CN107417118A - A kind of good antibacterial of wearability and the ceramic glaze of antistatic and the preparation method of ceramic tile - Google Patents
A kind of good antibacterial of wearability and the ceramic glaze of antistatic and the preparation method of ceramic tile Download PDFInfo
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- CN107417118A CN107417118A CN201710382753.7A CN201710382753A CN107417118A CN 107417118 A CN107417118 A CN 107417118A CN 201710382753 A CN201710382753 A CN 201710382753A CN 107417118 A CN107417118 A CN 107417118A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/10—Frit compositions, i.e. in a powdered or comminuted form containing lead
- C03C8/12—Frit compositions, i.e. in a powdered or comminuted form containing lead containing titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/02—Antibacterial glass, glaze or enamel
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Abstract
A kind of good antibacterial of wearability and the ceramic glaze of antistatic and the preparation method of ceramic tile, the glaze of the ceramic glaze include antistatic glass frit, nano composite antibacterial particle, inorganic oxide whisker and stamp-pad ink；The antistatic glass frit, nano composite antibacterial particle, the mass ratio of inorganic oxide whisker and stamp-pad ink are (1~1.5)：(0.5~0.8)：(0.5~2)：(2~2.5)；The fineness of the antistatic glass frit is 60~125 mesh；The present invention proposes the ceramic glaze of a kind of good antibacterial of wearability and antistatic, and it has the characteristics of anti-static effect is stable, good antiskid effect and antifouling property and resistance to elevated temperatures are high；It prepares the good antibacterial of wearability and the technique of the Ceramic Tiles of antistatic is simple, easy to operate.
Description
Technical field
The present invention relates to architectural pottery technical field, more particularly to the ceramic glaze of a kind of good antibacterial of wearability and antistatic
And the preparation method of ceramic tile.
Background technology
A kind of universal physical phenomenon of the electrostatic as nature, it is due to generation electric charge (electron outside nucleus) between different objects
Transfer and it is caused.When preparing high-purity powder material, due to powder during preparation it is quiet due to powder granule surface
Electricity adsorbs to the impurity particle in air, so as to cause the purity of material to reduce, in addition, static focus can also produce electric fire
Flower, produce security hidden trouble.
Static-electricity proof tile is widely used to the place higher to electrostatic requirement；Due to preventing the conduction used in quiet Ceramic Tiles
The price of material costly, in order to control production cost, typically applies one layer of glaze with anti-static effect in ceramic tile surface
Material, the electrostatic of ceramic tile surface is guided by conductive adhesive tape and other electric conductors；And common antistatic glaze paint in the market
It is conductive material that ceramic tile, which uses tin ash, and glaze face color is mostly blueness, and decorative pattern is fairly simple, and aesthetics is relatively low, but its
Performance is more single, still suffers from that antifouling property is relatively low, easily produces scratch, skid resistance and the problem of resistance to elevated temperatures difference；Therefore,
Had yet to be improved and developed for static-electricity proof tile technology.
The content of the invention
It is an object of the invention to propose the ceramic glaze of a kind of good antibacterial of wearability and antistatic, it has antistatic effect
The characteristics of fruit is stable, good antiskid effect and antifouling property and resistance to elevated temperatures are high.
It is another object of the present invention to propose a kind of technique is simple, prepare the good antibacterial of wearability easily to operate and
The method of the Ceramic Tiles of antistatic.
To use following technical scheme up to this purpose, the present invention：
The ceramic glaze of a kind of good antibacterial of wearability and antistatic, the glaze of the ceramic glaze melt including antistatic glass
Block, nano composite antibacterial particle, inorganic oxide whisker and stamp-pad ink；The antistatic glass frit, nano composite antibacterial particle,
The mass ratio of inorganic oxide whisker and stamp-pad ink is (1~1.5)：(0.5~0.8)：(0.5~2)：(2~2.5)；It is described anti-quiet
The fineness of electric glass frit is 60~125 mesh.
Further illustrate, the antistatic glass frit is by conductive powder and quality of the mass fraction for 24%~50%
The compound that the glass powder that fraction is 50%~76% forms is made through founding, cooling down and crush granulating；The conductive powder
Including one in conductive tin oxide, conductive titanium oxide, conductive zinc oxide, electric conductive oxidation iron, conductive barium titanate and conductive lead titanates
Kind or a variety of mixing compositions.
