CN102888167B - A kind of aging-resistant metal anti-rust paint and preparation method thereof - Google Patents
A kind of aging-resistant metal anti-rust paint and preparation method thereof Download PDFInfo
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- CN102888167B CN102888167B CN201210340770.1A CN201210340770A CN102888167B CN 102888167 B CN102888167 B CN 102888167B CN 201210340770 A CN201210340770 A CN 201210340770A CN 102888167 B CN102888167 B CN 102888167B
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- 239000003973 paint Substances 0.000 title claims abstract description 46
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 230000032683 aging Effects 0.000 title claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 14
- 239000002184 metal Substances 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 22
- 238000004537 pulping Methods 0.000 claims abstract description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 30
- 239000000843 powder Substances 0.000 claims description 25
- 239000006185 dispersion Substances 0.000 claims description 18
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 14
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 14
- 239000004576 sand Substances 0.000 claims description 12
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Diphosphoinositol tetrakisphosphate Chemical compound OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 238000003801 milling Methods 0.000 claims description 6
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 5
- QUKFNRQNPQSTPD-UHFFFAOYSA-N 2-methylpropanoic acid;pentane-1,3-diol Chemical compound CC(C)C(O)=O.CCC(O)CCO QUKFNRQNPQSTPD-UHFFFAOYSA-N 0.000 claims description 5
- ZDQWESQEGGJUCH-UHFFFAOYSA-N Diisopropyl adipate Chemical compound CC(C)OC(=O)CCCCC(=O)OC(C)C ZDQWESQEGGJUCH-UHFFFAOYSA-N 0.000 claims description 5
- 239000004593 Epoxy Substances 0.000 claims description 5
- 229920002125 Sokalan® Polymers 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 5
- 239000005543 nano-size silicon particle Substances 0.000 claims description 5
- 239000012188 paraffin wax Substances 0.000 claims description 5
- 229920002401 polyacrylamide Polymers 0.000 claims description 5
- 239000004584 polyacrylic acid Substances 0.000 claims description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 5
- 238000004062 sedimentation Methods 0.000 claims description 5
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 5
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 5
- 159000000000 sodium salts Chemical class 0.000 claims description 5
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- KOEFSMLBFZGZLD-UHFFFAOYSA-L [bis(2-ethylhexoxy)-oxidophosphaniumyl] dihydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] phosphate ethane-1,2-diolate titanium(4+) Chemical compound [Ti+4].[O-]CC[O-].CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)(O)=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP([O-])([O-])=O KOEFSMLBFZGZLD-UHFFFAOYSA-L 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 abstract description 5
- 230000002401 inhibitory effect Effects 0.000 abstract description 3
- 239000007921 spray Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000005477 standard model Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aging-resistant metal anti-rust paint and preparation method thereof, be made up of pulping raw material and paint raw material, the paint film that rust-inhibiting paint of the present invention is formed, have that hardness is high, damage resistant, strong adhesion, salt spray resistance, salt water resistance, acid and alkali-resistance, water-fast, oil resistant, reusable at old coating surface, paint film can not be caused to damage, superpower paint film flexibility etc.The general paint film life-span can reach 8-10.
Description
Technical field
The present invention relates to a kind of metallic anti-rust paint, specifically a kind of aging-resistant metal anti-rust paint.
Background technology
Various mechanical means appearance all needs coating layer of metal paint, increases attractive in appearance on the one hand, on the other hand dust-proof rust resistance and corrosion resistance; Rust-inhibiting paint of the prior art, because of containing a large amount of volatile organic solvent, produces volatile gases poisonous, harmful in a large number, polluted air and infringement human health.Ubiquity weather resistance is not good, easily comes off, inadaptable complicated, severe environment.
Summary of the invention
The invention provides a kind of aging-resistant metal anti-rust paint and preparation method thereof, there is good mechanical stability, snappiness and surface hardness, good weatherability.
