KR20090083006A - Pellets, and the methods thereof and pellets block - Google Patents
Pellets, and the methods thereof and pellets block Download PDFInfo
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- KR20090083006A KR20090083006A KR1020080008913A KR20080008913A KR20090083006A KR 20090083006 A KR20090083006 A KR 20090083006A KR 1020080008913 A KR1020080008913 A KR 1020080008913A KR 20080008913 A KR20080008913 A KR 20080008913A KR 20090083006 A KR20090083006 A KR 20090083006A
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- pellets
- pellet
- porous ceramic
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- 239000008188 pellet Substances 0.000 title claims abstract description 93
- 238000000034 method Methods 0.000 title claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 37
- 239000000919 ceramic Substances 0.000 claims abstract description 35
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000011521 glass Substances 0.000 claims abstract description 32
- 239000002699 waste material Substances 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 22
- 238000002156 mixing Methods 0.000 claims abstract description 21
- 238000010438 heat treatment Methods 0.000 claims abstract description 18
- 238000001035 drying Methods 0.000 claims abstract description 17
- 238000000465 moulding Methods 0.000 claims abstract description 15
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 12
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 12
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 12
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 12
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 11
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000292 calcium oxide Substances 0.000 claims abstract description 11
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011780 sodium chloride Substances 0.000 claims abstract description 11
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 11
- 239000002689 soil Substances 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims description 24
- 238000004519 manufacturing process Methods 0.000 claims description 22
- 238000002360 preparation method Methods 0.000 claims description 20
- 238000010304 firing Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 229940095674 pellet product Drugs 0.000 claims description 7
- 238000005507 spraying Methods 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 238000005303 weighing Methods 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims 2
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 2
- 241000251468 Actinopterygii Species 0.000 abstract 2
- 238000011109 contamination Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 239000002245 particle Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 241000195493 Cryptophyta Species 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003653 coastal water Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000242583 Scyphozoa Species 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K61/00—Culture of aquatic animals
- A01K61/70—Artificial fishing banks or reefs
- A01K61/77—Artificial fishing banks or reefs of monolithic form, e.g. blocks
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
- C04B35/62655—Drying, e.g. freeze-drying, spray-drying, microwave or supercritical drying
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/62695—Granulation or pelletising
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
- C04B2235/3274—Ferrites
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/444—Halide containing anions, e.g. bromide, iodate, chlorite
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Marine Sciences & Fisheries (AREA)
- Zoology (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
The present invention relates to a porous ceramic pellets, a method for manufacturing the same, and a block using the pellets. More specifically, a pellet made by processing waste glass to be treated at a predetermined level or less with powder and mixing with additives containing ocher powder is used. It can be used as a material for manufacturing various eco-friendly water reefs and alternative soils to reduce environmental pollution caused by waste glass, and to replace existing artificial reef blocks and soils that could have environmental problems. Porous ceramic pellets, a method of manufacturing the same and a block using the pellets.
With the development of modern building technology and the development of automobile industry and packaging industry, the use and use of glass have increased exponentially, and the amount of waste glass treated has increased. Meanwhile, as part of an effort to recycle waste glass, recycled glass is obtained through a refining process that separates foreign materials from the collected waste glass, and the recycled glass is being mixed to prepare new glass products. However, due to technical limitations in the separation of foreign matter contained in the waste glass, not all waste glass is recycled.
On the other hand, modern natural environment has long been an intertidal algae in coastal rock area due to lack of dynamics and biological activity due to severe pollution of coastal areas due to the increase of atmospheric carbon dioxide and the increase of water temperature due to global warming. It is being melted and lost.
Efforts have been made to install various types of porous artificial reefs in the water as a part of preventing the adverse effects of these phenomena on aquatic plants and animals, but since most of the raw materials for manufacturing artificial reefs are cement, There was a problem that secondary pollution occurred by erosion of seawater. In particular, this secondary pollution has been pointed out as a cause of the rapid imbalance of marine resources by causing the rapid proliferation of flip flop, the larvae of jellyfish.
The present invention has been made in view of the existing problems as described above, the waste glass to be processed by processing the waste glass to a predetermined level or less powder and mixed with additives containing ocher powder for improving various environmentally friendly water quality It can be used as a material for manufacturing artificial reefs and alternative soils to reduce the environmental pollution caused by waste glass and to replace the existing artificial reef blocks and soils that could have environmental problems. It is a first object to provide a manufacturing method.
In addition, the present invention has a second object to provide a block that is used as an artificial reef for maintaining the vegetation of aquatic flora and fauna more environmentally friendly by using a new type of environmentally friendly porous ceramic pellets.
