KR20090028309A - Stabilizing method of the cosmetic composition containing oil and polyol and the cosmetic composition prepared there from - Google Patents

Abstract

A method for stabilizing a cosmetic composition in which oil and polyol are contained is provided to disperse uniformly and stabilize oil and the polyol not mixed each other using pyrolysis porous silicon oxide, to have excellen skin-improvng effect and to maintain activity of effect ingredients for a long time. A method for stabilizing a cosmetic composition in which oil and polyol are contained includes steps of: adding pyrolysis porous silicon oxide in oil, dispersing a pyrolysis porous silicon oxide, adding polyol in the obtained dispersed solution; and stabilizing the cosmetic composition by dispersing the polyol.

Description

Stabilizing method of the cosmetic composition containing oil and polyol and the cosmetic composition prepared there from}

The present invention relates to a method for stabilizing oils and polyols through an incremental effect of fumed silica and a cosmetic composition using the same. More specifically, the present invention relates to a method of stabilizing a cosmetic composition uniformly dispersed by increasing the amount of oil and polyol that are not mixed with each other by using pyrolytic porous silicon oxide, and an oil gel type cosmetic composition of anhydrous formulations using the same.

These days, the skin dries and the surface is caused by various causes such as various stresses caused by changes in the environment and lifestyles, skin stress caused by environmental pollution, frequent face-washing caused by makeup habits, and natural skin aging due to age. Since the skin becomes rough and loses shine and dull appearance occurs, the need for a skin moisturizer with excellent moisturizing persistence is increasing. To this end, a method of increasing moisture retention in the stratum corneum by using a humectant, which has a property of absorbing moisture as a moisturizer, or an occlusive moisturizer that prevents evaporation of moisture, has been performed. Examples of the humectants include polyols such as glycerin, 1,3-butylene glycol, propylene glycol, polyethylene glycol, and sorbitol. These polyols have the disadvantage of having good water-containing ability but lacking in persistence for moisturizing feeling and being sticky or damp when applied to the skin. Oils generally have a higher moisturizing retention than polyols, but have a disadvantage in that they have a negative effect such as slow absorption, stickiness, and shine when used in large amounts in cosmetics (IFSCC, 9, 1-5, 2006).

In addition, recently, researches to give new value to cosmetics using various cosmetic formulation technologies are constantly underway. Emulsion is the formulation system most representatively used in the cosmetic industry and refers to a system in which an oil phase and a water phase are evenly dispersed using an emulsification technique. Factors affecting the physical and chemical properties of these emulsions include emulsion types (oil / water (O / W), water / oil (W / O), water / oil / water (W / O / W), oil / Polyols (O / P), polyols / oils (P / O, etc.), internal and external ratios, types of surfactants, thickeners, and the like. Attempts have been made to develop cosmetic formulations having physical properties and efficacy. However, since aerosil, which is a pyrolytic porous silicon oxide, is very light and easily blows, it is difficult to use a large capacity in the cosmetic manufacturing process.

The present inventors attempted to make an oil gel type cosmetic having a moisturizing effect maximized by using a polyol having excellent water-containing ability and an oil having excellent moisturizing sustainability. However, oil and polyol do not mix with each other like water and oil and thus stabilize it. There was a problem to be done. Accordingly, the present inventors studied a method for stabilizing a cosmetic composition containing oil and polyol through the incremental effect of pyrolytic porous silicon oxide (fumed silica) in order to stabilize the phase interface of the oil and polyol not mixed with each other, the thermal decomposition The present invention has been completed by discovering that oil gel type cosmetics of anhydrous formulations having improved stability may be prepared by increasing the amount through porous silicon oxide.

Accordingly, it is an object of the present invention to provide a method for stabilizing oils and polyols through the incremental effect of pyrolytic porous silicon oxide.

In addition, another object of the present invention is to provide a cosmetic composition that maintains the activity of the potency component for a long time by stabilizing the oil-soluble potency component or water labile potency component in the oil through pyrolytic porous silicon oxide. .

In order to achieve the above object, the present invention provides a method of stabilizing a cosmetic composition containing oil and polyol by adding and dispersing pyrolytic porous silicon oxide (fumed silica) in oil and then adding and dispersing polyol. .

In addition, in the cosmetic composition containing the oil and polyol, by adding pyrolytic porous silicon oxide (fumed silica) to homogeneously disperse the particles of the oil and polyol to provide a cosmetic composition stabilized oil and polyol.