Further illustrate, the nano composite antibacterial particle is by the water containing strontium ion, rare earth ion and lamellar clay
Solution is through ball milling and dries obtained；The concentration of strontium ion is 2.5~6mmol/L in the aqueous solution, and the concentration of rare earth ion is
5.5-16mmol/L, the concentration of lamellar clay is 18~35g/L.
Further illustrate, include anti-settling agent in the stamp-pad ink, the anti-settling agent is carboxymethyl cellulose and attapulgite
Clay, the content of the carboxymethyl cellulose is 0.5~1%, and the content of the attapulgite is 3~5%.
Further illustrate, the lubricant that content is 0.3~0.6%, the lubrication are also included in the glaze of the ceramic glaze
Agent is talcum powder and/or graphite powder.
Further illustrate, the inorganic oxide whisker is in alumina whisker, ZnOw or zirconium oxide whisker
Any one or more combination.
A kind of method for preparing the good antibacterial of wearability and the Ceramic Tiles of antistatic, comprises the following steps：
(1) glaze of antibacterial and antistatic is prepared：First by nano composite antibacterial particle, inorganic oxide whisker and stamp-pad ink
According to mass ratio mixing and ball milling, preliminary glaze slurry is obtained after sieving；Again by the antistatic glass frit according to matter
Amount ratio is added into the preliminary glaze slurry and mixed, and the glaze of the antibacterial and antistatic is made；
(2) ground-coat enamel charity：To the adobe surface charity ground-coat enamel after drying process；
(3) glaze of charity antibacterial and antistatic：By the glaze of antibacterial and antistatic described in the adobe charity after charity ground-coat enamel
Material；
(4) dry, burn till：After the brick blank drying after the glaze of antibacterial described in charity and antistatic, high temperature is burnt till, and is gone forward side by side
After row edging quality inspection, the Ceramic Tiles with antibacterial and electrostatic-proof function are obtained.
Further illustrate, the flow velocity of the ground-coat enamel in step (2) is 4.68g/s, and proportion is 1.75~1.85, and fineness is
325 mesh, tail over ＜ 0.5%.
Further illustrate, the flow velocity of the antibacterial and the glaze of antistatic in step (1) is 2.85g/s, and proportion is
1.13。
Further illustrating, the temperature that the high temperature in step (4) is burnt till is 1170~1250 DEG C, firing time is 60~
110mim。
Beneficial effects of the present invention：The present invention by the antistatic glass frit and nano composite antibacterial particle and
Formula rate system between stamp-pad ink is adjusted, and the antistatic glass frit is by combining the good profit of the stamp-pad ink
Slip and appropriate viscosity, not only make glaze realize anti-static effect, while the antistatic glass frit is had
Certain suction viscous force and compared with small flow, can more uniformly and stably flow distribution, what is combined with base substrate is even closer so that
Its anti-static effect is more stable, and the ceramic tile surface after burning till can form natural Z-Correct bump mapping Z-correct effect and possess more preferable
Skidproof effect；And by adding the nano composite antibacterial particle, make glaze that can there is good anti-microbial property, formation
Glaze layer surface compact, so as to improve the antifouling property of ceramic tile and resistance to elevated temperatures；It is and further described inorganic by with the addition of
Oxide whisker improves brick surface intensity and the wearability after glaze is burnt till, so as to improving the breakdown strength in brick face.
Embodiment
Technical scheme is further illustrated below by embodiment.
