KR20060026735A - Non-aqueous liquid bleach compositions containing peroxygen compound - Google Patents

Abstract

The present invention relates to a non-aqueous oxygen-based liquid bleach composition, and more particularly, a solid peroxide is a liquid phase composed by controlling the content of a nonpolar organic solvent, a nonionic and anionic surfactant, which has little water content. It is dispersed in the form of a high viscosity paste or gel in suspension form, and there is no loss of effective oxygen, pH is alkali range, so it is excellent in bleaching and washing power, there is no change in viscosity or phase separation during storage. The present invention relates to a new concept of a non-aqueous oxygen-based liquid bleach composition, which is chemically and physically stable and can be used for bleaching and stain removal of clothes and for cleaning the kitchen and bathroom.

Oxygen, Bleach, Multi-Purpose, Suspension

Description

Non-Aqueous Liquid Bleach Compositions Containing Peroxygen Compound

The present invention relates to a non-aqueous oxygen-based liquid bleach composition, and more particularly, a solid peroxide is a liquid phase composed by controlling the content of a nonpolar organic solvent, a nonionic and anionic surfactant, which has little water content. It is dispersed in the form of a high viscosity paste or gel in suspension form, and there is no loss of effective oxygen, pH is alkali range, so it is excellent in bleaching and washing power, there is no change in viscosity or phase separation during storage. The present invention relates to a new concept of a non-aqueous oxygen-based liquid bleach composition, which is chemically and physically stable and can be used for bleaching and stain removal of clothes and for cleaning the kitchen and bathroom.

Bleach is divided into chlorine bleach and oxygen bleach.

First, as a chlorine bleach, British Patent No. 2,229,460 discloses a bleach which contains sodium hypochlorite as a main component, but such a chlorine bleach has a strong bleaching power but discolors color clothing or destroys fiber structure when bleaching clothes. there is a problem. In addition, there is a disadvantage that generates an unpleasant smell due to the generation of chlorine harmful to the human body when using.

On the other hand, the oxygen-based bleaching agent does not have the above-mentioned disadvantages that the chlorine-based bleaching agent has, and its usage has recently increased. These oxygen-based bleaches are largely divided into liquid bleaches and powder bleaches depending on the form.

Most of the oxygen-based bleaches currently on the market are powder bleaches using sodium percarbonate or sodium perborate, and they have a disadvantage in that they are hardly soluble in water at room temperature, especially cold water. Furthermore, when the powder bleach is prepared, it is difficult to uniformly mix the solid components, and when the powder bleach is used, there is an inconvenience in that dust is generated, and in particular, there is a disadvantage in that partial bleaching of the stain is difficult.

Recently, however, liquid bleaches are more convenient to use than powder bleach products and thus tend to be favored by consumers. Liquid bleaches have the advantages of being easier to weigh than powder bleaches, dissolving quickly in water, no dust, and no caking that commonly occurs in powder bleaches during storage.

U.S. Pat.Nos. 6,235,699, 5,929,012, 4,900,468 and the like disclose liquid bleaches using hydrogen peroxide as a bleach. The liquid bleach using hydrogen peroxide expands the storage container due to decomposition of hydrogen peroxide during storage, or bleaching power. There is a problem such as being reduced. In addition, in order to stabilize the hydrogen peroxide, the pH of the bleach solution must be kept acidic, but under such low pH, the bleaching power and the washing power are significantly reduced.

U.S. Patent Nos. 3,499,844, 4,130,501 and the like disclose a method of increasing the viscosity of a composition in order to increase the chemical stability of the liquid bleach. However, the above method is also pointed out that the pH of the bleaching agent is markedly lowered in the bleaching power and washing power, and the viscosity of the composition changes due to the decomposition of hydrogen peroxide during storage has a problem that is difficult to commercialize.

Accordingly, the inventors of the present invention have been researched to solve the above problems, including a specific organic solvent having a very low water content and non-polar and well soluble in water and a surfactant defining a type and content A liquid bleach composition obtained in the form of a paste or a gel obtained by dispersing a solid peroxide having a particle size range in a liquid range to produce hydrogen peroxide in a liquid phase, which has a low loss of available oxygen during storage, and the like. The present invention has been found to have high chemical stability, high physical stability such as no phase separation between liquid and solid components in the composition, no change in viscosity, and the like.

