KR20090083006A - Pellets, and the methods thereof and pellets block - Google Patents

Pellets, and the methods thereof and pellets block Download PDF

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Publication number
KR20090083006A
KR20090083006A KR1020080008913A KR20080008913A KR20090083006A KR 20090083006 A KR20090083006 A KR 20090083006A KR 1020080008913 A KR1020080008913 A KR 1020080008913A KR 20080008913 A KR20080008913 A KR 20080008913A KR 20090083006 A KR20090083006 A KR 20090083006A
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South Korea
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weight
parts
pellets
pellet
porous ceramic
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KR1020080008913A
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Korean (ko)
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유춘식
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유춘식
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K61/00Culture of aquatic animals
    • A01K61/70Artificial fishing banks or reefs
    • A01K61/77Artificial fishing banks or reefs of monolithic form, e.g. blocks
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62645Thermal treatment of powders or mixtures thereof other than sintering
    • C04B35/62655Drying, e.g. freeze-drying, spray-drying, microwave or supercritical drying
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62695Granulation or pelletising
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64Burning or sintering processes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206Magnesium oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3272Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
    • C04B2235/3274Ferrites
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/444Halide containing anions, e.g. bromide, iodate, chlorite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Zoology (AREA)
  • Animal Husbandry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A porous ceramic pellet for artificial fish reef, a fabricating method thereof and a block using the porous ceramic pellet are provided to reduce environmental contamination due to waste glass and to replace existing blocks and soil for artificial fish reef. A method for fabricating a porous ceramic pellet comprises the following steps of: preparing waste glass; putting the waste glass with additives consisting of sodium silicate, loess powder, sodium chloride, calcium oxide, magnesium oxide, ferrite, sawdust and citric acid in a mixer and mixing them with water sprayed; molding the mixture into pellets; drying the pellets; covering the pellet with loess powder as a releasing agent; gradually heating the pellets to sinter them; and removing the loess from the pellets.

Description

Porous ceramic pellets, manufacturing method thereof and blocks using pellets {PELLETS, AND THE METHODS THEREOF AND PELLETS BLOCK}

The present invention relates to a porous ceramic pellets, a method for manufacturing the same, and a block using the pellets. More specifically, a pellet made by processing waste glass to be treated at a predetermined level or less with powder and mixing with additives containing ocher powder is used. It can be used as a material for manufacturing various eco-friendly water reefs and alternative soils to reduce environmental pollution caused by waste glass, and to replace existing artificial reef blocks and soils that could have environmental problems. Porous ceramic pellets, a method of manufacturing the same and a block using the pellets.

With the development of modern building technology and the development of automobile industry and packaging industry, the use and use of glass have increased exponentially, and the amount of waste glass treated has increased. Meanwhile, as part of an effort to recycle waste glass, recycled glass is obtained through a refining process that separates foreign materials from the collected waste glass, and the recycled glass is being mixed to prepare new glass products. However, due to technical limitations in the separation of foreign matter contained in the waste glass, not all waste glass is recycled.

On the other hand, modern natural environment has long been an intertidal algae in coastal rock area due to lack of dynamics and biological activity due to severe pollution of coastal areas due to the increase of atmospheric carbon dioxide and the increase of water temperature due to global warming. It is being melted and lost.

Efforts have been made to install various types of porous artificial reefs in the water as a part of preventing the adverse effects of these phenomena on aquatic plants and animals, but since most of the raw materials for manufacturing artificial reefs are cement, There was a problem that secondary pollution occurred by erosion of seawater. In particular, this secondary pollution has been pointed out as a cause of the rapid imbalance of marine resources by causing the rapid proliferation of flip flop, the larvae of jellyfish.

The present invention has been made in view of the existing problems as described above, the waste glass to be processed by processing the waste glass to a predetermined level or less powder and mixed with additives containing ocher powder for improving various environmentally friendly water quality It can be used as a material for manufacturing artificial reefs and alternative soils to reduce the environmental pollution caused by waste glass and to replace the existing artificial reef blocks and soils that could have environmental problems. It is a first object to provide a manufacturing method.

In addition, the present invention has a second object to provide a block that is used as an artificial reef for maintaining the vegetation of aquatic flora and fauna more environmentally friendly by using a new type of environmentally friendly porous ceramic pellets.

