KR20060015581A - Method for forming bactericidal water containing hypochlorous acid or chlorous acid, raw bactericidal material package and kit for forming bactericidal water, and method and apparatus for sterilizing space - Google Patents

Abstract

A combination of a first container containing a hypochlorite as a first component and a second container containing an acid, wherein the first and the second components are so adjusted as to form a bactericidal water having a predetermined effective chlorine content and having a pH of a weekly acidic region or a neutral region when they are mixed; and a method for forming a bactericidal water for carrying out the sterilization by hypochlorous acid or chlorous acid which comprises using the above combination. The method allows a general consumer to carry out the sterilization by hypochlorous acid or chlorous acid without the use of a mechanical apparatus through the preparation of a bactericidal water at the site of use with ease.

Description

TECHNICAL FOR FORMING BACTERICIDAL WATER CONTAINING HYPOCHLOROUS ACID OR CHLOROUS ACID, RAW BACTERICIDAL MATERIAL PACKAGE AND KIT FOR FORMING BACTERIC WATER, AND METHOD AND APPARATUS FOR STERILIZING SPACE}

The present invention relates generally to sterilization with hypochlorous acid or chlorite, and more particularly, to a method for producing sterilized water containing hypochlorous acid or chloric acid, a sterilizing material package and a sterilizing water generating kit and a space sterilizing method and apparatus. It is about.

As one form of using a sterilizing solution simply, the alcohol dilution sterilizing liquid contained in the portable container filled with the container which is portable with compressed gas or liquefied gas is conventionally marketed. The barrel is generally equipped with a spray nozzle, which sprays the internal sterilizing liquid by pressing the spray nozzle. Therefore, the sterilizing liquid in this kind of container is convenient for easy sterilization but cannot be used for food sterilization.

On the other hand, sterilization sprays for sterilization with rubbing alcohol are widely used in medical fields including hospitals. However, since rubbing alcohol causes dermatitis, it is not very welcome among female users. In addition, sterilization with rubbing alcohol may lead to the generation of resistant bacteria.

Sterilization by hypochlorous acid (HClO) or chlorous acid (HClO ₂ ) is known as a sterilization method to solve this problem. This sterilization method has a variety of advantages that the sterilization target has a wide range from viruses to fungi or anthrax, has an immediate sterilization effect on them, and does not produce resistant bacteria. In particular, sterilized water containing hypochlorous acid or chloric acid has an excellent advantage of not causing dermatitis or allergic reaction when adjusted to the weakly acidic region. The safety of the sterilized water containing hypochlorous acid is evident from the fact that hypochlorous acid is produced in the human body by neutrophils (also called polymorphonuclear leukocytes) and is responsible for sterilizing the body. Therefore, it can be considered that sterilization by hypochlorous acid is the most preferable method among various sterilization methods currently known in view of sterilization ability and harmlessness to human body.

However, sterilization with hypochlorous acid or chlorite has some problems to be solved. One problem is that sterilizing water containing hypochlorous acid loses its sterilizing ability over time. Another problem is the generation of toxic gases depending on the pH level. This problem will be described in more detail below.

For example, it is known that hypochlorous acid can exist only in an aqueous solution in which hypochlorite such as sodium hypochlorite is properly adjusted to pH. Sodium hypochlorite is generally shipped from the manufacturer in aqueous solution, typically adjusted to a 6% or 12% concentration. Aqueous solution of sodium hypochlorite in the alkaline state is, the component of Na, H, O and Cl in the water and hypochlorous acid Na ^+, H ^+, OH ^- are relatively stable, free of the ion state of the ^-, OCl. In this state, the sodium hypochlorite aqueous solution has a weak effect as sterilizing water. When the pH is adjusted to the neutral or weakly acidic region, the sodium hypochlorite aqueous solution can contain high concentration of hypochlorous acid (HOCl), thereby exerting an effect as HOCl sterilized water. Fig. 54 is a graph published on page 104 of the book name "Integer Description" (Publisher: Kiboden Publishing Co., Ltd.). FIG. 54 shows that hypochlorite ion OCl ⁻ requires 80 times as much time as HOCl (hypochlorite) to sterilize E. coli group. In other words, FIG. 54 shows that the sterilizing ability of hypochlorous acid is 80 times that of OCl ⁻ ions.

Therefore, it is very important to adjust the pH level of the sodium hypochlorite aqueous solution by adding an acid such as hydrochloric acid in order to obtain a sterilized water having high HOCl. However, when the amount of acid added is excessive, the sodium hypochlorite aqueous solution becomes acidic and generates harmful chlorine gas.

Furthermore, even when the aqueous solution is once adjusted to contain a sufficient amount of hypochlorous acid (HOCl), its pH level is likely to change over time, and hypochlorous acid (HOCl) cannot maintain its form for a long time.

That is, the equilibrium relationship shown in the following reaction formula exists between three chemical species Cl ₂ , HOCl, and OCl ⁻ .

Cl ₂ + H ₂ O ⇔ HCl + HOCl

HOCl ⇔ H ^{+ +} OCl ^-

Here, the left side has a low pH level, and the right side has a high pH level.

As mentioned above, the proportion of each species present is governed by pH. As can be understood from [Scheme 1], the lower the pH, the higher the proportion of chlorine gas (Cl ₂ ). In the weakly acidic and neutral regions, hypochlorous acid (HOCl) increases (Reaction 1), while in the alkaline region, hypochlorous acid (HOCl) is decomposed into H ⁺ ions and OCl ^- ions, resulting in a high ratio of OCl ^- ions ([ Scheme 2]).

Therefore, it is clear that the use of fresh, HOCl-rich sterilized water, which is certainly pH adjusted for effective sterilization, is desirable, but it must be ensured that the user is not affected by harmful gases.

By the way, sodium hypochlorite generates chlorine gas (Cl ₂ ) in the strongly acidic region, while sodium chlorite generates chlorine dioxide gas (ClO ₂ ). Chlorine gas and chlorine dioxide gas are both toxic gases. In particular, chlorine dioxide gas is ten times as toxic as chlorine gas.

Until now, it has been common knowledge that user manipulation of adding acid to sodium hypochlorite should be prohibited. For example, Kao Corporation (Kayabacho Nihombashi, Chuo-ku, Tokyo) manufactures and sells bleach disinfectant solutions for kitchens under the trade name of "Hai Tai" (registered trademark) for general consumers. This disinfectant solution contains sodium hypochlorite as its main ingredient, but "do not mix!" Danger "The danger of chlorine gas generated when used with acidic substances" is issued in red letters.

Japanese Laid-Open Patent Publication No. 2003-34375 proposes a portable sterilization container of the above-mentioned common sense range. This is a cylindrical container filled with compressed gas or liquefied gas that can be used as it is adjusted in the range of pH 4 to 8 and residual chlorine concentration of 10 to 2,000 ppm by adding an acid such as hydrochloric acid to sodium hypochlorite. The cylindrical container includes a spray nozzle, which sprays the sterilizing liquid by gas pressure as the spray nozzle is pressed. However, since the sterilizing water adjusted as described above decreases sterilizing power with time, there is no guarantee that sterilizing water having sufficient sterilizing power can be used for the sterilizing water contained in the prior art tub when necessary.

Due to the above circumstances, the sterilizing water generating device for installation in the site of use is sold. 55 shows a conventional sterilizing water generator. This sterilizing water generator is used to dilute sodium hypochlorite with water in the first process and dilute hydrochloric acid with water, and then, by mixing both diluents with each other in the second process, sterilization of effective chlorine concentration of 50 to 200 ppm in the weakly acidic or neutral region. It is supposed to generate numbers. This type of sterilizing water generator is useful for obtaining fresh preparations of the desired sterilizing water when needed. But these are too expensive for the average consumer to purchase for their own use. This type of sterilizing water generator is currently used only in limited places such as hospitals or factories that require cleaning and sterilization of large quantities of vegetables and meats or cleaning and sterilization of many machines, tools and instruments.

According to the present invention, if the generation of toxic gas is suppressed, the user himself may mix the components (hereinafter referred to as "components") to generate the sterilizing water. It is designed. This idea is a great leap from the common knowledge of those skilled in the art.

It is an object of the present invention to easily generate fresh sterilized water in the field anytime and anywhere without requiring mechanical equipment, so that powerful sterilization by hypochlorous acid or chlorine acid can be performed, and the pH level is adjusted to a weakly acidic region or a neutral region. A method of producing a sterilizing water, a sterilizing raw material package and a sterilizing water generating kit are provided.

It is another object of the present invention to provide a sterilized raw material package that is easy to generate fresh sterilized water in the field anytime and anywhere and is suitable for carrying out strong sterilization by hypochlorous acid or chlorine acid.

It is another object of the present invention to provide a sterilizing material package and a sterilizing water generating kit which can be stored for a long time and can be easily generated on site anytime and anywhere for fresh sterilization by hypochlorous acid or chloric acid. .

The raw materials applicable to the present invention are hypochlorite or chlorite containing sodium hypochlorite, sodium chlorite and calcium hypochlorite as typical examples. For example, sodium hypochlorite is available in crystalline form, but is typically provided in the form of an aqueous solution of 6% (60,000 ppm) or 12% (120,000 ppm) from the company that manufactures it. In addition, calcium hypochlorite is typically provided in powder form from the company that manufactures it.

In the description of the present invention, for the hypochlorous acid chloride provided in the liquid state from the manufacturer, the solution state as provided from the manufacturer is referred to as "stock solution concentration" or "stock solution", and water is further added to the "stock solution". What reduced the density | concentration is called "dilution concentration" or "dilution liquid".

In addition, another raw material applicable to this invention is acid, such as hydrochloric acid, for example. Other examples of the applicable acid include inorganic acids such as sulfuric acid and carbonic acid, and organic acids such as acetic acid. In the following description, the acid of the density | concentration provided as a manufacturer is called "stock solution", and what added water to this "stock solution" and reduced concentration is called "dilution concentration". For example, hydrochloric acid is provided by the manufacturer at a concentration of up to 36% for industrial use and up to 10% for household use. Therefore, when using it with the density | concentration available from this manufacturer, it is called "stock solution", and when water is added and the density | concentration is reduced, it is called "dilution concentration".

According to a first aspect of the present invention, a set includes a first container into which a hypochlorite (hereinafter referred to as a first component) is added and a second container into which an acid (hereinafter referred to as a second component) is added. Provide consumers with their own use. As shown in Figs. 1 and 2, the sterilized water produced by mixing the first and second components in the first and second containers by the consumer has a pH level in the weakly acidic region or the neutral region, and has a predetermined effective chlorine concentration. The said 1st, 2nd component is adjusted.