Therefore, the present invention provides a new type of non-aqueous oxygen-based liquid bleach composition which is free from dust when used as a liquid, and has excellent washing power as alkaline, which can be used for various purposes such as bleaching and stain removal of clothing, and cleaning kitchens and bathrooms. The purpose is.

The present invention is 0.1 to 85% by weight of solid peroxide, 10 to 80% by weight of non-aqueous organic solvent, 0.1 to 10% by weight of anionic surfactant, 0.1 to 10% by weight of nonionic surfactant, 0.1 to 85% by weight of filler, stabilizer It comprises 0.01 to 10% by weight, has a viscosity of 500 to 1,000,000 cps (25 ℃), a non-aqueous oxygen-based liquid bleaching agent in which the solid peroxide is dispersed in a liquid component to form a suspension (suspension) Characterized by a composition.

According to the present invention, a solid peroxide is dispersed in a liquid phase formed by controlling the content of a nonpolar organic solvent having little water content, a nonionic and anionic surfactant, thereby forming a suspension phase in the form of a paste or gel having a high viscosity. There is no loss of effective oxygen, pH ranges from alkali to excellent bleaching and washing power, and chemical and physical stability such as no change in viscosity or phase separation during storage. It relates to a new concept of a non-aqueous oxygen-based liquid bleach composition that can be used for multi-purpose.

This invention will be described in detail for each component of the composition.

The non-aqueous oxygen-based liquid bleach composition of the present invention comprises a solid peroxygen compound, a non-aqueous organic solvent, an anionic surfactant, a nonionic surfactant, a filler and a stabilizer, and additionally a thickening agent, Fluorescent whitening agent, enzyme, flavor and the like.

The solid peroxide used in the present invention is a material capable of forming hydrogen peroxide, percarbonate, perborate, persulfate, urea peroxide and metal peroxide (ZnO _2). , MnO ₂ , CaO ₂ ) and the like, and preferably, percarbonate is used. The percarbonate is a compound consisting of a combination of sodium carbonate and hydrogen peroxide and is an environmentally friendly compound having high effective oxygen content and high solubility in water. It is preferable to use such a peroxide having an average particle size in the range of 1 to 700 μm. If the average particle size is large, the peroxide content may be increased. However, if the average particle size is too large, solubility in water may be inferior. The amount of the solid peroxide used is 0.1 to 85% by weight, preferably 1 to 75% by weight. If the amount is less than 0.1% by weight, the effect as a bleaching agent is not effective, and when it exceeds 85% by weight, the physical stability is lowered.

Since the non-aqueous organic solvent has a great influence on the chemical and physical stability of the whole composition, particular attention should be paid to its selection, and the selective use of such a non-aqueous organic solvent is one of the technical features of the present invention.

As a non-aqueous organic solvent, an organic solvent (water-miscible solvent) mixed well with water is used. The peroxide (particularly in the case of percarbonate), when dissolved in water, adversely affects the chemical stability of the composition. Therefore, in the present invention, there should be almost no moisture (less than 0.5 wt%) as the non-aqueous organic solvent, and the organic solvent may be selected to be less absorbed in the air.

In addition, the non-aqueous organic solvent to be used in the present invention is selected to use a low polarity. That is, a solvent having a high polarity tends to dissolve peroxides such as percarbonate, so it is not recommended to use a solvent having a high polarity such as ethanol or propanol. In addition, the non-aqueous organic solvent to be used in the present invention should be free of chemical reactions with other components used together.

As the non-aqueous organic solvent that satisfies the above conditions, an organic solvent that can be used in the present invention is specifically, for example, among polyalkylene glycol, polyhydric alcohol, alkylene glycol monoalkyl ether, alkyl ester, alkylamide, and the like. One or more mixtures selected may be used.

It is preferable to use an organic solvent having a low polarity of low molecular weight. Among the polyalkylene glycols, polyethylene glycol having a molecular weight in the range of 200 to 600 may be used. Among the polyhydric alcohols, glycerol may be used, and methyl ester, methyl amide, methyl acetate, or the like may be used. The alkylene glycol monoalkyl ether may be all mono-, di-, tri- and tetra alkylene glycol monoalkyl ether, the alkylene is C ₂ ~ C ₃ , alkyl is C ₂ ~ C ₆ It is good to use that. At this time, the amount of the non-aqueous organic solvent is 10 to 80% by weight, preferably 20 to 60% by weight, but when the amount is less than 10% by weight or exceeds 80% by weight, the physical stability is lowered.

