CN102898915B - A kind of Epoxy composite metal antirust paint and preparation method thereof - Google Patents
A kind of Epoxy composite metal antirust paint and preparation method thereof Download PDFInfo
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- CN102898915B CN102898915B CN201210340768.4A CN201210340768A CN102898915B CN 102898915 B CN102898915 B CN 102898915B CN 201210340768 A CN201210340768 A CN 201210340768A CN 102898915 B CN102898915 B CN 102898915B
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- 239000003973 paint Substances 0.000 title claims abstract description 46
- 239000004593 Epoxy Substances 0.000 title claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 14
- 239000002184 metal Substances 0.000 title claims abstract description 14
- 239000002131 composite material Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 22
- 238000004537 pulping Methods 0.000 claims abstract description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 30
- 239000000843 powder Substances 0.000 claims description 20
- 239000006185 dispersion Substances 0.000 claims description 18
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 14
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 14
- 239000004576 sand Substances 0.000 claims description 12
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Diphosphoinositol tetrakisphosphate Chemical compound OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 238000003801 milling Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 5
- QUKFNRQNPQSTPD-UHFFFAOYSA-N 2-methylpropanoic acid;pentane-1,3-diol Chemical compound CC(C)C(O)=O.CCC(O)CCO QUKFNRQNPQSTPD-UHFFFAOYSA-N 0.000 claims description 5
- 229920002125 Sokalan® Polymers 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- 239000004816 latex Substances 0.000 claims description 5
- 229920000126 latex Polymers 0.000 claims description 5
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 5
- 229920002401 polyacrylamide Polymers 0.000 claims description 5
- 239000004584 polyacrylic acid Substances 0.000 claims description 5
- 238000004062 sedimentation Methods 0.000 claims description 5
- 159000000000 sodium salts Chemical class 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- KOEFSMLBFZGZLD-UHFFFAOYSA-L [bis(2-ethylhexoxy)-oxidophosphaniumyl] dihydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] phosphate ethane-1,2-diolate titanium(4+) Chemical compound [Ti+4].[O-]CC[O-].CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)(O)=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP([O-])([O-])=O KOEFSMLBFZGZLD-UHFFFAOYSA-L 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 6
- 150000003839 salts Chemical class 0.000 abstract description 5
- 230000002401 inhibitory effect Effects 0.000 abstract description 3
- 239000007921 spray Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 230000032683 aging Effects 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000005477 standard model Effects 0.000 description 1
Abstract
The invention discloses a kind of Epoxy composite metal antirust paint and preparation method thereof, be made up of pulping raw material and paint raw material, the paint film that rust-inhibiting paint of the present invention is formed, have that hardness is high, damage resistant, strong adhesion, salt spray resistance, salt water resistance, acid and alkali-resistance, water-fast, oil resistant, ultraviolet light, ageing-resistant, anti-low temperature, wet-heat resisting, reusable at old coating surface, paint film can not be caused to damage, superpower paint film flexibility etc.The general paint film life-span can reach 8-10.
Description
Technical field
The present invention relates to a kind of metallic anti-rust paint, specifically a kind of Epoxy composite metal antirust paint.
Background technology
Various mechanical means appearance all needs coating layer of metal paint, increases attractive in appearance on the one hand, on the other hand dust-proof rust resistance and corrosion resistance; Rust-inhibiting paint of the prior art, because of containing a large amount of volatile organic solvent, produces volatile gases poisonous, harmful in a large number, polluted air and infringement human health.Ubiquity weather resistance is not good, easily comes off, inadaptable complicated, severe environment.
Summary of the invention
The invention provides a kind of Epoxy composite metal antirust paint and preparation method thereof, there is good mechanical stability, snappiness and surface hardness, good weatherability.
