KR20030008145A - Functional ceramic product radiating negative ions and far infrared rays and manufacturing method of the same - Google Patents
Functional ceramic product radiating negative ions and far infrared rays and manufacturing method of the same Download PDFInfo
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- 239000000919 ceramic Substances 0.000 title claims abstract description 53
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 150000002500 ions Chemical class 0.000 title claims description 20
- 239000000843 powder Substances 0.000 claims abstract description 37
- 150000001450 anions Chemical class 0.000 claims abstract description 33
- 239000004927 clay Substances 0.000 claims abstract description 32
- 238000002156 mixing Methods 0.000 claims abstract description 16
- 239000011224 oxide ceramic Substances 0.000 claims abstract description 16
- 229910052574 oxide ceramic Inorganic materials 0.000 claims abstract description 16
- 238000001035 drying Methods 0.000 claims abstract description 8
- 238000005507 spraying Methods 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims description 25
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 20
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 19
- 229910021193 La 2 O 3 Inorganic materials 0.000 claims description 15
- 238000010304 firing Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 9
- 229910017493 Nd 2 O 3 Inorganic materials 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 5
- 238000000748 compression moulding Methods 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 2
- 238000005498 polishing Methods 0.000 abstract description 9
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 6
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 abstract 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 3
- 229910052681 coesite Inorganic materials 0.000 abstract 3
- 229910052593 corundum Inorganic materials 0.000 abstract 3
- 229910052906 cristobalite Inorganic materials 0.000 abstract 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 3
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 abstract 3
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 abstract 3
- 239000000377 silicon dioxide Substances 0.000 abstract 3
- 235000012239 silicon dioxide Nutrition 0.000 abstract 3
- 229910052682 stishovite Inorganic materials 0.000 abstract 3
- 229910052905 tridymite Inorganic materials 0.000 abstract 3
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 3
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 abstract 2
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 abstract 2
- 238000005245 sintering Methods 0.000 abstract 2
- 229910000421 cerium(III) oxide Inorganic materials 0.000 abstract 1
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- DRLFMBDRBRZALE-UHFFFAOYSA-N melatonin Chemical compound COC1=CC=C2NC=C(CCNC(C)=O)C2=C1 DRLFMBDRBRZALE-UHFFFAOYSA-N 0.000 abstract 1
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium oxide Inorganic materials [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 abstract 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 abstract 1
- 238000003825 pressing Methods 0.000 abstract 1
- FKTOIHSPIPYAPE-UHFFFAOYSA-N samarium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 abstract 1
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 abstract 1
- 239000000047 product Substances 0.000 description 28
- 230000009286 beneficial effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000036541 health Effects 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 235000015872 dietary supplement Nutrition 0.000 description 4
- 230000000144 pharmacologic effect Effects 0.000 description 4
- 230000001737 promoting effect Effects 0.000 description 3
- -1 far infrared Chemical class 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 210000000813 small intestine Anatomy 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N2005/0658—Radiation therapy using light characterised by the wavelength of light used
- A61N2005/0659—Radiation therapy using light characterised by the wavelength of light used infrared
- A61N2005/066—Radiation therapy using light characterised by the wavelength of light used infrared far infrared
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0097—Anion- and far-infrared-emitting materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Radiation-Therapy Devices (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Adornments (AREA)
Abstract
Description
본 발명은 음이온 및 원적외선을 방출하는 기능성 세라믹 제품 및 그 제조방법에 관한 것으로, 보다 구체적으로는 점토에 음이온 및 원적외선을 방출하는 산화물계 세라믹스 분말을 2%~40% 혼합하여 성형체를 만들고 그 성형체를 소성하거나 또는 유약처리 및 소성함으로써, 음이온 및 원적외선을 방출하게 하여 신체적으로 이롭고 예술적 신비감이 부여 되도록 하는 음이온 및 원적외선을 방출하는 기능성세라믹제품 및 그 제조방법에 관한 것이다.The present invention relates to a functional ceramic product that emits anions and far infrared rays, and a method of manufacturing the same. More specifically, to prepare a molded body by mixing 2% to 40% of oxide-based ceramic powders that emit anions and far infrared rays in clay, The present invention relates to a functional ceramic product that emits negative ions and far infrared rays by firing or glazing and firing, thereby releasing negative ions and far infrared rays to impart physically beneficial and artistic mystery.