Method for producing a porous ceramic pellets of the present invention for achieving the above object, 40 to 48 parts by weight, prepared by filtering waste glass powder to 200 mesh or less relative to the total combination ratio of the pellet, and 3 to 5 parts by weight of sodium silicate, 3 to 5 parts by weight of water, 15 to 21 parts by weight of ocher powder, 3 to 5 parts by weight of sodium chloride, 10 to 12 parts by weight of calcium oxide, 10 to 12 parts by weight of magnesium oxide, ferrite, sawdust and citric acid A raw material preparation step for weighing and preparing 1 part by weight or less of additives, 40 to 48 parts by weight of waste glass powder weighed after the raw material preparation step, 3 to 5 parts by weight of sodium silicate, 15 to 21 weight of ocher powder 1 part by weight or less of water, 3 to 5 parts by weight of sodium chloride, 10 to 12 parts by weight of calcium oxide, 10 to 12 parts by weight of magnesium oxide, and 1 part by weight or less of other additives consisting of ferrite, sawdust and citric acid are added to the mixer. Mixing step of mixing while spraying, the horn Refilling the pellets formed in the recirculation step and forming the spherical pellets of a certain size while spraying the water weighed in the raw material preparation step while rotating the material in the bulk state passed through the step into the recirculation step Drying step of setting and drying, the molding step of coating the ocher powder prepared separately from the tray as a release agent to the pellet so that the pellet product after the drying step is easily demolded, the size and strength and It includes a firing step of heating while gradually raising the temperature by setting the heating time and temperature according to the shape, and a demolding step of separating the pellets undergoing the firing step from the loess.

Method for producing a porous ceramic pellets of the present invention, characterized in that to further weigh 1.0 to 2.4 parts by weight of calcium carbonate in the raw material preparation step to mix in the mixing step.

The method for producing a porous ceramic pellet block according to the present invention includes 40 to 48 parts by weight of the waste glass powder, which is prepared by filtering the total amount of pellets to 200 mesh or less, 3 to 5 parts by weight of sodium silicate, 3 to 5 parts by weight of water, 15 to 21 parts by weight of ocher powder, 3 to 5 parts by weight of sodium chloride, 10 to 12 parts by weight of calcium oxide, 10 to 12 parts by weight of magnesium oxide, and 1 part by weight or less of other additives consisting of ferrite, sawdust and citric acid 40 to 48 parts by weight of the prepared raw material preparation step, the waste glass powder weighed after the raw material preparation step, 3 to 5 parts by weight of sodium silicate, 15 to 21 parts by weight of ocher powder, and 3 to 5 sodium chloride Mixing step of mixing, while adding 1 part by weight or less of calcium oxide, 10 to 12 parts by weight of magnesium oxide, 10 parts by weight of magnesium oxide, and 1 part by weight of ferrite, sawdust and citric acid to 1 part by weight or less, and sprinkling 1 part by weight of water. And, the ash in the bulk through the mixing step Is put into the refilling machine while spraying the water weighed in the raw material preparation step while forming a spherical pellet of a certain size and drying step of drying the pellet formed in the recirculation step by setting the heating time and temperature And, the forming step of placing the pellets subjected to the drying step into a mold having a desired shape, and heating the pellets product undergoing the molding step while heating the temperature gradually by setting the heating time and temperature according to the size, strength and shape Firing step, characterized in that it comprises a demolding step of separating the pellet block passed through the firing step from the mold.

As described above, according to the method of manufacturing the porous ceramic pellets of the present invention, artificial reefs for improving various eco-friendly water quality pellets made by processing waste glass to be processed into powder below a certain level and mixed with additives containing ocher powder In addition to reducing the environmental pollution caused by the waste glass by being used as a material for the production and replacement soil, there is an effect that can replace the existing artificial reef blocks and soil that had the potential for environmental problems.

In addition, according to the block using the pellet of the present invention, by using a new type of environmentally friendly porous ceramic pellets, there is an effect that can be used as artificial reefs for maintaining the vegetation of the flora and fauna underwater.

Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

1 (A) to (D) is an explanatory diagram showing a state in which the porous ceramic pellets of the present invention are molded into various sizes and shapes, and FIG. 2 is a block diagram showing a manufacturing process of the porous ceramic pellets of the present invention. 3A to 3N show an example of a block using the porous ceramic pellets of the present invention. Finally, the porous ceramic pellets produced are approximately spherical in shape as shown in FIG. 1 and have sizes in the range of 2 to 50 mm. In the following description, the name of the porous ceramic pellet may be used as a name abbreviated as pellet.

The main raw material used in the production of multi-use eco-friendly porous ceramic pellets is waste glass which is disposed of from buildings, automobiles and packaging containers. Waste glass collected for use in the production of multi-use eco-friendly porous ceramic pellets is first made into a powder through a predetermined shredding process using a shredder after a foreign material separation process and a washing process for removing foreign substances. The pulverized waste glass is pulverized in a pulverizer so as to be a powder having a particle size of 200 mesh or less which is a state suitable for carrying out the present invention in the raw material preparation step.

In the raw material preparation step, the crushing is performed in a crusher such that the loess powder, which is another raw material of the pellet, may have a particle size of 200 mesh or less. For reference, in the process of adjusting the particle size of the powder may pass through the screen having the particle size.