Technical scheme of the present invention is:
Epoxy composite metal antirust paint, is characterized in that being made up of the feed composition of following component weight part:
Pulping raw material:
Zinc powder 3-5, propylene glycol phenylate 1-3,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 5-8, anti-sedimentation agent 3300S1-2, flow agent BYK-3001-2, polyacrylic acid sodium salt SN-50001-2, magnesium hydroxide 10-15, modified nano montmorillonite powder 5-10, modified soluble nano silicone colloidal sol 5-10;
Paint raw material:
Pure acrylic latex 30-35, epoxy emulsion 10-15, myo-Inositol hexaphosphate 20-25, Polyacrylamide 1-2, sodium laurylsulfate 3-5, propylene glycol 50-60,2-amino-2-methyl-1-propanol 1-2;
Modified nano montmorillonite powder is prepared by the following method:
(1), montmorillonite powder add (0.8 ~ 1.2) g/L potassium permanganate solution soak 2-3 hour, pulls out, be washed to neutrality, then the sodium radio-phosphate,P-32 solution putting into 2-5% soaks, stirring reaction 3-4 hour at 60-80 DEG C;
(2) in soak solution, add the 3-4% sodium laurylsulfate, 1-2% Di(dioctylpyrophosphato) ethylene titanate, 2-3% vinyl three ('beta '-methoxy oxyethyl group) silane, the 20-25% ferrophosphorus powder that are equivalent to montmorillonite powder weight, high speed dispersion 4200-4500 rev/min, 20-30 minute;
(3) dry, pulverize, make ultrafine powder;
Modified soluble nano silicone colloidal sol is prepared by the following method:
Water-soluble nanoscale silica sol adds 4-5% nano-carbon powder, 3-5% ferric oxide, is mixed and heated to 50-60 DEG C, cools after 30-40 minute.
Described Epoxy composite metal antirust paint, is characterized in that being made up of the feed composition of following component weight part:
Pulping raw material:
Zinc powder 4, propylene glycol phenylate 2,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 6, anti-sedimentation agent 3300S1, flow agent BYK-3002, polyacrylic acid sodium salt SN-50002, magnesium hydroxide 15, modified nano montmorillonite powder 10, modified soluble nano silicone colloidal sol 10;
Paint raw material:
Pure acrylic latex 30, epoxy emulsion 15, myo-Inositol hexaphosphate 25, Polyacrylamide 2, sodium laurylsulfate 5, propylene glycol 60,2-amino-2-methyl-1-propanol 2.
The preparation method of described Epoxy composite metal antirust paint, is characterized in that comprising the following steps:
(1), slurrying: pulping raw material is poured into batching kettle mixing, then mixed pulping raw material is transported in high-speed dispersing kettle and carries out stirring, disperseing 50-60 minute, rotating speed 3200-3500 rev/min, slurrying component after dispersion is transported in sand mill carries out wet type sand milling, dispersion, obtain slurry, slurry mesh-of-grind is less than or equals 40 microns;
(2) paint: add paint raw material in obtained slurry, be then transported in high-speed dispersing kettle and carry out stirring, disperseing, after dispersion, being transported in sand mill of component carries out wet type sand milling, dispersion, obtains paint vehicle; Again with 3200-3600 rev/min of high speed dispersion 40-50min;
(3) obtained paint vehicle is transported to vibrating filter to carry out filtering and screening, fineness≤40um, then the product after filtration is packed, warehouse-in.
The paint film that rust-inhibiting paint of the present invention is formed, has that hardness is high, damage resistant, strong adhesion, and salt spray resistance, salt water resistance, acid and alkali-resistance, water-fast, oil resistant are reusable at old coating surface, paint film can not be caused to damage, superpower paint film flexibility etc.The general paint film life-span can reach 8-10.
Embodiment
Epoxy composite metal antirust paint, be made up of the raw material of following component weight part (kilogram):
Pulping raw material:
Zinc powder 4, propylene glycol phenylate 2,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 6, anti-sedimentation agent 3300S1, flow agent BYK-3002, polyacrylic acid sodium salt SN-50002, magnesium hydroxide 15, modified nano montmorillonite powder 10, modified soluble nano silicone colloidal sol 10;
Paint raw material:
Pure acrylic latex 30, epoxy emulsion 15, myo-Inositol hexaphosphate 25, Polyacrylamide 2, sodium laurylsulfate 5, propylene glycol 60,2-amino-2-methyl-1-propanol 2.
Modified nano montmorillonite powder is prepared by the following method:
(1), montmorillonite powder adds 0.8g/L potassium permanganate solution and soaks 2 hours, pulls out, is washed to neutrality, then the sodium radio-phosphate,P-32 solution putting into 5% soaks, stirring reaction 4 hours at 60-70 DEG C;
(2) in soak solution, add 3% sodium laurylsulfate, 2% Di(dioctylpyrophosphato) ethylene titanate, 2% vinyl three ('beta '-methoxy oxyethyl group) silane, the 20% ferrophosphorus powder that are equivalent to montmorillonite powder weight, high speed dispersion 4200-4500 rev/min, 20-30 minute;
(3) dry, pulverize, make ultrafine powder;
Modified soluble nano silicone colloidal sol is prepared by the following method:
Water-soluble nanoscale silica sol adds 5% nano-carbon powder, 3% ferric oxide, and mix and blend, is heated to 50-60 DEG C, cools after 30-40 minute.
