KR20030044306A - Composition of aromatic plants for deodorization - Google Patents

Abstract

PURPOSE: Provided is a deodorizing aromatic composition having excellent deodorizing and masking powers, which is useful to remove a distinctive smell frequently occurred in dwelling spaces of bachelorhood and aged man. CONSTITUTION: The composition comprises 1-5 wt% of jasmine, 1-5 wt% of citronella, 5-10 wt% of lime, 5-10 wt% of spearmint, 2-4 wt% of tomato leaf, 2-4 wt% of galbanum, 5-30 wt% of bergamot, 1-5 wt% of rose oil, 0.5-3 wt% of dimethylbenzylcarbinol, 1-5 wt% of hexenol, 5-30 wt% of verdox, 1-3 wt% of ethylvanillin, 0.5-3 wt% of styrallyl acetate, 1-5 wt% of galbex, 1-5 wt% of hexenyl acetate, 1-3 wt% of alpha damascone, and 1-3 wt% of beta damascone.

Description

Deodorant fragrance composition {COMPOSITION OF AROMATIC PLANTS FOR DEODORIZATION}

The present invention relates to a deodorant fragrance composition, particularly a deodorant fragrance composed of a fragrance raw material excellent in deodorizing and masking power for deodorizing the unique odor commonly occurring in the living space of only single men, such as dormitory, officetel It relates to a composition.

In general, different odors can be found in women's and babies' only spaces, as well as in residential areas only for men and the elderly. Occasionally, the smell of babies smells good and smells good, while the odors of the elderly and men are classified as unpleasant.

These discomforts occur throughout the body due to daily activities and exercise, aging and specific constitutions. In general, these body odors are caused by the action of microorganisms or enzymes such as sweat or sebum. It is produced by being decomposed or dismantled, and the unpleasant odor is more likely to occur when it is not clean, especially in the living spaces of men and the elderly.

Thus, there have been many attempts to deodorize this displeasure. Ethyl lactate, octyl crotonate, trimethyl citrate, caratan (4,6-dinitro-2- (methylheptyl) phenyl crotonate), BHA (butylated hydroxyanisol) or BHT (butyl ray) Including direct or indirect microbial inhibitors, enzyme inhibitors or antioxidants, such as Tied hydroxytoluene, to suppress the secretion of sweat, which causes unpleasant odors, or to prevent the decomposition and acidification of fatty acids such as sweat or sebum. Because it is used directly in the human body, if the suppression of sweat can cause a normal body maintenance dysfunction, there is a problem that needs to solve the safety problems for the skin, such as skin toxicity of the active ingredient remains.

In addition, attempts have been made to mask or deodorize indoor air in order to contaminate indoor air while preventing the occurrence of odors that have already occurred in the room. I couldn't.

Accordingly, the present invention tests and selects fragrance substances having excellent deodorizing and masking effects among numerous natural and synthetic fragrances, and measures the deodorizing effect by combining the fragrance substances, and finds that a particular fragrance combination has an excellent deodorizing effect. This invention was completed.

The present invention is 1-5% by weight of jasmine, 1-5% by weight of citronella, 5-10% by weight of lime, 5-10% by weight of spearmint, 2-4% by weight of tomato leaves, 2-4% by weight of galbanum, 5-30% by weight bergamot, 1-5% by weight rose oil, 0.5-3% by weight dimethylbenzylcarbinol, 1-5% by weight hexenol, 5-30% by weight Verdox, ethylvanillin 1 -3 wt%, styralyl acetate 0.5-3 wt%, 1-5 wt% Galbex, 1-5 wt% hexenyl acetate, 1-3 wt% alpha damascone and beta damascone A deodorant perfume composition, characterized in that it contains 1-3% by weight.

The present invention also relates to a deodorant characterized in that it contains 0.1-5.0% by weight of the deodorant perfume composition as described above.

Deodorant according to the present invention preferably further contains Order Neutralizer ™ (registered trademark of Odor Neutralizer, Haarmann & Reimer) as a deodorant material in addition to the deodorant perfume composition according to the present invention.

Hereinafter, the present invention will be described in more detail with reference to the following examples and examples, which should not be construed as limiting the scope of the present invention as merely illustrative of the present invention.

