CN113443832A - Rock plate with mutton tallow jade touch feeling and preparation method thereof - Google Patents
Rock plate with mutton tallow jade touch feeling and preparation method thereof Download PDFInfo
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- CN113443832A CN113443832A CN202111023980.3A CN202111023980A CN113443832A CN 113443832 A CN113443832 A CN 113443832A CN 202111023980 A CN202111023980 A CN 202111023980A CN 113443832 A CN113443832 A CN 113443832A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3436—Alkaline earth metal silicates, e.g. barium silicate
- C04B2235/3454—Calcium silicates, e.g. wollastonite
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5276—Whiskers, spindles, needles or pins
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- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
Abstract
The invention belongs to the technical field of rock plates, and particularly discloses a rock plate with a mutton tallow jade touch feeling, which comprises a blank layer and a glaze layer from bottom to top, wherein the glaze layer is formed by applying mutton tallow jade glaze on the blank layer and sintering; the mutton tallow jade glaze is prepared from the following raw materials in parts by weight: 28-40 parts of potassium-containing mineral, 20-30 parts of kaolin, 15-20 parts of quartz sand, 6-11 parts of modified aluminum borate whisker, 4-8 parts of spodumene, 3-7 parts of lubricant and 1-4 parts of calcium silicate. The rock plate disclosed by the invention has oily and fine touch feeling, has the touch feeling similar to that of mutton tallow jade, and has a good wear-resisting effect. Under the formula system taking the potassium-containing mineral and the kaolin as main materials, the rock plate which is oily and fine in touch and has touch similar to that of the suet jade can be obtained by adding the lubricant.
Description
Technical Field
The invention relates to the technical field of rock plates, in particular to a rock plate with a mutton tallow jade touch feeling and a preparation method thereof.
Background
With the integration of building materials and home furnishing, the rock plate becomes a new material of a decorative panel of kitchens and bathrooms, and replaces partial materials such as metal, plastic and the like with the special corrosion resistance, durability and easy cleaning property. With the development of society, people have pursued not only the performance but also the touch of the rock plate.
CN108530022A discloses a mutton tallow jade white porcelain usable for naked fire and a preparation method thereof, the mutton tallow jade white porcelain comprises a mutton tallow jade white porcelain body and mutton tallow jade white porcelain glaze arranged outside the white porcelain body, and the mutton tallow jade white porcelain glaze comprises the following components: 45-50 parts of transparent glaze, 15-20 parts of calcined spodumene powder, 15-20 parts of quartz, 5-10 parts of nano alumina, 1-5 parts of germanized kaolin, 1-5 parts of Longyan kaolin, 1-5 parts of calcium silicate and 1-5 parts of barium carbonate. The prepared material has good heat resistance, shock resistance and hardness. The mutton tallow jade white porcelain can be used on open fire, but the wear resistance of the mutton tallow jade white porcelain is insufficient due to excessive glass phases.
Disclosure of Invention
The rock plate has oily and fine touch feeling, has the touch feeling similar to that of the mutton tallow jade, and has a good wear-resisting effect.
The invention adopts the following technical scheme for solving the technical problems:
a rock plate with a mutton tallow jade touch feeling comprises a blank layer and a glaze layer from bottom to top, wherein the glaze layer is formed by applying mutton tallow jade glaze on the blank layer and sintering;
the mutton tallow jade glaze is prepared from the following raw materials in parts by weight: 28-40 parts of potassium-containing mineral, 20-30 parts of kaolin, 15-20 parts of quartz sand, 6-11 parts of modified aluminum borate whisker, 4-8 parts of spodumene, 3-7 parts of lubricant and 1-4 parts of calcium silicate.
The inventor of the invention finds that under the formula system taking the potassium-containing mineral and the kaolin as the main materials, the rock plate which is oily and fine in touch and has the touch similar to that of the suet jade can be obtained by adding the lubricant.
As a preferred scheme, the mutton tallow jade glaze is prepared from the following raw materials in parts by weight: 28-35 parts of potassium-containing mineral, 20-28 parts of kaolin, 15-18 parts of quartz sand, 8-11 parts of modified aluminum borate whisker, 5-8 parts of spodumene, 4-7 parts of lubricant and 1-3 parts of calcium silicate.