19세기초에 F. W. Hershel과 A. Ampere에 의해 발견된 적외선은 근적외선, 중적외선 및 원적외선 등이 있다. CIE 국제조명용어집에 의하면, 근적외선, 중적외선 및 원적외선의 파장은 각각 0.75∼1.4㎛, 1.4∼3㎛, 3∼1000㎛이다. 원적외선의 열효과와 비열효과를 응용하여 원적외선을 여러 산업과 인간의 건강 증진에 활용하고 있다. 원적외선의 열효과는 페인트나 식품의 건조에 활용되고 있으며, 또한 원적외선의 비열효과는 보온, 숙면, 혈류 촉진, 피로 회복, 성장 촉진 등의 생체 활성화, 물의 개질(改質), 술의 숙성 촉진 등에 활용되고 있다.The infrared rays discovered by F. W. Hershel and A. Ampere in the early 19th century include near-infrared, mid-infrared and far-infrared. According to the CIE International Illuminating Glossary, the wavelengths of near-infrared, mid-infrared, and far-infrared are 0.75 to 1.4 mu m, 1.4 to 3 mu m, and 3 to 1000 mu m, respectively. Far-infrared ray is used for various industries and human health by applying the heat effect and non-heat effect of far-infrared ray. The thermal effect of far-infrared rays is used to dry paints and foods, and the specific heat effects of far-infrared rays are to activate the living body, such as keeping warm, sleeping, promoting blood flow, restoring fatigue, promoting growth, reforming water, and promoting aging of alcohol. It is utilized.
20세기 초부터 주로 독일, 러시아, 일본 및 미국 등에서 공기 이온이 생체에 미치는 영향에 관하여 연구가 시작되었다. 공기 음이온은 혈액 정화, 세포 활성화, 면역력 증가, 신경안정, 호흡기 및 장기 향상, 피로감 경감 등의 효과를 얻을 수 있다.From the beginning of the 20th century, research on the effects of air ions on living organisms began mainly in Germany, Russia, Japan, and the United States. Air negative ions can be effective in purifying blood, activating cells, increasing immunity, nerve stabilization, respiratory and organ improvement, and reducing fatigue.
종래의 세라믹 장신구(목걸이, 귀걸이, 팔찌, 반지, 머리핀, 휴대폰장신구, 등), 장식품 또는 건강용품은 원적외선과 음이온이 발생하지 않았기 때문에 신체적 효능은 없었다.Conventional ceramic ornaments (necklaces, earrings, bracelets, rings, hairpins, cell phone accessories, etc.), ornaments or health care products have no physical efficacy because no far infrared rays and negative ions are generated.
또한, 원적외선과 음이온이 발생하여도 그 발생량이 극히 적기 때문에 충분한 효과를 얻을 수 없다는 문제점이 있다.In addition, even when far-infrared rays and negative ions are generated, there is a problem in that sufficient effects cannot be obtained because the generation amount is extremely small.
따라서, 음이온, 원적외선 또는 동시에 음이온과 원적외선을 방출하는 장신구, 장식품 또는 건겅보조용품 등과 같은 기능성 세락믹 제품에 대한 연구가 지속적으로 이루어져 왔고, 그것에 대한 결과물이 본 발명자에 의해 얻어지게 되었다.Therefore, research on functional ceramic products such as anions, far infrared rays or simultaneously releasing ions, ornaments or dry aids that emits anions and far infrared rays has been continuously made, and the result thereof has been obtained by the present inventors.
따라서, 본 발명의 목적은 상기한 문제점을 해결하기 위해 안출된 것으로서, 사용자에게 신체적으로 유익한 효능을 얻을 수 있도록 한 음이온, 원적외선, 또는 동시에 음이온과 원적외선을 방출하는 음이온 및 원적외선을 방출하는 기능성 세라믹 제품 및 그 제조방법을 제공하는 데 있다.Accordingly, an object of the present invention has been made to solve the above problems, functional ceramic products that emit anion, far infrared, or anion and far infrared that emits anion and far infrared at the same time to obtain a physically beneficial effect to the user And to provide a method for producing the same.
본 발명의 다른 목적은 제품 외관을 아름답게하여 소장의 가치를 증대시킬 수 있도록 한 음이온 및 원적외선을 방출하는 기능성 세라믹제품 및 그 제조방법을 제공하는데 있다.It is another object of the present invention to provide a functional ceramic product that emits negative ions and far-infrared rays, which can enhance the value of the small intestine by beautifying the appearance of the product and a manufacturing method thereof.
본 발명의 또 다른 목적은 생체학적인 약리기능을 가지며, 제조를 용이하게 하여 생산성을 크게 향상시키고 생산비를 저렴하게 할 수 있도록 한 음이온 및 원적외선을 방출하는 기능성 세라믹제품 및 그 제조방법을 제공하는 데 있다.It is still another object of the present invention to provide a functional ceramic product having a biological pharmacological function, releasing anions and far infrared rays, which facilitates manufacturing, greatly improving productivity and lowers production costs, and a method of manufacturing the same. .
