CN108947571B - Tourmaline ceramic product and preparation method thereof - Google Patents

Tourmaline ceramic product and preparation method thereof Download PDF

Info

Publication number
CN108947571B
CN108947571B CN201811094260.4A CN201811094260A CN108947571B CN 108947571 B CN108947571 B CN 108947571B CN 201811094260 A CN201811094260 A CN 201811094260A CN 108947571 B CN108947571 B CN 108947571B
Authority
CN
China
Prior art keywords
tourmaline
ceramic product
water
ceramic
kaolin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201811094260.4A
Other languages
Chinese (zh)
Other versions
CN108947571A (en
Inventor
唐家生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Dashi New Materials Technology Co ltd
Original Assignee
Shanghai Dashi New Materials Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Dashi New Materials Technology Co ltd filed Critical Shanghai Dashi New Materials Technology Co ltd
Priority to CN201811094260.4A priority Critical patent/CN108947571B/en
Publication of CN108947571A publication Critical patent/CN108947571A/en
Application granted granted Critical
Publication of CN108947571B publication Critical patent/CN108947571B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063Preparing or treating the raw materials individually or as batches
    • C04B38/0635Compounding ingredients
    • C04B38/0645Burnable, meltable, sublimable materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/04Clay; Kaolin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)

Abstract

The invention relates to a tourmaline ceramic product and a preparation method thereof, wherein the tourmaline ceramic product comprises the following components in percentage by weight: 5-30% of tourmaline, 5-15% of glazed fruit, 0.1-5% of loosening agent and the balance of porcelain clay and kaolin. Compared with the prior art, the ceramic product of the invention not only has the practicability and the process aesthetics of the traditional ceramic, but also has the characteristics of improving the water quality, releasing negative ions and radiating far infrared rays of the tourmaline, and endows the traditional ceramic with a health care function.