The ceramic glaze of a kind of good antibacterial of wearability and antistatic, the glaze of the ceramic glaze melt including antistatic glass
Block, nano composite antibacterial particle, inorganic oxide whisker and stamp-pad ink；The antistatic glass frit, nano composite antibacterial particle,
The mass ratio of inorganic oxide whisker and stamp-pad ink is (1~1.5)：(0.5~0.8)：(0.5~2)：(2~2.5)；It is described anti-quiet
The fineness of electric glass frit is 60~125 mesh.The ceramic glaze of a kind of good antibacterial of wearability proposed by the present invention and antistatic, lead to
Cross and the formula rate system between the antistatic glass frit and nano composite antibacterial particle and stamp-pad ink is adjusted, institute
Antistatic glass frit is stated by the good lubricity for combining the stamp-pad ink and appropriate viscosity, not only realizes glaze
Anti-static effect, while the antistatic glass frit is had certain suction viscous force and compared with small flow, can be more equal
Even stably flow distribution, what is combined with base substrate is even closer, so that its anti-static effect is more stable, and after burning till
Ceramic tile surface can be formed and natural Z-Correct bump mapping Z-correct effect and possess more preferable skidproof effect；And answered by adding the nanometer
Antibacterial granule is closed, makes glaze that can there is good anti-microbial property, the glaze layer surface compact of formation, so as to improve the soil resistance of ceramic tile
Energy and resistance to elevated temperatures；And it is strong further to improve the brick face after glaze is burnt till by with the addition of the inorganic oxide whisker
Degree and wearability, so as to improve the breakdown strength in brick face.
Further illustrate, the antistatic glass frit is by conductive powder and quality of the mass fraction for 24%~50%
The compound that the glass powder that fraction is 50%~76% forms is made through founding, cooling down and crush granulating；The conductive powder
Including one in conductive tin oxide, conductive titanium oxide, conductive zinc oxide, electric conductive oxidation iron, conductive barium titanate and conductive lead titanates
Kind or a variety of mixing compositions.It is well mixed by conductive powder with glass powder, obtained antistatic glass frit can be realized
The effect of electrostatic discharge, and in order to ensure anti-static effect, then need to control quality≤conductive powder quality of simple glass powder
3 times；If more than 3 times, the conducting bridge that the antistatic glass frit can be caused to be formed in glaze layer is less, and bulk resistor can surpass
109 Ω m are crossed, anti-static effect is poor or does not possess anti-static effect.
Further illustrate, the nano composite antibacterial particle is by the water containing strontium ion, rare earth ion and lamellar clay
Solution is through ball milling and dries obtained；The concentration of strontium ion is 2.5~6mmol/L in the aqueous solution, and the concentration of rare earth ion is
5.5-16mmol/L, the concentration of lamellar clay is 18~35g/L.The nano composite antibacterial particle passes through layered clay energy
It is enough strontium ion and rare earth ion are adsorbed to clay crystal layer between, so as to realize by rare-earth ion activated antibacterial effect, simultaneously
Also the heat resistance of nano composite antibacterial particle is greatly improved.
Further illustrate, include anti-settling agent in the stamp-pad ink, the anti-settling agent is carboxymethyl cellulose and attapulgite
Clay, the content of the carboxymethyl cellulose is 0.5~1%, and the content of the attapulgite is 3~5%.Due to the stamp-pad ink
It is a kind of aqueous polymer, is stirred afterwards, it is necessary to certain stability with the antistatic glass frit, it is ensured that
The short-term storage candy glaze glaze will not occur significantly to change, therefore by the anti-settling agent, that is, add a certain amount of
The carboxymethyl cellulose or the Concave-convex clay rod, the precipitated and separated of glaze can be effectively reduced, when can place glaze
Between greatly prolong, improve the stability of glaze；Meanwhile the carboxymethyl cellulose can also serve the effect of bonding agent, from
And make the distribution of the antistatic glass frit more stable.
Further illustrate, the lubricant that content is 0.3~0.6%, the lubrication are also included in the glaze of the ceramic glaze
Agent is talcum powder and/or graphite powder.The uniformity of distribution during due in order to ensure glaze cloth being imposed on to the billet surface, then
The lubricity of increase glaze is needed, improves the continuity and Modulatory character of glaze charity, therefore in the glaze of the ceramic glaze
Corresponding lubricant is added, improves the greasy property of the glaze containing the antistatic glass frit, optimizes charity effect, so as to
Improve the brick face decorative effect after burning till.
Further illustrate, the inorganic oxide whisker is in alumina whisker, ZnOw or zirconium oxide whisker
Any one or more combination.
A kind of method for preparing the good antibacterial of wearability and the Ceramic Tiles of antistatic, comprises the following steps：
(1) glaze of antibacterial and antistatic is prepared：First by nano composite antibacterial particle, inorganic oxide whisker and stamp-pad ink
According to mass ratio mixing and ball milling, preliminary glaze slurry is obtained after sieving；Again by the antistatic glass frit according to matter
Amount ratio is added into the preliminary glaze slurry and mixed, and the glaze of the antibacterial and antistatic is made；
(2) ground-coat enamel charity：To the adobe surface charity ground-coat enamel after drying process；
(3) glaze of charity antibacterial and antistatic：By the glaze of antibacterial and antistatic described in the adobe charity after charity ground-coat enamel
Material；
(4) dry, burn till：After the brick blank drying after the glaze of antibacterial described in charity and antistatic, high temperature is burnt till, and is gone forward side by side
After row edging quality inspection, the Ceramic Tiles with antibacterial and electrostatic-proof function are obtained.The present invention be prepared into with antibacterial and anti-
The method of the Ceramic Tiles of electrostatic function, first in one layer of ground-coat enamel of adobe surface charity, after ensuring the certain glossiness in its brick face,
The charity of the glaze of the antibacterial and antistatic is carried out again, and so as to obtain the Ceramic Tiles with antibacterial and electrostatic-proof function, it has
Have that preparation technology is simple, easy to operate, the surface of ceramic tile forms natural Z-Correct bump mapping Z-correct effect and possesses skidproof effect, antistatic
Effect is more stable, and its breakdown strength is higher.
Further illustrate, the flow velocity of the ground-coat enamel in step (2) is 4.68g/s, and proportion is 1.75~1.85, and fineness is
325 mesh, tail over ＜ 0.5%.The ground-coat enamel is to be formed by the chemical materials Jing Guo product examine according to formula rate is well mixed, and it is changed
Learning composition includes SiO2, Al2O3, ZnO, MgO, K2O, CaO, Na2O, and ZrO2, and the ground-coat enamel uses after ball milling detects.
Further illustrate, the flow velocity of the antibacterial and the glaze of antistatic in step (1) is 2.85g/s, and proportion is
1.13.By controlling the parameters such as the certain flow velocity of the glaze of the antibacterial and antistatic and proportion, so that it is guaranteed that its cloth imposes on base
The uniformity in body surface face and the tight ness rating combined with base substrate.
Further illustrating, the temperature that the high temperature in step (4) is burnt till is 1170~1250 DEG C, firing time is 60~
110mim。
A kind of preparation methods with antibacterial and the Ceramic Tiles of electrostatic-proof function of embodiment 1-, comprise the following steps：
(1) glaze of antibacterial and antistatic is prepared：Mass ratio is got out first as 1：0.8：0.5：2.5 antistatic glass
Frit, nano composite antibacterial particle, alumina whisker and stamp-pad ink；The fineness of the antistatic glass frit is 60 mesh；
Wherein, the antistatic glass frit includes 24% conductive tin oxide and the conducting powder of conductive titanium oxide mixing
Material, it is made with the compound of 76% glass powder composition through founding, cooling down and crush granulating；The nano composite antibacterial particle
Through ball milling and dried obtained for the aqueous solution containing strontium ion, rare earth ion and lamellar clay；Strontium ion in the aqueous solution
Concentration is 2.5mmol/L, and the concentration of rare earth ion is 5.5mmol/L, and the concentration of lamellar clay is 18g/L；The stamp-pad ink adds
1% carboxymethyl cellulose and 3% Concave-convex clay rod；
Nano composite antibacterial particle, alumina whisker and stamp-pad ink are mixed into simultaneously ball milling according to mass ratio, obtained after sieving
Obtain preliminary glaze slurry；The antistatic glass frit is added into the preliminary glaze slurry according to mass ratio again and mixed
Close, and add 0.6% talcum powder, the flow velocity of the glaze of the antibacterial and antistatic, the antibacterial and the glaze of antistatic is made
For 2.85g/s, proportion 1.13；
(2) ground-coat enamel charity：To the adobe surface charity ground-coat enamel after drying process, the flow velocity of the ground-coat enamel is 4.68g/s, than
Weight is 1.85, and fineness is 325 mesh, tails over ＜ 0.5%；
(3) glaze of charity antibacterial and antistatic：By the glaze of antibacterial and antistatic described in the adobe charity after charity ground-coat enamel
Material；
(4) dry, burn till：After the brick blank drying after the glaze of antibacterial described in charity and antistatic, high temperature is burnt till, described
The temperature that high temperature is burnt till is 1170 DEG C, firing time 110mim, and after carrying out edging quality inspection, acquisition has antibacterial and antistatic
The Ceramic Tiles 1 of function.