Method for producing a porous ceramic pellets of the present invention for achieving the above object, 40 to 48 parts by weight, prepared by filtering waste glass powder to 200 mesh or less relative to the total combination ratio of the pellet, and 3 to 5 parts by weight of sodium silicate, 3 to 5 parts by weight of water, 15 to 21 parts by weight of ocher powder, 3 to 5 parts by weight of sodium chloride, 10 to 12 parts by weight of calcium oxide, 10 to 12 parts by weight of magnesium oxide, ferrite, sawdust and citric acid A raw material preparation step for weighing and preparing 1 part by weight or less of additives, 40 to 48 parts by weight of waste glass powder weighed after the raw material preparation step, 3 to 5 parts by weight of sodium silicate, 15 to 21 weight of
Method for producing a porous ceramic pellets of the present invention, characterized in that to further weigh 1.0 to 2.4 parts by weight of calcium carbonate in the raw material preparation step to mix in the mixing step.
The method for producing a porous ceramic pellet block according to the present invention includes 40 to 48 parts by weight of the waste glass powder, which is prepared by filtering the total amount of pellets to 200 mesh or less, 3 to 5 parts by weight of sodium silicate, 3 to 5 parts by weight of water, 15 to 21 parts by weight of ocher powder, 3 to 5 parts by weight of sodium chloride, 10 to 12 parts by weight of calcium oxide, 10 to 12 parts by weight of magnesium oxide, and 1 part by weight or less of other additives consisting of ferrite, sawdust and citric acid 40 to 48 parts by weight of the prepared raw material preparation step, the waste glass powder weighed after the raw material preparation step, 3 to 5 parts by weight of sodium silicate, 15 to 21 parts by weight of ocher powder, and 3 to 5 sodium chloride Mixing step of mixing, while adding 1 part by weight or less of calcium oxide, 10 to 12 parts by weight of magnesium oxide, 10 parts by weight of magnesium oxide, and 1 part by weight of ferrite, sawdust and citric acid to 1 part by weight or less, and sprinkling 1 part by weight of water. And, the ash in the bulk through the mixing step Is put into the refilling machine while spraying the water weighed in the raw material preparation step while forming a spherical pellet of a certain size and drying step of drying the pellet formed in the recirculation step by setting the heating time and temperature And, the forming step of placing the pellets subjected to the drying step into a mold having a desired shape, and heating the pellets product undergoing the molding step while heating the temperature gradually by setting the heating time and temperature according to the size, strength and shape Firing step, characterized in that it comprises a demolding step of separating the pellet block passed through the firing step from the mold.
As described above, according to the method of manufacturing the porous ceramic pellets of the present invention, artificial reefs for improving various eco-friendly water quality pellets made by processing waste glass to be processed into powder below a certain level and mixed with additives containing ocher powder In addition to reducing the environmental pollution caused by the waste glass by being used as a material for the production and replacement soil, there is an effect that can replace the existing artificial reef blocks and soil that had the potential for environmental problems.
In addition, according to the block using the pellet of the present invention, by using a new type of environmentally friendly porous ceramic pellets, there is an effect that can be used as artificial reefs for maintaining the vegetation of the flora and fauna underwater.
Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
1 (A) to (D) is an explanatory diagram showing a state in which the porous ceramic pellets of the present invention are molded into various sizes and shapes, and FIG. 2 is a block diagram showing a manufacturing process of the porous ceramic pellets of the present invention. 3A to 3N show an example of a block using the porous ceramic pellets of the present invention. Finally, the porous ceramic pellets produced are approximately spherical in shape as shown in FIG. 1 and have sizes in the range of 2 to 50 mm. In the following description, the name of the porous ceramic pellet may be used as a name abbreviated as pellet.
The main raw material used in the production of multi-use eco-friendly porous ceramic pellets is waste glass which is disposed of from buildings, automobiles and packaging containers. Waste glass collected for use in the production of multi-use eco-friendly porous ceramic pellets is first made into a powder through a predetermined shredding process using a shredder after a foreign material separation process and a washing process for removing foreign substances. The pulverized waste glass is pulverized in a pulverizer so as to be a powder having a particle size of 200 mesh or less which is a state suitable for carrying out the present invention in the raw material preparation step.
In the raw material preparation step, the crushing is performed in a crusher such that the loess powder, which is another raw material of the pellet, may have a particle size of 200 mesh or less. For reference, in the process of adjusting the particle size of the powder may pass through the screen having the particle size.
Method for producing a porous ceramic pellets according to the present invention, 40 to 48 parts by weight, prepared by filtering waste glass powder to 200 mesh or less relative to the total combination ratio of the pellet, 3 to 5 parts by weight of sodium silicate, 3 to 5 parts by weight of water 15 to 21 parts by weight of ocher powder, 3 to 5 parts by weight of sodium chloride, 10 to 12 parts by weight of calcium oxide, 10 to 12 parts by weight of magnesium oxide, and 1 part by weight or less of other additives consisting of ferrite, sawdust and citric acid Raw material preparation step (S1) prepared by the step, and after the raw material preparation step 40 to 48 parts by weight of weighed waste glass powder, 3 to 5 parts by weight of sodium silicate, 15 to 21 parts by weight of ocher powder, 3 to 5 parts by weight of sodium chloride, 10 to 12 parts by weight of calcium oxide, 10 to 12 parts by weight of magnesium oxide, and 1 part by weight or less of other additives consisting of ferrite, sawdust and citric acid are added to the mixer, and sprinkled with 1 part by weight of water. Mixing step of mixing (S2), and the bulk phase through the mixing step Put the material in the refilling machine while spraying the water weighed in the raw material preparation step while rotating the recirculation step (S3) to form a spherical pellet of a certain size, and set the heating time and temperature of the pellet formed in the recirculation step Drying step (S4) to dry by, the molding step (S5) to coat the ocher powder prepared separately from the tray as a release agent on the pellet so that the pellet product after the drying step is easily demolded, and the pellet product after the molding step Firing step (S6) for heating while gradually raising the temperature by setting the heating time and temperature in accordance with the size, strength and shape, demolding step (S7) for separating the pellets undergoing the firing step from ocher, and the demolded pellet It includes a sorting step (S8) for classifying by size.