Reference Example 1: Preparation of Artificial Odor Substances

In order to manufacture the odor that is the deodorant of the perfume composition for deodorant, the smell of the living space is collected by headspace method in 10 dormitory rooms, which are single men's residences, or 5 elderly tablets, which are elderly people's residences. The components were analyzed by a chromatography / mass spectrometer, and then the analyzed components were combined to produce an artificial malodorous substance.

The components contained in the artificial malodorous substances are shown in Table 1.

Table 1: Compositions of Artificial Odor Substances

number Ingredient Name Content (% by weight) One 2-ethyl hexanoic acid 8 2 Geranyl acetate 0.4 3 Acetophenone 0.2 4 Carbitol 0.2 5 phenol 0.4 6 Benzyl alcohol 0.2 7 Dimethyl Phenolic Carbinol 0.4 8 2-ethyl hexanol 0.8 9 Nonanol 0.6 10 Octanol 0.3 11 Tridecanal 0.2 12 Dodecanal 0.3 13 Decanal 0.9 14 Nonal 0.7 15 Heptadecane One 16 Hexatecan 6 17 Tridecan 2 18 Dodecane 2 19 Butyl carbinol 3 20 l-methyl isovalerate 1.2 21 Octanoic acid 5 22 Dodecanol 20 23 l-menthol 0.5 24 Undecanal 0.3 25 nicotine One 26 Isopropyl myristate 20

The artificial malodorous substances in Table 1 were recognized as malodorous sources by 8 out of 10 professional sensory evaluation personnel, and they were set as the standard of artificial malodorous substances in the living space of single men or elderly people.

Reference Example 2: Selection of Fragrances with Excellent Deodorizing Effect

Masking or deodorizing effects of various natural and synthetic perfumes on artificial malodors including malodorous ingredients shown in Table 1 were evaluated by 10 expert evaluation personnel. For evaluation, put 4 cm of hygroscopic paper in 500 ml of inner coated paper cup, 0.1 ml of artificial malodor diluted to 5% concentration with ethyl alcohol and 1 ~ 5% concentration with ethyl alcohol as well. 0.1 ml of the diluted perfume diluent was dropped on a hygroscopic paper, and then sealed with a lid. After 2 hours, the deodorizing effect was evaluated.

The evaluation criteria were divided into four stages and evaluated as shown in Table 2. As a result of the evaluation, 15 kinds of natural flavors and 30 kinds of synthetic flavors having excellent deodorizing effects were selected.

Table 2: Evaluation criteria for deodorant effects on artificial odors

score Evaluation standard 0 Odor can not be detected. One Odor can only be detected. 2 Odor can be easily detected. 3 Strong odor

Table 3: Deodorizing effect of 15 natural fragrances and 30 synthetic fragrances with excellent deodorant effect

No. Perfume density(%) Score by expert evaluator Average One Jasmin One 0 0 One One 2 3 One 0 0 One 0.9 2 Ylang ylang One 0 One One One 0 One 2 2 0 One 0.9 cloth 3 Citronella One 0 2 One One One One 0 One 2 2 1.1 4 Lime 5 0 0 One 0 0 0 One 0 0 0 0.2 year 5 Cinnamon bark 5 0 One One 0 0 0 0 0 0 2 0.4 6 Spearmint 5 0 One One 0 2 0 2 0 0 0 0.6 incense 7 Tomato leaf 5 One 0 2 One 0 0 0 2 0 0 0.6 8 Galbanum 5 0 One 0 2 0 One One One 0 One 0.7 Ryo 9 Bergamot 5 One One One 0 2 0 One One One 2 One 10 Rose 5 One One One 2 0 0 2 One One One One 11 Rosemary 5 0 2 2 One 0 One 0 3 One 0 One 12 Eucalyptus 5 One One One One One 0 2 2 One One 1.1 13 Lemon 5 One One One One 2 One One 2 One One 1.2 14 Lavender 5 0 3 One One One One 3 One One 0 1.2 15 Peppermint 5 0 One 2 2 2 2 2 One 0 0 1.2 One Dimethyl benzyl carbinol 0.5 0 One 0 0 0 One 0 0 One 0 0.3 Synthetic fragrance 2 Phenyl acetic acid 0.5 One 0 0 0 0 0 0 One 2 0 0.4 3 Calone 0.5 One One One One 0 0 0 0 One 0 0.5 4 Adoxal 0.5 One 0 One One 0 0 One 0 0 One 0.5 5 Hexanol (cis-3-Hexenol) 0.5 One 0 One 0 One 0 One 0 One 0 0.5 6 Verdox 0.5 0 One 0 One One One 0 One 2 One 0.8 7 Ethyl vanillin 0.5 One 0 2 One 2 0 One One 0 One 0.9 8 Styrallyl acetate 0.5 One 0 One 0 One 2 One 2 One 2 1.1 9 Galbex 0.5 One 0 0 One 2 3 2 One One 0 1.1 10 Camper 0.5 0 2 3 2 0 2 One 0 One One 1.2 11 Benzaldehyde One 0 0 One 0 0 0 0 One 0 0 0.2 12 Hexenyl acetate (cis-3-Hexenyl acetate) One 0 0 One One 0 0 0 One 0 One 0.4 13 Ethyl linalool One 0 0 0 2 0 0 2 0 One 0 0.5