Description

Tourmaline ceramic product and preparation method thereof
Technical Field
The invention belongs to the field of ceramic chemical industry, and particularly relates to a ceramic product containing tourmaline.
Background
Tourmaline (Tourmaline) is a product of [ Si ] with additional anion, complex anion or water6O18]The cyclic ring-shaped silicate mineral group is divided into four groups, namely Dravite-schorl-elbaite (dralite), natronite (Tsilaisite), kainite (Uvite) and buergite (Buergerite) according to different chemical components. The four tourmaline chemical compositions are respectively: Mg-Fe-Li tourmaline Na (MgFeLiAl)3Al6[Si6O18][BO3]3(OH,O,F)4Sodium manganese tourmaline NaMn3Al6[Si6O18][BO3]3(OH)4Calcium magnesium tourmaline CaMg4Al5[Si6O18][BO3]3(OH)4Tourmaline of Bo Ge NaFe3Al6[Si6O18][BO3]3O3F。
The tourmaline is the only natural mineral substance which has piezoelectric effect and thermoelectric effect in the earth mineral products, and the micro-powder tourmaline has a positive electrode and a negative electrode. When the external environment changes, such as light irradiation, temperature change, contact with water, etc., the electrical performance is outstanding. The tourmaline has the main functions as follows: (1) releasing negative ions: the negative ions are also called as air vitamins, have the function of adjusting the ion balance of the human body, relax the body and mind, activate cells, improve the natural healing force and the like, and can inhibit the oxidation or aging of the body; (2) electrolyzing water: the tourmaline can generate weak current when contacting with water, and generate electric decomposition effect on water, so that the water becomes alkalescent (pH value is about 7.4) negative ion water which has better taste and is more beneficial to human health; (3) changing the large molecular groups of water into small molecular groups: molecules in water do not exist independently, but are combined with each other to form water molecule groups, the water molecule groups in tap water contain about 13 water molecules, the water molecule groups in pure water contain about 10 water molecules, and the water molecule groups treated by tourmaline contain 6-7 water molecules, so that small molecule group water is generally more beneficial to human bodies, and is called as 'energy water' in Japan; (4) emitting far infrared rays: the far infrared rays can permeate deep parts of the body, warm cells, promote blood circulation and smooth metabolism, and the far infrared ray radiation power of the tourmaline is close to 100 percent, which is higher than that of other minerals; (5) contains multiple trace elements; the tourmaline contains various mineral substances required by human body, and can generate microelements such as calcium, magnesium, iron, etc. in water after contacting with water, thereby having good supplementing effect on human body.
Tourmaline has a wide application range, and is widely used in semiconductor industry, medicine, daily chemical industry, textile, health care products and the like besides being used as traditional ornamental jewelry. The development of modern high technology makes tourmaline have a new invention which revives people in the aspect of ceramic materials. The tourmaline purple sand product is an invention patent (patent number ZL03141973.9) which is applied by Tang family in 2003 and granted by the national patent office in 5 months in 2005 by the inventor of the present application. The tourmaline purple sand product of the invention keeps all the practicability and manufacturability of Yixing purple sand ceramics, increases the physical health-care functional characteristic of tourmaline and compounds the physical health-care functional characteristic into a new high-tech functional characteristic. The tourmaline purple sand teapot or cup produced by the patent plays a great role in changing the water property and improving the human health level.
The ceramic is an inorganic non-metallic material prepared by crushing, mixing, molding and calcining natural clay and various natural minerals serving as main raw materials, and the ceramic product, namely domestic ceramic or industrial ceramic, is widely used in work and life of people.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a tourmaline ceramic product which not only has the practicability and the process aesthetics of the traditional ceramics, but also has the health-care functions of improving the water quality, releasing negative ions and radiating far infrared rays of tourmaline and the like, and a preparation method thereof.
The purpose of the invention can be realized by the following technical scheme: the tourmaline ceramic product is characterized by comprising the following components in percentage by weight:
5-30% of tourmaline, 5-15% of glazed fruit, 0.1-5% of loosening agent and the balance of porcelain clay and kaolin.
The tourmaline is high-quality non-radioactive tourmaline and is a product sold in the market.
The glazed fruit is a high-quality glazed fruit produced in Jingdezhen, Jiangxi province, China and is a product sold in the market.
The loosening agent is one or a mixture of more of calcite, calcium carbonate, calcium bicarbonate and calcium hydroxide.
The weight ratio of the porcelain clay to the kaolin is 1: 1-1: 3.
The ceramic product also contains other auxiliary materials of the commercial ceramic product.
The preparation method of the tourmaline ceramic product is characterized by comprising the following steps: the tourmaline is mixed with 5-30 wt%, glazed fruit 5-15 wt%, loosening agent 0.1-5 wt% and porcelain clay for the rest, and the ceramic product is prepared through conventional ceramic product firing process at 1000-1300 deg.c for 10-48 hr.
The preparation method specifically comprises the following steps:
1. preparing raw materials: the tourmaline, the glazed fruit, the porcelain clay, the kaolin, the loosening agent and other auxiliary materials with the particle fineness of 200 meshes to 2000 meshes after being crushed are fully mixed. The content of tourmaline is 5 to 30 percent, the content of enamel fruit is 5 to 15 percent, the content of loosening agent is 0.1 to 5 percent, and the rest is porcelain clay, kaolin and other auxiliary materials. The bulking agent can be one of calcite, calcium carbonate, calcium bicarbonate, calcium hydroxide, or a mixture thereof. The weight ratio of the kaolin to the china clay in the raw materials is 1:1 to 1: 3. When the raw materials are mixed, the raw materials may be mixed manually or may be stirred by a stirrer.
2. Blank preparation: adding water into the mixture, stirring, optionally adding other adjuvants, manually or mechanically making into required ware blank according to conventional porcelain making process, and drying in shade. Glazing may be provided or may not be provided.
