KR20040043502A - Manufacturing method of porous magnetic minerals - Google Patents
Manufacturing method of porous magnetic minerals Download PDFInfo
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- KR20040043502A KR20040043502A KR1020020071778A KR20020071778A KR20040043502A KR 20040043502 A KR20040043502 A KR 20040043502A KR 1020020071778 A KR1020020071778 A KR 1020020071778A KR 20020071778 A KR20020071778 A KR 20020071778A KR 20040043502 A KR20040043502 A KR 20040043502A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
- C04B38/0605—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances by sublimating
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/36—Inorganic materials not provided for in groups C04B14/022 and C04B14/04 - C04B14/34
- C04B14/363—Ferrites
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/08—Acids or salts thereof
- C04B22/12—Acids or salts thereof containing halogen in the anion
- C04B22/124—Chlorides of ammonium or of the alkali or alkaline earth metals, e.g. calcium chloride
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0097—Anion- and far-infrared-emitting materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00422—Magnetic properties
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Physical Water Treatments (AREA)
- Biological Treatment Of Waste Water (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
Description
본 발명은 천매암(千枚岩), 맥반석(飯石), 전기석(Tourmaline), 의왕석(王石), 태징석(泰澄石) 등과 같이 원적외선(遠赤外線) 및 음이온(陰 Ion)을 발생하는 광물의 분말과 페라이트(Ferrite ; MOㆍnFe₂O₃ ; M= Fe, Ba, Sr 등)분말을 혼합한 다음에 이들에 바인더(Binder), 기포발생제 등을 주입하고, 교반혼합하여 반죽을 만든 다음 구상(球)이나 환상의 펠렛트(Pellet) 형태로 가공한 다음에 건조 소성 후 착자(着磁)하여 자화(磁化)미네랄(Minerals)수의 제조, 미생물배양공정, 수경재배의 충진제 등에 사용하는 다공질자성광물(多孔質磁性物)의 제조하는 방법을 제시 한다.The present invention is a cheonmaeam (千 枚 岩), elvan Stone, Tourmaline, Uiwang Stone A mixture of ferrite powders and mineral powders that generate far infrared rays and anions such as wangseok, tajingstone, etc., and ferrite (MO, nFe₂O₃; M = Fe, Ba, Sr, etc.) Next, binders, bubble generators, and the like are injected into the mixture, and the mixture is stirred and mixed to form a dough. Porous minerals used in the manufacture of magnetized mineral water, microbial culture process, hydroponic filler, etc. (多孔 質 磁性 The preparation method of the article is presented.
일본 특허공보 평() 6-9280호에서는 연질다공성고대해양성부식질(軟質多孔性腐植質)을 Si6O8와 혼합해서 입상(粒),구상(球) 또는 환상(環)으로 성형가공 후 전기로에서 1000℃이상으로 소결(結)하여 다공질의 물질로 만든 것을 바이오세라믹(Bio-ceramics)이라하여, 토양개량제, 수질정화제 등으로 사용하였으나,자철광 함량이 낮거나 보자력(保磁力)이 낮은 경우에는 미생물의 대사활동이 활발하지 못하는 문제점이 있었다.Japanese Patent Publication In 6-9280, soft porous ancient oceanic corrosives were mixed with Si 6 O 8 and granulated. ), Concept ) Or illusion ) After sintering at 1000 ℃ in electric furnace 結) It is made of porous material and called bio-ceramics, and it is used as soil modifier and water purifying agent, but metabolic activity of microorganism is not active when magnetite content or low coercive force is low. There was a problem.
본 발명의 목적은 미생물배양공정, 자화미네랄수의 제조공정, 수경재배의 충진제 등에 사용하는 다공질자성광물을 제조하는 방법을 제시하는 것이 목적이다.An object of the present invention is to provide a method for producing a porous magnetic mineral used for microbial culture process, manufacturing process of magnetized mineral water, filler for hydroponic cultivation.
이와 같은 목적을 달성하기 위한 본 발명은, 원적외선 및 음이온을 발생하는 광물과 자성물질의 분말을 혼합한 것에 바인더, 기포발생제 등을 주입하고 교반 혼합하여 반죽을 만든 다음에 구상이나 환상의 펠렛트 형태로 가공한 다음 건조 소결 후 착자하여 원적외선 및 음이온을 발생하면서 자성을 띠는 다공질자성광물을 제조한다.In order to achieve the above object, the present invention is to inject a mixture of minerals and magnetic materials generating far-infrared rays and anions into the powder of a magnetic material, and then to inject and stir the mixture to form a dough, and then spherical or annular pellets. After processing to form and dried and sintered and magnetized to produce a magnetic magnetic porous mineral while generating far-infrared rays and anions.