In one method for producing sterile water, a stock solution or solid (typically a powder) or a first component of dilute concentration is accommodated in a first container, and a second component of dilution concentration is contained in a second container (FIG. 1). In another method of producing sterilizing water, a first component having a diluted concentration is accommodated in a first container, and a stock solution or a second component having a diluted concentration is accommodated in a second container (FIG. 2).

By mixing the hypochlorous acid salt of the first component and the acid of the second component, the first and second components are adjusted in advance so that the pH level is a weakly acidic region or a neutral region. If the pH adjustment by) is too sensitive, chlorine gas may be generated in the strongly acidic region. In addition, if the produced sterilized water is not used for a long time, the pH of the sterilized water is lowered, chlorine gas is generated, and the sterilizing effect is easily lowered. In solving such a problem, it is preferable to add a buffer to alleviate the pH adjustment by the second component (acid) (FIGS. 3 to 5). For example, a buffer such as bicarbonate may be added when the first and second components are mixed (FIGS. 3 and 4). As another example, a buffer such as bicarbonate may be mixed in advance in the first accommodation space containing the first component (FIG. 5). Examples of the bicarbonate include sodium hydrogen carbonate (NaHCO ₃ ), but other examples include potassium hydrogen carbonate, calcium hydrogen carbonate and magnesium hydrogen carbonate.

By adding buffers such as sodium hydrogen carbonate and potassium hydrogen carbonate, pH adjustment by the second component (acid) can be alleviated, and the pH of the sterilized water can be prevented from entering the strongly acidic region. In addition, since the produced sterilized water contains a buffer, it is possible to suppress the fluctuation in pH until the generated sterilized water is used up, and the sterilized water can be stably maintained in a weakly acidic or neutral region, and thus, H) Sterilizing effect by chloric acid can be maintained.

Hypochlorite tends to decrease in pH over time. The acid is stable in this regard. For this reason, even if the first component and the second component are accommodated in separate containers, when the container is stored in a warehouse for a long time, part of the first component (hypochlorite) decomposes with time and the pH decreases. It is thought that the pH of the sterilizing water produced by mixing the first component and the second component is lower than the originally scheduled pH. On the other hand, by mixing the first and second components in a state in which a buffer such as sodium hydrogen carbonate is introduced, sterilized water in a weakly acidic or neutral region can be stably obtained, and this can be assured to the consumer. This is extremely important in selling a product in which a container containing the first and second components in a separate space is sold to a consumer for mixing.

In addition, sterilized water containing a buffer can suppress the fluctuation of pH even when diluted with it. In addition, if the water used for dilution is far from neutral, for example, alkaline water at pH 9, the sterilization water may change to the alkali side due to dilution. To cope with this, it is necessary to provide the user with the acid (for example HCl) and buffer (for example, sodium bicarbonate) used in the dilution to the container and to provide the user with a manual describing the amount used. desirable. Instead of a buffer, a carbon dioxide container may be provided to the user. By diluting a buffer with an acid at the time of dilution, it is easy to suppress the large pH change of the sterilization water accompanying dilution and to maintain the sterilization water after dilution neutral and weakly acidic.

According to a second aspect of the present invention, a set consisting of a first container in which a first component is added, a second container in which a second component is added, and a third container in which a predetermined amount of water is provided, is provided for the consumer to use himself. do. As shown in FIG. 6, the sterilized water produced by adding and mixing the first and second components into a predetermined amount of water in the third container has a pH level of a weakly acidic region or a neutral region, and provides a predetermined effective chlorine concentration. The amounts of the first and second components and water are adjusted to have them.

As a variant of the invention of the second aspect, it is provided to the consumer an additional container in which a buffer such as sodium hydrogen carbonate is added as a third component together with the first container and the second container, so that the consumer can 1st-3rd component may be thrown into the 3rd container which injected | threw-in, and may mix. For this reason, as mentioned above, the possibility of entering into a strongly acidic region at the time of mixing can be prevented, and the pH fluctuation of sterilizing water can be suppressed at the time of diluting and using the produced sterilizing water.

According to a third aspect of the present invention, a set consisting of a first container containing a first component, a second container containing a second component, and a manual describing precautions when mixing is provided for use by the consumer. According to the instructions of the manual, the sterilized water produced by adding and mixing the first and second components into the indicated amount of water has a pH level of the weakly acidic or neutral region, and has a predetermined effective chlorine concentration. Two components are adjusted.

In the second and third aspects, a set consisting of a first container containing a stock solution, a solid (typically a powder) or a first component in a dilute concentration, and a second container containing a second component in a stock solution or dilution concentration It is provided for use by consumers.

In the present invention according to the third aspect, the third component may be provided to the consumer by adding a container containing a buffer such as bicarbonate (typically sodium hydrogen carbonate) or a carbon dioxide gas container. The consumer may inject the buffer or carbon dioxide gas which is the third component into the water when the first and second components are added to the indicated amount of water according to the instruction of the manual. The amount of buffer or carbon dioxide gas to be added should be described in the manual.

When applied directly to the affected area of atopic patients, it is advisable to adjust the first and second components so that the effective chlorine concentration of the sterilized water produced according to the present invention is about 30 ppm. However, in the case of general users, it is better to adjust the first and second components so that the effective chlorine concentration is about 50 to 300 ppm in consideration of the margin value. In the case of targeting the use in the military, the first and second components may be adjusted so that the effective chlorine concentration of the generated sterilizing water is about 50 to 1,000 ppm. In addition, sterilized water produced according to the present invention may be diluted with water and used. With space sterilization in this case, the effective chlorine concentration of the sterilized water produced according to the invention is about 50 to 60,000 ppm, preferably 50 to 10,000 ppm, more preferably 50 to 2,000 ppm, most preferably 50 It is good to adjust a 1st, 2nd component so that it may become-1,000 ppm. Here, the effective chlorine concentration means substantially the same as the free chlorine concentration.

In the case where the first component is provided to the consumer in liquid state, specifically, when sodium hypochlorite is provided to the consumer at a low concentration of 2,000 ppm or less, alkali (for example, NaOH) is added to the pH level to 10 or more. It is better to adjust and supply. Since sodium hypochlorite is relatively stable in an alkaline region of pH 10 or more, by lowering the sterilizing power of sodium hypochlorite over time by adjusting the pH to 10 or more with an alkali adjusting liquid. In other words, in order to provide the consumer with a relatively high concentration of sodium hypochlorite, for example, about 10,000 ppm (1%), a relatively high concentration of sodium hypochlorite is already in a high alkali state containing sodium hydroxide (NaOH). Therefore, it is not necessary to add alkali to this. However, for long-term storage in high temperature atmosphere, for example, for use in the military, an alkali adjusting solution may be added as necessary.

For example, for a user used for hand sterilization, sodium chloride (NaCl) may be added to the first component or the second component so that the generated sterilized water has the same concentration as that of the physiological saline solution. At the same time, for the user used for sterilization and washing, the surfactant may be added to the first component, the second component or the dilution water so that the generated sterilizing water contains the surfactant.

In a typical embodiment of the present invention, a self-supporting or flexible outer container containing an inner container is prepared, and the consumer is provided with the first and second components in the inner and outer containers, respectively. The consumer who obtains this incorporates the first component or the second component in the inner container into the outer container through intentional manipulation.

Intentional manipulations for incorporating the components contained in the inner container into the outer container are as follows.

(1) In one mixing method, the inner container is dropped and opened in the components contained in the outer container to mix the components in the inner container into the outer container.

(2) In another mixing method, the inner container contained in the outer container is forcibly communicated with the outer container to incorporate the components in the inner container into the outer container.

(3) In another mixing method, a strong force is applied to the outer container to make a hole or the like in the inner container therein, and the components in the inner container are mixed with the components in the outer container through the holes.

The container or sterilizing material package included in the sterilizing water generating kit according to the present invention may be provided to the consumer with a spray nozzle attachable thereto. Alternatively, the container or sterilization raw material package included in the sterilizing water generation kit may include a spray nozzle pre-assembled in the sealed cap.

The sterilized water generated using the sterilized water generating kit or sterilized raw material package according to the present invention can be used for washing and sterilizing a large amount of foods such as vegetables or meat, or for sterilizing a space, such as a hospital, as a conventional method. It is not necessary to install the sterilizing water generator.

In addition, the sterilization water generation kit or sterilization raw material package according to the present invention can be stored in the military, hospitals, homes, etc. at any time can be used to generate fresh sterilization water as needed. For example, when a woman puts in a handbag and carries the sterilizing material container of this invention, it can produce fresh sterilized water as needed anytime, anywhere, and can use it for sterilization by hypochlorous acid.

The above and other objects and effects of the present invention are apparent from the detailed description of the following specific examples.

1 is a view for explaining an example included in the basic concept of the present invention.

2 is a view for explaining another example included in the basic concept of the present invention.

3 is a diagram for explaining a modification of the basic concept shown in FIGS. 1 and 2.

4 is a view for explaining another modified example of the basic concept shown in FIGS. 1 and 2.

5 is a view for explaining another modification of the basic concept shown in FIG.

6 is a view for explaining another example included in the basic concept of the present invention.

7 is a view for explaining a modification of the basic concept shown in FIG.

8 is a partial cross-sectional view of the sterilizing raw material package of the first embodiment.

FIG. 9 is an enlarged view of a main part of the sterilizing raw material package shown in FIG. 8.

10 is an enlarged view of a main part of a modification of the first embodiment.

11 is an enlarged view of a main part of another modification of the first embodiment.

12 is an enlarged view of an essential part of still another modification of the first embodiment.

FIG. 13 is an enlarged view of an essential part of still another modification of the first embodiment, and shows a state where the circumferential groove of the cylindrical body containing the first component is sealed.

FIG. 14 is a view related to FIG. 13, wherein the circumferential groove of the cylindrical body containing the first component is exposed to the inner space of the bottle.

15 is an enlarged view of an essential part of still another modification of the first embodiment.

Fig. 16 shows the sterilizing raw material package of the second embodiment and shows a process of cutting the upper end portion of the inner container by the cutting aid included therein.

FIG. 17 illustrates a main part of the sterilizing raw material package of FIG. 16, and when storing the sterilizing raw material package, it is a view for explaining the accommodation in the sterilizing raw material package with the cutting knife of the cutting aid facing upward.

18 is a diagram illustrating a modification of the second embodiment.

19 shows another modified example of the second embodiment, and is a view for explaining a process of cutting the bottom of the inner container with a long and thin cutting knife included therein.

FIG. 20 is an enlarged view of a main part of FIG. 19 and illustrates a state when a user stores the sterilizing material package of FIG. 19.

21 is a view showing a sterilizing raw material package of the third embodiment.

22 is a view showing a sterilizing raw material package of the fourth embodiment.

Fig. 23 is a diagram showing a modification of the fourth embodiment.

24 is a view showing a sterilizing raw material package of the fifth embodiment.