As a preferred scheme, the mutton tallow jade glaze is prepared from the following raw materials in parts by weight: 33 parts of potassium-containing mineral, 26 parts of kaolin, 16 parts of quartz sand, 10 parts of modified aluminum borate whisker, 7 parts of spodumene, 6 parts of lubricant and 2 parts of calcium silicate.
Preferably, the potassium-containing mineral is prepared from illite, potash feldspar and muscovite in a weight ratio of 2-8: 1-5: 1 to 4.
The wear-resisting property can be improved to a certain extent by adopting the potassium-containing mineral, and compared with the single potassium feldspar, the wear-resisting property can be improved more obviously.
Preferably, the potassium-containing mineral is prepared from illite, potash feldspar and muscovite in a weight ratio of 5: 3: 2.
As a preferred scheme, the preparation method of the modified aluminum borate whisker comprises the following steps:
s1, adding 1-4 parts by weight of sodium oxalate, 1-3 parts by weight of sodium lignosulfonate and 2-5 parts by weight of glycerol into 20-40 parts by weight of deionized water to prepare a mixed solution, adding 8-15 parts by weight of aluminum borate whisker into the mixed solution, uniformly stirring at a rotating speed of 300-1000 rpm, adding 0.1-0.4 part by weight of triethanolamine, and uniformly stirring to obtain an aluminum borate whisker mixed solution;
s2, adding 0.8-2 parts by weight of phosphoric acid, 0.5-2 parts by weight of acetic acid and 0.2-0.6 part by weight of bis (dioctyloxypyrophosphate) ethylene titanate into 20-40 parts by weight of deionized water, uniformly mixing to prepare a modified solution, adding 2-6 parts by weight of white carbon black into the modified solution, uniformly stirring, washing with deionized water, and drying to constant weight to obtain modified white carbon black;
s3, adding 1-4 parts by weight of modified white carbon black into 10-40 parts by weight of aluminum borate whisker mixed solution, carrying out ultrasonic treatment for 10-35 min at 300-800W, adding 0.5-2 parts by weight of stearic acid, stirring uniformly at 70-85 ℃, filtering, and drying to obtain the modified aluminum borate whisker.
On the one hand, the aluminum borate whisker is modified, so that the touch feeling of the rock plate is not influenced, if the aluminum borate whisker is adopted, the aluminum borate whisker has certain influence on the touch feeling of the rock plate, and the modified aluminum borate whisker does not influence the touch feeling.
On the other hand, the aluminum borate whisker is modified and added into the rock plate formula system, so that the wear resistance can be remarkably improved, and the inventor finds that the modified aluminum borate whisker prepared by adopting the modified white carbon black can remarkably improve the wear resistance compared with other substances, namely, the modified aluminum borate whisker prepared by adopting the preparation method disclosed by the invention can remarkably improve the wear resistance compared with the modified aluminum borate whisker prepared by adopting other methods and added into the rock plate formula.
As a preferable scheme, the lubricant is prepared by mixing calcium fluoride, magnesium trifluoromethanesulfonate and hexagonal boron nitride according to a weight ratio of 1: 0.2-2: 0.2-2.
The inventor of the invention finds that the adoption of the ternary lubricant consisting of calcium fluoride, magnesium trifluoromethanesulfonate and hexagonal boron nitride can enable the rock plate to have oily and fine touch, so that the rock plate has touch similar to that of suet jade.
As a preferable scheme, the lubricant is prepared by mixing calcium fluoride, magnesium trifluoromethanesulfonate and hexagonal boron nitride according to a weight ratio of 1: 0.5: 1.5.
As a preferred scheme, the blank layer is prepared by the following raw materials in parts by weight through ball milling, mixing, pressing, sintering and edge grinding: 30-40 parts of potassium feldspar, 20-30 parts of kaolin, 15-25 parts of quartz sand, 10-15 parts of aluminum borate whisker, 4-8 parts of spodumene and 2-5 parts of calcium silicate.