본 발명에서는 미생물배양공정, 자화미네랄수의 제조공정, 수경재배 등에 사용하는 원적외선(遠赤外線) 및 음이온 등을 발생하면서 자성을 띠는 다공질자성광물(多孔質磁性物)의 제조방법을 상세히 설명하면 다음과 같다.In the present invention, a porous magnetic mineral having magnetic properties while generating far-infrared rays and anions used in microbial culture process, manufacturing process of magnetized mineral water, hydroponic cultivation, etc. Referring to the manufacturing method of the material in detail as follows.
1. 천매암(千枚岩), 전기석(Tourmaline), 맥반석(飯石), 의왕석(王石), 태징석(泰澄石), 옥(玉)과 같이 원적외선(遠赤外線) 및 음이온을 발생하는 광물의 40∼60 μm 정도의 분말에 4,3 산화철(Fe₃O₄;자철광), 바륨페라이트(Barium ferrite ; BaOㆍ6Fe₂O₃), 스트론튬페라이트(Strontium ferrite ; SrOㆍ6Fe₂O₃)와 같은 페라이트(Ferrite) 자성물질의 40∼60 μm 정도의 분말을 10∼50wt% 정도의 비율로 주입하여 교반 혼합한다.1. Aphrodite, Tourmaline, Elvan 飯 石, Uiwang Stone 40 to 60 μm powder of minerals generating far-infrared rays and anions, such as Wang, Tajing Stone and Jade, and Fe, O3, and barium ferrite Ferrite (40-60 μm) powders of ferrite magnetic materials such as ferrite (BaO · 6Fe₂O₃) and strontium ferrite (SrO · 6Fe₂O₃) are injected at a ratio of about 10 to 50 wt% and stirred and mixed.
2. 1항에 물을 주입하여 반죽이 용이하게 함수율을 35∼45wt% 정도로 조정한다.2. Add water to 1 to adjust the moisture content to 35 ~ 45wt% easily.
3. 2항에 무기바인더(Binder)로 벤토나이트(Bentonite), 소석회, 돌로마이트(Dolomite) 등을 단독 또는 2종류 이상 혼합한 것을 0.1∼0.5wt% 정도 주입하고, 유기바인더로 수용성 전분, 당밀, 알긴산나트륨(Sodiom alginate), 알긴산암모늄(Ammomium alginate), 덱스트린(Dextrin) 등을 몇 종류 혼합한 것을 0.03∼0.04wt% 정도 주입하고, 규산나트륨(Sodium silicate)을 0.1∼1.0wt% 정도 주입하여 교반 혼합한다.3. Use 0.1 to 0.5 wt% of Bentonite, Slaked Lime, Dolomite, etc. alone or a mixture of two or more kinds with an inorganic binder, and add water-soluble starch, molasses, alginic acid to the organic binder. A mixture of some types of sodium (Sodiom alginate), ammonium alginate, dextrin, and the like is infused about 0.03 to 0.04 wt%, and sodium silicate is infused by about 0.1 to 1.0 wt%, followed by stirring and mixing. do.
4. 3항에 염화암모늄(NH₄CI)을 미세한 기공을 형성하기 위해서 2∼5wt% 정도 주입하고 교반 혼합하여 반죽을 만든다.4. Add ammonium chloride (NH₄CI) in 2 to 5wt% to form fine pores and stir and mix to make dough.
5. 4항의 반죽을 구상이나 환상의 펠렛트(Pellet)으로 가공한 다음 4∼5일 정도 자연건조 한다.5. Process the dough of No. 4 into spherical or annular pellet and dry it naturally for 4 ~ 5 days.
6. 5항의 자연 건조된 펠렛트를 180∼250℃의 열풍에 의해서 함유된 수분을 증발한다.6. The naturally dried pellets of item 5 are evaporated by the hot air of 180 to 250 ° C.
7. 6항의 함유수분의 증발이 완료되면 온도를 250∼400℃로 상승하게 되면 결합수분이 증발되며, 이때(337∼338℃부근의 온도)염화암모늄(NH₄CI)이 NH₃ 및 HCI 가스(Gas)로 승화 분해 되면서 미세한 기공이 형성 된다.7. After the evaporation of the water content in Clause 6 is completed, the temperature rises to 250 ~ 400 ℃, and the combined moisture evaporates (at temperatures around 337 ~ 338 ℃) .Ammonium chloride (NH₄CI) is used for NH3 and HCI gas As the sublimation decomposes, fine pores are formed.