A kind of preparation methods with antibacterial and the Ceramic Tiles of electrostatic-proof function of embodiment 2-, comprise the following steps：
(1) glaze of antibacterial and antistatic is prepared：Mass ratio is got out first as 1.5：0.5：2：2 antistatic glass melts
Block, nano composite antibacterial particle, ZnOw and stamp-pad ink；The fineness of the antistatic glass frit is 125 mesh；
Wherein, the antistatic glass frit mixes including 50% conductive zinc oxide, electric conductive oxidation iron and conductive barium titanate
The conductive powder of conjunction, it is made with the compound of 50% glass powder composition through founding, cooling down and crush granulating；The nanometer is answered
Antibacterial granule is closed to be the aqueous solution containing strontium ion, rare earth ion and lamellar clay through ball milling and dry obtained；The aqueous solution
The concentration of middle strontium ion is 6mmol/L, and the concentration of rare earth ion is 16mmol/L, and the concentration of lamellar clay is 35g/L；The print
Oil adds 0.5% carboxymethyl cellulose and 5% Concave-convex clay rod；
Nano composite antibacterial particle, ZnOw and stamp-pad ink are mixed into simultaneously ball milling according to mass ratio, obtained after sieving
Obtain preliminary glaze slurry；The antistatic glass frit is added into the preliminary glaze slurry according to mass ratio again and mixed
Close, and add 0.3% talcum powder, the flow velocity of the glaze of the antibacterial and antistatic, the antibacterial and the glaze of antistatic is made
For 2.85g/s, proportion 1.13；
(2) ground-coat enamel charity：To the adobe surface charity ground-coat enamel after drying process, the flow velocity of the ground-coat enamel is 4.68g/s, than
Weight is 1.75, and fineness is 325 mesh, tails over ＜ 0.5%；
(3) glaze of charity antibacterial and antistatic：By the glaze of antibacterial and antistatic described in the adobe charity after charity ground-coat enamel
Material；
(4) dry, burn till：After the brick blank drying after the glaze of antibacterial described in charity and antistatic, high temperature is burnt till, described
The temperature that high temperature is burnt till is 1250 DEG C, firing time 60mim, and after carrying out edging quality inspection, acquisition has antibacterial and antistatic
The Ceramic Tiles 2 of function.
A kind of preparation methods with antibacterial and the Ceramic Tiles of electrostatic-proof function of embodiment 3-, comprise the following steps：
(1) glaze of antibacterial and antistatic is prepared：Mass ratio is got out first as 1.3：0.6：1：2.3 antistatic glass
Frit, nano composite antibacterial particle, zirconium oxide whisker and stamp-pad ink；The fineness of the antistatic glass frit is 100 mesh；
Wherein, the antistatic glass frit includes 45% conductive barium titanate and the conducting powder of conductive lead titanates mixing
Material, it is made with the compound of 55% glass powder composition through founding, cooling down and crush granulating；The nano composite antibacterial particle
Through ball milling and dried obtained for the aqueous solution containing strontium ion, rare earth ion and lamellar clay；Strontium ion in the aqueous solution
Concentration is 4mmol/L, and the concentration of rare earth ion is 10.5mmol/L, and the concentration of lamellar clay is 25g/L；The stamp-pad ink adds
0.8% carboxymethyl cellulose and 4% Concave-convex clay rod；
Nano composite antibacterial particle, zirconium oxide whisker and stamp-pad ink are mixed into simultaneously ball milling according to mass ratio, obtained after sieving
Obtain preliminary glaze slurry；The antistatic glass frit is added into the preliminary glaze slurry according to mass ratio again and mixed
Close, 0.45% graphite powder is added, the flow velocity of the glaze of the antibacterial and antistatic, the antibacterial and the glaze of antistatic is made
For 2.85g/s, proportion 1.13；
(2) ground-coat enamel charity：To the adobe surface charity ground-coat enamel after drying process, the flow velocity of the ground-coat enamel is 4.68g/s, than
Weight is 1.80, and fineness is 325 mesh, tails over ＜ 0.5%；
(3) glaze of charity antibacterial and antistatic：By the glaze of antibacterial and antistatic described in the adobe charity after charity ground-coat enamel
Material；
(4) dry, burn till：After the brick blank drying after the glaze of antibacterial described in charity and antistatic, high temperature is burnt till, described
The temperature that high temperature is burnt till is 1205 DEG C, firing time 85mim, and after carrying out edging quality inspection, acquisition has antibacterial and antistatic
The Ceramic Tiles 3 of function.
