KR20030015525A - The functional oil paint composition and its preparation method, and the oil paint utilizing thereof - Google Patents

Abstract

PURPOSE: Provided are a functional oil paint composition and an oil paint using the composition, which is dried fast, prevents cracks, improves adhesive force, and has deodorizing and electromagnetic wave-screening effects. CONSTITUTION: The functional oil paint composition is produced by a process comprising the steps of: adding 10-50wt% of a pigment and boiled oil to inorganic composite powder, as a functional component, having a particle size of 1-10nm and containing more than 25% of K2O, MgO, Na2O, and CaO, less than 58% of SiO2, and less than 20% of a metallic component such as Fe2O3, Al2O3; arc-discharging for 10-20 minutes by 3-phase electricity with 50V and 200A, wherein the discharging is continuous discharging through an intermittent time of 1-2 minutes. And the oil paint has various colors according to the particle size of the functional component.

Description

The functional oil paint composition and its preparation method, and the oil paint using the same}

The present invention relates to a functional oil paint composition, a method for producing the same and an oil paint using the same, more specifically, K ₂ O, MgO, Na ₂ O and CaO containing 25% or more, SiO ₂ is 58% or less, Pigments and oils used in known oil paint compositions for functional components obtained by grinding 1 to 10 nm (10 ^-9 m) in size of inorganic composites containing 20% or less of metallic components such as Fe ₂ O ₃ and Al ₂ O ₃ The functional oil-based paint composition obtained by adding 10 to 50% by weight of the arc discharge for 10 to 20 minutes in a three-phase electric current flowing at a voltage of 50 V and a current of 200 A, but continuously discharged in an intermittent period of 1 to 2 seconds. And it relates to a manufacturing method thereof and an oil paint using the same.

In general, paint is a generic term for a flowable material that paints on the surface of a solid material, such as paint or enamel, to form a solid film to protect and beautify the surface of the object. It is good to dry harden. In 2500 years ago, Egypt used paints whose main ingredients were solid membranes made by dry oil. Around 1760, oiliness varnishes and linoleum were produced domestically in Europe, using the phenomenon that when oil was heated beforehand, the viscosity increased and a solid film formed quickly.

Despite the radical development of modern industry by the twentieth century, the paint industry was dependent on experienced skill. Since then, due to the development of mass production technology to cope with the increasing demand of paint, the development of synthetic resin such as synthetic dry oil and the development of synthetic resin such as alkyd resin coating material, new and various paints are being produced.

In addition, the paint is generally composed of various components. That is, it is composed of various organic, resins, pigments, solvents and flame retardants, antistatic agents, antioxidants, sunscreens and other additives, and the environmental problems caused by various organic solvents added to the composition are serious, As a result, the amount of paint used is rapidly increasing, and the pollution problem caused by this is amplifying day by day.

In addition, oil paints have a problem of slow drying and poor hardness, water resistance, and alkali resistance.

In addition, the conventional paints have to use a large number of materials, the use of many materials requires a high level of skill in mixing, the use of a variety of components not only complicated the manufacturing process of the paint, but also complicated manufacturing equipment In addition, there is a problem that the material and equipment is expensive, which is a factor of the increase in the paint price.

The present invention can solve the problems of environmental pollution and pollution caused by the organic solvents of the conventional paint as described above, as well as the drying of the paint by the functional material as a main material, the cohesive force is enhanced, crack prevention and coating material It is to provide an oil-based coating composition that can improve the adhesion to and at the same time, the effect such as deodorization, heating and the like effect of heat retention, moisturizing and electromagnetic wave blocking function.

It is also an object of the present invention to provide a functional oil paint composition having a low cost because the manufacturing process and manufacturing equipment is simple.

Another object of the present invention to provide a method for producing a functional oil paint composition of the above object.

It is another object of the present invention to provide an oil paint and a method for producing the same using the functional oil paint composition of the above object.

In addition to the above objects, in order to achieve other objects that are easily expressed, in the present invention, 25% or more of K ₂ O, MgO, Na ₂ O, and CaO are contained, and SiO ₂ is 58% or less, and Fe ₂ O ₃ , Al 10 to 50% by weight of pigments and voile oils, which are used in known oil paint compositions, for functional ingredients obtained by grinding inorganic composites having a metallic component of 20% or less, such as ₂ O ₃ , to a size of 1 to 10 nm (10 ^-9 m). To obtain a functional oil-based paint composition, characterized in that obtained by the arc discharge for 10 to 20 minutes in a three-phase electricity flowing a voltage of 50V and a current of 200A, continuous discharge in an intermittent period of 1 to 2 seconds, By producing oil-based paints with various colors according to the particle size, it has far-infrared radiation function and magnetism to strengthen the cohesion of oil paints, preventing cracks due to internal stress of oil paints and improving adhesion to the coating material. In addition, the drying process is fast, the manufacturing process and manufacturing equipment are simple, and the cost is low, and the deodorizing effect of decomposing various odors around the paint (paint) is painted and environmentally friendly functionalities such as electromagnetic wave blocking effect. It is effective to obtain oil paint.