Technical scheme of the present invention is:
A kind of aging-resistant metal anti-rust paint, is characterized in that being made up of the feed composition of following component weight part:
Pulping raw material:
Aluminium powder 3-8, propylene glycol phenylate 1-3,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 3-5, anti-sedimentation agent 3300S1-2, flow agent BYK-3371-2, polyacrylic acid sodium salt SN-50001-2, polyvinylpyrrolidone 3-5, nano silicon 10-15, modified nano montmorillonite powder 5-10, modified soluble nano silicone colloidal sol 5-10;
Paint raw material:
Sodium hexametaphosphate 99 10-15, epoxy emulsion 10-15, myo-Inositol hexaphosphate 20-25, polyacrylamide 3-5, paraffin wax emulsions 5-10, propylene glycol 50-60, paregal O 3-5, dispersing agent MF 1-3, Wickenol 116 5-8,2-amino-2-methyl-1-propanol 5-8;
Modified nano montmorillonite powder is prepared by the following method:
(1), montmorillonite powder add (0.8 ~ 1.2) g/L potassium permanganate solution soak 2-3 hour, pulls out, be washed to neutrality, then the sodium radio-phosphate,P-32 solution putting into 2-5% soaks, stirring reaction 3-4 hour at 60-80 DEG C;
(2) in soak solution, add the 3-4% sodium laurylsulfate, 1-2% Di(dioctylpyrophosphato) ethylene titanate, 2-3% vinyl three ('beta '-methoxy oxyethyl group) silane, the 20-25% ferrophosphorus powder that are equivalent to montmorillonite powder weight, high speed dispersion 4200-4500 rev/min, 20-30 minute;
(3) dry, pulverize, make ultrafine powder;
Modified soluble nano silicone colloidal sol is prepared by the following method:
Water-soluble nanoscale silica sol adds 4-5% nano-carbon powder, 3-5% ferric oxide, is mixed and heated to 50-60 DEG C, cools after 30-40 minute.
Described aging-resistant metal anti-rust paint, is characterized in that being made up of the feed composition of following component weight part:
Pulping raw material:
Aluminium powder 6, propylene glycol phenylate 3,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 5, anti-sedimentation agent 3300S2, flow agent BYK-3372, polyacrylic acid sodium salt SN-50002, polyvinylpyrrolidone 5, nano silicon 10, modified nano montmorillonite powder 0, modified soluble nano silicone colloidal sol 10;
Paint raw material:
Sodium hexametaphosphate 99 10, epoxy emulsion 15, myo-Inositol hexaphosphate 20, polyacrylamide 5, paraffin wax emulsions 10, propylene glycol 50, paregal O 5, dispersing agent MF 1, Wickenol 116 5,2-amino-2-methyl-1-propanol 5.
The preparation method of described aging-resistant metal anti-rust paint, is characterized in that comprising the following steps:
(1), slurrying: pulping raw material is poured into batching kettle mixing, then mixed pulping raw material is transported in high-speed dispersing kettle and carries out stirring, disperseing 50-60 minute, rotating speed 3200-3500 rev/min, slurrying component after dispersion is transported in sand mill carries out wet type sand milling, dispersion, obtain slurry, slurry mesh-of-grind is less than or equals 40 microns;
(2) paint: add paint raw material in obtained slurry, be then transported in high-speed dispersing kettle and carry out stirring, disperseing, after dispersion, being transported in sand mill of component carries out wet type sand milling, dispersion, obtains paint vehicle; Again with 3200-3600 rev/min of high speed dispersion 40-50min;
(3) obtained paint vehicle is transported to vibrating filter to carry out filtering and screening, fineness≤40um, then the product after filtration is packed, warehouse-in.
The paint film that rust-inhibiting paint of the present invention is formed, has that hardness is high, damage resistant, strong adhesion, and salt spray resistance, salt water resistance, acid and alkali-resistance, water-fast, oil resistant are reusable at old coating surface, paint film can not be caused to damage, superpower paint film flexibility etc.The general paint film life-span can reach 8-10.
Embodiment
Aging-resistant metal anti-rust paint, be made up of the feed composition of following component weight part (kilogram):
Pulping raw material:
Aluminium powder 6, propylene glycol phenylate 3,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 5, anti-sedimentation agent 3300S2, flow agent BYK-3372, polyacrylic acid sodium salt SN-50002, polyvinylpyrrolidone 5, nano silicon 10, modified nano montmorillonite powder 0, modified soluble nano silicone colloidal sol 10;
Paint raw material:
Sodium hexametaphosphate 99 10, epoxy emulsion 15, myo-Inositol hexaphosphate 20, polyacrylamide 5, paraffin wax emulsions 10, propylene glycol 50, paregal O 5, dispersing agent MF 1, Wickenol 116 5,2-amino-2-methyl-1-propanol 5.
