KR20070048251A - 최적화된 액상 산화 방법 - Google Patents

최적화된 액상 산화 방법 Download PDF

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Publication number
KR20070048251A
KR20070048251A KR1020077006483A KR20077006483A KR20070048251A KR 20070048251 A KR20070048251 A KR 20070048251A KR 1020077006483 A KR1020077006483 A KR 1020077006483A KR 20077006483 A KR20077006483 A KR 20077006483A KR 20070048251 A KR20070048251 A KR 20070048251A
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KR
South Korea
Prior art keywords
reaction medium
reaction zone
reaction
zone
oxidant
Prior art date
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KR1020077006483A
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English (en)
Korean (ko)
Inventor
알란 조지 원더스
하워드 우드 주니어 젠킨스
리 레이놀즈 파틴
웨인 스코트 스트라세르
브리데 마르셀 데
푸니트 굽타
Original Assignee
이스트만 케미칼 컴파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Priority claimed from US11/154,116 external-priority patent/US7507857B2/en
Priority claimed from US11/153,993 external-priority patent/US7589231B2/en
Priority claimed from US11/154,253 external-priority patent/US7692037B2/en
Application filed by 이스트만 케미칼 컴파니 filed Critical 이스트만 케미칼 컴파니
Publication of KR20070048251A publication Critical patent/KR20070048251A/ko
Withdrawn legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/1862Stationary reactors having moving elements inside placed in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J10/00Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
    • B01J10/002Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor carried out in foam, aerosol or bubbles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42Separation; Purification; Stabilisation; Use of additives
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/14Monocyclic dicarboxylic acids
    • C07C63/15Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
    • C07C63/261,4 - Benzenedicarboxylic acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00004Scale aspects
    • B01J2219/00006Large-scale industrial plants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00121Controlling the temperature by direct heating or cooling
    • B01J2219/00123Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00121Controlling the temperature by direct heating or cooling
    • B01J2219/00128Controlling the temperature by direct heating or cooling by evaporation of reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00182Controlling or regulating processes controlling the level of reactants in the reactor vessel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00245Avoiding undesirable reactions or side-effects
    • B01J2219/0025Foam formation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761Details of the reactor
    • B01J2219/00763Baffles
    • B01J2219/00765Baffles attached to the reactor wall
    • B01J2219/00768Baffles attached to the reactor wall vertical
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761Details of the reactor
    • B01J2219/00763Baffles
    • B01J2219/00765Baffles attached to the reactor wall
    • B01J2219/0077Baffles attached to the reactor wall inclined
    • B01J2219/00774Baffles attached to the reactor wall inclined in the form of cones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761Details of the reactor
    • B01J2219/00763Baffles
    • B01J2219/00765Baffles attached to the reactor wall
    • B01J2219/00777Baffles attached to the reactor wall horizontal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18Details relating to the spatial orientation of the reactor
    • B01J2219/185Details relating to the spatial orientation of the reactor vertical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020077006483A 2004-09-02 2005-08-29 최적화된 액상 산화 방법 Withdrawn KR20070048251A (ko)

Applications Claiming Priority (18)

Application Number Priority Date Filing Date Title
US60661804P 2004-09-02 2004-09-02
US60680904P 2004-09-02 2004-09-02
US60661404P 2004-09-02 2004-09-02
US60/606,614 2004-09-02
US60/606,618 2004-09-02
US60/606,809 2004-09-02
US63132604P 2004-11-29 2004-11-29
US63138804P 2004-11-29 2004-11-29
US63149004P 2004-11-29 2004-11-29
US60/631,388 2004-11-29
US60/631,326 2004-11-29
US60/631,490 2004-11-29
US11/154,116 US7507857B2 (en) 2004-09-02 2005-06-16 Optimized liquid-phase oxidation
US11/154,116 2005-06-16
US11/154,253 2005-06-16
US11/153,993 US7589231B2 (en) 2004-09-02 2005-06-16 Optimized liquid-phase oxidation
US11/153,993 2005-06-16
US11/154,253 US7692037B2 (en) 2004-09-02 2005-06-16 Optimized liquid-phase oxidation

Publications (1)

Publication Number Publication Date
KR20070048251A true KR20070048251A (ko) 2007-05-08

Family

ID=35504394

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020077006483A Withdrawn KR20070048251A (ko) 2004-09-02 2005-08-29 최적화된 액상 산화 방법

Country Status (8)

Country Link
EP (1) EP1786746A2 (enExample)
JP (1) JP2008511645A (enExample)
KR (1) KR20070048251A (enExample)
CN (2) CN101010267B (enExample)
BR (1) BRPI0514773A (enExample)
CA (1) CA2576246A1 (enExample)
MX (1) MX2007002283A (enExample)
WO (1) WO2006028766A2 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7910769B2 (en) * 2004-09-02 2011-03-22 Eastman Chemical Company Optimized liquid-phase oxidation
US8790601B2 (en) * 2010-01-29 2014-07-29 Grupo Petrotemex, S.A. De C.V. Oxidation system with sidedraw secondary reactor
US8936767B2 (en) * 2010-01-29 2015-01-20 Grupo Petrotemex. S.A. de C.V. Oxidation system with sidedraw secondary reactor

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL282031A (enExample) * 1961-08-14
IT1129759B (it) * 1980-01-23 1986-06-11 Montedison Spa Metodo per ricuperare in forma attiva i componenti del sistema catalitico della sintesi dell'acido tereftalico
JPH07278048A (ja) * 1994-04-01 1995-10-24 Mitsui Petrochem Ind Ltd 芳香族カルボン酸の製造方法および装置
ID19133A (id) * 1996-12-12 1998-06-18 Praxair Technology Inc Pengisian oksigen langsung kedalam reaktor-reaktor ruang gelembung
DE19843573A1 (de) * 1998-09-23 2000-03-30 Degussa Blasensäule und deren Verwendung
US6949673B2 (en) * 2000-01-12 2005-09-27 E.I. Du Pont De Nemours And Company Process for producing carboxylic acids
MXPA03006122A (es) * 2001-01-10 2004-05-14 Du Pont Proceso mejorado para producir acidos carboxilicos.
US7196215B2 (en) * 2001-06-04 2007-03-27 Eastman Chemical Company Process for the production of purified terephthalic acid
PL208869B1 (pl) * 2002-12-09 2011-06-30 Eastman Chem Co Sposób wytwarzania produktu oczyszczonego kwasu karboksylowego

Also Published As

Publication number Publication date
MX2007002283A (es) 2007-04-23
JP2008511645A (ja) 2008-04-17
EP1786746A2 (en) 2007-05-23
CN101010267B (zh) 2013-05-29
CA2576246A1 (en) 2006-03-16
WO2006028766A2 (en) 2006-03-16
WO2006028766A3 (en) 2006-07-20
WO2006028766A8 (en) 2006-06-08
BRPI0514773A (pt) 2008-06-24
CN101010267A (zh) 2007-08-01
CN101768034A (zh) 2010-07-07

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PA0105 International application

Patent event date: 20070321

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
PC1203 Withdrawal of no request for examination
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid