds attractant, in bait, then add stomach poison and the insect growth regulator, IGR of slowly-releasing.Allow worker ant that poison bait is moved into ant nest Inner portion, spread to whole ant group through food trophallaxis, the ant composition that makes to go out in poison bait finally turns and amasss in queen body, reaches the object of extinction ant group.Therefore, whether effectively can the poison bait key ant composition that is namely to go out be passed in queen body smoothly.At present, exploitation both at home and abroad mainly contains for the toxic agent of Solenopsis invicta: ethiprole, sulfluramid, pleocidin, indoxacarb, ivermectin, ethene ethiprole, Nylar sulphur, fluorine sulfonamide, tetramethrin, orthene, chlopyrifos etc.Attractant is partial to find protein and the higher material of lipid content due to red fire ant, so make poison bait many employings fish meal, liquid vegetable oil, sugar, spices etc. as attractant, carrier is then common with corn flour, ground rice, soybean meal, flour or its mixture etc.But problem that in prior art, the poison bait ubiquity insecticidal power of killing red ants is limited, strong to surrounding environment toxic and side effect, cost is higher and preparation technology is multiple etc., has the place being worth improving.
Summary of the invention
Problem to be solved by this invention is to provide a kind of killing red ant Be very effective, safety is high, cost the is low red fire ant poison bait and preparation method thereof that goes out.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is: be made up of the raw material of following weight percentage: preservative 0.15 ~ 1.0%, preparing protodrug 0.005 ~ 0. 8%, attractant 98.20 ~ 99.845%; Described attractant is dried silkworm chrysalis meal.
In technique scheme, scheme can also be more specifically: described preservative is the one in potassium sorbate, natrium nitrosum or Sodium Benzoate; Described preparing protodrug is one, two or three mixture in ethiprole, sulfluramid, HEXAFLUMURON, hydramethylnon, pleocidin, indoxacarb, butene-fipronil, fluorine sulfonamide.
Its preparation process is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 10 ~ 50 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal and preservative stirring and evenly mixing;
C, for solvent, preparing protodrug to be dissolved with ethanol or acetone, be mixed with the insecticide solution of 0.1 ~ 5% concentration;
D, step C gained spray solution to be entered in step B gains, spray and stir, by whole drying materials after mixing, packing.
Owing to have employed technique scheme, the present invention compared with prior art has following beneficial effect:
1. killing red ant Be very effective, kills efficient more than 98%.Several pesticides contained in red fire ant poisoning bait formulation of the present invention, poisoning mechanism is different, and independent effect, does not produce resistance mutually, but has synergy.
2. silkworm chrysalis allure is strong.Silkworm chrysalis belongs to high protein animal inductor, is the protein material of red fire ant eating, adds its peat-reek brought after frying, can red fire ant be stimulated to rob food.
3. silkworm chrysalis raw material is sufficient and be conveniently easy to get.Central Guilin area, Guangxi to move westwards recipient place as the eastern silkworm of China, and have a large amount of silkworm by product silkworm chrysalises to wait for comprehensive utilization, in insecticide, be used as attractant is make the best use of everything.
4. be beneficial to the carrying of red fire ant to poison bait, expand poisoning scope.Dried silkworm chrysalis meal is as carrier, and proportion is little, even if sheet silkworm chrysalis weight is also light, also not easily bonds to each other agglomerating, is applicable to very much red fire ant carrying.
5. the method technique preparing this poison bait is simple, be easy to operation.
6. reduce the production cost of red fire ant poison bait.Difference compared with dried silkworm chrysalis meal ton cost and poison bait common carrier flour etc. is also little, the more important thing is, dried silkworm chrysalis meal not only can be used as attractant, also can be used as carrier, eliminate other expensive attractants, simultaneously because the apparent gravity of dried silkworm chrysalis meal is low, the poison bait of identical weight due to volume large, even if toxic effect is identical, cost also will be lower.
7. poison bait belongs to the biological insecticides of low toxicity, efficient, low-residual.Existing efficient insecticidal properties, has again the characteristic to having beneficial insect and mammalian safe, is the insecticide of a kind of low toxicity, efficient, environmental protection.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1:
Configure the raw material that 100 grams of red fire ant poison baits that go out need following weight:
Pleocidin 0.02 gram, preservative 0.15 gram, dried silkworm chrysalis meal 99.83 grams;
Preparation method is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 10 mesh sieves, obtain dried silkworm chrysalis meal 99.82 grams;
B, by dried silkworm chrysalis meal 99.83 grams and preservative 0.15 gram of stirring and evenly mixing;
C, with ethanol or acetone for solvent is by pleocidin 0.02 gram dissolving, be mixed with the insecticide solution of 0.2% concentration;
D, entered in step B gains by step C gained spray solution, spray and stir, by whole drying materials after mixing, packing, obtaining particle size is 10 ~ 50 object poison baits.
