WO2017138047A1 - Water treatment apparatus - Google Patents

Water treatment apparatus Download PDF

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Publication number
WO2017138047A1
WO2017138047A1 PCT/JP2016/004622 JP2016004622W WO2017138047A1 WO 2017138047 A1 WO2017138047 A1 WO 2017138047A1 JP 2016004622 W JP2016004622 W JP 2016004622W WO 2017138047 A1 WO2017138047 A1 WO 2017138047A1
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Prior art keywords
water
water tank
tank
electrode
treatment apparatus
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PCT/JP2016/004622
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French (fr)
Japanese (ja)
Inventor
亮子 乾
泰士 山本
敦志 辻
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パナソニックIpマネジメント株式会社
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Publication of WO2017138047A1 publication Critical patent/WO2017138047A1/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods

Definitions

  • This disclosure relates to water treatment equipment.
  • Alkaline water is known to contribute to the maintenance and enhancement of physical health.
  • alkaline water having a pH of about 9.5 is effective in improving gastrointestinal conditions.
  • Alkaline water having a pH higher than 10 is used for cooking.
  • a water treatment device is a device capable of producing such alkaline water. This is sometimes called an alkali ion water conditioner or the like.
  • a conventional water treatment apparatus includes an anode tank provided with an anode, a cathode tank provided with a cathode, a diaphragm partitioning the anode tank and the cathode tank, and a supply passage for supplying raw water to each of these tanks. .
  • the raw water passes through the anode tank to generate acidic water, and the raw water adds the cathode tank to generate alkaline water.
  • Alkaline water with high dissolved hydrogen concentration is thought to contribute to the removal of active oxygen, which is presumed to cause aging and disease.
  • a method for generating alkaline water having a high dissolved hydrogen concentration using a conventional water treatment device a method for increasing the degree of electrolysis in a cathode tank and generating a large amount of hydrogen is known.
  • this method since the pH of alkaline water further increases, it is difficult to produce alkaline water suitable for drinking.
  • Patent Document 1 discloses an example of a water treatment apparatus for solving the above problems.
  • this water treatment apparatus in addition to the anode tank, the cathode tank, and the diaphragm, the second anode tank to which the acidic water generated in the anode tank is supplied, and the alkaline water generated in the cathode tank is supplied.
  • alkaline water is electrolyzed by a solid polymer membrane (SPE) method, and hydrogen and hydroxide ions are generated. For this reason, the dissolved hydrogen concentration of the alkaline water supplied to the second cathode tank is increased by the generated hydrogen.
  • SPE solid polymer membrane
  • the hydrogen ions generated in the second anode tank move to the second cathode tank via the ion exchange membrane, an increase in the pH of the alkaline water supplied to the second cathode tank is suppressed.
  • the dissolved hydrogen concentration is increased while the increase in pH of the alkaline water supplied to the second cathode tank is suppressed, so that the dissolved hydrogen concentration is high and can be used for drinking. Suitable alkaline water is produced.
  • One form of the water treatment device includes a first water tank, a second water tank, a third water tank, a fourth water tank, a first electrode provided in the first water tank, A second electrode corresponding to the first electrode, a third electrode provided in the third water tank, and a fourth electrode corresponding to the third electrode provided in the fourth water tank. Electrode. Furthermore, one form of the water treatment apparatus supplies the third water tank and the fourth water tank with the ion exchange membrane that partitions the third water tank and the fourth water tank, and the water electrolyzed in the first water tank. A first water channel for taking out without performing, and a first communication passage communicating the second water tank and the fourth water tank.
  • FIG. 1 is a schematic diagram of the entire water treatment apparatus according to the first embodiment.
  • FIG. 2 is a schematic diagram of the entire water treatment apparatus according to the second embodiment.
  • FIG. 3 is a schematic diagram of the entire water treatment apparatus according to the third embodiment.
  • FIG. 4 is a schematic diagram of the entire water treatment apparatus according to the fourth embodiment.
  • One form of the water treatment device includes a first water tank, a second water tank, a third water tank, a fourth water tank, a first electrode provided in the first water tank, A second electrode corresponding to the first electrode, a third electrode provided in the third water tank, and a fourth electrode corresponding to the third electrode provided in the fourth water tank. Electrode. Furthermore, one form of the water treatment apparatus supplies the third water tank and the fourth water tank with the ion exchange membrane that partitions the third water tank and the fourth water tank, and the water electrolyzed in the first water tank. A first water channel for taking out without performing, and a first communication passage communicating the second water tank and the fourth water tank.
  • the water treatment apparatus when a voltage is applied to the first electrode and the second electrode so that the potential of the first electrode is higher than the potential of the second electrode, acidic water is generated in the first water tank. And alkaline water is generated in the second water tank. Since the acidic water is not supplied to the third water tank and the fourth water tank by including the first water channel in the water treatment device, the possibility that the third water tank and the fourth water tank are chemically damaged is reduced. To do.
  • the third water tank can be connected to a raw water channel that supplies raw water.
  • the alkaline water supplied to the fourth water tank is electrolyzed, so that the dissolved hydrogen concentration of the alkaline water is increased. Moreover, the alkaline water which passes through a 4th water tank by the hydrogen ion which generate
  • the fourth water tank can be connected to a raw water channel that supplies raw water.
  • raw water is supplied to the third water tank and the fourth water tank, and the third electrode and the fourth electrode are set such that the potential of the fourth electrode is higher than the potential of the third electrode.
  • acidic water is generated in the fourth water tank.
  • the first communication path further communicates the second water tank and the third water tank.
  • the alkaline water supplied to the fourth water tank is electrolyzed, so that the dissolved hydrogen concentration of the alkaline water is increased. Moreover, the hydrogen ion which generate
  • the water treatment apparatus further includes a second water channel for taking out the water electrolyzed in the second water tank without supplying the water to the third water tank and the fourth water tank.
  • the said water treatment apparatus can suppress that a scale adheres to a 4th water tank by taking out alkaline water using a 2nd water channel.
  • the water treatment device 10 includes a first water tank 31 and a second water tank 35 separated by a diaphragm 39, and a third water tank partitioned by an ion exchange membrane 49.
  • a hydrogen water tank 40 having a water tank 41 and a fourth water tank 45 is provided.
  • the alkaline water tank 30 and the hydrogen water tank 40 are stored in the case 20.
  • a faucet 1 and a flow path switch 2 are provided outside the water treatment apparatus 10.
  • the faucet 1 discharges tap water.
  • the flow path switching unit 2 is attached to the faucet 1 and supplies tap water to the water supply port 11 in accordance with a user operation.
  • the water treatment apparatus 10 includes a water supply port 11, a first water discharge port 12, a second water discharge port 13, and a third water discharge port 14 protruding toward the outside of the case 20.
  • the water supply port 11 supplies tap water to the inside of the water treatment apparatus 10.
  • the first water discharge port 12 discharges alkaline water or alkaline hydrogen water having a pH higher than that of tap water from the water treatment device 10.
  • Alkaline hydrogen water has a higher dissolved hydrogen concentration than alkaline water.
  • the second water outlet 13 and the third water outlet 14 discharge acidic water having a pH lower than that of tap water from the water treatment device 10.
  • the case 20 includes a water purification unit 21, a first power source 24, a second power source 25, a first switch 26, a second switch 27, a raw water channel 50, a first communication channel 51, and a first water channel 52.
  • the 1st water supply channel 53, the 1st pipe 61, and the 2nd pipe 62 are stored.
  • the water purification unit 21 is an activated carbon type and a filtration membrane type water purifier, and purifies tap water.
  • the raw water which is the water purified by the water purification unit 21, passes through the raw water channel 50 and is supplied to the alkaline water tank 30.
  • the water purification unit 21 includes an activated carbon unit 22 and a filtration membrane unit 23.
  • the activated carbon part 22 has activated carbon, and removes organic substances, odors, residual chlorine and the like from tap water.
  • the filtration membrane part 23 has a polyethylene hollow fiber membrane, and removes particles of 0.1 ⁇ m or more, bacteria, red rust, and the like from the water that has passed through the activated carbon part 22.
  • the first power supply 24 and the second power supply 25 are DC power supplies used for electrolysis in the alkaline water tank 30 and the hydrogen water tank 40.
  • the potential V1A of the anode 24X of the first power supply 24 is higher than the potential V1B of the cathode 24Y of the first power supply 24.
  • the potential V2A of the anode 25X of the second power source 25 is higher than the potential V2B of the cathode 25Y of the second power source 25.
  • the first switch 26 includes a first input terminal 26A, a second input terminal 26B, a first changeover switch 26E, a first output terminal 26X, and a second output terminal 26Y.
  • the first input terminal 26A and the second input terminal 26B are electrically connected to the anode 24X and the cathode 24Y of the first power supply 24, respectively.
