KR100463122B1 - Manufacturing method of magnetic minerals - Google Patents
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- KR100463122B1 KR100463122B1 KR10-2002-0069863A KR20020069863A KR100463122B1 KR 100463122 B1 KR100463122 B1 KR 100463122B1 KR 20020069863 A KR20020069863 A KR 20020069863A KR 100463122 B1 KR100463122 B1 KR 100463122B1
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Abstract
본 발명은 미생물의 배양공정에 사용하는 자성광물(磁性鑛物)의 제조하는 방법을 제시하는 것을 목적으로 한다.An object of the present invention is to provide a method for producing a magnetic mineral for use in the culturing process of microorganisms.
이를 위하여 본 발명은, 유문암(流紋岩) 또는 대사이드(Dacite)질의 부석(浮石), 각섬석(角閃石), 감람석(橄欖石), 흑운모(黑雲母), 화산회토(火山灰土) 등같이 풍화작용에 의해서 미네랄성분을 쉽게 용출하는 조암광물(造岩鑛物)의 분말과 천매암(千枚岩), 거정석(Pegmatite), 맥반석(麥飯石), 전기석(Tourmaline), 의왕석(醫王石), 태징석(泰澄石), 옥(玉)과 같이 원적외선(遠赤外線)이나 음이온(陰 Ion) 등을 발생하는 광물의 분말을 혼합한 다음 이들에 착염(錯鹽)을 생성하는 유기산과 광산(鑛酸) 수용액을 주입하고 교반혼합을 하면서 겔(Gel)상태의 킬레이트(Chelate)성미네랄착염 상태로 전환한 후 자성(磁性)물질의 분말을 혼합한 다음에 바인더(Binder)로 벤토나이트(Bentonite)와 알긴산소다(Sodium alginate), 키토산(Chitosan)수지, 셀룰로오스(Cellulose)수지, 녹말 등의 수용액을 주입하면서 혼합 교반하여 반죽을 만들고, 이를 펠렛트(Pellet)상이나 환상으로 가공한 다음 자연 건조한 후 열풍으로 건조한 다음 착자(着磁)하여 자성광물을 제조한다.To this end, the present invention, such as rhyolite or flow (Dacite) pumice (stone), hornblende (, 石), olivine (橄欖石), biotite (black), volcanic ash, etc. Powders of coarse minerals that easily elute minerals by weathering, feldspar, giant stone (Pegmatite), elvan, tourmaline, and uiwangseok (醫 王石) , Organic acids and mines that mix mineral powders that generate far infrared rays or anions, such as tajing stone and jade, and then form complex salts on them. Iii) After injecting aqueous solution and stirring and mixing, it is converted into gel chelate mineral complex salt state and magnetic powder is mixed, then bentonite as binder. And aqueous solutions of sodium alginate, chitosan resin, cellulose resin, starch, etc. Making a dough by mixing and stirring while injecting, and this pellets (Pellet) processed in the next phase or cyclic nature dried magnetized (着 磁) with a hot-air dried to produce a magnetic minerals.
특이한 사항은 유용 미생물 배양공정에 이를 이용하였을 때 미생물 배양효율이 우수하기 때문에 이 분야에 널리 이용될 것으로 전망된다.Unusual matters are expected to be widely used in this field because of their excellent microbial cultivation efficiency.