As a preferred scheme, the blank layer is prepared by the following raw materials in parts by weight through ball milling, mixing, pressing, sintering and edge grinding: 36 parts of potassium feldspar, 24 parts of kaolin, 18 parts of quartz sand, 12 parts of aluminum borate whisker, 6 parts of spodumene and 4 parts of calcium silicate.
The invention also provides the rock plate with the mutton tallow jade touch feeling and the preparation method thereof, and the preparation method comprises the following steps:
s11, adding the raw materials for preparing the green body layer into a ball mill for ball millingUniformly sieving the mixture by a 100-400-mesh sieve, drying the mixture by using 3000-7000 tons/m2Pressing the blank to a thickness of 5-20 mm to obtain a blank, and sintering the blank at 1250-1290 ℃ for 40-80 min to obtain a blank layer;
s12, applying a sheepskin jade glaze material on the blank layer, wherein the glazing amount is 150-300 g/m2And sintering at 1250-1290 ℃ for 60-100 min to obtain the rock plate with the mutton tallow jade touch feeling.
The invention has the beneficial effects that: the rock plate disclosed by the invention has oily and fine touch feeling, has the touch feeling similar to that of mutton tallow jade, and has a good wear-resisting effect.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are a part of the embodiments of the present invention, but not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the present invention, the parts are all parts by weight unless otherwise specified.
Example 1
The utility model provides a rock plate with mutton tallow jade sense of touch, from supreme body layer, glazed layer including down, glazed layer forms through applying mutton tallow jade frit through sintering on the body layer.
The mutton tallow jade glaze is prepared from the following raw materials in parts by weight: 33 parts of potassium-containing mineral, 26 parts of kaolin, 16 parts of quartz sand, 10 parts of modified aluminum borate whisker, 7 parts of spodumene, 6 parts of lubricant and 2 parts of calcium silicate.
Under the formula system taking the potassium-containing mineral and the kaolin as main materials, the rock plate which is oily and fine in touch and has touch similar to that of the suet jade can be obtained by adding the lubricant.
The potassium-containing mineral is prepared from illite, potash feldspar and muscovite in a weight ratio of 5: 3: 2.
The wear-resisting property can be improved to a certain extent by adopting the potassium-containing mineral, and compared with the single potassium feldspar, the wear-resisting property can be improved more obviously.
The preparation method of the modified aluminum borate whisker comprises the following steps:
s1, adding 2 parts by weight of sodium oxalate, 1.5 parts by weight of sodium lignosulfonate and 2.5 parts by weight of glycerol into 33.7 parts by weight of deionized water to prepare a mixed solution, adding 10 parts by weight of aluminum borate whisker into the mixed solution, uniformly stirring at the rotating speed of 500rpm, adding 0.3 part by weight of triethanolamine, and uniformly stirring to obtain an aluminum borate whisker mixed solution;
s2, adding 1.5 parts by weight of phosphoric acid, 1.2 parts by weight of acetic acid and 0.3 part by weight of bis (dioctyloxy pyrophosphate) ethylene titanate into 32 parts by weight of deionized water, uniformly mixing to prepare a modified solution, adding 5 parts by weight of white carbon black into the modified solution, uniformly stirring, washing with deionized water, and drying to constant weight to obtain modified white carbon black;
s3, adding 3 parts by weight of modified white carbon black into 15 parts by weight of aluminum borate whisker mixed solution, carrying out ultrasonic treatment for 25min at 500W, adding 0.6 part by weight of stearic acid, stirring uniformly at 80 ℃, filtering, and drying to obtain the modified aluminum borate whisker.
The aluminum borate whisker is modified, so that the touch feeling of the rock plate is not influenced, if the aluminum borate whisker is adopted, the aluminum borate whisker has certain influence on the touch feeling of the rock plate, and the modified aluminum borate whisker does not influence the touch feeling. The modified aluminum borate whisker prepared by adopting the modified white carbon black can obviously improve the wear resistance compared with other substances, namely, the modified aluminum borate whisker prepared by adopting the preparation method disclosed by the invention can obviously improve the wear resistance compared with the modified aluminum borate whisker prepared by other methods when being added into the rock plate formula.
The lubricant is prepared from calcium fluoride, magnesium trifluoromethanesulfonate and hexagonal boron nitride in a weight ratio of 1: 0.5: 1.5.
