KR20010098986A - Liquid heat insulation coat(TEMP-COAT) - Google Patents

Liquid heat insulation coat(TEMP-COAT) Download PDF

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Publication number
KR20010098986A
KR20010098986A KR1020010046873A KR20010046873A KR20010098986A KR 20010098986 A KR20010098986 A KR 20010098986A KR 1020010046873 A KR1020010046873 A KR 1020010046873A KR 20010046873 A KR20010046873 A KR 20010046873A KR 20010098986 A KR20010098986 A KR 20010098986A
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South Korea
Prior art keywords
insulation
silica
thermal conductivity
coat
liquid
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KR1020010046873A
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Korean (ko)
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김종군
전양읍
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김종군
주식회사삼우특수개발
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Priority to KR1020010046873A priority Critical patent/KR20010098986A/en
Publication of KR20010098986A publication Critical patent/KR20010098986A/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/022Emulsions, e.g. oil in water
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/113Silicon oxides; Hydrates thereof
    • C01B33/12Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14Colloidal silica, e.g. dispersions, gels, sols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013Fillers, pigments or reinforcing additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D107/00Coating compositions based on natural rubber
    • C09D107/02Latex
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic

Abstract

본 발명은 각종 건축물 및 산업설비에 사용되는 1액형 바르는(액상형) 단열 코팅재로서 결합재로서 접착력이 우수한 라텍스,아크릴 에멀전 및 액상 실리카-졸(sol)을 사용하고 무기질 필러 로서는 탈크,실리카 외에 열전도율이 낮은 마이크로 세라믹 필러(micro ceramic filler)를 사용하여 제조한 제품으로서 얇은 도막두께(1-1.5mm)로서도 일반적으로 사용되고 있는 스치로폼에 근접하는 단열효과를 발휘하는 장점을 가지고 있으며 특징 으로서는The present invention is a one-part coating (liquid type) thermal insulation coating material used in various buildings and industrial facilities as a binder using a latex, acrylic emulsion and liquid silica-sol having excellent adhesive strength, and as inorganic filler, low thermal conductivity besides talc and silica. It is a product manufactured using micro ceramic filler, and has the advantage of showing insulation effect close to that of styrofoam, which is also commonly used as a thin film thickness (1-1.5mm).

1) 시공이 간편하며 코팅만으로 마감처리가 되므로 별도의 마감작업이 필요치 않으며1) Easy construction and finish only by coating, so no separate finishing work is needed.

2) 기존의 단열재가 차지하는 부피에 따른 공간이 줄어들게 되며2) The space according to the volume occupied by the existing insulation is reduced

3) 수입품 대체효과를 기할수 있으며3) It can replace the imported goods

4) 낮은 열전도율로서 난방에 사용되는 에너지 절감효과와4) Low thermal conductivity and energy savings

5) 단열과 함께 결로방지 성능을 함께 지니고 있으며5) With insulation and condensation prevention

6) 재료자체의 적응 온도범위가 -40℃에서 +280℃까지로 어떠한 기후조건에서도 적응가능 하며 현재까지 사용되고 있는 기존 단열재(고상 및 액상제품)의 모든 문제점을 해결한 신 기술의 제품이다6) The adaptable temperature range of the material itself is -40 ℃ to + 280 ℃, which is adaptable to any climatic conditions and is a new technology product that solves all the problems of existing insulation materials (solid and liquid products).

Description

바르는 단열재(TEMP-COAT){Liquid heat insulation coat(TEMP-COAT)}Liquid heat insulation coat (TEMP-COAT)

현재 각종 건축물 및 산업설비에 단열목적으로 사용되고 있는 재료로는 스치로폼,우레탄폼,고상 건축용 단열자재 및 일반 단열페인트 등을 들수 있으나 충분한 단열효과를 발휘하지 못하고 있으며 내구성 및 작업성이 불편한 애로점이 발생되고 있다The materials currently used for insulation purposes in various buildings and industrial facilities include styrofoam, urethane foam, insulation materials for solid building and general insulation paint, but they do not exhibit sufficient insulation effect and have difficulties in durability and workability. have

스치로폼의 경우 재료자체의 부피가 큰 관계로 건축물의 활용공간을 많이 차지하여 실유효 면적을 줄이게 되는 단점과 우레탄폼의 경우 높은 도막두께로 인한 기본적인 단열효과는 있으나 내열성이 부족하여 화재의 위험이 있으며 화재 발생시 유독한 가스의 유출로 인한 문제점과 건축물 철거시 야기되는 다량의 우레탄폼 폐기물처리도 큰 문제점으로 지적되고 있다In the case of styrofoam, the material itself has a large volume, which occupies a lot of space for the building, reducing the effective area, and urethane foam has the basic insulation effect due to the high film thickness, but there is a risk of fire due to lack of heat resistance. Problems caused by the leakage of toxic gas in the event of fire and disposal of a large amount of urethane foam waste caused by the demolition of buildings are also pointed out as major problems.