도 1은 본 발명에 따라 제조된 장신구의 일예를 도시한 사시도.1 is a perspective view showing an example of ornaments made in accordance with the present invention.
도 2는 제조공정을 도시한 순서도.2 is a flow chart showing a manufacturing process.
<도면의 주요 부분에 대한 부호의 설명><Explanation of symbols for the main parts of the drawings>
10 : 성형체10: molded body
상기와 같은 목적을 달성하기 위하여, 본 발명에 따른 음이온 및 원적외선을 방출하는 기능성 세라믹제품은 점토에 산화물계 세라믹스 분말을 혼합하여 압축성형하여 제조된 것이다.In order to achieve the above object, the functional ceramic product that emits anions and far infrared rays according to the present invention is manufactured by compression molding by mixing oxide ceramic powder in clay.
이때, 상기 점토와 세라믹스 분말의 혼합비는 점토 60% ~ 98%와 산화물계 세라믹스 분말 2% ~ 40%인 것을 특징으로 한다.At this time, the mixing ratio of the clay and the ceramic powder is characterized in that the clay 60% to 98% and the oxide-based ceramic powder 2% to 40%.
또한, 종류에 따라서, 상기 산화물계 세라믹스 분말은 Al2O3, SiO2, Fe2O3, La2O3및 Ce2O3등의 혼합으로 구성되거나, Al2O3, SiO2, Fe2O3, La2O3, CeO2, P2O5및 CaO 등의 혼합으로 구성되거나, 또는 Al2O3, SiO2, Fe2O3, La2O3, CeO2, Sm2O3, Gd2O3, P2O5, Nd2O3, AgO 및 NiO 등의 혼합으로 구성된다.In addition, depending on the type, the oxide-based ceramic powder is composed of a mixture of Al 2 O 3 , SiO 2 , Fe 2 O 3 , La 2 O 3 and Ce 2 O 3 , or Al 2 O 3 , SiO 2 , Fe Or a mixture of 2 O 3 , La 2 O 3 , CeO 2 , P 2 O 5, and CaO, or Al 2 O 3 , SiO 2 , Fe 2 O 3 , La 2 O 3 , CeO 2 , Sm 2 O 3 , Gd 2 O 3 , P 2 O 5 , Nd 2 O 3 , AgO and NiO and the like mixture.
또한, 본 발명에 따른 제조방법은 혼합기에 점토 60%~98%와 산화물계 세라믹스2%~40%를 넣고 혼합하는 단계; 상기 혼합물을 소정의 형상으로 압축성형하는 단계; 성형체를 볼밀에 넣어 20분~96시간 1차 연마하는 단계: 연마된 성형체를 소성로에 800℃~1800℃의 온도로 1차 소성하는 단계: 소성된 성형체를 볼밀에 넣어 10분~24시간 2차 연마하는 단계: 볼밀로 연마된 상기 성형체를 건조로에서 60℃~200℃의 온도로 건조하는 단계: 건조된 성형체를 30℃~60℃의 온도로 유지시켜 스프레이로 유약을 도포하는단계; 및 유약이 도포된 상기 성형체를 300℃~1300℃로 2차 소성하는 단계;를 포함한다.In addition, the manufacturing method according to the present invention comprises the steps of mixing 60% to 98% clay and 2% to 40% oxide-based ceramics in a mixer; Compressing the mixture into a predetermined shape; First step of grinding the molded body in a ball mill for 20 minutes to 96 hours: First firing of the polished molded body in a firing furnace at a temperature of 800 ° C to 1800 ° C: Secondly put the calcined molded body in a ball mill for 10 minutes to 24 hours Polishing: Drying the molded body ball-grind in a drying furnace at a temperature of 60 ℃ ~ 200 ℃: maintaining the dried molded body at a temperature of 30 ℃ ~ 60 ℃ applying a glaze with a spray; And secondary baking the molded article having the glaze applied thereto at 300 ° C to 1300 ° C.
이때, 상기 유약 도포단계에서, 상기 성형체의 표면이 고르게 처리될 때까지 유약을 건조하고 성형체를 30℃~60℃의 온도로 유지시켜 스프레이로 유약을 다시 도포하는 것을 여러번 반복할 수도 있다.At this time, in the glaze application step, the glaze may be dried until the surface of the molded body is evenly treated, and the molded body may be maintained at a temperature of 30 ° C. to 60 ° C. to repeatedly apply the glaze with a spray.
