KR20030015524A - The functional water paint composition and its preparation method, and the water paint utilizing thereof - Google Patents

Abstract

PURPOSE: Provided are a functional aqueous paint composition and an aqueous paint using the composition, which is dried fast, has reinforced cohesive force, prevents cracks, improves adhesive force, and has deodorizing, heating, heat-keeping, hydrating, electromagnetic wave-screening effects. CONSTITUTION: The functional aqueous paint composition is produced by a process comprising the steps of: mixing discharge water arc-discharged by 3-phase electricity with 50V and 200A and inorganic composite powder, as a functional component, having a particle size of 1-10nm and containing more than 25% of K2O, MgO, Na2O, and CaO, less than 58% of SiO2, and less than 20% of a metallic component such as Fe2O3, Al2O3 in the ratio of 1.0:0.25-1.0 and then arc-discharging the mixture by the 3-phase electricity with 50V and 200A; adding 2-5wt%(based on the weight of the mixture) of a glue and heating. And the aqueous paint has various colors according to the particle size of the functional component.

Description

Functional water paint composition and its preparation method and water-based paint using the same {The functional water paint composition and its preparation method, and the water paint utilizing}

The present invention relates to a functional aqueous coating composition, a method of manufacturing the same, and an aqueous coating using the same. More specifically, the number of discharged arc discharged by three-phase electric current flowing at a voltage of 50 V and a current of 200 A, K ₂ O, MgO 1-10 nm (10 ^-9 m) of inorganic composite containing 25% or more of Na ₂ O and CaO, 58% or less of SiO ₂ , and 20% or less of metallic components such as Fe ₂ O ₃ , Al ₂ O _3, etc. The functional components pulverized to a size are mixed at a ratio of 1.0: 0.25 to 1.0, and the weight of the mixture obtained by arc-discharging them with a three-phase electric current flowing at a voltage of 50 V and a current of 200 A is used. It relates to a functional aqueous coating composition, a method for producing the same and an aqueous coating using the same, characterized in that the addition of ~ 5% by weight, mixing and heat treatment.

In general, paint is a generic term for a fluid substance that paints on the surface of a solid material, such as paint or enamel, to form a solid film to protect and beautify the surface of the object. It is good to dry harden. In 2500 years ago, Egypt used paints whose main ingredients were solid membranes made by dry oil. Around 1760, oiliness varnishes and linoleum were produced domestically in Europe, using the phenomenon that when oil was heated beforehand, the viscosity increased and a solid film formed quickly.

Despite the radical development of modern industry by the twentieth century, the paint industry was dependent on experienced skill. Since then, due to the development of mass production technology to cope with the increasing demand of paint, the development of synthetic resin such as synthetic dry oil and the development of synthetic resin such as alkyd resin coating material, new and various paints are being produced.

In addition, the paint is generally composed of various components. That is, it is composed of various organic, resins, pigments, solvents and flame retardants, antistatic agents, antioxidants, sunscreens and other additives, and the environmental problems caused by various organic solvents added to the composition are serious, As a result, the amount of paint used is rapidly increasing, and the pollution problem caused by this is amplifying day by day.

In addition, oil paints have a problem of slow drying and poor hardness, water resistance, and alkali resistance.

Therefore, the interest in water-based paints with water as the main medium is increasing rather than the oil-based paint, the main component of the pigment, water-based paints also pose the same problem of pollution problems due to the use of the pigment.

In addition, the conventional paints have to use a large number of materials, the use of many materials requires a high level of skill in mixing, the use of a variety of components not only complicated the manufacturing process of the paint, but also complicated manufacturing equipment In addition, there is a problem that the material and equipment is expensive, which is a factor of the increase in the paint price.

The present invention can solve the problems of environmental pollution and pollution caused by the organic solvents of the conventional paint as described above, as well as the drying of the paint by the functional material as a main material, the cohesive force is enhanced, crack prevention and coating material It is intended to provide an aqueous coating composition which can improve the adhesive force with and at the same time obtain effects such as deodorization and heating, and effects such as heat retention, moisturizing and electromagnetic wave blocking functions.

It is also an object of the present invention to provide a functional aqueous coating composition having a low cost because of a simple manufacturing process and manufacturing equipment.

Another object of the present invention to provide a method for producing a functional water-based coating composition of the above object.

Another object of the present invention to provide an aqueous coating and a method for producing the same using the functional aqueous coating composition of the above object.

