KR20060021012A - Method of manufacturing for natural mortar - Google Patents

Method of manufacturing for natural mortar Download PDF

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Publication number
KR20060021012A
KR20060021012A KR1020040069803A KR20040069803A KR20060021012A KR 20060021012 A KR20060021012 A KR 20060021012A KR 1020040069803 A KR1020040069803 A KR 1020040069803A KR 20040069803 A KR20040069803 A KR 20040069803A KR 20060021012 A KR20060021012 A KR 20060021012A
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South Korea
Prior art keywords
mortar
natural
mixing
seaweed
clay
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KR1020040069803A
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Korean (ko)
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손응주
박우복
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손응주
박우복
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Priority to KR1020040069803A priority Critical patent/KR20060021012A/en
Publication of KR20060021012A publication Critical patent/KR20060021012A/en

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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/10—Clay
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10—Coating or impregnating
    • C04B20/1018—Coating or impregnating with organic materials
    • C04B20/1029—Macromolecular compounds
    • C04B20/1048—Polysaccharides, e.g. cellulose, or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0076—Deodorizing agents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0097—Anion- and far-infrared-emitting materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08—Acids or salts thereof
    • C04B22/12—Acids or salts thereof containing halogen in the anion
    • C04B22/124—Chlorides of ammonium or of the alkali or alkaline earth metals, e.g. calcium chloride

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

본 발명은 백토, 맥반석, 황토, 숯의 천연재료를 이용하여 몰탈을 제조하는 천연몰탈의 제조방법에 대한 것으로써, 더욱 상세하게는 원료 총 중량에 대하여 천연색상소재와 정화수와 해초풀을 각각 일정 중량비로 혼합하고, 몰탈 총 중량에 대하여 소금을 1~3중량% 혼합하는 것을 특징으로 하는 천연몰탈의 제조방법을 제공함으로써, 시멘트 등 유해한 원료를 섞지 않고 건축자재로써의 강도 구현이 가능하면서 유해한 염료를 사용하지 않고 몰탈에 색상을 제공할 수 있으며, 따라서 다양한 건축재료로 제공하여 사용되는 천연 재료의 효과를 제공하므로 탈취, 항균, 원적외선 방사의 효과를 제공할 수 있는 발명이다.
The present invention relates to a method for producing natural mortar by using natural materials such as clay, elvan, loess, and charcoal, and more specifically, natural color material, purified water and seaweed grass, respectively, based on the total weight of the raw materials. By providing a method for producing natural mortar, characterized in that mixing by weight ratio, and mixing the salt 1 to 3% by weight based on the total weight of the mortar, it is possible to realize the strength as a building material without mixing harmful raw materials such as cement and harmful dyes It is possible to provide color to the mortar without using, thus providing the effect of natural materials used to provide a variety of building materials is an invention that can provide the effect of deodorization, antibacterial, far-infrared radiation.

백토, 맥반석, 황토, 숯, 해초, 몰탈 White clay, elvan, loess, charcoal, seaweed, mortar

Description

천연몰탈의 제조방법{Method of manufacturing for natural mortar}Method of manufacturing natural mortar

본 발명은 백토, 맥반석, 황토, 숯의 천연재료를 이용하여 몰탈을 제조하는 천연몰탈의 제조방법에 대한 것으로써, 더욱 상세하게는 원료 총 중량에 대하여 천연색상소재와 정화수와 해초풀을 각각 일정 중량비로 혼합하고, 몰탈 총 중량에 대하여 소금을 1~3중량% 혼합하는 것을 특징으로 하는 천연몰탈의 제조방법에 대한 것이다.
The present invention relates to a method for producing natural mortar by using natural materials such as clay, elvan, loess, and charcoal, and more specifically, natural color material, purified water and seaweed grass, respectively, based on the total weight of the raw materials. Mixing in a weight ratio, to a method for producing natural mortar, characterized in that the salt is mixed 1 to 3% by weight based on the total weight of the mortar.

일반적인 건축용 미장재료로써 시멘트 몰탈이 사용되고 있다. 그러나 상기 시멘트 몰탈은 양성화되면서 장시간 발생되는 라돈가스로 인하여 인체의 건강에 나쁜 영향을 미치게 되고, 압축강도에 비해 초기 인장강도가 약하다는 문제점이 발생되었다. 또한 시멘트 몰탈의 시공시 접착성이 불량하고 가소성이 좋지 않아 흘림방지를 위하여 초벌, 재벌, 정벌 등의 순서로 수회 나누어 바름으로써 작업성이 번거롭다는 문제점이 발생되었다.
Cement mortar is used as a general construction plastering material. However, the cement mortar has a problem that due to the radon gas generated for a long time to be positively adversely affect the health of the human body, the initial tensile strength is weak compared to the compressive strength. In addition, there is a problem that the workability is cumbersome by dividing several times in the order of the first, chaebol, conglomerate, etc. in order to prevent shedding because of poor adhesion and plasticity during construction of cement mortar.