The non-aqueous oxygen-based liquid bleach composition of the present invention uses an anionic surfactant and a nonionic surfactant as a surfactant.

The anionic surfactant is a linear alkylbenzene sulfonate represented by the following formula (1), a fatty acid salt represented by the following formula (2), a linear alkyl sulfonate represented by the following formula (3) and an alpha olefin sulfonate represented by the following formula (4) One or more mixtures selected from the like and the like are used.

R ¹ -C ₆ H ₄ -SO ₃ X

R ² -CH ₂ -COOX

R ³ -CH ₂ -SO ₃ X

R ³ -CH = CHCH ₂ -SO ₃ X

In Formulas 1 to 4, R ¹ is a C ₉ to C ₁₅ alkyl group, R ² is a C ₁₁ to C ₁₆ alkyl group, R ³ is a C ₁₁ to C ₁₈ alkyl group, and X is an alkali metal.

 The anionic surfactant is used in an amount of 0.1 to 10% by weight, preferably 0.5 to 5% by weight, but when the amount is less than 0.1% by weight, the washing power is lowered, and when it exceeds 10% by weight, the physical stability is lowered.

The nonionic surfactant is one selected from fatty acid alcohol polyoxyethylene glycol represented by the following formula (5), fatty acid polyoxyethylene glycol represented by the following formula (6), alkylphenyl polyoxyethylene glycol represented by the following formula (7), or the like The above mixture can be used.

R ⁴ -CH _2- (OCH ₂ CH ₂ ) _n -OH

R ⁴ -CO- (OCH ₂ CH ₂ ) _n -OH

R ⁴ -C ₆ H _4- (OCH ₂ CH ₂ ) _n -OH

In Chemical Formulas 5 to 7, n is an integer of 5 to 25, R ⁴ is an alkyl group of C ₁₁ ~ C ₁₈ .

The nonionic surfactant is used in an amount of 0.1 to 10% by weight, preferably 0.5 to 5% by weight, but when the amount is less than 0.1% by weight, the washing power is lowered, and when used in excess of 10% by weight, the physical stability is lowered.

In the present invention, the amount and ratio of the anionic surfactant and the nonionic surfactant described above greatly affect the chemical and physical stability of the composition. Therefore, the selective use of the kind of the surfactant and the limitation of the use ratio are one of the features of the technical construction of the present invention.

That is, in the non-aqueous oxygen-based liquid bleach composition of the present invention, the anionic surfactant and the nonionic surfactant are used in a weight ratio of 3: 1 to 1: 3, and when the use ratio is out of the range, physical stability may be lowered. . The amount of the surfactant used is 0.2 to 20% by weight, preferably 1 to 10% by weight.

The non-aqueous oxygen-based liquid bleach composition of the present invention uses a filler that can simultaneously perform the role of a builder and a desiccant. Specifically, the filler is selected from one or more mixtures of sodium carbonate (Na ₂ CO ₃ ), sodium bicarbonate (NaHCO ₃ ), sodium sulfate (Na ₂ SO ₄ ) and the like. At this time, the amount of the filler to be used is 0.1 to 85% by weight, preferably 0.5 to 70% by weight. If the amount is less than 0.1% by weight, the chemical stability is lowered, and when it exceeds 85% by weight, the physical stability is lowered.

The stabilizer (ion blocking agent) may be used by selecting one or more of organic acids, salts of organic acids, amino polyphosphonate compounds and the like. Specifically, the organic acid may be one selected from citric acid, dipicolinic acid, gluconic acid, and the like. Specific examples of the amino polyphosphonate-based compound include hydroxy ethylene diphosphonic acid, ethylene diamine tetra (methylene phosphonic acid), diethylene triamine penta (methylene phosphonic acid), aminotri (methylene phosphonic acid), and the like. You can use the selected one. In particular, stabilizers used should not contain water. Such stabilizer is used in an amount of 0.01 to 10% by weight, preferably 0.1 to 5% by weight. At this time, if the amount of use is less than 0.01% by weight, the chemical stability is lowered, and if it exceeds 5% by weight, the synergistic effect of the chemical stability is lost. Commercially available stabilizers include Solutia's Dequest ™ series.