In addition to the above objects, in order to achieve the other objects that are easily expressed in the present invention, the number of discharged arc discharged by three-phase electric current flowing a voltage of 50V and a current of 200A, K ₂ O, MgO, Na ₂ O and CaO Is a functional component obtained by crushing an inorganic composite containing 25% or more, 58% or less SiO ₂ , and 20% or less metallic component such as Fe ₂ O ₃ , Al ₂ O _3, or the like to a size of 1 to 10 nm (10 ^-9 m). The mixture was mixed at a ratio of 1.0: 0.25 to 1.0, and arc-discharged by a three-phase electric current flowing at a voltage of 50 V and a current of 200 A, but with respect to the weight of the mixture obtained by continuously discharging for 5 to 8 seconds for an intermittent period of 20 to 60 minutes. To obtain a functional coating composition characterized in that the mixture is heated by adding 2 to 5% by weight of a glue, a known adhesive material, and to prepare a paint having a variety of colors according to the particle size of the functional component, Magnetic coating Strengthen the force to prevent cracking due to the internal stress of the water-based paint and to improve the adhesion to the coating material, as well as to speed up the drying process, the manufacturing process and manufacturing equipment is simple and low cost, the paint (paint) Along with the deodorizing effect of decomposing various odors around the painted, there is an effect of obtaining an environmentally friendly functional water-based paint such as an electromagnetic wave blocking effect.

The present invention is described in more detail as follows.

The functional water-based coating composition according to the present invention is discharged water having a particle size of nano-size and having a particle size of 5 or less per cluster obtained by arc discharge with a three-phase electric current flowing at a voltage of 50 V and a current of 200 A, and K ₂ O. 1-10 nm (10 ^-9) for inorganic composites containing 25% or more of MgO, Na ₂ O and CaO, 58% or less of SiO ₂ , and 20% or less of metallic components such as Fe ₂ O ₃ , Al ₂ O _3, etc. m) Grinding to size, make the number of constituent molecules into 10 ² ~ 10 ³ state, and classify them by Gaussian by the difference in magnetic properties and magnetic flux density of each constituent particles, and in the order of particle size The particles are obtained in the order of black, red, orange, yellow, green, blue, indigo, purple, and white, and the functional components of each color are mixed at a ratio of 1.0: 0.25 to 1.0, which is a voltage of 50 V and a current of 200 A. Arc-discharge for 20 to 60 minutes with a 3-phase electric With respect to the weight of the mixture obtained by continuously discharging the 8-second intermittent period, characterized by adding a mixture of the second adhesive material is a glue of known weight to 5%, and heated at 55 ~ 60 ℃ for 3 to 8 hours.

In addition, the manufacturing method of the functional water-based coating composition according to the present invention has a discharge number having a nano-sized particle size having a molecular size of 5 or less per cluster obtained by arc discharge with a three-phase electric current flowing a voltage of 50V and a current of 200A 1-10 nm of an inorganic composite containing 25% or more of K ₂ O, MgO, Na ₂ O, and CaO, 58% or less of SiO ₂ , and 20% or less of a metallic component such as Fe ₂ O ₃ , Al ₂ O _3, or the like. Grinding (10 ^-9 m) to make the number of constituent molecules into the state of 10 ² to 10 ³ , classify them by Gaussian according to the magnetic difference and magnetic flux density of each constituent particle, and at the same time The particles were classified in the order of black, red, orange, yellow, green, blue, indigo, purple, and white to obtain particles, and the functional ingredients of each color were introduced into the grinder at a ratio of 1.0: 0.25 to 1.0, and 40 to Mix at 80 rpm for at least 48 hours and then mix 2 to 5% by weight of glue, a known adhesive material, was added to the mixture obtained by arc discharge for 20 to 60 minutes in a three-phase electric current with a voltage of 200 A and continuously discharged in an intermittent period of 5 to 8 seconds. It is characterized by addition and mixing for 24 hours at 40 to 80 rpm or 30 to 60 minutes at 1,500 to 2,000 rpm, and heating at 55 to 60 ° C. for 3 to 8 hours.

In addition, the functional water-based paint according to the invention is characterized in that it can be produced in a variety of colors by changing the mixing ratio of the discharge water and the functional component, and adjust the particle size of the functional component.