Modified nano montmorillonite powder is prepared by the following method:
(1), montmorillonite powder adds 0.8g/L potassium permanganate solution and soaks 2 hours, pulls out, is washed to neutrality, then the sodium radio-phosphate,P-32 solution putting into 5% soaks, stirring reaction 4 hours at 60-70 DEG C;
(2) in soak solution, add 3% sodium laurylsulfate, 2% Di(dioctylpyrophosphato) ethylene titanate, 2% vinyl three ('beta '-methoxy oxyethyl group) silane, the 20% ferrophosphorus powder that are equivalent to montmorillonite powder weight, high speed dispersion 4200-4500 rev/min, 20-30 minute;
(3) dry, pulverize, make ultrafine powder;
Modified soluble nano silicone colloidal sol is prepared by the following method:
Water-soluble nanoscale silica sol adds 5% nano-carbon powder, 3% ferric oxide, and mix and blend, is heated to 50-60 DEG C, cools after 30-40 minute.
The preparation method of aging-resistant metal anti-rust paint:
(1), slurrying: pulping raw material is poured into batching kettle mixing, then mixed pulping raw material is transported in high-speed dispersing kettle and carries out stirring, disperseing 50-60 minute, rotating speed 3200-3500 rev/min, slurrying component after dispersion is transported in sand mill carries out wet type sand milling, dispersion, obtain slurry, slurry mesh-of-grind is less than or equals 40 microns;
(2) paint: add paint raw material in obtained slurry, be then transported in high-speed dispersing kettle and carry out stirring, disperseing, after dispersion, being transported in sand mill of component carries out wet type sand milling, dispersion, obtains paint vehicle; Again with 3200-3600 rev/min of high speed dispersion 40-50min;
(3) obtained paint vehicle is transported to vibrating filter to carry out filtering and screening, fineness≤40um, then the product after filtration is packed, warehouse-in.
Metallic anti-rust paint performance index of the present invention:
1, paint film color and outward appearance: flat smooth, color conformance with standard model and aberration scope
2, viscosity (23 ± 1 DEG C of coating-4 viscosity meters, S): 80-120
3, fineness≤50
4, time of drying (25 DEG C): surface drying 25-30min, 48h is done solid work
5, snappiness mm≤2
6, hardness >=2H
7, high temperature resistant (130 DEG C) >=450h
8, shock-resistance 50
9, salt spray resistance (120h level) >=2
10, water tolerance (29 ± 1 DEG C of 240h): non-foaming, does not come off
11, oil resistant (90# gasoline, 56h): non-foaming, does not come off
12, alkali resistance (GB/T9755-2001): by 48 hours
13, artificial weathering ageing resistance (GB/T9755-2001): by 1000 hours.
Claims (3)
1. an aging-resistant metal anti-rust paint, is characterized in that being made up of the feed composition of following component weight part:
Pulping raw material:
Aluminium powder 3-8, propylene glycol phenylate 1-3,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 3-5, anti-sedimentation agent 3300S1-2, flow agent BYK-3371-2, polyacrylic acid sodium salt SN-50001-2, polyvinylpyrrolidone 3-5, nano silicon 10-15, modified nano montmorillonite powder 5-10, modified soluble nano silicone colloidal sol 5-10;
Paint raw material:
Sodium hexametaphosphate 99 10-15, epoxy emulsion 10-15, myo-Inositol hexaphosphate 20-25, polyacrylamide 3-5, paraffin wax emulsions 5-10, propylene glycol 50-60, paregal O 3-5, dispersing agent MF 1-3, Wickenol 116 5-8,2-amino-2-methyl-1-propanol 5-8;
Modified nano montmorillonite powder is prepared by the following method:
(1), montmorillonite powder add 0.8 ~ 1.2g/L potassium permanganate solution soak 2-3 hour, pulls out, be washed to neutrality, then the sodium radio-phosphate,P-32 solution putting into 2-5% soaks, stirring reaction 3-4 hour at 60-80 DEG C;
(2) in soak solution, add the 3-4% sodium laurylsulfate, 1-2% Di(dioctylpyrophosphato) ethylene titanate, 2-3% vinyl three ('beta '-methoxy oxyethyl group) silane, the 20-25% ferrophosphorus powder that are equivalent to montmorillonite powder weight, high speed dispersion 4200-4500 rev/min, 20-30 minute;
(3) dry, pulverize, make ultrafine powder;
Modified soluble nano silicone colloidal sol is prepared by the following method:
Water-soluble nanoscale silica sol adds 4-5% nano-carbon powder, 3-5% ferric oxide, is mixed and heated to 50-60 DEG C, cools after 30-40 minute.