In the present invention, it is possible to prepare a suspension having excellent physical stability without using a thickener, but if necessary, a more preferable effect can be obtained. The thickener is a fatty acid, a crosslinked acrylic acid copolymer, colloidal silica, carboxymethylcellulose, polyvinyl alcohol, polyvinylpyrrolidone ( One or more mixtures selected from polyvinyl pyrrolidone) and sodium polyacrylate may be used.

The fatty acid may be a mixture of two or more selected from saturated or unsaturated fatty acids having 10 to 18 carbon atoms, preferably capric acid, lauric acid, and myristic acid. And a mixture of two or more of palmitic acid. The amount of such fatty acids used is 0.01 to 5% by weight, preferably 0.1 to 1.5% by weight.

As the crosslinked acrylic copolymer, an acrylic acid copolymer crosslinked with 0.75 to 1.5% polyallyl sucrose may be used. The amount of the crosslinked acrylic copolymer is 0.01 to 1.5% by weight, preferably 0.2 to 1% by weight.

The colloidal silica may be a hydrophilic fumed silica having a surface area of 200 m 2 / g, an average particle size in the range of 10 to 12 nm, or a hydrophobic fumed silica having a surface area of 100 m 2 / g and an average particle size in the range of 10 to 20 nm. The amount of colloidal silica used is 0.01 to 5% by weight, preferably 1 to 3% by weight. Commercially available thickeners include B and F. Goodrich's Carbopol 934, 937, Degussa's Aerosil 200, and Cabot's Cabosil fumed silica.

Raw materials and metal materials introduced during manufacture (for example, iron, manganese, copper, chromium, etc.) promote the decomposition of peroxides, thereby lowering the chemical stability of the final composition, and should be excluded if possible. It may include components conventionally used in the art. That is, various other optional components such as antioxidants, colorants, optical brighteners, anti-fouling agents, cleaning enzymes, and flavoring agents may be included, and their amount is 0.01 to 2% by weight.

As described above, the non-aqueous oxygen-based liquid bleach composition of the present invention is a non-aqueous suspension in the form of a paste or a gel, and a peroxide generating hydrogen peroxide, an organic solvent mixed with water, a water-miscible solvent and a surfactant. , Viscosity of 500 ~ 1,000,000 cps (shear rate 21 /) including fillers, stabilizers (ion blockers), thickening agents, and other small amounts of additives, including optical brighteners, enzymes and flavors. sec. at 25 ° C.), water content is 1.0% by weight or less, preferably 0.5% by weight or less, physically and chemically stable for a long storage time, is easy to use, general washing (must be used with detergent) and It is a multi-purpose bleach composition that can be used for sterilization and cleaning of kitchens, bathrooms, and vents, as well as washing clothes and removing heavy stains without damaging clothes.

Hereinafter, the present invention will be described in detail with reference to Examples, but the present invention is not limited by the following Examples.

Examples 1-7 and Comparative Examples 1-3

In a 1L glass reactor equipped with a three-blade propeller agitator and a jacket, the organic solvent and nonionic surfactant were first added, followed by agitation at 600 rpm or higher to increase thickeners, anionic surfactants, stabilizers, and fluorescence. The bleach was added and dissolved for about 1 hour. Note that the stabilizer may not dissolve.

The filler was added to the mixed solution above, and stirred for about 10 minutes, and finally, peroxide and enzyme in powder form were slowly added to the mixed solution. After completely adding the peroxide and the enzyme, the mixture is stirred for about 30 minutes to 1 hour, and if the stirring is difficult due to the formation of bubbles during the stirring, the mixture is stirred while removing bubbles with a vacuum. Using to lower the temperature inside the reactor. If necessary, the flavor may be added after this step.

The composition components and the amount used in Examples 1 to 7 and Comparative Examples 1 to 3 are shown in Table 1 below.