The arc-discharged water with three-phase electric current flowing at a voltage of 50V and 200A plays a role in which various inorganic substances in the water are ionized to be easily combined or mixed with functional components. It is also possible to use water which has been treated in various forms so that the inorganic substances can be ionized.

The functional component is an inorganic composite containing 25% or more of K ₂ O, MgO, Na ₂ O, and CaO, 58% or less of SiO ₂ , and 20% or less of metallic components such as Fe ₂ O ₃ , Al ₂ O _3, and the like. SiO ₂ 54.42 wt%, Al ₂ O ₃ 9.16 wt%, Fe ₂ O ₃ 1.87 wt%, K ₂ O 4.18 wt%, Na ₂ O 3.74 wt%, CaO 4.17 wt%, MgO 14.19 wt% and other minor components 8.27 Aromatic granite (hereinafter, referred to as "deep granite A") powder composed of wt% is preferred, but SiO ₂ 79.76 wt%, Al ₂ O ₂ 9.87 wt%, Fe ₂ O ₃ 0.21 wt%, K ₂ O 3.79 wt %, Na ₂ O 2.81 wt%, CaO 1.59 wt%, MgO 0.86 wt%, and other granules 1.11 wt% containing germanium 0.5-2 ppm, powder of deep granite (hereinafter referred to as "deep granite B") powder, SiO ₂ 73.41wt%, Al ₂ O ₃ 14.56wt%, Fe ₂ O ₃ 1.13wt%, K ₂ O 4.13wt%, Na ₂ O 2.48wt%, CaO 2.28wt%, MgO 0.72wt% and Germanium 0.5 ~ 2ppm Deep granite (hereinafter referred to as "deep granite C") powder composed of 1.29 wt% of other trace components containing, SiO ₂ 73.53 wt%, Al ₂ O ₃ 12.52 wt%, Fe ₂ O ₃ Granite granite consisting of 4.76 wt%, K ₂ O 3.78 wt%, Na ₂ O 2.07 wt%, CaO 1.56 wt%, MgO 0.51 wt% and other trace components 1.27 wt% containing germanium 0.5-2 ppm Powder and SiO ₂ 79.89wt%, Al ₂ O ₃ 14.92wt%, Fe ₂ O ₃ 0.31wt%, K ₂ O 1.24wt%, Na ₂ O 0.64wt%, CaO 1.89wt% , Deep granite (hereinafter referred to as "deep granite E") powder composed of 0.17 wt% of MgO and 0.94 wt% of other trace components may be used.

However, deep granite B, C, D, and E contain 25% or more of K ₂ O, MgO, Na ₂ O, and CaO, 58% or less of SiO ₂ , and metallic such as Fe ₂ O ₃ , Al ₂ O _3, etc. Since it does not meet the conditions of 20% or less of the component, a separate pretreatment process is required.

The deep granite used in the present invention is a pure magma in the crust is cooled in the reduced state, each has a unique color, the color is a unique color formed by cooling the high temperature magma of 4000 ℃ or more, the far-infrared emissivity is 0.90 or more, Far-infrared emissivity changes according to the type of deep granite used, the mixing method, and the mixing ratio, thereby obtaining functional materials of various properties and uses.

That is, deep granite A, deep granite B, deep granite C, deep granite D, deep granite E can be used alone, or two or more kinds can be used in combination, and each mixed granite is 10 wt%. It is preferable to use more than%.

That is, after the first crushing to about 325 mesh by a general grinding process, and then classified into about 1㎛ (12,500 mesh) using a vacuum pressure difference, the granulated granite powder and water in a ball mill (1: 1) to 1: 1 When the mixture is pulverized by rotating at 40 to 80 rpm for more than 48 hours, particles of 1 to 10 nm in size are dispersed in a colloidal state to obtain a deep granite gel, which is continuously discharged by three-phase electricity of 50 V and 200 A. K ₂ 0, MgO, CaO, Na ₂ O, Al ₂ O ₃ , Fe ₂ O ₃ in granite particles react and pop out to form porous porous granite particles and K ⁺ , Mg ⁺² , Ca ⁺² , Na ⁺ , Al ⁺³ , Fe ⁺³ ions are in a mixed state, it can also be heated to evaporate the water to make a dry gel state.