By adopting the ternary lubricant consisting of calcium fluoride, magnesium trifluoromethanesulfonate and hexagonal boron nitride, the rock plate has oily and fine touch feeling, and the touch feeling is similar to that of mutton tallow jade.
The green body layer is prepared by ball-milling, mixing, pressing, sintering and edging the following raw materials in parts by weight: 36 parts of potassium feldspar, 24 parts of kaolin, 18 parts of quartz sand, 12 parts of aluminum borate whisker, 6 parts of spodumene and 4 parts of calcium silicate.
The rock plate with the mutton tallow jade touch feeling and the preparation method thereof comprise the following steps:
s11, adding the raw materials for preparing the blank layer into a ball mill, ball-milling uniformly, sieving with a 200-mesh sieve, drying, and using 5000 tons/m2Pressing to a thickness of 10mm to obtain a blank, and sintering the blank at 1280 ℃ for 60min to obtain a blank layer;
s12, applying the mutton tallow jade glaze material on the green body layer, wherein the glazing amount is 250g/m2And sintering at 1280 deg.C for 80min to obtain the rock plate with mutton tallow jade touch feeling.
Example 2
The utility model provides a rock plate with mutton tallow jade sense of touch, from supreme body layer, glazed layer including down, glazed layer forms through applying mutton tallow jade frit through sintering on the body layer.
The mutton tallow jade glaze is prepared from the following raw materials in parts by weight: 34 parts of potassium-containing mineral, 28 parts of kaolin, 20 parts of quartz sand, 6 parts of modified aluminum borate whisker, 8 parts of spodumene, 3 parts of lubricant and 1 part of calcium silicate.
The potassium-containing mineral is prepared from illite, potash feldspar and muscovite in a weight ratio of 2: 2: 1.
The preparation method of the modified aluminum borate whisker comprises the following steps:
s1, adding 3 parts by weight of sodium oxalate, 2 parts by weight of sodium lignosulfonate and 4 parts by weight of glycerol into 30.8 parts by weight of deionized water to prepare a mixed solution, adding 10 parts by weight of aluminum borate whisker into the mixed solution, uniformly stirring at the rotating speed of 800rpm, adding 0.2 part by weight of triethanolamine, and uniformly stirring to obtain an aluminum borate whisker mixed solution;
s2, adding 1 part by weight of phosphoric acid, 0.8 part by weight of acetic acid and 0.4 part by weight of bis (dioctyloxy pyrophosphate) ethylene titanate into 33.8 parts by weight of deionized water, uniformly mixing to prepare a modified solution, adding 4 parts by weight of white carbon black into the modified solution, uniformly stirring, washing with deionized water, and drying to constant weight to obtain modified white carbon black;
s3, adding 3 parts by weight of modified white carbon black into 15 parts by weight of aluminum borate whisker mixed solution, carrying out ultrasonic treatment for 20min at 500W, adding 1 part by weight of stearic acid, stirring uniformly at 80 ℃, filtering, and drying to obtain the modified aluminum borate whisker.
The lubricant is prepared from calcium fluoride, magnesium trifluoromethanesulfonate and hexagonal boron nitride in a weight ratio of 1: 0.8: 1.2.
The green body layer is prepared by ball-milling, mixing, pressing, sintering and edging the following raw materials in parts by weight: 36 parts of potassium feldspar, 24 parts of kaolin, 18 parts of quartz sand, 12 parts of aluminum borate whisker, 6 parts of spodumene and 4 parts of calcium silicate.
The rock plate with the mutton tallow jade touch feeling and the preparation method thereof comprise the following steps:
s11, adding the raw materials for preparing the blank layer into a ball mill, ball-milling uniformly, sieving with a 200-mesh sieve, drying, and using 5000 tons/m2Pressing to a thickness of 10mm to obtain a blank, and sintering the blank at 1280 ℃ for 60min to obtain a blank layer;
s12, applying the mutton tallow jade glaze material on the green body layer, wherein the glazing amount is 250g/m2And sintering at 1280 deg.C for 80min to obtain the rock plate with mutton tallow jade touch feeling.