Embodiment 2:
Configure the raw material that 100 grams of red fire ant poison baits that go out need following weight:
Ethiprole 0.05 gram, preservative 0.15 gram, dried silkworm chrysalis meal 99.8 grams;
Preparation method is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 30 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal 99.8 grams and preservative 0.15 gram of stirring and evenly mixing;
C, with ethanol or acetone for solvent is by ethiprole 0.05 gram dissolving, be mixed with the insecticide solution of 0.5% concentration;
D, entered in step B gains by step C gained spray solution, spray and stir, by whole drying materials after mixing, packing, obtaining particle size is 10 ~ 50 object poison baits.
Embodiment 3:
Configure the raw material that 100 grams of red fire ant poison baits that go out need following weight:
Indoxacarb 0.1 gram, preservative 1.0 grams, dried silkworm chrysalis meal 98.90 grams;
Preparation method is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 50 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal 98.9 grams and preservative 1.0 grams of stirring and evenly mixings;
C, with ethanol or acetone for solvent is by indoxacarb 0.1 gram dissolving, be mixed with 0.5% concentration insecticide solution;
D, entered in step B gains by step C gained spray solution, spray and stir, by whole drying materials after mixing, packing, obtaining particle size is 10 ~ 50 object poison baits.
Embodiment 4:
Configure the raw material that 100 grams of red fire ant poison baits that go out need following weight:
Pleocidin 0.01 gram, ethiprole 0.04 gram, preservative 1.0 grams, dried silkworm chrysalis meal 98.95 grams;
Preparation method is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 20 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal 98.95 grams and preservative 1.0 grams of stirring and evenly mixings;
C, with ethanol or acetone for solvent is by pleocidin 0.01 gram, ethiprole 0.04 gram dissolving, is mixed with
0.5%the insecticide solution of concentration;
D, entered in step B gains by step C gained spray solution, spray and stir, by whole drying materials after mixing, packing, obtaining particle size is 10 ~ 50 object poison baits.
Embodiment 5:
Configure the raw material that 100 grams of red fire ant poison baits that go out need following weight:
Fluorine sulfonamide 0.5 gram, ethiprole 0.01 gram, preservative 1.0 grams, dried silkworm chrysalis meal 98.49 grams;
Preparation method is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 40 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal 98.19 grams and preservative 1.0 grams of stirring and evenly mixings;
C, with ethanol or acetone for solvent is by fluorine sulfonamide 0.5 gram and ethiprole 0.01 gram dissolving, be mixed with the insecticide solution of 5% concentration;
D, entered in step B gains by step C gained spray solution, spray and stir, by whole drying materials after mixing, packing, obtaining particle size is 10 ~ 50 object poison baits.
Embodiment 6:
Configure the raw material that 100 grams of red fire ant poison baits that go out need following weight:
Fluorine sulfonamide 0.3 gram, sulfluramid 0.05 gram, preservative 0.15 gram, dried silkworm chrysalis meal 99.50 grams;
Preparation method is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 30 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal 99.51 grams and preservative 0.15 gram of stirring and evenly mixing;
C, with ethanol or acetone for solvent is by fluorine sulfonamide 0.3 gram, sulfluramid 0.04 gram dissolving, be mixed with the insecticide solution of 0.3% concentration;
D, entered in step B gains by step C gained spray solution, spray and stir, by whole drying materials after mixing, packing, obtaining particle size is 10 ~ 50 object poison baits.
Embodiment 7:
Configure the raw material that 100 grams of red fire ant poison baits that go out need following weight:
Indoxacarb 0.01 gram, butene-fipronil 0.5 gram, preservative 0.5 gram, dried silkworm chrysalis meal 98.99 grams;
Preparation method is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 10 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal 98.99 grams and preservative 0.5 gram of stirring and evenly mixing;
C, with ethanol or acetone for solvent is by indoxacarb 0.01 gram and butene-fipronil 0.5 gram dissolving, be mixed with the insecticide solution of 5% concentration;
D, entered in step B gains by step C gained spray solution, spray and stir, by whole drying materials after mixing, packing, obtaining particle size is 10 ~ 50 object poison baits.
