KR20010103832A - Protecting agent from grass disease - Google Patents
Protecting agent from grass disease Download PDFInfo
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- KR20010103832A KR20010103832A KR1020010064510A KR20010064510A KR20010103832A KR 20010103832 A KR20010103832 A KR 20010103832A KR 1020010064510 A KR1020010064510 A KR 1020010064510A KR 20010064510 A KR20010064510 A KR 20010064510A KR 20010103832 A KR20010103832 A KR 20010103832A
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- grass
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- disease
- weeds
- control
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/10—Animals; Substances produced thereby or obtained therefrom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Virology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
잔디의 유해병을 방제 및 잡초를 제거하기 위하여 여러가지 방제 약품을 사용해 왔으나 고농도로 사용하면 약해가 있고 인체에 유해하는 등 문제점이 있기 때문에 저농도로 안전하고 인체나 가축에 무해한 방제제의 개발이 요구된다.In order to control harmful diseases of grass and to remove weeds, various control chemicals have been used, but when used at high concentrations, there are problems such as weakness and harmful to human body. .
본 발명은 잔디병 방제 및 잡초를 제거할 수 있는 조성물에 관한 것으로키토산 또는 키토산 유도체을 염수에 유기산과 함께 용해시김으로써 키토산의 잔디병에 대한 작용기작의 안정성을 가져와 높은 항균활성을 나타내어 적은양으로 잔디병을 방제할 수 있고 동시에 잡초를 제거할 수 있을 뿐아니라 잔디의 발근을 촉진하고 잔디의 생체 활성을 높일 수 있는 잔디병 방제제 및 제초제에 관한 것이다.The present invention relates to a composition capable of controlling grass disease and removing weeds, and dissolving chitosan or chitosan derivatives together with organic acids in saline to bring about the stability of chitosan's mechanism of action against turfgrass and exhibit high antimicrobial activity. The present invention relates to a grass disease control agent and a herbicide which can control grass disease and at the same time remove weeds, promote grass rooting and increase grass bioactivity.
이 경우 잡초의 제거효과와 잔디에 발병되는 병을 예방 치료할 수 있을 뿐만 아니라 물에 용해시켜 사용할 경우 보다도 낮은 농도로 살포할 수 있기 때문에 잔디에 대한 효과와 경제적 효과도 기대할 수 있다.In this case, not only can weed removal effect of the weeds and the disease caused on the grass, but also can be sprayed at a lower concentration than when dissolved in water can be expected to be effective and economic effect on the grass.
Description
잔디의 유해 병을 방제 및 잡초를 제거하기 위하여 여러 가지 방제 약품을 사용해 왔으나 고농도로 사용하면 약해가 있고 인체에 유해하는 등 문제점이 있기 때문에 저농도로 안전하고 인체나 가축에 무해한 방제제의 개발을 기대한다.In order to control harmful diseases of grass and to remove weeds, various control chemicals have been used, but when used at high concentration, there are problems such as weakness and harmful to human body. do.
키토산은 갑각류나 미생물의 세포벽에서 추출한 키틴을 탈아세틸화하여 얻은 물질로서 근년 수처리제, 토양개량제 등으로 사용되고 있으며 특히 식물에 대하여는 발근 촉진하고 식물체의 활성을 높여 병충해의 발생을 억제하는 등 식물의 생장촉진 작용이 있으며 일본특개평5-30207호, 특개평8-175892, 특개평 10-236910 등에는 키토산을 유기산에 배합하여 사용할 경우에 야채의 부패병, 잔디의 춘고병, 라지패취, 입고병, 브라운패취, 과수의 흑성병 등에 유효한 것으로 기재하고 있다.Chitosan is a material obtained by deacetylating chitin extracted from the shells of shellfish and microorganisms. In recent years, chitosan has been used as a water treatment agent and soil improving agent. In Japanese Patent Laid-Open Nos. 5-30207, 8-175892, 10-236910, etc., when chitosan is used in combination with an organic acid, it is a vegetable decay disease, a grass spring disease, a large patch, a wearing bottle, and a brown patch. It is described as being effective in fruit trees, black diseases, and the like.