또한, 본 발명의 제조방법은 다양할 있는데, 첫째 점토에 산화물계 세라믹스 분말을 혼합하여 압축성형한 성형체를 소성, 연마 및 유약 처리하여 제조할 수도 있고, 점토에 산화물계 세라믹스 분말을 혼합하여 압축성형한 성형체를 소성처리하여 제조할 수도 있고, 점토를 압축성형 및 소성처리 한 성형체를 유약과 산화물계세라믹스 분말을 혼합한 혼합물로 코팅할 수도 있으며, 점토를 압축성형 및 소성처리 한 성형체에 산화물계 세라믹스 분말을 코팅한 후 소성하고 유약처리하여 소성할 수도 있다.In addition, the manufacturing method of the present invention may vary. First, the compacted molded body may be prepared by mixing oxide ceramic powder with clay, and then the compacted body may be manufactured by firing, polishing, and glazing. A molded article may be produced by calcining, the molded article obtained by compression molding and calcining clay may be coated with a mixture of glaze and oxide ceramic powder, and the oxide-based ceramics may be applied to the molded article obtained by compression molding and calcining clay. The powder may be coated, fired, glazed and fired.
본 발명은 음이온, 원적외선 또는 동시에 음이온과 원적외선을 방출하는 산화물계 세라믹스 분말과 점토를 혼합하여 압축성형한 성형체를 연마하여 소성하거나, 연마, 소성 및 유약처리 공정을 거쳐 세라믹 제품을 완성하는 것으로, 이렇게 제조한 세라믹 제품들로는 다양한 장신구, 장식품, 또는 건강보조용품 들이 있을 수 있다.The present invention is to produce a ceramic product by grinding the compacted molded body by mixing an anion, a far infrared ray, or an oxide-based ceramic powder that emits an anion and a far infrared ray at the same time and clay, or through a polishing, firing, and glazing process. Ceramic products manufactured may include a variety of jewelry, ornaments, or health care products.
이렇게 제조된 장신구, 장식품 또는 건강보조용품 등의 세라믹 제품은 혼합되는 산화물계 세라믹스 분말의 조성에 따라 음이온 또는 원적외선을 방출할 수도 있고, 음이온과 원적외선을 동시에 방출하게 할 수도 있다.Ceramic products such as jewelry, ornaments or health care products produced in this way may emit anion or far infrared rays, depending on the composition of the oxide-based ceramic powder to be mixed, and may also emit anion and far infrared at the same time.
즉, 음이온만을 방출하거나, 원적외선만을 방출하거나, 또는 음이온과 원적외선을 동시에 방출하는 장신구, 장식품 또는 건강보조용품은 필요에 따라 선택적으로 제조 될 수 있으며, 이는 점토에 첨가되는 산화물계 세라믹스 분말의 종류에 따라서 결정된다.That is, ornaments, ornaments or health supplements that emit only anions, emit only far infrared rays, or emit both anions and far infrared rays at the same time can be selectively produced as needed, which is dependent on the type of oxide-based ceramic powder added to the clay. Is determined.
음이온, 원적외선, 또는 동시에 음이온과 원적외선을 방출하는 산화물계 세라믹스 분말의 대표적인 화학적 성분이 표 1, 표 2, 표 3에 각각 기재되어 있다.Representative chemical constituents of an oxide-based ceramic powder that emits anions, far infrared rays, or simultaneously anions and far infrared rays are described in Tables 1, 2, and 3, respectively.
음이온을 방출하기 위해서는 Al2O3, SiO2, Fe2O3, La2O3및 Ce2O3등으로 구성된 산화물계 세라믹스 분말을 사용하며, 이들 산화물에 다른 산화물이나 원소를 첨가 할 수도 있다.In order to release anions, oxide ceramic powders composed of Al 2 O 3 , SiO 2 , Fe 2 O 3 , La 2 O 3, and Ce 2 O 3 are used, and other oxides or elements may be added to these oxides. .
원적외선을 방출하기 위해서는 Al2O3, SiO2, Fe2O3, La2O3, CeO2, P2O5및 CaO 등으로 구성된 산화물계 세라믹스 분말을 사용하며, 이들 산화물에 다른 산화물이나 원소를 첨가할 수도 있다.To emit far infrared rays, an oxide-based ceramic powder composed of Al 2 O 3 , SiO 2 , Fe 2 O 3 , La 2 O 3 , CeO 2 , P 2 O 5, and CaO is used. May be added.