또한, 점토질의 흙바름, 석회반죽바름 등의 작업방법이 있으나, 이 미장재료들은 바름벽에 부착력이 약하고 균열이 쉽게 발생하는 문제점이 발생되었고, 이를 방지하기 위해 현장에서 해초풀류를 끓여 혼합반죽 하였으나, 이 또한 작업방법이 번거로워 작업성이 저하되는 문제점이 발생되었으며, 이러한 작업의 번거로움을 피하기 위해 화학제인 풀류를 사용하기도 하였으나 건조 후 내수성 및 강도가 약하다는 문제점이 발생하였다.
In addition, there is a work method such as clay soil, lime plaster, etc., but these plastering materials have a weak adhesion to the walls and easily cause cracking. To prevent this, the seaweed grass was boiled and mixed in the field to prevent this. In addition, there was a problem that the work method is cumbersome and the workability is deteriorated. In order to avoid the hassle of working, pools, which are chemical agents, are used, but the water resistance and strength are weak after drying.

따라서 최근 미장재로써 시멘트, 석고 등을 대체하고자 하는 노력이 계속되고 있으며, 특히 여러 가지 천연재료를 사용하여 건축자재를 제조한 발명이 다수 출원 및 등록되어 있다. 그러나 건축자재는 그 기능성도 중요하지만 외관에 미치는 영향도 중요하다 할 수 있는데, 종래 발명들은 그 기능성에만 치중한 면이 있다.
Accordingly, efforts have recently been made to replace cement, gypsum, and the like as plastering materials. In particular, many inventions have been applied and registered for manufacturing construction materials using various natural materials. However, the building material is also important in its functionality, but the effect on the appearance can also be important, the conventional inventions are focused only on the functionality.

한편, 건축물에 색상을 나타내기 위해서는 페인트를 덧칠해야 하며, 또는 건축자재에 염료를 혼합하여야 하는데, 페인트와 염료는 대표적인 유해한 화학물질로써 인체에 매우 해롭다.
On the other hand, in order to display the color of the building, the paint must be painted, or the dye must be mixed with the building material, the paint and the dye is a representative harmful chemicals are very harmful to the human body.

이에 본 발명자는 기능성은 물론 천연소재를 사용하여 다양한 색상을 제공할 수 있는 몰탈 제공할 수 있음을 확인하고 본 발명을 완성하게 되었다.
The present inventors have confirmed that it can provide a mortar that can provide a variety of colors using natural materials as well as functionality and completed the present invention.

이에 본 발명은 천연색상소재에 해초풀을 혼합하여 천연몰탈을 제조함으로써, 시멘트 등 유해한 원료를 섞지 않고 건축자재로써의 강도 구현이 가능하면서 유해한 염료를 사용하지 않고 몰탈에 색상을 제공하여 심미감을 형성하고, 사용되는 천연 재료의 효과를 제공하며, 따라서 벽지 냄새 등 악취를 차단하고, 항균, 원적외선 방사의 효과가 있는 천연몰탈 제조방법을 제공하는 데 그 목적이 있다.
Accordingly, the present invention is to prepare a natural mortar by mixing the seaweed grass in a natural color material, it is possible to realize the strength as a building material without mixing harmful raw materials such as cement, while providing a color to the mortar without using harmful dyes to form aesthetic sense And, to provide the effect of the natural materials used, and thus to block the odor, such as wallpaper odor, and to provide a natural mortar manufacturing method having the effect of antibacterial, far infrared radiation.

상기와 같은 목적을 달성하기 위한 본 발명은 원료 총 중량에 대하여 천연색상소재와 정화수와 해초풀을 각각 일정 중량비로 혼합하고, 몰탈 총 중량에 대하여 소금을 1~3중량% 혼합하는 것을 특징으로 하는 천연몰탈 제조방법을 제공한다.
The present invention for achieving the above object is characterized by mixing a natural color material, purified water and seaweed grass in a specific weight ratio with respect to the total weight of the raw material, and mixing 1 to 3% by weight of salt with respect to the total weight of the mortar. It provides a natural mortar manufacturing method.