3. Firing: and (3) putting the dried device blank into a kiln for burning, wherein the burning temperature is 1000-1300 ℃, and the burning time is 10-48 hours.
In the manufacturing process of the invention, the proportion of the tourmaline is not too high or too low, the tourmaline can not be exerted if the proportion is too low, and the tourmaline is not easy to be fired and molded if the proportion is too high. During firing, temperature control is very important, and lower temperature firing is preferably selected, and the firing time is correspondingly prolonged.
Compared with the prior art, the invention has the following beneficial effects:
1. the invention adds tourmaline, glaze fruit and loosening agent with special formula into the raw material of ceramic product, wherein the tourmaline is a product with [ Si ] added with anion, complex anion or water6O18]The invention relates to a ring-shaped base type silicate mineral group, in particular to a glaze fruit which is one of glaze making raw materials in the traditional porcelain making process of Jingdezhen. The invention selects high-quality tourmaline without radioactivity produced in Xinjiang, combines with the glaze fruit which is a traditional glaze making raw material and is special in Jingdezhen area, adds a loosening agent, and has the combined action of the three, so that the original compact porcelain can generate a micro ion channel, and the contact between water molecules and the tourmaline is increased, thereby realizing the effect of improving the water quality by the tourmaline. If the surface of the porcelain is glazed, the improvement of water quality can be reduced or even completely avoided.
In the field of tourmaline ceramics, particularly porcelain, are compact and pore-free, and unlike purple sand, tourmaline added into the ceramics is difficult to contact water or has limited contact area under general technical conditions, so that the tourmaline cannot improve water quality. On the basis of multiple experimental studies, the invention selects the glaze fruit and the loosening agent to be matched with the tourmaline to achieve more ideal effects.
2. The tourmaline ceramic product not only keeps the characteristics of traditional ceramic products such as simplicity, elegance, beauty and practicability, but also has the health care functions of releasing anions and far infrared of tourmaline, leading water to be ionized into alkaline anion water, reducing water molecular groups and the like. The tourmaline ceramic cup is used for drinking water, so that the water quality is optimized, the taste is better, and the tourmaline ceramic cup is beneficial to the body; the tourmaline ceramic pot is used for making tea, so that the tea has more fragrant and elegant taste; the wine drinking by using the tourmaline ceramic wine set can make the wine taste more mellow and full; the cigarette is put into a tourmaline ceramic utensil for storage, so that the taste of the cigarette is more smooth; the tourmaline ceramics is made into flowerpots and fish tanks, so that flowers and plants can grow more flourishing, fishes are more active and the like. The tourmaline ceramic product provided by the invention can be various daily necessities, and brings health and happiness for the life of people.
Detailed Description
The following examples are given for the detailed implementation and specific operation of the present invention, but the scope of the present invention is not limited to the following examples.
The tourmaline adopted by the invention is high-quality non-radioactive tourmaline sold in the market.
Example 1
Crushing all raw materials to the particle fineness of about 1000 meshes, taking 5 kg of tourmaline powder, 5 kg of enamel, 0.1 kg of calcite, 30 kg of kaolin, 56 kg of porcelain clay and 3.9 kg of other auxiliary materials, fully mixing, adding water, stirring, manually or mechanically preparing a required ware blank according to a traditional porcelain manufacturing process, and drying in the shade. And (3) firing the dried device blank in a kiln at the firing temperature of 1000 ℃ for 48 hours to obtain the tourmaline ceramic.
Example 2:
all raw materials are crushed to the particle fineness of about 300 meshes, 30 kg of tourmaline powder, 15 kg of glaze fruit, 5 kg of calcium bicarbonate, 20 kg of kaolin and 30 kg of porcelain clay are taken, fully mixed, added with water and stirred, manually or mechanically made into a required ware blank according to the traditional porcelain manufacturing process, and dried in the shade. And (3) firing the dried device blank in a kiln at 1300 ℃ for 10 hours to obtain the tourmaline ceramic.
Example 3:
all raw materials are crushed to the particle fineness of about 500 meshes, 10 kg of tourmaline powder, 10 kg of glaze fruit, 1 kg of calcium hydroxide, 30 kg of kaolin, 45 kg of porcelain clay and 4 kg of other auxiliary materials are taken, fully mixed, added with water and stirred, manually or mechanically made into a required ware blank according to the traditional porcelain manufacturing process, and dried in the shade. And (3) firing the dried device blank in a kiln at 1100 ℃ for 24 hours to obtain the tourmaline ceramic.
Example 4:
the preparation method comprises the steps of crushing all raw materials to the particle fineness of about 800 meshes, taking 5 kg of tourmaline powder, 5 kg of glaze, 2 kg of calcium carbonate, 30 kg of kaolin, 55 kg of porcelain clay and 3 kg of other auxiliary materials, fully mixing, adding water, stirring, manually or mechanically preparing a required ware blank according to a traditional porcelain manufacturing process, and drying in the shade. And (3) firing the dried device blank in a kiln at 1200 ℃ for 18 hours to obtain the tourmaline ceramic.
The tourmaline ceramic product provided by the invention is detected by the analytical test center of Shanghai light industry institute, and the product prepared in the embodiment is placed in the product prepared in the embodiment with commercially available drinking purified water, and is kept stand for 4 hours, and the detection result is as follows:
Figure BDA0001805158080000051
2. the ceramic product manufactured in the above example was measured for normal emissivity at 50 ℃, and the test results were as follows:
F1 F2 F3 F4 F5 F6 F7 F8
0.89 0.90 0.90 0.89 0.89 0.89 0.89 0.89
wherein: f1 is the total wavelength emissivity, F2 is the integral emissivity of 8-25 μm, F3 is 8.45 μm, F4 is 9.50 μm, F5 is 10.60 μm, F6 is 12.00 μm, F7 is 13.50 μm, and F8 is the integral emissivity of 14-25 μm. The control detection results are all lower than 0.50.
It can be seen that the ceramic product of the present invention has the features of improved water quality, releasing negative ion and radiating far infrared ray.