또한 고상형 단열자재는 작업성이 불편하며 일반 단열페인트의 경우 열전도율이 낮아 단열효과가 크지 못하며 다량의 무기질 필러(filler)의 첨가로 인하여 건축물 내,외부의 온도차이로 인하여 발생되는 결로(結露) 현상을 어느정도 방지할수 있으나 이 또한 충분한 효과를 기하기 어려운 실정이다In addition, solid insulation materials are inconvenient in workability, and in the case of general insulation paints, the thermal conductivity is low, so the insulation effect is not large. Condensation caused by the temperature difference inside and outside the building due to the addition of a large amount of inorganic fillers The phenomenon can be prevented to some extent, but it is also difficult to achieve sufficient effects.

본 발명은 1액형 액상형 단열 코팅재로서 기존의 각종 단열재료가 지니고 있는 상기의 모든 문제점을 해결한 새로운 기술의 제품으로서The present invention is a one-component liquid type thermal insulation coating material as a product of a new technology that solves all the problems of the existing various insulating materials

1) 낮은 열전도율로 인하여 단열효과가 뛰어 나므로 각종 건축물에 대해 에너지 절약효과를 기할수 있고(열전도율 : 0.03Kcal/mh℃: KSL 9016-95)1) Because of the excellent thermal insulation effect due to low thermal conductivity, energy saving effect can be achieved for various buildings (thermal conductivity: 0.03Kcal / mh ℃: KSL 9016-95)

2) 적은 도막두께로서도 높은 단열효과를 발휘하므로 건축물의 사용공간을 넓힐수 있으며2) It has a high insulation effect even with a small film thickness, so it can increase the use space of the building.

3) 액상형 단열재 이므로 붓,로라,스프레이등 바르는 작업이 가능하며3) As it is a liquid insulation material, it is possible to apply brushes, rollers, sprays, etc.

4) 실리카-졸(sol)과 세라믹 필러의 사용으로 인하여 단열효과와 함께 건축물의 결로현상을 방지할수 있는 장점을 지니고 있다4) The use of silica sol and ceramic fillers has the advantage of preventing insulation and condensation of buildings.

특히 바인더(결합재)중의 실리카-졸(sol)은 열전도율이 낮은 실리카 파우더를 액상화 시킨 졸(sol)형태의 물질로서 바인더분 자체의 열전도율을 낮출수 있다 또한 열전도율이 낮은 마이크로 세라믹 필러(micro ceramic filler)의 사용은 기존의 무기질 필러인 실리카,탈크(talc),탄산칼슘 등의 재료와는 달리 제품의 열전도율을 획기적으로 낮출수 있으며 바인더분에 적절하게 분산(dispersion)시키는 것이 핵심 기술이라 할수 있다Particularly, the silica-sol in the binder (binder) is a sol type material in which silica powder with low thermal conductivity is liquefied and can lower the thermal conductivity of the binder powder itself. In addition, the micro ceramic filler with low thermal conductivity Unlike the existing inorganic filler materials such as silica, talc, and calcium carbonate, it is possible to drastically lower the thermal conductivity of the product, and to disperse the binder powder properly is the core technology.

본 발명은 라텍스(latex),아크릴에멀젼 및 실리카-졸을 결합재로 하고 무기질 필러 로서는 탈크,실리카 및 마이크로 세라믹 필러를 사용하여 단열효과를 증대시켜 건축물에 사용되는 에너지의 절감효과를 기하며 얇은 도막두께로서 시공하므로(1-1.5mm) 건축물의 유효면적을 극대화 시킬수 있는 새로운 기술의 1액형 액상형단열코팅재 이다The present invention is a latex (latex), acrylic emulsion and silica-sol as a binder and as the inorganic filler using talc, silica and micro-ceramic fillers to increase the thermal insulation effect to reduce the energy used in buildings and thin film thickness It is a one-component liquid type thermal insulation coating material of new technology that can maximize the effective area of buildings as it is constructed (1-1.5mm).

아래에 실시 예를 통하여 본 발명을 상세히 설명한다The present invention will be described in detail through the following examples.

실시 예에 있어 "부"는 중량비 이다In the example, "part" is weight ratio.

실시 예Example

제조 용기에 라텍스 10-30부,아크릴 에멀젼 수지 10-30부, 액상 실리카-졸 10-30부를 차례로 투입하여 40-60℃ 에서 30분-1시간 서서히 교반후 zinc oxide 10-30부,titanium dioxide 10-30부,탄산칼슘 5-15부를 투입하여 고속교반으로 30분간 분산 시킨다 이때 사용되는 라텍스는 CR계,SBR계 등이 사용 될수 있다10-30 parts of latex, 10-30 parts of acrylic emulsion resin, and 10-30 parts of liquid silica-sol were gradually added to the production container, and stirred slowly at 40-60 ° C. for 30 minutes to 1 hour, followed by 10-30 parts of zinc oxide, and titanium dioxide. 10-30 parts, 5-15 parts of calcium carbonate are added and dispersed for 30 minutes by high speed agitation. The latex used can be CR, SBR, etc.

