WO2017171108A1 - Perfume composition for masking body odor and cosmetic composition comprising same - Google Patents

Perfume composition for masking body odor and cosmetic composition comprising same Download PDF

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Publication number
WO2017171108A1
WO2017171108A1 PCT/KR2016/003204 KR2016003204W WO2017171108A1 WO 2017171108 A1 WO2017171108 A1 WO 2017171108A1 KR 2016003204 W KR2016003204 W KR 2016003204W WO 2017171108 A1 WO2017171108 A1 WO 2017171108A1
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Prior art keywords
weight
perfume
composition
fragrance
masking
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PCT/KR2016/003204
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French (fr)
Korean (ko)
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윤동선
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주식회사 엘지생활건강
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Priority to PCT/KR2016/003204 priority Critical patent/WO2017171108A1/en
Priority to KR1020187028167A priority patent/KR102599099B1/en
Publication of WO2017171108A1 publication Critical patent/WO2017171108A1/en

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35Ketones, e.g. benzophenone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q13/00Formulations or additives for perfume preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00Anti-perspirants or body deodorants

Definitions

  • the present invention relates to a fragrance composition for masking body odor and a cosmetic composition comprising the same, and more particularly to a fragrance composition capable of masking a unique body odor occurring in the human body and a cosmetic composition comprising the same.
  • the characteristic odor of the human body has a unique odor due to the addition of general human odors (hormonal changes according to age, adolescent odors, and senile odors) and lifestyle traits associated with the eating culture.
  • the main malodor masking effect using perfume is vapor pressure reduction technology. This is a technique that allows the smell to be volatilized before perceived.
  • perfumes with lower odor thresholds and higher volatilities than odors are limited to citrus and herbal scents, and there are limitations in developing various scents based on palatability.
  • the present invention is to solve the above problems, to provide a perfume composition and a cosmetic composition having excellent masking effect.
  • the present invention aims to provide a fragrance composition having a broad odor spectrum and excellent body odor masking effect.
  • the present invention provides a cosmetic composition that can effectively mask the body malodor (body malodor) of the human body.
  • the inventors of the present invention while studying the masking effect with reference to the characteristics of the existing Malodor Counteractant (hereinafter referred to as MOC), 1) a perfume having a certain physical properties; And 2) finding a combination fragrance having a variety of fragrances with high aroma preference as well as an excellent masking effect on the human-specific odor when using a fragrance having a specific structure expected to have a certain low reactivity with human malodor, the present invention To complete.
  • MOC Malodor Counteractant
  • the fragrance used is only volatilized faster than the odor, and has the disadvantage that it can be developed only with the odor that is limited to herbs.
  • fragrances that play a sensory harmonizing role for certain odors have a disadvantage that they do not have a wide odor spectrum.
  • the inventors of the present invention as a result of repeated studies, to provide a perfume composition and a cosmetic composition using the same that can obtain an excellent body odor masking effect.
  • the inventors of the present invention provide a perfume with low olfactory threshold; And at least one carbonyl group and a flavor having a carbon double bond combined together as an active ingredient to develop a more effective MOC flavor for human malodor. This provides a cosmetic composition having an excellent fragrance preference based on the development of various scents.
  • odor threshold means the minimum concentration of vapor in the air that can be smelled.
  • compounds with low olfactory thresholds may be said to be more potent than compounds with high olfactory thresholds, and therefore only very small concentrations may be used in the perfume composition to achieve the olfactory effect.
  • the olfactory threshold used herein refers to the value of Leffingwell & Associates, and represents the value measured by dissolving the fragrance component in water at 20 ° C. Odor threshold measurement methods have been introduced in Odor Threshold Determinations of 53 Odorant Chemicals.
  • the fragrance component may refer to a single compound having an olfactory threshold value which may itself stimulate human smell.
  • the fragrance composition as used herein may include one or more of the fragrance components, and may mean that two or more components are mixed as a whole.
  • the present invention relates to a fragrance component having (A) an olfactory threshold of greater than 0 and 350 ppb in water at 20 ° C. and a vapor pressure of at least 0.0004 mmHg and up to 7.85 mmHg at 25 ° C., and (B) at least one carbonyl group and a carbon double bond. It provides a fragrance composition for masking body odor comprising a fragrance component having a structure.
  • the inventors of the present invention have confirmed that the fragrance composition mixed with the component (A) and the component (B) have an excellent body odor masking effect and have completed the present invention.
  • the fragrance components (A) having an olfactory threshold of 0 to 350 ppb or less (in water, 20 ° C.) and a vapor pressure of 0.0004 mmHg or more and 7.85 mmHg or less at 25 ° C. include Iso E super, Lilial, Li, and Li.
  • Lnalool Stemon, Benzaldehyde, Cinnamic aldehyde, L-carvone, Cyclopidene, Damasconone ⁇ , Hedione (Hedione), Linalyl acetate, Ethyl acetate, Methyl pamplemousse, Ethyl methyl-2-butyrate, Manzanate, Ethyl Ethyl acetate, ionone beta (Ionone ⁇ ), raspberry ketone (Raspberry ketone), Javanol (Javanol) and may comprise any one or more perfume ingredients selected from the group consisting of Mayol (Mayol).
  • linalyl acetate (Linalyl acetate), L-carvone (L-carvone), Lilial (Lilial), Linalol and Mayol (mayol) And even more preferably L-carvone, Linalol and Maiol.
  • the fragrance component having a structure in which at least one carbonyl group and a carbon double bond are connected is cuminicic aldehyde, ethyl vanillin, vanillin, cinnamic aldehyde ), Alpha-amyl cinnamic aldehyde, alpha-hexyl cinamaldehyde, heliotropin, anisic aldehyde, damascone, Methyl ⁇ -naphthyl ketone, alpha-ionone, iron, citrylal, sandranol, al-ocean propanal ) And any one or more perfume ingredients selected from the group consisting of dynascone 10.
  • ethyl vanillin, citrylal, damascone, alpha-hexyl cinamaldehyde, anisic aldehyde, dynascone 10 may include any one or more selected from the group consisting of Sandranol, even more preferably alpha-hexyl cinamaldehyde ( ⁇ -hexyl cinamaldehyde), anisic aldehyde (Anisic aldehyde), dinascon 10 ( dynascone 10) and Sandranol.
  • the fragrance composition of the present invention (A) iso super (Iso E super), Lilial (Lilial), Linalul (Linalool), Stemon (Stemon), Benzaldehyde (Benzaldehyde), Cinnamic aldehyde, L-carvone, Cyclopidene, Mayol, Hexyl cinnamic aldehyde, Aldehyde C14, and Myol (Mayol) any one or more flavoring ingredients selected from the group consisting of Heliotropin, Dynascone 10, Sandranol, Methyl beta-naphthyl ketone, and sheet It may include any one or more flavoring ingredients selected from the group consisting of Citrylal.
  • the perfume composition of the present invention may have a weight ratio of (A) perfume component: (B) perfume component in a weight ratio of 1: 1 to 5, preferably in a weight ratio of 1: 1 to 3.
  • the fragrance composition is 1-20% by weight of isoisuper, 1-10% by weight of lily, 5-10% by weight of linalul, 1-5% by weight of stemon, ben 1-5% by weight of zaldehyde, 1-10% by weight of cinnamic aldehyde, 1-5% by weight of l-carbon, 1-5% by weight of cyclopydene, 0.5-2% by weight of miol, 5-25% of hexyl cinnamic aldehyde At least one perfume component selected from the group consisting of%, 5-25% by weight of aldehyde C14, and 1-5% by weight of miol; And 1-10% by weight of heliotropin, 0.1-1% by weight of dinaconcone, 1-10% by weight of sandronol, 1-5% by weight of methyl beta naphthyl ketone, and 1-10% by weight of citralal It may include any one or more flavoring ingredients selected.
  • the fragrance composition is dibutylhydroxytoluene, heptanoic acid, octanoic acid, nonenal, octenal, 3-hydroxy-3-methyl-hexanoic acid, methional, 2-isopropyl-4-methyl thiazole, And triethyl citrate may be effective for masking any one or more components selected from the group consisting of, preferably methional (Methional), 2-isopropyl-4-methyl thiazole (2-isopropyl-4-methyl thiazole ), And 3-hydroxy-3-methyl-hexanoic acid may be masked any one or more selected from the group consisting of.
  • the term masking means that the odor, refractory odor, etc. are not recognized by using the fragrance component, and unlike the odor caused by the chemical reaction, the odor substance is removed by using other fragrances. It means a technique that is not to be perceived sensually.
  • a cosmetic composition comprising the body odor masking fragrance composition.
  • the cosmetic composition is not particularly limited as long as it is a formulation applied to the skin, hair or scalp, preferably any one selected from the group consisting of body pact, body powder, body wash, shampoo, hair conditioner, body lotion and body mist for deodorant It may have a formulation.
  • the cosmetic composition may be a wash-off or a leave-on product.
  • the cosmetic composition may use the components and the manufacturing method commonly used in the cosmetic industry.
  • the body odor masking perfume composition may be included 0.01 to 10% by weight relative to the total weight of the cosmetic composition, preferably 0.1 to 5% by weight. If the content is less than 0.01% by weight may not be effective because the smell is not felt, if more than 10% by weight the smell is too strong affects the preference and may be negatively on the stability of the product.