The cosmetic composition of the present invention provides a unique appearance and feeling by using a method of stabilizing oil and polyol through the incremental effect of pyrolytic porous silicon oxide, and an oil gel type cosmetic composition of an anhydrous (non-water) formulation, thereby providing moisture retention and overall skin It can improve the condition and ultimately give new value to consumers. In addition, the present invention as a cosmetic that maintains the long-term stable activity of the active ingredient, such as moisturizing, wrinkles, whitening, antioxidant by stabilizing the oil-soluble efficacy component or water-labile efficacy component that is susceptible to oxidation in the oil through a pyrolytic porous silicon oxide It can be usefully used.

The present invention provides a method for stabilizing a cosmetic composition containing an oil and a polyol through the incremental effect of fumed silica (fumed silica) and a cosmetic composition using the same.

Hereinafter, the present invention will be described in more detail.

The oil used in the present invention is Sqalane, Pentaerythrityl Tetraisostearate, Butylene Glycol Dicaprylate.Dicaprate, Hydrogenated Polydecene Polydecene, Hydrogenated Polyisobutene, Ethylhexyl Palmitate, Dicaprylyl Carbonate, Octyldodecyl Myristate, Meadowfoam Seed Oil ), Macadamia Nut Oil, Jojoba Oil, Caprylic / Capric Acid Triglyceride, and Hydrogenated Isocetyl Olivate One or more may be selected, but is not limited thereto and for most cosmetics It is available both one-component applications.

The oil is contained in an amount of 1 to 50% by weight based on the total weight of the composition in the O / P (oil / polyol) formulation and 1 to 90% by weight in the total weight of the composition in the P / O (polyol / oil) formulation. If the content is less than the long-term stability of the formulation is a problem, if the content exceeds the content is too sticky or lustrous and sloppy feeling in the skin is not suitable as a cosmetic.

The polyol used in the present invention is one or more from the group consisting of glycerin (Glycerin), 1,3-butylene glycol (Butylene Glycol), propylene glycol (Propylene Glycol), polyethylene glycol and sorbitol (Sorbitol) Although not limited thereto, most cosmetic polyol components are applicable.

The polyol is contained 1 to 90% by weight relative to the total weight of the composition in the O / P (oil / polyol) formulation, 1 to 50% by weight relative to the total weight of the composition in the P / O (polyol / oil) formulation. If the content is less than the long-term stability of the formulation is a problem, if the content exceeds the content is too sticky or lustrous and sloppy feeling in the skin is not suitable as a cosmetic.

Fumed silica used in the present invention is a colloidal silicon dioxide produced through a flame hydrolysis process, which is highly-dispersed and amorphous. ) Synthetic silica of the powder type (pulverulent powder), and the manufacturing process and particle micrographs are shown in FIGS. 1 and 2. In the present invention, aerosil (AEROSIL) manufactured by Deggusa Co., Ltd. was used as the pyrolytic porous silicon oxide. Pyrolytic porous silicon oxide acts as a gel-former to thicken the oil to aid effective gelling and as a viscosity adjuster to increase the viscosity of oils, waxes and emulsions (Fig. 3). Therefore, it is used to increase the viscosity and improve the stability of the emulsion in the manufacture of cosmetics such as creams, lotions, makeup. It also helps to reduce the amount of surfactant by stabilizing the phase interface of different phases that do not mix with each other. It also acts as an effective dispersing agent that prevents agglomeration of powders into agglomerates and maintains the dispersion uniformly.It has a property of absorbing excess sebum due to its porosity. Prevents grease and reduces oiliness.

Pyrolytic porous silicon oxide (fumed silica) used in the present invention is characterized in that it is contained in a concentration of 0.01 to 30.0% by weight, preferably 0.1 to 10.0% by weight based on the total weight of the composition. It can not be expected to increase the oil at less than 0.01% by weight, it is difficult to realize the appearance, feeling and active ingredient stabilization effect, when it exceeds 30.0% by weight due to the excessive oil thickening effect of the oil in the cosmetic formulation is a stiff and sticky feeling This makes it unsuitable for application as a cosmetic.

In the cosmetic composition according to the present invention, the lipophilic or water labile physiologically active component and the potent component are characterized in that they can be trapped in oil stabilized by the pyrolytic porous silicon oxide.