또한 본 발명은 상기 천연색상소재가 백토, 맥반석, 황토, 숯 중에서 선택된 어느 한가지인 것을 특징으로 하는 천연몰탈 제조방법을 제공한다.
In another aspect, the present invention provides a natural mortar production method, characterized in that the natural color material is any one selected from white clay, elvan, loess, charcoal.

아울러 본 발명은 상기 중량비가 건식일 경우 천연색상소재와 정화수와 해초풀을 75~95 : 0 : 5~25로 하고, 습식일 경우 천연색상소재 : 정화수 : 해초풀을 30~45 : 45~65 : 5~10으로 하는 것을 특징으로 하는 천연몰탈 제조방법을 제공한다.
In addition, the present invention, when the weight ratio is dry natural color material and purified water and seaweed grass 75 ~ 95: 0: 5 to 25, when wet, natural color material: purified water: seaweed grass 30 ~ 45: 45 ~ 65 : Provides a natural mortar production method characterized in that 5 to 10.

백토는 법적광물의 고령토에 준하고 있는 Montmorillonite계 점토광물의 일 종으로써, 이 중 활성 가능한 원광을 엄선하여 이를 산 반응(활성화)등의 복잡한 과정을 통해 얻어지는 화학공업제품을 산성백토(활성백토; Activated clay)라 한다. 산성백토는 활성화 처리에 의해 그 구조내의 가용성 물질을 용출하여 미세한 세공이 있는 표면을 형성하고 있으며, 3층 구조로 되어 있어 이온교환수지와 유사한 양이온교환성이 있고, 활성화처리에 의해 양이온의 일부는 수소이온으로 치환된다. 또한 산성백토는 극성물질, 불포화물질, 방향족 물질에 대하여 선택적인 흡착력을 나타낸다.
The clay is a kind of Montmorillonite clay mineral which is similar to the kaolin of legal minerals. Acid clay (active clay) is selected from chemical industrial products obtained through a complex process such as acid reaction (activation) by carefully selecting active ore among them. Activated clay. The acidic clay is eluted from the soluble substance in its structure by the activation treatment to form a surface with fine pores. It has a three-layer structure and has a cation exchange similar to that of the ion exchange resin. Substituted by hydrogen ions. Acidic clay also shows selective adsorption to polar, unsaturated and aromatic substances.

맥반석은 허준의 동의보감과 중국의 본초강목에 따르면 그 성질이 달고 따뜻하여 도성이 없어 등창, 종기 등 각종 피부질환에 소염제로 사용했다는 기록이 있듯이 신비의 돌, 약석(藥石)이라고 명명되어 있다. 무수규산 및 산화알루미늄이 주성분이며, 인체 및 살아있는 세포에 꼭 필요한 산화 제2철이 함유되어 있는 것이 특징이고, 40여종의 미네랄 구성으로 생체의 발육과 생리기능을 조절하여 세포의 활력을 유지하고, 다공질로 되어 있어 강력한 흡착작용, 미네랄 용출, 이온교환작용, 원적외선 방사 등의 기능이 있는 것으로 생물의 각종 직병의 예방과 치료, 체내해독, 생육촉진, 수확량 증가 등의 효과가 있으며, 아울러 유해물질 및 중금속을 흡착, 분해하며 부패원인 제거, 신선도 유지기능을 한다.
McBanseok is named Mysterious Stone and Yakseok (허 石), according to Heo Jun-Ho's consent and Chinese herbal tree, which has a sweet and warm nature and has no sacrificing properties. Its main components are silicic anhydride and aluminum oxide, and it contains ferric oxide, which is essential for human body and living cells. It is composed of 40 kinds of minerals to control the growth and physiological functions of living organisms and maintain the vitality of cells. It has strong adsorption, mineral elution, ion exchange, and far-infrared radiation. It is effective in preventing and treating various direct diseases of living organisms, detoxification, promoting growth, and increasing yields. Adsorption, decomposition, removal of sources of corruption, and freshness.

