KR20090093083A - High density alkali water maker - Google Patents

High density alkali water maker

Info

Publication number
KR20090093083A
KR20090093083A KR1020080018414A KR20080018414A KR20090093083A KR 20090093083 A KR20090093083 A KR 20090093083A KR 1020080018414 A KR1020080018414 A KR 1020080018414A KR 20080018414 A KR20080018414 A KR 20080018414A KR 20090093083 A KR20090093083 A KR 20090093083A
Authority
KR
South Korea
Prior art keywords
electrode plate
water
ion exchange
electrolyte
electrolytic cell
Prior art date
Application number
KR1020080018414A
Other languages
Korean (ko)
Other versions
KR101029888B1 (en
Inventor
박태욱
Original Assignee
박태욱
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 박태욱 filed Critical 박태욱
Priority to KR1020080018414A priority Critical patent/KR101029888B1/en
Publication of KR20090093083A publication Critical patent/KR20090093083A/en
Application granted granted Critical
Publication of KR101029888B1 publication Critical patent/KR101029888B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/14—Alkali metal compounds
    • C25B1/16—Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00—Diaphragms; Spacing elements
    • C25B13/04—Diaphragms; Spacing elements characterised by the material
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • C25B9/77—Assemblies comprising two or more cells of the filter-press type having diaphragms

Abstract

A manufacturing device of high density alkali water is provided to obtain high density alkaline water by spaying an anion layer in the cathode direction of an ion exchange film and passing the ion exchange film though cation and discharging the water of the cathode side. In the electrolytic cell, an anode electrode board(22) and a cathode electrode board(23) are installed. The ion exchange film is installed between the anode electrode board and cathode electrode board. The electrolytic cell fuses electrolyte(11) and supplies the electrolyte to the cathode side of the electrolytic cell. An anion layer is installed at the side of the ion exchange film. The anion later blocks the ion infiltration of the acid component. In the cathode electrode board, the alkali component is moved by the anion layer and the high density alkaline water is obtained.

Description

강알카리수 제조장치{High density alkali water maker}High Alkaline Water Production Equipment

본 발명은 이온교환수지를 이용한 전기 분해방식을 기초로 별도의 전해질조를 사용하여 양이온을 순환 공급토록 하고, 이온교환막은 양이온만 통과시키고 음이온은 투과를 차단 시키는 일방향 이온교환막을 사용하여 음극측에서 강알카리수를 수득토록 하는 강알카리수 제조장치에 관한 것이다.The present invention uses a separate electrolyte tank based on the electrolysis method using an ion exchange resin to circulate and supply the cation, the ion exchange membrane in the cathode side using a one-way ion exchange membrane to pass only the cation and the anion blocks permeation The present invention relates to a strong alkaline water production device for obtaining strong alkaline water.

일반적으로 물의 전기 분해방식은 지하수나 수돗물을 음극과 양극이 동축 상태로 배열된 원통을 통과시켜 전기 분해하거나,In general, the electrolysis method of water is to electrolyze ground water or tap water through a cylinder arranged in a coaxial state of the cathode and the anode,

음극과 양극을 이루는 각 전극 사이에 격막을 설치한 전해조를 설치하고 공급한 물이 격막을 상호 통과시켜 이온교환이 이루어짐으로써 알카리수와 산성수를 생성시켜 농업용수나 의료용수로 사용하여 왔다. An electrolytic cell with a diaphragm is installed between the electrodes forming the cathode and the anode, and the supplied water passes through the diaphragm to perform ion exchange to generate alkaline water and acidic water, which has been used as agricultural water or medical water.

그러나 지구 온난화 등 지구촌의 환경문제는 산업용 세척 분야에도 페기물 처리에 많은 규제나 의무가 생겨 지금까지 사용해왔던 각종 유, 무기용제의 세척제들이 사용을 할 수 없게 되어 세척제를 개발하지 않으면 않 되게 되었다.However, global environmental problems such as global warming have caused a lot of regulations and obligations to treat waste in the industrial washing field, and the cleaners used for various oil and inorganic solvents that have been used until now have to be developed.