Example 3
The utility model provides a rock plate with mutton tallow jade sense of touch, from supreme body layer, glazed layer including down, glazed layer forms through applying mutton tallow jade frit through sintering on the body layer.
The mutton tallow jade glaze is prepared from the following raw materials in parts by weight: 31 parts of potassium-containing mineral, 30 parts of kaolin, 15 parts of quartz sand, 9 parts of modified aluminum borate whisker, 6 parts of spodumene, 5 parts of lubricant and 4 parts of calcium silicate.
The potassium-containing mineral is prepared from illite, potash feldspar and muscovite in a weight ratio of 6: 3: 1.
The preparation method of the modified aluminum borate whisker comprises the following steps:
s1, adding 2 parts by weight of sodium oxalate, 1.5 parts by weight of sodium lignosulfonate and 2.5 parts by weight of glycerol into 33.7 parts by weight of deionized water to prepare a mixed solution, adding 10 parts by weight of aluminum borate whisker into the mixed solution, uniformly stirring at the rotating speed of 500rpm, adding 0.3 part by weight of triethanolamine, and uniformly stirring to obtain an aluminum borate whisker mixed solution;
s2, adding 1.5 parts by weight of phosphoric acid, 1.2 parts by weight of acetic acid and 0.3 part by weight of bis (dioctyloxy pyrophosphate) ethylene titanate into 32 parts by weight of deionized water, uniformly mixing to prepare a modified solution, adding 5 parts by weight of white carbon black into the modified solution, uniformly stirring, washing with deionized water, and drying to constant weight to obtain modified white carbon black;
s3, adding 3 parts by weight of modified white carbon black into 15 parts by weight of aluminum borate whisker mixed solution, carrying out ultrasonic treatment for 25min at 500W, adding 0.6 part by weight of stearic acid, stirring uniformly at 80 ℃, filtering, and drying to obtain the modified aluminum borate whisker.
The lubricant is prepared from calcium fluoride, magnesium trifluoromethanesulfonate and hexagonal boron nitride in a weight ratio of 1: 0.5: 1.5.
The green body layer is prepared by ball-milling, mixing, pressing, sintering and edging the following raw materials in parts by weight: 36 parts of potassium feldspar, 24 parts of kaolin, 18 parts of quartz sand, 12 parts of aluminum borate whisker, 6 parts of spodumene and 4 parts of calcium silicate.
The rock plate with the mutton tallow jade touch feeling and the preparation method thereof comprise the following steps:
s11, adding the raw materials for preparing the blank layer into a ball mill, ball-milling uniformly, sieving with a 200-mesh sieve, drying, and using 5000 tons/m2Pressing to a thickness of 10mm to obtain a blank, and sintering the blank at 1280 ℃ for 60min to obtain a blank layer;
s12, applying the mutton tallow jade glaze material on the green body layer, wherein the glazing amount is 250g/m2Sintering at 1280 deg.C for 80min to obtain the final productA tactile rock plate.
Comparative example 1
Comparative example 1 differs from example 1 in that comparative example 1 does not contain the lubricant, and the other things are the same.
Comparative example 2
Comparative example 2 differs from example 1 in that the lubricant employs calcium fluoride alone, and is otherwise the same.
Comparative example 3
Comparative example 3 differs from example 1 in that the potassium-containing mineral described in comparative example 3 is a single potassium feldspar, all other things being equal.
Comparative example 4
Comparative example 4 differs from example 1 in that comparative example 4 does not contain the modified aluminum borate whiskers, and the other things are the same.
Comparative example 5
Comparative example 5 differs from example 1 in that comparative example 5 uses aluminum borate whiskers in place of modified aluminum borate whiskers, all other things being equal.
Comparative example 6
Comparative example 6 is different from example 1 in that the modified aluminum borate whisker in comparative example 6 was prepared by a method different from that of example 1, and the other steps were the same.
In this comparative example, the aluminum borate whisker was not modified with modified white carbon black.