Description
본 발명은 유문암(流紋岩) 또는 대사이드(Dacite)질의 부석(浮石), 각섬석(角閃石), 감람석(橄欖石), 흑운모(黑雲母), 화산회토(火山灰土) 등과 같이 풍화작용에 의해서 미네랄성분을 쉽게 용출하는 조암광물(造岩鑛物)의 분말과 천매암(千枚岩), 거정석(Pegmatite), 맥반석(麥飯石), 전기석(Tourmaline), 의왕석(醫王石), 태징석(泰澄石), 옥(玉)과 같이 원적외선(遠赤外線)이나 음이온(陰 Ion) 등을 발생하는 광물의 분말을 혼합한 다음 이들에 착염(錯鹽)을 생성하는 유기산(有機酸)과 광산(鑛酸) 수용액을 주입하고 교반혼합을 하면서 겔(Gel)상태의 킬레이트(Chelate)성미네랄착염 상태로 전환한 후 자철광(磁鐵鑛), 페라이트(Ferrite ; MOㆍnFe₂O₃; M= Fe, Ba, Sr 등)와 같은 자성(磁性)물질의 분말을 혼합한 다음에 바인더(Binder)로 벤토나이트(Bentonite)와 알긴산소다(Sodium alginate), 키토산(Chitosan)수지, 셀룰로오스(Cellulose)수지, 녹말 등의 수용액을 가해서 혼합 교반하여 반죽을 만들고, 이를 펠렛트(Pellet)상이나 환상으로 가공한 다음 자연 건조한 후 열풍으로 건조한 다음에 착자(着磁)하여 자성광물을 제조한다.The present invention is used for weathering such as rhyolite or Dacite-like pumice, hornblende, olivine, biotite, volcanic ash, etc. Powders of coarse minerals that easily elute minerals, feldspar rock, macromatite, pebiteite, ganbanite, tourmaline, uiwangseok and tajingite Organic acids and mines that mix powders of minerals that generate far-infrared rays or anions, such as jade and jade, and then form complex salts on them. (Iv) Injecting an aqueous solution and mixing with agitation, converting to a gel chelate mineral complex salt state, and then magnetite, ferrite (MO.nFe₂O₃; M = Fe, Ba, Bentonite and Sodium Alginate as a binder after mixing powders of magnetic materials such as Sr) , Chitosan resin, cellulose resin, starch and other aqueous solutions are mixed and stirred to make a dough, which is processed into pellet or annular form, and then dried by hot air and then magnetized (着 磁) ) To prepare a magnetic mineral.
일본 특허공보 평(平) 5-66199호 생물학적 폐수처리의 미생물배양조에 부식질(腐植質) 펠렛트와 유문암 또는 대사이드질의 부석을 충전(充塡)한 생물반응기(Bio-reactor)를 설치하고 처리한 결과 일반 활성오니법에 비해서 처리효율이 향상되었으나 무기질인 부석광물(浮石鑛物)을 사용하므로 미생물에 미네랄 공급능력이 떨어져 시운전 경우나 비정상운전의 경우 정상상태로 회복하는데 장시간 소요되었으며, 특히 자철광 함량이 적은 부석을 사용한 경우에는 미생물 배양효율이 향상되지 못하는 문제점이 있었다Japanese Patent Publication Hei 5-66199 A microbial culture tank for biological wastewater treatment was installed and treated with a bioreactor filled with humus pellets and rhyolite or pavement stone. As a result, the treatment efficiency was improved compared to the general activated sludge method, but the mineral supplying ability to the microorganisms was reduced due to the use of mineral pumice minerals. In case of using less pumice stone, there was a problem that the microbial culture efficiency was not improved.
본 발명의 목적은 미생물배양공정에 사용하여 미생물 배양효율이 우수한 자성광물을 제조하는 방법을 제시하는 것이 목적이다.An object of the present invention is to propose a method for producing a magnetic mineral having excellent microbial culture efficiency using in the microbial culture process.
이와 같은 목적을 달성하기 위한 본 발명은, 가용성 미네랄성분이 다량 함유한 조암광물의 분말과 원적외선이나 음이온을 발생하는 광물의 분말에 착염을 생성하는 유기산 및 광산 수용액을 주입하여 미네랄착염을 생산하고 여기에 자성물질의 분말을 혼합한 후 바인더를 가해서 혼합 교반하여 반죽을 만들고, 이를 구상이나 환상으로 가공한 다음 자연 건조한 후 열풍으로 건조한 다음 착자하여 미생물 배양효율이 우수한 자성광물을 제조한다.In order to achieve the above object, the present invention is to produce a mineral complex salt by injecting an aqueous solution of organic acid and mine to form a complex salt in the powder of coarse minerals containing a large amount of soluble mineral components and the powder of minerals generating far infrared rays or anions After mixing the powder of the magnetic material in the mixture and adding a binder and stirring to make a dough, processed it into spherical or annular shape, then dried naturally with hot air and then magnetized to produce a magnetic mineral with excellent microbial culture efficiency.