Method for producing a porous ceramic pellets according to the present invention, 40 to 48 parts by weight, prepared by filtering waste glass powder to 200 mesh or less relative to the total combination ratio of the pellet, 3 to 5 parts by weight of sodium silicate, 3 to 5 parts by weight of water 15 to 21 parts by weight of ocher powder, 3 to 5 parts by weight of sodium chloride, 10 to 12 parts by weight of calcium oxide, 10 to 12 parts by weight of magnesium oxide, and 1 part by weight or less of other additives consisting of ferrite, sawdust and citric acid Raw material preparation step (S1) prepared by the step, and after the raw material preparation step 40 to 48 parts by weight of weighed waste glass powder, 3 to 5 parts by weight of sodium silicate, 15 to 21 parts by weight of ocher powder, 3 to 5 parts by weight of sodium chloride, 10 to 12 parts by weight of calcium oxide, 10 to 12 parts by weight of magnesium oxide, and 1 part by weight or less of other additives consisting of ferrite, sawdust and citric acid are added to the mixer, and sprinkled with 1 part by weight of water. Mixing step of mixing (S2), and the bulk phase through the mixing step Put the material in the refilling machine while spraying the water weighed in the raw material preparation step while rotating the recirculation step (S3) to form a spherical pellet of a certain size, and set the heating time and temperature of the pellet formed in the recirculation step Drying step (S4) to dry by, the molding step (S5) to coat the ocher powder prepared separately from the tray as a release agent on the pellet so that the pellet product after the drying step is easily demolded, and the pellet product after the molding step Firing step (S6) for heating while gradually raising the temperature by setting the heating time and temperature in accordance with the size, strength and shape, demolding step (S7) for separating the pellets undergoing the firing step from ocher, and the demolded pellet It includes a sorting step (S8) for classifying by size.

Here, the sodium silicate is composed of a liquid phase, the water sprayed in the mixing step (S2) is used within the range of 1 part by weight as the weather is clear and humid.

In addition, when spraying the water in the recirculation step (S3) to form a pellet of a spherical shape of a certain size bar, the size of the pellet is determined according to the injection form of water.

And in the drying step (S4) is dried for about 2 hours at 60 ~ 80 ℃ in this embodiment.

In addition, when the ocher powder is coated with a release agent on the pellet in the forming step (S5), the pellet and the ocher are coated with the ocher powder as a release agent on the tray in a ratio of 1: 1 so that the mold can be easily demolded.

On the other hand in the firing step (S6) to reach 100 ℃ within 1 hour and maintain a certain time, to reach 300 ℃ within 3 hours and maintain a certain time, to reach 830 ℃ within 7 hours and maintain a certain time, After that, it is cooled to room temperature. In the firing step, the strength and the porous size are determined according to the set temperature.

In addition, in the demolding step (S7) to remove the ocher by separating the pellet from the ocher sprinkled with a release agent to the pellet during molding.

Thus prepared pellets can be made of various types of pellets, as shown in (A) to (D) of Figure 1, because these pellets are made of a number of porous has an excellent effect on water purification or water quality improvement.

Meanwhile, 1.0 to 2.4 parts by weight of calcium carbonate may be further weighed in the raw material preparation step and mixed in the mixing step.

When the calcium carbonate is not included at all when mixing the raw materials, it is used for artificial reef or water purification and improvement, and when calcium deoxidation is included in 1 parts by weight, it is used as an alternative soil, and it is contained in 2.4 parts by weight. In this case, it is used for planting.

The method for producing the pellets described above is just one embodiment for producing a multi-use eco-friendly porous ceramic pellets according to the present invention, the porous ceramic pellets according to the present invention is more applied based on the method as described above It may be prepared by other methods.

On the other hand, the method of manufacturing a porous ceramic pellet block of the present invention, in the manufacturing method of the pellet, the forming step (S9) to put the pellets undergoing the drying step in the mold of the desired shape during the molding step and the forming step It comprises a firing step (S6) for heating the pellet product while setting the heating time and temperature according to the size, strength and shape gradually increasing the temperature, and the demolding step (S10) for separating the pellet block subjected to the firing step from the molding die do.

Therefore, various pellet blocks are made into various shapes as shown in FIGS. 3A to 3N by molding molds having various shapes of porous ceramic pellets.