범세계적으로 많은 수용성 세제들이 개발되어 사용되고 있으나 산업용 각종 재료들이 필요로 하는 세척요구를 만족시키기 위해서는 유화력이 뛰어나고, 방청 효과가 있는 세정제나 세척 설비를 만들어야만 했다. Many water-soluble detergents have been developed and used all over the world, but in order to satisfy the washing demands required by various industrial materials, it was necessary to make a cleaning agent or a washing machine having excellent emulsifying power and anti-rust effect.

예를 들면, 각종 자동차 부품들이 프레싱이나 볼링 시 상당량의 가공유를 사용하는데 다음 공정에 보내기 위하여는 세척을 하고 철강 제품일 경우에는 대기 시간 동안 방청방지를 위하여 방청제를 도포하여야 하므로 세척 브로잉 건조, 방청 기능을 위한 대형장비가 필요하게 되어 많은 투자를 해야만 하는 어려움에 처하게 되었다.For example, various automobile parts use a large amount of processed oil when pressing or bowling. To send to the next process, they need to be washed and steel products have to be coated with rust preventive to prevent rust during waiting time. The need for large equipment for function has led to the difficulty of making a large investment.

이온교환방식을 이용한 알카리수 및 산성수 제조장치의 예로는 도 1 과 같이 전해조(1)의 양측에 양극전극판(2)과 음극전극판(3)을 설치하여 직류 전원을 공급하고, 전해조(1)의 중앙에는 이온교환막(5)을 설치하여, 양이온은 음극전극판(3) 측으로, 음이온은 양극천극판(2) 측으로 이동하여 음극전극판(3) 측으로는 알카리수를, 양극전극판(2) 측으로는 산성수를 수득한다. As an example of the alkaline water and acidic water production apparatus using the ion exchange method, as shown in FIG. 1, the positive electrode plate 2 and the negative electrode plate 3 are installed on both sides of the electrolytic cell 1 to supply DC power, and the electrolytic cell 1 ), An ion exchange membrane (5) is provided in the center thereof, and positive ions move toward the cathode electrode plate 3 side, anions move toward the cathode electrode plate 2 side, and alkali water is supplied to the cathode electrode plate 3 side, and the anode electrode plate 2 On the) side, acidic water is obtained.

이 경우 산성수는 살균 기능 용도로, 알카리수는 비료 용도 등으로 다양하게 사용한다. 그러나 강산성수와 강알카리수를 수득하지만, 예를 들어 강알카리수 만을 사용하는 경우, 강산성수는 폐수가 되므로, 이를 처리하는 별도의 비용이 들게 되며, 강알카리수에는 용존산소가 포함되므로, 이를 사용하여 금속이나 엔진 세척제로 사용할 경우, 세척은 되지만, 용존 산소가 엔진 내 표면에 붙어 금방 녹이 나게 되어 발청을 이루므로, 방청을 위한 별도의 공정과 설비를 갖추어야 하는 문제점이 있다.In this case, acidic water is used for sterilizing function and alkaline water is used for various purposes. However, if strong acidic water and strong alkaline water are obtained, for example, only strong alkaline water is used, since strong acidic water becomes wastewater, there is a separate cost of treating it, and since strong alkaline water contains dissolved oxygen, it can be used for a metal or engine. When used as a cleaning agent, it is washed, but dissolved oxygen is quickly melted to the surface of the engine to form the rust, there is a problem to have a separate process and equipment for rust prevention.

본 발명은 이를 해결하고자 하는 것으로, 친환경적이고 발청을 방지할 수 있는 친철강적 세척제 제조장치를 제공하려는 것이 본 발명의 목적이다.The present invention is to solve this problem, it is an object of the present invention to provide an environment-friendly and non-corrosive cleaning agent manufacturing apparatus that can prevent the rust.

본 발명의 다른 목적은 이온교환이 양이온만 음극측으로 교환 가능토록 하여 강산성수의 제조 없이 고농도의 강알카리를 제조 가능토록 하려는 것이다.Another object of the present invention is to allow the ion exchange to exchange only the cation to the cathode side to produce a high concentration of strong alkali without the production of strong acidic water.

이를 위하여 본원발명은 별도의 전해질조를 만들어 일정 농도의 전해질을 순환공급토록 하여 전해질 공급이 용이하도록 하고,To this end, the present invention makes a separate electrolyte tank to circulate and supply the electrolyte of a certain concentration to facilitate the supply of electrolyte,

이온교환막의 음극방향에 음이온의 투과를 차단하는 음이온층을 도포하여 이온교환막이 양이온만 투과토록 하고,Apply an anion layer to block the anion permeation in the direction of the cathode of the ion exchange membrane, so that the ion exchange membrane permeates only cations,

양이온만 투과한 음극측의 물을 배출하여 강알카리수를 수득 가능토록 하는 강알카리수 제조장치를 제공한다.The present invention provides a strong alkaline water production apparatus capable of obtaining strong alkaline water by discharging water on a negative electrode side through which only positive ions have passed.

이상과 같이 본원발명은 친환경적이고 발청을 방지할 수 있는 친철강적 세척제 기능을 하는 강알카리수 제조장치를 제공한다.As described above, the present invention provides a strong alkaline water production apparatus that functions as an environment-friendly and anti-corrosive detergent that can prevent corrosion.

본 발명은 또한 이온교환이 양이온만 음극측으로 교환 가능토록 하여 강산성수의 제조 없이 고농도의 강알카리를 제조 가능토록 하여 폐수 발생이 없는 강알카리수 제조장치를 제공한다.The present invention also provides an apparatus for producing strong alkaline water, in which ion exchange is possible to exchange only cations to the cathode side, so that high concentrations of strong alkali can be produced without producing strong acidic water.

도 1 은 종래의 이온교환수 제조장치의 구성도,1 is a block diagram of a conventional ion exchange water production apparatus,

도 2 는 본 발명의 강알카리수 제조장치 구성도이다.2 is a block diagram of a strong alkaline water production apparatus of the present invention.

도면의 주요 부분에 대한 부호의 설명Explanation of symbols for the main parts of the drawings

10;전해질조 11;전해질 13,13;순환관 15;순수공급관 16;순수공급관 20;전해조 22;양극전극판 23;음극전극판 25;이온교환막 26;음이온층 27;순수공급관 28;강알카리수 배출구 29;밸브 P;펌프 10; electrolyte tank 11; electrolyte 13, 13; circulation pipe 15; pure water supply pipe 16; pure water supply pipe 20; electrolytic bath 22; anode electrode plate 23; cathode electrode plate 25; ion exchange membrane 26; anion layer 27; pure water supply pipe 28; strong alkaline water Outlet 29; valve P; pump

도 2 는 본 발명의 구성도로, 전해조(20)에 양극전극판(22)과 음극전극판(23)을 설치하고, 이들 사이에 이온교환막(25)을 설치하고;2 is a configuration diagram of the present invention, in which an anode electrode plate 22 and a cathode electrode plate 23 are provided in an electrolytic cell 20, and an ion exchange membrane 25 is provided therebetween;

전해질(11)을 용융시켜 전해조(20)의 음극측에 공급하는 별도의 전해질조(10)를 부가하고;Adding an additional electrolyte tank 10 for melting the electrolyte 11 and supplying it to the cathode side of the electrolytic cell 20;

상기 이온교환막(25)의 음극전극판(23) 측 면에는 산성 성분의 이온침투를 차단하는 음이온층(26)을 부가하여, 알카리 성분만 음극전극판(23) 측으로 이동하여 음극전극판(23) 측에서 강알카리수의 수득을 가능토록 구성한다. Anion layer 26 is added to the cathode electrode plate 23 side of the ion exchange membrane 25 to block ion permeation of acidic components, so that only the alkaline component is moved to the cathode electrode plate 23 side, so that the cathode electrode plate 23 is provided. It is possible to obtain a strong alkali water on the) side.