25 is a view showing a sterilizing raw material package of the sixth embodiment.

FIG. 26 is a cross-sectional view of an essential part of the sterilizing raw material package of Example 6 as seen from arrow X26 in FIG. 25.

27 is a view showing a sterilizing raw material package of the seventh embodiment.

FIG. 28 is an enlarged view of a main part of the sterilizing raw material package of FIG. 27.

Fig. 29 is a sterilizing water generation kit explained as an eighth embodiment.

Fig. 30 is a view showing a sterilizing water generation kit according to a modification of the eighth embodiment.

Fig. 31 is a view showing a sterilizing water generating kit of another modification of the eighth embodiment.

FIG. 32 is a view showing a sterilizing water generating kit according to still another modification of the eighth embodiment.

FIG. 33 is a view illustrating usage of spraying sterilized water generated by using the sterilizing material package of the embodiment by attaching a sprayer to the sterilizing material package.

34 is a view illustrating a usage of spraying the sterilization water generated using the sterilization material package of the embodiment by attaching a different type of sprayer to the sterilization material package.

FIG. 35 is a perspective view of the mixing promoting member attached to the sterilizing water discharge port of the sprayer illustrated in FIG. 34.

36 is an enlarged cross-sectional view of the sterilizing water discharge port of the sprayer illustrated in FIG. 34.

FIG. 37 is a view for explaining one method of sterilizing a wound with the sprayer equipped sterilization raw material package illustrated in FIG. 34.

FIG. 38 is a view showing a space sterilization apparatus that is easy to sterilize space with sterilization water generated using the sterilization raw material package or the sterilization water generating kit of the embodiment.

FIG. 39 is a view showing a modification of the space sterilization apparatus of FIG. 38, showing the form used in the form of supplying sterilization water from the cartridge tank. FIG.

FIG. 40 is a view showing a modified example of the space sterilization apparatus of FIG. 38, and is used in the form of supplying sterilization water through a pipe.

FIG. 41 is a view showing an electrolysis space sterilizer as a modification of the space sterilizer of FIG. 38.

It is a figure which shows the modified example of the bottle provided with an inner container.

It is a figure which shows the modified example of the container provided with an inner container.

It is a figure which shows the other modified example of the bottle provided with an inner container.

It is a figure which shows another modified example of the bottle provided with an inner container.

It is a figure which shows the modification of the bottle of FIG.

Fig. 47 is a view showing a bottle containing a buffer having an inner container.

FIG. 48 is a view showing a state in which the first component, the second component, and the buffer are mixed in the bottle containing the buffer of FIG. 47.

FIG. 49 is an enlarged view of a main part of the bottle containing the buffer of FIG. 47. FIG.

50 is a cross-sectional view taken along a line X50-X50 of FIG. 49.

Fig. 51 is an enlarged view of an essential part of a modification of the bottle containing a buffer.

FIG. 52 is an enlarged view of an essential part of another modification of the bottle containing a buffer. FIG.

Fig. 53 is a plot of pH changes in sterilized water when hydrochloric acid is added to sodium hypochlorite containing buffer.

Fig. 54 shows potent sterilizing ability by hypochlorous acid.

55 is a view illustrating a procedure of generating sterilizing water using a conventional sterilizing water generating device.

Before describing the preferred embodiments of the present invention in detail these embodiments are as follows.

Sterilization raw material package of a preferred embodiment as shown in Figs. 8 to 20, 22 to 23, 25 to 28,

A first component containing hypochlorite or chlorite,

A second component containing an acid,

A single container in which the first component and the second component are separated and accommodated so as not to be mixed, and

A displacement member displaceable by artificial force on the outside of the container,

The first component and the second component may be mixed in the vessel to produce sterilized water according to the displacement of the displacement member,

When the said 1st component and the said 2nd component mix these, it is adjusted so that the sterilizing water of the weakly acidic region or neutral region of predetermined effective chlorine concentration can be produced | generated. The hypochlorite or chlorite of the first component may contain a buffer such as sodium hydrogencarbonate as the third component.

More specifically, as shown in Figures 8 to 15, 27, the sterilizing raw material package of the embodiment,

An outer container containing either the first component containing hypochlorite or chlorite or the second component containing acid,

An inner container housed in the outer container to accommodate the other of the first component or the second component;

A sealing member for sealing the inner container, and

An operation member installed in relation to the outer container and accessible from the outside of the outer container,

By operating the operating member, the inner container can be released from the sealing member so that the other component in the inner container flows into the outer container to generate sterilized water,

When the said 1st component and the said 2nd component mix these, it is adjusted so that the sterilizing water of the weakly acidic region or neutral region of predetermined effective chlorine concentration can be produced | generated. The hypochlorite or chlorite of the first component may contain a buffer such as sodium hydrogencarbonate as the third component.

For example, the said operation member is a sealing cap of an outer container in the example of FIG. 8, For example, it may be a pusher exposed to the exterior as a modification with reference to FIG. 22, FIG. 23 later. In addition, the inner container mentioned above may be provided in the inlet of an outer container as illustrated in FIG.

In addition, when the inner container is released from the sealing member, the inner container may fall into the outer container. In order to achieve this object, a weight may be attached to the inner container.

In addition, in the specific example of the sterilizing raw material package of the present invention, as shown in Figure 42, 43,

An outer container containing either the first component containing hypochlorite or chlorite or the second component containing acid,

An inner container housed in the outer container to accommodate the other of the first component or the second component;

A plug formed in the inner container and inserted into a passage communicating with an inner space of the outer container, and

An operation member installed in relation to the outer container and accessible from the outside of the outer container,

By deliberately manipulating the operating member, the plug may exit the passage of the inner container in connection with the movement of the operating member, and the other component in the inner container may flow into the outer container to generate sterilized water. There is,

When the said 1st component and the said 2nd component mix these, it is adjusted so that the sterilizing water of the weakly acidic region or neutral region of predetermined effective chlorine concentration can be produced | generated. In addition to the hypochlorite or chlorite of the first component, a buffer such as sodium bicarbonate may be placed in the outer container or the inner container.

First embodiment (Figs. 8 and 9)

The sterilization raw material package 1 has a portable and self-supporting bottle 2, which is made of a chemical-resistant plastic material. The bottle 2 is preferably made of a light-shielding material. The bottle 2 has a cylindrical shape having a diameter enough to be grasped by one hand and has an internal volume of about 100 cc.

In particular, referring to FIG. 9, the upper portion of the bottle 2 has a bottle opening 3 of a circular cross section that is open upwards, and a thread 4 is formed on the outer circumferential surface of the bottle inlet 3 to form a screw thread 4. The sealing cap 5 is screwed together. The sealing cap 5 is made of a plastic material, and the stopper ring 6 is integrally formed at the lower end of the skirt portion 5a of the sealing cap 5. The stopper ring 6 functions as a stopper or a space as shown in the following description throughout the bottle inlet 3, and may be formed separately from the skirt portion 5a of the closure cap 5.

In addition, the sealing cap 5 is provided with the spray nozzle 7, and can spray the liquid in the bottle 2 by pressing the head 7a of the spray nozzle 7 as shown by the arrow. Since this kind of spray nozzle 7 is conventionally known, its detailed description is omitted. In addition, the sterilization raw material package 1 provided with the spray nozzle 7 covers the spray nozzle 7 with the protective cap C, or the resin band D (shown in FIG. 9 when shipping this). It is also possible to cover the spray nozzle 7 with a protective cap with Fig. 13). In that case, you may integrally shape the stopper ring 6 in the resin band D (FIG. 13).

The cylindrical body 8 is fitted around the spray nozzle main body 7b located in the bottle inlet 3, and the upper end of the cylindrical body 8 is in contact with the upper part 5b of the sealing cap 5. As shown in FIG. The cylindrical body 8 is provided with the circumferential protrusion 8a which can engage with the upper edge of the circumferential sealing member 9 around it. Moreover, the cylindrical body 8 has the pocket, ie, the circumferential groove 10 in the outer peripheral surface, The circumferential groove 10 is in the state sealed by the sealing member 9 unless the stopper ring 6 is removed. That is, the circumferential groove 10 forms the inner space sealed by the sealing member 9 inside the bottle 2.

Either the first component or the second component can be accommodated in the bottle 2, but in this example, diluted hydrochloric acid (second component) is accommodated. On the other hand, in the circumferential groove 10 of the cylindrical body 8, in this embodiment, sodium hypochlorite which is the first component of the stock solution or dilution concentration is accommodated, and preferably sodium hydrogen carbonate is accommodated.

In the method of using the sterilizing raw material package 1 of the first embodiment, when the user who has obtained this removes the stopper ring 6 from the lower end of the sealing cap 5 and then rotates the sealing cap 5 in the tight tightening direction, the sealing is performed. The cap 5 can be displaced downward only by removing the stopper ring 6.

When the closing cap 5 is displaced downward, the cylindrical body 8 can be pressed downward by the upper end 5b of the sealing cap 5, so that the circumferential protrusion 8a of the cylindrical body 8 At the same time as entering the sealing member 9, the circumferential groove 10 is displaced to the lower part of the sealing member 9 and exposed to the inner space of the bottle 2, so that the first component contained in the circumferential groove 10 is Spill into bottle (2).

The user can generate 100 cc of sterile water by shaking the bottle 2 and mixing the liquid in the bottle 2. The resulting sterilized water has a pH of weakly acidic or neutral region, and the effective chlorine concentration generally has an arbitrary concentration of about 50 to 300 ppm. For example, in other words, the second component filled in the bottle 2 and the first component filled in the circumferential groove 10 have a pH and effective chlorine concentration of about 50 to 300 ppm in the weakly acidic or neutral region when they are mixed. It is adjusted to be any concentration of. In addition, if the object is to be used in the army or the like, the first and second components may be adjusted so that the effective chlorine concentration is about 800 ppm.

If the sterilization raw material package 1 of the first embodiment is manufactured, for example, for women or home use, even if sodium chloride is added to the bottle 2, for example, so that the generated sterilization water is at a concentration equivalent to physiological saline (about 0.9%). Okay. A woman who purchases the sterilizing raw material package 1 can carry out strong sterilization by hypochlorous acid anytime and anywhere by carrying the sterilizing raw material package 1 in a handbag, for example. In addition, if the sterilized raw material package (1) is manufactured for home use, for example, by adding a surfactant in the bottle (2), it is easy to remove the oil while sterilizing the tableware.