The preparation method of the modified aluminum borate whisker comprises the following steps:
s1, adding 2 parts by weight of sodium oxalate, 1.5 parts by weight of sodium lignosulfonate and 2.5 parts by weight of glycerol into 33.7 parts by weight of deionized water to prepare a mixed solution, adding 10 parts by weight of aluminum borate whisker into the mixed solution, uniformly stirring at the rotating speed of 500rpm, adding 0.3 part by weight of triethanolamine, and uniformly stirring to obtain an aluminum borate whisker mixed solution;
and S2, adding 0.6 part by weight of stearic acid into 15 parts by weight of aluminum borate whisker mixed solution, uniformly stirring at 80 ℃, filtering, and drying to obtain the modified aluminum borate whisker.
Comparative example 7
Comparative example 7 differs from example 1 in that the modified aluminum borate whiskers described in comparative example 7 were prepared by a method different from that of example 1, and the other steps were the same.
In the comparative example, titanium dioxide is used for replacing the modified white carbon black to modify the aluminum borate whisker.
The preparation method of the modified aluminum borate whisker comprises the following steps:
s1, adding 2 parts by weight of sodium oxalate, 1.5 parts by weight of sodium lignosulfonate and 2.5 parts by weight of glycerol into 33.7 parts by weight of deionized water to prepare a mixed solution, adding 10 parts by weight of aluminum borate whisker into the mixed solution, uniformly stirring at the rotating speed of 500rpm, adding 0.3 part by weight of triethanolamine, and uniformly stirring to obtain an aluminum borate whisker mixed solution;
s2, adding 3 parts by weight of titanium dioxide into 15 parts by weight of aluminum borate whisker mixed solution, carrying out ultrasonic treatment for 25min at 500W, adding 0.6 part by weight of stearic acid, stirring uniformly at 80 ℃, filtering, and drying to obtain the modified aluminum borate whisker.
To further demonstrate the effect of the present invention, the following test methods were provided:
1. the rock panels described in examples 1 to 3 and comparative examples 1 to 2, 5 were subjected to tactile evaluation, and the test results are shown in table 1.
TABLE 1 tactile feel test
As can be seen from table 1, the rock plate of the present invention has a smooth and fine touch and a jatropha-like touch, while the use of the ternary lubricant comprising calcium fluoride, magnesium trifluoromethanesulfonate, and hexagonal boron nitride as the lubricant enables the rock plate to have a smooth, fine, and jatropha-like touch as in comparative example 1 and comparative examples 1 and 2, while the use of the aluminum borate whisker instead of the modified aluminum borate whisker affects the touch of the rock plate and does not have a jatropha-like touch as in comparative example 1 and comparative example 5.
2. The glaze wear resistance is tested by the test method in GB/T3810.7-2016 (determination of glazed tile surface wear resistance), the wear value is tested at 6000 revolutions, and the test result is shown in Table 2.
Table 2 abrasion resistance test results
As can be seen from table 2, the rock panels according to the invention have good wear resistance.
Comparing example 1 with comparative example 3, it can be seen that the wear resistance can be improved more remarkably by using the potassium-containing mineral of the present invention than by using potassium feldspar alone.
Compared with the comparative examples 4 to 7, the modified aluminum borate whisker can obviously improve the wear resistance of the rock plate, and the modified aluminum borate whisker prepared by different modification methods has different improvements on the wear resistance of the rock plate.
In light of the foregoing description of preferred embodiments according to the invention, it is clear that many changes and modifications can be made by the person skilled in the art without departing from the scope of the invention. The technical scope of the present invention is not limited to the contents of the specification, and must be determined according to the scope of the claims.
Claims (10)
1. A rock plate with a mutton tallow jade touch feeling is characterized by comprising a blank layer and a glaze layer from bottom to top, wherein the glaze layer is formed by applying mutton tallow jade glaze on the blank layer and sintering;
the mutton tallow jade glaze is prepared from the following raw materials in parts by weight: 28-40 parts of potassium-containing mineral, 20-30 parts of kaolin, 15-20 parts of quartz sand, 6-11 parts of modified aluminum borate whisker, 4-8 parts of spodumene, 3-7 parts of lubricant and 1-4 parts of calcium silicate.
2. The rock plate with a sheepskin jade touch according to claim 1, wherein the sheepskin jade glaze is prepared from the following raw materials in parts by weight: 28-35 parts of potassium-containing mineral, 20-28 parts of kaolin, 15-18 parts of quartz sand, 8-11 parts of modified aluminum borate whisker, 5-8 parts of spodumene, 4-7 parts of lubricant and 1-3 parts of calcium silicate.