The porous ceramic pellet block produced as described above has the following advantages. 1) It is possible to function as a porous artificial reef in coastal waters necessary for habitat, such as feeding, spawning, and growing of various aquatic organisms. 2) It is possible to maintain the fishery function continuously by constructing the marine forests using artificially generated algae blocks or by periodically providing new surface substrates that were not possible in the existing integrated artificial reef structure. 3) In coastal waters where algae are lost due to the tidal currents and strong external force, it has a functional effect as a fishing term for early marine forest formation. 4) The blast furnace slag, which is a conventional porous concrete or industrial waste, has a high possibility of secondary pollution, whereas the porous ceramic pellet block according to the present invention has the value of eco-friendly composition to improve marine pollution by using environmentally friendly and harmless waste resources. . 5) The application of this porous ceramic pellet block can be expected to raise the standard of living by rethinking competitiveness using fishery marine resources and improving the income of fishermen.

An embodiment of the present invention described above and illustrated in the drawings should not be construed as limiting the technical idea of the present invention. The protection scope of the present invention is limited only by the matters described in the claims, and those skilled in the art can change and change the technical idea of the present invention in various forms. Therefore, such improvements and modifications will fall within the protection scope of the present invention, as will be apparent to those skilled in the art.

1 (A) to (D) are explanatory views showing a state in which the porous ceramic pellets of the present invention are molded into various sizes and shapes,

2 is a block diagram showing a process for producing the porous ceramic pellets of the present invention;

3A to 3N show an example of a block using the porous ceramic pellets of the present invention.

Claims (5)

40 to 48 parts by weight of waste glass powder, which is prepared by filtering the total amount of pellets to 200 mesh or less, 3 to 5 parts by weight of sodium silicate, 3 to 5 parts by weight of water, 15 to 21 parts by weight of ocher powder, sodium chloride 3 A raw material preparation step of weighing and preparing ~ 5 parts by weight, 10-12 parts by weight of calcium oxide, 10-12 parts by weight of magnesium oxide, and 1 part by weight or less of other additives consisting of ferrite, sawdust and citric acid; After the raw material preparation step, 40 to 48 parts by weight of weighed waste glass powder, 3 to 5 parts by weight of sodium silicate, 15 to 21 parts by weight of ocher powder, 3 to 5 parts by weight of sodium chloride, and 10 to 12 calcium oxide A mixing step of mixing by weight, adding 1 to 12 parts by weight of magnesium oxide, 1 part by weight or less of ferrite, sawdust and citric acid, into a mixer, and sprinkling 1 part by weight or less of water; A recirculation step of forming a spherical pellet having a predetermined size while spraying the water weighed in the raw material preparation step while rotating the material of the bulk obtained through the mixing step into the recirculator; A drying step of drying the pellets formed in the recycling step by setting a heating time and a temperature; A molding step of coating the ocher powder prepared separately from the tray with a release agent on the pellet so that the pellet product after the drying step is easily demolded; A firing step of heating the pellet product which has undergone the molding step while gradually raising the temperature by setting the heating time and temperature according to the size, strength and shape; Method for producing porous ceramic pellets comprising the demolding step of separating the pellets passed through the firing step from the yellow soil. The method of claim 1, The method for producing a porous ceramic pellets, characterized in that to further weigh 1.0 to 2.4 parts by weight of calcium carbonate in the raw material preparation step to mix in the mixing step. Porous ceramic pellets prepared by the method of claims 1 and 2. 40 to 48 parts by weight of waste glass powder, which is prepared by filtering the total amount of pellets to 200 mesh or less, 3 to 5 parts by weight of sodium silicate, 3 to 5 parts by weight of water, 15 to 21 parts by weight of ocher powder, sodium chloride 3 A raw material preparation step of weighing and preparing ~ 5 parts by weight, 10-12 parts by weight of calcium oxide, 10-12 parts by weight of magnesium oxide, and 1 part by weight or less of other additives consisting of ferrite, sawdust and citric acid; After the raw material preparation step, 40 to 48 parts by weight of weighed waste glass powder, 3 to 5 parts by weight of sodium silicate, 15 to 21 parts by weight of ocher powder, 3 to 5 parts by weight of sodium chloride, and 10 to 12 calcium oxide A mixing step of mixing by weight, adding 1 to 12 parts by weight of magnesium oxide, 1 part by weight or less of ferrite, sawdust and citric acid, into a mixer, and sprinkling 1 part by weight or less of water; A recirculation step of forming a spherical pellet having a predetermined size while spraying the water weighed in the raw material preparation step while rotating the material of the bulk obtained through the mixing step into the recirculator; A drying step of drying the pellets formed in the recycling step by setting a heating time and a temperature; A molding step of putting the pellets subjected to the drying step into a molding mold having a desired shape; A firing step of heating the pellet product which has undergone the molding step while gradually raising the temperature by setting the heating time and temperature according to the size, strength and shape; Method for producing a porous ceramic pellets block comprising the demolding step of separating the pellet block passed through the firing step in the molding die. A porous ceramic pellets block prepared by the method of claim 4.
KR1020080008913A 2008-01-29 2008-01-29 Pellets, and the methods thereof and pellets block KR20090083006A (en)

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