In the cosmetic composition according to the present invention, the component is a component used in cosmetics, such as moisturizing enhancement, wrinkle improvement, anti-aging, whitening enhancement or antioxidant ingredients, it can be adjusted according to the purpose and use of each product It is done.

The skin cosmetic composition according to the present invention can be used in all kinds of cosmetics and is not particularly limited in the formulation. For example, supple cosmetics, astringent cosmetics, nourishing cosmetics, nourishing cream, massage cream, eye cream, eye essence, essence, cleansing cream, cleansing lotion, cleansing foam, cleansing water, pack, powder, body lotion, body cream, body essence , Body cleansers, hair dyes, shampoos, rinses, toothpastes, mouthwashes, hairdressing agents, wool, lotions, ointments, gels, creams, patches, transdermal or spray formulations.

Hereinafter, the present invention will be described in more detail with reference to Examples and Test Examples. However, the scope of the present invention is not limited to the following examples and test examples.

Reference Example 1 Preparation of Oil / Polyol Formulations

The cosmetics of Example 1 and Comparative Examples 1-4 were prepared according to the compositions shown in Table 1 below. The oil and the polyol used pentaerythritol tetraisostearate and glycerin, respectively, and Example 1 added 3% by weight of aerosil, pyrolytic porous silicon oxide, and Comparative Example 1 did not add pyrolytic porous silicon oxide. Comparative Examples 2 to 4 were prepared by adding 3% by weight of another powder instead of pyrolytic porous silicon oxide. The following units are in weight percent.

ingredient Comparative Example 1 Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 1.Pentaerythrityl tetraisostearate To 100 To 100 To 100 To 100 To 100 2. Fumed silica - 3.0 - - - 3. Silica - - 3.0 - - 4. talc - - - 3.0 - 5. Nylon powder - - - - 3.0 6. Glycerin 30 30 30 30 30

<Production method>

1) Add 2 ~ 5 powder to 1 oil part and disperse with homogenizer.

2) While slowly adding the polyol part of 6 to 1), disperse the particles evenly using a homogenizer and homogenizer.

Test Example 1 Formulation Stability According to Powder Type

The formulations of Example 1 and Comparative Examples 1-4 were observed at room temperature the day after the preparation are shown in Table 2 and FIG. 4.

ingredient Stability Example 1 Stable with uniform formulation Comparative Example 1 Separation into two layers of oil / polyol Comparative Example 2 Separation into two layers of oil / polyol Comparative Example 3 Separation into two layers of oil / polyol Comparative Example 4 Separation into two layers of oil / polyol

In the results of Table 2 and FIG. 4, in Comparative Example 1, the oil and polyol not mixed with each other are separated into two layers (the upper layer is an oil layer and the lower layer is a polyol layer due to density difference). In this case, it can be observed that aerosil, a pyrolytic porous silicon oxide, increases the oil to form a highly-dispersed oil gel formulation. In addition, in the case of Comparative Example 2-4 using ordinary silica, talc, and nylon powder instead of the porous powder, oil and polyol are separated into two layers, and the powder of the silica of Comparative Example 2 is in the middle of the polyol and oil layer due to the difference in density. It can be observed that the talc of Comparative Example 3 and the nylon powder of Comparative Example 4 sink in the oil layer. This acts as a powder surfactant that stabilizes the phase interface of oil and polyol, which does not mix with each other, and increases the stability of the cosmetic composition composed of oil and polyol. It has been shown to be effective in improving.

Reference Example 2 Preparation of Oil / Polyol Formulation According to Pyrolytic Porous Silicon Oxide Content

Checking the viscosity change and stability of the oil gel formulation according to the content of pyrolytic porous silicon oxide The cosmetics of Examples 2 and 3 were prepared according to the composition shown in Table 3 below, 1% by weight of aerosil, pyrolytic porous silicon oxide, respectively , 5% by weight was added. The manufacturing method is the same as that of Reference Example 1, and the following units are by weight.

ingredient Example 2 Example 3 1. Pentaerythritol tetraisostearate To 100 To 100 2. Pyrolytic porous silicon oxide (fumed silica) 1.0 5.0 3. Glycerin 30 30

Experimental Example 2 Viscosity Change According to Pyrolytic Porous Silicon Oxide Content

After preparing the formulation of Example 1-3 and stored in a 30 ℃ thermostat, the next day the viscosity was measured and the results are shown in Table 4 below. Viscosity is an internal resistance when a liquid flows and is measured based on the rotational force applied to the rotating spindle. Viscosity was measured using a Brookfield Viscometer and the unit is centipoise (cPs).