또한, 음이온과 원적외선을 동시에 방출하기 위해서는 Al2O3, SiO2, Fe2O3, La2O3, CeO2, Sm2O3, Gd2O3, P2O5, Nd2O3, AgO 및 NiO 등으로 구성된 산화물계 세라믹스 분말을 사용하며, 이들 산화물에 다른 산화물이나 원소를 첨가할 수도 있다.In addition, in order to simultaneously release anions and far infrared rays, Al 2 O 3 , SiO 2 , Fe 2 O 3 , La 2 O 3 , CeO 2 , Sm 2 O 3 , Gd 2 O 3 , P 2 O 5 , Nd 2 O 3 Oxide-based ceramic powders composed of, AgO, NiO, or the like are used, and other oxides or elements may be added to these oxides.
[표 1]TABLE 1
[표 2]TABLE 2
[표 3]TABLE 3
본 발명에 따른 음이온과 원적외선을 방출하는 장신구, 장식품 또는 건강 보조용품은 도 1에 일예로 도시된 바와 같이, 점토에 산화물계 세라믹스 분말을 혼합하여 성형가공된 성형체(10)에 유약소성한 표면층을 형성한다. 이때, 표면층을 통해 성형체의 외부로 음이온, 원적외선, 또는 동시에 음이온과 원적외선이 발생되어 신체에 유익한 약리현상이 일어나게 된다.Ornaments, ornaments or health care accessories that emit anions and far infrared rays according to the present invention, as shown as an example in Figure 1, by mixing the oxide-based ceramic powder in clay to form a glazed surface layer on the molded body (10) Form. At this time, negative ions, far infrared rays, or negative ions and far infrared rays are generated to the outside of the molded body through the surface layer, which causes beneficial pharmacological phenomenon to the body.
또한, 필요에 따라서 점토로 분말야금하여 성형가공된 성형체 표면에 산화물계 세라믹스 분말을 코팅한 후 유약 처리하여 소성 할 수도 있고, 점토로 분말야금 하여 가공된 성형체 표면에 유약과 산화물계 세라믹스 분말을 혼합하여 소성하면 음이온과 원적외선, 음이온이나 원적외선이 발생되어 신체에 유익한 약리 현상이 일어나게 된다.In addition, if necessary, the powder metallurgy powder may be coated with an oxide ceramic powder on the surface of the molded product, and then glazed and calcined, or the glaze and the oxide ceramic powder may be mixed on the surface of the molded metal powder processed with clay. When calcination is carried out, negative ions and far infrared rays, negative ions or far infrared rays are generated, and beneficial pharmacological phenomenon occurs to the body.
즉, 사용한 산화물계 세라믹스 분말의 조성에 따라 음이온만 방출 될 수도 있고, 원적외선만 방출될 수도 있고, 또는 음이온과 원적외선이 동시에 방출 될 수도 있다.That is, depending on the composition of the oxide-based ceramic powder used, only the anion may be emitted, only the far infrared may be emitted, or the anion and the far infrared may be emitted simultaneously.
또한, 점토는 제품이나 장식품, 건강보조용품의 용도, 생산성, 및 특성에 따라 다양한 비율로 혼합하여 제조할 수 있다.In addition, clay may be prepared by mixing in various ratios according to the use, productivity, and properties of products or ornaments, health supplements.
본 발명의 주요 구성요소인 점토는 SiO2, Al2O3, Fe2O3, CaO, MgO, TiO, K2O, Na2O 등으로 구성되어 있으며 주성분은 SiO2, Al2O3이다. 점토의 구성비율은 용도에 따라 비율을 다르게 할 수도 있다.Clay, which is a main component of the present invention, is composed of SiO 2 , Al 2 O 3 , Fe 2 O 3 , CaO, MgO, TiO, K 2 O, Na 2 O, etc. The main component is SiO 2 , Al 2 O 3 . The composition of clay may vary in proportion to use.
상기 점토에 산화물계 세라믹스 분말을 혼합하여 본 발명에 따른 기능성 세라믹 제품을 제조하는 방법에 대하여 상세한 설명을 한다.It will be described in detail a method for producing a functional ceramic product according to the present invention by mixing the oxide-based ceramic powder in the clay.
혼합기(MIXER)에 점토 40% ~ 98%와 산화물계 세라믹스 분말을 2% ~ 40%을 투입하여 혼합하고, 성형기에서 상기 혼합물을 소정의 형상으로 압축성형한 후, 상기 성형체를 볼밀에 넣어 1차 연마한다. 상기 연마방법은 건식방법과 습식방법으로 나누며 크기, 용도, 정밀정도에 따라 시간을 조절하는데, 연마시간은 10분에서 96시간까지 다양하다.40% to 98% of clay and 2% to 40% of oxide-based ceramic powder are added to a mixer, and the mixture is compression molded into a predetermined shape in a molding machine, and then the molded body is put into a ball mill for the first time. Polish The polishing method is divided into a dry method and a wet method to adjust the time according to the size, use, and precision, and the polishing time varies from 10 minutes to 96 hours.