Table 1：The performance comparision of the antistatic of different ceramic brick surfaces
As shown in Table 1, the existing Ceramic Tiles with electrostatic-proof function and the present invention by embodiment 1, embodiment 2 and are implemented
The Ceramic Tiles that example 3 is prepared into respectively compare, it can be clearly seen that the anti-static ability of Ceramic Tiles 1~3 significantly improves, and has
Certain antibacterial ability, its non-skid property and soil resistance are more preferable, and its breakdown strength significantly increases, and wearability is more preferable.
The technical principle of the present invention is described above in association with specific embodiment.These descriptions are intended merely to explain the present invention's
Principle, and limiting the scope of the invention can not be construed in any way.Based on explanation herein, the technology of this area
Personnel would not require any inventive effort the other embodiments that can associate the present invention, and these modes are fallen within
Within protection scope of the present invention.
Claims (10)
1. the ceramic glaze of a kind of good antibacterial of wearability and antistatic, it is characterised in that：The glaze of the ceramic glaze includes anti-quiet
Electric glass frit, nano composite antibacterial particle, inorganic oxide whisker and stamp-pad ink；It is the antistatic glass frit, nano combined
The mass ratio of antibacterial granule, inorganic oxide whisker and stamp-pad ink is (1~1.5)：(0.5~0.8)：(0.5~2)：(2~2.5)；
The fineness of the antistatic glass frit is 60~125 mesh.
2. the ceramic glaze of a kind of good antibacterial of wearability according to claim 1 and antistatic, it is characterised in that：It is described anti-
The glass dust that the conductive powder that it is 24%~50% by mass fraction that electrostatic glass frit, which is, is 50%~76% with mass fraction
The compound of material composition is made through founding, cooling down and crush granulating；The conductive powder includes conductive tin oxide, electric conductive oxidation
One or more mixing compositions in titanium, conductive zinc oxide, electric conductive oxidation iron, conductive barium titanate and conductive lead titanates.
3. the ceramic glaze of a kind of good antibacterial of wearability according to claim 1 and antistatic, it is characterised in that：It is described to receive
Rice composite antibacterial particle is to be made by the aqueous solution containing strontium ion, rare earth ion and lamellar clay through ball milling and drying；It is described
The concentration of strontium ion is 2.5~6mmol/L in the aqueous solution, and the concentration of rare earth ion is 5.5-16mmol/L, lamellar clay it is dense
Spend for 18~35g/L.
4. the ceramic glaze of a kind of good antibacterial of wearability according to claim 1 and antistatic, it is characterised in that：The print
Include anti-settling agent in oil, the anti-settling agent is carboxymethyl cellulose and Concave-convex clay rod, and the carboxymethyl cellulose contains
Measure as 0.5~1%, the content of the attapulgite is 3~5%.
5. the ceramic glaze of a kind of good antibacterial of wearability according to claim 1 and antistatic, it is characterised in that：The pottery
Also include the lubricant that content is 0.3~0.6% in the glaze of enamel, the lubricant is talcum powder and/or graphite powder.
6. the ceramic glaze of a kind of good antibacterial of wearability according to claim 1 and antistatic, it is characterised in that：The nothing
Machine oxide whisker is any one or more combination in alumina whisker, ZnOw or zirconium oxide whisker.
