CN110574763A - Insecticidal composition - Google Patents
Insecticidal composition Download PDFInfo
- Publication number
- CN110574763A CN110574763A CN201910959559.XA CN201910959559A CN110574763A CN 110574763 A CN110574763 A CN 110574763A CN 201910959559 A CN201910959559 A CN 201910959559A CN 110574763 A CN110574763 A CN 110574763A
- Authority
- CN
- China
- Prior art keywords
- insecticidal composition
- emamectin benzoate
- dicyclopropionate
- percent
- pests
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 31
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 claims abstract description 39
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 15
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 claims abstract description 8
- 229960005199 tetramethrin Drugs 0.000 claims abstract description 8
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 6
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 5
- 239000000839 emulsion Substances 0.000 claims abstract description 5
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 5
- 239000000375 suspending agent Substances 0.000 claims abstract description 4
- 239000011248 coating agent Substances 0.000 claims abstract description 3
- 239000012053 oil suspension Substances 0.000 claims abstract description 3
- 239000004563 wettable powder Substances 0.000 claims abstract description 3
- 239000003905 agrochemical Substances 0.000 claims abstract 4
- 238000009472 formulation Methods 0.000 claims abstract 2
- 239000000575 pesticide Substances 0.000 claims description 24
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- 241001414720 Cicadellidae Species 0.000 claims description 4
- 241000258937 Hemiptera Species 0.000 claims description 4
- 241001414989 Thysanoptera Species 0.000 claims description 4
- 241001124076 Aphididae Species 0.000 claims description 3
- 235000009024 Ceanothus sanguineus Nutrition 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims description 2
- 240000003553 Leptospermum scoparium Species 0.000 claims description 2
- 235000015459 Lycium barbarum Nutrition 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 244000204900 Talipariti tiliaceum Species 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 235000013399 edible fruits Nutrition 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 26
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 230000009471 action Effects 0.000 abstract description 4
- 238000003912 environmental pollution Methods 0.000 abstract description 4
- 206010059866 Drug resistance Diseases 0.000 abstract description 2
- 239000004480 active ingredient Substances 0.000 abstract description 2
- 230000007246 mechanism Effects 0.000 abstract description 2
- 239000000447 pesticide residue Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000003963 antioxidant agent Substances 0.000 description 8
- 230000003078 antioxidant effect Effects 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000004519 grease Substances 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 229920002261 Corn starch Polymers 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000008120 corn starch Substances 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 239000005822 Propiconazole Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GINJFDRNADDBIN-FXQIFTODSA-N bilanafos Chemical compound OC(=O)[C@H](C)NC(=O)[C@H](C)NC(=O)[C@@H](N)CCP(C)(O)=O GINJFDRNADDBIN-FXQIFTODSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000010902 jet-milling Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- -1 phosphate ester Chemical class 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an insecticidal composition, which consists of emamectin benzoate and dicyclopropionate, wherein the weight ratio of the emamectin benzoate to the dicyclopropionate is 1-30: 30-1, wherein the weight ratio of the emamectin benzoate to the dicyclopropionate is 1-10: 10-1, the insecticidal composition is emamectin benzoate and dicyclopropyl tetramethrin, and is added with an agricultural chemical auxiliary agent to prepare a formulation allowed on agricultural chemicals, including but not limited to missible oil, a suspending agent, a wettable powder, an aqueous emulsion, a microemulsion, a water dispersible granule, an oil suspension and a seed coating. Compared with a single agent, the composition has obvious synergy on the piercing-sucking pests, and improves the application effect; the field dosage is greatly reduced, the use cost is reduced, and the environmental pollution and the pesticide residue are reduced; the two active ingredients in the composition have completely different action mechanisms, so that the generation of drug resistance of pests is overcome, and the treatment of resistant pests is facilitated.
Description
Technical Field
the invention belongs to the technical field of agricultural insecticide preparation, and particularly relates to an insecticide composition compounded by emamectin benzoate and dicyclopropyl tetramethrin.
Background
Conventionally, piercing-sucking mouthpart pests are difficult to control in agriculture, and simultaneously, due to the single action site of the pesticide and the unscientific use of the pesticide, the piercing-sucking mouthpart pests have higher resistance to the currently used chemical pesticides. Frequent mass application of the pesticide results in high production cost and aggravates environmental pollution. Therefore, a new high-efficiency, low-toxicity and environment-friendly variety is urgently needed in agricultural production, and therefore, the insecticidal composition is provided.