The present invention is described in more detail as follows.

The functional oil paint composition according to the present invention contains 25% or more of K ₂ O, MgO, Na ₂ O and CaO, 58% or less of SiO ₂ , 20% of metallic components such as Fe ₂ O ₃ , Al ₂ O _3, etc. Grinding the inorganic composite below 1 to 10 nm (10 ^-9 m) in size to make the number of constituent molecules in the state of 10 ² to 10 ³ , by the Gauss (Gauss) by the magnetic difference and magnetic flux density of each constituent particle At the same time, the particles are classified in the order of particle size to obtain particles in the order of black, red, orange, yellow, green, blue, indigo, purple, and white, and the known oil-based coating composition for the functional components of each color. 10 to 50% by weight of the pigment and voile oil used in the present invention are arc discharged for 10 to 20 minutes with a three-phase electric current flowing at a voltage of 50 V and a current of 200 A, but are continuously discharged in an intermittent period of 1 to 2 seconds. It is erased.

In addition, the method for preparing a functional oil paint composition according to the present invention contains 25% or more of K ₂ O, MgO, Na ₂ O and CaO, 58% or less of SiO ₂ , such as Fe ₂ O ₃ , Al ₂ O ₃ , etc. Grinding the inorganic composite with a metallic component of 20% or less to a size of 1 to 10 nm (10 ^-9 m) to make the number of constituent molecules into 10 ² to 10 ³ state, which is determined by the magnetic difference and magnetic flux density of each constituent particle. At the same time, the particles are sorted by the size of the Gauss, and the particles are obtained in the order of black, red, orange, yellow, green, blue, indigo, purple, and white. 10 to 50% by weight of the pigment and voile oil used in the oil paint composition of the oil is added to the mill, and mixed at 40 to 80 rpm for more than 48 hours, and then this is a three-phase electric furnace with a voltage of 50 V and a current of 200 A. Arc discharge for 10 to 20 minutes, with interrupter 1 to 2 seconds Characterized that obtained by continuously discharging a.

In addition, the functional oil paint according to the present invention can be produced in various colors by changing the mixing ratio of the functional ingredient and the pigment and voile oil used in known oil paint compositions, and controlling the particle size of the functional ingredient. It is done.

The functional component is an inorganic composite containing 25% or more of K ₂ O, MgO, Na ₂ O, and CaO, 58% or less of SiO ₂ , and 20% or less of metallic components such as Fe ₂ O ₃ , Al ₂ O _3, and the like. SiO ₂ 54.42 wt%, Al ₂ O ₃ 9.16 wt%, Fe ₂ O ₃ 1.87 wt%, K ₂ O 4.18 wt%, Na ₂ O 3.74 wt%, CaO 4.17 wt%, MgO 14.19 wt% and other minor components 8.27 Aromatic granite (hereinafter, referred to as "deep granite A") powder composed of wt% is preferred, but SiO ₂ 79.76 wt%, Al ₂ O ₂ 9.87 wt%, Fe ₂ O ₃ 0.21 wt%, K ₂ O 3.79 wt Heart granite (hereinafter referred to as "deep granite B") powder consisting of%, Na ₂ O 2.81wt%, CaO 1.59wt%, MgO 0.86wt% and other trace components 1.11wt% containing germanium 0.5-2ppm, SiO ₂ 73.41wt%, Al ₂ O ₃ 14.56wt%, Fe ₂ O ₃ 1.13wt%, K ₂ O 4.13wt%, Na ₂ O 2.48wt%, CaO 2.28wt%, MgO 0.72wt% and Germanium 0.5 ~ 2ppm Deep granite (hereinafter referred to as "deep granite C") powder composed of 1.29 wt% of other trace components containing, SiO ₂ 73.53 wt%, Al ₂ O ₃ 12.52 wt%, Fe ₂ O ₃ Granite granite consisting of 4.76 wt%, K ₂ O 3.78 wt%, Na ₂ O 2.07 wt%, CaO 1.56 wt%, MgO 0.51 wt% and other trace components 1.27 wt% containing germanium 0.5-2 ppm Powder and SiO ₂ 79.89wt%, Al ₂ O ₃ 14.92wt%, Fe ₂ O ₃ 0.31wt%, K ₂ O 1.24wt%, Na ₂ O 0.64wt%, CaO 1.89wt% , Deep granite (hereinafter referred to as "deep granite E") powder composed of 0.17 wt% of MgO and 0.94 wt% of other trace components may be used.