Modifications of the First Embodiment (Figs. 10 to 15)

In the above-described first embodiment, the inner space enclosed in the bottle 2 is formed by the circumferential groove 10 of the cylindrical body 8, but as shown in FIGS. 10 to 12, the lower end of the cylindrical body 8 is shown. You may provide the additional member 12 of the separate piece which stuck together, and may form the airtight space 13 at the lower end of the additional member 12 and the cylindrical body 8. According to this, if the user rotates the sealing cap 5 in the tightening direction after removing the stopper ring 6, the cylindrical body 8 can be pressed to the bottom by the upper end 5b of the sealing cap 5. have. And if the additional member 12 can be pushed downward by the shoulder 8b of the lower end part of the cylindrical body 8, and the additional member 12 deviates from the sealing member 9, the additional member 12 will become a bottle ( 2) Components falling into the additional member 12 flow out into the bottle 2. The user may shake the bottle 2 to facilitate mixing of the contents. The lower view of FIG. 11 shows the dropping additional member 12.

10 to 12 show that the other elements are substantially the same except for the shape of the additional member 12, and the additional member 12 shown in FIG. 11 is shown in FIG. The volume of the inner space 13 is larger, and the additional member 12 of FIG. 12 has a larger volume of the inner space 13 than that of FIG. When the additional member 12 which can make such a large internal volume is employ | adopted, it is also possible to fill this with the 2nd component, such as hydrochloric acid, fully diluted, and to fill the 2nd component with the 1st component. In addition, FIG. 12 is illustrated with a closed cap 5 without a spray nozzle, and the additional member 12 also has a cup-shaped inner space 13.

In the modification of FIG. 13, FIG. 14, the sealing member 9 located in the bottle inlet 3 extends below. And the sealing member 9 is provided with the passage 16 in the lower middle part, and the circumferential groove 10 of the cylindrical body 8 is sealed by the lower part 9a rather than the passage 16 (FIG. 13). . When mixing the first component and the second component, the cylindrical body attached to the end of the spray nozzle body 7b is removed by removing the stopper ring 6 and the resin band D and tightening the sealing cap 5 securely. 8) moves downward (FIG. 14), and the first component contained in the circumferential groove 10 is exposed to the inner space of the bottle 2 at the lower end of the circumferential groove 10 at the bottom of the sealing member 9a. 2) spilled into. Reference numeral 17 is a ventilation hole, and 18 is a sealing material on the sealing cap 5 side.

FIG. 15 is spaced up and down on the outer circumferential surface of the cylindrical body 8 so as to be understood in comparison with FIG. 9 to form the first and second circumferential grooves 10 and 14, and also to the lower end of the sealing cap 5. And the example which provided the 2nd stopper rings 6 and 15 are shown. According to this, only the first stopper ring 6 is removed and the first component in the first circumferential groove 10 is mixed into the bottle 2, and then, for example, it is not used for a long time, When the sterilization capacity is lowered, the second unopened guarantee strip 15 can be removed to incorporate additional first components in the second circumferential groove 14 into the bottle 2 to restore the sterilization ability to the initial capacity. have.

For example, when sodium hypochlorite is filled with the first component in the first circumferential groove 10 shown in Figs. 9 and 13, it may be further filled with sodium hydrogen carbonate. 9 and 13 form a single circumferential groove 10 but form an additional circumferential groove, such as the second circumferential groove 14 of FIG. 15, and accommodate sodium hydrogen carbonate in the additional circumferential groove to form a first circumferential groove. When mixing the 2nd component, you may mix, including sodium hydrogencarbonate. This is the same in the example of FIG. 15, when the second columnar groove 14 is filled with sodium bicarbonate instead of putting sodium hypochlorite, and the components of the first columnar groove 10 are incorporated into the bottle 2, Sodium hydrogen carbonate in the second circumferential groove 14 added thereto may be mixed.

Second Embodiment (Fig. 16, Fig. 17)

The sterilizing raw material package 20 of the second embodiment with reference to FIGS. 16 and 17 has a freestanding bottle 21. The bottle 21 may be, for example, a tank capable of carrying 1 l or 10 l or more, and it is effective in molding in terms of molding a chemical-resistant plastic material.

The inner container 23 is enclosed in the bottle 21 in the sealed state, and the volume of the inner container 23 accommodates the powdery 1st component in the inner container 23, for example, It may be relatively small as long as it contains the powdered sodium hydrogen carbonate in addition to the first component. The inner container 23 is typically made of chemical resistant plastic material or film material. That is, the inner container 23 may be a bottle or an envelope may be sufficient as it.

The inner container 23 has an outer flange 23a that engages the end face of the bottle inlet 24 at its upper rim. The outer flange 23a engages the sealing member 25 between the top surface of the bottle inlet 24 and the sealing cap 5, whereby the inner container 23 creates an independent closed space in the bottle 21. Form.

The cutting aid 26 provided with the cutting knife 26a is attached to the back surface of the upper end part 5b of the sealing cap 5 so that attachment or detachment is possible. When the cutting aid 26 is shipped to the consumer, the cutting aid 26 is attached to the sealing cap 5 with the cutting knife 26a facing upward. In this state, the cutting aid 26 is the main body of the cutting aid 26. It has the function of the cap which blocks the inlet of the inner container 23 in 26b (FIG. 17). The first or second component is accommodated in the bottle 21, and the other component is contained in the inner container 23.

The user who obtained the sterilizing raw material package 20 of the second embodiment, peeled off the sealing cap 5 and inverted the cutting aid 26, that is, the cutting knife 26a facing downward (FIG. 16). Again, screw the sealing cap (5) to the bottle inlet (24). Therefore, the cutting aid 26 can be pressed by the upper end part 5b of the sealing cap 5, and the cutting knife 26a cut | disconnects while entering the horizontal end part 23b of the inner container 23. As shown in FIG. As a result, the inner container 23 falls into the bottle 21, and the components therein flow out into the bottle 21. In order to assist the fall of the inner container 23, for example, a weight 27 may be prepared at the bottom of the inner container 23. It is preferable that the user promotes mixing in the bottle 21 by shaking the bottle 21 up, down, left, and right. Further, instead of cutting the horizontal end 23b of the inner container 23 with the cutting knife 26a of the cutting aid 26, a weak line is formed at the horizontal end 23b to press the cutting aid 26. You can cut weak lines.

The sterilizing raw material package 20 of the second embodiment is good for providing a relatively large amount of raw materials to the user. You may adjust the 1st, 2nd component so that the sterilization water produced | generated when mixing the components in the bottle 21 by the operation mentioned above may have an effective chlorine concentration of 10,000 ppm, for example. The user can generate sterilized water in the bottle 21 in the state sealed by the sealing cap 5, and can divide this, and dilute it with water suitably, and use it. This type of use is good for use in, for example, hospitals that use sterile water in large quantities.

If the water used for dilution is, for example, an alkaline environment, it is better to provide the user with an acid introduced into the container to prevent the pH of the sterilized water from changing by dilution. It is advisable to provide the user with a container with the same buffer.

Modifications of the Second Embodiment (Figs. 18-20)

In the sterilization raw material package 20 of the second embodiment described above, when the user generates the sterilization water, it is necessary to remove the sealing cap 5 once and invert the cutting aid 26, as shown in FIG. The stopper ring 6 may be integrally formed on the skirt portion 5a of the closure cap 5 while the cutting aid 26 is fixed to the upper end portion 5b of the closure cap 5. The user can drop the inner container 23 into the bottle 21 by the lowering operation of the cutting aid 26 by removing the stopper ring 6 and tightening the sealing cap 5 securely. Instead of the knife 26a of the cutting aid 26, the bottom of the inner container 23 is formed of an opening and closing stopper while installing a rod extending downward, for example. The inner container 23 may be opened by pressing the opening / closing plug constituting the bottom of the inner container 23 with a rod extending downward from the cutting aid 26 by pressing 26).

As a modified example of the sterilizing raw material package 20 of the second embodiment described above, as shown in Figs. 19 and 20, the hat-type stop aid 28 is housed in the closing cap 5, and this hat-type stop aid is provided. You may operate the long thin knife 29 by inverting the sphere 28. Specifically, the long and thin cutting knife 29 has a projection 30 at the upper end thereof, and the projection 30 is cut by being detachably fitted into the hole 28a of the hat-shaped stopper 28 to be cut. The knife 29 is fixed to the hat-shaped stop aid 28. When the user generates the sterilizing water, the sealing cap 5 is peeled off, and as shown in FIG. 20, the hat-shaped stop aid 28 is fitted into the recess of the upper end portion 5b of the sealing cap 5. Peel off from cap 5. Then, the cutting knife 29 is peeled off from the hat-type stop aid 28, the hat-type stop aid 28 is reversed, and the cutting knife 29 is mounted on the hat-type stop aid 28 again. Thereafter, the cutting knife 29 is inserted into the inner container 23. Then, when the sealing cap 5 is screwed back into the bottle inlet 24 (FIG. 19), the cutting knife 29 can be pressed by the hat-shaped stop aid 28 so that the cutting edge of the tip ( 29a) enters and cuts the bottom of the inner container 23, so that the components in the inner container 23 flow into the bottle 21. The cutting here also includes the case where a hole is drilled in the bottom of the inner container 23. In the modified examples shown in Figs. 19 and 20, it is preferable to employ an envelope made of sheet material as the inner container 23. In this case, longitudinal ribs are formed on the cutting knife 29 to the cutting knife 29. It is preferable to prevent the inner container 23 from sticking and damaging the envelope-shaped inner container 23.

Third Embodiment (Figure 21)

21 shows a sterilizing raw material package 30 of the third embodiment. In this embodiment, for example, an outer flange 31 is formed in the upper passage portion of the inner container 23, and the outer flange 31 is sealed between the sealing cap 5 and the upper surface of the bottle 21. It is provided to the consumer in a state of being fitted at 25.

The user who obtained the sterilizing raw material package 30 of the third embodiment removes the sealing cap 5 and pushes the outer flange 31 of the inner container 23 into the bottle 21 with a finger and then closes the sealing cap 5. ) Is screwed back into the bottle 21 and then shakes the bottle 21 well to drop the inner container 23 to incorporate the components in the inner container 23 into the bottle 21. To this end, the inner container 23 is preferably made of at least the upper portion of the flexible material capable of bending deformation.

Fourth Embodiment (Fig. 22)

The sterilizing raw material package 40 of the fourth embodiment has an externally accessible pusher 41, and by pressing the pusher 41, the inner container 23 is cut to remove the components in the inner container 23 into the bottle 21. It is supposed to spill. By adding a lever to the pusher 41 and pressing the lever, the pusher 41 may be moved downward by the principle of the lever.

In the sterilized raw material package 40 shown, the upper end 5b of the closure cap 5 has a pusher 41 therethrough. A stopper ring 42 is formed integrally with the pusher 41. In addition, the cutting aid 26 is fixed to the pusher 41. When the pusher 41 is strongly pressed after the stopper ring 42 is removed, the cutting aid 26 moves downward, and the cutting knife 26a moves to the inner container ( It cuts into the horizontal end part 23b of 23). As a result, the inner container 23 falls into the bottle 21, and the components therein flow out into the bottle 21. Instead of the knife 26a of the cutting aid 26, the bottom of the inner container 23 is formed of an opening and closing stopper while installing a rod extending downward, for example. The inner container 23 may be opened by pressing the opening and closing stopper constituting the bottom of the inner container 23 with a rod extending downward from the cutting aid 26 by pressing 26).

