CN101010267B - 优化的液相氧化 - Google Patents

优化的液相氧化 Download PDF

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Publication number
CN101010267B
CN101010267B CN2005800295420A CN200580029542A CN101010267B CN 101010267 B CN101010267 B CN 101010267B CN 2005800295420 A CN2005800295420 A CN 2005800295420A CN 200580029542 A CN200580029542 A CN 200580029542A CN 101010267 B CN101010267 B CN 101010267B
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CN
China
Prior art keywords
reaction medium
reaction zone
reactor
reaction
zone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2005800295420A
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English (en)
Chinese (zh)
Other versions
CN101010267A (zh
Inventor
A·G·万德斯
H·W·小詹金斯
L·R·帕丁
W·S·施特拉泽
M·德弗里德
P·古普塔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Grupo Petrotemex SA de CV
Original Assignee
Grupo Petrotemex SA de CV
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/154,116 external-priority patent/US7507857B2/en
Priority claimed from US11/153,993 external-priority patent/US7589231B2/en
Priority claimed from US11/154,253 external-priority patent/US7692037B2/en
Application filed by Grupo Petrotemex SA de CV, Eastman Chemical Co filed Critical Grupo Petrotemex SA de CV
Publication of CN101010267A publication Critical patent/CN101010267A/zh
Application granted granted Critical
Publication of CN101010267B publication Critical patent/CN101010267B/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1862—Stationary reactors having moving elements inside placed in series
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
    • B01J10/002—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor carried out in foam, aerosol or bubbles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/14—Monocyclic dicarboxylic acids
    • C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
    • C07C63/26—1,4 - Benzenedicarboxylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00121—Controlling the temperature by direct heating or cooling
    • B01J2219/00123—Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00121—Controlling the temperature by direct heating or cooling
    • B01J2219/00128—Controlling the temperature by direct heating or cooling by evaporation of reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00182—Controlling or regulating processes controlling the level of reactants in the reactor vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/0025—Foam formation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/00768—Baffles attached to the reactor wall vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/0077—Baffles attached to the reactor wall inclined
    • B01J2219/00774—Baffles attached to the reactor wall inclined in the form of cones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/00777—Baffles attached to the reactor wall horizontal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/185—Details relating to the spatial orientation of the reactor vertical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2005800295420A 2004-09-02 2005-08-29 优化的液相氧化 Expired - Fee Related CN101010267B (zh)

Applications Claiming Priority (19)

Application Number Priority Date Filing Date Title
US60661804P 2004-09-02 2004-09-02
US60680904P 2004-09-02 2004-09-02
US60661404P 2004-09-02 2004-09-02
US60/606,614 2004-09-02
US60/606,618 2004-09-02
US60/606,809 2004-09-02
US63132604P 2004-11-29 2004-11-29
US63138804P 2004-11-29 2004-11-29
US63149004P 2004-11-29 2004-11-29
US60/631,388 2004-11-29
US60/631,326 2004-11-29
US60/631,490 2004-11-29
US11/154,116 US7507857B2 (en) 2004-09-02 2005-06-16 Optimized liquid-phase oxidation
US11/154,116 2005-06-16
US11/154,253 2005-06-16
US11/153,993 US7589231B2 (en) 2004-09-02 2005-06-16 Optimized liquid-phase oxidation
US11/153,993 2005-06-16
US11/154,253 US7692037B2 (en) 2004-09-02 2005-06-16 Optimized liquid-phase oxidation
PCT/US2005/030649 WO2006028766A2 (en) 2004-09-02 2005-08-29 Optimized liquid-phase oxidation

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201010113905A Division CN101768034A (zh) 2004-09-02 2005-08-29 优化的液相氧化

Publications (2)

Publication Number Publication Date
CN101010267A CN101010267A (zh) 2007-08-01
CN101010267B true CN101010267B (zh) 2013-05-29

Family

ID=35504394

Family Applications (2)

Application Number Title Priority Date Filing Date
CN2005800295420A Expired - Fee Related CN101010267B (zh) 2004-09-02 2005-08-29 优化的液相氧化
CN201010113905A Pending CN101768034A (zh) 2004-09-02 2005-08-29 优化的液相氧化