상기 전해질(11)은 탄산칼륨으로, 순수 10리터에 탄산칼륨 1키로그램 비율로 첨가하는 것이 좋다.The electrolyte 11 is potassium carbonate, which is preferably added to 10 liters of pure water at a ratio of 1 kg of potassium carbonate.

상기 음이온층(26)은 음이온을 발생하는 토르말린, 마그네슘, 칼슘, 알루미늄, 갈륨 중의 적어도 일종을 재료로 코팅층을 이룬다.The anion layer 26 forms a coating layer of at least one of tourmaline, magnesium, calcium, aluminum, and gallium generating anion.

상기 음극전극판(23) 측 및 전해질조(10)에 공급하는 물은 프리 필터(바람직한 여과 밀도는 5㎛로, 이온교환막(25)의 수명을 연장토록 그 이상의 입자를 여과시킴)와 활성탄 필터(물의 잔류염소와 미량의 유기물을 제거한 순수를 제공)를 거친 순수로 순수공급관(27)(15)으로 공급되고(필요시 순수는 역삼투막(Reverse Osmosis 막)을 추가(또는 단독으로)로 통과 한 물을 사용할 수 있다), 생성된 강알카리수는 강알카리수배출구(28)로 배출된다. 물론 강알카리수배출구(28)에는 배출시 여닫히도록 하는 밸브(29)를 설치하여야 한다.Water supplied to the cathode electrode plate 23 side and the electrolyte tank 10 is a pre-filter (preferably filtration density of 5㎛, which filters more particles to extend the life of the ion exchange membrane 25) and activated carbon filter Pure water, which is passed through (provides pure water from which residual chlorine and trace organics are removed), is supplied to the pure water supply pipes 27 and 15 (if necessary, pure water is additionally passed through (or alone) a reverse osmosis membrane). Water may be used), and the generated strong alkaline water is discharged to the strong alkaline water outlet 28. Of course, the strong alkaline water outlet 28 must be provided with a valve (29) to open and close when discharged.

전해질조(10)에서 녹은 전해질을 포함하는 전해수는 펌프(P)를 통하여 전해조(20)의 양극 전극판(22) 측으로 순환 공급하도록 순환관(12,13)을 설치한다. 바람직한 펌프(P)의 수압은 0.1MPa 이상이어야 전해질조의 전해질을 순환 공급토록 한다.The electrolytic water containing the electrolyte dissolved in the electrolytic cell 10 is provided with circulation pipes 12 and 13 to circulate and supply the positive electrode plate 22 side of the electrolytic cell 20 through the pump P. Preferred water pressure of the pump (P) is not less than 0.1MPa to circulate the supply of the electrolyte of the electrolyte tank.

이와 같이 구성한 본원발명은 이온교환수 작용의 기본 원리는 동일하므로 이에 설명은 생략한다. 다만 본원발명은 별도의 전해질조(10)를 구비하고, 전해질(11)(예를 들어 탄산칼륨(K2CO3)) 1키로그램을 순수공급관(15)을 통한 순수 10리터 비율로 첨가하고, 전해질을 녹도록 저은 다음 펌프(P)를 작동시켜 전해조(20)의 양극전극판(22)측으로 공급하고, 순환관(12,13)을 통하여 순환되도록 한다. 이는 전해질이 녹아서 양극 전극판(22)측의 전해조(20)에서 양이온(K+)으로 분해된 것이 계속하여 이온교환막(25)을 통하여 음극전극판(23)측으로 이온교환을 지속적으로 이루어지도록 하는 작용을 한다.The present invention constructed as described above has the same basic principle of ion-exchanged water action, and thus description thereof is omitted. However, the present invention is provided with a separate electrolyte tank 10, 1 kg of electrolyte 11 (for example potassium carbonate (K 2 CO 3 )) is added at a rate of 10 liters of pure water through the pure water supply pipe 15, The next step is to operate the pump P to melt the electrolyte to supply to the positive electrode plate 22 side of the electrolytic cell 20 and to circulate through the circulation pipes 12 and 13. This causes the electrolyte to dissolve and decompose into positive ions (K + ) in the electrolytic cell 20 on the positive electrode plate 22 side to continuously carry out ion exchange to the negative electrode plate 23 side through the ion exchange membrane 25. It works.