Modification of the fourth embodiment (Fig. 23)

In the sterilizing raw material package 40 illustrated in FIG. 22 described above, the inner container 23 is cut by pressing the cutting aid 26 so that the components in the inner container 23 are allowed to flow into the bottle 21. As a modification, as shown in FIG. 23, the pressing member 43 is fixed to the pusher 41, and the pusher 41 is pressed strongly to press the horizontal end 23b of the inner container 23 through the pressing member 43. A force may be applied and the inner container 23 may be forcibly dropped. To this end, at least the upper portion of the inner container 23 is preferably made of a soft material which can be easily bent and deformed by the force of a finger.

As another modification, the inner container 23 is omitted in FIG. 23, and instead, the circumferential groove 10 illustrated in FIG. 8 and the like is formed on the outer circumferential surface of the pressing member 43 described above, and the inner container 23 is formed in the circumferential groove 10. You may accommodate a 1st or 2nd component.

Fifth Embodiment (Fig. 24)

In the sterilizing raw material package 50 illustrated in FIG. 24, the cutting part 51 is integrally formed at the lower end of the inner container 23, but not necessarily, and the inner container 23 is removed by removing the cutting part 51. The communication hole 52 is formed in the lower end of (). The front end of the shaft 52 which extends up and down inside the inner container 23 is inserted in the communication hole 53, and thereby the communication hole 53 is closed. That is, the tip of the shaft 52 constitutes a movable valve body. In addition, the operation flange 54 is fixed to the upper end of the shaft 52. The inner container 23 is closed by a piston 55 fitted after filling the first or second component therein, the shaft 52 penetrating the piston 55.

The user who has obtained the sterilizing raw material package 50 removes the sealing cap 5 and then removes the inner container 23 from the bottle inlet 24 to tension the operation flange 54 to raise the shaft 52. A flange 56 is formed at the lower end of the shaft 52, and when the shaft 52 is raised, the flange 56 is coupled to the inner circumferential groove 55a of the piston 55, thereby causing the shaft 52 and The piston 55 is integrated. Then, the cutout portion 51 of the lower end of the inner container 23 is removed.

The user can press the operating flange 54 to lower the piston 55 and inject the first or second component filled in the inner container 23 into the bottle 21. The injection operation may be in a state in which the inner container 23 is disposed at the bottle inlet 24, or the tip of the inner container 23 may be in a state of facing the bottle inlet 24.

When the injection operation is completed, it is good to shake the bottle 21 in a state in which the bottle 21 is sealed in the sealing cap 5 to mix the components in the bottle 21. In the case of using the generated sterilized water, the inner container 23 having the piston 55 may be utilized as a cylinder. That is, by raising the piston 55 by raising the operating flange 54, an appropriate amount of sterilizing water is introduced into the inner container 23, and then the inner container 23 is taken out, for example, in a state toward the affected part to be disinfected. By pressing the operating flange 54, the sterilizing water in the inner container 23 can be ejected toward the affected part.

As a variation of the sterilization raw material package 50, the inner container 23 has a bottomed structure, and after the user removes the sealing cap cap 5, the user removes the inner container 23 and removes the ingredients in the inner container 23. (21) It's okay to put it in. This method is better when the first component in powder form is accommodated in the inner container 23.

Sixth Embodiment (FIGS. 25 and 26)

25 and 26 are shown as a sixth embodiment as a specific example, which is a good case when the inner and outer double containers are made of a sheet of flexible chemical-resistant material. The sterilized raw material package 60 shown in the figure is composed of an outer container 61 and an inner container 62 having a flat bag, and the bag is made of a chemical resistant sheet material. Such bags are variously used as containers for retort foods, for example, and thus detailed description thereof will be omitted.

A portion of the inner bag 62 is welded to the edge portion of the outer bag 61. The sterilizing raw material package 60 has a first inlet 63 in communication with the inside of the outer bag 61 and a second inlet 64 in communication with the inside of the inner bag 62. The 63 and 64 are heat-welded to be sealed to the outer periphery of the outer bag 61 and the outer periphery of the inner bag 62.

Inside the outer bag 61, a cutting tool 65 for cutting the inner bag 62 is incorporated. The cutting tool 65 has a lever 67 exerted by a spring 66, and when the lever 67 is pressed, the inner bag 62 can be cut by the cutting knife 68 installed on the lever 67. have.

The sterilizing raw material package 60 is a first in the outer bag 61 through the first and second inlets 63 and 64 in a state in which the index pin 69 is removed from the first and second inlets 63 and 64. After filling the component (preferably a buffer such as sodium hydrogen carbonate added thereto) or the second component, and also filling the other component into the inner bag 62, the index pin 69 is inserted into the first and second inlets. Insert into (63, 64) and close. This state is provided to the consumer.

The user who has obtained the sterilizing raw material package 60, for example, places the sterilizing raw material package 60 on the floor or the ground, and then steps on the cutting tool 65 with the foot on the outer bag 61. Therefore, at least a portion of the inner bag 62 is cut, and the components therein flow out into the outer bag 61 so that the first and second components are mixed in the outer bag 61 to generate sterilized water. The sterilizing water in the sterilizing raw material package 60 can be discharged by removing the water discharge pin 69 of the inlet 63 for the outer container.

In order to prevent the outer bag 61 from being damaged by the lever 67 or the like when the user steps on the sterilizing raw material package 60 by the foot, for example, the spring 66 is constituted by a bent pin to form the lever 67. When stepped on, the flexure pin 66 may be displaced outward to protect the outer envelope 61.

Seventh Embodiment (FIGS. 27, 28)

The sterilizing raw material package 70 of the seventh embodiment uses the inside of the inlet 63 of the outer bag 61 as the second hermetically sealed space. That is, the inlet 63 has a cylindrical shape, in which the inner container 71 of the cylindrical shape which has a bottom is accommodated, and the cutting tool of the state which cut | disconnected the cutting knife 72a down in the inner container 71 was carried out. 72 is housed.

The user who received the sterilizing material package 70 cuts the bottom of the inner container 71 by pressing the cutting tool 72 by removing the stopper ring 6 from the sealing cap 5 and then tightening the sealing cap 5 securely. do. Thereby, the first or second component in the inner container 71 can flow into the outer bag 61. In order to ensure such outflow, it is preferable to form the through hole 73 in the cutting tool 72.

As a modification of the sterilizing raw material package 70 of the seventh embodiment, it may be replaced by a lightweight plastic container without independence in place of the flexible outer bag 61. When using such a flexible outer bag 61 or a lightweight plastic container instead, it is desirable to provide the consumer with the sterilizing raw material package 70 contained in the stair container.

Example 8 (Fig. 29)

29 shows a sterilizing water generating kit according to the present invention as a fifth embodiment. The sterilizing water generating kit 80 includes a first bottle 81 containing a first component, a second bottle 82 containing a second component, and a third bottle 83 containing water, In addition, the manual 84 containing the precautions at the time of mixing preferably is included. It is preferable to apply a scale 85 to the first to third bottles 81 to 83. At least the first and second bottles 81 and 82 may be made of a plastic material having chemical resistance and light shielding properties.

The manual 84 describes, for example, the relationship between the amount of water, the amount of the first component, the amount of the second component, and the amount and concentration of the sterilizing water produced by mixing them. Then, a predetermined amount of water is introduced into the third bottle 83, and the predetermined amount of the first and second components are introduced into the third bottle 83 and the second bottle 82 to sterilize the water. Can be generated.

The third bottle 83 may be provided to the consumer in an empty state. The user who has received the sterilizing water generation kit 80 sees the manual and first inputs the prescribed amount of water into the third bottle 83 and then the first and second bottles 81 into the third bottle 83. , 82) may be added to generate sterilized water.

The sterilizing water generating kit 80 is preferably provided to the consumer in a state of being placed in the stairwell container 86, and is also good for the user who has obtained a lot of them to store in a warehouse, for example.

The pH adjusting liquid may be put in the third bottle 83. For example, a pH adjusting liquid such as dilute hydrochloric acid or dilute NaOH is placed in the third bottle 83 to store the sterilizing water generation kit 80 under poor environment, and when the user makes the sterilizing water, the pH of the sterilizing water is fine. The adjustment may be performed with the pH adjusting liquid of the third bottle 83. In addition, a buffer such as sodium hydrogencarbonate may be mixed into the first bottle 81 containing the first component. Instead, a fourth bottle containing bicarbonate (typically sodium hydrogen carbonate) or a carbon dioxide gas container is added to the sterilizing water generation kit 80 described above, whereby the fourth bottle of sodium hydrogen carbonate is added when the user makes the sterilizing water. It is preferable to add or mix the carbon dioxide gas in the carbon dioxide gas container with the first and second components.

Variation of Embodiment 8 (Figs. 30 to 32)

As illustrated in FIG. 30, the sterilizing water generating kit 80 includes a first and second bottles 81 and 82 containing first and second components and a manual 84, for example, a water-resistant bag. You may put it in 87 and give it to a consumer. The user who received this puts a predetermined amount of water into a suitable container according to the instruction of the manual 84, and then, adds the components of the first and second containers 81, 82 to sterilized water of a weakly acidic or neutral region of a predetermined concentration. Can be generated. In addition to the first component, sodium hydrogencarbonate may be contained in the first bottle 81. Instead, a third bottle (not shown) or a carbon dioxide gas container containing a buffer such as sodium hydrogen carbonate is added to the kit 80 so that the user can produce the sterilized water together with the first and second components. You may mix sodium or carbon dioxide.

As illustrated in FIG. 31, the sterilizing water generating kit 80 may constitute the first to third bottles 81 to 83 described above in a container divided into three inner spaces of one container, and this is a manual manual. (84) may be bonded, or a pocket may be formed in the three compartment container and provided to the consumer in the state where the manual 84 is accommodated in the pocket. As illustrated in FIG. 32, the sterilizing water generation kit 80 may constitute the first and second bottles 81 82 described above with a container in which the internal space of one container is divided into two. In addition, the manual 84 may be attached to the two compartment container.

In the case where the generated sterilized water is diluted and used by the user, when the water to be used is alkaline or acidic, it is preferable to provide the user with a container containing an acid or an alkali used to neutralize it. It is desirable to provide the user with a container with a buffer such as sodium or a carbon dioxide gas container.