  • the present invention provides a fragrance composition in which a wide range of fragrances are expanded in various fragrance directions by combining components having different characteristics, unlike the conventional ones limited to citrus and herbs.
  • the present invention can provide a perfume composition effective to mask the body odor of the human body and a cosmetic composition comprising the same.
  • the experiment was conducted by collecting body odors from Koreans.
  • one piece of cotton T-shirt per person may be worn for one day's sleep period to allow body odor to be cut. Open the sealed T-shirt, cut it out, cut it in half (25 x 25 cm), and perform body odor evaluation and instrument analysis.
  • Instrument analysis was performed by SPME method using GC-MS, and analysis conditions were as follows.
  • Substance Content (% by weight) Dibutylhydroxytoluene 1.0 Heptanoic acid 10.0 Octanoic acid 10.0 Nonenal 1% triethyl citrate 15.0 Octenal 1% triethyl citrate 2.5 3-hydroxy-3-methyl-hexanoic acid 1% triethyl citrate 25.0 Methional 3% triethyl citrate 10.0 2-isopropyl-4-methyl thiazole 3% triethyl citrate 15.0 Triethyl citrate 11.5
  • Human malodor has odor which is characteristic of fatty, acidic, aldehydic and watery.
  • the masking effect of the body lotion (Formula 2, Table 11), which is a non-washable product (Leave-in) for the combination perfumes prepared in the contents shown in Table 4, was investigated in the questionnaire 1 of 12 of the professional stewards. The sensory evaluation was performed, and the evaluation results are shown in Table 6.
  • the fragrance preference for the body wash (Formulation Example 1, Table 10), which is a wash-off product for the combination fragrances prepared in the contents shown in Table 4, was collected from 30 healthy men and women aged 25 to 40 years. Evaluation was conducted with Questionnaire 2 of Table 3. At this time, a 5-minute break was provided between the samples so that there was no olfactory paralysis. The results are shown in Table 7.
  • the fragrance preference for body lotion (Formulation Example 2, Table 11), which is a non-washable product (Leave-on) for the combination flavors prepared in the contents shown in Table 4, was applied to 30 healthy men and women aged 25 to 40 years.
  • the questionnaire 2 of Table 3 was used to evaluate. At this time, a 5-minute break was provided between the samples so that there was no olfactory paralysis. The results are shown in Table 8.
  • the inventors of the present invention provide a fragrance material having a masking effect on the human malodor component according to the present invention, but having at least one carbonyl group and carbon double bonds conjugated to a variety of fragrances and fragrances having good aroma preference. It is shown in Table 9.
  • the combination perfume composition of the present invention was formulated to prepare a body wash of Table 10.
  • Experimental Example 1 As a result of evaluating the masking effect according to Experimental Example 2, Experimental Example 1 was almost ineffective, and Experimental Example 2 was too strong in odor, causing problems in formulation stability with rejection.
  • Body lotion containing the combination perfume composition of the present invention (content: wt%) Experimental Example 1
  • Experimental Example 2 Experimental Example 3
  • Combination perfume of the present invention (Example 3) Water Glycerin PEG 40 hydrogenated castor oil Mineral oil Carbomer (Carbopol 940) Methyl paraben Triethanolamine 0.01To 10051100.10.20.1 0.5To 10051100.10.20.1 15To 10051100.10.20.1
  • the present invention can provide a perfume composition effective to mask the body odor of the human body and a cosmetic composition comprising the same.
  • the present invention can be used in various fields, such as perfume, human cleanser, cosmetics.

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Abstract

The present invention provides a perfume composition for masking body odor, comprising: (A) a perfume component with an olfactory threshold of greater than 0 and less than or equal to 350 ppb (at 20℃ in water), and a vapor pressure of greater than or equal to 0.0004 mmHg and less than or equal to 7.85 mmHg at 25℃; and (B) a perfume component having a structure in which at least one carbonyl group is connected to a carbon double bond. The present invention can provide a perfume composition effective for masking the body odor of a human body and a cosmetic composition comprising the same.

Description

체취 마스킹용 향료 조성물 및 이를 포함하는 화장품 조성물Perfume composition for body odor masking and cosmetic composition comprising the same
본 발명은 체취 마스킹용 향료 조성물 및 이를 포함하는 화장품 조성물에 관한 것으로, 보다 상세하게는 인체에서 발생하는 특유의 체취를 마스킹할 수 있는 향료 조성물 및 이를 포함하는 화장품 조성물에 관한 것이다. The present invention relates to a fragrance composition for masking body odor and a cosmetic composition comprising the same, and more particularly to a fragrance composition capable of masking a unique body odor occurring in the human body and a cosmetic composition comprising the same.
남에게 보여지는 이미지를 중시하는 사회 문화에서 내 몸에서의 불쾌한 취를 의식하고 이에 민감한 사람들이 늘고 있다. 인체의 불쾌 취는 생리학적인 흐름에 의한 인체 취와 식생활 습관과 연관된 생활취로 나뉠 수 있으며, 한 사람의 체취는 인체 취와 생활 취가 결합된 형태로 나타난다. 인간의 땀 성분, 피지 성분은 동일하지만, 그 사람의 식생활 습관이나 유전(미생물 분포도)에 의해 체취는 다르게 구현된다. In a social culture that emphasizes the image seen by others, more and more people are aware of the unpleasant odors in my body. The discomfort of the human body can be divided into the human odor caused by the physiological flow and the life odor associated with the dietary habits, and the human body odor appears as a combination of the human odor and the life odor. The sweat and sebum components of a human are the same, but body odor is realized differently depending on the dietary habits and genetics (microbial distribution) of the person.
인체의 특징적인 취는 일반적인 인체 취(연령에 따른 호르몬 변화, 청소년 취, 노인 취)와 식생활 문화와 관련된 생활 취가 더해져 독특한 취를 갖는다. The characteristic odor of the human body has a unique odor due to the addition of general human odors (hormonal changes according to age, adolescent odors, and senile odors) and lifestyle traits associated with the eating culture.
향료를 이용한 기존의 malodor 마스킹 효과는 vapor pressure reduction 기술이 주이다. 이는 악취보다 향이 먼저 휘발되어 인지되도록 하는 기술이다. 일반적으로 악취보다 후각역치(odor threshold)가 낮고 휘발도가 높은 향료는 citrus, herbal 계통의 향취로 한정되며 기호성에 입각한 다양한 향취 개발의 한계가 존재한다.The main malodor masking effect using perfume is vapor pressure reduction technology. This is a technique that allows the smell to be volatilized before perceived. In general, perfumes with lower odor thresholds and higher volatilities than odors are limited to citrus and herbal scents, and there are limitations in developing various scents based on palatability.
최근 데오도란트에 대한 소비자의 관심이 증대되고 시장에 제품이 소개되고 있지만, 대부분 다국적회사 제품으로 땀 억제 성분과 프레시한 느낌의 향(citrus, mint), 베이비 파우더 느낌의 향(powdery)을 사용하고 있다. 위에서 언급한 인체의 특징적인 취에 대한 마스킹 및 관능적 하모나이징 향료 성분에 의한 것은 전무하다.Recently, consumers' interest in Deodorant has been increasing and products have been introduced to the market, but most of them are multinational companies, which use sweat suppressant, fresh citrus, mint, and baby powdery powder. . There is no masking and organoleptic harmonizing flavoring component for the above mentioned characteristic odors of the human body.
종래의 Malodor 마스킹 기술로는 휘발도가 높은 향료 성분을 이용하여 악취보다 빨리 휘발되게 하여 Malodor 를 쉽게 인지하지 못하게 마스킹 하는 기술을 적용한 향료 개발(JP-2804993), 특정 malodor에 관능적으로 하모나이징 효과가 우수한 향료 조합 기술 (US 2010-816717), 모발 염모제나 탈색제품 등에서의 암모니아 냄새의 인지를 낮추어서 일정한 확산 계수 이상의 향료를 사용하여 마스킹 하는 방법(US 6403075) 등이 있다. 악취를 제거하기 위해 다공성 물질인 제올라이트와 실리카를 사용하여 악취를 물리적으로 흡착 시켜서 제거 하는 기술(US-6376741) 등이 있다. Conventional Malodor masking technology uses a highly volatile fragrance ingredient to make it volatilize faster than odors, thus developing a fragrance that masks Malodor easily (JP-2804993). Excellent fragrance combination technology (US 2010-816717), a method of lowering the perception of ammonia odor in hair dyes or bleaching products and masking with fragrances having a constant diffusion coefficient (US 6403075). In order to remove odors, there is a technique of physically adsorbing odors using zeolite and silica, which are porous materials (US-6376741).
따라서 본 발명은 위와 같은 문제점을 해결하고, 마스킹 효과가 우수한 향료 조성물 및 이를 포함하는 화장품 조성물을 제공하고자 한다.Therefore, the present invention is to solve the above problems, to provide a perfume composition and a cosmetic composition having excellent masking effect.
특히, 특징적인 인체 malodor를 효과적으로 마스킹하고 선호도를 고려한 화장품 향료 조성물을 제공하고자 한다.In particular, to effectively mask the characteristic human malodor and to provide a cosmetic fragrance composition in consideration of preference.
본 발명은 넓은 향취 스펙트럼을 가지면서, 체취 마스킹 효과가 우수한 향료 조성물을 제공하고자 한다. 상기 과제를 해결하기 위하여, 본 발명은 인체의 체취(body malodor)를 효과적으로 마스킹할 수 있는 화장품 조성물을 제공한다.The present invention aims to provide a fragrance composition having a broad odor spectrum and excellent body odor masking effect. In order to solve the above problems, the present invention provides a cosmetic composition that can effectively mask the body malodor (body malodor) of the human body.
본 발명의 발명자들은 기존 Malodor Counteractant(이하 MOC)의 특성을 참고하여 마스킹 효과를 연구하던 중, 1) 특정 물리적 성질을 갖는 향료; 및 2) 인체 malodor와 어느 정도의 낮은 반응성이 있을 것으로 예상되는 특정 구조를 갖는 향료를 함께 사용할 경우 인체 특이 취에 탁월한 마스킹 효과뿐 아니라 향기 선호도가 높은 다양한 향기를 갖는 조합 향료를 발견하여, 본 발명을 완성하게 되었다. The inventors of the present invention while studying the masking effect with reference to the characteristics of the existing Malodor Counteractant (hereinafter referred to as MOC), 1) a perfume having a certain physical properties; And 2) finding a combination fragrance having a variety of fragrances with high aroma preference as well as an excellent masking effect on the human-specific odor when using a fragrance having a specific structure expected to have a certain low reactivity with human malodor, the present invention To complete.
기존의 휘발성을 이용한 마스킹의 경우, 사용된 향료가 단순히 악취보다 빨리 휘발될 뿐이며, 허브에 국한된 향취로만 개발 가능하다는 단점이 있었다. 또한, 특정 취에 관능적 하모나이징 역할을 하는 향료도 넓은 향취 스펙트럼을 갖지 못한다는 단점이 있었다. In the case of masking using the existing volatility, the fragrance used is only volatilized faster than the odor, and has the disadvantage that it can be developed only with the odor that is limited to herbs. In addition, fragrances that play a sensory harmonizing role for certain odors have a disadvantage that they do not have a wide odor spectrum.
따라서, 본 발명의 발명자들은 거듭된 연구 결과, 우수한 체취 마스킹 효과를 얻을 수 있는 향료 조성물 및 이를 이용한 화장품 조성물을 제공하게 되었다. 본 발명의 발명자들은 후각 역치가 낮은 향료; 및 적어도 하나 이상의 카르보닐 그룹과 탄소 이중결합이 결합되어 있는 특징을 갖는 향료를 유효성분으로 함께 사용하여 인체 malodor에 더 효과적인 MOC 향료를 개발하게 되었다. 이를 통하여 다양한 향취 개발 가능성을 기반으로 뛰어난 향기 선호도를 갖는 화장품 조성물을 제공한다.Therefore, the inventors of the present invention, as a result of repeated studies, to provide a perfume composition and a cosmetic composition using the same that can obtain an excellent body odor masking effect. The inventors of the present invention provide a perfume with low olfactory threshold; And at least one carbonyl group and a flavor having a carbon double bond combined together as an active ingredient to develop a more effective MOC flavor for human malodor. This provides a cosmetic composition having an excellent fragrance preference based on the development of various scents.
본 명세서에서 사용된 "후각 역치(odor threshold)"는 냄새로 맡을 수 있는, 공기 중 증기의 최소 농도를 의미한다. 일반적으로 낮은 후각 역치를 갖는 화합물은 높은 후각 역치를 갖는 화합물보다 강력하다고 말할 수 있으며, 따라서 후각 효과를 달성하기 위한 향료 조성물에서 매우 적은 농도만을 이용할 수 있다. As used herein, "odor threshold" means the minimum concentration of vapor in the air that can be smelled. In general, compounds with low olfactory thresholds may be said to be more potent than compounds with high olfactory thresholds, and therefore only very small concentrations may be used in the perfume composition to achieve the olfactory effect.
본 명세서에서 사용된 후각 역치는 Leffingwell & Associates의 값을 참고 하였으며, 향료 성분을 20℃에서 물에 용해시켜 측정한 값을 나타낸 것이다. 후각 역치 측정 방법은 Odor Threshold Determinations of 53 Odorant Chemicals 에 소개되었다. The olfactory threshold used herein refers to the value of Leffingwell & Associates, and represents the value measured by dissolving the fragrance component in water at 20 ° C. Odor threshold measurement methods have been introduced in Odor Threshold Determinations of 53 Odorant Chemicals.
본 명세서에서 사용된 향료 성분은 그 자체로 인간의 후각을 자극할 수 있는 후각 역치값을 가지는 단일 화합물을 의미할 수 있다. 본 명세서에서 사용된 향료 조성물은 상기 향료 성분을 하나 이상 포함하고, 2 종 이상의 성분이 전체적으로 혼합된 것을 의미할 수 있다. As used herein, the fragrance component may refer to a single compound having an olfactory threshold value which may itself stimulate human smell. The fragrance composition as used herein may include one or more of the fragrance components, and may mean that two or more components are mixed as a whole.
본 발명은 (A) 후각 역치가 20 ℃ 물에서 0 초과 350ppb 이하이고, 25℃ 에서 증기압이 0.0004mmHg 이상 7.85mmHg 이하인 향료 성분, 및 (B) 적어도 하나 이상의 카르보닐 그룹과 탄소 이중결합이 연결되어 있는 구조를 갖는 향료 성분을 포함하는 체취 마스킹용 향료 조성물을 제공한다. The present invention relates to a fragrance component having (A) an olfactory threshold of greater than 0 and 350 ppb in water at 20 ° C. and a vapor pressure of at least 0.0004 mmHg and up to 7.85 mmHg at 25 ° C., and (B) at least one carbonyl group and a carbon double bond. It provides a fragrance composition for masking body odor comprising a fragrance component having a structure.
본 발명의 발명자들은 상기 (A) 성분 및 (B) 성분을 혼합한 향료 조성물은 탁월한 체취 마스킹 효과를 가진다는 것을 확인하고 본 발명을 완성하게 되었다. The inventors of the present invention have confirmed that the fragrance composition mixed with the component (A) and the component (B) have an excellent body odor masking effect and have completed the present invention.
상기 (A) 후각 역치가 0 초과 350ppb 이하(in water, 20℃)이고, 25℃ 에서 증기압이 0.0004mmHg 이상 7.85mmHg 이하인 향료 성분은 아이소이수퍼(Iso E super), 릴리알(Lilial), 리날룰(Linalool), 스테몬(Stemon), 벤즈알데하이드(Benzaldehyde), 시나믹 알데하이드(Cinnamic aldehyde), 엘-카본(L-carvone), 사이클로피덴(Cyclopidene), 다마스콘 알파(Damascone α),헤디온 (Hedione), 리날릴 아세테이트(Linalyl acetate), 에틸 아세테이트(Ethyl acetate), 메틸 팜플르무스(Methyl pamplemousse), 에틸 메틸-2-부티레이트(Ethyl methyl-2-butyrate), 만자네이트(Manzanate), 에틸 아세테이트(Ethyl acetate), 아이오논 베타(Ionone β), 라스베리 케톤(Raspberry ketone), 자바놀(Javanol) 및 마이올(Mayol)로 이루어진 군에서 선택된 어느 하나 이상의 향료 성분을 포함할 수 있다. 바람직하게는 리날릴 아세테이트(Linalyl acetate), 엘-카본(L-carvone), 릴리알(Lilial), 리날롤(Linalool) 및 마이올(Mayol)로 이루어진 군에서 선택된 어느 하나 이상을 포함할 수 있으며, 더욱 더 바람직하게는 엘-카본(L-carvone), 리날롤(Linalool) 및 마이올을 포함할 수 있다.The fragrance components (A) having an olfactory threshold of 0 to 350 ppb or less (in water, 20 ° C.) and a vapor pressure of 0.0004 mmHg or more and 7.85 mmHg or less at 25 ° C. include Iso E super, Lilial, Li, and Li. Lnalool, Stemon, Benzaldehyde, Cinnamic aldehyde, L-carvone, Cyclopidene, Damasconone α, Hedione (Hedione), Linalyl acetate, Ethyl acetate, Methyl pamplemousse, Ethyl methyl-2-butyrate, Manzanate, Ethyl Ethyl acetate, ionone beta (Ionone β), raspberry ketone (Raspberry ketone), Javanol (Javanol) and may comprise any one or more perfume ingredients selected from the group consisting of Mayol (Mayol). Preferably it may include any one or more selected from the group consisting of linalyl acetate (Linalyl acetate), L-carvone (L-carvone), Lilial (Lilial), Linalol and Mayol (mayol) And even more preferably L-carvone, Linalol and Maiol.
상기 (B) 적어도 하나 이상의 카르보닐 그룹과 탄소 이중결합이 연결되어 있는 구조를 갖는 향료 성분은 큐미닉 알데하이드(cuminicic aldehyde), 에틸 바닐린(ethyl vanillin), 바닐린(vanillin), 시나믹 알데하이드(cinnamic aldehyde), 알파-아밀 시나믹 알데하이드 (α-amyl cinnamic aldehyde), 알파-헥실 시나말데하이드(α-hexyl cinamaldehyde), 헬리오트로핀(Heliotropin), 아니식 알데하이드(Anisic aldehyde), 다마스콘 (Damascone), 메틸 베타-나프틸 케톤(Methyl β-naphthyl ketone), 알파 아이오논(α-Ionone), 아이론(Irone), 시트릴랄(Citrylal), 산드라놀(Sandranol), 알-오션 프로파날(R-Ocean propanal) 및 디나스콘 10(dynascone 10) 로 이루어진 군에서 선택된 어느 하나 이상의 향료 성분을 포함할 수 있다. 바람직하게는 에틸 바닐린(ethyl vanillin), 시트릴랄(Citrylal), 다마스콘 (Damascone), 알파-헥실 시나말데하이드(α-hexyl cinamaldehyde), 아니식 알데하이드(Anisic aldehyde), 디나스콘 10(dynascone 10) 및 산드라놀(Sandranol)로 이루어진 군에서 선택된 어느 하나 이상을 포함할 수 있으며, 더욱 더 바람직하게는 알파-헥실 시나말데하이드(α-hexyl cinamaldehyde), 아니식 알데하이드(Anisic aldehyde), 디나스콘 10(dynascone 10) 및 산드라놀(Sandranol)을 포함할 수 있다.(B) The fragrance component having a structure in which at least one carbonyl group and a carbon double bond are connected is cuminicic aldehyde, ethyl vanillin, vanillin, cinnamic aldehyde ), Alpha-amyl cinnamic aldehyde, alpha-hexyl cinamaldehyde, heliotropin, anisic aldehyde, damascone, Methyl β-naphthyl ketone, alpha-ionone, iron, citrylal, sandranol, al-ocean propanal ) And any one or more perfume ingredients selected from the group consisting of dynascone 10. Preferably, ethyl vanillin, citrylal, damascone, alpha-hexyl cinamaldehyde, anisic aldehyde, dynascone 10 And may include any one or more selected from the group consisting of Sandranol, even more preferably alpha-hexyl cinamaldehyde (α-hexyl cinamaldehyde), anisic aldehyde (Anisic aldehyde), dinascon 10 ( dynascone 10) and Sandranol.
본 발명의 실시예에 따르면, 본 발명의 향료 조성물은 (A) 아이소이수퍼(Iso E super), 릴리알(Lilial), 리날룰(Linalool), 스테몬(Stemon), 벤즈알데하이드(Benzaldehyde), 시나믹알데하이드(Cinnamic aldehyde), 엘-카본(L-carvone), 사이클로피덴(Cyclopidene), 마이올(Mayol), 헥실 시나믹 알데하이드(Hexyl cinnamic aldehyde), 알데하이드 씨14(Aldehyde C14), 및 마이올(Mayol)로 이루어진 군에서 선택된 어느 하나 이상의 향료 성분 및 헬리오트로핀(Heliotropin), 디나스콘 10(Dynascone 10), 산드라놀(Sandranol), 메틸 베타 나프틸 케톤(Methyl beta-naphthyl ketone), 및 시트릴랄(Citrylal)로 이루어진 군에서 선택된 어느 하나 이상의 향료 성분을 포함할 수 있다. According to an embodiment of the present invention, the fragrance composition of the present invention (A) iso super (Iso E super), Lilial (Lilial), Linalul (Linalool), Stemon (Stemon), Benzaldehyde (Benzaldehyde), Cinnamic aldehyde, L-carvone, Cyclopidene, Mayol, Hexyl cinnamic aldehyde, Aldehyde C14, and Myol (Mayol) any one or more flavoring ingredients selected from the group consisting of Heliotropin, Dynascone 10, Sandranol, Methyl beta-naphthyl ketone, and sheet It may include any one or more flavoring ingredients selected from the group consisting of Citrylal.
본 발명의 향료 조성물은 상기 (A) 향료 성분:(B) 향료 성분의 중량비가 1:1 내지 5의 중량비, 바람직하게는 1:1 내지 3의 중량비를 가질 수 있다. The perfume composition of the present invention may have a weight ratio of (A) perfume component: (B) perfume component in a weight ratio of 1: 1 to 5, preferably in a weight ratio of 1: 1 to 3.
상기 중량비를 가질 때 탁월한 마스킹 효과를 얻을 수 있을 뿐만 아니라, 향취 선호도 또한 우수할 수 있다. Not only can an excellent masking effect be obtained when having the above weight ratio, but also aroma preference can be excellent.
본 발명의 일 실시예에 따르면 상기 향료 조성물은 조성물 총 중량 대비 아이소이수퍼 1-20중량%, 릴리알 1-10중량%, 리날룰 5-10중량%, 스테몬 1-5중량%, 벤잘데하이드 1-5중량%, 시나믹 알데하이드 1-10중량%, 엘-카본 1-5중량%, 사이클로피덴 1-5중량%, 마이올 0.5-2중량%, 헥실 시나믹 알데하이드 5-25중량%, 알데하이드 씨14 5-25중량%, 및 마이올 1-5중량%로 이루어진 군에서 선택된 어느 하나 이상의 향료 성분; 및 헬리오트로핀 1-10중량%, 디나스콘 10 0.1-1중량%, 산드라놀 1-10 중량%, 메틸 베타 나프틸 케톤 1-5중량%, 및 시트릴랄 1-10중량%로 이루어진 군에서 선택된 어느 하나 이상의 향료 성분을 포함할 수 있다. According to one embodiment of the present invention, the fragrance composition is 1-20% by weight of isoisuper, 1-10% by weight of lily, 5-10% by weight of linalul, 1-5% by weight of stemon, ben 1-5% by weight of zaldehyde, 1-10% by weight of cinnamic aldehyde, 1-5% by weight of l-carbon, 1-5% by weight of cyclopydene, 0.5-2% by weight of miol, 5-25% of hexyl cinnamic aldehyde At least one perfume component selected from the group consisting of%, 5-25% by weight of aldehyde C14, and 1-5% by weight of miol; And 1-10% by weight of heliotropin, 0.1-1% by weight of dinaconcone, 1-10% by weight of sandronol, 1-5% by weight of methyl beta naphthyl ketone, and 1-10% by weight of citralal It may include any one or more flavoring ingredients selected.
상기 향료 조성물은 다이부틸하이드록시톨루엔, 헵탄산, 옥탄산, 노네날, 옥테날, 3-하이드록시-3-메틸-헥사노익 액시드, 메티오날, 2-아이소프로필-4-메틸 티아졸, 및 트리에틸시트레이트로 이루어진 군에서 선택된 어느 하나 이상의 성분을 마스킹하는데 효과적일 수 있으며, 바람직하게는 메티오날(Methional), 2-아이소프로필-4-메틸 티아졸(2-isopropyl-4-methyl thiazole), 및 3-하이드록시-3-메틸-헥사노익 액시드(3-methyl-hexanoic acid)로 이루어진 군에서 선택된 어느 하나 이상을 마스킹할 수 있다. The fragrance composition is dibutylhydroxytoluene, heptanoic acid, octanoic acid, nonenal, octenal, 3-hydroxy-3-methyl-hexanoic acid, methional, 2-isopropyl-4-methyl thiazole, And triethyl citrate may be effective for masking any one or more components selected from the group consisting of, preferably methional (Methional), 2-isopropyl-4-methyl thiazole (2-isopropyl-4-methyl thiazole ), And 3-hydroxy-3-methyl-hexanoic acid may be masked any one or more selected from the group consisting of.
본 명세서에서 사용된 마스킹이라는 용어는 향료 성분을 이용하여 악취, 거부감이 드는 냄새 등을 인지하기 못하도록 하는 것을 의미하며, 화학적 반응에 의한 탈취로 악취를 제거하는 것과 달리 다른 향료를 이용하여 원인 물질을 관능적으로 인지하지 못하도록 하는 기술을 의미한다.As used herein, the term masking means that the odor, refractory odor, etc. are not recognized by using the fragrance component, and unlike the odor caused by the chemical reaction, the odor substance is removed by using other fragrances. It means a technique that is not to be perceived sensually.
본 발명의 일 실시예에는 상기 체취 마스킹 향료 조성물을 포함하는 화장료 조성물을 제공할 수 있다. 상기 화장료 조성물은 피부, 모발 또는 두피에 적용하는 제형이라면 특별히 제한되지 않으나, 바람직하게 데오도란트 용 바디 팩트, 바디 파우더, 바디워시, 샴푸, 헤어 컨디셔너, 바디로션 및 바디 미스트로 이루어진 군에서 선택된 어느 하나의 제형을 가질 수 있다. 상기 화장료 조성물은 씻어내는 제품(wash-off) 또는 씻어내지 않는 제품(leave-on)일 수 있다. In one embodiment of the present invention may provide a cosmetic composition comprising the body odor masking fragrance composition. The cosmetic composition is not particularly limited as long as it is a formulation applied to the skin, hair or scalp, preferably any one selected from the group consisting of body pact, body powder, body wash, shampoo, hair conditioner, body lotion and body mist for deodorant It may have a formulation. The cosmetic composition may be a wash-off or a leave-on product.