However, the pretreatment of the deep granite is not limited thereto, and contains 25% or more of K ₂ O, MgO, Na ₂ O, and CaO, 58% or less of SiO ₂ , and such as Fe ₂ O ₃ , Al ₂ O _3, and the like. Any method can be used as long as the metallic component can satisfy the condition of 20% or less.

The functional ingredients are ground to 1 ~ 10 nm (10 ^-9 m) size, the particle size of less than 1nm is not easy to manufacture, there is a problem that the process is complicated and the cost rises, if it exceeds 10nm There is a disadvantage in that the expression of the function is not satisfactory and the desired effect is not obtained in the present invention.

In addition, the functional ingredient is characterized in that the porous.

However, all the above-mentioned water-based paints are first put into the mill in the discharged water and functional components at the ratio described above, and operated by mixing at 40 to 80 rpm for at least 48 hours, and then mixed with glue 2-5, a known adhesive material. The weight percent must be added and mixed at 40-80 rpm for at least 24 hours or at 1,500-2,000 rpm for 30-60 minutes and heated at 55-60 ° C. for 3-8 hours.

In addition, it is possible to add known components suitable for the application depending on the use of the aqueous coating to be produced.

Aqueous paints prepared as described above have far-infrared radiation and magnetic properties to strengthen the cohesive force of the water-based paints to prevent cracking due to the internal stress of the water-based paints and to improve adhesion to the coating material, as well as to speed up drying. The manufacturing process and equipment are simple and inexpensive, and the deodorizing effect of decomposing various odors around the paint (paint) and the environmentally friendly functional water-based coating such as electromagnetic wave blocking effect can be obtained. .

As described above, the water-based paint according to the present invention contains the discharge water arc-discharged by a three-phase electric current with a voltage of 50 V and a current of 200 A, K ₂ O, MgO, Na ₂ O, and CaO containing 25% or more, and SiO ₂ Is not more than 58%, and the functional component obtained by pulverizing an inorganic composite having 20% or less of metallic components such as Fe ₂ O ₃ , Al ₂ O _3, etc. to 1 to 10 nm (10 ^-9 m) in size is 1.0: 0.25 to 1.0. 2 to 5% by weight of glue, a known adhesive substance, was mixed and heated to the weight of the mixture obtained by arc discharge with a three-phase electric current flowing at a voltage of 50 V and a current of 200 A. By obtaining a functional water-based coating composition, and preparing a paint of various colors according to the particle size of the functional ingredient, by using a functional material of a ceramic granite having a far-infrared radiation function and magnetic, that is, a germanium component containing far-infrared rays, Various effects are provided, and the cohesive force of the water-based paint is strengthened to prevent cracking due to the internal stress of the water-based paint and to improve adhesion to the coating material, as well as to speed up drying, and to manufacture the manufacturing process and the equipment. It is simple and inexpensive, and in addition to deodorizing effect of decomposing various odors around paint (paint), the environmentally friendly functions such as electromagnetic wave blocking effect can be provided.

Claims (7)