또한 잔디에 있어서 클로버나 쑥등의 잡초에 의해 잔디가 제대로 자라지 못하여 고가의 잔디를 죽이게 되는 경우가 허다하다. 이를 방지하기 위하여 잡초를 일일이 손으로 제거하거나 맹독성 농약으로 된 제초제를 살포하여 잡초를 제거하는 방법이 사용되어지고 있다. 그러나 상기와 같이 잡초를 일일이 손으로 제거하거나 맹독성 농약으로 된 제초제를 살포하여 잡초를 제거하는 방법은 많은 시간과 인력이 필요하고, 각종 화학성분에 의해 토양이나 수질을 오염시켜 환경을 파괴하고, 인체에 해로운 영향을 미치게 되는 문제점이 있었다. 이를 해결하는 수단으로 한국특허공고 2001-0000642에는 염수를 주제로 한 조성물을 잔디에 사용함으로써 인체나 가축에 무해하고 제초성능이 유효하다는 것을 기재하고 있다.In addition, in grass, grasses cannot grow properly due to weeds such as clover or wormwood, and expensive grass is often killed. To prevent this, weeds have been used to remove weeds by hand or by spraying herbicides with toxic pesticides. However, the method of removing the weeds by removing the weeds manually by hand or by spraying the herbicides of toxic pesticides requires a lot of time and manpower, and destroys the environment by contaminating soil or water by various chemicals, There was a problem that has a detrimental effect on. As a means to solve this problem, Korean Patent Publication No. 2001-0000642 discloses that the composition of the saline-based composition is harmless to humans or livestock, and the herbicidal performance is effective.
그러나 상기의 키토산은 어느정도 잔디의 병에는 효과가 있지만 병원균의 핵은 완전히 제거하지 못하는 단점이 있고 잡초제거에 있어서도 염분의 농도가 높아 여름과 같은 경우 잔디에 해가 될 수 있다.However, the chitosan to some extent is effective in the disease of grass, but the nucleus of pathogens are not completely eliminated, and the high concentration of salt in the weed removal may be harmful to grass in summer.
본 발명에서는 잔디병 방제 및 잡초를 제거할 수 있는 조성물에 관한 것으로 키토산 또는 키토산 유도체을 염수에 유기산과 함께 용해시킴으로써 키토산의 잔디병에 대한 작용기작의 안정성을 가져와 높은 항균활성을 나타내어 적은 양으로 잔디병을 방제할 수 있고 동시에 잡초를 제거할 수 있을 뿐 아니라 잔디의 발근을 촉진하고 잔디의 생체 활성을 높일 수 있는 잔디병 방제제 및 제초제에 관한 것이다.The present invention relates to a composition capable of controlling grass disease and removing weeds, and by dissolving chitosan or chitosan derivatives together with organic acid in saline, bringing the stability of the mechanism of action against chitosan grass disease, showing high antimicrobial activity The present invention relates to a grass disease control agent and a herbicide which can control weeds and simultaneously remove weeds, promote rooting of grass and increase grass bioactivity.
본 발명은 잔디의 병방제 및 잡초의 제거할 수 있는 조성물에 관한 것으로 더욱 상세하게는 해수 또는 염분이 용해된 염수에 유기산을 용해하고 키토산 또는 키토산 유도체을 상기의 용액에 용해함으로써 제조되는 잔디의 병 방제제 및 제초제에 관한 것이다.The present invention relates to a disease control of grass and a composition capable of removing weeds, and more particularly, to the control of grass prepared by dissolving organic acid in seawater or salt-dissolved saline and dissolving chitosan or chitosan derivatives in the above solution. It relates to herbicides and herbicides.