한편 본원발명은 이온교환막(25)의 음극전극판(23) 대향면에 음이온층(26)을 형성하였기에, 음극전극판(23)측의 전해조에 공급하는 순수를 전기분해하여 양이온(H+)과 음이온(OH-)이 발생하지만, 음이온은 은이온층(26)의 반발 작용으로 양극전극판(22)측으로 이동을 못하고, 대신 양극 전극판(22) 측의 양이온(K+) 성분만 일방향으로 이온교환되어 음극전극판(23)측으로 이온교환된다. 즉, 음이온층(26)을 형성한 이온교환막(25) 때문에 양극전극판(22)측의 전해조에는 음이온의 증가가 없이 단순히 양이온만 이온교화되도록 함으로써 강산성수의 발생이 않 생겨 강 산성수를 처리하는 폐수 처리비용이 없어지게 된다.On the other hand, according to the present invention, since the anion layer 26 is formed on the opposite surface of the cathode electrode plate 23 of the ion exchange membrane 25, the pure water supplied to the electrolytic cell on the cathode electrode plate 23 side is electrolyzed to cation (H + ). And anion (OH − ) is generated, but the anion cannot move toward the positive electrode plate 22 side due to the repulsive action of the silver ion layer 26, and instead, only the cation (K + ) component on the positive electrode plate 22 side is directed in one direction. It is ion-exchanged and ion-exchanged to the cathode electrode plate 23 side. That is, the ion exchange membrane 25 having the anion layer 26 formed thereon does not generate strong acidic water by simply ionizing cations in the electrolytic cell on the positive electrode plate 22 side without increasing anion. Wastewater treatment costs are eliminated.

아울러 음극 전극판(23) 측의 전해조(20) 부위는 양이온(K+)이 과잉 공급된 강알카리수의 생성을 가능토록 작용한다. 시간과 순수 공급량 및 전해조의 크기에 따라 차이가 있으나 수소이온온도(pH 15) 의 강알카리수의 수득이 가능함을 확인하였다.In addition, the portion of the electrolytic cell 20 on the side of the negative electrode plate 23 acts to enable the generation of strong alkaline water in which the cation (K + ) is excessively supplied. It was confirmed that it is possible to obtain a strong alkali water of hydrogen ion temperature (pH 15), although there is a difference depending on the time, the pure water supply and the size of the electrolyzer.

또한 전해질조(10)를 외부에 별도로 설치함으로써, 전해조의 개폐 작용없이 지속적으로 강알카리수의 제조를 가능토록 작용하는바, 이는 시험에 의하여 설정한 전해질양과, 강알카리수의 수득이 가능한 시간을 미리 파악하면, 별도의 타이머나 별도의 전해질 추가공급수단(도시하지 않음)을 통하여 공급토록 함으로써, 휴식 없이 장시간 강알카리수를 지속적으로 제조 가능토록 작용한다.In addition, by separately installing the electrolytic cell 10 to the outside, it is possible to continuously produce a strong alkaline water without opening and closing action of the electrolytic cell, which determines in advance the amount of electrolyte set by the test, and the time to obtain a strong alkaline water If so, by supplying through a separate timer or a separate electrolyte additional supply means (not shown), it is possible to continuously produce strong alkaline water for a long time without rest.

본 발명에서 사용하는 이온교환막은 바람직하기는 약 3000시간을 기준으로 교환하는 것이 성능과 품질을 유지하나 이에 한정하지는 않고, 제조사에 따라 특성 시간을 기초로 타이머를 작동시키거나, 메모하였다가 교체토록 한다.Preferably, the ion exchange membrane used in the present invention maintains performance and quality, but is not limited thereto. The timer is operated or memoized based on the characteristic time depending on the manufacturer. do.