A fourth bottle containing an alkali adjusting liquid (pH adjusting liquid) such as sodium hydroxide may be added to the sterilizing water generating kit 80 and variations thereof of FIGS. 29 to 32, and in addition to this, the pH of the litmus test paper is confirmed. You can add a means to do this. When the sterilizing water generation kit 80 is stored for a long time or stored in a poor environment, even when mixed as described in the manual 84, when the sterilizing water is considered to be acidic than pH 5, for example, the fourth bottle It is good to add the alkaline adjusting solution in water beforehand to make the sterilizing water while checking the pH by the pH checking means so that the pH of the sterilizing water can be adjusted to about 5.5.

It goes without saying that the present invention may arbitrarily combine various elements employed in the specific examples described above. For example, you may comprise the outer container 2, 21, 61, the inner container 23, or the thin plastic container which does not stand free from the 1st-3rd bottles 81-83.

In the above-mentioned various specific examples, since the generated sterilizing water becomes the pH of the neutral region or the weakly acidic region, it is possible to prevent the generation of toxic gases such as chlorine gas when the first and second components are mixed. In addition, since mixing operation is basically performed in the airtight container which tightened the airtight cap 5, it is safe without a user from touching a chemical | medical agent (1st, 2nd component).

In addition, sterilization with hypochlorous acid or chlorite is reported in yeast, Staphylococcus aureus, CNS, Bacillus bacillus, Micrococcus, Ashnetbacta, MRSA, etc. according to recent reports, for example, at pH 5.5 and effective chlorine concentration of 50 ppm It has been confirmed that it can be effectively sterilized. Therefore, if it is possible to easily sterilize with hypochlorous acid or chloric acid at any time and anywhere as in the specific example of the present invention, it is possible to cope with social problems such as hospital infection in hospital, etc. without introducing a special device immediately. .

In addition, so far, sterilization with neutral or weakly acidic hypochlorous acid or chlorine acid has not been available in a general household, but a specific example of the present invention can be provided to a consumer at low cost, so that a general consumer obtains it and easily Sterilization with chloric acid or chlorous acid can be performed. In addition, regular households can store this at all times, and each family can protect themselves from the outbreak of an outbreak such as SARS. Sterilization by hypochlorous acid is the same as the sterilization mechanism by neutrophils in the human body, as described above, so it is harmless to be injected into the human body through breathing or food. Therefore, a household humidifier (preferably an ultrasonic humidifier) can be used to spray sterilizing water in a room where a person is active, to sterilize the space, and also to exert a deodorizing effect, thereby deodorizing the room. Of course, it can also be used for cleaning and sterilization of ingredients and dishes in the mouth.

In addition, the military stores a specific example of the present invention for each camp, it is possible to respond to biological weapons terrorism or emergency medical activities.

In the sterilization using the specific example of this invention, the sprayer 90 is attached to the bottle inlet 24 of the bottle 21 used for mixing, as shown in FIG. 33, and this sprayer 90 is used, Sterilization water can be discharged. Sprayer 90 may spray sterilizing water in bottle 21 by pressing head 91. Further, sterilizing water can also be discharged using a nebulizer 93 of the type shown in FIG. The sprayer 93 illustrated in FIG. 34 can spray sterile water in the bottle 21 by pulling the handle 94. In addition, although the bottle 21 used as the specific example shown in FIG. 19 is shown in FIG. 33, FIG. 34, it is not limited to this.

The sprayers 90 and 93 illustrated in FIGS. 33 and 34 have a mist 96 using a cap 96 as shown in FIG. 36 while providing the mixing promoting member 95 shown in FIG. It is desirable to be able to control the state.

That is, the mixing facilitation member 95 has a turning confluence 95a at its distal end surface, and the sterilizing water pumped from the bottle 21 has two opposing cutouts 95b at the distal end surface of the mixing facilitating member 95. , 95b) flows into the turning confluence unit 95a, is mixed in the turning confluence unit 95a, and then discharged. In addition, the sterilized water discharged by adjusting the tightening amount of the cap 96 can be changed from a linear spray state to a mist state.

For example, the nebulizer 93 shown in FIG. 34 can be used for the treatment by attaching the enclosure cover 97 to this (refer FIG. 37). By adjusting the tightening amount of the cap 96 in accordance with the wound (U) state at the time of treatment and disinfecting the sterilizing water in a straight line form, it is possible to remove the sterilization and pus of the wound. The sterilized water after the treatment is sanitary if it is received by the support container 98.

Example regarding space sterilization

For example, when performing space sterilization in a hospital room in a hospital, it is preferable to spray sterilization water extensively without sound. 38 illustrates a portable indoor space sterilizer 100 suitable for this. The space sterilizer 100 has a tray 102 for receiving hypochlorous acid-containing sterilizing water contained in the cassette tank 101. The cap 103 of the cassette tank 101 has a movable pin 104, and the outlet of the cap 103 is opened by the operation of the movable pin 104. When the water level of the tray 102 goes down to the lower surface of the cap 103, air is blown into the cassette tank 101 through the cap 103, whereby the level of the tray 102 is kept constant. The tray 102 is arranged in the apparatus main body 105, and the sterilizing water in the tray 102 is atomized by the ultrasonic generator 106. The space sterilizer 100 has a main fan 108 arranged in an open space driven by an electric motor 107, and the main fan 108 and the motor 107 are arranged in an upper portion of the apparatus main body 105. Thus, the up and down direction can be adjusted about the axis 109.

The sterilized water atomized by the ultrasonic generator 106 passes through the first passage 110 extending upward from the apparatus main body 105, adjacent to the main fan 108, and carried forward. To facilitate this, a portion of the wind generated by the rotation of the main fan 108 is fed through the second passage 111 into the apparatus body 105, from the second passage 111 into the apparatus body 105. By using the supplied wind, the mist of the granulated sterilized water in the ultrasonic generator 106 is conveyed to the vicinity of the main fan 108.

The outlet 110a of the first passage 110 is preferably open toward the front, and the outlet 110a is preferably adjacent to the center of the main fan 108 and disposed in front of it. The position and direction of the outlet 110a may be adjusted by the pleat box 110b constituting part of the first passageway 110. The main fan 108 is preferably surrounded by a mesh 112 or the like to take safety measures.

The electric motor 107 and the ultrasonic generator 106 are controlled by the power supply part and the control part 113 accommodated in the apparatus main body 105.

According to the space sterilization apparatus 100, the main fan 108 installed in the open space makes it possible to spread the sterilization water widely without the sound of blowing, and thus applies to the space sterilization in the hospital room where the blowing sound has been a problem until now. It is possible. When the space sterilization of the room by the space sterilization device 100, the infection of the hospital can be prevented through the space sterilization in the room where the patient whose body is weakened without suffering from the sound of blowing air. The effect can also solve the odor problem of the room. By using the sterilizing material package or the sterilizing water generating kit of the present invention, sterilizing water for replenishing the cassette tank 101 can be easily made in the vicinity of the apparatus 100. In this case, the sterilizing water containing hypochlorous acid generated from the sterilizing raw material package or the sterilizing water generating kit may be put into the cassette tank 101 as it is, but the space sterilization may be performed. It is preferable to add into the cassette tank 101 after diluting properly. In addition, in the case of the sterilizing water generating kit, sterilizing water having a good concentration for space sterilization may be generated using the scale 85 and sprayed indoors using the space sterilizing apparatus 100. In addition, you may use the above-mentioned bottle 21 instead of the cassette tank 101. FIG.

In addition, you may employ | adopt a crossflow fan as the main fan 108 of the space sterilizer 100 (FIGS. 39 and 40). The cross flow fan forms a uniform average flow in a direction perpendicular to the suction direction of the gas as is known, and has a feature of low blowing sound. Further, a relatively small second electric fan is installed in the apparatus main body 105, and the mist of atomized sterilized water is conveyed to the vicinity of the main fan 108 by using the wind generated by the second electric fan, and the conveyed sterilized water It is also possible to spray the sterilizing water to a far place by entraining the mist of the air to the wind generated by the main fan 108.

In addition, in order to prevent excessive humidity in the room, a control mechanism is installed in the space sterilization apparatus 100, for example, spraying sterilizing water for 3 minutes and then spraying sterilizing water intermittently to stop the operation for 10 minutes. Is also ok. In addition, you may combine the spray control mechanism with the sensor which detects indoor humidity or temperature, for example, and may control spraying time and an operation stop time according to indoor humidity or temperature. In addition, it is also possible to combine a control pattern programmed in advance and control the spray time and the operation stop time by varying the control pattern.

The hypochlorous acid-containing sterilizing water contained in the cassette tank 101 of the space sterilizer 100 is not particularly limited, but an effective chlorine concentration of 50 to 200 ppm is suitable.

Although the above-described space sterilizer 100 exemplifies a portable device, for example, the space sterilizer 100 may be a fixed type receiving sterilized water through a pipe. In this case, it is preferable to design so that the sterilizing water can be supplied to the ultrasonic generator 106 so that the supply form by the piping and the supply form by the cassette tank 101 can be selected arbitrarily.

39 and 40 show a space sterilization apparatus 120 in which a supply form by a cassette tank (FIG. 39) and a supply form by a pipe (FIG. 40) can be selected according to the accessory to be mounted. The first and second accessories 122 and 123 can be selectively mounted on the outer case 121. When the first accessory 122 is mounted as shown in FIG. 39, the cassette 122 is removed by removing the cover 122a. The tank 101 can be taken out. On the other hand, when the second accessory 123 is mounted, the sterilizing water can be supplied through the pipe 124 (FIG. 40). Reference numeral 125 in FIG. 40 denotes an electronic on-off valve, and 126 denotes a water level sensor. The water level of the sterilizing water is maintained substantially constant by the water level sensor 126 and the electronic closing valve 125.

39 and 40, a cross flow fan is employed as the main fan 108, and a louver 127 is provided in the air blower 108a of the main fan 108. By adjusting the direction of the louver 127, the direction of the wind generated by the main fan 108 may be changed. The vent 108a of the main fan 108 faces the open space so that there is no blow duct. The outer case 121 has an air inlet 128, and the air inlet 128 is preferably equal to or larger than the opening area of the blower 108a.

The space sterilizer 120 shown in FIGS. 39 and 40 is provided with a second electric fan 130, and the mist of the sterilized water atomized by the second electric fan 130 is near the main fan 108. Is returned.