Disclosure of Invention
The invention aims to: in order to solve the problems that the existing agricultural pest control pesticide is not standard, not only aggravates the environmental pollution, but also causes the resistance of pests, the pesticide composition is provided.
the technical scheme adopted by the invention is as follows:
An insecticidal composition is composed of emamectin benzoate and dicyclopropionate, wherein the weight ratio of the emamectin benzoate to the dicyclopropionate is 1-30: 30 to 1.
Wherein the weight ratio of the emamectin benzoate to the dicyclopropionate is 1-10: 10 to 1.
The insecticidal composition is emamectin benzoate and propiconazole, and is prepared into a pesticide allowable dosage form by adding a pesticide auxiliary agent, wherein the pesticide allowable dosage form comprises but is not limited to missible oil, a suspending agent, a suspending emulsion, wettable powder, an aqueous emulsion, a microemulsion, a water dispersible granule, an oil suspension and a seed coating agent.
wherein, the pesticide auxiliary agent is one or more of a solvent, a dispersant and an emulsifier.
Wherein, the insecticidal composition is applied to the control of crop pests.
Wherein the crops are one or more of fruit trees, vegetables, Chinese medicinal materials, rice, cotton and tea trees.
wherein the pests are sucking mouthparts pests, such as aphids, thrips, whiteflies and leafhoppers.
In summary, due to the adoption of the technical scheme, the invention has the beneficial effects that:
1. Compared with a single agent, the composition has obvious synergy on the piercing-sucking pests, and improves the application effect; 2. the field dosage is greatly reduced, the use cost is reduced, and the environmental pollution and the pesticide residue are reduced; 3. the two active ingredients in the composition have completely different action mechanisms, so that the generation of drug resistance of pests is overcome, and the treatment of resistant pests is facilitated; 4. compared with emamectin benzoate, the long-acting insecticidal composition obviously improves the lasting period, and has good quick-acting property compared with the dicyclopropanate.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
The first embodiment is an insecticidal composition, which comprises the following components: 2.5% of emamectin benzoate, 5% of dicyclopropyl tetramethrin, 10% of cyclohexanone, 16% of an emulsifier, 1% of an antioxidant and the balance of water;
the preparation method of the insecticidal composition comprises the following steps:
Step 1: dissolving emamectin benzoate and dicyclopropyl tetramethrin by using cyclohexanone;
Step 2: adding an antioxidant into the product obtained in the step 1, and mixing and stirring the mixture until the mixture is uniform and transparent;
And step 3: and (3) adding an emulsifier into the product obtained in the step (2), adding water, mixing and stirring uniformly to prepare the microemulsion insecticidal composition consisting of 7.5% of emamectin benzoate and dicyclopropyl grease.
When in use, the microemulsion of the emamectin benzoate and the dicyclopropyl cinfenot of 7.5 percent is diluted by adding water of 2500 times and sprayed for use, which has special effect on preventing and treating aphids, and the preventing and treating effects of the microemulsion of the emamectin benzoate and the dicyclopropyl cinfenot are respectively 88.4 percent, 97.6 percent and 94.9 percent after 1 day, 7 days and 15 days after the application. After 5% of single preparation of emamectin benzoate and dicyclopropyl tetramethrin is used by spraying after being diluted 2500, the control effect 1 day after the pesticide is respectively 78.3% and 62.4%; the control effect 7 days after the pesticide is 68.9 percent and 85.5 percent respectively; the control effect 15 days after the pesticide is 61.9 percent and 80.5 percent respectively. It can be seen that the prevention and treatment effect is greatly improved after the emamectin benzoate and the dicyclopropanate are compounded, and the quick action and the persistence are better than those of single dosage.
Example two: an insecticidal composition comprises the following components: 3% of emamectin benzoate, 30% of dicyclopropyl tetramat, 6% of phosphate, 0.16% of xanthan gum, 0.4% of preservative, 1% of antioxidant and the balance of water;
The preparation method of the insecticidal composition comprises the following steps:
Step 1: pouring water into a stirring kettle, then sequentially adding phosphate ester, emamectin benzoate, dicyclopropyl tetramat, xanthan gum, preservative and antioxidant, shearing and stirring for 30 minutes;
Step 2: and (3) performing serial sanding on the product obtained in the step (1) by using 3 sanding machines to prepare the suspending agent-state insecticidal composition consisting of 33 percent of emamectin benzoate and bialaphos.