Experimental Example 1 Measurement of Chemical and Physical Stability

Loss of available oxygen by titration method using potassium permanganate (KMnO ₄ ) after storing the bleach composition prepared according to Examples 1 to 7 and Comparative Examples 1 to 3 for 1 month. The chemical stability was measured and the results are shown in the following Table 1. When the loss of the effective oxygen was 10% or less (stable 90% or more), it was determined to be stable.

The bleach composition prepared according to Examples 1 to 7 and Comparative Examples 1 to 3 was placed in a graduated 100 ml cylinder and stored at room temperature for 1 month, and then the degree of phase separation was measured. In addition, the degree of phase separation after storage for one month under freeze-thaw cycles (-4 ° C./40° C.) was measured. The results are shown in Table 1 below. Physically stable means that no phase separation occurs.

Experimental Example 2 Bleaching Force Test

To a Terg-O-tometer, water (water temperature 20 ° C., hardness 50 CaCO ₃ ppm) and the bleach composition of the present invention prepared according to Examples 1 and 4 and 1 g / L of a commercially available powder bleach are added, respectively. Using 10 standard contaminants such as red wine (EMPA 114), coffee (wfk BC-2), red pepper (wfk 10P), and tea (wfk BC-3), 10 contaminants (5 cm x 5 cm) are added. After washing for 3 minutes, rinsing with tap water for 3 minutes and allowed to dry naturally. The whiteness was measured using a colorimeter before and after washing the cotton cloth, and then bleaching power was calculated by substituting the Kubellka-Munk equation of Equation 1 as follows. Shown in

Bleaching rate (%) = [(1- Rs) 2 / 2Rs - (1-Rb) 2 / 2Rb] / [(1-Rs) 2 / 2Rs - (1-Ro) 2 / 2Ro] x 100

In Equation 1, Rs is the surface reflectance of the contaminated cotton cloth, Rb is the surface reflectivity of the cotton cloth after decontamination, and Ro is the surface reflectance of the white cotton cloth.

      Usage amount (% by weight) Example Comparative example One 2 3 4 5 6 7 One 2 3 Sodium lauryl sulfonate 1.0 2.0 2.0 2.0 2.0 2.0 2.0 1.0 1.0 2.0 Polyoxyethylene Lauryl Ether (9 mol of ethylene oxide) 0.5 3.0 3.0 3.0 3.0 3.0 3.0 0.5 0.5 3.0 Soda ash (sodium carbonate) - 4.0 4.0 4.0 4.0 30 4.0 - - 4.0 Forget-me-not (sodium sulfate) - 1.0 1.0 1.0 1.0 30 1.0 - - 1.0 Percarbonate ¹⁾ 59 62.4 62.5 63.1 73 ²⁾ 3.0 - 59 59 61.4 Perborate ³⁾ - - - - - - 63.1 - - - TAED ⁴⁾ - - - - - - - - - 1.0 D2016D ⁵⁾ 0.1 0.5 0.5 0.5 0.5 1.0 0.5 0.1 0.1 0.5 Sodium Gluconate - 0.5 0.5 0.5 0.5 - 0.5 - - 0.5 Lauric acid 1.0 0.5 - - 0.5 0.5 - 1.0 1.0 0.5 Myristic acid 0.4 0.2 - - 0.2 0.2 - 0.4 0.4 0.2 Carbomer ⁶⁾ - - 0.6 - - - - - - - PEG400 ⁷⁾ 38 25 25 25 14.4 29.4 25 - 19 25 PEG200 - - - - - - - 38 - - Anhydrous ethanol - - - - - - - - 19 - Fluorescent Dye ⁸⁾ - 0.3 0.3 0.3 0.3 0.3 0.3 - - 0.3 Enzyme ⁹⁾ - 0.5 0.5 0.5 0.5 0.5 0.5 - - 0.5 incense - 0.1 0.1 0.1 0.1 0.1 0.1 - - 0.1 Physical stability Room temperature, 1 month stability stability stability stability stability stability stability Instability Instability Instability Freeze-thawing (minus 4-40 ℃), 1 month stability stability stability stability stability stability stability Instability Instability Instability Chemical stability 50 ℃, one month 92% 95% 95% 95% 97% 93% 97% 80% 85% 73%  1) Sodium percarbonate with average particle size of 70㎛ 2) Sodium percarbonate with average particle size of 620㎛ 3) Sodium perbrorate with average particle size of 150㎛ 4) TAED: Mikon ATC-Green, Warwick, Bleach Activator 5) D2016D: Solutia, Stabilizer 6) Carbomer: Carbopol 934, BF Goodrich, Thickener 7) PEG400: Molecular Weight 400 Polyethylene glycol 8) Fluorescent dye: AMS-GX, Ciba Specialty 9) Enzyme: Everlase 6.0T, Novozymes