2. aging-resistant metal anti-rust paint according to claim 1, is characterized in that being made up of the feed composition of following component weight part:
Pulping raw material:
Aluminium powder 6, propylene glycol phenylate 3,2,2,4-trimethylammonium 1,3-pentanediol mono isobutyrate 5, anti-sedimentation agent 3300S2, flow agent BYK-3372, polyacrylic acid sodium salt SN-50002, polyvinylpyrrolidone 5, nano silicon 10, modified nano montmorillonite powder 0, modified soluble nano silicone colloidal sol 10;
Paint raw material:
Sodium hexametaphosphate 99 10, epoxy emulsion 15, myo-Inositol hexaphosphate 20, polyacrylamide 5, paraffin wax emulsions 10, propylene glycol 50, paregal O 5, dispersing agent MF 1, Wickenol 116 5,2-amino-2-methyl-1-propanol 5.
3. the preparation method of aging-resistant metal anti-rust paint according to claim 1, is characterized in that comprising the following steps:
(1), slurrying: pulping raw material is poured into batching kettle mixing, then mixed pulping raw material is transported in high-speed dispersing kettle and carries out stirring, disperseing 50-60 minute, rotating speed 3200-3500 rev/min, pulping raw material after dispersion is transported in sand mill and carries out wet type sand milling, dispersion, obtain slurry, slurry mesh-of-grind is less than or equals 40 microns;
(2) paint: add paint raw material in obtained slurry, be then transported in high-speed dispersing kettle and carry out stirring, disperseing, the component after dispersion is transported in sand mill carries out wet type sand milling, dispersion, obtains paint vehicle; Again with 3200-3600 rev/min of high speed dispersion 40-50min;
(3) obtained paint vehicle is transported to vibrating filter to carry out filtering and screening, fineness≤40 μm, then the product after filtration is packed, warehouse-in.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201210340770.1A CN102888167B (en) | 2012-09-15 | 2012-09-15 | A kind of aging-resistant metal anti-rust paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210340770.1A CN102888167B (en) | 2012-09-15 | 2012-09-15 | A kind of aging-resistant metal anti-rust paint and preparation method thereof |
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| CN102888167A CN102888167A (en) | 2013-01-23 |
| CN102888167B true CN102888167B (en) | 2016-03-23 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103254790A (en) * | 2013-04-17 | 2013-08-21 | 马鞍山拓锐金属表面技术有限公司 | Anti-rust oil employing propanediol butyl ether as base oil and preparation method thereof |
| CN103980771B (en) * | 2014-06-10 | 2016-03-16 | 马鞍山创宁新材料科技有限公司 | Water base functional sound-absorbing coating of a kind of nano modification and preparation method thereof |
| CN108129924A (en) * | 2018-01-02 | 2018-06-08 | 马鞍山佳夫尼电气科技有限公司 | A kind of anti-oxidant antirust paint for power equipment |
| CN111036343B (en) * | 2019-12-18 | 2021-06-22 | 长沙一力涂料科技有限公司 | Preparation method of antirust paint |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101326308A (en) * | 2005-12-15 | 2008-12-17 | 日本帕卡濑精株式会社 | Surface treatment for metal materials, surface treatment process, and surface- treated metal materials |
| CN101481553A (en) * | 2008-11-06 | 2009-07-15 | 常州市纳罗可涂料有限公司 | Normal temperature cured self-assembly composite nano oxide anti-corrosive paint |
| CN102485805A (en) * | 2010-12-02 | 2012-06-06 | 广东高科达科技实业有限公司 | Method for preparing modified nano montmorillonite |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5817177A (en) * | 1981-07-23 | 1983-02-01 | Dainippon Toryo Co Ltd | Coating composition for power transmission pylon |
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2012
- 2012-09-15 CN CN201210340770.1A patent/CN102888167B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101326308A (en) * | 2005-12-15 | 2008-12-17 | 日本帕卡濑精株式会社 | Surface treatment for metal materials, surface treatment process, and surface- treated metal materials |
| CN101481553A (en) * | 2008-11-06 | 2009-07-15 | 常州市纳罗可涂料有限公司 | Normal temperature cured self-assembly composite nano oxide anti-corrosive paint |
| CN102485805A (en) * | 2010-12-02 | 2012-06-06 | 广东高科达科技实业有限公司 | Method for preparing modified nano montmorillonite |
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