However, deep granite B, C, D, and E contain 25% or more of K ₂ O, MgO, Na ₂ O, and CaO, 58% or less of SiO ₂ , and metallic such as Fe ₂ O ₃ , Al ₂ O _3, etc. Since it does not meet the conditions of 20% or less of the component, a separate pretreatment process is required.

The deep granite used in the present invention is a pure magma in the crust is cooled in the reduced state, each has a unique color, the color is a unique color formed by cooling the high temperature magma of 4000 ℃ or more, the far-infrared emissivity is 0.90 or more, Far-infrared emissivity changes according to the type of deep granite used, the mixing method, and the mixing ratio, thereby obtaining functional materials of various properties and uses.

That is, deep granite A, deep granite B, deep granite C, deep granite D, deep granite E can be used alone, or two or more kinds can be used in combination, and each mixed granite is 10 wt%. It is preferable to use more than%.

That is, after the first crushing to about 325 mesh by a general grinding process, and then classified into about 1㎛ (12,500 mesh) using a vacuum pressure difference, the granulated granite powder and water in a ball mill (1: 1) to 1: 1 When the mixture is pulverized by rotating at 40 to 80 rpm for more than 48 hours, particles of 1 to 10 nm in size are dispersed in a colloidal state to obtain a deep granite gel, which is continuously discharged by three-phase electricity of 50 V and 200 A. K ₂ 0, MgO, CaO, Na ₂ O, Al ₂ O ₃ , Fe ₂ O ₃ in granite particles react and pop out to form porous porous granite particles and K ⁺ , Mg ⁺² , Ca ⁺² , Na ⁺ , Al ⁺³ , Fe ⁺³ ions are in a mixed state, it can also be heated to evaporate the water to make a dry gel state.

However, the pretreatment of the deep granite is not limited thereto, and contains 25% or more of K ₂ O, MgO, Na ₂ O, and CaO, 58% or less of SiO ₂ , and such as Fe ₂ O ₃ , Al ₂ O _3, and the like. Any method can be used as long as the metallic component can satisfy the condition of 20% or less.

The functional ingredients are ground to 1 ~ 10 nm (10 ^-9 m) size, the particle size of less than 1nm is not easy to manufacture, there is a problem that the process is complicated and the cost increase, if exceeding 10nm There is a disadvantage in that the expression of the function is not satisfactory and the desired effect is not obtained in the present invention.

In addition, the functional ingredient is characterized in that the porous.

However, all of the above oil-based paints are added to the grinder by adding 10 to 50% by weight of the pigment and voile oil used in the known oil paint composition to the functional ingredient of the ratio described above, and at least for 48 hours at 40 to 80rpm After mixing, it is arc-discharged for 10 to 20 minutes with a three-phase electric current flowing at a voltage of 50 V and a current of 200 A, but continuously discharged in an intermittent period of 1 to 2 seconds.

In addition, according to the use of the oil paint to be produced, it is possible to add known ingredients suitable for the use.

The oil paint prepared as described above has far-infrared radiation function and magnetism, which enhances the cohesive force of the oil paint to prevent cracking due to the internal stress of the oil paint and to improve adhesion to the coating material, as well as to speed up drying. The manufacturing process and equipment are simple and inexpensive. The deodorizing effect of decomposing various odors around paints (paints) and the environmentally friendly functional oil paint such as electromagnetic wave blocking effect can be obtained. .

The present invention relates to a functional oil paint composition, a method for producing the same and an oil paint using the same, containing at least 25% K ₂ O, MgO, Na ₂ O and CaO, 58% or less SiO ₂ , Fe ₂ O ₃ , 10 to 50% by weight of pigment and voile oil, which are used in known oil paint compositions, for functional ingredients obtained by grinding inorganic composites having a metallic component of 20% or less such as Al ₂ O ₃ to 1 to 10 nm (10 ^-9 m) in size A functional oil paint composition was obtained by adding a% and arc-discharging for 10 to 20 minutes with a three-phase electric current flowing at a voltage of 50 V and a current of 200 A, followed by continuous discharge in an intermittent period of 1 to 2 seconds. By producing paints of various colors according to the particle size of, by using a functional material of ceramics having far-infrared radiation function and magnetic, that is, deep granite powder containing germanium component, To increase the cohesiveness of the oil paint and prevent cracking due to the internal stress of the oil paint and to improve the adhesion to the coating material, as well as to speed up drying, and to simplify the manufacturing process and manufacturing equipment It is inexpensive, and in addition to the deodorizing effect of decomposing various odors around the paint (paint), the environmentally friendly functions such as the electromagnetic wave blocking effect can be provided.