7. a kind of ceramic glaze using as described in any one in claim 1~6 prepares the good antibacterial of wearability and antistatic
Ceramic Tiles method, it is characterised in that：Comprise the following steps：
(1) glaze of antibacterial and antistatic is prepared：First by nano composite antibacterial particle, inorganic oxide whisker and stamp-pad ink according to
Mass ratio mixing and ball milling, obtain preliminary glaze slurry after sieving；Again by the antistatic glass frit according to mass ratio
Example is added into the preliminary glaze slurry and mixed, and the glaze of the antibacterial and antistatic is made；
(2) ground-coat enamel charity：To the adobe surface charity ground-coat enamel after drying process；
(3) glaze of charity antibacterial and antistatic：By the glaze of antibacterial and antistatic described in the adobe charity after charity ground-coat enamel；
(4) dry, burn till：After the brick blank drying after the glaze of antibacterial described in charity and antistatic, high temperature is burnt till, and is ground
After the quality inspection of side, the Ceramic Tiles with antibacterial and electrostatic-proof function are obtained.
8. a kind of method for preparing the good antibacterial of wearability and the Ceramic Tiles of antistatic according to claim 7, its feature
It is：The flow velocity of the ground-coat enamel in step (2) is 4.68g/s, and proportion is 1.75~1.85, and fineness is 325 mesh, tails over ＜
0.5%.
9. a kind of method for preparing the good antibacterial of wearability and the Ceramic Tiles of antistatic according to claim 7, its feature
It is：The flow velocity of the antibacterial and the glaze of antistatic in step (1) is 2.85g/s, proportion 1.13.
10. a kind of method for preparing the good antibacterial of wearability and the Ceramic Tiles of antistatic according to claim 7, its feature
It is：The temperature that the high temperature in step (4) is burnt till is 1170~1250 DEG C, and firing time is 60~110mim.
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| CN201710382753.7A CN107417118A (en) | 2017-05-26 | 2017-05-26 | A kind of good antibacterial of wearability and the ceramic glaze of antistatic and the preparation method of ceramic tile |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113443832A (en) * | 2021-09-02 | 2021-09-28 | 广东欧文莱陶瓷有限公司 | Rock plate with mutton tallow jade touch feeling and preparation method thereof |
| WO2022252931A1 (en) * | 2021-05-31 | 2022-12-08 | 佛山欧神诺陶瓷有限公司 | Antibacterial and antistatic laboratory ceramic countertop and preparation method therefor |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103739199A (en) * | 2013-12-17 | 2014-04-23 | 佛山市粤峤陶瓷技术创新服务中心 | Manufacturing method of antistatic glass frit |
| CN103922815A (en) * | 2014-03-25 | 2014-07-16 | 广东金意陶陶瓷有限公司 | Manufacturing process of ceramic brick with candy effect |
| CN104355607A (en) * | 2014-10-16 | 2015-02-18 | 佛山市禾才科技服务有限公司 | High-strength semitransparent ceramic sheet and preparation method thereof |
| CN105271753A (en) * | 2015-10-30 | 2016-01-27 | 淄博金狮王科技陶瓷有限公司 | Anti-skid and antibacterial ceramic tile and preparation process thereof |
-
2017
- 2017-05-26 CN CN201710382753.7A patent/CN107417118A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103739199A (en) * | 2013-12-17 | 2014-04-23 | 佛山市粤峤陶瓷技术创新服务中心 | Manufacturing method of antistatic glass frit |
| CN103922815A (en) * | 2014-03-25 | 2014-07-16 | 广东金意陶陶瓷有限公司 | Manufacturing process of ceramic brick with candy effect |
| CN104355607A (en) * | 2014-10-16 | 2015-02-18 | 佛山市禾才科技服务有限公司 | High-strength semitransparent ceramic sheet and preparation method thereof |
| CN105271753A (en) * | 2015-10-30 | 2016-01-27 | 淄博金狮王科技陶瓷有限公司 | Anti-skid and antibacterial ceramic tile and preparation process thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张晏清主编: "《建筑结构材料》", 29 February 2016, 同济大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022252931A1 (en) * | 2021-05-31 | 2022-12-08 | 佛山欧神诺陶瓷有限公司 | Antibacterial and antistatic laboratory ceramic countertop and preparation method therefor |
| CN113443832A (en) * | 2021-09-02 | 2021-09-28 | 广东欧文莱陶瓷有限公司 | Rock plate with mutton tallow jade touch feeling and preparation method thereof |
| CN113443832B (en) * | 2021-09-02 | 2021-11-12 | 广东欧文莱陶瓷有限公司 | Rock plate with mutton tallow jade touch feeling and preparation method thereof |
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