Embodiment 8:
Configure the raw material that 100 grams of red fire ant poison baits that go out need following weight:
Pleocidin 0.02 gram, butene-fipronil 0.4 gram, preservative 0.6 gram, dried silkworm chrysalis meal 98.98 grams;
Preparation method is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 50 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal 98.98 grams and preservative 0.6 gram of stirring and evenly mixing;
C, with ethanol or acetone for solvent is by pleocidin 0.02 gram and butene-fipronil 0.4 gram dissolving, be mixed with the insecticide solution of 5% concentration;
D, entered in step B gains by step C gained spray solution, spray and stir, by whole drying materials after mixing, packing, obtaining particle size is 10 ~ 50 object poison baits.
Embodiment 9:
Configure the raw material that 100 grams of red fire ant poison baits that go out need following weight:
Pleocidin 0.03 gram, butene-fipronil 0.2 gram, HEXAFLUMURON 0.2 gram, preservative 1.0 grams, dried silkworm chrysalis meal 98.57 grams;
Preparation method is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 30 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal 98.57 grams and preservative 1 gram of stirring and evenly mixing;
C, with ethanol or acetone for solvent is by pleocidin 0.03 gram and ethene ethiprole 0.2 gram dissolving, be mixed with the insecticide solution of 3% concentration;
D, entered in step B gains by step C gained spray solution, spray and stir, by whole drying materials after mixing, packing, obtaining particle size is 10 ~ 50 object poison baits.
Embodiment 10:
Configure the raw material that 100 grams of red fire ant poison baits that go out need following weight:
Pleocidin 0.03 gram, HEXAFLUMURON 0.8 gram, preservative 1.0 grams, dried silkworm chrysalis meal 98.17 grams;
Preparation method is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 50 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal 98.17 grams and preservative 1.0 grams of stirring and evenly mixings;
C, with ethanol or acetone for solvent is by pleocidin 0.03 gram and HEXAFLUMURON 0.8 gram dissolving, be mixed with the insecticide solution of 5% concentration;
D, entered in step B gains by step C gained spray solution, spray and stir, by whole drying materials after mixing, packing, obtaining particle size is 10 ~ 50 object poison baits.
Embodiment 11:
Configure the raw material that 100 grams of red fire ant poison baits that go out need following weight:
Indoxacarb 0.08 gram, HEXAFLUMURON 0.5 gram, preservative 0.15 gram, dried silkworm chrysalis meal 99.27 grams;
Preparation method is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 50 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal 99.27 grams and preservative 0.15 gram of stirring and evenly mixing;
C, with ethanol or acetone for solvent is by indoxacarb 0.08 gram and HEXAFLUMURON 0.5 gram dissolving, be mixed with the insecticide solution of 5% concentration;
D, entered in step B gains by step C gained spray solution, spray and stir, by whole drying materials after mixing, packing, obtaining particle size is 10 ~ 50 object poison baits.
Embodiment 12:
Configure the raw material that 100 grams of red fire ant poison baits that go out need following weight:
Hydramethylnon 0.75 gram, preservative 0.15 gram, dried silkworm chrysalis meal 99.1 grams;
Preparation method is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 40 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal 99.1 grams and preservative 0.15 gram of stirring and evenly mixing;
C, with ethanol or acetone for solvent is by hydramethylnon 0.75 gram dissolving, be mixed with the insecticide solution of 5% concentration;
D, entered in step B gains by step C gained spray solution, spray and stir, by whole drying materials after mixing, packing, obtaining particle size is 10 ~ 50 object poison baits.
Originally to go out the using method of red fire ant poison bait:
When this poison bait uses killing red ant at the scene, according to the life characteristic of red fire ant, must not rain before executing bait, not rain in 24h after dispenser; Red fire ant ant nest can not be startled during dap, ant nest surface and around evenly spread fertilizer over the fields poison bait 30-50g according to ant nest size within the scope of 30 ~ 100cm.Within after dispenser the 3rd day, observe poison bait surplus situation, suitably supplement poison bait; If also have red fire ant movable when the 7th day, can again offer medicine.After executing bait by above method, red fire ant eradicative rate is more than 98%.
the test of pesticide effectiveness:
Originally the killing effect of red fire ant poison bait to red fire ant that go out is as shown in table 1.