Discharge water having a nano-sized particle size of 5 or less molecular clusters per arc cluster obtained by arc-discharge with a 3-phase electric current having a voltage of 50 V and a current of 200 A, and K ₂ O, MgO, Na ₂ O and CaO Inorganic composites containing 25% or more, 58% or less SiO ₂ , and 20% or less metallic components such as Fe ₂ O ₃ , Al ₂ O _3, etc. are ground to 1-10 nm (10 ^-9 m) in size to obtain the number of constituent molecules. 10 ² to 10 ³ states, which are classified according to the Gaussian according to the difference in magnetic properties and magnetic flux density of each constituent particle, and in the order of particle size, black, red, orange, yellow, The particles are obtained in the order of green, blue, indigo blue, purple, and white, and the functional components of each color are mixed at a ratio of 1.0: 0.25 to 1.0, and 20 to 60 in a three-phase electric furnace with a voltage of 50 V and a current of 200 A. Arc discharge for minutes, obtained by continuous discharge in an interruption period of 5 to 8 seconds Functional water-based coating composition with respect to the mixture weight, characterized in that a mixture by the addition of 2-5% by weight of the adhesive material is a glue of known and, in 55 ~ 60 ℃ 3 ~ 8 time Heating. The functional component of claim 1, wherein the functional component contains 25% or more of K ₂ O, MgO, Na ₂ O, and CaO, 58% or less of SiO ₂ , and 20% of metallic components such as Fe ₂ O ₃ , Al ₂ O _3, or the like. Functional aqueous coating composition, characterized in that the inorganic composite below. The method of claim 1, wherein the functional component is SiO ₂ 54.42wt%, Al ₂ O ₃ 9.16wt%, Fe ₂ O ₃ 1.87wt%, K ₂ O 4.18wt%, Na ₂ O 3.74wt%, CaO 4.17wt%, Functional aqueous coating composition, characterized in that the deep granite powder consisting of MgO 14.19wt% and other minor components 8.27wt%. The functional aqueous coating composition according to claim 1, wherein the functional component is porous. The porous functional component of claim 4, wherein the porous functional component is SiO ₂ 79.76 wt%, Al ₂ O ₂ 9.87 wt%, Fe ₂ O ₃ 0.21 wt%, K ₂ O 3.79 wt%, Na ₂ O 2.81 wt%, CaO 1.59 wt% , Deep granite powder, consisting of 0.86 wt% MgO and 1.11 wt% of other trace components containing germanium 0.5-2 ppm, SiO ₂ 73.41 wt%, Al ₂ O ₃ 14.56 wt%, Fe ₂ O ₃ 1.13 wt%, K ₂ Deep granite powder composed of O.13wt%, Na ₂ O 2.48wt%, CaO 2.28wt%, MgO 0.72wt% and other trace components 1.29wt% containing 0.5-2ppm germanium, SiO ₂ 73.53wt%, Al _{2 3} 12.52wt% O, Fe ₂ O ₃ 4.76wt%, 3.78wt%, K ₂ O, Na ₂ O 2.07wt%, 1.56wt% CaO, MgO 0.51wt other minor components containing germanium% and 0.5 ~ 2ppm 1.27wt Deep granite powder composed of%, SiO ₂ 79.89wt%, Al ₂ O ₃ 14.92wt%, Fe ₂ O ₃ 0.31wt%, K ₂ O 1.24wt%, Na ₂ O 0.64wt%, CaO 1.89wt%, Pulverized granite powder consisting of 0.17 wt% MgO and 0.94 wt% of other trace components is first pulverized to 325 mesh, and then to 1 μm (12,500 mesh) using a vacuum pressure difference. After the classification, the granulated granite powder and water are added to the ball mill in a ratio of 1: 1 and rotated at 40 to 80 rpm for 48 hours for pulverization, whereby particles of 1 to 10 nm in size collide in a colloidal state to obtain the existing granite granite gel. It can be continuously discharged by three-phase electricity of 50V, 200A, K ₂ 0, MgO, CaO, Na ₂ O, Al ₂ O ₃ , Fe ₂ O ₃ in the deep granite granules reacts and pops out of the porous deep granite particles And K ⁺ , Mg ⁺² , Ca ⁺² , Na ⁺ , Al ⁺³ , Fe ⁺³ ions are mixed, functional water-based paint, characterized in that by heating the water to evaporate to dry gel state Composition. Discharge water having a nano-sized particle size of 5 or less molecular clusters per arc cluster obtained by arc discharge with a 3-phase electric current having a voltage of 50 V and a current of 200 A, and K ₂ O, MgO, Na ₂ O and CaO Inorganic composites containing 25% or more, 58% or less SiO ₂ , and 20% or less metallic components such as Fe ₂ O ₃ , Al ₂ O _3, etc. are ground to 1-10 nm (10 ^-9 m) in size to obtain the number of constituent molecules. 10 ² to 10 ³ states, which are classified according to the Gaussian according to the difference in magnetic properties and magnetic flux density of each constituent particle, and in the order of particle size, black, red, orange, yellow, The particles are obtained in the order of green, blue, indigo blue, purple, and white, and the functional ingredients of each color are introduced into the grinder at a ratio of 1.0: 0.25 to 1.0, mixed at 40 to 80 rpm for at least 48 hours, and then 50 V of Arc room for 20 to 60 minutes with three-phase electric current with a voltage of 200 A To the weight of the mixture obtained by continuous discharge in an intermittent period of 5 to 8 seconds, 2 to 5% by weight of a known adhesive substance is added, and the temperature is 40 to 80 rpm for 24 hours or 30 to 1,500 to 2,000 rpm. Mixing for 60 minutes, and heating for 3 to 8 hours at 55 to 60 ℃ method for producing a functional water-based coating composition. Functional water-based paint prepared from the composition of any one of claims 1 to 5.