Claims (5)

1. The tourmaline ceramic product is characterized by comprising the following components in percentage by weight: 5-30% of tourmaline, 5-15% of glaze, 0.1-5% of a loosening agent and the balance of porcelain clay and kaolin, wherein the weight ratio of the porcelain clay to the kaolin is 1: 1-1: 3, and the particle fineness of the tourmaline is 200-2000 meshes.
2. The tourmaline ceramic product according to claim 1, wherein the tourmaline is commercially available high-quality non-radioactive tourmaline.
3. The tourmaline ceramic product according to claim 1, wherein the glaze is a high quality glaze produced in Jingdezhen, Jiangxi, China.
4. The tourmaline ceramic product according to claim 1, wherein the bulking agent is one or more of calcite, calcium carbonate, calcium bicarbonate and calcium hydroxide.
5. A method for preparing the tourmaline ceramic product according to claim 1, comprising the steps of: uniformly mixing 5-30% of tourmaline, 5-15% of glazed fruit, 0.1-5% of a loosening agent and the balance of porcelain clay and kaolin according to the weight percentage, and preparing the ceramic product according to a conventional firing method of the ceramic product, wherein the firing temperature is 1000-1300 ℃, and the firing time is 10-48 hours.
CN201811094260.4A 2018-09-19 2018-09-19 Tourmaline ceramic product and preparation method thereof Active CN108947571B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811094260.4A CN108947571B (en) 2018-09-19 2018-09-19 Tourmaline ceramic product and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811094260.4A CN108947571B (en) 2018-09-19 2018-09-19 Tourmaline ceramic product and preparation method thereof

Publications (2)

Publication Number Publication Date
CN108947571A CN108947571A (en) 2018-12-07
CN108947571B true CN108947571B (en) 2021-08-27

Family

ID=64471349

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811094260.4A Active CN108947571B (en) 2018-09-19 2018-09-19 Tourmaline ceramic product and preparation method thereof

Country Status (1)

Country Link
CN (1) CN108947571B (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101182234A (en) * 2007-11-19 2008-05-21 赣州托玛琳环保科技有限公司 Tourmaline honeycomb ceramics and method for making same
JP2008308354A (en) * 2007-06-13 2008-12-25 Shoichi Miyasaka Porcelain tile and its manufacturing method
CN102432325A (en) * 2011-07-25 2012-05-02 广东骏丰频谱实业有限公司 Three-dimensional porous far infrared negative ion ceramic body, preparation method and application
CN107628807A (en) * 2017-10-18 2018-01-26 魏喜成 A kind of preparation method of anion porous ceramic film material