Table 1
As can be seen from the table, poison bait of the present invention has efficient killing effect to red fire ant, traps and kills very competent.
Claims (3)
1. go out a red fire ant poison bait, it is characterized in that being made up of the raw material of following weight percentage: preservative 0.15 ~ 1.0%, preparing protodrug 0.005 ~ 0. 8%, attractant 98.20 ~ 99.845%; Described attractant is dried silkworm chrysalis meal.
2. the red fire ant poison bait that goes out according to claim 1, is characterized in that: described preservative is the one in potassium sorbate, natrium nitrosum or Sodium Benzoate; Described preparing protodrug is one, two or three mixture in ethiprole, sulfluramid, HEXAFLUMURON, hydramethylnon, pleocidin, indoxacarb, butene-fipronil, fluorine sulfonamide.
3. to go out the preparation method of red fire ant poison bait, it is characterized in that:
Adopt following raw material: preservative 0.15 ~ 1.0%, preparing protodrug 0.005 ~ 0. 8%, attractant 98.20 ~ 99.845%; Described attractant is dried silkworm chrysalis meal;
Its preparation process is:
A, silk cocoon is reeled off raw silk from cocoons after silkworm chrysalis cross after water cleans up and drain, dry in heat release pot, fry fragrant, and to pulverize while hot, cross 10 ~ 50 mesh sieves, obtain dried silkworm chrysalis meal;
B, by dried silkworm chrysalis meal and preservative stirring and evenly mixing;
C, for solvent, preparing protodrug to be dissolved with ethanol or acetone, be mixed with the insecticide solution of 0.1% ~ 5% concentration;
D, step C gained spray solution to be entered in step B gains, spray and stir, by whole drying materials after mixing, packing.
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Cited By (8)
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| CN106135254A (en) * | 2016-07-01 | 2016-11-23 | 安徽喜丰收农业科技有限公司 | A kind of indoxacarb bait formulation preventing and treating red fire ant |
| CN106305707A (en) * | 2016-07-21 | 2017-01-11 | 柳州市白云生物科技有限公司 | Solenopsis invicta killing poison bait and preparation method thereof |
| CN106472548A (en) * | 2016-10-14 | 2017-03-08 | 广州瑞丰生物科技有限公司 | Termiticide bait formulation |
| CN106857602A (en) * | 2017-03-29 | 2017-06-20 | 广州百昆生物科技有限公司 | Eliminate fire ant bait agent and preparation method |
| CN108094418A (en) * | 2018-01-26 | 2018-06-01 | 厦门万嘉生态科技有限公司 | A kind of pure-natural biological ingredient kills fire ant bait agent and preparation method thereof |
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| CN111134141A (en) * | 2019-12-31 | 2020-05-12 | 广东省生物资源应用研究所 | Red fire ant bait containing hermetia illucens powder |
| CN112314635A (en) * | 2020-10-30 | 2021-02-05 | 柳州衍生科技有限公司 | Insecticide containing silkworm chrysalis powder and preparation method thereof |
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| CN106135254A (en) * | 2016-07-01 | 2016-11-23 | 安徽喜丰收农业科技有限公司 | A kind of indoxacarb bait formulation preventing and treating red fire ant |
| CN106305707A (en) * | 2016-07-21 | 2017-01-11 | 柳州市白云生物科技有限公司 | Solenopsis invicta killing poison bait and preparation method thereof |
| CN106472548A (en) * | 2016-10-14 | 2017-03-08 | 广州瑞丰生物科技有限公司 | Termiticide bait formulation |
| CN106857602A (en) * | 2017-03-29 | 2017-06-20 | 广州百昆生物科技有限公司 | Eliminate fire ant bait agent and preparation method |
| CN108094418A (en) * | 2018-01-26 | 2018-06-01 | 厦门万嘉生态科技有限公司 | A kind of pure-natural biological ingredient kills fire ant bait agent and preparation method thereof |
| CN110771619A (en) * | 2019-11-26 | 2020-02-11 | 深圳市威必达有害生物防治有限公司 | Medicament for killing solenopsis invicta and preparation method thereof |
| CN111134141A (en) * | 2019-12-31 | 2020-05-12 | 广东省生物资源应用研究所 | Red fire ant bait containing hermetia illucens powder |
| CN112314635A (en) * | 2020-10-30 | 2021-02-05 | 柳州衍生科技有限公司 | Insecticide containing silkworm chrysalis powder and preparation method thereof |
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Application publication date: 20150225 |