다음 열전도율이 낮은 마이크로 세라믹 필러(micro ceramic filler)를 서서히 투입하여 혼합 교반후 2-5시간 숙성시킨다 이때의 숙성은 세라믹 필러와 기타 무기질 필러 사이에 결합재가 충분히 습윤되어 완전한 분산상태를 이루기 위해서 이며 마이크로 세라믹 필러는 SiO2/Al2O3/Fe2O3계 이며 particle size는 10마이크론 이하의 것을 사용한다Next, the micro ceramic filler with low thermal conductivity is gradually added and aged for 2-5 hours after mixing and stirring. At this time, the binder is sufficiently wetted between the ceramic filler and other inorganic fillers to achieve a complete dispersion state. Ceramic filler is SiO2 / Al2O3 / Fe2O3 type and particle size is less than 10 micron.

다음 동결안정제 로서 ethylene glycol 또는 propylene glycol을 약 2-5부 투입하여 30분 동안 서서히 교반한다 다음 물을 5-10부 혼합하여 20-30분간 저속 교반한 다음 증점제(thickner)로서 미립자 실리카계를 1-2부 첨가하여 1시간 숙성후 본 발명품을 완성한다Next, add about 2-5 parts of ethylene glycol or propylene glycol as a freeze stabilizer, and stir for 30 minutes. Then, mix 5-10 parts of water and stir at low speed for 20-30 minutes, and then use fine particle silica as thickener. -2 parts are added and the present invention is completed after 1 hour of aging.

상기의 제품으로서 열전도율 시험을 한 결과 0.03Kcal/mh℃(KSM 9016-95)가 나왔으며 이는 일반 건축물의 단열재로서 사용 가능한 수치이며 기존 사용하고 있는 각종 고상형 단열재의 대체효과와 건축물의 유효면적을 넓힐수 있고 기존 단열재로서 사용되고 있는 우레탄 폼의 폐기물 처리문제도 해결할수 있는 장점을 지닐수 있다As a result of the thermal conductivity test, 0.03Kcal / mh ℃ (KSM 9016-95) was obtained as the above product. It can be expanded and solve the waste disposal problem of urethane foam which is used as the existing insulation.

또한 현재 수입하여 사용되고 있는 액상형 단열재의 수입대체 효과를 기할 수 있는 신 기술의 제품이라 할수 있다In addition, it can be said to be a new technology product that can replace the import effect of the liquid type heat insulating material currently imported and used.

Claims (2)

1. 결합재(binder)로서 라텍스,아크릴 에멀젼 및 실리카-졸(sol)을 사용하여 제조한 1액형 바르는(액상형) 단열 코팅재 조성물1. A one-part top coating (liquid) thermal insulation coating composition prepared using latex, acrylic emulsion and silica-sol as binder. 상기 1항의 결합재에 마이크로 세라믹 필리(micro ceramic filler)를 사용하여 제조한 1액형 바르는(액상형) 단열 코팅재 조성물A one-part coating (liquid type) thermal insulation coating composition prepared using a micro ceramic filler to the binder of claim 1
KR1020010046873A 2001-07-27 2001-07-27 Liquid heat insulation coat(TEMP-COAT) KR20010098986A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102234482A (en) * 2010-04-29 2011-11-09 陈轶 Energy-efficient priming paint
CN102382533A (en) * 2010-09-01 2012-03-21 北京航材百慕新材料技术工程股份有限公司 Environment-friendly aqueous industrial thermal insulation coating

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0192290A (en) * 1987-10-05 1989-04-11 Bridgestone Corp Fireproofing coating material
KR920000788A (en) * 1990-06-18 1992-01-29 후지사와 도모 기치로 Polypeptide Compounds and Methods for Making the Same
JP2000027020A (en) * 1998-07-06 2000-01-25 Tanizawa Seisakusho Ltd Tropical cap

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0192290A (en) * 1987-10-05 1989-04-11 Bridgestone Corp Fireproofing coating material
KR920000788A (en) * 1990-06-18 1992-01-29 후지사와 도모 기치로 Polypeptide Compounds and Methods for Making the Same
JP2000027020A (en) * 1998-07-06 2000-01-25 Tanizawa Seisakusho Ltd Tropical cap

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102234482A (en) * 2010-04-29 2011-11-09 陈轶 Energy-efficient priming paint
CN102382533A (en) * 2010-09-01 2012-03-21 北京航材百慕新材料技术工程股份有限公司 Environment-friendly aqueous industrial thermal insulation coating

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