황토는 일부 북미에도 분포되어 있으나, 한반도를 비롯하여 중국의 화북지방 황하연안 등 주로 동북아에 집중적으로 분포되어 있으며, 주로 석영을 함유하면서 휘석, 각섬석 등을 함유하는 황갈색의 석회질로써, 실리카 60~65%, 철분 5~6%, 알루미나 10~13%, 마그네슘과 나트륨 각 2% 내외, 칼리 1.5%, 석회 8% 내외의 화학적 조성을 가지며, 분해력, 자장력, 흡수력 등이 뛰어나며 인체에 유익한 약성을 갖는 것으로 알려져 왔다. 이에, 예로부터 가옥의 건축자재로써 중요하게 쓰여졌으며, 식기나 기구로 만들어져 생활의 도구로도 활용되었다. 뿐만 아니라, 황토는 해독과 질병치료에도 탁월한 약효를 가지고 있어, 동양의학에서는 중요한 약제로 쓰여졌다. 그 중 대표적인 동양의서들인 본초강목, 동의보감 및 향약집성방 등에는 황토가 본디 색을 지닌 흙으로 약성이 가장 뛰어나 널리 중요하게 쓰이는 것으로써 맛은 달고 독이 없으며 부인병과 소아병에 탁월한 효능이 있다고 기록되어 있다. 또한, 본초강목의 중수부편에는 황토에 물을 부어 우러나온 물을 지장 또는 토장이라 하며, 이는 각종 독을 해독하고 마음을 안정시키는 효능이 있다고 기록되어 있다.
Ocher is distributed in North America, but is mainly distributed in Northeast Asia, including the Korean Peninsula and the Yellow River coast of China's North China Region. It is a yellowish brown lime that contains quartz, whistle and hornblende, and is 60 ~ 65% silica. It has 5 ~ 6% of iron, 10 ~ 13% of alumina, about 2% of magnesium and sodium, about 1.5% of Kali, and about 8% of lime, and has good degradability, magnetic field, absorption, etc. It has been known. Therefore, it has been used importantly as a building material of houses since ancient times, and was used as a tool of living by making dishes and utensils. In addition, ocher has excellent efficacy in treating detoxification and disease, and has been used as an important medicine in oriental medicine. Among them, the main oriental texts, such as the herbaceous wood, Dongbobogam and Hyangjegbangbang, are the most widely used soils with ocher, the most fragile soils. . In addition, the heavy water part of the herbaceous wood is called Jijang or Sojang, which is poured water into the ocher, and it is recorded that it is effective in detoxifying various poisons and stabilizing the mind.

숯은 강력한 환원작용과 에너지 상승작용을 하여 각종 공해물질을 걸러서 정화하고, 탈취, 여과기능이 탁월하다. 또한 음이온을 발생시켜 심신안정효과가 있으며 원적외선을 방출시켜 온열효과를 통해 신진대사를 촉진시키고, 인체의 항균성을 향상시키며, 전자파 등의 차단효과가 있으며 각종 질환에 폭넓은 약효가 있는 것으로 알려져 있다.
Charcoal has strong reduction and energy synergy to filter and clean various pollutants, and has excellent deodorizing and filtration functions. In addition, it has an effect of stabilizing the mind and body by releasing anion, and by releasing far-infrared rays, it promotes metabolism through the thermal effect, improves the antibacterial properties of the human body, has a blocking effect such as electromagnetic waves, and has a wide range of effects on various diseases.

이하, 본 발명을 상세히 설명한다.
Hereinafter, the present invention will be described in detail.

목적하고자 하는 색상에 따라 백토와 맥반석, 황토, 숯 중에서 선택하여 300~500mesh로 분쇄한다. 즉, 흰색의 몰탈을 제조하고자 하는 경우 백토를, 회백색의 몰탈을 제조하고자 하는 경우 맥반석을, 황색의 몰탈을 제조하고자 하는 경우 황토를, 검정색의 몰탈을 제조하고자 하는 경우 숯을 선택하여 천연색상소재를 제조한다.
Choose from white clay, elvan, loess, and charcoal according to the color you want to grind to 300 ~ 500mesh. In other words, if you want to produce white mortar, white clay, gray-white mortar to produce a machanite, yellow mortar to produce ocher, black mortar to choose a charcoal natural material To prepare.

그리고 다시마, 미역, 천초와 같은 해초류를 분말화하여 해초분말을 제조한다. 이 때 다시마와 미역은 끓여 추출하여 젤리상태로 만들고 건조시켜서 분말화하고, 천초는 그대로 건조시켜 분말화한다. 상기 해초분말을 물과 1 : 7~10의 비율로 혼합하여 해초풀을 제조한다. 해초풀은 접착성분을 함유하고 있어 원료들 간의 결속력을 더하여 주는 역할을 함으로써 균열을 방지하여준다.
And seaweed powder is prepared by powdering seaweeds such as kelp, seaweed and cheoncho. At this time, kelp and seaweed are boiled, extracted, made into a jelly state, dried and powdered, and cheoncho is dried and powdered. The seaweed powder is mixed with water in a ratio of 1: 7 to 10 to prepare a seaweed pool. Seaweed grass contains adhesive components, which adds cohesion between raw materials, preventing cracks.

건식일 경우 상기 제조된 천연색상소재와 정화수와 해초풀을 75~95 : 0 : 5~25로 하고, 습식일 경우 천연색상소재 : 정화수 : 해초풀을 30~45 : 45~65 : 5~10으로 한다.
In case of dry, the natural color material and purified water and seaweed grass prepared above are 75 to 95: 0: 5 to 25, and in case of wet, natural color material: purified water: seaweed grass 30 to 45: 45 to 65: 5 to 10 It is done.

그리고 상기 해초의 부패를 방지하기 위하여 상기 혼합된 몰탈 총 중량에 대하여 소금 또는 간수를 1~3중량% 혼합한다.
And 1 to 3% by weight of salt or brine are mixed with respect to the total weight of the mixed mortar to prevent the seaweed from rot.

이렇게 제조된 몰탈을 건축물 벽면에 페인트를 칠하는 것보다 두껍게 미장하 고 그대로 건조시킬 수도 있고, 건조 전에 타일 등을 부착할 수도 있다.
The mortar thus prepared may be thicker and dried as it is than painting the walls of the building, or tiles may be attached before drying.

이상에서 설명한 바와 같이 본 발명은 시멘트 등 유해한 원료를 섞지 않고 건축자재로써의 강도 구현이 가능하면서 유해한 염료를 사용하지 않고 몰탈에 색상을 제공할 수 있으며, 따라서 다양한 건축재료로 제공하여 사용되는 천연 재료의 효과를 제공하므로 탈취, 항균, 원적외선 방사의 효과를 제공할 수 있다.As described above, the present invention can realize the strength as a building material without mixing harmful raw materials such as cement, and can provide color to mortar without using harmful dyes, and thus, a natural material used by providing various building materials. It can provide the effect of deodorization, antibacterial, far infrared radiation.

Claims (3)

원료 총 중량에 대하여 천연색상소재와 정화수와 해초풀을 각각 일정 중량비로 혼합하고, 몰탈 총 중량에 대하여 소금을 1~3중량% 혼합하는 것을 특징으로 하는 천연몰탈 제조방법.A natural mortar manufacturing method comprising mixing a natural color material, purified water and seaweed grass in a specific weight ratio with respect to the total weight of the raw material, and mixing 1 to 3% by weight of salt with respect to the total weight of the mortar. 제1항에 있어서,The method of claim 1, 상기 천연색상소재는 백토, 맥반석, 황토, 숯 중에서 선택된 어느 한가지인 것을 특징으로 하는 천연몰탈 제조방법.The natural color material is natural mortar, characterized in that any one selected from clay, elvan, loess, charcoal. 제1항 또는 제2항에 있어서,The method according to claim 1 or 2, 상기 중량비는 건식일 경우 천연색상소재와 정화수와 해초풀을 75~95 : 0 : 5~25로 하고, 습식일 경우 천연색상소재 : 정화수 : 해초풀을 30~45 : 45~65 : 5~10으로 하는 것을 특징으로 하는 천연몰탈 제조방법.The weight ratio is 75 to 95: 0: 5 to 25 for the natural color material, purified water and seaweed grass if dry, and for natural color to 30: 45: 45 to 65: 5-10 for the wet color natural material. Natural mortar production method characterized in that.
KR1020040069803A 2004-09-02 2004-09-02 Method of manufacturing for natural mortar KR20060021012A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101159123B1 (en) * 2012-01-12 2012-06-25 장홍기 Method for producing natural pigment composition containing phytoncide and chitosan
KR20160043441A (en) * 2014-10-13 2016-04-21 고계석 plaster composition for construction and manufacturing method thereof
KR102030405B1 (en) * 2019-05-13 2019-10-10 (주)이스텍 Multi-pattern sidewalk blocks and their manufacturing methods

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101159123B1 (en) * 2012-01-12 2012-06-25 장홍기 Method for producing natural pigment composition containing phytoncide and chitosan
KR20160043441A (en) * 2014-10-13 2016-04-21 고계석 plaster composition for construction and manufacturing method thereof
KR102030405B1 (en) * 2019-05-13 2019-10-10 (주)이스텍 Multi-pattern sidewalk blocks and their manufacturing methods

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