As shown in Table 1, in the composition of Comparative Example 1 in which the solvent was changed from PEG400 to PEG200 in comparison with the composition of Example 1, phase separation occurred and the loss of free radicals was not good, resulting in poor chemical stability. In addition, it can be seen that the physical and chemical stability of the Comparative Example 2 composition using PEG400 and anhydrous ethanol as a solvent is also poor.

The composition of Example 2 using soda ash and forget-me-not as a filler has higher chemical stability and better bleaching power than Example 1 composition. The composition of Example 3 using Carbomer instead of fatty acid as a thickener is also excellent in stability, especially the composition of Example 4 without using thickener shows the same physical and chemical stability as the composition of Example 2 and Example 3 using thickener. Could know. On the other hand, Comparative Example 3 composition using a bleach activator was excellent in bleaching power but poor physical and chemical stability.

The composition of Example 5 uses percarbonate having an average particle size of 620 μm, and the composition of Example 6 uses 3% by weight of percarbonate and 60% by weight of a filler (soda ash and forget-me-not) to have excellent physical and chemical stability. appear. The composition of Example 7 using perborate as peroxide also has good physical and chemical stability.

division Example 1 Example 4 Commercial Powder Bleach Red wine pollution 84% 89% 80% Coffee pollution 85% 87% 81% Pepper pollution 84% 88% 80% Secondary pollution 79% 82% 72%

In Table 2, the non-aqueous oxygen-based liquid bleach composition prepared according to Examples 1 and 4 of the present invention shows the same or more bleaching power in the contamination of commercial powder bleach and wine, coffee, pepper, tea Can be.

As described above, the non-aqueous oxygen-based liquid bleach composition of the present invention is applied to the advantages of the liquid bleach and powder bleach as much as possible, and even if stored for a long time in low temperature and high temperature conditions, there is little loss of available oxygen (available oxygen) during storage The chemical stability of the back and the like (high), the phase separation does not occur between the liquid component and the solid component in the bleach composition, there is no change in the viscosity of the physical stability (physical stability) is high.

In addition, the non-aqueous oxygen-based liquid bleach composition of the present invention is characterized by excellent bleaching power, high solubility at low temperatures, no dust generated when used, and for multi-purpose bleaching, stain removal, and cleaning of kitchens and bathrooms. You can expect the effect to be used.

Claims (17)