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1244516C (en) * 2000-10-13 2006-03-08 中外合资湖南安沙尼传质设备有限公司 Special tourmaline ceramic product
CN1207244C (en) * 2003-07-31 2005-06-22 唐家生 Tourmaline-purple sand product
KR100890228B1 (en) * 2008-09-19 2009-03-24 (주)일원산업 Pitcher ceramic block
CN104860653B (en) * 2015-06-02 2016-08-24 景德镇市亚星特种陶瓷有限公司 A kind of preparation technology of ling-lung ware teacup
CN105060843B (en) * 2015-08-17 2017-09-01 景德镇红叶陶瓷股份有限公司 A kind of preparation method of strengthened jade porcelain and its prepared product
CN107572822A (en) * 2017-09-28 2018-01-12 禹州市大龙山钧瓷文化有限公司 A kind of pottery plum green glaze and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008308354A (en) * 2007-06-13 2008-12-25 Shoichi Miyasaka Porcelain tile and its manufacturing method
CN101182234A (en) * 2007-11-19 2008-05-21 赣州托玛琳环保科技有限公司 Tourmaline honeycomb ceramics and method for making same
CN102432325A (en) * 2011-07-25 2012-05-02 广东骏丰频谱实业有限公司 Three-dimensional porous far infrared negative ion ceramic body, preparation method and application
CN107628807A (en) * 2017-10-18 2018-01-26 魏喜成 A kind of preparation method of anion porous ceramic film material

Also Published As

Publication number Publication date
CN108947571A (en) 2018-12-07

Similar Documents

Publication Publication Date Title
CN101342042A (en) Health preserving health care dark-red enameled pottery
CN110015884A (en) A kind of antibacterial environment protection domestic ceramics and preparation method thereof
JP2018193292A (en) Composite ceramic and method of production and method of application thereof
CN1207244C (en) Tourmaline-purple sand product
CN107573047B (en) Hydrogen water preparation ceramic material and preparation method and application thereof
CN101264435A (en) Pottery fragments capable of adsorbing, purifying, mineralizing and generating alkalescence food
CN109437924B (en) A kind of antibacterial ceramic product and preparation method thereof
CN103387421A (en) Ceramic glaze with nanometer self-cleaning sterilization function and using method of ceramic glaze
CN112028471B (en) Inorganic antibacterial material for high-temperature ceramic and preparation method and application thereof
CN107117818B (en) Medium-temperature saturated bubble glaze ceramic with gold tailing configuration and manufacturing process thereof
CN108516683B (en) Crystal glazed tile capable of continuously generating negative ions and preparation method thereof
CN112441745A (en) Antibacterial glaze and preparation method and application thereof
CN108947571B (en) Tourmaline ceramic product and preparation method thereof
CN101638314B (en) Light foamed tourmaline purple sand material and preparation method thereof
CN105110778A (en) Beer mate ceramic ball
CN109160733A (en) A kind of ceramics of the glaze containing tourmaline ceramic and preparation method thereof
CN1244516C (en) Special tourmaline ceramic product
CN110642612A (en) Energy temmoku ceramic cup and preparation process thereof
CN112194475B (en) Antibacterial ivory porcelain
CN112110651B (en) Preparation method of ultra-smooth sanitary ceramic antibacterial glaze
KR100545046B1 (en) Functional ceramic products that emit negative ions and far infrared rays and methods of manufacturing the same
CN111995359A (en) Nixing pottery capable of controllably releasing negative oxygen ions and generating hydrogen-rich water and preparation method thereof
KR20180021989A (en) Multi-function ceramic ware and Manufacturing Method thereof
CN109305812A (en) Anion titanium crystalline substance sterilizes ecological brick
CN109851320A (en) The preparation method of photosensitive Antibacterial ceramics

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant