KR20030029880A - 착화 구조체, 액상 유출물을 처리하는 장치 및 방법 - Google Patents
착화 구조체, 액상 유출물을 처리하는 장치 및 방법 Download PDFInfo
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- KR20030029880A KR20030029880A KR10-2003-7002966A KR20037002966A KR20030029880A KR 20030029880 A KR20030029880 A KR 20030029880A KR 20037002966 A KR20037002966 A KR 20037002966A KR 20030029880 A KR20030029880 A KR 20030029880A
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- film
- ions
- effluent
- complexing
- polymer
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- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
NH3농도 (mol.ℓ-1) | 1.1 | 1.6 | 3 | 16 |
구리 용액의 농도 레벨 또는 그 양 (15㎎.ℓ-1)L | 500 | 700 | 13000 | 7000 |
Claims (20)
- 기판 및 기판 상에 위치하는 필름을 포함하며, 상기 필름이 이온을 착화시킬 수 있는 중합체 또는 전기적으로 중성인 유기 공중합체로 그래프트된 착화 구조체.
- 제1항에 있어서, 상기 기판 상에 그래프트된 전기적으로 중성인 유기 공중합체가,- 아민, 아미드, 에테르, 카르보닐, 포스핀, 포스핀 산화물, 티오에테르, 디설파이드, 우레아, 크라운 에테르, 아자 크라운, 티오 크라운, 크립탄드(cryptands), 세풀크란드(sepulcrands), 포단드(podands), 포르필린(porphyrines), 칼릭사렌(calixanrenes), 피리딘, 바이피리딘, 터피리딘, 퀴놀레인, 오르토페난트롤린 화합물, 나프톨, 이소나프톨, 티오우레아, 시더로포어(siderophores), 항생물질, 에틸렌글리콜, 사이클로덱스트린으로부터 선택된 착화특성을 갖는 하나 이상의 동일 또는 상이한 관능기, 및 상기 관능기들로 치환 및/또는 관능화된 분자 구조체, 및/또는- 하나 이상의 레독스 록(redox lock) 타입의 착화 캐비티를 포함하는 것을 특징으로 하는 구조체.
- 제1항에 있어서, 상기 중합체가 4-비닐 피리딘, 비닐 바이피리딘, 티오펜으로부터 선택된 모노머를 포함하는 중합체인 것을 특징으로 하는 구조체.
- 제1항에 있어서, 상기 중합체 또는 유기 공중합체 필름이 메틸메타크릴레이트와 에스테르의 메틸기가 레독스 록이 제공된 크라운 에테르에 의해 치환된 메틸메타크릴레이트의 공중합체인 것을 특징으로 하는 구조체.
- 제1항에 있어서, 중합체 또는 유기 공중합체 필름이 4-비닐 피리딘과 비릴 페로센 또는 비닐 디페로센의 공중합체인 것을 특징으로 하는 구조체.
- 제1항에 있어서, 상기 유기 중합체 필름이 약 10㎛ 이하의 두께를 갖는 것을 특징으로 하는 구조체.
- 제1항에 있어서, 상기 기판이 플레이트, 스트립, 테이프, 거즈, 메시, 와이어, 비드, 분말, 칩핑(chipping) 및 튜브로 이루어진 군으로부터 선택된 것임을 특징으로 하는 구조체.
- 제1항 및 7항중 어느 한항에 있어서, 상기 기판의 전부 또는 일부가 전기 도전성 물질 또는 반도체 물질로 형성된 것을 특징으로 하는 구조체.
- 제1항 또는 8항에 있어서, 상기 기판이 316L 스테인리스강인 것을 특징으로 하는 구조체.
- 액상 유출물로부터 이온을 추출하기 위해 상기 액상 유출물을 처리하는 방법에 있어서,처리할 유출물을 제1항 내지 9항중 어느 한항 기재의 구조체와 접촉시켜서 추출될 이온을 상기 전기적으로 중성인 중합체 필름에 의해 착화시키는 단계를 포함하는 방법.
- 제10항에 있어서, 상기 중합체에 의해 착화된 이온을 화학적 또는 전기적 수단에 의해 축출하는 단계를 더 포함하는 것을 특징으로 하는 방법.
- 제11항에 있어서, 상기 착화된 이온의 축출 단계가 화학적 수단에 의해 이루어지는 경우에, 상기 단계가 유기 중합체 필름을 상기 필름에 의해 착화된 이온에 대해 강력한 친화력을 나타내는 리간드를 포함하는 용액에 침지시킴으로써 실시되는 것을 특징으로 하는 방법.
- 제11항에 있어서, 상기 필름이 폴리-4-비닐 피리딘 필름이고 유출물로부터 추출되는 이온이 구리 및/또는 아연 이온이고, 필름으로부터의 이온 축출이 열수(hot water)를 이용하는 방법, 암모니아 용액을 이용하는 방법, 또는 상기 두가지 방법을 조합한 방법에 의해 이루어지는 것을 특징으로 하는 방법.
- 제11항에 있어서, 상기 필름이 도전성 기판 또는 반도체 기판이고 기판으로 그래프트된 유기 중합체들이 레독스 록이 제공된 하나 이상의 착화 캐비티를 포함하는 경우에, 착화된 이온의 축출이 중합체 필름을 가진 도전성 기판 또는 반도체 기판을 전기적으로 극성화시키는 전기적 방법에 의해 이루어지는 것을 특징으로 하는 방법.
- 제10항에 있어서, 이온을 착화시킨 폴리머 필름을 제거하기 위한 기판 박리 단계, 및 선택적으로 기판 위에 새로운 중합체 필름을 부착시키는 후속의 필름 형성 단계를 더 포함하는 것을 특징으로 하는 방법.
- - 제 1항 내지 9항중 어느 한항에 따른 착화 구조체,- 추출될 이온을 포함하는, 처리될 유출물을 수납하기 위한 제1 용기;- 상기 구조체의 중합체에 의해 착화된 이온을 제거하는 용액을 수납하기 위한 제2 용기; 및- 상기 구조체를 제어된 속도로, 처리될 유출물을 수납하는 제1 용기 및 상기 착화 구조체의 중합체에 의해 착화된 이온을 제거하는 용액을 수납하는 제2 용기에 순차적으로 통과시키는 수단을 포함하는, 유출물 처리용 연속 처리 장치.
- 제16항에 있어서, 상기 구조체가 말단이 결합된 테이프인 것을 특징으로 하는 처리 장치.
- 제16항에 있어서, 상기 착화 구조체가 버킷에 정렬된 메시 어셈블리이며, 상기 버킷은 수차 시스템에 의해 구동되는 것을 특징으로 하는 처리 장치.
- 제16항에 있어서, 상기 제1 용기 및 상기 제2 용기를 순차적으로 통과하는 속도를 처리될 유출물의 유속 및/또는 처리될 유출물 중의 이온 농도에 대하여, 및/또는 유기 필름에 의해 이온을 착화시키고 탈착화시키는 속도에 대하여 조절하는 조절 수단을 더 포함하는 처리 장치.
- - 제1항 내지 9항중 어느 한항에 따른 착화 구조체,- 추출될 이온을 포함하는, 처리된 유출물을 수납하기 위한 제1 용기; 및- 처리될 유출물을, 제어된 속도로 제1 용기로부터, 처리될 유출물을 포함하는 상기 착화 구조체의 표면 위로 또는 상기 구조체를 통해서 처리되도록 연속적으로 통과시키는 수단을 포함하는, 유출물을 처리하기 위한 연속 처리 장치.
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FR00/11074 | 2000-08-30 | ||
FR0011074A FR2813208B1 (fr) | 2000-08-30 | 2000-08-30 | Structure complexante, dispositif et procede de traitement d'effluents liquides |
PCT/FR2001/002692 WO2002018050A1 (fr) | 2000-08-30 | 2001-08-29 | Structure complexante, dispositif et procede de traitement d'effluents liquides |
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EP (1) | EP1315565B1 (ko) |
JP (1) | JP2004507348A (ko) |
KR (1) | KR100848582B1 (ko) |
CN (1) | CN1289196C (ko) |
AT (1) | ATE279984T1 (ko) |
AU (2) | AU2001286022B2 (ko) |
CA (1) | CA2419807A1 (ko) |
DE (1) | DE60106636T8 (ko) |
ES (1) | ES2230361T3 (ko) |
FR (1) | FR2813208B1 (ko) |
RU (1) | RU2274487C2 (ko) |
WO (1) | WO2002018050A1 (ko) |
ZA (1) | ZA200301157B (ko) |
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FR2821575B1 (fr) | 2001-03-02 | 2003-10-24 | Commissariat Energie Atomique | Procede de greffage organique localise sans masque sur des protions conductrices ou semiconductrices de surfaces composites |
AU2002317800A1 (en) * | 2001-06-04 | 2002-12-16 | Universite De Liege | Process for depositing strong adherend polymer coating onto an electrically conductive surface |
FR2851258B1 (fr) * | 2003-02-17 | 2007-03-30 | Commissariat Energie Atomique | Procede de revetement d'une surface, fabrication d'interconnexion en microelectronique utilisant ce procede, et circuits integres |
FR2851181B1 (fr) * | 2003-02-17 | 2006-05-26 | Commissariat Energie Atomique | Procede de revetement d'une surface |
RU2282906C2 (ru) * | 2004-01-15 | 2006-08-27 | Владимир Михайлович Полосин | Способ очистки радиоактивных водных растворов |
RU2270056C2 (ru) * | 2004-01-15 | 2006-02-20 | Владимир Михайлович Полосин | Комплексообразующий сорбент, способ его получения и использования |
US8377297B2 (en) * | 2009-12-23 | 2013-02-19 | Bae Systems Information And Electronic Systems Integration Inc. | Water desalination apparatus |
FR2957941B1 (fr) | 2010-03-26 | 2012-06-08 | Commissariat Energie Atomique | Procede pour graver une couche d'oxyde metallique conducteur utilisant une microelectrode |
CN107055912B (zh) * | 2017-05-31 | 2020-05-29 | 国家电投集团远达环保工程有限公司重庆科技分公司 | Scr催化剂再生废水的废水零排放处理系统 |
CN110052257A (zh) * | 2019-03-06 | 2019-07-26 | 宁波大学 | 一种氧化石墨烯膜/聚4-乙烯基吡啶/多孔三维花状微米银复合材料的制备方法 |
CN118630243A (zh) * | 2021-09-27 | 2024-09-10 | 山东东岳未来氢能材料股份有限公司 | 一类带有菲罗啉侧基的全氟离子聚合物及其合成方法以及燃料电池用质子交换膜和膜电极 |
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FR2491670A1 (fr) * | 1980-10-07 | 1982-04-09 | Commissariat Energie Atomique | Dispositif d'epuration pour la decontamination d'effluents aqueux en metaux lourds |
JPS5942041A (ja) * | 1982-09-02 | 1984-03-08 | Nitto Electric Ind Co Ltd | 金属イオン吸着剤の製造方法 |
US4476003A (en) * | 1983-04-07 | 1984-10-09 | The United States Of America As Represented By The United States Department Of Energy | Chemical anchoring of organic conducting polymers to semiconducting surfaces |
NL8400916A (nl) * | 1984-03-22 | 1985-10-16 | Stichting Ct Voor Micro Elektr | Werkwijze voor het vervaardigen van een isfet en een aldus vervaardigde isfet. |
DK483586A (da) * | 1985-10-21 | 1987-04-22 | Rohm & Haas | Insecticide n'-substituerede-n,n'-diacylhydraziner |
FR2644469B1 (fr) * | 1989-03-17 | 1991-05-31 | Centre Nat Rech Scient | Element composite comportant un polyether ou copolyether, son procede de preparation et son utilisation pour l'extraction et la separation de cations metalliques |
US5078978A (en) * | 1989-11-06 | 1992-01-07 | Brigham Young University | Pyridine-containing alkoxysilanes bonded to inorganic supports and processes of using the same for removing and concentrating desired ions from solutions |
FR2688336B1 (fr) * | 1992-03-03 | 1994-05-13 | Matieres Nucleaires Cie Gle | Procede pour separer le niobium, l'antimoine et/ou au moins un element des groupes viib et viii a partir de solutions aqueuses issues du retraitement des combustibles nucleaires uses. |
GB2274843B (en) * | 1993-02-09 | 1997-02-26 | Agricultural & Food Res | Continuous separation and purification of materials |
BE1006963A3 (fr) * | 1993-04-01 | 1995-02-07 | Cockerill Rech & Dev | Procede de depot par electropolymerisation d'un film d'un materiau composite sur une surface conductrice d'electricite. |
JP2956740B2 (ja) * | 1993-06-24 | 1999-10-04 | 矢崎総業株式会社 | 金属イオン捕捉材の製造方法 |
FR2725382B1 (fr) * | 1994-10-05 | 1997-01-03 | Commissariat Energie Atomique | Polyazacycloalcanes, complexes tri-, tetra- ou pentaazamacrocycliques, procede de fabrication de ces polyazacycloalcanes substitues ou non et greffes sur un support et utilisations des polyazacycloalcanes |
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EP0992283A3 (en) * | 1998-09-21 | 2000-06-14 | Polymer Group, Inc. | Method and product for selectively removing ions from aqueous solutions |
RU2141377C1 (ru) * | 1998-12-25 | 1999-11-20 | Орлов Андрей Васильевич | Гетерогенный комплексообразующий сорбент |
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- 2001-08-29 KR KR1020037002966A patent/KR100848582B1/ko not_active IP Right Cessation
- 2001-08-29 JP JP2002523014A patent/JP2004507348A/ja active Pending
- 2001-08-29 WO PCT/FR2001/002692 patent/WO2002018050A1/fr active IP Right Grant
- 2001-08-29 RU RU2003108742/15A patent/RU2274487C2/ru not_active IP Right Cessation
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- 2001-08-29 CA CA002419807A patent/CA2419807A1/fr not_active Abandoned
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Publication number | Publication date |
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DE60106636D1 (de) | 2004-11-25 |
CA2419807A1 (fr) | 2002-03-07 |
ATE279984T1 (de) | 2004-11-15 |
FR2813208A1 (fr) | 2002-03-01 |
AU8602201A (en) | 2002-03-13 |
FR2813208B1 (fr) | 2003-03-28 |
ES2230361T3 (es) | 2005-05-01 |
US20030149122A1 (en) | 2003-08-07 |
CN1289196C (zh) | 2006-12-13 |
KR100848582B1 (ko) | 2008-07-28 |
EP1315565A1 (fr) | 2003-06-04 |
DE60106636T2 (de) | 2006-03-09 |
WO2002018050A1 (fr) | 2002-03-07 |
DE60106636T8 (de) | 2006-06-08 |
EP1315565B1 (fr) | 2004-10-20 |
RU2274487C2 (ru) | 2006-04-20 |
JP2004507348A (ja) | 2004-03-11 |
CN1449307A (zh) | 2003-10-15 |
ZA200301157B (en) | 2004-04-16 |
AU2001286022B2 (en) | 2005-09-29 |
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