  • the first switch 26 sets the potential of the first output terminal 26X and the potential of the second output terminal 26Y to the potential V1A and the potential V1B in accordance with the operation of the first switch 26E. Further, it is possible to switch between the normal mode and the reverse power mode by operating the first changeover switch 26E.
  • the first changeover switch 26E is a button provided on the outer surface of the case 20 as an example.
  • the second switch 27 includes a third input terminal 27A, a fourth input terminal 27B, a second changeover switch 27E, a third output terminal 27X, and a fourth output terminal 27Y.
  • the third input terminal 27A and the fourth input terminal 27B are electrically connected to the anode 25X and the cathode 25Y of the second power supply 25, respectively.
  • the second switch 27 sets the potential of the third output terminal 27X and the potential of the fourth output terminal 27Y to the potential V2A and the potential V2B according to the operation of the second switch 27E. Further, it is possible to switch to the normal mode, the reverse power mode, and the insulation mode by operating the second changeover switch 27E.
  • the potential of the third output terminal 27X is set to the potential V2A
  • the potential of the fourth output terminal 27Y is set to the potential V2B
  • the potential of the third output terminal 27X is set to the potential V2B
  • the potential of the fourth output terminal 27Y is set to the potential V2A.
  • the third input terminal 27A and the fourth input terminal 27B are not electrically connected to the anode 25X and the cathode 25Y of the second power source.
  • the second changeover switch 27E is a button provided on the outer surface of the case 20 as an example.
  • the alkaline water tank 30 generates alkaline water by electrolyzing raw water using the first power source 24.
  • the alkaline water tank 30 includes a first water tank 31, a second water tank 35, and a diaphragm 39.
  • the first water tank 31 includes a first inlet 32, a first outlet 33, and a first electrode 34.
  • the second water tank 35 includes a second inlet 36, a second outlet 37, and a second electrode 38.
  • the first water tank 31 and the second water tank 35 are integrally formed and are separated by a diaphragm 39.
  • the shape of the alkaline water tank 30 is preferably such that water easily passes from the first inlet 32 and the second inlet 36 to the first outlet 33 and the second outlet 37.
  • the first electrode 34 and the second electrode 38 have a shape that increases the contact area with the water passing through the alkaline water tank 30, for example, along the inner surface of the first water tank 31 and the inner surface of the second water tank 35. An elongated shape is preferred.
  • the first electrode 34 and the first output terminal 26X are electrically connected.
  • the second electrode 38 and the second output terminal 26Y are electrically connected.
  • the hydrogen water tank 40 generates alkaline hydrogen water by electrolyzing the alkaline water generated in the alkaline water tank 30 using the second power source 25.
  • the hydrogen water tank 40 includes a third water tank 41, a fourth water tank 45, and an ion exchange membrane 49.
  • the third water tank 41 includes a third inflow port 42, a third outflow port 43, and a third electrode 44.
  • the fourth water tank 45 includes a fourth inlet 46, a fourth outlet 47, and a fourth electrode 48.
  • the third water tank 41 and the fourth water tank 45 are formed integrally and are partitioned by an ion exchange membrane 49.
  • the ion exchange membrane 49 is a cation exchange membrane and can pass cations contained in the water in the third water tank 41 and the fourth water tank 45.
  • the shape of the hydrogen water tank 40 is preferably a shape in which water easily passes from the third inlet 42 and the fourth inlet 46 to the third outlet 43 and the fourth outlet 47.
  • the third electrode 44 and the third output terminal 27X are electrically connected.
  • the fourth electrode 48 and the fourth output terminal 27Y are electrically connected.
  • the first communication path 51 communicates the second outlet 37 and the fourth inlet 46.
  • the first water channel 52 communicates the first outlet 33 and the third water outlet 14.
  • the first water supply channel 53 communicates the filtration membrane part 23 and the third inflow port 42.
  • the raw water channel 50 communicates the filtration membrane part 23 with the first inlet 32 and the second inlet 36.
  • the first pipe 61 communicates the fourth outlet 47 and the first water outlet 12.
  • the second pipe 62 communicates the third outlet 43 and the second water outlet 13.
  • the tap water discharged from the faucet 1 passes through the water supply port 11 and is supplied to the water purification unit 21.
  • the raw water purified by the water purification unit 21 is supplied to the first water tank 31 and the second water tank 35 of the alkaline water tank 30.
  • the potential of the first electrode 34 is set to about V1A, and the potential of the second electrode 38 is set to about V1B. Since the potential of the first electrode 34 is higher than the potential of the second electrode 38, a reduction reaction of raw water represented by the following formula [1] occurs in the second water tank 35.
  • [1] expression is reduced water molecules of H 2 O raw water, hydroxide ions OH - is a chemical reaction formula showing that and hydrogen H 2 are produced.
  • hydroxide ion OH - increases the concentration of the alkaline water is generated.
  • the electrolysis of the alkaline water tank 30 is controlled such that the pH of the alkaline hydrogen water is suitable for drinking, for example, the pH is about 9.5.
  • the generated alkaline water is sent to the fourth water tank 45 of the hydrogen water tank 40 through the first communication path 51.
  • the formula [2] is a chemical reaction formula showing that water molecules H 2 O in raw water are oxidized to generate hydrogen ions H + and oxygen O 2 . As electrolysis progresses, the concentration of hydrogen ions H + increases and acidic water is generated.
  • the formula [3] is a chemical reaction formula showing that chloride ion Cl 2 ⁇ in raw water is oxidized to produce chlorine Cl 2 . The reaction of formula [3] takes precedence over the reaction of formula [2]. The produced chlorine Cl 2 causes a chemical reaction represented by the following formula [4].
  • [4] is a chemical reaction formula showing that hypochlorous acid HClO and hydrochloric acid HCl are generated from water molecules H 2 O and chlorine Cl 2 in raw water.
  • the potential of the third electrode 44 is set to about V2A
  • the potential of the fourth electrode 48 is set to about V2B. Since the potential of the third electrode 44 is higher than the potential of the fourth electrode 48, a reduction reaction of alkaline water occurs in the fourth water tank 45. That is, the chemical reaction represented by the formula [1] occurs. Moreover, in the 3rd water tank 41, the oxidation reaction of raw
  • the acidic water produced in the first water tank 31 contains hypochlorous acid HClO.
  • the water containing hypochlorous acid HClO produced is strongly acidic. Strongly acidic water may cause chemical damage to components such as water tanks.
  • the water treatment device 10 since acidic water is discharged from the first outlet 33 to the outside of the water treatment device 10 through the first water channel 52, the third water tank 41, the fourth water tank 45, In addition, the possibility that the ion exchange membrane 49 is chemically damaged is reduced.
  • the water treatment apparatus 10A according to the second embodiment has substantially the same configuration as the water treatment apparatus 10 according to the first embodiment.
  • the second embodiment is different from the first embodiment in that a first communication path 51A is provided instead of the first communication path 51 and the first water supply path 53.
  • the first communication path 51A includes a first branch 51X.
  • the first communication passage 51 ⁇ / b> A communicates the second water tank 35, the third water tank 41, and the fourth water tank 45.
  • the water discharged from the second outlet 37 is divided into the third inlet 42 and the fourth inlet 46 in the first branch 51X and supplied to each.
  • the water treatment apparatus 10 ⁇ / b> A it is not necessary to provide the first water supply channel 53 between the first water tank 31 and the second water tank 35 and the third water tank 41 and the fourth water tank 45.
  • the configuration can be simplified.
  • the water treatment device 10B according to the third embodiment has substantially the same configuration as the water treatment device 10 according to the first embodiment.
  • the third embodiment is different from the configuration of the first embodiment in that the second water channel 54, the fourth water discharge port 15, and the first valve 17 are further provided.
  • the fourth water discharge port 15 penetrates the case 20.
  • the first valve 17 communicates with the first communication passage 51, the second water channel 54, and the fourth inflow port 46.
  • the second water channel 54 communicates the first valve 17 and the fourth water discharge port 15.
  • the first valve 17 can switch the flow path from any one of the first communication path 51 to the fourth inlet 46 and from the first communication path 51 to the second water path 54.
  • the second switch 27 is set to the insulation mode, and the alkaline water is extracted using the second water channel 54, thereby suppressing the scale from adhering to the fourth water tank 45. it can.
  • the water treatment device 10C of the fourth embodiment has substantially the same configuration as the water treatment device 10 of the first embodiment.
  • the fourth embodiment is different from the configuration of the first embodiment in that the second water supply channel 56 and the second valve 18 are further provided.
  • the second water supply channel 56 branches off from the raw water channel 50.
  • the second valve 18 communicates with the second water supply path 56, the first communication path 51, and the fourth inflow port 46.