상기 화장료 조성물은 화장품 업계에서 일반적으로 사용되는 성분들과 제조방법을 이용할 수 있다.The cosmetic composition may use the components and the manufacturing method commonly used in the cosmetic industry.
상기 체취 마스킹 향료 조성물은 화장료 조성물 총 중량 대비 0.01 내지 10 중량% 포함될 수 있으며, 바람직하게 0.1 내지 5 중량% 포함될 수 있다. 상기 함량이 0.01 중량% 미만일 경우 향취가 느껴지지 않아 효과가 없을 수 있고, 10 중량% 초과일 경우 향취가 너무 강하여 선호도에 영향을 미치며 제품의 안정성에 부정적일 수 있다. The body odor masking perfume composition may be included 0.01 to 10% by weight relative to the total weight of the cosmetic composition, preferably 0.1 to 5% by weight. If the content is less than 0.01% by weight may not be effective because the smell is not felt, if more than 10% by weight the smell is too strong affects the preference and may be negatively on the stability of the product.
본 발명은 시트러스, 허브로 국한되었던 기존과 달리, 차별적 특성을 갖는 성분들을 조합하여 다양한 향취 방향으로 향취의 선택 범위가 확대된 향료 조성물을 제공한다. The present invention provides a fragrance composition in which a wide range of fragrances are expanded in various fragrance directions by combining components having different characteristics, unlike the conventional ones limited to citrus and herbs.
본 발명은 인체의 체취를 마스킹하는데 효과적인 향료 조성물 및 이를 포함하는 화장품 조성물을 제공할 수 있다. The present invention can provide a perfume composition effective to mask the body odor of the human body and a cosmetic composition comprising the same.
이하, 본 발명을 보다 구체적으로 설명하기 위하여 하기 실시예 등을 들어 설명한다. 그러나, 본 발명에 따른 실시예들은 여러 가지 다른 형태로 변형될 수 있으며 본 발명의 범위가 아래에서 상술하는 실시예들에 한정되는 것으로 해석되어서는 안 된다. 본 발명의 실시예들은 본 발명의 구체적 이해를 돕기 위해 예시적으로 제공되는 것이다.Hereinafter, the following examples and the like will be described in order to describe the present invention in more detail. However, embodiments according to the present invention can be modified in many different forms and the scope of the present invention should not be construed as being limited to the embodiments described below. Embodiments of the present invention are provided by way of example in order to facilitate a specific understanding of the present invention.
[시험예 1] 한국인 체취 채집 및 분석 방법과 결과[Test Example 1] Methods for collecting and analyzing body odor
한국인을 대상으로 체취를 채집하여 실험을 하였다.The experiment was conducted by collecting body odors from Koreans.
체취를 채집하기 위해서, 실험 대상자인 20-60대 남녀 20명에게 무향 제품으로 세탁처리 한 면 티셔츠와 무향 바디워시를 대상 인원에게 제공한다. To collect body odors, 20 males and females in their 20s and 60s, subject to the experiment, will be provided with cotton t-shirts and fragrance-free body washes that were washed with fragrance-free products.
제공된 무향 바디워시를 이용하여 샤워한 후 1인당 면 티셔츠 1종을 1일 수면 시간 동안 착용하여 체취가 베게 한다. 밀봉하여 회수된 티셔츠를 개봉하여 등 부분을 오려내어(25X25cm) 반으로 나눈 다음 체취 평가와 기기 분석을 실시 한다.After taking a shower using the fragrance-free body wash provided, one piece of cotton T-shirt per person may be worn for one day's sleep period to allow body odor to be cut. Open the sealed T-shirt, cut it out, cut it in half (25 x 25 cm), and perform body odor evaluation and instrument analysis.
기기 분석은 GC-MS를 이용하여 SPME 법으로 진행하였고 분석 조건은 다음과 같다.Instrument analysis was performed by SPME method using GC-MS, and analysis conditions were as follows.
== 다음 ==== next ==
- 사용 기기: Agilent 6890N/5973 inertInstrument used: Agilent 6890N / 5973 inert
- 컬럼: BC-WAX (GL Science, 50m X 0.25mm, df=0.15㎛)Column: BC-WAX (GL Science, 50 m × 0.25 mm, df = 0.15 μm)
- 분석 조건: Head pressure: 120Kpa, Splitness, 오븐 온도 70-220 (4C/min), Detector: MSD, Carrier gas: HeAnalytical conditions: Head pressure: 120 Kpa, Splitness, Oven temperature 70-220 (4 C / min), Detector: MSD, Carrier gas: He
상기 분석 결과를 토대로 새로 조합한 표 1의 조성을 갖는 인체 malodor 조합 향료를 만들고, 전문 조향사 그룹의 관능 평가를 통하여 실제 한국인의 인체 malodor와 유사함을 확인하였다.Based on the analytical results, a new combination of human malodor fragrance having the composition of Table 1 was prepared, and the sensory evaluation of the professional steering group was confirmed to be similar to the actual human malodor of Korean.
한국인 인체 Malodor 조성Malodor composition of Korean human body
물질명Substance 함량 (중량%)Content (% by weight)
다이부틸하이드록시톨루엔Dibutylhydroxytoluene 1.01.0
헵탄산Heptanoic acid 10.010.0
옥탄산Octanoic acid 10.010.0
노네날Nonenal 1%함유 트리에틸시트레이트 15.01% triethyl citrate 15.0
옥테날Octenal 1%함유 트리에틸시트레이트 2.51% triethyl citrate 2.5
3-하이드록시-3-메틸-헥사노익 액시드3-hydroxy-3-methyl-hexanoic acid 1%함유 트리에틸시트레이트 25.01% triethyl citrate 25.0
메티오날Methional 3%함유 트리에틸시트레이트 10.03% triethyl citrate 10.0
2-아이소프로필-4-메틸 티아졸2-isopropyl-4-methyl thiazole 3%함유 트리에틸시트레이트 15.03% triethyl citrate 15.0
트리에틸시트레이트Triethyl citrate 11.511.5
인체 malodor는 fatty, acidic, aldehydic, watery의 특징인 취를 가지고 있다. 메티오날, 2-아이소프로필-4-메틸 티아졸, 3-하이드록시-3-메틸-헥사노익 액시드 등 몇 가지 성분의 조합이 인체 malodor의 고유 향취를 만들어내는 주요 성분임을 확인하였다.Human malodor has odor which is characteristic of fatty, acidic, aldehydic and watery. Several combinations of components, such as methional, 2-isopropyl-4-methyl thiazole, and 3-hydroxy-3-methyl-hexanoic acid, have been identified as key ingredients in creating the malodor of human malodor.
[시험예 2] 씻어내는 제품(Wash-off)에 대한 마스킹 효과 평가 방법[Test Example 2] Evaluation method of the masking effect on the wash-off product
Blotter(3X3cm)에 평가용 조합 향료를 부향한 샘플 0.2g을 골고루 바르고, 1분 후 100mL 물로 헹군다. 표 1의 인체 Malodor 4% 희석 용액 0.1mL를 blotter의 지정된 3개 점에 바르고 2시간 후에 표 2의 설문지1로 관능 평가를 실시한다.Evenly apply 0.2 g of the sample, flavored with the evaluation combination fragrance, to Blotter (3 × 3 cm) and rinse with 100 mL water after 1 minute. 0.1 mL of the human Malodor 4% dilution solution of Table 1 is applied to three designated points of the blotter and 2 hours later the sensory evaluation is performed with Questionnaire 1 of Table 2.
[시험예 3] 씻어내지 않는 제품(Leave-on)에 대한 마스킹 효과 평가 방법[Test Example 3] Evaluation method of the masking effect on the product (Leave-on) not washed off
Blotter(3X3cm)에 평가용 조합 향료를 부향한 샘플 0.2g을 골고루 바르고, 1분 후 표 1의 인체 Malodor 4% 희석 용액 0.1mL를 blotter의 지정된 3개 점에 바르고 2시간 후에 표 2의 설문지1로 관능 평가를 실시한다.Evenly apply 0.2 g of the sample containing the fragrance combination for evaluation to Blotter (3X3 cm) evenly, and after 1 minute, apply 0.1 mL of the human Malodor 4% dilution solution of Table 1 to three designated points of the blotter, and after 2 hours, the questionnaire 1 of Table 2 Sensory evaluation is performed by.
[시험예 4] 씻어내는 제품(Wash-off)에 대한 향기 선호도 평가 방법[Test Example 4] Evaluation of fragrance preference for the wash-off product
Blotter(3X3cm)에 평가용 조합 향료를 부향한 샘플 0.2g을 골고루 바르고, 1분 후 100mL 물로 헹군다. 표 1의 인체 Malodor 4% 희석 용액 0.1mL를 blotter의 지정된 3개 점에 바르고 2시간 후에 표 3의 설문지2로 관능 평가를 실시한다.Evenly apply 0.2 g of the sample, flavored with the evaluation combination fragrance, to Blotter (3 × 3 cm) and rinse with 100 mL water after 1 minute. 0.1 mL of the human Malodor 4% dilution solution of Table 1 is applied to three designated points of the blotter and sensory evaluation is performed with Questionnaire 2 of Table 3 after 2 hours.
[시험예 5] 씻어내지 않는 제품(Leave-on)에 대한 향기 선호도 평가 방법[Test Example 5] Evaluation of the aroma preference for the product (Leave-on) not washed off
Blotter(3X3cm)에 평가용 조합 향료를 부향한 샘플 0.2g을 골고루 바르고, 1분 후 표 1의 인체 Malodor 4% 희석 용액 0.1mL를 blotter의 지정된 3개 점에 바르고 2시간 후에 표 3의 설문지2로 관능 평가를 실시한다.Evenly apply 0.2 g of the sample containing the fragrance-based fragrance for evaluation to Blotter (3X3 cm), and after 1 minute, apply 0.1 mL of the human Malodor 4% dilution solution of Table 1 to three designated points of the blotter, and after 2 hours, the questionnaire of Table 3 Sensory evaluation is performed by.
설문지1 (malodor intensity 평가)Questionnaire 1 (malodor intensity evaluation)
구분division Malodor intensity*Malodor intensity *
1One 냄새 나지 않음Does not smell
22 아주 약하게 느껴짐Feels very weak
33 약하게 느껴짐Feeling weak
44 중간 강도Medium strength
55 강함Strong
66 매우 강함Very strong
*Malodor intensity는 MOC 개발향료의 인체 malodor 마스킹 효과를 고려한 평가 항목임.* Malodor intensity is an evaluation item considering the human malodor masking effect of MOC-developed fragrance.
설문지2(샘플에 대한 향취 선호도)Questionnaire 2 (Favorite Preference for Samples)
구분division 향취 선호도Scent preference
1One 전혀 좋지 않음Not good at all
22 별로 좋지 않음Not so good
33 보통usually
44 약간 좋음Slightly good
55 매우 좋음Very good
[조합 향료 제조: 비교예 1~3 및 실시예 1~6][Combined fragrance manufacture: Comparative Examples 1 to 3 and Examples 1 to 6]
순서대로 투입하여 균일하게 교반 용해 시켜 조합 향료를 제조 한다.Put in order to dissolve uniformly to prepare a combination fragrance.
향료명Perfume 비교예(중량%)Comparative example (% by weight) 실시예(중량%)Example (% by weight)
1One 22 1One 22 33 44 55 66
헤디온Hedion 2020 2020 2020 2020 3030 2020 2020 2020
메틸팜플레모스Methyl Flamples 1010 1010 1010 1010 1010 1010 1010 55
리날릴 아세테이트Linalyl acetate 55 55 1One 1One 1One 66 1One 1One
갈락솔라이드Galaxolide 55 55 1One 1One 1One 66 1One 1One
아이소이수퍼Isoi super 1010 -- 1010 1010 1010 55 55 55
릴리알Lilly 55 -- 6.56.5 33 6.56.5 -- -- --
리날롤Linalol 2020 -- 55 55 55 55 55 55
스테몬Stemon 22 -- -- 55 55 -- -- --
아니식 알데하이드Aniform aldehyde 55 -- 2020 -- 1010 1010 1010 1010
벤즈알데하이드Benzaldehyde 55 -- -- -- 55 55 55 55
시나믹알데하이드Cinnamicaldehyde 55 -- 1010 -- 1010 55 55 55
엘-카본L-Carbon 33 -- -- 1One -- 1One 1One 1One
사이클로피덴Cyclopydene 33 -- 44 -- -- -- --
마이올Maiol 22 -- 1One 1One -- 1One 1One 1One
알파 헥실 시나믹 알데하이드Alpha hexyl cinnamic aldehyde -- 1010 55 1212 -- 1010 2020 2525
알데하이드 씨14Aldehyde C14 -- 2525 -- -- -- 1010 1010 1010
헬리오트로핀 Heliotropin -- 88 55 1010 55 -- -- --
디나스콘 10Dinascon 10 -- 1One 1One 1One 1One 1One 1One 1One
산드라놀Sandranol -- 55 -- 1010 -- 55 55 55
메틸-베타 나프틸 케톤Methyl-beta naphthyl ketone -- 55 0.30.3 55 0.30.3 -- -- --
시트릴랄Citralal -- 66 0.20.2 55 0.20.2 -- -- --
표 4에 나타낸 함량으로 제조된 조합 향료들에 대하여 씻어내는 제품(Wash-off)인 바디 워시(제형예 1, 표 10)에 대한 마스킹 효과는 전문 조향사 12명을 대상으로 표 2의 설문지1로 관능 평가를 하였으며, 평가 결과는 표 5에 나타내었다. The masking effect on the body wash (Formulation Example 1, Table 10), which is a wash-off product for the combination fragrances prepared at the contents shown in Table 4, was obtained from Questionnaire 1 of Table 2 of 12 professional stewards. Sensory evaluation was made, and the evaluation results are shown in Table 5.
향료명Perfume 비교예Comparative example 실시예Example
1One 22 1One 22 33 44 55 66
Malodor intensityMalodor intensity 4.54.5 4.24.2 2.52.5 2.52.5 2.82.8 2.62.6 2.32.3 2.32.3
표 4에 나타낸 함량으로 제조된 조합 향료들에 대하여 씻어내지 않는 제품(Leave-in)인 바디 로션(제형예 2, 표 11)에 대한 마스킹 효과는 전문 조향사 12명을 대상으로 표 2의 설문지1로 관능 평가를 하였으며, 평가 결과는 표 6에 나타내었다. The masking effect of the body lotion (Formula 2, Table 11), which is a non-washable product (Leave-in) for the combination perfumes prepared in the contents shown in Table 4, was investigated in the questionnaire 1 of 12 of the professional stewards. The sensory evaluation was performed, and the evaluation results are shown in Table 6.
향료명Perfume 비교예Comparative example 실시예Example
1One 22 1One 22 33 44 55 66
Malodor intensityMalodor intensity 4.24.2 4.44.4 2.52.5 2.32.3 2.82.8 2.62.6 2.32.3 2.12.1
표 4에 나타낸 함량으로 제조된 조합 향료들에 대하여 씻어내는 제품(Wash-off)인 바디 워시(제형예 1, 표 10)에 대한 향기 선호도는 25~40세의 건강한 일반 남녀 30명을 대상으로 표 3의 설문지2로 평가를 실시하였다. 이때 후감각 마비현상이 없도록 견본 간 5분의 휴식 시간을 제공하였다. 그 결과는 표 7에 나타내었다. The fragrance preference for the body wash (Formulation Example 1, Table 10), which is a wash-off product for the combination fragrances prepared in the contents shown in Table 4, was collected from 30 healthy men and women aged 25 to 40 years. Evaluation was conducted with Questionnaire 2 of Table 3. At this time, a 5-minute break was provided between the samples so that there was no olfactory paralysis. The results are shown in Table 7.
향료명Perfume 비교예Comparative example 실시예Example
1One 22 1One 22 33 44 55 66
향취 선호도Scent preference 2.82.8 3.33.3 3.93.9 44 44 4.24.2 4.44.4 4.14.1
표 4에 나타낸 함량으로 제조된 조합 향료들에 대하여 씻어내지 않는 제품(Leave-on)인 바디 로션(제형예 2, 표 11)에 대한 향기 선호도는 25~40세의 건강한 일반 남녀 30명을 대상으로 표 3의 설문지2로 평가를 실시하였다. 이때 후감각 마비현상이 없도록 견본 간 5분의 휴식 시간을 제공하였다. 그 결과는 표 8에 나타내었다. The fragrance preference for body lotion (Formulation Example 2, Table 11), which is a non-washable product (Leave-on) for the combination flavors prepared in the contents shown in Table 4, was applied to 30 healthy men and women aged 25 to 40 years. The questionnaire 2 of Table 3 was used to evaluate. At this time, a 5-minute break was provided between the samples so that there was no olfactory paralysis. The results are shown in Table 8.
향료명Perfume 비교예Comparative example 실시예Example
1One 22 1One 22 33 44 55 66
향취 선호도Scent preference 2.82.8 3.03.0 3.93.9 3.83.8 44 4.04.0 4.24.2 4.14.1
인체 Malodor와 다소 휘발도가 높은 시트러스 허벌(Citrus herbal)은 일정 시간이 지나면 인체 Malodor와 향을 같이 느끼게 되는 역효과가 있었고, 앰버리 머스키(Ambery musky)한 향에는 누린 내가 더 나는 역효과가 있으며, 플로럴 오리스(Floral orris) 향이 강하면 굽굽한 남성 취가 더 나는 역효과가 나타났고, 톡쏘는 산취(sparkling acidic)의 향기는 서로 조화롭지 않은 역효과를 나타내었다. 약간의 시프레 악센트(Chypre accent), 아로마틱 후제아(Aromatic fougere), 플로럴 후르티(Floral fruity)는 향기를 조화롭게 하는 것으로 평가되었다. Malodor and the highly volatile Citrus herbal have the opposite effect of feeling malodor with Malodor after a certain period of time.Amery musky scent has the opposite effect that I enjoyed. A strong floral orris scent had a more adverse effect of stiff male odor, and the fragrance of sparkling acidic had an incompatible effect. A few Cypre accents, Aromatic fougere and Floral fruity were evaluated to harmonize the scent.