바람직한 실시예로는 전해질조(10)에 순수10리터에 전해질(K2CO3)1키로를 넣어 전해질을 녹인다.In a preferred embodiment, the electrolyte (K 2 CO 3 ) 1 kilo in 10 liters of pure water in the electrolyte tank 10 to dissolve the electrolyte.

그리고 전해조(20)에는 순수를 순수공급관(16,27)을 통하여 공급하여 전해조(20)를 순수로 채운다(물론 도 2 에는 도시하지 않았지만 뚜껑을 닫아야 하고 뚜껑에는 가스 배출공을 구비하여야 한다).The electrolytic cell 20 is supplied with pure water through the pure water supply pipes 16 and 27 to fill the electrolytic cell 20 with pure water (although not shown in FIG. 2, the lid should be closed and the lid should have a gas discharge hole).

이 상태에서 전해질조(10)의 전해수를 펌프(P)를 통하여 공급하면서 순환관(12)으로 순환되도록 한다. 이러한 순환은 전해질을 이루는 양이온(K+)이 지속적으로 공급되도록 하기 위함이다. 물론 순수공급관(160을 통한 순수를 받아서 전해질과의 상호 반응을 하는 것은 물론이다. 이는 순수의 수소이온(H+)은 전해질과 반응하여 H2CO3 와 KHCO3 반응하고 과량의 전해질(K+)이 이온교환작용 하는 것이다. 물론 반응하지 않은 산소는 가스로 방출하게 된다. 이 경우 전해질을 순환하여 도 2 와 같이 지속적으로 공급하니까, 양이온(K+)이 과량으로 되어 이온교환막(25)을 통하여 음극전극판(23) 측으로 이동하게 된다.아울러 전해조(20)의 뚜껑 개방 없이 전해질을 공급 가능토록 작용한다. 이 경우 순수공급관(27)은 한곳에 설치할 수도 있고, 2곳에 설치할 수도 있다.In this state, the electrolytic water of the electrolyte tank 10 is circulated to the circulation pipe 12 while supplying the pump P. This circulation is to continuously supply the cation (K + ) constituting the electrolyte. Of course, the pure water supply pipe (160) receives the pure water and reacts with the electrolyte. Of course, the hydrogen ions (H + ) of pure water react with the electrolyte to react with H 2 CO 3 and KHCO 3 and excess electrolyte (K + Of course, the unreacted oxygen is released as a gas, in which case the electrolyte is circulated and continuously supplied as shown in Fig. 2, so that the cation (K + ) becomes excessive and the ion exchange membrane 25 is removed. It moves to the cathode electrode plate 23 side. In addition, it serves to supply the electrolyte without opening the lid of the electrolytic cell 20. In this case, the pure water supply pipe 27 may be installed in one place or in two places.

한편 음극전극판(23) 측으로는 이온교환된 양이온(K+)이 음이온(OH-)과 결합하여 수산화칼륨(KOH)으로 되고, 순수가 분해된 수소(H2)는 가스로 분출되고, 양이온은 전해질로 지속적으로 이온교환 상태로 공급받으므로, 음극전극판(23)측의 전해조(20)는 강알카리수로 되어 강알카리수 배출구(28)로 배출토록 하여 강알카리수를 수득하게 된다. 이 경우 음이온(OH-)은 음이온층(26)에 의하여 전기적으로 반발작용하므로 이온교환막(25)의 이온 교환을 못하게 되어 양극전극판(22) 측에서 산성수가 생성되지 않게 된다. 바람직한 알카리수 생성량은 전해질조에 순수를 10리터에, 전해질 1키로그램을 첨가하고, 전해조에서는 양이온 투과에 의한 강알카리수 생성량은 1000키로그램이었고, 강알카리수의 수소이온농도는 최대 12.5 이었다.The negative electrode plate 23 toward the ion-exchange the cation (K +) is the anion (OH -) in combination with and with potassium hydroxide (KOH), the purified water is decomposition of hydrogen (H 2) is ejected into the gas, cation Since the silver electrolyte is continuously supplied in an ion exchange state, the electrolytic cell 20 on the cathode electrode plate 23 side becomes strong alkaline water and is discharged to the strong alkaline water outlet 28 to obtain strong alkaline water. In this case, since the anion (OH − ) is electrically repulsed by the anion layer 26, ion exchange of the ion exchange membrane 25 is prevented, and acidic water is not generated at the anode electrode plate 22 side. The preferred amount of alkaline water was added to 10 liters of pure water and 1 kilogram of electrolyte in the electrolytic cell. In the electrolytic cell, the strong alkaline water produced by cation permeation was 1000 kilograms, and the hydrogen ion concentration of the strong alkaline water was at most 12.5.