3. The rock plate with a sheepskin jade touch according to claim 1, wherein the sheepskin jade glaze is prepared from the following raw materials in parts by weight: 33 parts of potassium-containing mineral, 26 parts of kaolin, 16 parts of quartz sand, 10 parts of modified aluminum borate whisker, 7 parts of spodumene, 6 parts of lubricant and 2 parts of calcium silicate.
4. The rock plate with a mutton tallow jade feeling as claimed in claim 1, wherein the potassium-containing mineral is formed by mixing illite, potash feldspar and muscovite according to a weight ratio of 2-8: 1-5: 1 to 4.
5. The rock plate with a mutton tallow jade feeling as claimed in claim 1, wherein the potassium-containing mineral is composed of illite, potash feldspar, muscovite mica in a weight ratio of 5: 3: 2.
6. The rock plate with a sheepskin jade touch according to claim 1, wherein the modified aluminum borate whiskers are prepared by a method comprising:
s1, adding 1-4 parts by weight of sodium oxalate, 1-3 parts by weight of sodium lignosulfonate and 2-5 parts by weight of glycerol into 20-40 parts by weight of deionized water to prepare a mixed solution, adding 8-15 parts by weight of aluminum borate whisker into the mixed solution, uniformly stirring at a rotating speed of 300-1000 rpm, adding 0.1-0.4 part by weight of triethanolamine, and uniformly stirring to obtain an aluminum borate whisker mixed solution;
s2, adding 0.8-2 parts by weight of phosphoric acid, 0.5-2 parts by weight of acetic acid and 0.2-0.6 part by weight of bis (dioctyloxypyrophosphate) ethylene titanate into 20-40 parts by weight of deionized water, uniformly mixing to prepare a modified solution, adding 2-6 parts by weight of white carbon black into the modified solution, uniformly stirring, washing with deionized water, and drying to constant weight to obtain modified white carbon black;
s3, adding 1-4 parts by weight of modified white carbon black into 10-40 parts by weight of aluminum borate whisker mixed solution, carrying out ultrasonic treatment for 10-35 min at 300-800W, adding 0.5-2 parts by weight of stearic acid, stirring uniformly at 70-85 ℃, filtering, and drying to obtain the modified aluminum borate whisker.
7. The rock plate with a sheepskin jade feel according to claim 1, wherein said lubricant is comprised of calcium fluoride, magnesium triflate, hexagonal boron nitride in a weight ratio of 1: 0.2-2: 0.2-2.
8. The rock plate with a mutton tallow jade touch feeling as claimed in claim 1, wherein the green body layer is prepared by ball milling, mixing, pressing, sintering and edging the following raw materials in parts by weight: 30-40 parts of potassium feldspar, 20-30 parts of kaolin, 15-25 parts of quartz sand, 10-15 parts of aluminum borate whisker, 4-8 parts of spodumene and 2-5 parts of calcium silicate.
9. The rock plate with a mutton tallow jade touch feeling as claimed in claim 1, wherein the green body layer is prepared by ball milling, mixing, pressing, sintering and edging the following raw materials in parts by weight: 36 parts of potassium feldspar, 24 parts of kaolin, 18 parts of quartz sand, 12 parts of aluminum borate whisker, 6 parts of spodumene and 4 parts of calcium silicate.
10. A method for preparing a rock plate having a sheepskin jade touch, for preparing the rock plate having a sheepskin jade touch of any of claims 1-9, comprising the steps of:
s11, adding the raw materials for preparing the blank layer into a ball mill, uniformly ball-milling, sieving with a 100-400-mesh sieve, drying, and using 3000-7000 tons/m2Pressing the blank to a thickness of 5-20 mm to obtain a blank, and sintering the blank at 1250-1290 ℃ for 40-80 min to obtain a blank layer;
s12, applying a sheepskin jade glaze material on the blank layer, wherein the glazing amount is 150-300 g/m2And sintering at 1250-1290 ℃ for 60-100 min to obtain the rock plate with the mutton tallow jade touch feeling.
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