상기 시험예 1로부터, 인체 Malodor의 특징적인 향취의 주 성분이 메티오날과 3-하이드록시-3-메틸-헥사노익 액시드의 조합으로 인체 특이 취를 발생시킴을 확인할 수 있었다. From Test Example 1, it can be seen that the main component of the characteristic odor of human malodor causes human specific odor by the combination of methional and 3-hydroxy-3-methyl-hexanoic acid.
본 발명자는 본 발명에 따른 인체 Malodor 성분에 대해 마스킹 효과가 탁월하면서도, 다양한 향기 계열과 향기 선호도가 좋은 조합 향료에 적합한 적어도 하나 이상의 카르보닐 그룹과 탄소 이중결합이 conjugated되어 있는 특징을 갖는 향료 물질을 표 9에 표기하였다.The inventors of the present invention provide a fragrance material having a masking effect on the human malodor component according to the present invention, but having at least one carbonyl group and carbon double bonds conjugated to a variety of fragrances and fragrances having good aroma preference. It is shown in Table 9.
향료 물질Fragrance substance 향취Aroma 향료 물질Fragrance substance 향취Aroma
Anisic aldehydeAnisic aldehyde AnisicAnisic Dartanol (=sandranol)Dartanol (= sandranol) WoodyWoody
BenzaldehydeBenzaldehyde FruityFruity R-ocean propanalR-ocean propanal FloralFloral
Cuminic aldehydeCuminic aldehyde SpicySpicy Mayol®Mayol® FloralFloral
Cinnamic aldehydeCinnamic aldehyde SpicySpicy Vanillin Vanillin VanillaVanilla
α-amyl cinnamic ald.α-amyl cinnamic ald. FloralFloral (ethyl) crotonate(ethyl) crotonate FermentedFermented
α-hexyl cinnamic ald.α-hexyl cinnamic ald. FloralFloral Methyl β-naphthyl ketoneMethyl β-naphthyl ketone FloralFloral
Ethyl vanillinEthyl vanillin VanillaVanilla Aldehyde C14Aldehyde C14 FruityFruity
Heliotropin Heliotropin FloralFloral L-carvoneL-carvone MintyMinty
Dynascone® 10 Dynascone® 10 GreenGreen Cyclopidene Cyclopidene FloralFloral
Citrylal Citrylal CitrusCitrus
이를 활용하면 기존의 시트러스(Citrus), 허벌(Herbal)로 국한된 것과 비교하여 플로럴(Floral), 후르티(Fruity), 우디(Woody), 그린(Green), 바닐라(Vanilla) 등으로 다양한 향기 방향의 새로운 조합 향료 개발이 가능하게 되었다.This allows the use of new fragrances in various fragrances, such as Floral, Fruity, Woody, Green, Vanilla, etc., compared to traditional Citrus and Herbal. Combination fragrance development is now possible.
[제형예 1]Formulation Example 1
상기에서와 같이 본 발명의 조합향료 조성물을 배합하여, 표 10의 바디 워시를 제조하였다.As described above, the combination perfume composition of the present invention was formulated to prepare a body wash of Table 10.
본 발명의 조합향료 조성물을 함유하는 바디워시 (함량: 중량%)Body wash containing the combination perfume composition of the present invention (content: wt%) 실험예 1Experimental Example 1 실험예 2Experimental Example 2 실험예 3Experimental Example 3
본 발명의 조합향료 (실시예 1)Polyoxyethylene sodium lauryl sulfate (30%)Polyquaternium -10 (polymer JR-400)Phenoxyethanol구연산 EDTA 4Na물Combination perfume of the present invention (Example 1) Polyoxyethylene sodium lauryl sulfate (30%) Polyquaternium -10 (polymer JR-400) Phenoxyethanol Citric acid EDTA 4Na water 0.01200.50.5적량적량To 1000.01200.50.5 Appropriate quantityTo 100 0.8200.50.5적량적량To 100Proper ToTo 100 15200.50.5적량적량To 100Proper ToTo 100
실험예 2에 따른 마스킹 효과 평가 결과 실험 예1은 거의 효과가 없었고, 실험예 2는 향취가 너무 강해 거부감과 함께 제형 안정성에 문제가 발생했다.As a result of evaluating the masking effect according to Experimental Example 2, Experimental Example 1 was almost ineffective, and Experimental Example 2 was too strong in odor, causing problems in formulation stability with rejection.
[제형예 2]Formulation Example 2
상기에서와 같이 본 발명의 조합향료 조성물을 배합하여, 표 11의 바디 로션를 제조하였다.As described above, the combination perfume composition of the present invention was combined to prepare a body lotion of Table 11.
본 발명의 조합향료 조성물을 함유하는 바디로션 (함량: 중량%)Body lotion containing the combination perfume composition of the present invention (content: wt%) 실험예 1Experimental Example 1 실험예 2Experimental Example 2 실험예 3Experimental Example 3
본 발명의 조합향료 (실시예 3)물Glycerin PEG 40 hydrogenated castor oil미네랄 오일Carbomer (Carbopol 940)Methyl parabenTriethanolamineCombination perfume of the present invention (Example 3) Water Glycerin PEG 40 hydrogenated castor oil Mineral oil Carbomer (Carbopol 940) Methyl paraben Triethanolamine 0.01To 10051100.10.20.10.01To 10051100.10.20.1 0.5To 10051100.10.20.10.5To 10051100.10.20.1 15To 10051100.10.20.115To 10051100.10.20.1
실험예 2에 따른 마스킹 효과 평가 결과 실험 예1은 거의 효과가 없었고, 실험예 2은 향취가 너무 강해 거부감과 함께 제형 안정성에 문제가 발생했다.As a result of evaluating the masking effect according to Experimental Example 2, Experimental Example 1 was almost ineffective, and Experimental Example 2 had too strong aroma, causing problems in formulation stability with rejection.
[제형예 3][Formulation Example 3]
상기에서와 같이 본 발명의 조합향료 조성물을 배합하여, 표 12의 데오팩트를 제조하였다.As described above, the combination perfume composition of the present invention was blended to prepare a depot of Table 12.
본 발명의 조합향료 조성물을 함유하는 데오팩트 (함량: 중량%)Deo pact containing the combination perfume composition of the present invention (content: wt%) 실험예 1Experimental Example 1 실험예 2Experimental Example 2 실험예 3Experimental Example 3
본 발명의 조합향료 (실시예 5)티타늄옥사이드마이카탈크산화철Methyl parabenSilicone oil (6cSt)Isopropyl palmitateCombination fragrance of the present invention (Example 5) Titanium oxide Mycatal iron oxide Methyl parabenSilicone oil (6cSt) Isopropyl palmitate 0.0110.020.0To 1005.00.25.05.00.0110.020.0To 1005.00.25.05.0 0.510.020.0To 1005.00.25.05.00.510.020.0To 1005.00.25.05.0 1510.020.0To 1005.00.25.05.01510.020.0To 1005.00.25.05.0
실험예 2에 따른 마스킹 효과 평가 결과 실험 예1은 거의 효과가 없었고, 실험예 2은 향취가 너무 강해 거부감과 함께 제형 안정성에 문제가 발생했다.As a result of evaluating the masking effect according to Experimental Example 2, Experimental Example 1 was almost ineffective, and Experimental Example 2 had too strong aroma, causing problems in formulation stability with rejection.
본 발명은 인체의 체취를 마스킹하는데 효과적인 향료 조성물 및 이를 포함하는 화장품 조성물을 제공할 수 있다.The present invention can provide a perfume composition effective to mask the body odor of the human body and a cosmetic composition comprising the same.
본 발명은 향료, 인체 세정제, 화장품 등 다양한 분야에서 이용될 수 있다.The present invention can be used in various fields, such as perfume, human cleanser, cosmetics.

Claims (10)

  1. (A) 후각 역치가 0초과 350ppb 이하(in water, 20℃)이고, 25℃ 에서 증기압이 0.0004mmHg 이상 7.85mmHg 이하인 향료 성분; 및 (A) the fragrance component having an olfactory threshold greater than 0 and no greater than 350 ppb (in water, 20 ° C) and a vapor pressure of at least 0.0004 mmHg and not more than 7.85 mmHg at 25 ° C; And
    (B) 적어도 하나 이상의 카르보닐 그룹과 탄소 이중결합이 연결되어 있는 구조를 갖는 향료 성분을 포함하는, 체취 마스킹용 향료 조성물.(B) A fragrance composition for body odor masking comprising a fragrance component having a structure in which at least one carbonyl group and a carbon double bond are connected.