The preparation method of Epoxy composite metal antirust paint:
(1), slurrying: pulping raw material is poured into batching kettle mixing, then mixed pulping raw material is transported in high-speed dispersing kettle and carries out stirring, disperseing 50-60 minute, rotating speed 3200-3500 rev/min, slurrying component after dispersion is transported in sand mill carries out wet type sand milling, dispersion, obtain slurry, slurry mesh-of-grind is less than or equals 40 microns;
(2) paint: add paint raw material in obtained slurry, be then transported in high-speed dispersing kettle and carry out stirring, disperseing, after dispersion, being transported in sand mill of component carries out wet type sand milling, dispersion, obtains paint vehicle; Again with 3200-3600 rev/min of high speed dispersion 40-50min;
(3) obtained paint vehicle is transported to vibrating filter to carry out filtering and screening, fineness≤40um, then the product after filtration is packed, warehouse-in.
Metallic anti-rust paint performance index of the present invention:
1, paint film color and outward appearance: flat smooth, color conformance with standard model and aberration scope
2, viscosity (23 ± 1 DEG C of coating-4 viscosity meters, S): 80-120
3, fineness≤50
4, time of drying (25 DEG C): surface drying 25-30min, 48h is done solid work
5, snappiness mm≤2
6, hardness >=2H
7, high temperature resistant (130 DEG C) >=450h
8, shock-resistance 50
9, salt spray resistance (120h level) >=2
10, water tolerance (29 ± 1 DEG C of 240h): non-foaming, does not come off
11, oil resistant (90# gasoline, 56h): non-foaming, does not come off
12, alkali resistance (GB/T9755-2001): by 48 hours
13, artificial weathering ageing resistance (GB/T9755-2001): by 1000 hours.
Claims (2)
1. an Epoxy composite metal antirust paint, is characterized in that being made up of the feed composition of following component weight part:
Pulping raw material:
Zinc powder 3-5, propylene glycol phenylate 1-3,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 5-8, anti-sedimentation agent 3300S1-2, flow agent BYK-3001-2, polyacrylic acid sodium salt SN-50001-2, magnesium hydroxide 10-15, modified nano montmorillonite powder 5-10, modified soluble nano silicone colloidal sol 5-10;
Paint raw material:
Pure acrylic latex 30-35, epoxy emulsion 10-15, myo-Inositol hexaphosphate 20-25, Polyacrylamide 1-2, sodium laurylsulfate 3-5, propylene glycol 50-60,2-amino-2-methyl-1-propanol 1-2;
Modified nano montmorillonite powder is prepared by the following method:
(1), montmorillonite powder add (0.8 ~ 1.2) g/L potassium permanganate solution soak 2-3 hour, pulls out, be washed to neutrality, then the sodium radio-phosphate,P-32 solution putting into 2-5% soaks, stirring reaction 3-4 hour at 60-80 DEG C;
(2) in soak solution, add the 3-4% sodium laurylsulfate, 1-2% Di(dioctylpyrophosphato) ethylene titanate, 2-3% vinyl three ('beta '-methoxy oxyethyl group) silane, the 20-25% ferrophosphorus powder that are equivalent to montmorillonite powder weight, high speed dispersion 4200-4500 rev/min, 20-30 minute;
(3) dry, pulverize, make ultrafine powder;
Modified soluble nano silicone colloidal sol is prepared by the following method:
Water-soluble nanoscale silica sol adds 4-5% nano-carbon powder, 3-5% ferric oxide, is mixed and heated to 50-60 DEG C, cools after 30-40 minute;
The preparation method of described Epoxy composite metal antirust paint, comprises the following steps:
(1), slurrying: pulping raw material is poured into batching kettle mixing, then mixed pulping raw material is transported in high-speed dispersing kettle and carries out stirring, disperseing 50-60 minute, rotating speed 3200-3500 rev/min, slurrying component after dispersion is transported in sand mill carries out wet type sand milling, dispersion, obtain slurry, slurry mesh-of-grind is less than or equals 40 microns;
(2) paint: add paint raw material in obtained slurry, be then transported in high-speed dispersing kettle and carry out stirring, disperseing, after dispersion, being transported in sand mill of component carries out wet type sand milling, dispersion, obtains paint vehicle; Again with 3200-3600 rev/min of high speed dispersion 40-50min;
(3) obtained paint vehicle is transported to vibrating filter to carry out filtering and screening, fineness≤40um, then the product after filtration is packed, warehouse-in.