14 Methyl salicylate One 0 One One One One 0 One One 0 0 0.6 15 Beta damascone One 0 One One One 0 One 2 2 0 One 0.9 16 Alpha damascone One 2 0 One One 0 One 2 One One One One 17 l-menthol One One 2 2 0 0 2 One One One One 1.1 18 Hexyl cinnamicaldehyde One 2 One One One 0 0 One One 2 2 1.1 19 Allyl amyl glycolate One 3 0 One 3 2 0 0 One One One 1.2 20 Benzyl acetate One 2 One 0 One 2 2 One 0 2 One 1.2 21 Triplal One 2 0 One 2 One One 2 One 2 One 1.3 22 Cyclacet 5 One One 0 0 0 One 0 0 One 0 0.4 23 Allyl cyclohexyl propionate 5 One One 0 0 One 0 One 0 One 0 0.5 24 Cinamic Aldehyde 5 One 0 One 0 One One 0 One 0 One 0.6 25 Terpineol 5 0 0 One 2 One One One 0 One 0 0.7 26 Geraniol 5 One 0 2 One 0 2 0 0 One One 0.8 27 Beta methyl naphthyl ketone 5 One 3 0 0 0 0 0 0 2 2 0.8 28 Citronellol 5 2 0 2 0 2 One 0 One One 0 0.9 29 Phenylethyl acetate 5 0 One One One 0 0 One One 2 2 0.9 30 Tetra hydro linalool 5 0 One 3 2 0 One 0 0 One One 0.9 Reference Artificial pollutants 2 2 One 2 2 2 3 3 3 3 2.3

Example 1 Preparation of Fragrance Composition

Perfume composition according to the present invention, and raw materials and other fragrances of 1.0 or more mainly on natural and synthetic fragrances having an average of 1.0 or less (excellent deodorizing effect) in the masking and deodorizing effect evaluation according to Table 3 above, considering the harmony and preference of the fragrance To prepare a control 1 to 4 by using a small amount of the composition is shown in Table 4 below.

Table 4: Composition of Example 1 Control and 1-4 (Unit: Weight%)

Spices people Example 1 Control 1 Control 2 Control 3 Control 4 Jasmine 3 3 3 3 One Ylang-ylang 3 3 3 One Citronella 3 3 3 3 Lime 8 8 8 8 8 cinnamon One Spearmint 7 7 7 7 15 Tomato leaves 3 Galbanum 3 Bergamot 15 10 10 10 10 Rose oil 5 5 10 5 5 Rosemary 5 3 Dimethylbenzyl carbinol One One 2 One One Phenyl acetic acid 5 Calon One Poisoning One Cis-3-hexanol 3 Burdox 15 15 20 15 15 Ethyl vanillin 2 2 2 2 2 Styralyl acetate One Galvex 3 5 Camper 2 Benzylaldehyde One Cis-3-hexenyl acetate 5 Ethyl linal wool 10 Methyl salicylate 3 Beta Damascon 3 One Alpha Damascon 3 3 One Etc 32 16 31 19 37 Sum 100 100 100 100 100

Example 2 Deodorant Effect Experiment

The deodorant effect was evaluated by the criteria shown in Table 2 for the perfume compositions of Example 1 and Controls 1 to 4 as described above, and the results were as shown in Table 5 below.