  • the second valve 18 can switch the flow path from the first communication path 51 to the fourth inlet 46 and from the second water supply path 56 to the fourth inlet 46.
  • each said embodiment is an illustration of the form which the water treatment apparatus which concerns on this indication can take, and it does not intend restrict
  • the water treatment apparatus according to the present disclosure may take a form in which, for example, the modifications of the above-described embodiments described below and at least two modifications not contradicting each other are combined.
  • Raw water creation method can be changed arbitrarily.
  • well water or mineral water is purified by the water purification unit 21, and the purified raw water is supplied to the water treatment device 10.
  • the water purification unit 21 is omitted, and tap water is directly supplied to the water treatment apparatus 10 as raw water.
  • FIG. An addition part adds the salt which is an example of electrolyte to the raw
  • Sodium ions Na added salt is in water + and chloride ion Cl -, and therefore, the electrolysis of the raw water is promoted. For this reason, the pH of the generated alkaline water is likely to be increased.
  • the first valve 17 need not be provided.
  • the second switch 27 When the second switch 27 is in the insulation mode, alkaline water can be discharged from the second water channel 54 and the first pipe 61.
  • the first switch 26 according to the third embodiment may be set in the reverse power mode, and acidic water may be generated in the second water tank 35. Even in the second water tank 35 through which raw water passes, the scale may adhere after a long period of time. The scale adhering to the second water tank 35 can be removed by the generated acidic water. Further, the scales attached to the second water tank 35 and the fourth water tank 45 can be simultaneously removed by combining the configurations of the third embodiment and the fourth embodiment.
  • the water treatment apparatus is difficult to chemically damage the constituent elements and can extend the life of the apparatus, the water treatment apparatus is used for home appliances that use a large amount of water or are difficult to repair the constituent elements. Applicable.

Abstract

This water treatment apparatus is provided with a first water tank, a second water tank, a third water tank, a fourth water tank, a first electrode provided in the first water tank, a second electrode provided in the second water tank and corresponding to the first electrode, a third electrode provided in the third water tank, and a fourth electrode provided in the fourth water tank and corresponding to the third electrode. The water treatment apparatus is also provided with: an ion exchange membrane that partitions the third water tank from the fourth water tank; a first water channel for removing water electrolyzed in the first water tank without being fed to the third and fourth water tanks; and a first communication channel for bringing the second water tank into communication with the fourth water tank.

Description

水処理装置Water treatment equipment
 本開示は水処理装置に関する。 This disclosure relates to water treatment equipment.
 アルカリ性水が身体の健康の維持および増進に寄与することが知られている。例えば、pHが9.5程度のアルカリ性水は、胃腸の状態の改善に効果がある。pHが10よりも高いアルカリ性水は料理のあく抜き等に用いられる。水処理装置はそうしたアルカリ性水を生成可能な装置である。これはアルカリイオン整水器等と称されることもある。 ア ル カ リ Alkaline water is known to contribute to the maintenance and enhancement of physical health. For example, alkaline water having a pH of about 9.5 is effective in improving gastrointestinal conditions. Alkaline water having a pH higher than 10 is used for cooking. A water treatment device is a device capable of producing such alkaline water. This is sometimes called an alkali ion water conditioner or the like.
 従来の水処理装置は、陽極が設けられた陽極槽、陰極が設けられた陰極槽、陽極槽と陰極槽とを区画する隔膜、および、これらの槽のそれぞれに原水を供給する供給通路を備える。陽極および陰極に電圧が与えられた状態において、原水が陽極槽を通過することにより酸性水が生成され、原水が陰極槽を追加することによりアルカリ性水が生成される。 A conventional water treatment apparatus includes an anode tank provided with an anode, a cathode tank provided with a cathode, a diaphragm partitioning the anode tank and the cathode tank, and a supply passage for supplying raw water to each of these tanks. . In a state where a voltage is applied to the anode and the cathode, the raw water passes through the anode tank to generate acidic water, and the raw water adds the cathode tank to generate alkaline water.
 溶存水素濃度が高いアルカリ性水は老化および病気の原因と推測されている活性酸素の除去に寄与すると考えられている。従来の水処理装置を利用して溶存水素濃度が高いアルカリ性水を生成する方法の一例として、陰極槽における電気分解の進行の度合を高め、水素を多く発生させる方法が知られている。ただし、この方法によれば、アルカリ性水のpHがさらに上昇するため、飲用に適したアルカリ性水を生成しにくい。 Alkaline water with high dissolved hydrogen concentration is thought to contribute to the removal of active oxygen, which is presumed to cause aging and disease. As an example of a method for generating alkaline water having a high dissolved hydrogen concentration using a conventional water treatment device, a method for increasing the degree of electrolysis in a cathode tank and generating a large amount of hydrogen is known. However, according to this method, since the pH of alkaline water further increases, it is difficult to produce alkaline water suitable for drinking.
 特許文献1は上記課題を解決するための水処理装置の一例を開示している。この水処理装置は、陽極槽、陰極槽、および、隔膜等に加え、陽極槽において生成された酸性水が供給される第2の陽極槽、陰極槽において生成されたアルカリ性水が供給される第2の陰極槽、第2の陽極槽に設けられる第2の陽極、第2の陰極槽に設けられる第2の陰極、および、第2の陽極槽と第2の陰極槽とを区画するイオン交換膜を備える。第2の陰極槽では固体高分子膜(SPE:Solid Polymer Electrolyte)法によりアルカリ性水が電気分解され、水素および水酸化物イオンが発生する。このため、第2の陰極槽に供給されたアルカリ性水の溶存水素濃度が発生した水素により高められる。一方、第2の陽極槽において生成された水素イオンがイオン交換膜を介して第2の陰極槽に移動することにより、第2の陰極槽に供給されたアルカリ性水のpHの上昇が抑えられる。 Patent Document 1 discloses an example of a water treatment apparatus for solving the above problems. In this water treatment apparatus, in addition to the anode tank, the cathode tank, and the diaphragm, the second anode tank to which the acidic water generated in the anode tank is supplied, and the alkaline water generated in the cathode tank is supplied. Two cathode tanks, a second anode provided in the second anode tank, a second cathode provided in the second cathode tank, and an ion exchange partitioning the second anode tank and the second cathode tank With a membrane. In the second cathode chamber, alkaline water is electrolyzed by a solid polymer membrane (SPE) method, and hydrogen and hydroxide ions are generated. For this reason, the dissolved hydrogen concentration of the alkaline water supplied to the second cathode tank is increased by the generated hydrogen. On the other hand, when the hydrogen ions generated in the second anode tank move to the second cathode tank via the ion exchange membrane, an increase in the pH of the alkaline water supplied to the second cathode tank is suppressed.
 このように、上記水処理装置によれば、第2の陰極槽に供給されたアルカリ性水のpHの上昇が抑えられながら溶存水素濃度が高められることにより、溶存水素濃度が高く、かつ、飲用に適したアルカリ性水が生成される。 As described above, according to the water treatment apparatus, the dissolved hydrogen concentration is increased while the increase in pH of the alkaline water supplied to the second cathode tank is suppressed, so that the dissolved hydrogen concentration is high and can be used for drinking. Suitable alkaline water is produced.
 特許文献1の水処理装置によれば、アルカリ性水の生成にともない生成される次亜塩素酸の濃度が高い強酸性水が陽極槽に供給される。このため、陽極槽およびイオン交換膜の寿命を縮めるおそれがある。 According to the water treatment apparatus of Patent Document 1, strongly acidic water having a high concentration of hypochlorous acid generated with the generation of alkaline water is supplied to the anode tank. For this reason, there exists a possibility of shortening the lifetime of an anode tank and an ion exchange membrane.
特開2005-40781号公報JP 2005-40781 A
 本開示に係る水処理装置の一形態は、第1の水槽と、第2の水槽と、第3の水槽と、第4の水槽と、第1の水槽に設けられる第1の電極と、第2の水槽に設けられ、第1の電極に対応する第2の電極と、第3の水槽に設けられる第3の電極と、第4の水槽に設けられ、第3の電極に対応する第4の電極とを備えている。さらに、水処理装置の一形態は、第3の水槽と第4の水槽とを区画するイオン交換膜と、第1の水槽で電気分解された水を第3の水槽および第4の水槽に供給することなく取り出すための第1の水路と、第2の水槽と第4の水槽とを連通する第1の連通路とを備える。 One form of the water treatment device according to the present disclosure includes a first water tank, a second water tank, a third water tank, a fourth water tank, a first electrode provided in the first water tank, A second electrode corresponding to the first electrode, a third electrode provided in the third water tank, and a fourth electrode corresponding to the third electrode provided in the fourth water tank. Electrode. Furthermore, one form of the water treatment apparatus supplies the third water tank and the fourth water tank with the ion exchange membrane that partitions the third water tank and the fourth water tank, and the water electrolyzed in the first water tank. A first water channel for taking out without performing, and a first communication passage communicating the second water tank and the fourth water tank.