그 후에, 상기 성형물을 전기로, 가스로 또는 석유로 등의 로에서 800℃~1800℃의 온도로 1차 소성하고, 소성이 완료된 성형체를 볼밀에 넣어서 10분~24시간 동안 2차 연마한다. 연마가 완료된 성형체는 열풍건조기에 건조시켜 습기를 제거한 후, 30℃~60℃의 온도를 유지시켜 유약을 스프레이로 도포한다.Thereafter, the molded product is first calcined at a temperature of 800 ° C to 1800 ° C in a furnace such as an electric furnace, a gas furnace or a petroleum furnace, and secondly polished for 10 minutes to 24 hours by placing the completed molded body in a ball mill. The polished molded body is dried in a hot air dryer to remove moisture, and then maintained at a temperature of 30 ° C. to 60 ° C. to apply glaze with a spray.
유약처리공정을 거친 성형체는 300℃~1300℃의 온도로 2차 소성을 한다.After the glaze treatment, the molded product is subjected to secondary firing at a temperature of 300 ° C to 1300 ° C.
<실시예1>Example 1
점토 90%(구성비율:SiO246wt%, Al2O339wt%, Fe2O33wt%, CaO 4wt%, MgO 2wt%, TiO 1wt%, K2O 2wt%, Na2O 3wt%,)에 산화물계 세라믹스 분말 10%(구성비율:Al2O339.18wt%, SiO216.66wt%, Fe2O319.49wt%, La2O310.17wt%, Ce2O314.50wt%) 를 첨가하여 혼합한다. 상기 혼합물을 소정의 형상으로 압축성형하고, 볼밀에 2시간 연마한다. 연마후 소성로에 1300℃로 소성시킨다. 소성후 면을 더욱 고르게 하기 위해 볼밀을 사용하여 다시 연마하고, 열풍건조기에 60℃로 5시간 건조시킨다, 건조후유약 처리하여 900℃로 소성시키면 세라믹스 제품이 완성되는데, 이렇게 완성된 세라믹스 제품은 약 200~1,300개의 음이온을 방출한다.Clay 90% (Composition ratio: 46 wt% SiO 2, 39 wt% Al 2 O 3 , 3 wt% Fe 2 O 3 , CaO 4 wt%, MgO 2 wt%, TiO 1 wt%, K 2 O 2 wt%, Na 2 O 3 wt%, 10% (composition ratio: 39.18 wt% Al 2 O 3 , SiO 2 16.66 wt%, Fe 2 O 3 19.49 wt%, La 2 O 3 10.17 wt%, Ce 2 O 3 14.50 wt%) Add and mix. The mixture is compression molded into a predetermined shape and ground in a ball mill for 2 hours. After polishing, the resultant was calcined at 1300 ° C. in a kiln. After firing, the surface is polished again using a ball mill and dried in a hot air dryer for 5 hours at 60 ° C. After drying, the ceramics are finished by glazing and firing at 900 ° C. It releases 200 to 1,300 anions.
<실시예2>Example 2
점토 90%(구성비율:SiO246wt%, Al2O339wt%, Fe2O33wt%, CaO 4wt%, MgO 2wt%, TiO 1wt%, K2O 2wt%, Na2O 3wt%,)에 산화물계 세라믹스 분말 10%(구성비율:Al2O316.99wt%, SiO28.54wt%, Fe2O313.03wt%, La2O315.58wt%, CeO239.12wt%, P2O56.13wt% 및 CaO 0.61wt%)를 첨가하여 혼합한다. 상기 혼합물을 압축성형하고 연마하여 소성하고 면을 고르게 하기 위하여 다시 연마한다. 원적외선은 약 90%이상의 방사율을 갖는 것으로 나타났다.Clay 90% (Composition ratio: 46 wt% SiO 2, 39 wt% Al 2 O 3 , 3 wt% Fe 2 O 3 , CaO 4 wt%, MgO 2 wt%, TiO 1 wt%, K 2 O 2 wt%, Na 2 O 3 wt%, 10% (composition ratio: 16.99 wt% Al 2 O 3 , SiO 4 8.54 wt%, 13.03 wt% Fe 2 O 3 , La 2 O 3 15.58 wt%, CeO 2 39.12 wt%, P 2) 6.13 wt% O 5 and 0.61 wt% CaO) are added and mixed. The mixture is compression molded, ground, calcined and ground again to even the face. Far infrared rays have an emissivity of about 90% or more.