The space sterilizers 100 and 120 provided with the main fan or the cross flow fan 108 shown in FIGS. 38 to 40 may include an electrolytic sterilization water generating mechanism. FIG. 41 illustrates a space sterilization apparatus 135 having an electrolytic sterilization water generating mechanism. The space sterilizer 135 contains hydrochloric acid (HCl) diluted with water in the removable cassette tank 101, and hypochlorous acid (HClO) is generated by passing hydrochloric acid through the electrolytic unit 136 without a diaphragm. The electrolytic unit 136 has a plus pole 137 and a minus pole 138 composed of two cylindrical metal pipes of different diameters (for example, a pipe plated with titanium material). The electrolytic unit 136 preferably has a heat dissipation or cooling mechanism 139, and preferably suppresses heat generation of the electrolytic unit 136 by the heat dissipation or cooling mechanism 139. For example, a corrosion resistant plate (for example, titanium plate) 139a and a Peltier element 139b which are arranged to penetrate into the electrolytic unit 136 as a heat dissipation or cooling mechanism 139 and are excellent in heat transfer are employed as a set. The electrolytic unit 136 can be cooled without any sound.

According to the electrolytic space sterilizer 135, since the salt is not substantially contained in the atomized sterilized water to be sprayed, it is suitable for space sterilization in a hospital. The cooling method of the electrolytic section 136 is not limited to the Peltier element 139b but may be air-cooled or water-cooled.

Various variants

As mentioned above, although the specific example of this invention was described, this invention is not limited to this specific example. For example, as shown in FIG. 42, the inner container 23 installed in the bottle 21 is held by the upper end of the bottle inlet 24, and the upper and lower two parts fitted to the sleeve 140 are supported. In the two plugs 142 and 143, a sealed space may be provided between the two plugs 142 and 143, and the sealed space may be used as the inner container 23. To open the inner container 23, for example, the two plugs 142, 143 are connected to each other by a shaft 144 extending up and down, and sealed for example by a sealing cap 5 for pressing the shaft 144. What is necessary is just to provide the rod 145 suspended by the cap 5. As shown in FIG. 42, the rod 145 may have a structure separate from the sealing cap 5, or may be a structure integral with the sealing cap 5. When the stopper ring 6 is removed and the sealing cap 5 is firmly tightened to lower the rod 145, the plugs 142 and 143 are pressed to lower the plug 143 from the lower end of the sleeve 140 to release the sleeve 140. The component in the c) flows into the bottle 21.

The configuration of forming the inner container by using the detachable plug 142 described with reference to FIG. 42 can be applied to the inner container 71 disposed at the inlet 63 of the outer bag 61 shown in FIGS. 27 and 28. have. That is, as shown in FIG. 43, the plug 142 is inserted into the lower end passage of the sleeve constituting the side wall of the inner container 71, and the plug 142 is pressed by the rod 145 associated with the sealing cap 5 to the inside. The container 71 may be opened. The plug 142 is preferably fitted by sealingly sealing the lower inner peripheral surface and / or lower outer peripheral surface of the sleeve constituting the side wall of the inner container (71).

44 shows an example of means for preventing the plug 142 from unintentionally leaving the inner container 23. In the example of FIG. 44, the rod 145 is fixed to the plug 142, and the end of the arm 148 integral with the rod 145 spans the stepped portion 149 of the sleeve 140. Therefore, the arm 142 functions as a stopper that regulates the downward movement of the rod 145, thereby preventing the unintentional downward movement of the rod 145, thereby avoiding the dropping accident of the plug 142. have. In addition, the weaker portion 150 (eg, for example) may be removed from a portion of the arm 142 so that the stopper ring 6 and the tight cap 5 are firmly tightened so as not to interfere with the regular mixing operation of lowering the rod 145. It is preferable to form the arm 142 and the connecting portion of the rod 145 so as to break or bend at the weak portion of the arm 142 when the sealing cap 5 is tightly tightened.

In addition, FIG. 44 has shown that the relief valve 152 is provided in the sealing cap 5 which comprises the cap of the inner container 23 substantially. When the internal pressure of the inner container 23 rises, the relief valve 152 opens, and the pressure of the inner container 23 can be kept substantially constant. By installing a pressure adjusting means such as a relief valve 152 in the inner container 23, for example, when oxygen gas is generated from sodium hypochlorite and the internal pressure of the inner container 23 rises, the plug 142 is operated by the internal pressure. Pressing may prevent the plug 142 from falling off.

The pressure release means shown in Fig. 44 is composed of a ball and a spring, but instead of this, the gas inside the inner container 23 may be discharged to the atmosphere through the gas-liquid separation membrane using a gas-liquid separation membrane, or a flexible packing having cushioning performance ( For example, a packing made of a flexible resin of an independent bubble may be used as a sealing material of the sealing cap 5 to adjust the degree of compression of the packing so as to block the passage of liquid from which gas leaks.

From the other point of view, the modification shown in FIG. 42 described above comprises the inner container 23 composed of two members (the first member 140 and the second member 144, 142, 143) capable of relative displacement, The inner container 23 is opened by displacing the other members 144, 142, and 143 while the one member 140 is fixed to the outer container 21 so that the components in the inner container 23 are replaced with the outer container ( 21) It is supposed to spill into. Another specific example in accordance with this aspect is shown in FIGS. 45 and 46.

45 is a second member 150 having a sleeve 140 (first member) fixed to an outer container, that is, a bottle 21, and two flanges 142, 143 spaced up and down. The inner container 23 is formed by fitting the second member 150 into the sleeve 140.

When the stopper ring 6 is removed and the sealing cap 5 is tightly lowered to lower the rod 145, the second member 150 is pressed by the rod 145, and as a result, a part of the inner container 23 is closed. The component in the inner container 23 is opened to flow into the bottle 21. As shown in FIG. 45, if the main body 152 of the 2nd member 150 is cylindrical, it is good to form a through-hole as shown with the reference numeral 152. As shown in FIG.

46, the second member 150 is positioned outside the sleeve 140, the lower end of the cylindrical body 151 of the second member 150 is closed by the bottom 155, and the bottom ( 155 abuts against the sleeve 140. And the upper end of the cylindrical body 151 has an inner flange 156, the inner end of the inner flange 156 is hermetically in contact with the sleeve 140, thereby the inner container 23 on the outside of the sleeve 140 ) Is formed.

When the stopper ring 6 is removed and the sealing cap 5 is tightened to lower the rod 145, the second member 150 is pressed by the rod 145, resulting in the bottom 155 of the second member 150. ) Is spaced apart from the lower end of the sleeve 140 to open a portion of the inner container 23 so that the components in the inner container 23 flow into the bottle 21.

As shown in Figs. 47 to 50 with respect to the cutting aid 26 included in specific examples such as Fig. 16, the recess 26b is formed on the upper portion thereof, and the powdered sodium hydrogen carbonate is formed on the recess 26b. It is okay to accept. When the pusher 41 is pressed after the stopper ring 42 is removed, the cutting aid 26 is forced to move downward to cut the horizontal end 23b of the inner container 23 so that the inner container 23 falls. The cutting aid 26 also falls into the bottle 21 (FIG. 48). Therefore, in addition to the component accommodated in the inner container 23, sodium hydrogencarbonate accommodated in the recessed part 26b of the cutting aid 26 flows into the bottle 21, and sodium hydrogencarbonate in the bottle 21 is carried out. Three components, including, may be mixed to produce sterile water including sodium hydrogen carbonate as a buffer.

The cutting knife 26a formed at the lower end of the cutting aid 26 preferably has an inclined outline as understood from FIG. 47. Moreover, it is preferable that the cutting knife 26a is equipped with the sharp tip part 26c which protrudes toward the lower part at the lowest end. If the cutting aid 26 with the cutting knife 26a can be enjoyed by the pusher 41, the sharpest tip 26c at the lowermost end enters the horizontal end 23b of the inner container 23 and removes a part thereof. After penetrating, the horizontal end 23b is sequentially entered by the cutting knife 26a of the inclined outline, and finally the entire horizontal end 23b is cut off. Therefore, the cutting of the inner container 23 by the cutting knife 26a is assured, and the force required for cutting can be reduced.

When the sodium hypochlorite is accommodated in the inner container 23, if it is necessary to discharge the gas generated from sodium hypochlorite to the outside while storing the bottle 21, the cutting aid 26 is illustrated as shown in FIG. The through hole 160 is formed in the bottom portion of the recessed portion 26b, and the second through hole 161 is also formed in the pusher 41 serving as a lid of the recessed portion 26b. You can also release the gas to outside through). Reference numeral 163 in FIG. 51 denotes a first gas permeable membrane blocking the first passage hole 160, and 164 denotes a second gas permeable membrane blocking the second passage hole 161.

As a modification of FIG. 51, as shown in FIG. 52, the cylindrical gas discharge | emission path 166 which penetrates the center part of the cutting aid 26 from the center part of the pusher 41, and extends downward is formed, The gas discharged by sodium hypochlorite in the inner container 23 may be discharged to the outside through the gas discharge passage 166. Reference numeral 167 in FIG. 52 denotes a check valve.

Buffering

Figure 53 shows the change in pH value by mixing hydrochloric acid with sodium hypochlorite. The table shows the pH value when hydrochloric acid is mixed in an aqueous solution containing sodium hypochlorite and sodium hydrogen carbonate, and the table ▲ shows the pH value when hydrochloric acid is mixed with sodium hypochlorite. Each component used in this experiment is as follows.

(1) 250 ml of tap water

(2) 0.4 ml of sodium hypochlorite (concentration 12%)

(3) hydrochloric acid (concentration 7.2%)

(4) sodium hydrogencarbonate 0.3g

When sampling the data in the table, hydrochloric acid is added to the aqueous solution of sodium hypochlorite and sodium bicarbonate in tap water little by little to measure the pH change in the sterilized water. When sampling the data in the table, hydrochloric acid is added little by little to an aqueous solution containing sodium hypochlorite in tap water to measure the change in pH of sterilized water.

As can be understood from FIG. 53, it can be seen that in the experiment without adding sodium hydrogen carbonate, the pH value of the sterilized water is rapidly lowered to a strongly acidic region sensitively to the increase in the amount of hydrochloric acid. In particular, it sharply falls from pH6 to pH3 at once. In the experiment in which sodium hydrogen carbonate was added, the decrease in the pH value of the sterilized water is suppressed, and it can be seen that the decrease to pH of about 5 is particularly slow. Those skilled in the art will readily understand that it is easy to add sodium hydrogen carbonate to add hydrochloric acid to sodium hypochlorite to adjust the pH value of the sterilized water to be neutral or weakly acidic. In addition, the pH variation of the generated sterilized water can be suppressed. In addition, even when the produced sterilized water is diluted with water and used, for example, if the water to be used is, for example, an alkaline well water, the same buffering effect can be obtained by adding an acid such as hydrochloric acid together with a buffer such as sodium bicarbonate. Can be obtained. In addition, a buffering effect may be obtained by adding carbonic acid gas or high concentration of carbonated water to the generated sterilized water.