When in use, the emamectin benzoate and the dicyclopropyl tetramethrin in 33 percent are diluted by 5000 times of water and sprayed for use, and the control effect on the thrips is special, and the control effect on 1 day, 7 days and 15 days after the application is respectively 90.4 percent, 98.6 percent and 96.3 percent. The single dose of 5 percent of emamectin benzoate and dicyclopropangolin is diluted by 2500 times, and after the single dose is used under the same condition, the control effect 1 day after the single dose is 75.3 percent and 52.4 percent respectively; the control effect 7 days after the pesticide is 57.9 percent and 87.3 percent respectively; the control effect 15 days after the pesticide is 47.5 percent and 83.7 percent respectively. It can be seen that the synergistic effect of the emamectin benzoate and the dicyclopropanate after compounding is very obvious, the control effect on the thrips is greatly improved, and the quick-acting property and the lasting property are both superior to those of a single agent.
in a third embodiment, an insecticidal composition comprises the following components: 2% of emamectin benzoate, 10% of dicyclopropanate, 18% of emulsifier, 2% of organic soil, 1% of antioxidant and the balance of methyl esterified vegetable oil;
the preparation method of the insecticidal composition comprises the following steps:
step 1: pouring the methyl esterified vegetable oil into a stirring kettle, sequentially adding the emulsifier, the emamectin benzoate, the dicyclopropyl grease, the organic soil and the antioxidant, and shearing and stirring for 30 minutes;
Step 2: and (3) performing serial sanding on the product obtained in the step (1) by using three sanding machines to prepare the suspending agent-state insecticidal composition consisting of 12% of emamectin benzoate and diproprionate.
when in use, 12 percent of emamectin benzoate and the dicyclopropyl grease suspending agent are diluted by 2000 times of water and sprayed for use, the pesticide has special effect on preventing whiteflies, and the preventing and treating effects of the pesticide for 1 day, 7 days and 15 days are respectively 92.4 percent, 96.6 percent and 98.3 percent. The pesticide is diluted 2500 times by using 5 percent of emamectin benzoate and dicyclopropanil single agent, and the control effect 1 day after the pesticide is used under the same condition is 78.2 percent and 58.9 percent respectively; the control effect 7 days after the pesticide is 64.6 percent and 89.6 percent respectively; the control effect 15 days after the pesticide is 56.3 percent and 81.9 percent respectively. The synergistic effect is very obvious after the emamectin benzoate and the dicyclopropanaplate insecticide are compounded, the control effect on the whitefly is greatly improved, and the timeliness and the persistence are both superior to those of a single agent.
In a fourth embodiment, an insecticidal composition comprises the following components: 3% of emamectin benzoate, 45% of dicyclopropanate, 2% of sodium dodecyl benzene sulfonate, 5% of NNO, 3% of polycarboxylate, 1% of antioxidant and the balance of corn starch;
The preparation method of the insecticidal composition comprises the following steps:
Step 1: respectively adding emamectin benzoate, dicyclopropyl tetramethrin, sodium dodecyl benzene sulfonate, NNO, polycarboxylate, antioxidant and corn starch into a mixing kettle, and mixing for 45 minutes;
step 2: performing jet milling on the product obtained in the step (1) by using a jet mill, and adding water for extrusion granulation;
And step 3: and (3) drying and screening the product obtained in the step (2) to obtain the water dispersible granule insecticidal composition consisting of 48% of emamectin benzoate and dicyclopropyl tetramat.
when in use, the water dispersible granule consisting of 48 percent of emamectin benzoate and dicyclopropanesefat is diluted by 10000 times of water and sprayed for use, and the control effect on the lesser leafhopper is special, and the control effect on 1 day, 7 days and 15 days after the application is respectively 95.3 percent, 100 percent and 99.3 percent. The single dose of 5 percent of emamectin benzoate and dicyclopropangolin is diluted by 2500 times and used under the same condition, and the control effect 1 day after the application is 52.3 percent and 84.6 percent respectively; the control effect 7 days after the pesticide is 75.4 percent and 90.6 percent respectively; the control effect 15 days after the pesticide is 52.3 percent and 84.6 percent respectively. It can be seen that the synergistic effect is very obvious after the emamectin benzoate and the dicyclopropanate are compounded, the control effect on the lesser leafhoppers is greatly improved, and the quick-acting property and the lasting property are both superior to those of a single agent.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.
Claims (7)
1. An insecticidal composition characterized by: the insecticidal composition consists of emamectin benzoate and dicyclopropionate, wherein the weight ratio of the emamectin benzoate to the dicyclopropionate is 1-30: 30 to 1.
2. An insecticidal composition according to claim 1, wherein: the weight ratio of the emamectin benzoate to the dicyclopropionate is 1-10: 10 to 1.
3. an insecticidal composition according to any one of claims 1 to 2, wherein: the insecticidal composition is emamectin benzoate and dicyclopropyl tetramethrin, and is added with an agricultural chemical auxiliary agent to prepare a formulation allowed on agricultural chemicals, including but not limited to missible oil, suspending agent, suspending emulsion, wettable powder, aqueous emulsion, microemulsion, water dispersible granules, oil suspension and seed coating agent.