Claims (4)

전해조에 양극전극판과 음극전극판을 설치하고, 이들 사이에 이온교환막을 가지는 알카리수 제조장치에 있어서,In the alkaline water production apparatus which has a positive electrode plate and a negative electrode plate in an electrolytic cell, and has an ion exchange membrane between them, 전해질(11)을 용융시켜 전해조(20)의 음극측에 공급하는 별도의 전해질조(10)를 부가하고;Adding an additional electrolyte tank 10 for melting the electrolyte 11 and supplying it to the cathode side of the electrolytic cell 20; 상기 이온교환막(25)의 음극전극판(23) 측 면에는 산성 성분의 이온침투를 차단하는 음이온층(26)을 부가하여, 알카리 성분만 음극전극판(23) 측으로 이동하여 음극전극판(23) 측에서 강알카리수의 수득을 가능토록 한 것을 특징으로 하는 강알카리수 제조장치.Anion layer 26 is added to the cathode electrode plate 23 side of the ion exchange membrane 25 to block ion permeation of acidic components, so that only the alkaline component is moved to the cathode electrode plate 23 side, so that the cathode electrode plate 23 is provided. Strong alkali water production apparatus, characterized in that to obtain a strong alkali water at the) side. 제 1 항에 있어서, 전해질(11)은 탄산칼륨으로, 순수 10리터에 탄산칼륨 1키로그램 비율로 첨가하는 것을 특징으로 하는 강알카리수 제조장치. The strong alkaline water production apparatus according to claim 1, wherein the electrolyte (11) is potassium carbonate, which is added to 10 liters of pure water at a ratio of 1 kilogram of potassium carbonate. 제 1 항에 있어서, 음이온층(26)은 토르말린, 마그네슘, 칼슘, 알루미늄, 갈륨 중의 적어도 일종을 재료로 코팅층을 이룬 것을 특징으로 하는 강알카리수 제조장치.The strong alkaline water production apparatus according to claim 1, wherein the anion layer (26) forms a coating layer of at least one of tourmaline, magnesium, calcium, aluminum, and gallium. 제 1 항에 있어서, 음극전극판(23) 측에 공급하는 물은 프리필터와 활성탄 필터를 거친 순수인 것을 특징으로 하는 강알카리수 제조장치.The strong alkaline water production apparatus according to claim 1, wherein the water supplied to the cathode electrode plate (23) is pure water passed through a prefilter and an activated carbon filter.
KR1020080018414A 2008-02-28 2008-02-28 High density alkali water maker KR101029888B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020080018414A KR101029888B1 (en) 2008-02-28 2008-02-28 High density alkali water maker

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020080018414A KR101029888B1 (en) 2008-02-28 2008-02-28 High density alkali water maker

Publications (2)

Publication Number Publication Date
KR20090093083A true KR20090093083A (en) 2009-09-02
KR101029888B1 KR101029888B1 (en) 2011-04-15

Family

ID=41301604

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020080018414A KR101029888B1 (en) 2008-02-28 2008-02-28 High density alkali water maker

Country Status (1)