본 발명에서 미생물 배양공정에 사용하는 자성광물(磁性鑛物)의 제조방법을 상세히 설명하면 다음과 같다.Referring to the method of producing a magnetic mineral (磁性 鑛物) used in the microbial culture step in the present invention in detail.
1. 유문암(流紋岩) 또는 대사이드(Dacite)질의 부석(浮石), 각섬석(角閃石), 감람석(橄欖石), 흑운모(黑雲母), 화산회토(火山灰土) 등과 같이 풍화작용에 의해서 미네랄성분을 쉽게 용출하는 조암광물(造岩鑛物) 1종류 이상의 분말과 천매암(千枚岩), 거정석(Pegmatite), 맥반석(麥飯石), 전기석(Tourmaline), 의왕석(醫王石), 태징석(泰澄石), 옥(玉)과 같이 원적외선(遠赤外線)이나 음이온(陰 Ion)을 발생하는 광물의 분말을 혼합한다.1. By weathering, such as rhyolite or dacite-like pumice, hornblende, olivine, biotite, volcanic ash, etc. One or more powders of coarse minerals that easily elute minerals, feldspar, macrorite, ganbanite, tourmaline, uiwangseok, and Taetae Mixing powders of minerals that generate far-infrared rays and anions, such as stone stones and jade.
2. 1항에 물을 주입하여 함수율을 40∼60wt%로 조정한다.2. Add water to 1 and adjust the water content to 40 ~ 60wt%.
3. 2항에 금속착염(金屬錯鹽)을 생성하는 구연산(枸酸), 주석산(酒石酸), 호박산(琥珀酸), 풀브산(Fulvic acid)과 같은 유기산(有機酸)을 10∼20wt% 주입하여 교반혼합한다.3. Citric acid, which forms metal complex salts in 2) ∼) 10-20 wt% of organic acids, such as tartaric acid, succinic acid, succinic acid, and fulvic acid, are mixed and stirred.
4. 3항에 염산(鹽酸), 황산(黃酸)과 같은 광산(鑛酸)을 주입하여 pH를 1.5∼2.5의 범위로 조정하면서 교반혼합하면 겔(Gel)상태의 킬레이트(Chelate)성미네랄착염 상태로 전환한다.4. Inject the mineral acid such as hydrochloric acid and sulfuric acid into Paragraph 3 and adjust the pH to a range of 1.5 to 2.5, and stir and mix the gel chelate-like mineral. Transition to complex
5. 4항에 자철광(磁鐵鑛 ; FeOㆍFe₂O₃)분말, 4,3산화철(Fe₃O₄), 바륨 페라이트(Barium ferrite ; Baㆍ6Fe₂O₃), 스트론튬 페라이트(Strontium ferrite ; SrOㆍ6Fe₂O₃)와 같은 자성물질의 분말을 10∼50wt% 정도의 비율로 주입하여 교반혼합한다.5. Paragraph 4 of magnetic materials such as magnetite (磁鐵鑛; FeO · Fe₂O₃) powder, ferrous trioxide (Fe₃O₄), barium ferrite (Ba · 6Fe₂O₃), strontium ferrite (SrO · 6Fe₂O₃) The powder is poured at a rate of about 10 to 50 wt% and mixed with stirring.
6. 5항에 무기바인더로 벤토나이트(Bentonite) 분말을 0.1∼0.5wt% 정도 가해서 교반혼합한다.6. Add Bentonite powder in 0.1 to 0.5wt% with inorganic binder and stir and mix.
7, 6항에 유기바인더로 알긴산소다(Sodium alginate), 키토산(Chitosan)수지, 셀룰로오스(Cellulose)수지, 전분 등의 수용액을 0.02∼0.05wt% 정도를 가해서 교반하면서 반죽을 만든다.The organic binder is used to prepare the dough while stirring by adding 0.02 ~ 0.05wt% of aqueous solution of sodium alginate, chitosan resin, cellulose resin, and starch.