4. an insecticidal composition according to claim 3, wherein: the pesticide auxiliary agent is one or more of a solvent, a dispersant and an emulsifier.
5. An insecticidal composition according to claim 4, wherein: the insecticidal composition is applied to the control of crop pests.
6. an insecticidal composition according to claim 5, wherein: the crops are one or more of fruit trees, vegetables, traditional Chinese medicinal materials, rice, cotton and tea trees.
7. An insecticidal composition according to claim 5, wherein: the pests are sucking mouth parts, such as aphids, thrips, whiteflies and leafhoppers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910959559.XA CN110574763A (en) | 2019-10-10 | 2019-10-10 | Insecticidal composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910959559.XA CN110574763A (en) | 2019-10-10 | 2019-10-10 | Insecticidal composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110574763A true CN110574763A (en) | 2019-12-17 |
Family
ID=68814368
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910959559.XA Pending CN110574763A (en) | 2019-10-10 | 2019-10-10 | Insecticidal composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110574763A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101188937A (en) * | 2005-06-01 | 2008-05-28 | 明治制果株式会社 | Pest control agents |
| CN102905528A (en) * | 2010-05-28 | 2013-01-30 | 巴斯夫欧洲公司 | Pesticidal mixtures |
| CN102917593A (en) * | 2010-05-28 | 2013-02-06 | 巴斯夫欧洲公司 | Pesticidal mixtures |
-
2019
- 2019-10-10 CN CN201910959559.XA patent/CN110574763A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101188937A (en) * | 2005-06-01 | 2008-05-28 | 明治制果株式会社 | Pest control agents |
| CN102905528A (en) * | 2010-05-28 | 2013-01-30 | 巴斯夫欧洲公司 | Pesticidal mixtures |
| CN102917593A (en) * | 2010-05-28 | 2013-02-06 | 巴斯夫欧洲公司 | Pesticidal mixtures |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102771482B (en) | Micro-capsule suspension-suspending agent containing atrazine | |
| CN1559216A (en) | Seed coating agent for preventing smut | |
| CN102771506A (en) | Nematicide composition containing oligosaccharides and application thereof | |
| CN103125505A (en) | Dispersible oil suspending agent containing florasulam and MCPA-isooctyl | |
| CN104082335B (en) | There is the insect-killing and mite-killing agent composition of synergism | |
| CN100411523C (en) | Compound pesticide of triperygium wilfordii alkaloid | |
| CN102334498B (en) | Insect-killing and disease-preventing suspension seed coating formulation | |
| CN105994439A (en) | Nontoxic and residue-free efficient plant protectant and preparation method thereof | |
| CN109221140A (en) | A kind of Pesticidal combination containing (R)-4-isopropenyl-1-methyl-1-cyclohexene and pyridine quinazoline | |
| CN103027051B (en) | Microcapsule suspending-suspending agent containing pendimethalin | |
| CN107950541A (en) | A kind of garlic seed coat agent composition and preparation method thereof | |
| CN106376590B (en) | A kind of Pesticidal combination containing Celastrus angulatus and indoxacarb | |
| CN102217638B (en) | Pesticide composition for preventing and treating plant virus diseases | |
| CN104522010A (en) | Synergistic acaricidal composition containing cyenopyrafen and bifenazate | |
| CN110574763A (en) | Insecticidal composition | |
| CN105503456A (en) | Insecticide composition containing thiamethoxam and cyhalothrin and application thereof | |
| CN101380002A (en) | Insecticide and acaricide composition containing spirodiclofen | |
| CN107950564A (en) | A kind of composite insecticide and its preparation process containing phenthoate dimephenthoate cidial and dimethoate emulsifiable concentrate | |
| CN107027783A (en) | A kind of pharmaceutical composition and its application containing the methaldehyde and tropane alkali | |
| CN107251908A (en) | A kind of water-base pesticides potentiating agent | |
| CN102599168A (en) | Pesticide composition containing Tolfenpyrad and Envidor | |
| CN106689200B (en) | Suspended bird repellent and preparation method thereof | |
| CN111280173A (en) | Pesticide composition containing sulfoxaflor and d-limonene | |
| CN109769848A (en) | A kind of plant growth regulator composition | |
| CN110012909A (en) | A kind of Pesticidal combination containing sanguinarine |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20200117 Address after: 057250 no.065, anwangzhuang village, Baizhai Township, Quzhou County, Handan City, Hebei Province Applicant after: Wang Zhichao Address before: 057250 No.1, Junxing Road, Quzhou West Industrial Zone, Handan City, Hebei Province Applicant before: Hebei Junxing Biochemical Co., Ltd. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191217 |