0.1-85 wt% of solid peroxide, 10-80 wt% of non-aqueous organic solvent, 0.1-10 wt% of anionic surfactant, 0.1-10 wt% of nonionic surfactant, 0.1-85 wt% of filler and stabilizer 0.01-10 It comprises a weight percent, the viscosity is 500 ~ 1,000,000 cps (25 ℃), the non-aqueous oxygen-based liquid, characterized in that the solid peroxide is dispersed in a liquid component to form a suspension (suspension) Bleach composition. The non-aqueous oxygen-based liquid bleach composition according to claim 1, wherein the non-aqueous oxygen-based liquid bleach composition further comprises 0.01 to 5% by weight of one or a mixture thereof selected from 0.01 to 5% by weight of a thickener, an optical brightener, an enzyme and a fragrance. Aqueous oxygen based liquid bleach composition. The non-aqueous oxygen-based liquid bleach composition according to claim 1, wherein the peroxide has an average particle size in the range of 1 to 700 µm. The non-aqueous oxygen-based liquid bleach composition according to claim 1, wherein the peroxide is selected from percarbonate, perborate, persulfates and urea peroxide. The non-aqueous oxygen system according to claim 1, wherein the non-aqueous organic solvent is one or more mixtures selected from polyalkylene glycol, polyhydric alcohol, alkylene glycol monoalkyl ether, alkyl ester, and alkylamide. Liquid Bleach Composition. The non-aqueous organic solvent according to claim 1 or 5, wherein the non-aqueous organic solvent is polyethylene glycol, glycerol, methyl ester, methyl amide, methyl acetate and C ₂ -C ₃ alkylene glycol monoC ₂ -C ₆ Non-aqueous oxygen-based liquid bleach composition, characterized in that the alkyl ether. The method of claim 1, wherein the anionic surfactant is a linear alkylbenzene sulfonate represented by the following formula (1), a fatty acid salt represented by the following formula (2), a linear alkyl sulfonate represented by the following formula (3) and Non-aqueous oxygen-based liquid bleach composition characterized in that the mixture of one or more selected from the alpha olefin sulfonate to be displayed; [Formula 1] R ¹ -C ₆ H ₄ -SO ₃ X [Formula 2] R ² -CH ₂ -COOX [Formula 3] R ³ -CH ₂ -SO ₃ X [Formula 4] R ³ -CH = CHCH ₂ -SO ₃ X In Formulas 1 to 4, R ¹ is a C ₉ to C ₁₅ alkyl group, R ² is a C ₁₁ to C ₁₆ alkyl group, R ³ is a C ₁₁ to C ₁₈ alkyl group, and X is an alkali metal. According to claim 1, wherein the nonionic surfactant is a fatty alcohol polyoxyethylene glycol represented by the following formula (5), fatty acid polyoxyethylene glycol represented by the following formula (6) and alkylphenyl polyoxyethylene glycol represented by the following formula (7) Non-aqueous oxygen-based liquid bleach composition, characterized in that one or more mixtures selected; [Formula 5] R ⁴ -CH _2- (OCH ₂ CH ₂ ) _n -OH [Formula 6] R ⁴ -CO- (OCH ₂ CH ₂ ) _n -OH [Formula 7] R ⁴ -C ₆ H _4- (OCH ₂ CH ₂ ) _n -OH In Chemical Formulas 5 to 7, n is an integer of 5 to 25, R ⁴ is an alkyl group of C ₁₁ ~ C ₁₈ . The non-aqueous oxygen-based liquid bleach composition according to claim 1, wherein the anionic surfactant and the nonionic surfactant are included in a weight ratio of 3: 1 to 1: 3. The non-aqueous oxygen-based liquid bleach composition according to claim 1, wherein the filler is one or more mixtures of sodium carbonate (Na ₂ CO ₃ ), sodium bicarbonate (NaHCO ₃ ), and sodium sulfate (Na ₂ SO ₄ ). . The non-aqueous oxygen-based liquid bleach composition according to claim 1, wherein the stabilizer is one or more mixtures selected from organic acids, salts of organic acids, and amino polyphosphonate compounds. 12. The non-aqueous oxygen based liquid bleach composition according to claim 11, wherein the organic acid is selected from citric acid, dipicolinic acid and gluconic acid. The compound according to claim 11, wherein the amino polyphosphonate compound is selected from hydroxy ethylene diphosphonic acid, ethylene diamine tetra (methylene phosphonic acid), diethylene triamine penta (methylene phosphonic acid) and aminotri (methylene phosphonic acid). Non-aqueous oxygen-based liquid bleach composition, characterized in that selected. The method of claim 2, wherein the thickener is one or more mixtures selected from fatty acids, cross-linked acrylic copolymers, colloidal silica, carboxymethylcellulose, polyvinyl alcohol, polyvinylpyrrolidone and sodium polyacrylate. A non-aqueous oxygen-based liquid bleach composition to be used. The non-aqueous oxygen based liquid bleach composition according to claim 14, wherein the fatty acid is a mixture of two or more selected from C ₁₀ to C ₁₈ saturated or unsaturated fatty acids. The non-aqueous oxygen-based liquid bleach composition according to claim 14, wherein the crosslinked acrylic copolymer is an acrylic acid copolymer crosslinked with 0.75 to 1.5% polyallyl sucrose. 15. The method of claim 14, wherein the colloidal silica has a surface area of 200 m 2 / g, hydrophilic fumed silica having an average particle size in the range of 10 to 12 nm or hydrophobic fume having a surface area of 100 m 2 / g and an average particle size in the range of 10 to 20 nm. Non-aqueous oxygen-based liquid bleach composition, characterized in that the silica.