본 발명을 상세히 설명하면 키토산은 분자량이 5,000 내지 2,000,000 범위인 키토산을 전제 총량에 대하여 0.1 내지 30중량 %함유 되도록 사용하고 본 발명에사용된 저분자 키토산은 탈아세틸화도 75% 이상이고 분자량 5,000 내지 2,000,000인 것을 사용하되 특히 탈아세틸화도가 90%이상, 분자량이 10,000 내지100,000인 것을 사용하면 더욱 좋다. 키토산 유도체는 CM-키토산, 4급화한 키토산을 사용할 수 있고 4급화 키토산이 더욱 효과적이다.Detailed Description of the Invention Chitosan is used to contain 0.1 to 30% by weight of chitosan with a molecular weight in the range of 5,000 to 2,000,000, and the low molecular weight chitosan used in the present invention has a deacetylation degree of 75% or more and a molecular weight of 5,000 to 2,000,000. In particular, the deacetylation degree is 90% or more, the molecular weight of 10,000 to 100,000 is better to use. Chitosan derivatives may use CM-chitosan, quaternized chitosan, and quaternized chitosan is more effective.
한편, 본 발명에서 사용한 유기산은 초산, 젓산, 글루콘산, 아스코브산 등이고 이중 초산이 가장 적당하다. 유기산의 농도는 저분자 키토산의 중량에 대하여 30중량% 내지는 300중량%까지 사용할 수 있고 이중 키토산의 중량에 대하여 50중량%내지 동량을 사용하는 것이 바람직하다.On the other hand, the organic acid used in the present invention is acetic acid, lactic acid, gluconic acid, ascorbic acid and the like, of which acetic acid is most suitable. The concentration of the organic acid may be used in an amount of 30% to 300% by weight based on the weight of the low molecular weight chitosan, and preferably 50% by weight to the same amount based on the weight of the chitosan.
또한 본 발명에 사용한 해수 또는 염수는 농도를 3중량% 내지 30중량%의 염분이 포함되도록 사용하며 바람직하게는 3중량% 내지 10중량%를 포함한 것을 사용하는 것이 바람직하다.In addition, the seawater or brine used in the present invention is used to contain a concentration of 3% by weight to 30% by weight of salt, it is preferable to use those containing 3% by weight to 10% by weight.
이하, 상기와 같은 혼합물로 제조된 본 발명을 구체적으로 설명한다.Hereinafter, the present invention prepared with the mixture as described above will be described in detail.
실시예 1Example 1
해수 900g(1000g 당 염분 함유량 50g으로 조정)에 초산 50g을 희석하고 여기에 저분자 키토산(분자량 45000, 탈아세틸화도 93%)를 50g 용해시켜 잔디의 병 방제제 및 제초제를 제조하였다.50 g of acetic acid was diluted in 900 g of seawater (adjusted to 50 g of salt content per 1000 g), and 50 g of low molecular weight chitosan (molecular weight 45000, 93% deacetylation) was dissolved to prepare a bottle control agent and a herbicide of grass.
실시예 2Example 2
염수(염분 3%) 900g을 넣은 것을 제외하고는 실시예 1과 동일하게 실시하였다.The same procedure as in Example 1 was conducted except that 900 g of brine (3% saline) was added thereto.
비교예 1Comparative Example 1
해수 대신 물을 사용한 것을 제외하고는 실시예 1과 동일하게 사용하였다.It was used in the same manner as in Example 1 except that water was used instead of sea water.
실시예 3 (항균실험)Example 3 (Antibacterial Test)
배지에 잔디의 춘고병원균인Pythium handermatum IFO 7030, 라지패취, 브라운패취 병원균인Rhizoctonia solani IFO 30462, 잔디의 입고병의 병원균인Helminthosporium sacchari IFO 9283 을 PSA배지에 25℃로 5일간 배양한 균체를 접종하고 25℃에서 10일간 배안 배양한 MIC값의 결과를 표 1에 나타내었다.The culture medium was inoculated with Pythium handermatum IFO 7030 , a grass patch, Brown patch pathogen, Rhizoctonia solani IFO 30462 , and Helminthosporium sacchari IFO 9283 , a pathogen in grass, at 25 ° C for 5 days. Table 1 shows the results of the MIC values incubated at 25 ° C. for 10 days.
표1에서 보는 바와 같이 비교예에 비하여 매우 높은 항균활성을 가지고 있임을 알 수 있다.As shown in Table 1 it can be seen that it has a very high antimicrobial activity compared to the comparative example.