Formulation Viscosity (cPs) Example 2 3400 Example 1 9200 Example 3 30300

In Table 4, as the content of the pyrolytic porous silicon oxide increases, the viscosity of the oil gel formulation may be increased. It can be seen that the pyrolytic porous silicon oxide serves as a viscosity adjuster to increase the viscosity by absorbing oil.

Reference Example 3 Preparation of Cosmetic Composition Containing Efficacy Component

Formulation composition is shown in Table 5, and the preparation method was the same as in Reference Example 1 to prepare Examples 4, 5, 6. Additional raw materials, Retinol 10S (BASF Co., Retinol (10%) / Soybean Oil (90%)), Coenzyme Q10 and Tocopherol were added to the oil part just before the polyol part injection. The following units are in weight percent.

ingredient Example 4 Example 5 Example 6 1. Pentaerythritol tetraisostearate To 100 To 100 To 100 2. Pyrolysis Porous Silicon Oxide 3.0 3.0 3.0 3. Retinol 10S 1.0 4. Coenzyme Q10 - 1.0 - 5. Tocopherol - - 1.0 6. Glycerin 30 30 30

Test Example 3 Stabilization and Efficacy Test of Wrinkle Improvement Efficacy Components

Recently, as the customer's demand for the functionality of cosmetics increases, studies are being actively conducted to stably contain various functional ingredients in the formulation. For example, retinol, which is most widely known as an anti-wrinkle functional cosmetic ingredient, is known to exhibit high anti-wrinkle effect when applied as a cosmetic ingredient because of its excellent antioxidant effect. However, there is a problem that the oxidation reaction occurs easily due to light, oxygen, heat, etc., and the hydrolysis stability is extremely poor, and when it is applied to a formulation containing water, the activity is rapidly decreased.

Therefore, when the retinol is contained in the cosmetic composition of the anhydrous formulation according to the present invention, it was examined to what extent the active ingredient stabilization effect.

In Example 4 prepared according to the prescription of Table 5, the results of the stability analysis of the retinol under 45 ℃ temperature storage conditions are shown in Table 6 below.

Formulation Retinol Stability After One Month Example 4 94%

Through Table 6, it was confirmed that the stability of the retinol raw material is maintained at 94% after 30 days storage at 45 ℃. Through this, it was confirmed that there is a stabilizing effect of the active ingredient by trapping the soluble or water-stable physiologically active ingredient and potency ingredient in the oil stabilized by pyrolytic porous silicon oxide.

In addition, to confirm the wrinkle improvement effect according to Example 4, the following experiment was carried out. Fifty women in their 30s and 40s (mean 35.3 ± 2.9 years old) were used to apply Example 4 to their face once every evening for 12 weeks, and then scooped up replicas using silicone to measure wrinkles. visiometer; SV600, Courage + Khazaka electronic GmbH, Germany) for image analysis. The results are shown in FIG.

As shown in the results of FIG. 5, when the cosmetic composition of Example 4 was applied to the facial wrinkles, 12 weeks after use, it was confirmed that the skin wrinkles were improved enough to be easily distinguished by the naked eye.

[Test Example 4] Skin whitening improvement efficacy test

For example, Coenzyme Q10, which is widely known as a functional cosmetic ingredient for whitening improvement, is known to exhibit high whitening effect when applied as a cosmetic ingredient due to its excellent antioxidant effect. Coenzyme Q10, along with other enzymes in the body, participates in biochemical reactions that energize nutrients that enter cells. It also acts as a powerful antioxidant to prevent damage to cells from unstable harmful oxygen. However, there is a problem that the oxidation reaction occurs easily due to light, oxygen, heat, etc., and the hydrolysis stability is extremely poor, and when it is applied to a formulation containing water, the activity is rapidly decreased.

In addition, tocopherol is a fat-soluble vitamin that appears in foods in the form of four types of tocopherols (α-, β-, γ-, δ-) and four types of tocotrienols (α-, β-, γ-, δ-). The most common and high bioactivity is α-tocopherol, commonly referred to as vitamin E. Tocopherol's most important function in human body is antioxidant, which prevents cell membrane damage and even tissue damage by inhibiting oxidation of substances that are easily oxidized in cell, especially unsaturated fatty acids that make up cell membrane.

Therefore, when the cosmetic composition of the anhydrous formulation according to the present invention contains coenzyme Q10, tocopherol, it was examined how much whitening effect.