Table 5: Deodorizing effect of the perfume according to Example 1 and Controls 1 to 4

division score Average Example 1 0 0 One One 0 One One 0 One 0 0.5 Control 1 One 0 0 One One 0 One One One One 0.7 Control 2 One One One One One One 2 One 0 2 1.1 Control 3 0 One 0 0 One 2 One One One One 0.8 Control 4 One 2 0 2 One 2 One One 2 2 1.4

As can be seen in Table 5, the deodorizing effect of the composition according to the present invention was an average of 0.5, much less odor than the control, the deodorizing effect was excellent.

In addition, the survey was conducted on 27 females and 20 females aged 20 to 40 years. The results were as shown in Table 6.

Table 6: Satisfaction of perfume composition according to Example 1 and Controls 1 to 4

division 27 women 20 men 57 people in total Example 1 3.81 3.95 3.87 Control 1 3.65 3.89 3.77 Control 2 3.62 3.74 3.68 Control 3 3.48 3.55 3.51 Control 4 3.44 3.40 3.43

(Five points: very good, four points: good, three points: normal, two points: bad, one point: very bad)

As can be seen in Table 6, the composition according to the present invention was superior to the flavor 1 to 4 compared to the control.

Examples 3 to 5: Preparation of Deodorant

The deodorant containing the fragrance composition according to Example 1 and an order neutralizer of Hamanmann & Reimer, a known deodorant raw material, was prepared in the composition shown in Table 8 below. A composition containing only Order Neutralizer ™, a conventional deodorant, was prepared as Comparative Example 1.

Table 8: Composition of Deodorant in Weight%

ingredient Example 2 Example 3 Example 4 Comparative Example 1 Perfume composition prepared in Example 1 One 2 3 - Order Neutralizer ™ 2 2 2 2 ethanol 30 Polyethylene glycol 5 Solubilizer handful water Remainder

When the composition according to Examples 3 to 5 and Comparative Example 1 was used for about 1 month for 20 single men and 10 elderly people living alone, a questionnaire about satisfaction after use of the deodorant was found. It was like

Table 9 Survey Results after Using Deodorant

Survey item Example 2 Example 3 Example 4 Comparative Example 1 Smell good 3.41 3.79 3.26 2.44 Could not smell strange. 3.51 3.66 3.52 2.15 Overall, I like it. 3.55 3.83 3.49 2.31

(Five points: very good, four points: good, three points: normal, two points: bad, one point: very bad)

As shown in Table 9 it can be seen that when using the deodorant flavor composition according to the present invention is more excellent than the deodorant according to Comparative Example 1.

As described above, 1-5% by weight of jasmine, 1-5% by weight of citronella, 5-10% by weight of lime, 5-10% by weight of spearmint, 2-4% by weight of tomato leaves, 2-4 galvanum Wt%, Bergamot 5-30 wt%, Rose Oil 1-5 wt%, Dimethylbenzylcarbinol 0.5-3 wt%, Hexenol 1-5 wt%, Verdox 5-30 wt%, Ethyl vanillin 1 -3 wt%, styralyl acetate 0.5-3 wt%, 1-5 wt% Galbex, 1-5 wt% hexenyl acetate, 1-3 wt% alpha damascone and beta damascon Deodorant fragrance composition characterized in that it contains 1-3% by weight and deodorant containing 0.5% to 5% of such a fragrance composition is superior to the deodorant effect of the conventional.

Claims (3)

Jasmine 1-5%, Citronella 1-5%, Lime 5-10%, Spearmint 5-10%, Tomato leaves 2-4%, Galbanum 2-4%, Bergamot 5- 30% by weight, 1-5% by weight of rose oil, 0.5-3% by weight of dimethylbenzylcarbinol, 1-5% by weight of hexenol, 5-30% by weight of Verdox, 1-3% by weight of ethyl vanillin, sty 0.5-3% by weight of ralyl acetate, 1-5% by weight of Galbex, 1-5% by weight of hexenyl acetate, 1-3% by weight of alpha Damascone and 1-3% by weight of beta damascone. Deodorant fragrance composition, characterized in that it contains. Deodorant, characterized in that it contains 0.1-5.0% by weight of the deodorant perfume composition according to claim 1. The deodorant according to claim 2, which further contains 0.1-5% of order neutralizer (registered trademark of Odor Neutralizer, Haarmann & Reimer).