실시예 3Example 3
토끼풀이나 다년생 잡초의 제초성을 조사하기 위하여 상기의 조성물을 500배 희석하여 100평당 40L를 분무하여 살포한 결과 잔디가 강하게 잘 자랄 뿐아니라 잔디에는 해가 없고 다년생 잡초, 토끼풀 등이 죽는 것을 확인할 수 있었고 병해도 전혀 생기지 않았다.In order to investigate the herbicidal properties of shamrock or perennial weeds, the composition was diluted 500 times and sprayed by spraying 40L per 100 pyeong, and the grass grows well and the grass is harmless and perennial weeds, shamrock, etc. can be confirmed. There was no disease at all.
상기와 같이 염수에 키토산을 녹여 잔디에 살포하였을 경우 잡초의 제거효과와 잔디에 발병되는 병을 예방 치료할 수 있을 뿐만 아니라 물에 용해시켜 사용할경우보다도 낮은 농도로 살포할 수 있기 때문에 잔디에 대한 효과와 경제적 효과도 기대할 수 있다.When the chitosan is dissolved in the brine and sprayed on the grass as described above, it is possible to prevent the treatment of weeds and to prevent diseases caused by the grass, and to spray at a lower concentration than when used by dissolving it in water. Economic effects can also be expected.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100468002B1 (en) * | 2002-02-19 | 2005-01-24 | 이수양 | The manufacturing method of a herbicidal composition comprising mainly salt for grass-protection |
KR100611561B1 (en) * | 2004-04-26 | 2006-08-10 | 이상호 | A mildewcide composition using NaOH, wood vinegar liquor, SiO2, platycodon root, chitosan |
KR100722366B1 (en) * | 2005-05-06 | 2007-05-28 | 남궁선 | Process of protecting agent from grass disease |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01313403A (en) * | 1988-06-14 | 1989-12-18 | Fuso Kagaku Kogyo Kk | Controller of blight for laver and controlling of blight of laver |
JPH06181636A (en) * | 1992-12-18 | 1994-07-05 | Supaisu Food Kk | Growth activating agent for lawn grass |
JPH06345609A (en) * | 1993-06-03 | 1994-12-20 | Masashi Yokoyama | Disease injury controlling agent in zoisia japonica |
JPH0812514A (en) * | 1993-08-12 | 1996-01-16 | Suetsuna Yoko | Plant disease controlling agent specifically containing peptide, chitosan and organic acid salt |
KR20010000642A (en) * | 2000-10-11 | 2001-01-05 | 이수양 | A herbicidal composition for grass-protection comprising mainly saltwater |
-
2001
- 2001-10-19 KR KR1020010064510A patent/KR20010103832A/en not_active Application Discontinuation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01313403A (en) * | 1988-06-14 | 1989-12-18 | Fuso Kagaku Kogyo Kk | Controller of blight for laver and controlling of blight of laver |
JPH06181636A (en) * | 1992-12-18 | 1994-07-05 | Supaisu Food Kk | Growth activating agent for lawn grass |
JPH06345609A (en) * | 1993-06-03 | 1994-12-20 | Masashi Yokoyama | Disease injury controlling agent in zoisia japonica |
JPH0812514A (en) * | 1993-08-12 | 1996-01-16 | Suetsuna Yoko | Plant disease controlling agent specifically containing peptide, chitosan and organic acid salt |
KR20010000642A (en) * | 2000-10-11 | 2001-01-05 | 이수양 | A herbicidal composition for grass-protection comprising mainly saltwater |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100468002B1 (en) * | 2002-02-19 | 2005-01-24 | 이수양 | The manufacturing method of a herbicidal composition comprising mainly salt for grass-protection |
KR100611561B1 (en) * | 2004-04-26 | 2006-08-10 | 이상호 | A mildewcide composition using NaOH, wood vinegar liquor, SiO2, platycodon root, chitosan |
KR100722366B1 (en) * | 2005-05-06 | 2007-05-28 | 남궁선 | Process of protecting agent from grass disease |
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