Human melanoma cells, HM3KO cells (Y. Funasaka, Department of dermatology, Kobe university school of medicine, 5-1 Kusunoki-cho 7-chrome, Chuo-ku, Kobe 650, Japan) Fetal calf serum was added to a minimum essential medium containing 10% (Minimum Essential Medium, MEM) was incubated under 37 ℃, 5% CO ₂ conditions. The cultured cells were spread over 75 flasks so that the number of cells was 3 × 10 ⁵ per flask, waited overnight for the cells to adhere to the base wall, and after confirming that the cells adhered well, the medium was tested in Examples 5 and 6. Changed to a new medium containing 10ppm. As a control, a medium containing DMSO was used. In this way, every two to three days, the cells were transferred to a new medium containing samples, and the cells were incubated until the flask was filled. After removing the culture solution, washed with PBS and dissolved with 1N sodium hydroxide to measure the absorbance at 500nm and calculated the melanin production inhibition rate according to the following equation 1 shown in Table 7 below.

Test substance Melanin production inhibition rate (%) Example 5 14.5 Example 6 12.1

To test the whitening effect on human skin, a small amount of erythema of each subject (Minimal Erythema Dose) was applied to 12 healthy males by attaching an opaque tape with 6 holes of 1.5 cm in diameter to the upper forearm of the subject. Irradiate 1.5 ~ 2 times of ultraviolet (UVB) of the skin to induce blackening of the skin, and apply the topical skin preparations of Examples 5 and 6 twice daily in the morning and evening, and then use the colorimeter after two months. The contrast of the skin was measured.

The determination of the effect was determined by obtaining a "L" value representing the darkness of the skin (unburned Korean skin color generally indicates a value of 50-70). If the test material is effective to apply the L value is gradually increased and the comparison between the test materials is calculated according to the following equation (2), it is shown in Table 8.

Whitening effect test on human skin Test substance Whitening Effect (? L) Example 5 2.82 Example 6 3.04

As can be seen from Tables 7 and 8, it can be seen that the results of human clinical experiments of Examples 5 and 6 are excellent in whitening effects. Through this, it was confirmed that there is a stabilizing effect of the active ingredient by trapping the soluble or water-stable physiologically active ingredient and potency ingredient in the oil stabilized by pyrolytic porous silicon oxide.

[Test Example 5] skin moisturizing effect experiment

In order to find out the moisturizing sustainability of the skin at one time of application, 50 adults, men and women in their 30s and 40s who are considered to be dry skin, or apply the cosmetic composition of Example 1 to the inside of the face and forearm, Skin moisture content was measured using a corneometer (CM820 courage Khazaka electronic GmbH, Germany) for 24 hours. Before the start of the application, the skin moisture content was measured in advance using a conniometer at constant temperature and humidity conditions (24 ° C., 40% humidity), and the change after 12 hours and 24 hours was measured. The results are shown in Table 9 below.

<Corneometer measurement method>

Principle: Moisture is measured by measuring the amount of moisture in the skin's epidermis using a sensor and numerically calculating the amount of moisture.

1) The Koniometer probe was placed on the skin area to be measured.

2) When the probe is pressed on the skin, the electrical conductivity of the skin is quantified through the sensor and displayed on the screen.

3) The measurement was repeated with different measurement sites.

4) After measuring once, the sensor was wiped with a tissue such as Kimwipe and then measured again.

Skin moisture content (%) sample Before application 12 hours later 24 hours later Example 1 25 52 49

Through the results of Table 9, when applying to the skin Example 1, an oil gel-type cosmetic containing oil / polyol stabilized by pyrolytic porous silicon oxide, the moisturizing power lasts more than 24 hours and the skin moisture content is increased The effect was also very good.

In addition, subjective efficacy evaluation was conducted through a questionnaire about the improvement effect on dry skin after using Example 1 in the test subjects at the end of the test. The questionnaire survey was to indicate the degree of satisfaction of the skin dryness improvement effect is classified as very good, good, normal and poor, the results are shown in Table 10 below.

Skin dryness improvement effect questionnaire sample Respondents Very good Good usually Inadequate Example 1 28 20 2 0

Through the results in Table 10, it can be seen that in the case of Example 1 which is an oil gel type cosmetic of the anhydrous formulation stabilized by the pyrolytic porous silicon oxide according to the present invention, the skin dryness improvement effect is excellent.