8. 7항의 반죽을 구상의 펠렛트(Pellet)상이나 환상으로 가공한 다음 4∼5일정도 자연건조를 한 후 100∼250℃의 열풍으로 건조하여 건조된 펠렛트를 제조한다.8. Process the dough of Clause 7 into spherical pellets or annular form, and then naturally dry for 4 to 5 days, and then dry with hot air at 100 to 250 ° C to prepare dried pellets.
9. 8항의 건조된 펠렛트를 착자기에서 자속밀도(Magnetic flux density)가 300G(Gauss)이상 착자(着磁)하여 자성을 띠는 자성광물을 제조한다.9. Magnetic dried minerals are prepared by magnetizing the dried pellets of Clause 8 in a magnetizer with a magnetic flux density of 300 G (Gauss) or more.
전술한 기술내용으로부터 자명하듯이, 본 발명의 자성광물은 하ㆍ폐수의 생물학처리공정, 생물학적 탈취처리공정, 가축음용수처리 등의 미생물배양공정에서 미생물배양효율이 우수하기 때문에 이들 분야에 널리 보급 될 것으로 기대된다.As is apparent from the above description, the magnetic mineral of the present invention is widely distributed in these fields because of its excellent microbial culture efficiency in microbial culture processes such as biological treatment of sewage and wastewater, biological deodorization treatment, and animal drinking water treatment. It is expected to be.
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KR100518675B1 (en) * | 2002-11-18 | 2005-10-04 | 서희동 | Manufacturing method of porous magnetic minerals |
KR100471000B1 (en) * | 2002-11-25 | 2005-03-10 | 서희동 | Manufacturing and using method of stabilizer for sewage and waste water biological treatment |
CN108355621B (en) * | 2018-03-21 | 2022-04-01 | 成都理工大学 | Magnetic porous bentonite chitosan composite microsphere and preparation method thereof |
CN115417500A (en) * | 2022-09-29 | 2022-12-02 | 江西零真生态环境集团有限公司 | Sulfur autotrophic denitrification filler and preparation method thereof |
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JPS6135826A (en) * | 1984-07-27 | 1986-02-20 | Enzaimu Kogyo Kk | Removal of malodor by activated humic substance |
JPH069280A (en) * | 1991-07-09 | 1994-01-18 | Baitaru Japan Kk | Calcined bioceramic and production of calcined bioceramic |
JPH08309394A (en) * | 1996-01-16 | 1996-11-26 | Enzaimu Kk | Deodorization of organic sludge and manufacture of property change inhibiting agent |
JP2002301482A (en) * | 2001-04-09 | 2002-10-15 | San Friend Medical Kk | Sintered natural ore activating city water |
KR20040037706A (en) * | 2002-10-29 | 2004-05-07 | 서희동 | Manufacturing and using method for pellet of magnetized oceanic humic acid colloidal micelle |
KR20040040014A (en) * | 2002-11-05 | 2004-05-12 | 서희동 | Manufacturing method of magnetized Humus soil. |
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Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS6135826A (en) * | 1984-07-27 | 1986-02-20 | Enzaimu Kogyo Kk | Removal of malodor by activated humic substance |
JPH069280A (en) * | 1991-07-09 | 1994-01-18 | Baitaru Japan Kk | Calcined bioceramic and production of calcined bioceramic |
JPH08309394A (en) * | 1996-01-16 | 1996-11-26 | Enzaimu Kk | Deodorization of organic sludge and manufacture of property change inhibiting agent |
JP2002301482A (en) * | 2001-04-09 | 2002-10-15 | San Friend Medical Kk | Sintered natural ore activating city water |
KR20040037706A (en) * | 2002-10-29 | 2004-05-07 | 서희동 | Manufacturing and using method for pellet of magnetized oceanic humic acid colloidal micelle |
KR20040040014A (en) * | 2002-11-05 | 2004-05-12 | 서희동 | Manufacturing method of magnetized Humus soil. |
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