2. Epoxy composite metal antirust paint according to claim 1, is characterized in that being made up of the feed composition of following component weight part:
Pulping raw material:
Zinc powder 4, propylene glycol phenylate 2,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 6, anti-sedimentation agent 3300S1,
Flow agent BYK-3002, polyacrylic acid sodium salt SN-50002, magnesium hydroxide 15, modified nano montmorillonite powder 10, modified soluble nano silicone colloidal sol 10;
Paint raw material:
Pure acrylic latex 30, epoxy emulsion 15, myo-Inositol hexaphosphate 25, Polyacrylamide 2, sodium laurylsulfate 5, propylene glycol 60,2-amino-2-methyl-1-propanol 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210340768.4A CN102898915B (en) | 2012-09-15 | 2012-09-15 | A kind of Epoxy composite metal antirust paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210340768.4A CN102898915B (en) | 2012-09-15 | 2012-09-15 | A kind of Epoxy composite metal antirust paint and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102898915A CN102898915A (en) | 2013-01-30 |
| CN102898915B true CN102898915B (en) | 2016-04-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210340768.4A Expired - Fee Related CN102898915B (en) | 2012-09-15 | 2012-09-15 | A kind of Epoxy composite metal antirust paint and preparation method thereof |
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| Country | Link |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108129924A (en) * | 2018-01-02 | 2018-06-08 | 马鞍山佳夫尼电气科技有限公司 | A kind of anti-oxidant antirust paint for power equipment |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5945364A (en) * | 1982-09-06 | 1984-03-14 | Kubota Ltd | Epoxy resin powder paint |
| JPS63309561A (en) * | 1987-06-11 | 1988-12-16 | Mitsui Eng & Shipbuild Co Ltd | Heat-resistant alkali paint |
| CN1978564A (en) * | 2005-12-02 | 2007-06-13 | 中国科学院金属研究所 | Nano clay modified epoxy zinc-rich coating, and its preparing method |
| CN101029115A (en) * | 2007-03-07 | 2007-09-05 | 哈尔滨工业大学 | Antirust emulsion of self-crosslinked interpenetrating net polymer and its production |
| CN102093799A (en) * | 2009-12-15 | 2011-06-15 | 徐昌彪 | Water-borne metal self-drying antirusting paint |
| CN102134438A (en) * | 2011-03-02 | 2011-07-27 | 天津通远涂料化工有限公司 | Environmental friendly anticorrosion baking finish for water-based coiled materials |
-
2012
- 2012-09-15 CN CN201210340768.4A patent/CN102898915B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5945364A (en) * | 1982-09-06 | 1984-03-14 | Kubota Ltd | Epoxy resin powder paint |
| JPS63309561A (en) * | 1987-06-11 | 1988-12-16 | Mitsui Eng & Shipbuild Co Ltd | Heat-resistant alkali paint |
| CN1978564A (en) * | 2005-12-02 | 2007-06-13 | 中国科学院金属研究所 | Nano clay modified epoxy zinc-rich coating, and its preparing method |
| CN101029115A (en) * | 2007-03-07 | 2007-09-05 | 哈尔滨工业大学 | Antirust emulsion of self-crosslinked interpenetrating net polymer and its production |
| CN102093799A (en) * | 2009-12-15 | 2011-06-15 | 徐昌彪 | Water-borne metal self-drying antirusting paint |
| CN102134438A (en) * | 2011-03-02 | 2011-07-27 | 天津通远涂料化工有限公司 | Environmental friendly anticorrosion baking finish for water-based coiled materials |
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| CN102898915A (en) | 2013-01-30 |
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Inventor after: Ni Shujun Inventor before: Liu Chunfang |
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Address after: 233400 Anhui Province Economic Development Zone, Huaiyuan City, the west side of Tu Shan Avenue Patentee after: Huaiyuan County crown still renewable resources Co.,Ltd. Address before: 233400 Anhui Province Economic Development Zone, Huaiyuan City, the west side of Tu Shan Avenue Patentee before: ANHUI HUAIYUAN COUNTY SHANGGUAN MOULD TECHNOLOGY Co.,Ltd. |
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