8. 7항의 결함수분이 증발제거 및 미세기공 형성이 완료되면 온도를 950∼1,100℃로 예열조작 후 1,250∼1,350℃에서 10∼15분 정도 소성(成)한 다음 서서히 냉각하여 펠렛트상의 다공질광물을 만든다.8. When the defective moisture of paragraph 7 is evaporated and the micropores are completed, the temperature is preheated to 950-1,100 ℃, and then fired at 1,250-1,350 ℃ for 10-15 minutes. And then slowly cooled to form pelleted porous minerals.
9. 8항의 다공질광물을 착자기(着磁器)에서 자속밀도(Magnetie flux density)가 300G(Gauss)이상으로 착자하여 자성을 띠면서 원적외선 및 음이온을 발생하는 다공질자성광물이 제조된다.9. A porous magnetic mineral is produced by magnetizing the porous mineral of paragraph 8 in a magnetizer with a magnetic flux density of more than 300 G (Gauss), producing magnetic and far-infrared rays and anions.
전술한 기술내용으로부터 자명하듯이, 본 발명의 원적외선 및 음이온을 발생하는 다공질자성광물은 하ㆍ폐수의 생물학처리, 생물학적탈취처리, 가축음용수처리 등의 미생물배양공정, 수경재배의 충진제, 미네랄수의 제조공정 등에 사용하였을 때 효율이 우수하기 때문에 이들 분야에 널리 보급 될 것으로 기대된다.As is apparent from the above description, the porous magnetic minerals generating far-infrared rays and anions of the present invention include microbial culture processes such as biological treatment of sewage and wastewater, biological deodorization treatment, livestock drinking water treatment, fillers for hydroponic cultivation, and mineral water. It is expected to be widely used in these fields because of its efficiency when used in manufacturing processes.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1768932A1 (en) * | 2004-07-06 | 2007-04-04 | Byung Kul Lee | Water purifier |
KR100880047B1 (en) * | 2006-07-06 | 2009-01-22 | 김동현 | Processed porous gemstones and preparation methods thereof, and drain pipes having a mixture of these porous gemstones attached therein |
KR100888059B1 (en) * | 2008-05-15 | 2009-03-11 | 이은희 | Charcoal powder paint composition |
CN103289643A (en) * | 2013-06-14 | 2013-09-11 | 邬汝源 | Negative oxygen ion hard porous material body and production method thereof |
CN103289642A (en) * | 2013-06-14 | 2013-09-11 | 邬汝源 | Negative oxygen ion porous soft material body and production method thereof |
KR101329637B1 (en) * | 2010-12-06 | 2013-11-27 | 이학섭 | bio-soil for sewage using natural meterials and the manufacture method amd manufacture device |
CN104844102A (en) * | 2015-03-30 | 2015-08-19 | 上海轩颂建筑装饰有限公司 | Anion heat-insulating material |
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WO1996020018A1 (en) * | 1994-12-27 | 1996-07-04 | Minato Company Ltd. | Deodorizing composition and deodorizing resin composition both containing iron (ii) compound |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1768932A1 (en) * | 2004-07-06 | 2007-04-04 | Byung Kul Lee | Water purifier |
EP1768932A4 (en) * | 2004-07-06 | 2009-09-02 | Byung Kul Lee | Water purifier |
KR100880047B1 (en) * | 2006-07-06 | 2009-01-22 | 김동현 | Processed porous gemstones and preparation methods thereof, and drain pipes having a mixture of these porous gemstones attached therein |
KR100888059B1 (en) * | 2008-05-15 | 2009-03-11 | 이은희 | Charcoal powder paint composition |
KR101329637B1 (en) * | 2010-12-06 | 2013-11-27 | 이학섭 | bio-soil for sewage using natural meterials and the manufacture method amd manufacture device |
CN103289643A (en) * | 2013-06-14 | 2013-09-11 | 邬汝源 | Negative oxygen ion hard porous material body and production method thereof |
CN103289642A (en) * | 2013-06-14 | 2013-09-11 | 邬汝源 | Negative oxygen ion porous soft material body and production method thereof |
CN104844102A (en) * | 2015-03-30 | 2015-08-19 | 上海轩颂建筑装饰有限公司 | Anion heat-insulating material |
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