Here, the sodium silicate is composed of a liquid phase, the water sprayed in the mixing step (S2) is used within the range of 1 part by weight as the weather is clear and humid.
In addition, when spraying the water in the recirculation step (S3) to form a pellet of a spherical shape of a certain size bar, the size of the pellet is determined according to the injection form of water.
And in the drying step (S4) is dried for about 2 hours at 60 ~ 80 ℃ in this embodiment.
In addition, when the ocher powder is coated with a release agent on the pellet in the forming step (S5), the pellet and the ocher are coated with the ocher powder as a release agent on the tray in a ratio of 1: 1 so that the mold can be easily demolded.
On the other hand in the firing step (S6) to reach 100 ℃ within 1 hour and maintain a certain time, to reach 300 ℃ within 3 hours and maintain a certain time, to reach 830 ℃ within 7 hours and maintain a certain time, After that, it is cooled to room temperature. In the firing step, the strength and the porous size are determined according to the set temperature.
In addition, in the demolding step (S7) to remove the ocher by separating the pellet from the ocher sprinkled with a release agent to the pellet during molding.
Thus prepared pellets can be made of various types of pellets, as shown in (A) to (D) of Figure 1, because these pellets are made of a number of porous has an excellent effect on water purification or water quality improvement.
Meanwhile, 1.0 to 2.4 parts by weight of calcium carbonate may be further weighed in the raw material preparation step and mixed in the mixing step.
When the calcium carbonate is not included at all when mixing the raw materials, it is used for artificial reef or water purification and improvement, and when calcium deoxidation is included in 1 parts by weight, it is used as an alternative soil, and it is contained in 2.4 parts by weight. In this case, it is used for planting.
The method for producing the pellets described above is just one embodiment for producing a multi-use eco-friendly porous ceramic pellets according to the present invention, the porous ceramic pellets according to the present invention is more applied based on the method as described above It may be prepared by other methods.
On the other hand, the method of manufacturing a porous ceramic pellet block of the present invention, in the manufacturing method of the pellet, the forming step (S9) to put the pellets undergoing the drying step in the mold of the desired shape during the molding step and the forming step It comprises a firing step (S6) for heating the pellet product while setting the heating time and temperature according to the size, strength and shape gradually increasing the temperature, and the demolding step (S10) for separating the pellet block subjected to the firing step from the molding die do.
Therefore, various pellet blocks are made into various shapes as shown in FIGS. 3A to 3N by molding molds having various shapes of porous ceramic pellets.
The porous ceramic pellet block produced as described above has the following advantages. 1) It is possible to function as a porous artificial reef in coastal waters necessary for habitat, such as feeding, spawning, and growing of various aquatic organisms. 2) It is possible to maintain the fishery function continuously by constructing the marine forests using artificially generated algae blocks or by periodically providing new surface substrates that were not possible in the existing integrated artificial reef structure. 3) In coastal waters where algae are lost due to the tidal currents and strong external force, it has a functional effect as a fishing term for early marine forest formation. 4) The blast furnace slag, which is a conventional porous concrete or industrial waste, has a high possibility of secondary pollution, whereas the porous ceramic pellet block according to the present invention has the value of eco-friendly composition to improve marine pollution by using environmentally friendly and harmless waste resources. . 5) The application of this porous ceramic pellet block can be expected to raise the standard of living by rethinking competitiveness using fishery marine resources and improving the income of fishermen.
An embodiment of the present invention described above and illustrated in the drawings should not be construed as limiting the technical idea of the present invention. The protection scope of the present invention is limited only by the matters described in the claims, and those skilled in the art can change and change the technical idea of the present invention in various forms. Therefore, such improvements and modifications will fall within the protection scope of the present invention, as will be apparent to those skilled in the art.
1 (A) to (D) are explanatory views showing a state in which the porous ceramic pellets of the present invention are molded into various sizes and shapes,
2 is a block diagram showing a process for producing the porous ceramic pellets of the present invention;
3A to 3N show an example of a block using the porous ceramic pellets of the present invention.
Claims (5)
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KR1020080008913A KR20090083006A (en) | 2008-01-29 | 2008-01-29 | Pellets, and the methods thereof and pellets block |
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KR1020080008913A KR20090083006A (en) | 2008-01-29 | 2008-01-29 | Pellets, and the methods thereof and pellets block |
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2008
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