<실시예3>Example 3
점토 90%(구성비율:SiO246wt%, Al2O339wt%, Fe2O33wt%, CaO 4wt%, MgO 2wt%, TiO 1wt%, K2O 2wt%, Na2O 3wt%,) 에 산화물계 세라믹스분말 10%(구성비율: Al2O31.56wt%, SiO24.15wt%, Fe2O31.78wt%, La2O317.84wt%, CeO235.07wt%, Sm2O32.90wt%, Gd2O31.41wt%, P2O516.12wt%, Nd2O312.89wt%, AgO 2.47wt% 및 NiO 3.81wt%)를 첨가하여 혼합한다. 상기 혼합물을 소정의 형상으로 압축성형하고, 볼밀을 사용하여 2시간 연마한다. 연마후 소성로에 1,300℃로 소성시킨다. 소성후 면을 더욱 고르게 하기 위해 볼밀을 사용하여 다시 연마하고, 열풍건조기에 60℃로 5시간 건조시킨다, 건조 후 유약 처리하여 900℃로 소성시키면 세라믹스 제품이 완성되며, 상기 세라믹스 제품은 음이온이 200~1,300개가 방출되고 원적외선은 약 90%이상의 방사율을 갖는 것으로 나타났다.Clay 90% (Composition ratio: 46 wt% SiO 2, 39 wt% Al 2 O 3 , 3 wt% Fe 2 O 3 , CaO 4 wt%, MgO 2 wt%, TiO 1 wt%, K 2 O 2 wt%, Na 2 O 3 wt%, 10% (composition ratio: 1.56 wt% Al 2 O 3, 4.15 wt% SiO 2, 1.78 wt% Fe 2 O 3 , La 2 O 3 17.84 wt%, CeO 2 35.07 wt%, Sm 2) 2.90 wt% O 3, 1.41 wt% Gd 2 O 3, 16.12 wt% P 2 O 5, 12.89 wt% Nd 2 O 3, 2.47 wt% AgO and 3.81 wt% NiO). The mixture is compression molded into the desired shape and polished for 2 hours using a ball mill. After polishing, the resultant is fired at 1,300 ° C. in a firing furnace. After firing, the surface is further polished using a ball mill and dried in a hot air dryer at 60 ° C. for 5 hours. After drying, glazing and firing at 900 ° C. completes a ceramics product. ~ 1,300 are emitted and far infrared rays have emissivity of about 90% or more.
상기 실시예 1에 의해 만들어진 세라믹스 제품, 즉 장신구, 장식품 및 건강보조용품은 음이온을 200~1,300개 방출하며 산화물계 세라믹스 비율을 증가시키면 방출량이 높아진다.The ceramic products made by Example 1, that is, jewelry, ornaments and health care products emit 200 ~ 1,300 negative ions and increasing the amount of the oxide-based ceramics increases.
실시예 2에 의해 제조된 세락믹스 제품은 원적외선을 90%이상 방사하며, 실시예 3에 의해 제조된 제품은 음이온 200~1,300개를 방출하고 동시에 원적외선을 90%이상 방사하여, 사용자에게 신체적으로 유익한 효능을 줄 수 있다.The cerammix product manufactured by Example 2 emits more than 90% of far infrared rays, and the product produced by Example 3 emits 200-1,300 anions and simultaneously emits more than 90% of far infrared rays, which is physically beneficial to the user. It can give efficacy.
이상과 같이 본 발명의 실시예를 설명하였으나 본 발명의 구체적인 구성은 상기 실시예에 한정하지 않고 본 발명의 요지를 이탈하지 않는 범위 내에서 다양하게 변경이 가능하다.Although the embodiments of the present invention have been described as described above, the specific configuration of the present invention is not limited to the above embodiments and various modifications can be made without departing from the gist of the present invention.
또한, 상기 점토와 산화물계 세라믹스 분말의 혼합물에 원적외선을 방출하는 맥반석, 옥, 제올라이트, 코디어라이트, 고령토, 흑연, 또는 숯 등의 분말을 첨가할 수도 있다.In addition, powders such as ganbanite, jade, zeolite, cordierite, kaolin, graphite, or charcoal that emit far infrared rays may be added to the mixture of the clay and the oxide ceramic powder.
또한, 성형체는 제품이나 장식품은 건강보조용품은 실생활 주변에서 다양하게 사용되는 모든 세라믹스 제품에 폭 넓게 응용될 수 있다.In addition, the molded body products or ornaments, health supplements can be widely applied to all ceramic products that are used in various ways around the real life.