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201010113905A Pending CN101768034A (zh) 2004-09-02 2005-08-29 优化的液相氧化

Country Status (8)

Country Link
EP (1) EP1786746A2 (enExample)
JP (1) JP2008511645A (enExample)
KR (1) KR20070048251A (enExample)
CN (2) CN101010267B (enExample)
BR (1) BRPI0514773A (enExample)
CA (1) CA2576246A1 (enExample)
MX (1) MX2007002283A (enExample)
WO (1) WO2006028766A2 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7910769B2 (en) * 2004-09-02 2011-03-22 Eastman Chemical Company Optimized liquid-phase oxidation
US8790601B2 (en) * 2010-01-29 2014-07-29 Grupo Petrotemex, S.A. De C.V. Oxidation system with sidedraw secondary reactor
US8936767B2 (en) * 2010-01-29 2015-01-20 Grupo Petrotemex. S.A. de C.V. Oxidation system with sidedraw secondary reactor

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3240803A (en) * 1961-08-14 1966-03-15 Eastman Kodak Co Preparation of benzenecarboxylic acid
WO2004052820A1 (en) * 2002-12-09 2004-06-24 Eastman Chemical Company Process for the purification of a crude carboxylic acid slurry

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1129759B (it) * 1980-01-23 1986-06-11 Montedison Spa Metodo per ricuperare in forma attiva i componenti del sistema catalitico della sintesi dell'acido tereftalico
JPH07278048A (ja) * 1994-04-01 1995-10-24 Mitsui Petrochem Ind Ltd 芳香族カルボン酸の製造方法および装置
ID19133A (id) * 1996-12-12 1998-06-18 Praxair Technology Inc Pengisian oksigen langsung kedalam reaktor-reaktor ruang gelembung
DE19843573A1 (de) * 1998-09-23 2000-03-30 Degussa Blasensäule und deren Verwendung
US6949673B2 (en) * 2000-01-12 2005-09-27 E.I. Du Pont De Nemours And Company Process for producing carboxylic acids
MXPA03006122A (es) * 2001-01-10 2004-05-14 Du Pont Proceso mejorado para producir acidos carboxilicos.
US7196215B2 (en) * 2001-06-04 2007-03-27 Eastman Chemical Company Process for the production of purified terephthalic acid

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3240803A (en) * 1961-08-14 1966-03-15 Eastman Kodak Co Preparation of benzenecarboxylic acid
WO2004052820A1 (en) * 2002-12-09 2004-06-24 Eastman Chemical Company Process for the purification of a crude carboxylic acid slurry

Also Published As

Publication number Publication date
MX2007002283A (es) 2007-04-23
JP2008511645A (ja) 2008-04-17
EP1786746A2 (en) 2007-05-23
CA2576246A1 (en) 2006-03-16
WO2006028766A2 (en) 2006-03-16
WO2006028766A3 (en) 2006-07-20
WO2006028766A8 (en) 2006-06-08
BRPI0514773A (pt) 2008-06-24
CN101010267A (zh) 2007-08-01
KR20070048251A (ko) 2007-05-08
CN101768034A (zh) 2010-07-07

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Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
ASS Succession or assignment of patent right

Owner name: PEMEX GROUP LLC

Free format text: FORMER OWNER: EASTMAN CHEM CO.

Effective date: 20110906

C41 Transfer of patent application or patent right or utility model
TA01 Transfer of patent application right

Effective date of registration: 20110906

Address after: Nuevo Leon, Mexico

Applicant after: Grupo Petrotemex Sa De Cv

Address before: Tennessee

Applicant before: Eastman Chem Co.

EE01 Entry into force of recordation of patent licensing contract

Assignee: Jiaxing Petrochemical Co., Ltd.

Assignor: Eastman Chemical Company

Contract record no.: 2012990000015

Denomination of invention: Optimized liquid-phase oxidation

License type: Common License

Open date: 20070801

Record date: 20120113

C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130529

Termination date: 20140829

EXPY Termination of patent right or utility model