 溶存水素濃度が高いアルカリ性水の生成が可能であり、構成要素が化学的に損傷しにくい水処理装置を提供できる。 It is possible to provide a water treatment apparatus capable of generating alkaline water having a high dissolved hydrogen concentration and hardly causing chemical damage to its constituent elements.
図1は、第1の実施形態の水処理装置の全体の模式図である。FIG. 1 is a schematic diagram of the entire water treatment apparatus according to the first embodiment. 図2は、第2の実施形態の水処理装置の全体の模式図である。FIG. 2 is a schematic diagram of the entire water treatment apparatus according to the second embodiment. 図3は、第3の実施形態の水処理装置の全体の模式図である。FIG. 3 is a schematic diagram of the entire water treatment apparatus according to the third embodiment. 図4は、第4の実施形態の水処理装置の全体の模式図である。FIG. 4 is a schematic diagram of the entire water treatment apparatus according to the fourth embodiment.
 (水処理装置が取り得る形態の一例)
 本開示に係る水処理装置の一形態は、第1の水槽と、第2の水槽と、第3の水槽と、第4の水槽と、第1の水槽に設けられる第1の電極と、第2の水槽に設けられ、第1の電極に対応する第2の電極と、第3の水槽に設けられる第3の電極と、第4の水槽に設けられ、第3の電極に対応する第4の電極とを備えている。さらに、水処理装置の一形態は、第3の水槽と第4の水槽とを区画するイオン交換膜と、第1の水槽で電気分解された水を第3の水槽および第4の水槽に供給することなく取り出すための第1の水路と、第2の水槽と第4の水槽とを連通する第1の連通路とを備える。
(An example of a form that the water treatment device can take)
One form of the water treatment device according to the present disclosure includes a first water tank, a second water tank, a third water tank, a fourth water tank, a first electrode provided in the first water tank, A second electrode corresponding to the first electrode, a third electrode provided in the third water tank, and a fourth electrode corresponding to the third electrode provided in the fourth water tank. Electrode. Furthermore, one form of the water treatment apparatus supplies the third water tank and the fourth water tank with the ion exchange membrane that partitions the third water tank and the fourth water tank, and the water electrolyzed in the first water tank. A first water channel for taking out without performing, and a first communication passage communicating the second water tank and the fourth water tank.
 上記水処理装置において、第1の電極の電位が第2の電極の電位よりも高くなるように第1の電極および第2の電極に電圧が与えられた場合、第1の水槽において酸性水が生成され、第2の水槽においてアルカリ性水が生成される。第1の水路が水処理装置に含まれることにより、その酸性水が第3の水槽および第4の水槽に供給されないため、第3の水槽および第4の水槽が化学的に損傷するおそれが低減する。 In the water treatment apparatus, when a voltage is applied to the first electrode and the second electrode so that the potential of the first electrode is higher than the potential of the second electrode, acidic water is generated in the first water tank. And alkaline water is generated in the second water tank. Since the acidic water is not supplied to the third water tank and the fourth water tank by including the first water channel in the water treatment device, the possibility that the third water tank and the fourth water tank are chemically damaged is reduced. To do.
 上記水処理装置の一例によれば、第3の水槽は原水を供給する原水路を接続可能である。 According to an example of the water treatment apparatus, the third water tank can be connected to a raw water channel that supplies raw water.
 上記水処理装置によれば、第4の水槽に供給されたアルカリ性水が電気分解されることにより、そのアルカリ性水の溶存水素濃度が高められる。また、第3の水槽に供給された原水が電気分解されることにより発生した水素イオンがイオン交換膜を通過して第4の水槽に供給されることにより、第4の水槽を通過するアルカリ性水のpHの増加が抑えられる。この装置構成によれば、第2の水槽において生成されたアルカリ性水の全部を第4の水槽に供給できるため、高い溶存水素濃度を有するアルカリ性水の生成に要する時間を短縮できる。 According to the water treatment device, the alkaline water supplied to the fourth water tank is electrolyzed, so that the dissolved hydrogen concentration of the alkaline water is increased. Moreover, the alkaline water which passes through a 4th water tank by the hydrogen ion which generate | occur | produced when the raw | natural water supplied to the 3rd water tank electrolyzed passes an ion exchange membrane and is supplied to a 4th water tank. An increase in the pH is suppressed. According to this apparatus configuration, since all the alkaline water generated in the second water tank can be supplied to the fourth water tank, the time required for generating alkaline water having a high dissolved hydrogen concentration can be shortened.
 上記水処理装置の一例によれば、第4の水槽は原水を供給する原水路を接続可能である。 According to an example of the water treatment apparatus, the fourth water tank can be connected to a raw water channel that supplies raw water.
 上記水処理装置によれば、第3の水槽および第4の水槽に原水を供給し、第4の電極の電位が第3の電極の電位よりも高くなるように第3の電極および第4の電極に電圧が与えられることにより、第4の水槽において酸性水が生成される。これにより、第4の水槽に付着しているスケールが酸性水に溶解するため、第4の水槽に付着したスケールを除去できる。 According to the water treatment apparatus, raw water is supplied to the third water tank and the fourth water tank, and the third electrode and the fourth electrode are set such that the potential of the fourth electrode is higher than the potential of the third electrode. By applying a voltage to the electrodes, acidic water is generated in the fourth water tank. Thereby, since the scale adhering to the fourth water tank is dissolved in the acidic water, the scale adhering to the fourth water tank can be removed.
 上記水処理装置の一例によれば、第1の連通路は第2の水槽と第3の水槽とをさらに連通する。 According to an example of the water treatment apparatus, the first communication path further communicates the second water tank and the third water tank.
 上記水処理装置によれば、第4の水槽に供給されたアルカリ性水が電気分解されることにより、そのアルカリ性水の溶存水素濃度が高められる。また、第3の水槽に供給されたアルカリ性水が電気分解されることにより発生した水素イオンがイオン交換膜を通過して第4の水槽に供給されることにより、第4の水槽を通過するアルカリ性水のpHの増加が抑えられる。この装置構成によれば、第1の水槽および第2の水槽と第3の水槽および第4の水槽との間に第1の連通路とは別の水路を設ける必要がないため、水路に関する構成を簡素化できる。 According to the water treatment device, the alkaline water supplied to the fourth water tank is electrolyzed, so that the dissolved hydrogen concentration of the alkaline water is increased. Moreover, the hydrogen ion which generate | occur | produced when the alkaline water supplied to the 3rd water tank is electrolyzed passes an ion-exchange membrane, and is supplied to a 4th water tank, The alkalinity which passes a 4th water tank Increase in pH of water is suppressed. According to this device configuration, there is no need to provide a water channel different from the first communication passage between the first water tank and the second water tank, and the third water tank and the fourth water tank. Can be simplified.
 上記水処理装置の一例によれば、第2の水槽で電気分解された水を第3の水槽および第4の水槽に供給することなく取り出すための第2の水路をさらに備える。 According to an example of the water treatment apparatus, the water treatment apparatus further includes a second water channel for taking out the water electrolyzed in the second water tank without supplying the water to the third water tank and the fourth water tank.
 アルカリ性水の生成時間が長くなるにつれて第4の水槽に炭酸カルシウムおよび水酸化マグネシウム等のスケールが付着しやすくなる。上記水処理装置によれば、第2の水路を利用してアルカリ性水を取り出すことにより、第4の水槽にスケールが付着することを抑制できる。 As the generation time of alkaline water becomes longer, scales such as calcium carbonate and magnesium hydroxide tend to adhere to the fourth water tank. According to the said water treatment apparatus, it can suppress that a scale adheres to a 4th water tank by taking out alkaline water using a 2nd water channel.
 (実施の形態1)
 図1に示されるように、水処理装置10は、隔膜39で隔離された第1の水槽31および第2の水槽35を有するアルカリ水槽30、および、イオン交換膜49で区画された第3の水槽41および第4の水槽45を有する水素水槽40を備える。アルカリ水槽30および水素水槽40は、ケース20に格納されている。
(Embodiment 1)
As shown in FIG. 1, the water treatment device 10 includes a first water tank 31 and a second water tank 35 separated by a diaphragm 39, and a third water tank partitioned by an ion exchange membrane 49. A hydrogen water tank 40 having a water tank 41 and a fourth water tank 45 is provided. The alkaline water tank 30 and the hydrogen water tank 40 are stored in the case 20.