Claims (35)

A first component containing hypochlorite or chlorite and contained in a first confined space, Preparing a second component containing an acid and contained in a second confined space, Sterilizing water is produced by mixing the first component and the second component, A method for producing sterilized water by hypochlorous acid or chlorite, wherein the first component and the second component are mixed so as to produce sterilized water in a weakly acidic or neutral region having a predetermined effective chlorine concentration. The method according to claim 1, A buffer having bicarbonate is contained in the first confined space together with the first component. The method according to claim 1, Further preparing a third component containing a buffer with bicarbonate and contained in a third confined space, A method of producing sterilized water by hypochlorous acid or chlorochloric acid, wherein the third component is contained and mixed when the first component and the second component are mixed. The method according to any one of claims 1 to 3, Predetermined effective chlorine when the said 1st component and the said 2nd component mixed the whole amount of the said 1st component accommodated in the said 1st sealed space, and the whole amount of the said 2nd component accommodated in the said 2nd sealed space. A method for producing sterilized water by hypochlorous acid or chloric acid, characterized in that it is adjusted to generate sterilized water in a weakly acidic or neutral region of concentration. The method according to claim 1, The first sealed space is formed by a first container, The second sealed space is formed by a second container, the method for producing sterilized water by hypochlorous acid or chlorous acid. The method according to claim 1, The first sealed space and the second sealed space is formed in a single container, the method for producing sterilized water by hypochlorous acid or chlorochloric acid. The method according to any one of claims 1 to 4, The method of producing sterilized water by hypochlorous acid or chlorous acid, wherein the first component is an alkaline liquid having a pH of 10 or more. A first component containing hypochlorite or chlorite and contained in a first confined space, Preparing a second component containing an acid and contained in a second confined space, Sterilizing water is produced by mixing the first component and the second component with a predetermined amount of water, Of the sterilized water by hypochlorous acid or chlorine acid, which is adjusted to produce a sterilized water of a weakly acidic region or a neutral region of a predetermined effective chlorine concentration when the first component and the second component are mixed with the predetermined amount of water. How to create. The method according to claim 8, A buffer having bicarbonate is contained in the first confined space together with the first component. The method according to claim 8, Further preparing a third component containing a buffer with bicarbonate and contained in a third confined space, A method of producing sterilized water by hypochlorous acid or chlorous acid, wherein the third component is contained and mixed when the first component and the second component are mixed with water. The method according to claim 8, Further prepare a manual containing the amount of water, The first component and the second component are introduced into the predetermined amount of water described in the manual according to the manual, and the method for producing sterilized water by hypochlorous acid or chlorous acid. A first component containing hypochlorite or chlorite, A second component containing an acid, A single container separated and partitioned into partitions to prevent the first component and the second component from mixing, and And a displacement member that is displaceable by applying an artificial force outside of the container, The first component and the second component may be mixed in the vessel by the displacement of the displacement member to produce sterile water, A sterilizing raw material package which is adapted to generate a sterilized water of a weakly acidic region or a neutral region having a predetermined effective chlorine concentration when the first component and the second component are mixed with these. The method according to claim 12, Further comprising a third component containing a buffer having a bicarbonate, The first component, the second component, and the first component, the second component and the third component are separated into partition walls so as not to mix with each other, and the force is applied to the displacement member to displace the displacement member. A sterilizing raw material package, characterized in that a third component is mixed in the container to produce sterilizing water. The method according to claim 12, And the displacement member has a blade, and the partition wall is torn with the blade to mix the first component and the second component. An outer container containing either the first component containing hypochlorite or chlorite or the second component containing acid, An inner container housed in the outer container to accommodate the other of the first component or the second component; A sealing member for sealing the inner container, and An operation member installed in relation to the outer container and accessible from the outside of the outer container, By operating the operating member, the inner container can be released from the sealing member so that the other component in the inner container flows into the outer container to generate sterilized water, A sterilizing raw material package which is adapted to generate sterilizing water in a weakly acidic region or a neutral region having a predetermined effective chlorine concentration when the first component and the second component are mixed with these. The method according to claim 15, The inner container has first and second spaces independent of each other, The first component or the second component is accommodated in the first space, Sterilizing raw material package, characterized in that the buffer containing the bicarbonate is accommodated in the second space. The method according to claim 15 or 16, The sterilizing raw material package, characterized in that the operation member contains a closed cap of the outer container. The method according to claim 15 or 16, A sterilizing raw material package, characterized in that the operation member has a pusher having a portion exposed from the outer container. The method according to claim 15 or 16, The outer container has an inlet, Sterilization raw material package, A circumferential sealing member provided inside the inlet; A movable member having a circumferential groove sealed with the circumferential sealing member, and Further comprising a closure cap for closing the inlet, The inner container is constituted by the circumferential groove of the movable member, And the movable member is lowered by operating the closure cap and the circumferential groove is released from the sealing member so that the other component in the circumferential groove flows out into the outer container. An outer container containing either the first component containing hypochlorite or chlorite or the second component containing acid, An inner container housed in the outer container to accommodate the other of the first component or the second component; A plug formed in the inner container and inserted into a passage communicating with an inner space of the outer container; Accessible from the outside of the outer container and provided with an operation member associated with the plug, By intentionally operating the operating member, the plug is released from the passage of the inner container in connection with the movement of the operating member, and the other component in the inner container is discharged into the outer container. You can create A sterilizing raw material package which is adapted to generate a sterilized water of a weakly acidic region or a neutral region having a predetermined effective chlorine concentration when the first component and the second component are mixed with these. The method according to claim 21, The sterilizing raw material package, characterized in that the operation member contains a closed cap of the outer container. An outer container containing either the first component containing hypochlorite or chlorite or the second component containing acid, A sterilizing raw material package having an inner container housed in the outer container and containing the other of the first component or the second component, The inner space of the inner container is formed of a first member fixed to the outer container and a second member relatively movable relative to the first member, An operation member associated with the second member that is accessible from the outside of the outer container, By deliberately manipulating the operating member to move the second member in relation to the movement of the operating member to open a portion of the inner container, and to drain the other component in the inner container into the outer container. Can generate sterile water, A sterilizing raw material package, characterized in that the first component and the second component are adjusted to produce sterilized water in a weakly acidic region or a neutral region having a predetermined effective chlorine concentration when these are mixed. The method according to claim 22, The sterilizing raw material package, characterized in that the operation member contains a closed cap of the outer container. An outer container having an inlet for an outer container and containing either a hypochlorite or a first component containing chlorite or a second component containing an acid; An inner container having an upper opening open upwardly, the upper opening being held in the outer container in combination with the inlet for the outer container, the inner container containing the other of the first component or the second component, And A closing cap for closing the inlet for the outer container and closing the top opening of the inner container, Peel off the sealing cap and press the upper opening of the inner container to release the coupling of the upper opening and the inlet for the outer container to drop the inner container into the outer container so that the other side of the inner container Sterilizing water can be produced by pouring a component into the outer container, A sterilizing raw material package which is adapted to generate sterilizing water in a weakly acidic region or a neutral region having a predetermined effective chlorine concentration when the first component and the second component are mixed with these. The method of claim 24, The inner container is a sterilized raw material package, characterized in that at least the top opening is made of a soft material that can be easily bent and deformed by the force of the finger. An outer container having an inlet for an outer container and containing either a hypochlorite or a first component containing chlorite or a second component containing an acid; An inner container having an upper opening open upwardly, the upper opening being supported in the outer container by engaging the inlet for the outer container, the inner container containing the other component of the first component or the second component, And A closing cap for closing the inlet for the outer container and closing the top opening of the inner container, The sterilizing water can be generated by removing the sealing cap and taking the inner container out of the outer container to introduce the other component in the inner container into the outer container, A sterilizing raw material package which is adapted to generate a sterilized water of a weakly acidic region or a neutral region having a predetermined effective chlorine concentration when the first component and the second component are mixed with these. A first container containing either a first component containing hypochlorite or chlorite or a second component containing an acid; A second container accommodating the other component of the first component or the second component, and And a manual describing the amount of the first component, the amount of the second component, and the amount of water to mix the first and second components, Sterilizing water can be generated by mixing the first and second components in a predetermined amount of water according to the instructions of the manual, A sterilizing water generation kit adapted to generate sterilizing water in a weakly acidic region or a neutral region of a predetermined effective chlorine concentration when the first component and the second component are mixed with the predetermined amount of water. An ultrasonic generator for atomizing hypochlorous acid-containing sterilizing water in a weakly acidic or neutral region having an effective chlorine concentration suitable for space sterilization; Electric main fan which blows toward open space, and And a second electric fan for conveying the mist of the atomized sterilized water generated by the ultrasonic generator to the vicinity of the main fan, Space sterilizer for spraying the mist of the atomized sterilized water to the wind generated by the main fan. The method according to claim 28, The hypochlorous acid-containing product produced by the user mixing a first component contained in a first confined space and containing a pre-adjusted concentration of hypochlorite and a second component containing an acid of a preset concentration and contained in a second enclosed space. Further provided with a cassette tank for accommodating sterilized water, And sterilizing water supplied from the cassette tank by atomizing the ultrasonic generator. The method of claim 29, And the space sterilization device selects the supply type of the sterilizing water by the cassette tank and the supply type by the pipe. Suitable for space sterilization produced by the user by mixing a first component contained in a first confined space with a hypochlorite of a predetermined concentration and a second component containing an acid of a preconcentrated concentration contained in a second confined space. A cassette tank capable of containing sterilized water in a weakly acidic or neutral region of effective chlorine concentration, An ultrasonic generator for atomizing the sterilizing water supplied from the cassette tank; Electric main fan which blows toward open space, and And a second electric fan for conveying the mist of the atomized sterilized water generated by the ultrasonic generator to the vicinity of the main fan, Portable space sterilizer for spraying the mist of the atomized sterilized water to the wind generated by the main fan. The method according to claim 31, Space mixing apparatus characterized in that when mixing the first component and the second component or after mixing the first component and the second component diluted with water to produce sterilized water of effective chlorine concentration suitable for space sterilization. The method according to claim 31 or 32, And said main fan and said second electric fan are common electric fans. Effectiveness suitable for space sterilization by the user mixing the first component contained in the first confined space and containing the preset concentration of hypochlorite and the second component containing the acid in the second confined space and adjusted in the second confined space. Sterile water generation process for generating sterile water in a weakly acidic or neutral region of chlorine concentration, Sterilizing water receiving step of receiving the sterilizing water generated in the sterilizing water generating step in the tank, A sterilizing mist generating step of atomizing the sterilizing water supplied from the tank to generate a flow of mist of the sterilizing water; A guide step of guiding the flow of mist of the sterilizing water to the vicinity of the main fan blowing toward the open space, and And a sterilizing water spraying step of spraying the sterilizing water far away by entraining the mist flow of the sterilizing water guided to the vicinity of the electric fan to the wind generated by the main fan. The method of claim 34, wherein And mixing water to dilute when the first component and the second component are mixed or after mixing the first component and the second component.

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