[Test Example 6] Overall skin improvement effect questionnaire

With Example 1, 50 general monitors of women in their 30s to 50s were tested for overall skin improvement effects. Each item of the test was given 0 to 7 points and the average score result is shown in FIG. 6.

In the results of FIG. 6, when applying to the skin Example 1, which is an oil gel type cosmetic containing oil / polyol stabilized by pyrolytic porous silicon oxide, strong moisturizing power and moisturizing sustainability by oil gel type oil and polyol And due to the unique feeling of skin moisturizing, elasticity enhancement, wrinkle reduction, skin texture improvement, skin shine and brightening, such as the overall skin moisturizing, wrinkles, whitening improvement effect was excellent.

In addition, with Example 1, 50 general monitors of women in their 30s and 50s were questioned whether they were suitable for their skin and their overall satisfaction. The questionnaire results are shown in FIG. 7.

In the results of FIG. 7, when applying Example 1 to the skin, 83% of the respondents said they were suitable for their skin, and 96% of the respondents showed high satisfaction with the cosmetic of Example 1.

FIG. 1 illustrates a process for preparing pyrolytic porous silicon oxide (fumed silica) through a flame hydrolysis process.

2 is a micrograph of pyrolytic porous silicon oxide particles.

3 is a schematic of an oil / polyol formulation captured by pyrolytic porous silicon oxide.

Figure 4 shows the results of observing the stability of the oil / polyol formulation according to the type of powder.

Figure 5 shows the effect of improving the wrinkles according to Example 4, the result of measuring the state of the wrinkles after applying for 12 weeks before the application of Example 4 with an aging degree measuring device.

6 is a graph of the score results for the overall skin improvement effect after using Example 1. FIG.

FIG. 7 is a graph illustrating the results of questionnaire regarding skin suitability and overall satisfaction of Example 1, and FIG. 7A is a graph showing skin suitability and FIG. 7B is overall satisfaction.

Claims (14)

A method of stabilizing a cosmetic composition containing an oil and a polyol by adding and dispersing pyrolytic porous silica oxide to an oil and then adding and dispersing a polyol. A cosmetic composition comprising an oil and a polyol, wherein the cosmetic composition is stabilized in oil and polyol by adding pyrolytic porous silica oxide to the cosmetic composition to homogeneously disperse particles of oil and polyol. The cosmetic composition according to claim 2, wherein the content of the fumed silica is 0.01 to 30.0 wt% based on the total weight of the composition. The oil content according to claim 2, wherein the oil content is 1.0 to 50.0% by weight relative to the total weight of the composition in the O / P (oil / polyol) formulation, and 1.0 to the total weight of the composition in the P / O (polyol / oil) formulation. Cosmetic composition, characterized in that ~ 90.0% by weight. The method according to claim 2, wherein the polyol content is 1.0 to 90.0% by weight relative to the total weight of the composition in the O / P (oil / polyol) formulation, and 1.0 to the total weight of the composition in the P / O (polyol / oil) formulation. Cosmetic composition, characterized in that ~ 50.0% by weight. The cosmetic composition according to claim 2, wherein the oil-soluble bioactive component is trapped in the oil. According to claim 2, wherein the cosmetic composition is a cosmetic composition, characterized in that for promoting skin moisturizing. The cosmetic composition according to claim 2, wherein the cosmetic composition is for improving skin wrinkles. According to claim 2, wherein the cosmetic composition is a cosmetic composition, characterized in that for preventing skin aging. According to claim 2, wherein the cosmetic composition is a cosmetic composition, characterized in that for enhancing skin whitening. The cosmetic composition according to claim 2, wherein the cosmetic composition is for skin antioxidant. The cosmetic composition of claim 2, wherein the cosmetic composition is an oil-in-poly-ol (O / P) emulsion of an anhydrous formulation. The cosmetic composition according to claim 2, wherein the cosmetic composition is a polyol-in-oil (P / O) emulsion of anhydrous formulation. According to claim 2, wherein the composition is softening cream, astringent makeup, nutrition cream, nutrition cream, massage cream, eye cream, eye essence, essence, cleansing cream, cleansing lotion, cleansing foam, cleansing water, pack, powder, body lotion Cosmetic composition characterized in that the formulation of body cream, body essence, body cleaner, hair dye, shampoo, rinse, toothpaste, mouthwash, hair dressing, wool, lotion, ointment, gel, cream, patch or spray.

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