상기에 언급된 바와 같이, 본 발명에 따른 음이온 및 원적외선을 방출하는 기능성 세라믹제품 및 그 제조방법은 장신구, 장식품 또는 건강보조용품에 관한 것으로, 음이온, 원적외선, 또는 동시에 음이온과 원적외선을 방출할 수 있도록 함으로써 사용자에게 신체적으로 유익한 효능을 줄 수 있다.As mentioned above, the functional ceramic products that emit anions and far infrared rays according to the present invention and methods for manufacturing the same are related to jewelry, ornaments or health supplements, so that they can emit anions, far infrared rays, or at the same time anion and far infrared rays. As a result, a physically beneficial effect can be given to the user.
또한, 본 발명은 제품 외관을 아름답게 하여 소장의 가치를 증대시킬 수 있도록 하며, 생체학적인 약리기능을 가지며, 제조를 용이하게 하여 생산성을 크게 향상시키고 생산비를 저렴하게 할 수 있도록 하는 장점이 있다.In addition, the present invention to increase the value of the small intestine to beautify the appearance of the product, has a biological pharmacological function, and has the advantage of greatly improving the productivity and low production cost by facilitating the manufacture.
한편, 상기에서는 본 발명의 바람직한 실시예들을 참조하여 설명하였지만, 해당 기술분야에서 통상의 지식을 가진 자라면 하기의 청구의 범위에 기재된 본 발명의 사상 및 영역으로부터 벗어나지 않는 범위 내에서 본 발명을 다양하게 수정 및 변경시킬 수 있음을 이해할 수 있을 것이다.On the other hand, while the above has been described with reference to the preferred embodiments of the present invention, those skilled in the art to which the present invention pertains without departing from the spirit and scope of the present invention described in the claims below It will be understood that modifications and changes can be made.
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Cited By (7)
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| KR20110119435A (en) * | 2010-04-27 | 2011-11-02 | 신언장 | The anion occurrence stick for an automobile fuel curtailment and the manufacturing method |
| CN101328082B (en) * | 2008-06-06 | 2012-10-24 | 牛崇光 | Manufacturing process of high pure negative ion far infrared multifunctional ceramic glaze additive |
| WO2014123294A1 (en) * | 2013-02-06 | 2014-08-14 | (주)에릭스 | Heating element composition heated by being coated on surface of heat resistant ceramic ware and absorbing microwaves, ceramic ware transfer paper containing same, far infrared ray-radiating and heating ceramic ware containing same, and preparation method therefor |
| KR20190043262A (en) * | 2017-10-18 | 2019-04-26 | 정래옥 | A helping device for health and the using method for the device |
| RU2706285C1 (en) * | 2018-06-13 | 2019-11-15 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Владимирский Государственный Университет имени Александра Григорьевича и Николая Григорьевича Столетовых" (ВлГУ) | Ceramic mixture for making front articles |
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| KR910009955A (en) * | 1989-11-17 | 1991-06-28 | 김종기 | Manufacturing method of panel with excellent surface gloss |
| KR0134174B1 (en) * | 1992-04-30 | 1998-04-27 | 사또우 후미오 | Receiving device for remote control signal |
| KR960011317A (en) * | 1994-09-06 | 1996-04-20 | 이헌조 | Heating control method of combined air / heater |
| KR970020126A (en) * | 1995-10-06 | 1997-05-28 | 김영초 | Manufacturing method of far infrared radiation tile |
| KR19990079691A (en) * | 1998-04-08 | 1999-11-05 | 정금주 | Disposable Heating Element Composition |
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| CN101328082B (en) * | 2008-06-06 | 2012-10-24 | 牛崇光 | Manufacturing process of high pure negative ion far infrared multifunctional ceramic glaze additive |
| KR20110119435A (en) * | 2010-04-27 | 2011-11-02 | 신언장 | The anion occurrence stick for an automobile fuel curtailment and the manufacturing method |
| WO2014123294A1 (en) * | 2013-02-06 | 2014-08-14 | (주)에릭스 | Heating element composition heated by being coated on surface of heat resistant ceramic ware and absorbing microwaves, ceramic ware transfer paper containing same, far infrared ray-radiating and heating ceramic ware containing same, and preparation method therefor |
| KR20190043262A (en) * | 2017-10-18 | 2019-04-26 | 정래옥 | A helping device for health and the using method for the device |
| RU2706285C1 (en) * | 2018-06-13 | 2019-11-15 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Владимирский Государственный Университет имени Александра Григорьевича и Николая Григорьевича Столетовых" (ВлГУ) | Ceramic mixture for making front articles |
| CN111620700A (en) * | 2019-02-28 | 2020-09-04 | 曾曼利 | Formaldehyde-removing ceramic product and manufacturing process thereof |
| CN112010678A (en) * | 2020-10-26 | 2020-12-01 | 佛山市东鹏陶瓷发展有限公司 | Photocatalytic anion ceramic tile containing multiple dielectric substances and preparation process thereof |
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