 水処理装置10の外部には、蛇口1および流路切替器2が設けられる。蛇口1は水道水を吐出する。流路切替器2は、蛇口1に取り付けられ、使用者の操作に応じて給水口11に水道水を給水する。 A faucet 1 and a flow path switch 2 are provided outside the water treatment apparatus 10. The faucet 1 discharges tap water. The flow path switching unit 2 is attached to the faucet 1 and supplies tap water to the water supply port 11 in accordance with a user operation.
 水処理装置10は、ケース20の外部に向けて突出する給水口11、第1の吐水口12、第2の吐水口13、および、第3の吐水口14を備える。給水口11は、水処理装置10の内部に水道水を給水する。第1の吐水口12は、水処理装置10から水道水よりもpHが高いアルカリ性水、または、アルカリ性水素水を吐水する。アルカリ性水素水は、アルカリ性水よりも溶存水素濃度が高い。第2の吐水口13および第3の吐水口14は、水処理装置10から水道水よりもpHが低い酸性水を吐水する。 The water treatment apparatus 10 includes a water supply port 11, a first water discharge port 12, a second water discharge port 13, and a third water discharge port 14 protruding toward the outside of the case 20. The water supply port 11 supplies tap water to the inside of the water treatment apparatus 10. The first water discharge port 12 discharges alkaline water or alkaline hydrogen water having a pH higher than that of tap water from the water treatment device 10. Alkaline hydrogen water has a higher dissolved hydrogen concentration than alkaline water. The second water outlet 13 and the third water outlet 14 discharge acidic water having a pH lower than that of tap water from the water treatment device 10.
 ケース20は、浄水部21、第1の電源24、第2の電源25、第1の切替器26、第2の切替器27、原水路50、第1の連通路51、第1の水路52、第1の給水路53、第1の管61、および、第2の管62を格納する。浄水部21は、活性炭式およびろ過膜式の浄水器であり、水道水を浄化する。浄水部21により浄化された水である原水は、原水路50を通過してアルカリ水槽30に供給される。浄水部21は、活性炭部22およびろ過膜部23を備える。活性炭部22は活性炭を有し、水道水から有機物、臭い、および、残留塩素等を除去する。ろ過膜部23は、一例として、ポリエチレン製の中空糸膜を有し、活性炭部22を通過した水から0.1マイクロメートル以上の粒子、雑菌、および、赤錆等を除去する。 The case 20 includes a water purification unit 21, a first power source 24, a second power source 25, a first switch 26, a second switch 27, a raw water channel 50, a first communication channel 51, and a first water channel 52. The 1st water supply channel 53, the 1st pipe 61, and the 2nd pipe 62 are stored. The water purification unit 21 is an activated carbon type and a filtration membrane type water purifier, and purifies tap water. The raw water, which is the water purified by the water purification unit 21, passes through the raw water channel 50 and is supplied to the alkaline water tank 30. The water purification unit 21 includes an activated carbon unit 22 and a filtration membrane unit 23. The activated carbon part 22 has activated carbon, and removes organic substances, odors, residual chlorine and the like from tap water. As an example, the filtration membrane part 23 has a polyethylene hollow fiber membrane, and removes particles of 0.1 μm or more, bacteria, red rust, and the like from the water that has passed through the activated carbon part 22.
 第1の電源24および第2の電源25は、アルカリ水槽30および水素水槽40において電気分解を行うために使用される直流電源である。第1の電源24の陽極24Xの電位V1Aは、第1の電源24の陰極24Yの電位V1Bよりも高い。第2の電源25の陽極25Xの電位V2Aは、第2の電源25の陰極25Yの電位V2Bよりも高い。 The first power supply 24 and the second power supply 25 are DC power supplies used for electrolysis in the alkaline water tank 30 and the hydrogen water tank 40. The potential V1A of the anode 24X of the first power supply 24 is higher than the potential V1B of the cathode 24Y of the first power supply 24. The potential V2A of the anode 25X of the second power source 25 is higher than the potential V2B of the cathode 25Y of the second power source 25.
 第1の切替器26は、第1の入力端子26A、第2の入力端子26B、第1の切替スイッチ26E、第1の出力端子26X、および、第2の出力端子26Yを備える。第1の入力端子26Aおよび第2の入力端子26Bは、それぞれ第1の電源24の陽極24Xおよび陰極24Yに電気的に接続される。第1の切替器26は、第1の切替スイッチ26Eの操作に応じて、第1の出力端子26Xの電位および第2の出力端子26Yの電位を電位V1Aおよび電位V1Bに設定する。また、第1の切替スイッチ26Eの操作により、通常モードおよび逆電モードに切替え可能である。通常モードでは、第1の出力端子26Xの電位が電位V1Aに設定され、第2の出力端子26Yの電位が電位V1Bに設定される。逆電モードでは、第1の出力端子26Xの電位が電位V1Bに設定され、第2の出力端子26Yの電位が電位V1Aに設定される。第1の切替スイッチ26Eは、一例として、ケース20の外面に設けられたボタンである。 The first switch 26 includes a first input terminal 26A, a second input terminal 26B, a first changeover switch 26E, a first output terminal 26X, and a second output terminal 26Y. The first input terminal 26A and the second input terminal 26B are electrically connected to the anode 24X and the cathode 24Y of the first power supply 24, respectively. The first switch 26 sets the potential of the first output terminal 26X and the potential of the second output terminal 26Y to the potential V1A and the potential V1B in accordance with the operation of the first switch 26E. Further, it is possible to switch between the normal mode and the reverse power mode by operating the first changeover switch 26E. In the normal mode, the potential of the first output terminal 26X is set to the potential V1A, and the potential of the second output terminal 26Y is set to the potential V1B. In the reverse power mode, the potential of the first output terminal 26X is set to the potential V1B, and the potential of the second output terminal 26Y is set to the potential V1A. The first changeover switch 26E is a button provided on the outer surface of the case 20 as an example.
 第2の切替器27は、第3の入力端子27A、第4の入力端子27B、第2の切替スイッチ27E、第3の出力端子27X、および、第4の出力端子27Yを備える。第3の入力端子27Aおよび第4の入力端子27Bは、それぞれ第2の電源25の陽極25Xおよび陰極25Yに電気的に接続される。第2の切替器27は、第2の切替スイッチ27Eの操作に応じて、第3の出力端子27Xの電位および第4の出力端子27Yの電位を電位V2Aおよび電位V2Bに設定する。また、第2の切替スイッチ27Eの操作により、通常モード、逆電モード、および、絶縁モードに切替え可能である。通常モードでは、第3の出力端子27Xの電位が電位V2Aに設定され、第4の出力端子27Yの電位が電位V2Bに設定される。逆電モードでは、第3の出力端子27Xの電位が電位V2Bに設定され、第4の出力端子27Yの電位が電位V2Aに設定される。絶縁モードでは、第3の入力端子27Aおよび第4の入力端子27Bは、第2の電源の陽極25Xおよび陰極25Yと電気的に接続されない。第2の切替スイッチ27Eは、一例として、ケース20の外面に設けられたボタンである。 The second switch 27 includes a third input terminal 27A, a fourth input terminal 27B, a second changeover switch 27E, a third output terminal 27X, and a fourth output terminal 27Y. The third input terminal 27A and the fourth input terminal 27B are electrically connected to the anode 25X and the cathode 25Y of the second power supply 25, respectively. The second switch 27 sets the potential of the third output terminal 27X and the potential of the fourth output terminal 27Y to the potential V2A and the potential V2B according to the operation of the second switch 27E. Further, it is possible to switch to the normal mode, the reverse power mode, and the insulation mode by operating the second changeover switch 27E. In the normal mode, the potential of the third output terminal 27X is set to the potential V2A, and the potential of the fourth output terminal 27Y is set to the potential V2B. In the reverse power mode, the potential of the third output terminal 27X is set to the potential V2B, and the potential of the fourth output terminal 27Y is set to the potential V2A. In the insulation mode, the third input terminal 27A and the fourth input terminal 27B are not electrically connected to the anode 25X and the cathode 25Y of the second power source. The second changeover switch 27E is a button provided on the outer surface of the case 20 as an example.