Claims (7)

Inorganic composites containing 25% or more of K ₂ O, MgO, Na ₂ O, and CaO, 58% or less of SiO ₂ , and 20% or less of metallic components such as Fe ₂ O ₃ , Al ₂ O _3, and the like are prepared in a range of 1 to 10 nm ( 10 ^-9 m) is pulverized to make the number of constituent molecules into 10 ² to 10 ³ state, and classified by Gauss according to the magnetic difference and magnetic flux density of each constituent particle, and in order of particle size The particles are obtained in the order of black, red, orange, yellow, green, blue, indigo, purple, and white, and the pigments and voile oils used in the known oil-based paint compositions for functional ingredients of each color are 10 to A functional oil-based coating composition obtained by adding 50% by weight to an arc discharge for 10 to 20 minutes with a three-phase electric current flowing at a voltage of 50 V and a current of 200 A, and continuously discharging at an intermittent period of 1 to 2 seconds. The functional component of claim 1, wherein the functional component contains 25% or more of K ₂ O, MgO, Na ₂ O, and CaO, 58% or less of SiO ₂ , and 20% of metallic components such as Fe ₂ O ₃ , Al ₂ O _3, or the like. A functional oil paint composition characterized in that the inorganic composite below. The method of claim 1, wherein the functional component is SiO ₂ 54.42wt%, Al ₂ O ₃ 9.16wt%, Fe ₂ O ₃ 1.87wt%, K ₂ O 4.18wt%, Na ₂ O 3.74wt%, CaO 4.17wt%, A functional oil paint composition, characterized in that it is a deep granite powder consisting of MgO 14.19wt% and other minor components 8.27wt%. The functional oil paint composition according to claim 1, wherein the functional ingredient is porous. The porous functional component of claim 4, wherein the porous functional component is SiO ₂ 79.76 wt%, Al ₂ O ₂ 9.87 wt%, Fe ₂ O ₃ 0.21 wt%, K ₂ O 3.79 wt%, Na ₂ O 2.81 wt%, CaO 1.59 wt% , Deep granite powder, consisting of 0.86 wt% MgO and 1.11 wt% of other trace components containing germanium 0.5-2 ppm, SiO ₂ 73.41 wt%, Al ₂ O ₃ 14.56 wt%, Fe ₂ O ₃ 1.13 wt%, K ₂ Deep granite powder composed of O.13wt%, Na ₂ O 2.48wt%, CaO 2.28wt%, MgO 0.72wt% and other trace components 1.29wt% containing 0.5-2ppm germanium, SiO ₂ 73.53wt%, Al ₂ 12.52wt% O _3, 4.76wt% Fe ₂ O _3, 3.78wt% K ₂ O, 2.07wt% Na ₂ O, 1.56wt% CaO, 0.51wt% MgO and other minor components containing 0.5-2ppm germanium Deep granite powder composed of%, SiO ₂ 79.89wt%, Al ₂ O ₃ 14.92wt%, Fe ₂ O ₃ 0.31wt%, K ₂ O 1.24wt%, Na ₂ O 0.64wt%, CaO 1.89wt%, Pulverized granite powder consisting of 0.17 wt% MgO and 0.94 wt% of other trace components is first pulverized to 325 mesh, and then to 1 μm (12,500 mesh) using a vacuum pressure difference. After hurrying, the granulated granite powder and water were added to 1: 1 in a ball mill, and rotated at 40 to 80 rpm for 48 hours to pulverize. The granulated granite gel having 1-10 nm size was dispersed in a colloidal state. It is continuously discharged with three-phase electricity of 50V and 200A, and K ₂ 0, MgO, CaO, Na ₂ O, Al ₂ O ₃ , Fe ₂ O ₃ in the deep granite granules react to pop out and Functional oil paint composition characterized in that K ⁺ , Mg ⁺² , Ca ⁺² , Na ⁺ , Al ⁺³ , Fe ⁺³ ions are mixed, and heated to evaporate water into dry gel . Inorganic composites containing 25% or more of K ₂ O, MgO, Na ₂ O, and CaO, 58% or less of SiO ₂ , and 20% or less of metallic components such as Fe ₂ O ₃ , Al ₂ O _3, and the like are prepared in a range of 1 to 10 nm ( 10 ^-9 m) is pulverized to make the number of constituent molecules into 10 ² to 10 ³ state, and classified by Gauss according to the magnetic difference and magnetic flux density of each constituent particle, and in order of particle size The particles are obtained in the order of black, red, orange, yellow, green, blue, indigo, purple, and white, and the pigments and voile oils used in the known oil-based paint compositions for functional ingredients of each color are 10 to 50 wt% was added to the grinder, mixed at 40 to 80 rpm for 48 hours or longer, and then arc-discharged for 10 to 20 minutes with a three-phase electric current flowing at a voltage of 50 V and a current of 200 A. Function characterized in that obtained by continuous discharge in the intermittent period Method for producing an oil paint composition. A functional oil paint prepared from the composition of any one of claims 1 to 5.