Country Link
KR (1) KR101029888B1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101252109B1 (en) * 2011-01-28 2013-04-12 한국원자력연구원 Apparatus for alkalization of water using the tourmaline and electrolysis, apparatus and method for treating wastewater using the same
KR101691874B1 (en) * 2016-03-18 2017-01-03 주식회사 성민코리아 Method of producing alkaline water
US9689079B2 (en) 2011-12-08 2017-06-27 Ecospec Global Technology Pte Ltd. Composite electrode for electrolytically producing alkaline water, apparatus comprising the same and use of the alkaline water produced
CN107308183A (en) * 2017-07-13 2017-11-03 深圳市新量子科技有限公司 A kind of hemopathic Chinese medicine of auxiliary treatment or food hydroxyl radical negative ion aqua

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3453414B2 (en) * 1993-12-03 2003-10-06 ホシザキ電機株式会社 Electrolyzed water generator
JP3139159U (en) 2007-11-20 2008-01-31 ファースト・オーシャン株式会社 Electrolyzer for water electrolysis

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101252109B1 (en) * 2011-01-28 2013-04-12 한국원자력연구원 Apparatus for alkalization of water using the tourmaline and electrolysis, apparatus and method for treating wastewater using the same
US9689079B2 (en) 2011-12-08 2017-06-27 Ecospec Global Technology Pte Ltd. Composite electrode for electrolytically producing alkaline water, apparatus comprising the same and use of the alkaline water produced
KR101691874B1 (en) * 2016-03-18 2017-01-03 주식회사 성민코리아 Method of producing alkaline water
CN107308183A (en) * 2017-07-13 2017-11-03 深圳市新量子科技有限公司 A kind of hemopathic Chinese medicine of auxiliary treatment or food hydroxyl radical negative ion aqua

Also Published As

Publication number Publication date
KR101029888B1 (en) 2011-04-15

Similar Documents

Publication Publication Date Title
JP4828420B2 (en) Machining fluid quality control device and method, and electrical discharge machining device
JP5102157B2 (en) Method and apparatus for removing and recovering copper from copper-containing acidic waste liquid
JP2011056345A (en) Desalination system
EP3848331A1 (en) Desalination system capable of producing hydrogen
KR101029888B1 (en) High density alkali water maker
WO2013176111A1 (en) Processing method and apparatus for copper chloride-containing acidic waste liquids
JP2018035024A (en) Method for producing sodium hypochlorite, and sodium hypochlorite production device
JP5731262B2 (en) Desalination treatment method and desalination treatment system
JP4641003B2 (en) Electrolyzed water generation method and electrolyzed water generator
KR102328974B1 (en) A fresh water system capable of producing hydrogen gas
JP4394941B2 (en) Electrolytic ozonizer
RU162651U1 (en) DEVICE FOR INTEGRATED PRODUCTION OF CHLORINE-CONTAINING REAGENTS AND SODIUM FERRATE
JP2010209370A (en) Production apparatus of ozone water and production method of ozone water
JP5237850B2 (en) Water treatment method and mechanism
JP6236392B2 (en) Continuous electrolysis method using electrolyzer for producing polysulfide and electrolysis apparatus for carrying out the method
KR101367779B1 (en) Nacl supply structure of generation-system for antiseptic solution including chlorine
JP2007014828A (en) Apparatus for producing strong alkaline electrolytic water and strong alkaline electrolytic water generated by its apparatus
JP2009208073A (en) Water treatment method and mechanism
WO2017138047A1 (en) Water treatment apparatus
JP2004249221A (en) Desalinizing method of seawater or the like using alkali ionized water generator and apparatus therefor
WO2022254878A1 (en) Method and apparatus for producing sodium hypochlorite solution
JP2004275841A (en) Strong alkaline electrolytic water and method and apparatus for making the same
JP2003117554A (en) Cleaning water producing apparatus
JP2004089975A (en) Strong electrolytic water generator
CN110028193B (en) Waste water recycling system

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E90F Notification of reason for final refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20140401

Year of fee payment: 4

FPAY Annual fee payment

Payment date: 20160404

Year of fee payment: 6

FPAY Annual fee payment

Payment date: 20170410

Year of fee payment: 7

FPAY Annual fee payment

Payment date: 20190110

Year of fee payment: 8

R401 Registration of restoration
FPAY Annual fee payment

Payment date: 20190410

Year of fee payment: 9