 アルカリ水槽30は、原水を第1の電源24を用いて電気分解することによりアルカリ性水を生成する。アルカリ水槽30は、第1の水槽31、第2の水槽35、および、隔膜39を備える。第1の水槽31は、第1の流入口32、第1の流出口33、および、第1の電極34を備える。第2の水槽35は、第2の流入口36、第2の流出口37、および、第2の電極38を備える。第1の水槽31および第2の水槽35は一体に形成され、隔膜39により隔離される。アルカリ水槽30の形状は、第1の流入口32および第2の流入口36から第1の流出口33および第2の流出口37に水が通過しやすい形状が好ましい。第1の電極34および第2の電極38は、アルカリ水槽30を通過する水との接触面積が広くなる形状、一例として、第1の水槽31の内面および第2の水槽35の内面に沿って伸びる形状が好ましい。第1の電極34と第1の出力端子26Xとは電気的に接続される。第2の電極38と第2の出力端子26Yとは電気的に接続される。 The alkaline water tank 30 generates alkaline water by electrolyzing raw water using the first power source 24. The alkaline water tank 30 includes a first water tank 31, a second water tank 35, and a diaphragm 39. The first water tank 31 includes a first inlet 32, a first outlet 33, and a first electrode 34. The second water tank 35 includes a second inlet 36, a second outlet 37, and a second electrode 38. The first water tank 31 and the second water tank 35 are integrally formed and are separated by a diaphragm 39. The shape of the alkaline water tank 30 is preferably such that water easily passes from the first inlet 32 and the second inlet 36 to the first outlet 33 and the second outlet 37. The first electrode 34 and the second electrode 38 have a shape that increases the contact area with the water passing through the alkaline water tank 30, for example, along the inner surface of the first water tank 31 and the inner surface of the second water tank 35. An elongated shape is preferred. The first electrode 34 and the first output terminal 26X are electrically connected. The second electrode 38 and the second output terminal 26Y are electrically connected.
 水素水槽40は、アルカリ水槽30で生成されたアルカリ性水を第2の電源25を用いて電気分解することにより、アルカリ性水素水を生成する。水素水槽40は、第3の水槽41、第4の水槽45、および、イオン交換膜49を備える。第3の水槽41は、第3の流入口42、第3の流出口43、および、第3の電極44を備える。第4の水槽45は、第4の流入口46、第4の流出口47、および、第4の電極48を備える。第3の水槽41および第4の水槽45は一体に形成され、イオン交換膜49により区画される。イオン交換膜49は陽イオン交換膜であり、第3の水槽41および第4の水槽45中の水に含まれる陽イオンを通過させることができる。水素水槽40の形状は、第3の流入口42および第4の流入口46から第3の流出口43および第4の流出口47に水が通過しやすい形状が好ましい。第3の電極44および第3の出力端子27Xは電気的に接続される。第4の電極48および第4の出力端子27Yは電気的に接続される。 The hydrogen water tank 40 generates alkaline hydrogen water by electrolyzing the alkaline water generated in the alkaline water tank 30 using the second power source 25. The hydrogen water tank 40 includes a third water tank 41, a fourth water tank 45, and an ion exchange membrane 49. The third water tank 41 includes a third inflow port 42, a third outflow port 43, and a third electrode 44. The fourth water tank 45 includes a fourth inlet 46, a fourth outlet 47, and a fourth electrode 48. The third water tank 41 and the fourth water tank 45 are formed integrally and are partitioned by an ion exchange membrane 49. The ion exchange membrane 49 is a cation exchange membrane and can pass cations contained in the water in the third water tank 41 and the fourth water tank 45. The shape of the hydrogen water tank 40 is preferably a shape in which water easily passes from the third inlet 42 and the fourth inlet 46 to the third outlet 43 and the fourth outlet 47. The third electrode 44 and the third output terminal 27X are electrically connected. The fourth electrode 48 and the fourth output terminal 27Y are electrically connected.
 第1の連通路51は、第2の流出口37と第4の流入口46とを連通する。第1の水路52は、第1の流出口33と第3の吐水口14とを連通する。第1の給水路53は、ろ過膜部23と第3の流入口42とを連通する。原水路50は、ろ過膜部23と第1の流入口32および第2の流入口36とを連通する。第1の管61は、第4の流出口47と第1の吐水口12とを連通する。第2の管62は、第3の流出口43と第2の吐水口13とを連通する。 The first communication path 51 communicates the second outlet 37 and the fourth inlet 46. The first water channel 52 communicates the first outlet 33 and the third water outlet 14. The first water supply channel 53 communicates the filtration membrane part 23 and the third inflow port 42. The raw water channel 50 communicates the filtration membrane part 23 with the first inlet 32 and the second inlet 36. The first pipe 61 communicates the fourth outlet 47 and the first water outlet 12. The second pipe 62 communicates the third outlet 43 and the second water outlet 13.
 水処理装置10のアルカリ水槽30の動作について説明する。 The operation of the alkaline water tank 30 of the water treatment apparatus 10 will be described.
 蛇口1から吐出された水道水は、給水口11を通過し、浄水部21に供給される。浄水部21により浄化された原水は、アルカリ水槽30の第1の水槽31および第2の水槽35に供給される。 The tap water discharged from the faucet 1 passes through the water supply port 11 and is supplied to the water purification unit 21. The raw water purified by the water purification unit 21 is supplied to the first water tank 31 and the second water tank 35 of the alkaline water tank 30.
 第1の切替器26が通常モードのとき、第1の電極34の電位はV1A程度に設定され、第2の電極38の電位はV1B程度に設定される。第1の電極34の電位は第2の電極38の電位よりも高いため、第2の水槽35において、以下の[1]式に示される原水の還元反応が生じる。 When the first switch 26 is in the normal mode, the potential of the first electrode 34 is set to about V1A, and the potential of the second electrode 38 is set to about V1B. Since the potential of the first electrode 34 is higher than the potential of the second electrode 38, a reduction reaction of raw water represented by the following formula [1] occurs in the second water tank 35.
Figure JPOXMLDOC01-appb-C000001
Figure JPOXMLDOC01-appb-C000001
 [1]式は、原水中の水分子HOが還元され、水酸化物イオンOHおよび水素Hが生成されることを表した化学反応式である。電気分解が進むと水酸化物イオンOHの濃度が高まり、アルカリ性水が生成される。アルカリ水槽30の電気分解は、アルカリ性水素水のpHが飲用に適した値、例えば、pHが9.5程度となるように制御される。生成されたアルカリ性水は、第1の連通路51を介して水素水槽40の第4の水槽45に送られる。 [1] expression is reduced water molecules of H 2 O raw water, hydroxide ions OH - is a chemical reaction formula showing that and hydrogen H 2 are produced. When the electrolysis proceeds hydroxide ion OH - increases the concentration of the alkaline water is generated. The electrolysis of the alkaline water tank 30 is controlled such that the pH of the alkaline hydrogen water is suitable for drinking, for example, the pH is about 9.5. The generated alkaline water is sent to the fourth water tank 45 of the hydrogen water tank 40 through the first communication path 51.
 一方、第1の水槽31において、以下の[2]式および[3]式に示される原水の酸化反応が生じる。 On the other hand, in the first water tank 31, the oxidation reaction of the raw water shown by the following formulas [2] and [3] occurs.
Figure JPOXMLDOC01-appb-C000002
Figure JPOXMLDOC01-appb-C000002
Figure JPOXMLDOC01-appb-C000003
Figure JPOXMLDOC01-appb-C000003
 [2]式は、原水中の水分子HOが酸化され、水素イオンHおよび酸素Oが生成されることを表した化学反応式である。電気分解が進むと水素イオンHの濃度が高まり、酸性水が生成される。[3]式は原水中の塩化物イオンClが酸化され塩素Clが生成されることを表した化学反応式である。[3]式の反応は[2]式の反応よりも優先する。生成された塩素Clにより、以下の[4]式に示される化学反応が生じる。[4]式は、原水中の水分子HOおよび塩素Clから次亜塩素酸HClOおよび塩酸HClが生成されることを表した化学反応式である。 The formula [2] is a chemical reaction formula showing that water molecules H 2 O in raw water are oxidized to generate hydrogen ions H + and oxygen O 2 . As electrolysis progresses, the concentration of hydrogen ions H + increases and acidic water is generated. The formula [3] is a chemical reaction formula showing that chloride ion Cl 2 − in raw water is oxidized to produce chlorine Cl 2 . The reaction of formula [3] takes precedence over the reaction of formula [2]. The produced chlorine Cl 2 causes a chemical reaction represented by the following formula [4]. [4] Formula is a chemical reaction formula showing that hypochlorous acid HClO and hydrochloric acid HCl are generated from water molecules H 2 O and chlorine Cl 2 in raw water.
Figure JPOXMLDOC01-appb-C000004
Figure JPOXMLDOC01-appb-C000004
 水処理装置10の水素水槽40の動作について説明する。 The operation of the hydrogen water tank 40 of the water treatment apparatus 10 will be described.
 第2の切替器27が通常モードのとき、第3の電極44の電位はV2A程度に設定され、第4の電極48の電位はV2B程度に設定される。第3の電極44の電位は第4の電極48の電位よりも高いため、第4の水槽45においては、アルカリ性水の還元反応が生じる。すなわち[1]式に示される化学反応が生じる。また、第3の水槽41においては、原水の酸化反応が生じる。すなわち[2]式~[4]式に示される化学反応が生じる。 When the second switch 27 is in the normal mode, the potential of the third electrode 44 is set to about V2A, and the potential of the fourth electrode 48 is set to about V2B. Since the potential of the third electrode 44 is higher than the potential of the fourth electrode 48, a reduction reaction of alkaline water occurs in the fourth water tank 45. That is, the chemical reaction represented by the formula [1] occurs. Moreover, in the 3rd water tank 41, the oxidation reaction of raw | natural water arises. That is, the chemical reactions shown in the formulas [2] to [4] occur.
 電気分解の進行度を大きくすると、第4の水槽45において水素Hの発生量が増加し、アルカリ性水の溶存水素濃度を高めることができる。同時に、水酸化物イオンOHの濃度も増加し、pHも増加する。このとき、第3の水槽41で発生した水素イオンHが、イオン交換膜49を通過し第4の水槽45へ移動する。このため、水酸化物イオンOHの濃度の増加が抑制され、pHの増加が抑制される。したがって、第4の水槽45において、飲用に適したアルカリ性水素水を生成できる。 When the degree of progress of electrolysis is increased, the amount of hydrogen H 2 generated in the fourth water tank 45 is increased, and the dissolved hydrogen concentration of alkaline water can be increased. At the same time, hydroxide ion OH - concentration also increased, pH also increases. At this time, hydrogen ions H + generated in the third water tank 41 pass through the ion exchange membrane 49 and move to the fourth water tank 45. For this reason, an increase in the concentration of hydroxide ions OH is suppressed, and an increase in pH is suppressed. Therefore, alkaline hydrogen water suitable for drinking can be generated in the fourth water tank 45.
 また、第2の切替器27が絶縁モードのとき、第3の電極44および第4の電極48には電圧が加えられず、電気分解が行われない。このため、第4の水槽45から、溶存水素濃度を高めないアルカリ性水を入手することができる。 Further, when the second switch 27 is in the insulation mode, no voltage is applied to the third electrode 44 and the fourth electrode 48, and electrolysis is not performed. For this reason, alkaline water that does not increase the dissolved hydrogen concentration can be obtained from the fourth water tank 45.
 また、アルカリ水槽30において、[4]式に示されるように、第1の水槽31にて生成される酸性水には、次亜塩素酸HClOが含まれている。生成された次亜塩素酸HClOを含む水は強酸性である。強酸性水は、水槽等の構成要素を化学的に損傷させるおそれがある。 Moreover, in the alkaline water tank 30, as shown in the formula [4], the acidic water produced in the first water tank 31 contains hypochlorous acid HClO. The water containing hypochlorous acid HClO produced is strongly acidic. Strongly acidic water may cause chemical damage to components such as water tanks.
 水処理装置10によれば、酸性水が第1の流出口33から第1の水路52を介して水処理装置10の外部に吐出されるため、第3の水槽41、第4の水槽45、および、イオン交換膜49が化学的に損傷するおそれが低減される。 According to the water treatment device 10, since acidic water is discharged from the first outlet 33 to the outside of the water treatment device 10 through the first water channel 52, the third water tank 41, the fourth water tank 45, In addition, the possibility that the ion exchange membrane 49 is chemically damaged is reduced.
 また、第3の水槽41に原水が供給されるため、第2の水槽35において生成されたアルカリ性水の全部を第4の水槽45に供給できる。このため、高い溶存水素濃度を有するアルカリ性水の生成に要する時間を短縮でき、生成に要する電力を削減できる。 Further, since raw water is supplied to the third water tank 41, all of the alkaline water generated in the second water tank 35 can be supplied to the fourth water tank 45. For this reason, the time required for the production of alkaline water having a high dissolved hydrogen concentration can be shortened, and the power required for the production can be reduced.
 (実施の形態2)
 実施の形態2の水処理装置10Aは、実施の形態1の水処理装置10と実質的に同じ構成を備える。実施の形態2では、第1の連通路51および第1の給水路53に替えて、第1の連通路51Aを備える点において、実施の形態1の構成と相違する。
(Embodiment 2)
The water treatment apparatus 10A according to the second embodiment has substantially the same configuration as the water treatment apparatus 10 according to the first embodiment. The second embodiment is different from the first embodiment in that a first communication path 51A is provided instead of the first communication path 51 and the first water supply path 53.
 図2に示されるとおり、第1の連通路51Aは、第1の分岐51Xを含む。第1の連通路51Aは、第2の水槽35と第3の水槽41および第4の水槽45とを連通する。第2の流出口37から吐水された水は、第1の分岐51Xにおいて第3の流入口42および第4の流入口46へ分けられてそれぞれに供給される。 As shown in FIG. 2, the first communication path 51A includes a first branch 51X. The first communication passage 51 </ b> A communicates the second water tank 35, the third water tank 41, and the fourth water tank 45. The water discharged from the second outlet 37 is divided into the third inlet 42 and the fourth inlet 46 in the first branch 51X and supplied to each.
 第2の切替器27が通常モードのとき、第3の水槽41において、アルカリ水の酸化反応が生じる。すなわち[2]式~[4]式に示される化学反応が生じる。第4の水槽45において、実施の形態1と同様に、アルカリ性水の還元反応が生じる。すなわち[1]式に示される化学反応が生じる。 When the second switch 27 is in the normal mode, an alkaline water oxidation reaction occurs in the third water tank 41. That is, the chemical reactions shown in the formulas [2] to [4] occur. In the fourth water tank 45, the reduction reaction of alkaline water occurs as in the first embodiment. That is, the chemical reaction represented by the formula [1] occurs.
 水処理装置10Aによれば、第1の水槽31および第2の水槽35と第3の水槽41および第4の水槽45との間に第1の給水路53を設ける必要がないため、水路に関する構成を簡素化できる。 According to the water treatment apparatus 10 </ b> A, it is not necessary to provide the first water supply channel 53 between the first water tank 31 and the second water tank 35 and the third water tank 41 and the fourth water tank 45. The configuration can be simplified.
 (実施の形態3)
 実施の形態3の水処理装置10Bは、実施の形態1の水処理装置10と実質的に同じ構成を備える。実施の形態3では、第2の水路54、第4の吐水口15、および、第1の弁17をさらに備える点において、実施の形態1の構成と相違する。
(Embodiment 3)
The water treatment device 10B according to the third embodiment has substantially the same configuration as the water treatment device 10 according to the first embodiment. The third embodiment is different from the configuration of the first embodiment in that the second water channel 54, the fourth water discharge port 15, and the first valve 17 are further provided.
 図3に示されるとおり、第4の吐水口15はケース20を貫通する。第1の弁17は、第1の連通路51、第2の水路54、および、第4の流入口46を連通する。第2の水路54は、第1の弁17および第4の吐水口15を連通する。第1の弁17は、第1の連通路51から第4の流入口46、および、第1の連通路51から第2の水路54のいずれかに流路を切替可能である。 As shown in FIG. 3, the fourth water discharge port 15 penetrates the case 20. The first valve 17 communicates with the first communication passage 51, the second water channel 54, and the fourth inflow port 46. The second water channel 54 communicates the first valve 17 and the fourth water discharge port 15. The first valve 17 can switch the flow path from any one of the first communication path 51 to the fourth inlet 46 and from the first communication path 51 to the second water path 54.
 アルカリ性水の生成時間が長くなるにつれて、第4の水槽45に炭酸カルシウムおよび水酸化マグネシウム等のスケールが付着しやすくなる。水処理装置10Bによれば、第2の切替器27を絶縁モードに設定し、第2の水路54を利用してアルカリ性水を取り出すことにより、第4の水槽45にスケールが付着することを抑制できる。 As the generation time of alkaline water becomes longer, scales such as calcium carbonate and magnesium hydroxide tend to adhere to the fourth water tank 45. According to the water treatment device 10 </ b> B, the second switch 27 is set to the insulation mode, and the alkaline water is extracted using the second water channel 54, thereby suppressing the scale from adhering to the fourth water tank 45. it can.
 (実施の形態4)
 実施の形態4の水処理装置10Cは、実施の形態1の水処理装置10と実質的に同じ構成を備える。実施の形態4では、第2の給水路56および第2の弁18をさらに備える点において、実施の形態1の構成と相違する。
(Embodiment 4)
The water treatment device 10C of the fourth embodiment has substantially the same configuration as the water treatment device 10 of the first embodiment. The fourth embodiment is different from the configuration of the first embodiment in that the second water supply channel 56 and the second valve 18 are further provided.
 図4に示されるとおり、第2の給水路56は原水路50から分岐している。第2の弁18は、第2の給水路56、第1の連通路51、および、第4の流入口46を連通する。第2の弁18は、第1の連通路51から第4の流入口46、および、第2の給水路56から第4の流入口46のいずれかに流路を切替可能である。 As shown in FIG. 4, the second water supply channel 56 branches off from the raw water channel 50. The second valve 18 communicates with the second water supply path 56, the first communication path 51, and the fourth inflow port 46. The second valve 18 can switch the flow path from the first communication path 51 to the fourth inlet 46 and from the second water supply path 56 to the fourth inlet 46.
 第2の切替器27が逆電モードのとき、第4の水槽45において、原水の酸化反応が生じる。すなわち、[2]式~[4]式に示される化学反応が生じ、第4の水槽45において酸性水が生成される。このため、第4の水槽45に付着しているスケールが酸性水に溶解し、スケールが除去される。 When the second switch 27 is in the reverse power mode, an oxidation reaction of raw water occurs in the fourth water tank 45. That is, a chemical reaction represented by the formulas [2] to [4] occurs, and acidic water is generated in the fourth water tank 45. For this reason, the scale adhering to the 4th water tank 45 melt | dissolves in acidic water, and a scale is removed.
 (変形例)
 上記各実施の形態に関する説明は本開示に係る水処理装置が取り得る形態の例示であり、その形態を制限することを意図していない。本開示に係る水処理装置は実施の形態以外に例えば以下に示される上記各実施の形態の変形例、および、相互に矛盾しない少なくとも2つの変形例が組み合わせられた形態を取り得る。
(Modification)
The description regarding each said embodiment is an illustration of the form which the water treatment apparatus which concerns on this indication can take, and it does not intend restrict | limiting the form. In addition to the embodiments, the water treatment apparatus according to the present disclosure may take a form in which, for example, the modifications of the above-described embodiments described below and at least two modifications not contradicting each other are combined.
 ・原水の作成方法は、任意に変更可能である。第1の例では、井戸水またはミネラルウォーターを浄水部21により浄水し、浄水された原水を水処理装置10に供給する。第2の例では、浄水部21を省略して、水道水を原水として水処理装置10に直接的に供給する。 ・ Raw water creation method can be changed arbitrarily. In the first example, well water or mineral water is purified by the water purification unit 21, and the purified raw water is supplied to the water treatment device 10. In the second example, the water purification unit 21 is omitted, and tap water is directly supplied to the water treatment apparatus 10 as raw water.
 ・原水に電解質を添加する添加部を、水処理装置10に付加できる。添加部は、例えば浄水部21から吐出された原水に、電解質の一例である塩を添加する。添加された塩が水中でナトリウムイオンNaおよび塩化物イオンClとなるため、原水の電気分解が促進される。このため、生成されるアルカリ性水のpHが高められやすい。 -The addition part which adds an electrolyte to raw | natural water can be added to the water treatment apparatus 10. FIG. An addition part adds the salt which is an example of electrolyte to the raw | natural water discharged from the water purification part 21, for example. Sodium ions Na added salt is in water + and chloride ion Cl -, and therefore, the electrolysis of the raw water is promoted. For this reason, the pH of the generated alkaline water is likely to be increased.
 ・実施の形態3において、第1の弁17を設けなくともよい。第2の切替器27が絶縁モードのとき、第2の水路54および第1の管61からアルカリ性水を吐出することができる。 In the third embodiment, the first valve 17 need not be provided. When the second switch 27 is in the insulation mode, alkaline water can be discharged from the second water channel 54 and the first pipe 61.
 ・実施の形態3の第1の切替器26を逆電モードに設定し、第2の水槽35において酸性水を生成してもよい。原水が通過する第2の水槽35においても、長期間経過するとスケールが付着することがある。生成した酸性水により第2の水槽35に付着したスケールを除去することができる。また、実施の形態3および実施の形態4の構成を組み合わせて、第2の水槽35および第4の水槽45に付着したスケールを同時に除去することもできる。 The first switch 26 according to the third embodiment may be set in the reverse power mode, and acidic water may be generated in the second water tank 35. Even in the second water tank 35 through which raw water passes, the scale may adhere after a long period of time. The scale adhering to the second water tank 35 can be removed by the generated acidic water. Further, the scales attached to the second water tank 35 and the fourth water tank 45 can be simultaneously removed by combining the configurations of the third embodiment and the fourth embodiment.
 本開示の一形態に係る水処理装置は、構成要素を化学的に損傷しにくく装置の寿命を延ばすことが可能となるため、多量の水を使用、または、構成要素を補修しにくい家電製品に適用できる。 Since the water treatment apparatus according to one embodiment of the present disclosure is difficult to chemically damage the constituent elements and can extend the life of the apparatus, the water treatment apparatus is used for home appliances that use a large amount of water or are difficult to repair the constituent elements. Applicable.
 10 水処理装置
 10A 水処理装置
 10B 水処理装置
 10C 水処理装置
 31 第1の水槽
 34 第1の電極
 35 第2の水槽
 38 第2の電極
 41 第3の水槽
 44 第3の電極
 45 第4の水槽
 48 第4の電極
 49 イオン交換膜
 50 原水路
 51 第1の連通路
 51A 第1の連通路
 52 第1の水路
 54 第2の水路
DESCRIPTION OF SYMBOLS 10 Water treatment apparatus 10A Water treatment apparatus 10B Water treatment apparatus 10C Water treatment apparatus 31 1st water tank 34 1st electrode 35 2nd water tank 38 2nd electrode 41 3rd water tank 44 3rd electrode 45 4th Water tank 48 Fourth electrode 49 Ion exchange membrane 50 Raw water channel 51 First communication channel 51A First communication channel 52 First water channel 54 Second water channel

Claims (5)

  1.  第1の水槽と、
     第2の水槽と、
     第3の水槽と、
     第4の水槽と、
     前記第1の水槽に設けられる第1の電極と、
     前記第2の水槽に設けられ、前記第1の電極に対応する第2の電極と、
     前記第3の水槽に設けられる第3の電極と、
     前記第4の水槽に設けられ、前記第3の電極に対応する第4の電極と、
     前記第3の水槽と前記第4の水槽とを区画するイオン交換膜と、
     前記第1の水槽で電気分解された水を前記第3の水槽および前記第4の水槽に供給することなく取り出すための第1の水路と、
     前記第2の水槽と前記第4の水槽とを連通する第1の連通路とを備える
     水処理装置。
    A first aquarium;
    A second aquarium,
    A third aquarium,
    A fourth aquarium,
    A first electrode provided in the first water tank;
    A second electrode provided in the second water tank and corresponding to the first electrode;
    A third electrode provided in the third water tank;
    A fourth electrode provided in the fourth water tank and corresponding to the third electrode;
    An ion exchange membrane that partitions the third water tank and the fourth water tank;
    A first water channel for extracting water electrolyzed in the first water tank without supplying it to the third water tank and the fourth water tank;
    A water treatment apparatus comprising: a first communication passage that communicates the second water tank and the fourth water tank.
  2.  前記第3の水槽は原水を供給する原水路を接続可能である
     請求項1に記載の水処理装置。
    The water treatment apparatus according to claim 1, wherein the third water tank is connectable to a raw water channel that supplies raw water.
  3.  前記第4の水槽は原水を供給する原水路を接続可能である
     請求項1または2に記載の水処理装置。
    The water treatment apparatus according to claim 1, wherein the fourth water tank is connectable to a raw water channel that supplies raw water.
  4.  前記第1の連通路は前記第2の水槽と前記第3の水槽とをさらに連通する
     請求項1~3のいずれか一項に記載の水処理装置。
    The water treatment device according to any one of claims 1 to 3, wherein the first communication path further communicates the second water tank and the third water tank.
  5.  前記第2の水槽で電気分解された水を前記第3の水槽および前記第4の水槽に供給することなく取り出すための第2の水路をさらに備える
     請求項1~4のいずれか一項に記載の水処理装置。
    The second water channel for removing water electrolyzed in the second water tank without supplying the water to the third water tank and the fourth water tank. Water treatment equipment.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09192667A (en) * 1996-01-24 1997-07-29 Mizu:Kk Electrolyzed water generating device
JPH10202260A (en) * 1997-01-16 1998-08-04 Tokico Ltd Electrolyzed water forming device
JP2000176452A (en) * 1998-12-14 2000-06-27 Chemicoat & Co Ltd Production of electrolytically ionized water
JP2005040781A (en) * 2003-07-08 2005-02-17 Kyushu Hitachi Maxell Ltd Water conditioner

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09192667A (en) * 1996-01-24 1997-07-29 Mizu:Kk Electrolyzed water generating device
JPH10202260A (en) * 1997-01-16 1998-08-04 Tokico Ltd Electrolyzed water forming device
JP2000176452A (en) * 1998-12-14 2000-06-27 Chemicoat & Co Ltd Production of electrolytically ionized water
JP2005040781A (en) * 2003-07-08 2005-02-17 Kyushu Hitachi Maxell Ltd Water conditioner

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