  2. 제1항에 있어서, 상기 (A) 후각 역치가 0초과 350ppb 이하(in water, 20℃)이고, 25℃에서 증기압이 0.0004mmHg 이상 7.85mmHg 이하인 향료 성분은 아이소이수퍼(Iso E super), 릴리알(Lilial), 리날룰(Linalool), 스테몬(Stemon), 벤잘데하이드(Benzaldehyde), 시나믹 알데하이드(Cinnamic aldehyde), 엘-카본(L-carvone), 사이클로피덴(Cyclopidene), 다마스콘 알파(Damascone α),헤디온 (Hedione), 리날릴 아세테이트(Linalyl acetate), 에틸 아세테이트(Ethyl acetate), 메틸 팜플르무스(Methyl pamplemousse), 에틸 메틸-2-부티레이트(Ethyl methyl-2-butyrate), 만자네이트(Manzanate), 에틸 아세테이트(Ethyl acetate), 아이오논 베타(Ionone β), 라스베리 케톤(Raspberry ketone), 자바놀(Javanol)및 마이올(Mayol)로 이루어진 군에서 선택된 어느 하나 이상의 향료 성분을 포함하는, 체취 마스킹용 향료 조성물.The perfume component according to claim 1, wherein the perfume component (A) has an olfactory threshold greater than 0 and no greater than 350 ppb (in water, 20 ° C.), and has a vapor pressure of at least 0.0004 mmHg and not more than 7.85 mmHg at 25 ° C. (Iso E super, Lily). Lial, Linalool, Stemon, Benzaldehyde, Cinnamic aldehyde, L-carvone, Cyclopidene, Damascon Alpha (Damascone α), Hedione, Linalyl acetate, Ethyl acetate, Methyl pamplemousse, Ethyl methyl-2-butyrate, One or more perfume ingredients selected from the group consisting of Manzanate, Ethyl acetate, Ionone β, Raspberry ketone, Javanol and Mayol Containing, fragrance composition for body odor masking.
  3. 제1항에 있어서, 상기 (B) 적어도 하나 이상의 카르보닐 그룹과 탄소 이중결합이 연결되어 있는 구조를 갖는 향료 성분은 큐미닉 알데하이드(cuminicic aldehyde), 에틸 바닐린(ethyl vanillin), 바닐린(vanillin), 시나믹 알데하이드(cinnamic aldehyde), 알파-아밀 시나믹 알데하이드 (α-amyl cinnamic aldehyde), 알파-헥실 시나말데하이드(α-hexyl cinamaldehyde), 헬리오트로핀(Heliotropin), 아니식 알데하이드(Anisic aldehyde), 다마스콘 (Damascone), 메틸 베타-나프틸 케톤(Methyl β-naphthyl ketone), 알파 아이오논(α-Ionone), 아이론(Irone), 시트릴랄(Citrylal), 산드라놀(Sandranol), 알-오션 프로파날(R-Ocean propanal) 및 디나스콘 10(dynascone 10) 로 이루어진 군에서 선택된 어느 하나 이상의 향료 성분을 포함하는, 체취 마스킹용 향료 조성물.According to claim 1, wherein (B) the fragrance component having a structure in which at least one carbonyl group and a carbon double bond is connected to the cubic aldehyde (cuminicic aldehyde), ethyl vanillin (ethyl vanillin), vanillin (vanillin), Cinnamic aldehyde, alpha-amyl cinnamic aldehyde, alpha-hexyl cinamaldehyde, heliotropin, anisic aldehyde, Damascone, Methyl β-naphthyl ketone, α-Ionone, Iron, Citrylal, Sandranol, Al-Ocean Pro Panal (R-Ocean propanal) and dynascon 10 (dynascone 10) comprising any one or more flavoring ingredients selected from the group consisting of, perfume composition for masking body odor.
  4. 제1항에 있어서, 상기 향료 조성물은According to claim 1, wherein the fragrance composition
    아이소이수퍼(Iso E super), 릴리알(Lilial), 리날룰(Linalool), 스테몬(Stemon), 아니식 알데하이드(Anisic aldehyde), 벤잘데하이드(Benzaldehyde), 시나믹알데하이드(Cinnamic aldehyde), 엘-카본(L-carvone), 사이클로피덴(Cyclopidene), 마이올(Mayol), 헥실 시나믹 알데하이드(Hexyl cinnamic aldehyde), 감마-운데칼락톤(γ-undecalactone), 및 마이올(Mayol)로 이루어진 군에서 선택된 어느 하나 이상의 향료 성분; 및Iso E super, Lilial, Linalool, Stemone, Anisic aldehyde, Benzaldehyde, Cinnamic aldehyde, L-Carvone, Cyclopidene, Mayol, Hexyl cinnamic aldehyde, Gamma-undecalactone, and Mayol Any one or more perfume ingredients selected from the group; And
    헬리오트로핀(Heliotropin), 디나스콘 10(Dynascone 10), 산드라놀(Sandranol), 메틸 베타 나프틸 케톤(Methyl beta-naphthyl ketone), 및 시트릴랄(Citrylal)로 이루어진 군에서 선택된 어느 하나 이상의 향료 성분을 포함하는 체취 마스킹용 향료 조성물.At least one perfume component selected from the group consisting of heliotropin, Dynascone 10, Sandranol, methyl beta-naphthyl ketone, and citrylal Perfume composition for masking body odor comprising a.
  5. 제1항에 있어서, 상기 향료 조성물은 (A) 향료 성분:(B) 향료 성분의 중량비가 1:1 내지 3의 중량비를 갖는 것을 특징으로 하는 체취 마스킹용 향료 조성물.The perfume composition according to claim 1, wherein the perfume composition has a weight ratio of (A) perfume component: (B) perfume component in a weight ratio of 1: 1 to 3.
  6. 제4항에 있어서, 상기 향료 조성물은The fragrance composition of claim 4, wherein
    향료 조성물 총 중량 대비 아이소이수퍼 1-20중량%, 릴리알 1-10중량%, 리날룰 5-10중량%, 스테몬 1-5중량%, 벤잘데하이드 1-5중량%, 시나믹 알데하이드 1-10중량%, 엘-카본 1-5중량%, 사이클로피덴 1-5중량%, 마이올 0.1-2중량%, 헥실 시나믹 알데하이드 5-25중량%, 알데하이드 씨14 1-25중량% 및 마이올 1-5중량%로 이루어진 군에서 선택된 어느 하나 이상의 향료 성분; 및1-20% by weight of isoisuper, 1-10% by weight of lily, 5-10% by weight of linalul, 1-5% by weight of stemon, 1-5% by weight of benzaldehyde, cinnamic aldehyde 1-10% by weight, 1-5% by weight of L-carbon, 1-5% by weight of cyclopydene, 0.1-2% by weight of myol, 5-25% by weight of hexyl cinnamic aldehyde, 1-25% by weight of aldehyde C14 and At least one perfume component selected from the group consisting of 1-5% by weight of miol; And
    헬리오트로핀 1-10중량%, 디나스콘 10 0.1-1중량%, 산드라놀 1-10 중량%, 메틸 베타 나프틸 케톤 1-5중량%, 아니식 알데하이드 중량5-10% 및 시트릴랄 1-10중량%로 이루어진 군에서 선택된 어느 하나 이상의 향료 성분을 포함하는 체취 마스킹용 향료 조성물. 1-10% by weight heliotropin, 0.1-1% by weight dinascone, 1-10% by weight sandronol, 1-5% by weight methyl beta naphthyl ketone, 5-10% by weight of anicaldehyde aldehyde and citralal 1- Perfume composition for masking body odor comprising at least one perfume component selected from the group consisting of 10% by weight.
  7. 제1항에 있어서, 상기 향료 조성물은 메티오날(Methional), 2-아이소프로필-4-메틸 티아졸(2-isopropyl-4-methyl thiazole), 및 3-하이드록시-3-메틸-헥사노익 액시드(3-methyl-hexanoic acid)로 이루어진 군에서 선택된 어느 하나 이상을 마스킹하는 것을 특징으로 하는 체취 마스킹용 향료 조성물.According to claim 1, wherein the fragrance composition is methional (Methional), 2-isopropyl-4-methyl thiazole, and 3-hydroxy-3-methyl-hexanoic liquid Flavor composition for masking body odor, characterized in that masking any one or more selected from the group consisting of seeds (3-methyl-hexanoic acid).
  8. 제1항 내지 제7항 중 어느 한 항의 체취 마스킹용 향료 조성물을 포함하는 화장료 조성물.Cosmetic composition containing the fragrance composition for masking odor of any one of claims 1 to 7.
  9. 제8항에 있어서, 상기 화장료 조성물은 상기 데오도란트 용 바디 팩트, 바디 파우더, 바디워시, 샴푸, 헤어 컨디셔너, 바디로션 및 바디 미스트로 이루어진 군에서 선택된 어느 하나의 제형을 갖는 것을 특징으로 하는 화장료 조성물.The cosmetic composition according to claim 8, wherein the cosmetic composition has any one formulation selected from the group consisting of a body pact, a body powder, a body wash, a shampoo, a hair conditioner, a body lotion, and a body mist for the deodorant.
  10. 제8항에 있어서, 상기 화장료 조성물은 씻어내는 제품(wash-off) 또는 씻어내지 않는 제품(leave-on)인 화장료 조성물.The cosmetic composition of claim 8, wherein the cosmetic composition is a wash-off or a leave-on product.
PCT/KR2016/003204 2016-03-29 2016-03-29 Perfume composition for masking body odor and cosmetic composition comprising same WO2017171108A1 (en)

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US5795566A (en) * 1989-05-29 1998-08-18 Robertet S.A. Deodorant compositions containing at least two aldehydes and the deodorant products containing them
JP2002285189A (en) * 2001-01-16 2002-10-03 Kanebo Ltd Perfumery composition
KR20030044306A (en) * 2001-11-29 2003-06-09 씨제이 주식회사 Composition of aromatic plants for deodorization
US20080050326A1 (en) * 2006-08-22 2008-02-28 David Frederick Swaile Deodorant composition comprising linalool and dihydromyrcenol
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